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**IIT-JEE 2011 – Pattern and Analysis
**

IIT-JEE, the most challenging of the Engineering Entrance exams in the country and probably the world has proved that it has not lost its charm at all and has retained its glory as ever. IIT-JEE 2011 was conducted on 10th April 2011 in 131 cities all over India in 1051 centres for 4,85,262 registered candidates. Paper 1 was from 9.00 – 12.00 hrs and paper 2 from 14.00 to 17.00 hrs.

For the first time, JEE has announced that scanned images of the Optical Response Sheets with the candidates’ details and their responses (answers) will be displayed on the JEE website after 25th May, 2011. Answer key to the JEE 2011 questions will be displayed on the JEE website on 15th May, 2011 after completing the evaluation of OMR sheets.

There were 10 versions for IIT-JEE 2011 – 0 to 9. The order of subjects in both papers were the same – Chemistry, Mathematics and Physics but the total marks, the number of questions and types of questions in both papers were distinct from each other.

Paper 1

Paper1 had 69 questions in total for 240 marks - in the order of Chemistry, Physics and Mathematics. Each subject had 23 questions and the pattern was exactly the same for all the subjects.

Number Type of question of questions Section I - Single Correct Answer Type Section II - Multiple Correct Answers Type Section III - Paragraph Type Section IV - Integer Answer Type 7 4 5 7

Marks for a correct answer 3 4 3 4

Negative marking –1 NIL –1 NIL

Total Marks for the Section 21 16 15 28

**What was new in IIT-JEE 2010 in comparison with earlier years – Paper 1:
**

NO partial marks are awarded for correct answers in Multiple Correct Type questions. Last year there were partial marks.

Part 1 - Chemistry This is a moderate level paper leaning more towards easy level of difficulty. The usual weightage of Physical > Organic > Inorganic Chemistry is maintained. Most of the questions in this paper evaluate the conceptual clarity of the student.

**CHEMISTRY - PAPER I - Difficulty Analysis
**

(on a total of 80 marks) 20% Easy 28% Medium

Difficult 53%

The topic wise distribution of the questions is shown below:

**CHEMISTRY - PAPER I - Topic wise Analysis
**

(on a total of 80 marks) 24% 46% Inorganic Chemistry Organic Chemistry Physical Chemistry

30%

Part 2 – Physics Overall the difficulty level of the paper was moderate. Still there were a few numerical questions involving elaborate mathematical calculations making them time consuming and hence difficult. No representation of Optics in this paper. Major focus in this paper was on Mechanics (for a total marks of 31)

**PHYSICS - PAPER I - Difficulty Analysis
**

(on a total of 80 marks)

36% 38%

Easy

Medium

Difficult

26%

The topic wise analysis of paper 1 for Physics is shown below.

**PHYSICS - PAPER I - Topic wise Analysis
**

(on a total of 80 marks)

Electricity & Magnetism 8% 16% 29% Heat & thermodynamics Mechanics

Modern Physics 9% 38% Properties of Matter

Part 3 – Mathematics Mathematics part of the 2011 JEE paper 1 was considered easier than the paper 1 of 2010. Few questions in Integer answer type require in-depth understanding of the concepts with perseverance in solving problems. Trigonometry had a good representation in the paper; the passage on matrices required quick thinking to interpret and solve the questions. One question about ‘3 3 non-singular skew symmetric matrices’ has a basic flaw since odd ordered skew symmetric matrices are always singular. As shown below paper 1 was a moderately difficult paper.

**MATHEMATICS - PAPER I - Difficulty Analysis
**

(on a reduced total of 76 marks) 5% Easy 41% Medium

Difficult 54%

Algebra and Matrices & Determinants, Vectors had the major shares with Calculus and Trigonometry following close. Topic wise analysis is given below.

MATHEMATICS - PAPER I - Topic wise Analysis

(on a reduced total of 76 marks) Algebra Coordinate Geometry Differential Calculus Integral Calculus Trigonometry 18% 13% 5% 9% Vectors, 3-D, Matrices & Determinants

22%

33%

Paper 2

Paper 2 had 60 questions in total - in the order of Chemistry, Physics and Mathematics. Each subject had 20 questions and as in paper 1 the pattern was exactly the same across the subjects. Questions had differential markings, each subject had 80 marks and the maximum mark for the paper was 240.

Number Type of question of questions Section I - Single Correct Choice Type Section II – Multiple Correct answers Type Section III - Integer Answer Type Section IV – Matrix Match Type 8 4 6 2

Marks for a correct answer 3 4 4 8

Negative marking –1 NIL NIL NIL

Total Marks for the Section 24 16 18 16

**What was new in IIT-JEE 2011 in comparison with earlier years – Paper 2:
**

For the first time Multiple Answer Type, Integer Answer Type and Matrix Match Type appeared in one paper.

Part 1 - Chemistry Paper 2 of IIT-JEE 2011 was difficult compared to paper 1. Weightage wise the Physical > Organic > Inorganic formula is maintained. Generally the nature of the questions in Physical chemistry is calculation oriented and hence the difficulty. Also complexity of Organic questions made this paper a challenging one. The difficulty analysis and the topic wise analysis are shown below:

**CHEMISTRY - PAPER II - Difficulty Analysis
**

(on a total of 80 marks) 13% 34% Medium Easy

Difficult 54%

**CHEMISTRY - PAPER II - Topic wise Analysis
**

(on a total of 80 marks)

23% 41%

Inorganic Chemistry Organic Chemistry Physical Chemistry

36%

Part 2 – Physics Questions from certain areas which were not represented in paper 1 (gravitation, optics etc.) appeared in paper 2 thus balancing the syllabus coverage. The difficulty level of this paper was slightly less than paper 1 especially the Integer Answer Type.

**PHYSICS - PAPER II - Difficulty Analysis
**

(on a total of 80 marks) 5% Easy 48% Medium

Difficult 48%

And the less colourful distribution of marks across the topics in Physics shown below confirms the overall lion’s share of Mechanics in Physics part of the IIT-JEE 2011 paper 2.

PHYSICS - PAPER II - Topic wise Analysis

(on a total of 80 marks) 9% 5% 31%

Electricity & Magnetism Heat & thermodynamics Mechanics

Modern Physics

45%

10%

Optics

Part 3 – Mathematics Paper 2 Mathematics part was tougher than the first paper – for the complexity in combining topic areas, for e.g. the matrix match had questions from 4 different areas posing a challenge for the student in the exam hall. Likewise, this paper required more calculations in solving than the first paper.

Matrices & Determinants .Topic wise Analysis (on a total of 80 marks) Algebra 13% 14% 25% Coordinate Geometry Differential Calculus Integral Calculus 21% 27% Vectors.PAPER II . The topic wise distribution is shown below: MATHEMATICS .PAPER I .Difficulty Analysis (on a total of 80 marks) 14% 26% Easy Medium Difficult 60% The second paper was restricted to lesser number of areas. 3-D.g. But this time Differential Calculus and Coordinate Geometry were well represented. MATHEMATICS . there were no questions from Trigonometry. for e.Overall Mathematics part of IIT-JEE 2011 was less difficuly and less time consuming than that of 2010.

. (B). Corporate Office : ALLEN CAREER INSTITUTE. tetrahedral and square planar (B) tetrahedral.in Website: www. CN and H2O respectively. out of which QPN["QPG is correct. Fax : +91-744-2435003.744 . [Ni(H 2O) 6 ]2+ Cl 2 Cl Cl sp3 tetrahedral 40 AgNO3 (aq.ac. INDRA VIHAR.1 RCTV" /" K" *EJGOKUVT[+ UGEVKQP"/"K"*VQVCN"OCTMU"<"43+ *Ukping"Eqttgev"Cpuygt"V{rg+ This section contains 9"ownvkrng"ejqkeg"swguvkqpu.allen. square planar and octahedral (C) square planar. the plot of conductance (L) versus the volume of AgNO3 is - A LL EN Ni Cl 30 Cpu0*D+ NC NC Ni CN 2 H2 O OH2 H2 O dsp square planar 2 CN OH2 OH2 sp3d2 octahedral Ni OH2 2+ L L L L volume (S) (D) (S) volume (P) (A) (P) 40 Cpu0*F+ As AgNO3 is added volume (Q) (B) (Q) volume (R) (C) (R) K+ + Cl + Ag+ + NO3 ¾® AgCl(s)¯ + K+ + NO3 Number of ions are approximately constant. E-mail: info@allen. KOTA-324005 PHONE : +91 . After equivalence point number of ions. 30 Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl. Each question has four choices (A). when AgNO3 is added till equivalence point. are (A) octahedral. CP-6. tetrahedral and octahedral (D) octahedral.ac.2011) PAPER .) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured.04 . (C) and (D).IIT-JEE 2011 EXAMINATION (HELD ON : 10 .2436001. [Ni(CN)4 ]2. increases and hence conductivity.. “SANKALP”.in 1 / 28 . square planar and octahedral [NiCl 4 ]2.

2011) PAPER . (i) and (ii) as shown. Z ® positron 60 Extra pure N2 can be obtained by heating (A) NH3 with CuO (C) (NH4)2Cr2O7 60 Cpu0*F+ Extra pure N2 can be obtained by heating of Ba(N3)2 D Ba(N3)2 ¾¾ ® Ba+ 3N2 70 Among the following compounds. neutron (A) proton.2436001. "[ and \ respectively are : 27 Al 13 (i) 30 14 Si (ii) 30 P 15 + [ + Z 30 14Si + \ (B) neutron.in . the most acidic is (A) p-nitrophenol (C) o-hydroxybenzoic acid (B) p-hydroxybenzoic acid (D) p-toluic acid 70 Cpu0*E+ Most acidic Due to ortho effect and chelation in its conjugate base. positron (C) proton. E-mail: info@allen. proton (D) positron.allen. CP-6. positron.ac. Fax : +91-744-2435003. neutron.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . “SANKALP”. o-hydroxy benzoic acid is most acidic. Y ® neutron. proton.1 50 Bombardment of aluminium by a-particle leads to its artificial disintegration in two ways.ac. positron.04 . neutron 50 Cpu0*C+ (i) (ii) 27 13 4 30 1 Al + 2 He ¾¾ ® 14 Si + 1 P X ® proton. Products Z. 2 / 28 A LL EN 27 13 4 30 Al + 2 He ¾¾ ® 15 P+ 1 0n 30 14 0 Si + 1 e (B) NH4NO3 (D) Ba(N3)2 O COH OH O C O H O Intramolecular H-bonding 1 Conjugate base Corporate Office : ALLEN CAREER INSTITUTE. KOTA-324005 PHONE : +91 .744 . INDRA VIHAR.in Website: www.

ac. INDRA VIHAR.00 M (C) 2.15 Corporate Office : ALLEN CAREER INSTITUTE.1 80 The major product of the following reaction is O C (i) KOH NH (ii) Br CH2Cl C O O C (A) O Br C (B) C NCH2 O O C N O O CH2Cl (C) 80 A LL EN N (D) C C N OCH2 Br O Cpu0*C+ CH2Cl O C O C C NH + KOH N K + C O O Br CH2 Cl O C N CH2 Br C O 90 Dissolving 120 g of urea (mol.2436001. wt. Fax : +91-744-2435003.78 M (B) 2.744 .allen.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . CP-6.2011) PAPER . The molarity of the solution is (A) 1. “SANKALP”.15 g/mL.in 90 3 / 28 .ac. E-mail: info@allen.04 . KOTA-324005 PHONE : +91 .05 M (D) 2.22 M Cpu0*E+ Mass of solute (urea) = 120 g Mass of solvent (water) = 1000 g Total mass of solution = (mass of solute + mass of solvent) = 120 + 1000 = 1120 g 2 ´ 1000 = 2.in Website: www. 60) in 1000 g of water gave a solution of density 1.05 M M= 1120 /1.

Each questions has four choices (A). Fax : +91-744-2435003. is (are) - A LL EN H CC H H2C CH2 (B) H C º C C H H CH2 CH2 H CH2 (A) (C) H2C = C = O . INDRA VIHAR.2436001.0 Cpu0*D.ac. H H Corporate Office : ALLEN CAREER INSTITUTE.in Website: www.2011) PAPER . D D CuS + 2O2 ¾¾ ® CuSO4 . (b) HCºCC CH2 H Molecular plane (c) H C=C=O H Molecular plane H (d) H C=C=C All atoms are not present in the same plane.allen. KOTA-324005 PHONE : +91 . “SANKALP”.F+ Extraction of tin from cassiterite (SnO2) involves reduction of ore (oxide) by carbon. (C) and (D) out of which QPG"qt"OQTG may be correct. CP-6. (B). E-mail: info@allen.E. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any).04 . FeS + 2O2 ¾¾ ® FeSO4 . When the concentrated tin stone ore SnO2 (ore of Sn) is heated strongly in a free supply of air (roasting) the impurities of CuS and FeS present in the ore are converted into CuSO4 and FeSO4 tgurgevkxgn{0"The CuSO4 and FeSO4 are water soluble which are leached out by hot water.744 .in Ans.E+ (D) H2C = C = CH2 (a) Different conformations dont have all atoms in the same plane.ac.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . is (B) and (C) 4 / 28 . :0 Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (C) removal of copper impurity :0 (B) self-reduction of a sulphide ore (D) removal of iron impurity Cpu0*C.0 Amongst the given option.1 UGEVKQP"/" KK"*VQVCN"OCTMU"<"38+ *Ownvkrng"Eqttgev"Cpuygtu"V{rg+ This section contains 4 ownvkrng"ejqkeg"swguvkqpu.

ac.ac. Addition of aqueous NH3 dissolves O and gives in intense blue solution.D.2436001. the solution turns light blue.04 .E. 340 350 360 The metal rod M is (A) Fe The compound N is (A) AgNO3 (B) Zn(NO3)2 (C) Al(NO3)3 (D) Pb(NO3)2 The final solution contains (A) [Pb(NH3)4]2+ and [CoCl4]2 (C) [Ag(NH3)2]+ and [Cu(NH3)4]2+ (B) [Al(NH3)4]3+ and [Cu(NH3)4]2+ (D) [Ag(NH3)2]+ and [Ni(NH3)6]2+ (B) Cu (C) Ni (D) Co A LL EN 330 According to kinetic theory of gases Corporate Office : ALLEN CAREER INSTITUTE. Each of these questions has four choices (A). Fax : +91-744-2435003. however it is very slow due to higher energy of activation 320 Cpu0*C. INDRA VIHAR.allen.in Website: www. Rctcitcrj" hqt" Swguvkqpu" Pqu0" 34" vq" 36 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N. 5"ownvkrng"ejqkeg"swguvkqpu and based on the other paragraph 4"ownvkrng"ejqkeg"swguvkqpu have to be answered.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . CP-6.F+ Pqvg"<"Qrvkqp"*C+"ku"eqttgev"cu"rgt"PEGTV"dqqm"dwv"hgy"gzcorngu"ctg"mpqyp"yjgtg"DJcfuqtrvkqp ku"gxgp"gpfqvjgtoke0 (A) collisions are always elastic (B) heavier molecules transfer more momentum to the wall of the container (C) only a small number of molecules have very high velocity 330 Cpu0*C. the molecules move in straight lines with constant velocities. KOTA-324005 PHONE : +91 . (C) and (D).D.F+ (D) between collisions. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Based upon one of the paragraph. UGEVKQP"/"KKK"*VQVCN"OCTMU"<"37+ *Rctcitcrj"V{rg+ This section contains 4"rctcitcrju. (B).in 5 / 28 . E-mail: info@allen. “SANKALP”. out of which QPN["QPG is correct.2011) PAPER .744 .1 320 The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are) (A) Adsorption is always exothermic (B) Physisorption may transform into chemisorption at high temperature (C) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature (D) Chemisorption is more exothermic than physisorption.

AgCl Cu + 2AgNO3 ¾® Cu(NO3)2 + 2Ag + AgNO3 (unreacted) excess light Blue AgNO3 + NaCl ¾® AgCl¯ + NaNO3 (unreacted) white ppt AgCl + 2NH3 ¾® [Ag(NH3)2]+ + Cl Cu(NO3)2 + 4 NH3 ¾® [Cu(NH3)4]2+ + NO3 deep Blue 340 350 360 Cpu0*D+ Cpu0*C+ Cpu0*E+ Rctcitcrj" hqt" Swguvkqpu" Pqu0" 37" vq" 38 An acyclic hydrocarbon P. E-mail: info@allen. O . KOTA-324005 PHONE : +91 . INDRA VIHAR. Fax : +91-744-2435003. CP-6.AgNO3 .2436001.04 .allen.acid (i) dil H2SO4/HgSO4 Q 2 H3C O C CH3 370 The structure of compound P is (A) CH3CH2CH2CH2CºCH H3C (C) H–C–CºC–CH3 H3C (B) H3CH2CºCCH2CH3 H3C (D) H3C–C–CºC–H H3C 380 The structure of the compound Q is H3C OH (A) H–C–C–CH2CH3 H3C H H3C OH (B) H3C–C–C–CH3 H3C H OH H3C (C) H–C–CH2CHCH3 H3C OH (D) CH3CH2CH2CHCH2CH3 6 / 28 Corporate Office : ALLEN CAREER INSTITUTE. gave acetone as the only organic product through the following sequence of reactions.1 Uqn0"qh" 34"vq"36 M .ac.Cu . having molecular formula C6H10. in the which Q is an intermediate organic compound. (i) conc.2011) PAPER .ac. “SANKALP”.in . N .744 .IIT-JEE 2011 EXAMINATION (HELD ON : 10 .in Website: www.H2SO4 (Catalytic amount) (–H2O) (ii) O3 (iii) Zn/H2O A LL EN P (C6H10) (ii) NaBH4/ethanol (iii) dil.

in Website: www. ms = 1/2.ac.2436001. n=3. 390 Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas. KOTA-324005 PHONE : +91 . CP-6.2 shift of CH3 H3 C + H3C C CH CH 3 H3C O C H2SO4 H3C H3C H *Kpvgigt"Cpuygt"V{rg+ This section contains 9"swguvkqpu. No. ranging from 0 to 9.1 370 380 Uqn0"qh" 37"vq"38 Cpu0*F+ Cpu0*D+ P Þ Me3C C º CH HgSO4/dil.+ l=0 l=1 l=2 Total No.in . The answer to each of the questions is a ukping/fkikv"kpvgigt. E-mail: info@allen. Cpu0*7+ OH 3Br2 + 3Na2CO3 ¾¾¾¾¾¾¾¾¾ disproportionation reaction ® 5NaBr + NaBrO3 + 3CO2 390 3:0 3:0 The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is.744 .H2SO4 Me3C C CH3 O NaBH4 / Ethanol dil.0 O Hence. “SANKALP”. the difference in oxidation states of S atom = 5 0 = 5 The maximum number of electrons that can have principal quantum number. Cpu0*7+ +– Na O S S S S O Na O (+5) (0) 3.allen.2011) PAPER .04 .IIT-JEE 2011 EXAMINATION (HELD ON : 10 .0 3.ac. The number of sodium bromide molecules involved in the balanced chemical equation is. The bubble corresponding to the correct answer is to be darkened in the ORS. Fax : +91-744-2435003. of e = 1 n=3. INDRA VIHAR. and spin quantum number. is Cpu0*. of e having ms=1/2 1 3 5 +3+5 =9 7 / 28 A LL EN H3 C CH3 O O – + CH3 H3 C C= C CH3 H3 C O3/Zn 2 UGEVKQP"/"KX"*VQVCN"OCTMU"<"4:+ Corporate Office : ALLEN CAREER INSTITUTE.acid C CH CH3 CH3 OH H3 C H3 C C CH CH 3 CH3 + + 1.

Fax : +91-744-2435003. 0. 796) on complete hydrolysis gives glycine (Mol. Glycine contributes 47. KOTA-324005 PHONE : +91 . 450 wt. The number of glycine units present in the decapeptide is Cpu0*8+ No. of units of glycine = = 6 units 75 To an evacuated vessel with movable piston under external pressure of 1 atm.0% to the total weight of the hydrolysed products.in .1 mol of He and 1.1 × (R × 273) Þ V = 7 litre.32 atm 0. number of molecules of H2O added = 9 So total wt. 75). the total volume (in litre) of the gases at 0°C is close to P =1atm Cpu0*9+ Since external pressure is 1 atm PV + PHe = 1 Þ PHe = 1 0.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .32 × V = 0.744 .ac. of the product = Mol. CP-6. of glycine obtained = 958 × 100 450 No.. “SANKALP”.1 mol He Now from idal gas equation Þ PV = nRT PV=0.68 atm.68 atm 1 mol X(s) Þ 0. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is Cpu0*7+ Br 420 430 430 440 440 CCCCCC alcoholic KOH A LL EN CCCCCC + 1 product \ CC=CCCC + 2 products (Geometrical isomers) CCC=CCC 2 products (Geometrical isomers) 8 / 28 Corporate Office : ALLEN CAREER INSTITUTE. Wt.1 420 A decapeptide (Mol. INDRA VIHAR. wt. E-mail: info@allen.allen. of H2O added. of polypeptide + total wt.68 = 0. Considering the ideal gas behaviour.2436001.0 mol of an unknown compound (vapour pressure 0.ac. = 796 + (9 × 16) = 796 + 162 = 958 47 . =n1 So.04 . of peptide linkage = No.in Website: www.2011) PAPER . at 0°C) are introduced. alanine and phenylalanine. Wt. of water molecules added for complete hydrolysis.

KOTA-324005 PHONE : +91 .ac. Total no. “SANKALP”.allen. of metals that show photoelectric effect will be 4.2011) PAPER .4 2.in Website: www.3 4.744 . Fax : +91-744-2435003.ac.13 eV To show photoelectric effect E ³ f. The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metal is : :Metal Li Na K Mg Cu Ag Fe Pt W f(eV) 2.2 3.3 4.in 9 / 28 .75 450 Cpu0*6+ l = 300 nm 1240 E = l in nm eV = 1240 eV 300 = 4.2436001.1 450 The work function (f) of some metals is listed below.04 . A LL EN Corporate Office : ALLEN CAREER INSTITUTE. INDRA VIHAR.3 2.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .7 4.7 6. E-mail: info@allen. CP-6.8 4.

5jgrcp.2436001. a 0 &B' E .allen.4 / = 00.. KOTA-324005 PHONE : +91 .mdkmjcq.04 ._ 0 r z (a.1 RCTV"/" KK"*RJ[UKEU+ UGEVKQPK"<"*Vqvcn"Octmu"<"43+ *Ukping"Eqttgev"Cpuygt"V{rg+ Rfgqqcargmlamlr_glq9"ownvkrng"ejqkeg"swguvkqpu.R0&.5'0-1Þ R/&6'0-1.kw0J 102. RT/ cvrcpl_j g -/ 2´0 6 6 ?`_jjmdk_qq&k'. 470 A LL EN /R ( 1T/ ) ´ 1 ..Rfck_vgksknmqqg`jct_jscmd_lesj_p tcjmagrwmd`_jj&glp_bg_l-q'gq &?'7 &@'/6 &A'05 &B'14 Cpu0 *F+ Rqglq. CP-6.dS .kw Jqglq q Tcosq T R.amlqr_lrÞR/&3. a0 0 x (0.C_afoscqrgmlf_qdmspafmgacq&?'*&@'*&A'_lb &B'* msr mdufgaf QPN[" QPG gq amppcar.Rfck_vgksk rclqgmlrf_rrfcqrpglea_l`c_pgq102L. mg Amlqgbcp_lcjcarpgadgcjb E = E0 x ˆ *ufcpcC.a.CÕ_0 Corporate Office : ALLEN CAREER INSTITUTE.. Rfc`_jjgqpmr_rcbml_fmpgxmlr_jagpasj_pn_rf_`msrtcprga_j_vgq. E-mail: info@allen.ac.3k.4'0-1..Rfcdjsvrfpmsef rfcqf_bcb_pc_&_qqfmulglrfcdgespc'bscrmrfgqdgcjbgq &?'0C. n = 1 &@' RT/ 0 3.4jgrcpmdfcjgske_q_rQRNgq_bg_`_rga_jjwamknpcqqcbrm.14 48._0 &A'C.R_iglerfcglgrg_jrckncp_rspcrm`c R/*rfcumpibmlcglrfcnpmacqqgq 7 &?' RT/ 6 Cpu0 *C+ Lm.RfcpcdmpcU .gq_amlqr_lr.RT/ .2 2 &A' /3 RT 6 / 7 &B' RT/ 0 RTg/.R0Þ 2R/.2011) PAPER .744 .in Website: www.0. INDRA VIHAR.3iegq_rr_afcbrmrfcclbmd_qrpglef_tglejclerf&J'.R0 U.0.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .a.ac. “SANKALP”. 460 3.a) &@' 0 E. \\\\\\\\\\\\\\ J k / ( 0)/ w 0 0 Tsin q Rfcpcdmpcw .0) y Cpu0 *E+ uur f = ò E .a)) (a.kw0p \\\\\\\\\\\\\\ 0 Rqglq. Fax : +91-744-2435003.in 10 / 28 .nRDT 7 7 == .Cvnpmhcarcb_pc_ncpnclbgsaj_prmC&v+_vgq'.0) (0.

x ++++++ ----- x 2m F 8m F æ 0V ö 0 0V .Rfcclb+amppcargmlq _pc/ak_lb0akpcqncargtcjwdmprfcclbq?_lb@..- ? @ &B'//. + /.2011) PAPER ..03iFx &A'5. /. Þ #jmqq./mfk 4.0T* Þ Vi = ´ ( 0) V = V 9 U = æ + = ç ÷ f 0 0 6 3 è 3ø 0´0 3 2V 0 ´ /.iFx Cpu0 *C+ æ v ö æ v + v. Fax : +91-744-2435003.1 ?nmjgaca_pugrf_qgpclmddpcosclaw6iFxgqkmtgleugrfslgdmpktcjmagrw14ik-fprmu_pbq_r_jj `sgjbgleufgafpcdjcarqrfcqmslbu_tcq./.IIT-JEE 2011 EXAMINATION (HELD ON : 10 ..04 .3. 2V 0 Jmqq.Rfcdpcosclawmdrfc qgpclfc_pb`wrfca_pbpgtcpgq &?'6. 3 = 6.k-q.ac./. E-mail: info@allen. O/. 4:.# 3 V0 0 Corporate Office : ALLEN CAREER INSTITUTE.2436001. ø è 10.mfk pcqgqrmp.Rfcbcrcpkglcbt_jscmdVgq V 10W &?'/.Rfcncpaclr_ecmdgrq ?nnjwamlbgrgmlmdufc_rqrmlc`pgbec* qrmpcbclcpewbgqqgn_rcb_drcprfcqugrafQgqrsplcbrmnmqgrgml0gq &?'.4W Þ x = 30 + / 26 + 0 3.Rfcqnccbmdqmslbgl_gpgq10.53iFx &B'5. ?kcrcp`pgbecgqqcr+sn_qqfmul*rmbcrcpkglc_lslilmulpcqgqr_lacVsqgle_qr_lb_pb/. x /.x x 6V / 0 0 è 3 ÷ ø 6V ö ç 2V 0 = * x = O/.6mfk &@'0.. ?0mDa_n_agrmpgqaf_pecb_qqfmulgldgespc..# / 0 q T 0m D 6m D &A'53# Cpu0 *F+ V 2m F 8m F V ++++++ ----- 2V.# &B'6.Rfce_jt_lmkcrcpqfmuqlsjjnmglrufclr_nngle+icwgq_r30akk_pi.-. = ´ 31 Þv. KOTA-324005 PHONE : +91 . “SANKALP”.0mfk Cpu0 *D+ A LL EN &@'/.# ++++++ Q . ö æ 10..3.3. INDRA VIHAR.iFx &@'6. ö f¢=ç f Þ f¢=æ ç ÷ ç ÷ç ÷ ´ 6 Þ f ¢ » 6. ö 10.in 11 / 28 .allen.iFx ÷ è ø è v v v è 10. CP-6.ac.AT.744 . ..4mfk &A'/. ø sø 49.in Website: www.

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“SANKALP”.in .Rfcl momentum E1 E2 2a a position &?' E1 = 2E2 14 / 28 &@'C/.ac. Rctcitcrj"hqt"Swguvkqpu"Pqu0"57"vq"59 Nf_qcqn_acbg_ep_kq_pcsqcdsjrmmjqgl_l_jwxgle_jjiglbqmdbwl_kga_jnpm`jckq.n&r'asptcglrfgqnj_lc. Fax : +91-744-2435003. CP-6.Dmpqsafqwqrckq*nf_qcqn_acgq_nj_lcglufgaf nmqgrgmlgqnjmrrcb_jmlefmpgxmlr_j_vgq_lbkmkclrskgqnjmrrcb_jmletcprga_j_vgq.04 .2C0 &B'C/.Rfcnf_qcqn_ac bg_ep_kgqv&r'tq.Ucsqcrfcqgelamltclrgmlglufgafnmqgrgmlmpkmkclrsksnu_pbq&mprmpgefr'gqnmqgrgtc_lb bmulu_pbq&mprmjcdr'gqlce_rgtc. KOTA-324005 PHONE : +91 .Rfcw_pccqncag_jjw sqcdsjglqrsbwglerfcaf_lecqglkmrgml_qglgrg_jnmqgrgml_lbkmkclrsk_pcaf_lecb. Rfcnf_qcqn_acbg_ep_kdmpqgknjcf_pkmlgakmrgmlgq_agpajcaclrcpcb_rrfcmpgegl.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .2436001. INDRA VIHAR.Fcpcucamlqgbcp qmkcqgknjcbwl_kga_jqwqrckqglmlc+bgkclqgml.Glrfcdgespc*rfc rumagpajcqpcnpcqclrrfcq_kcmqagjj_rmp`srdmpbgddcpclrglgrg_jamlbgrgmlq*_lbC/_lbC0_pcrfcrmr_j kcaf_lga_jclcpegcqpcqncargtcjw.allen. 570 Rfcnf_qcqn_acbg_ep_kdmp_`_jjrfpmultcprga_jjwsndpmkepmslbgq Momentum Momentum A LL EN Position Momentum Momentum Momentum &?' position &@' position &A' position &B' position Cpu0 *F+ Glgrg_jkmkclrsku_qnmqgrgtc_lbdgl_jkmkclrsklce_rgtc.Qmmnrgml&B'gqamppcar.Dmpcv_knjc* rfcnf_qcqn_acbg_ep_kdmp_n_prgajckmtgleugrfamlqr_lrtcjmagrwgq_qrp_gefrjglc_qqfmulglrfc dgespc.744 ./4C0 Corporate Office : ALLEN CAREER INSTITUTE. E-mail: info@allen.1 UGEVKQPKKK" <" *Vqvcn" Octmu" <" 37+ *Rctcitcrj" V{rg+ Rfgqqcargmlamlr_glq4"rctcitcrju.2011) PAPER .ac.Rfc_ppmumlrfcasptcglbga_rcqrfcrgkcdjmu.@_qcbsnmlmlcmdrfcn_p_ep_nf* 5"ownvkrng"ejqkeg"swguvkqpu _lb`_qcbmlrfcmrfcpn_p_ep_nf 4"ownvkrng"ejqkeg"swguvkqpuf_tcrm`c_lqucpcb.0C0 &A'C/. 58.C_afmdrfcqc oscqrgmlqf_qdmspafmgacq&?'* &@'* &A'_lb &B'*msr md ufgaf QPN["QPGgqamppcar.in Website: www.

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" cpf"W4"eqpvckpu"qpn{"3 yjkvg"dcnn0"C"hckt"eqkp" ku"vquugf0"Kh"jgcf"crrgctu"vjgp"3"dcnn"ku"ftcyp"cv"tcpfqo"htqo"W3"cpf"rwv kpvq"W40"Jqygxgt. d "? "8 " " "( e "? "9 4 z " . "ab" ? "9 Jgpeg" *C+" 840 35 45 3. CP-6. 33 *D+" *E+" *F+" 52 52 52 52 Ikxgp" vjcv" vjg" ftcyp" dcnn" htqo" W4" ku" yjkvg.in Website: www. E-mail: info@allen.allen.744 . KOTA-324005 PHONE : +91 . “SANKALP”.1 820 5 3 5 3 1 3 + d + e ? 2 + 12 + -14 " ? "5w-3-5w4 c w w w w w w ?" 5" -" 3" ?" 4 Cpu0" *D+ Q d "? "8 Þ 8M "? "8 Þ M "? "3 Þ c" ?" 3. Fax : +91-744-2435003. INDRA VIHAR.6 p =0 è ø 7 Uqn0 " " Rctcitcrj" hqt" Swguvkqp" 83" cpf" 84 Ngv"W3"cpf"W4"dg"vyq"wtpu"uwej"vjcv"W3"eqpvckpu"5"yjkvg"cpf"4"tgf"dcnnu.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER ." vjg" rtqdcdknkv{" vjcv" jgcf" crrgctgf" qp" vjg" eqkp" ku" / A LL EN 39 45 ¥ æ a +b ö 1 æ6ö =7 å ç ab ÷ = å ç 7 ÷ = Þ p =0 è ø 1."8z " "9 " "? "2 Þ a" -" b" ? "8 ".ac.2436001.ac." kh"vckn"crrgctu"vjgp"4"dcnnu"ctg"ftcyp"cv"tcpfqo" htqo"W3"cpf"rwv"kpvq"W40"Pqy 3" dcnn" ku" ftcyp" cv" tcpfqo" htqo" W40 830 Vjg" rtqdcdknkv{" qh" vjg" ftcyp" dcnn" htqo" W4" dgkpi" yjkvg" ku" / ¥ n n *C+" *D+" 33 37 *E+" 45 45 Rctcitcrj" hqt" Swguvkqp" 83" cpf" 84 *F+" 34 45 1/2 d a He Start 1 Ta /2 il U1 3W 2R 1 ball U2 1W U2 U1 3W 2R 2 balls 1W 830 Cpu0" *D+ Tgswktgf"rtqdcdknkv{ 4 4 3æ 5 4 3 ö 3 æ 5E E 3 5E E 4 ö ? ç 03 + 0 ÷ + ç 7 4 03 + 7 4 0 + 7 3 3 0 ÷ 4è 7 7 4 ø 4 è E4 E4 5 E4 5 ø 840 3 æ 6 ö 3 æ 5 3 4 ö 4 33 45 = ç ÷+ ç + + ÷ = + 4 è 7 ø 4 è 32 52 7 ø 7 52 52 Cpu0" *F+ Tgswktgf"rtqdcdknkv{ = ? 417 " *wukpi" Dc{g)u" vjgqtgo+ 4 1 7 + 331 52 34 45 Corporate Office : ALLEN CAREER INSTITUTE.in ?" 25 / 28 .

E-mail: info@allen.ac.1)d] 2 Sm 5[(2a 1 .0"Vjg"dwddng"eqttgurqpfkpi"vq"vjg"eqttgev"cpuygt"ku"vq"dg"fctmgpgf"kp"vjg"QTU0 850 Ngv"c3.–4) .2) 2 3 5 """" ? " 0:0 = 8 4 4 D4" ?" *Wukpi" rtqrgtv{" <" Ctgc" qh" vtkcping" hqtogf" d{" vcpigpvu" ku"cnyc{u"jcnh" qh" qtkikpcn" vtkcping+ 26 / 28 Corporate Office : ALLEN CAREER INSTITUTE. CP-6." cpf" D4" dg" vjg" ctgc" qh" vjg" vtkcping" hqtogf" d{ è4 ø D3 ftcykpi" vcpigpvu" cv" R" cpf" cv" vjg" gpf" rqkpvu" qh" vjg" ncvwu" tgevwo0" Vjgp" D " ku 4 (2.in Website: www."c322 ®"CR Uo " vq" dg" kpfgrgpfgpv" qh" p Up P Þa=2 3 " *D3+ 4 A' (2.4) Uqn0 Cpu0 "4 A D3" ?"ctgc" qh" D" RCC) y = 8x (1/2.d) + 5nd] = Sn [(2a1 .c4.744 .allen. "qt "5 *Eqoogpv"<"Vjg"kphqtocvkqp"cdqwv"vjg"eqooqp"fkhhgtgpeg"k0g0"|gtq"qt"pqp/|gtq"ku"pqv"ikxgp"kp vjg" swguvkqp0" Jgpeg" vjgtg" ctg" vyq" rquukdng" cpuygtu+ Eqpukfgt" f" ¹" 2" vjg" uqnwvkqp" ku c3.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER ."c4. 4 ÷ qp" vjg"rctcdqnc.1 UGEVKQPKX"<"*Vqvcn"Octmu"<"4:+ *Kpvgigt"Cpuygt"V{rg+ Vjku"Ugevkqp"eqpvckpu""9"swguvkqpu0"Vjg"cpuygt"vq"gcej"qh"vjg"swguvkqp"ku"c"ukping"fkikv"kpvgigt.""tcpikpi htqo"2"vq". Fax : +91-744-2435003. INDRA VIHAR.ac."ngv"o"?"7p0"Kh" U "fqgu"pqv"fgrgpf"qp"p.d) + nd] hqt" 860 \" 4c3" "f "? "2 " " Þ " f" ?" 4c3" Þ f" ?" 8" Þ " c4" ? "."vjgp"c4"ku p c3" ? "5 " "= " " "Ur" ? å a i """ 3" £" p" £" 42 i =1 o" ?" 7p m [2a1 + (m .in A LL EN p Uqn0 Cpu0 ".2436001.1)d] Sm = 2 n Sn [2a1 + (n .3 £ r £ 322 0"Hqt"cp{ k =3 r Uo kpvgigt"p"ykvj"3">"p">"42.c322"dg"cp"ctkvjogvke"rtqitguukqp"ykvj"c3"?"5"cpf" Ur = å c k .c5. KOTA-324005 PHONE : +91 ."c5."000000000000. Kh " "f "? "2 " " " " Þ c4" ? "c3" ? "5 Eqpukfgt" vjg" rctcdqnc" {4" ?" :z0" Ngv" D3" dg" vjg" ctgc"qh" vjg" vtkcping"hqtogf" d{" vjg" gpf" rqkpvu" qh" kvu æ3 ö ncvwu"tgevwo" cpf"vjg" rqkpv" R ç .000000000. “SANKALP”.

00000000 4 6 8 Þ Þ p" ?" 9 4o + 3 Þ p" ?" 9.ac. “SANKALP”. " yjgtg" .. E-mail: info@allen. CP-6. INDRA VIHAR.2436001. 0000000 9 9 5 7 æ -3 æ ukp q ö ö p p f * *q++ " ku Ngv" *q+ = ukp ç vcp ç ÷ ÷ .sin 2cos sin n n = 1 n n = 1 Þ" Þ p 3p 2p p 3p 2p sin sin sin sin sin sin n n n n n n sin Þ p= 3 4o 3 3 3 Þ p" ?" .744 ." vjgp" vjg" okpkowo" xcnwg" qh" ~4|" " 8" -" 7k~ ku Corporate Office : ALLEN CAREER INSTITUTE.in 27 / 28 . .ac. .allen. Fax : +91-744-2435003."3 9p = *4o + 3+ p p Rquukdng" xcnwg" qh" p" ku" 9 A LL EN 2p 2p 3p sin = sin n n n 4p 3p 4p 3p = sin Þ = Kp + ( -1) K n n n n p = 4op p 3p p 2p p .in Website: www.6 < q < 6 0" Vjgp" vjg" xcnwg"qh" f*vcp q+ è equ4q ø ø è Uqn0 Cpu0 "3 880 ukp q ö -3 æ Ngv" * q+ = ukp a " yjgtg" a = vcp ç ÷ è equ 4q ø Þ Þ Þ Þ 890 vcp a = ukp a = ukp q equ 4q ukp q = vcp q equ q æ æ p p öö çQ q Î ç . KOTA-324005 PHONE : +91 .IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER . ÷ ÷ è 6 6 øø è * q+ = vcp q f* *q++ =3 f*vcp q+ Kh" |" ku" cp{" eqorngz" pwodgt" ucvkuh{kpi" ~|" " 5" " 4k~" >" 4.1 Þ 870 D3 =4 D4 Vjg" rqukvkxg" kpvgigt" xcnwg" qh" p" @" 5" ucvkuh{kpi" vjg" gswcvkqp 3 3 3 = + ku æpö æ 4p ö æ 5p ö ukp ç ÷ ukp ç ÷ ukp ç ÷ èpø è p ø è p ø Uqn0 Cpu0 "9 1 sin p n = 1 1 + 2p 3p sin sin n n Þ"" 1 sin p n - 1 1 = 3p 2p sin sin n n Þ 2cos Þ sin Kh " "M "? "4o Þ Kh " "M "? "4o ".

" vjgp" vjg" xcnwg" qh" *4+" ku Uqn0 Cpu0 "8 *Eqoogpv"<"Vjg"ikxgp"tgncvkqp"fqgu"pqv"jqnf"hqt"z"?3. "c6.ç 5 .0) ç 5."c:" ."4 "? "8 28 / 28 A LL EN Þ" zf{ . " z ³ 3 3 z Pqy" crrn{kpi" Pgyvqp" Ngkdpkv|" vjgqtgo 8 *z+" ?" 5z )*z+" " 5z4" -" 5 *z+ Þ 5 *z+" ?" 5z )*z+" " 5z4 Ngv" {" ?" *z+ Þ Þ z f{ . .2436001. CP-6. E-mail: info@allen.744 .ac.2) ?" 4" Ù" *okpkowo" fkuvcpeg" dgvyggp" |" cpf" rqkpv" ç 5.2+" cpf" æ (3.ac. “SANKALP”."vjgtghqtg"kv"ku"pqv"cp"kfgpvkv{0"Jgpeg"vjgtg ku" cp" gttqt" kp" ikxgp" swguvkqp0" Vjg" eqttgev" kfgpvkv{" owuv" dg/+ 8 ò h*v+fv ? 5zh*z+ z 5 7.–5/2) 7 ?" 4" Ù" " ?" 7" wpkvu0 4 8:0 Vjg" okpkowo" xcnwg" qh" vjg" uwo" qh" tgcn" pwodgtu" c7.¥+" ®" ]4. . KOTA-324005 PHONE : +91 . INDRA VIHAR.z 5 3 z hqt" cnn" z" @" 3.÷ + 4ø è (3."c32" .{fz = fz z4 7ö æ (3.÷ + 4 è ø 7ö ?" 4" Ù" *fkuvcpeg" dgvyggp" *5.¥+" dg" c" fkhhgtgpvkcdng" hwpevkqp" uwej" vjcv" h*3+" ?" 40" Kh" 8 ò *v+fv = 5z *z+ .in ."5c5" .in Website: www." c:" cpf" c32" ykvj "c "@ "2 "ku Uqn0 Cpu0 ": Cu c "@ "2 cpf" cnn" vjg" ikxgp" vgtou" ctg" rqukvkxg jgpeg" eqpukfgtkpi" C0O0" @" I0O0" hqt" ikxgp" pwodgtu" < |z–3–2i| < 2 Re Þ ÷ = ò fz ò fç èzø æ {ö Corporate Office : ALLEN CAREER INSTITUTE." 3."c6" ."3+okp" ? ": " " " "yjgp "c "? "3 Þ 8. Fax : +91-744-2435003.{ = z4 fz { = z+E *yjgtg" E" ku" eqpuvcpv+ z Þ { "? "z4" -" Ez \ *z+"?" z4" .0 Ngv" " <" ]3.k ÷ 4 ø è 3 c -7 + c -6 + c -5 + c -5 + c -5 + c : + c32 -7 -6 -5 -5 -5 : 32 9 ³ ( c 0c 0c 0c 0c 0c 0c ) 9 c -7 + c -6 + c -5 + c -5 + c -5 + c : + c32 -7 -6 -5 : 32 ³3 Þ ( c + c + 5c + c + c ) okp ? "9 9 yjgtg" c7" ? "c6" ? "c5" ? "c:" ? "c32" k0g0 "c "? "3 Þ *c7" .allen.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER ."Ez Ikxgp" *3+" ?" 4 Þ E "? "3 \ *4+"?" 44" ." 5c5.1 Im Uqn0 Cpu0 "7 7 ö æ Yg"jcxg" vq" hkpf"okpkowo" xcnwg" qh" 4 | .

744 .IIT-JEE 2011 EXAMINATION (HELD ON : 10 .in Website: www. KOTA-324005 PHONE : +91 . INDRA VIHAR.2436001.GGG mvgb_rgmlQr_rcmdDc. E-mail: info@allen. “SANKALP”.Dc0M1' Rfcdmjjmuglea_p`mfwbp_rcgq F FM FM &?' _icrmfcvmqc &A'_l a+dsp_lmqc 40 Cpu0"*D+ F FM FM &?jbmfcvmqc' 50 Rfck_hmpnpmbsarmdrfcdmjjmuglepc_argmlgq PAF0MF F (_lfwbpmsq) Å &?'_fckg_acr_j &A'_lcrfcp 50 Cpu0*D+ A LL EN MF F M MF F F MF F mvgb_rgmlQr_rcmdDc. 30 Mvgb_rgmlqr_rcqmdrfckcr_jglrfckglcp_jqf_ck_rgrc_lbk_elcrgrc*pcqncargtcjw*_pc &?'GG*GGGglf_ck_rgrc_lbGGGglk_elcrgrc &@'GG*GGGglf_ck_rgrc_lbGGglk_elcrgrc &A'GGglf_ck_rgrc_lbGG*GGGglk_elcrgrc &B'GGGglf_ck_rgrc_lbGG*GGGglk_elcrgrc 30 Cpu0"*F+ F_ck_rgrcDc0M1 40 K_elcrgrcDc1M2&DcM. Fax : +91-744-2435003.2 RCTV" /" K" *EJGOKUVT[+ UGEVKQPK"<"*Vqvcn"Octmu"<"46+ *Ukping"Eqttgev"Cpuygt"V{rg+ Rfgqqcargmlamlr_glq:"ownvkrng"ejqkeg"swguvkqpu.2011) PAPER . CP-6.GG*GGG &@'_l_jbmfcvmqc &B'_l a+nwp_lmqc MF F M MF F F MF F b-pyranose M &@'_l_acr_j &B'_lcqrcp Corporate Office : ALLEN CAREER INSTITUTE.C_afoscqrgmlf_qdmspafmgacq&?'*&@'*&A'_lb &B'* msr mdufgaf QPN[" QPG gq amppcar.04 .ac.ac.allen.in 1 / 29 .

“SANKALP”.0®A 2 / 29 Corporate Office : ALLEN CAREER INSTITUTE.1 Õ /..kÕIdÕg .0 &A' 3. Fax : +91-744-2435003.1Õ/./emdI1YDc&AL'4[&Kmj..0 Rd./. E-mail: info@allen.in .0 &@' 3./.04 .0 Õ /.Ur.0.2 R–CH2OH O O O (An acetal) CH2–R + HÅ O 60 R–CH2OH •• •• O Å O O–CH2R H Å H+ O O–CH2R ?kmleqrrfcamknmslbqegtcl*rfcmlcrf_rumsjbdmpk_`pgjjg_lramjmspcbbwcmlrpc_rkclrugrf L_LM0glbgj..107'gl/..ac..e mdu_rcp &Id . .0 Cpu0"*C+ DRd. ´ /.64 ´ 2 /.5 Õ /.DRd.2436001.FAjdmjjmucb`w_bbgrgmlrm_l_ji_jglcqmjsrgmlmdb+l_nfrfmjgq+ &?' A LL EN &@' &A' H3C N(CH3)2 NHCH3 NH2 &B' CH2NH2 60 Cpu0"*E+ OH H3 C NH2 HCl + NaNO2 Me N2Cl– + alkaline N=N OH Me 70 Orange coloured dye Rfcdpccxglenmglr&gl®A'md_qmjsrgmlamlr_glgle.64Iiekmj/' gq + &?' 0.5 Õ /.. CP-6.in Website: www.004/ ...IIT-JEE 2011 EXAMINATION (HELD ON : 10 . 70 .allen..0. KOTA-324005 PHONE : +91 .1 &B' /..744 . INDRA VIHAR.2011) PAPER .1Õ/.ac.107 ´ /.

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**?rYDc [;/. K* N&M0';.,/_rk_lbnF;1*rfc acjjnmrclrg_j _r03®Agq+ &?' /,25 T 80 Cpu0"*F+ 0Dc&q')M0&e')2F)&_o'¾® 0Dc0)&_o,')0F0M&l'
**

.,.4 YDc +0 [ C;C® jme l NM ,YF + [2

0

&@' /,55 T

.,.4 &/. -1 ' 0 jme ;/,45 2 .,/ ´ &/. -1 ' 2

C;/,45 ;/,45

;/,45.,/.3 ;/,343T |/,35T 90

N_qqgleF0Qe_qglrm_kgvrspcmdKl0)*Lg0)*As0)_lbFe0)gmlqgl_l_agbgdgcb_oscmsqqmjsrgml npcagngr_rcq &?' AsQ _lb FeQ &A' KlQ _lb LgQ &@' KlQ _lb AsQ &B' LgQ _lb FeQ

90

Cpu0"*C+

AsQ_lbFeQugjj`cnpcagngr_rcbufclF0Qgln_qqcbrfpmsef_oscmsqqmjsrgmlamlr_glgleKl0)*Lg0)* As0)_lbFe0)gmlqgl_agbgakcbgsk, :0 ?kmlerfcdmjjmugleamknjcvcq&MR' I1YDc&AL'4[ *M+*YAm&LF1'4[Aj1 *N+*L_1YAm&mv_j_rc'1[ *O+*YLg&F0M'4[Aj0 *P+. I0YNr&AL'2[ *Q+" _lb" YXl&F0M'4[&LM1'0 *R+ Rfcbg_k_elcrgaamknjcv_pc+ &?' I* J* K* L &A' J* K* M* N :0 Cpu0"*E+ Bg_k_lcrgaamknjcvcq_pc *N+""YAm&LF1'4[Aj1= *O+"L_1YAm&mv_j_rc'1[ *Q+"I0YNr&AL'2[= *R+""YXl&F0M'4[&LM1'0 &@' I* K* M* N &B' J* K* L* M

A LL EN

.,.4 jme/. 5 2 .,.4 ´5 2

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3 / 29

**IIT-JEE 2011 EXAMINATION
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PAPER - 2

UGEVKQPKK"<"*Vqvcn"Octmu"<"38+ *Ownvkrng"Eqttgev"Cpuygt"V{rg+ Rfgqqcargmlamlr_glq6"ownvkrng"ejqkeg"swguvkqpu,C_afoscqrgmlf_qdmspafmgacq&?'*&@'*&A'_lb &B' msrmd ufgaf QPG"qt"OQTG k_w `c amppcar, ;0 Pcbsargmlmdrfckcr_jaclrpcgl_oscmsqncpk_le_l_rcgmlgltmjtcq+ &?'1cjcarpmlqgllcsrp_jkcbgsk &A'1cjcarpmlqgl_ji_jglckcbgsk ;0 Cpu0"*C.E.F+ &@'3cjcarpmlqgllcsrp_jkcbgsk &B'3cjcarpmlqgl_agbgakcbgsk

MnO4–

7+

acidic strong alkaline

Mn2+ Mn6+

320

Dmprfcdgpqrmpbcppc_argml

&?'rfcamlaclrp_rgmlmdrfcpc_ar_lrbcapc_qcqcvnmlclrg_jjwugrfrgkc &@'rfcf_jd+jgdcmdrfcpc_argmlbcapc_qcqugrfglapc_qglerckncp_rspc, &A'rfcf_jd+jgdcmdrfcpc_argmlbcnclbqmlrfcglgrg_jamlaclrp_rgmlmdrfcpc_ar_lr, &B'rfcpc_argmlnpmaccbqrm77,4#amknjcrgmlglcgefrf_jd+jgdcbsp_rgml, 320 Cpu0"*C.D.F+ ?r ;?. cir

dmpmnrgml&B'

r 77,4 jl 03. = = 5,743 ; 6 r/- 0 jl 0

330

Rfccosgjg`pgsk

gl_oscmsqkcbgsk_r03®Aqfgdrqrmu_pbqrfcjcdrgl rfcnpcqclacmd &?' LM1 &@' Aj &A' QAL &B' AL

4 / 29

A LL EN

Faintly alkaline Mn4+ or neutral

0L0M3&e' ¾® 2LM0&e')M0&e'

/

r/- 0

jl

/.. / /.. = jl 3. r 77,4# .,2

Asm ) AsGG 0AsG

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PAPER - 2

330

Cpu0"*D.E.F+

** Asm)AsGG Rfccol,0AsG
**

qfgdrqrmu_pbqjcdrglrfcnpcqclacmdAj*QAL*_lbALbscrmdmpk_rgmlmdAsAj&nnr', YAs&QAL'2[1_lbYAs&AL'2[1gmlqpcqncargtcjw, 340 Rfcamppcardslargml_jepmsnV_lbrfcpc_eclr-pc_argmlamlbgrgmlqWglrfcdmjjmugleqafckc_pc V&AF0'2V

(i) Y (ii) O O

amlbclq_rgmlnmjwkcp

**A&AF0' 2 A OH FM &?' V ; AMMAF1* W ; F0-Lg-fc_r
**

&A' V ; AMLF0* W ; @p0-L_MF &B' V ; AL* W ; F0-Lg-fc_r 34 Cpu0*C.D.E.F+

(i) y

X–(CH2)4–X

A LL EN

(ii) HOOC–(CH2)4–COOH polymer

H2/Ni D

&@' V ; AMLF0* W ; F0-Lg-fc_r

Condensation

H3COOC–(CH2)4–COOCH3 H2NOC–(CH2)4–CONH2 H2NOC–(CH2)4–CONH2

HO–(CH2)6–OH Hexane-1,6-diol

HOOC–(CH2)4–COOH D HOOC–(CH2)4–COOH D HOOC–(CH2)4–COOH D

Condensation polyester Condensation polyamide Condensation polyamide Condensation polyamide

H2/Ni D

H2N–(CH2)6–NH2 Hexamethylene diamine H2N–(CH2)4–NH2 Tetramethylene diamine

Br2/NaOH

NC–(CH2)4–CN

H2/Ni D

H2N–(CH2)6–NH2 Hexamethylene diamine

HOOC–(CH2)4–COOH D

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5 / 29

**IIT-JEE 2011 EXAMINATION
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PAPER - 2

UGEVKQPKKK"<"*Vqvcn"Octmu"<"46+ *Kpvgigt"Cpuygt"V{rg+ RfgqQcargmlamlr_glq"8"swguvkqpu,Rfc_lqucprmc_afmdrfcoscqrgmlqgq_ukping/fkikv"kpvgigt."p_legle dpmk.rm7,Rfc`s``jcamppcqnmlbglermrfcamppcar_lqucpgqrm`cb_piclcbglrfcMPQ, 350 Gl / J q_rsp_rcb qmjsrgml md ?eAj YIqn&?eAj' ; /,4 Õ /./.[* .,/ kmj md AsAj YI qn&AsAj' ; /,. Õ /. 4[ gq _bbcb, Rfc pcqsjr_lr amlaclrp_rgml md ?e ) gl rfc qmjsrgml gq /,4Õ/.v,Rfct_jscmdvgq, 350 Cpu0*9+ ?e) ) Aj ?eAj _ _ ) ` As) ) Aj AsAj

I qn &?eAj' I qn &AsAj'

` &` ) _' ;

Qglac _::: ` Q `0 ; /.4 Þ ` ; /.1 _lb _ Õ ` ; /,4 Õ /./. _ ; /,4 Õ /.5 ; /,4 Õ /.v 360

qm v ; 5 Rfck_vgksklsk`cpmdgqmkcpq&glajsbgleqrcpcmgqmkcpq'rf_r_pcnmqqg`jcmlkmlm+afjmpgl_rgmlmdrfc dmjjmugleamknmslbq*gq

CH3CH2

360 Cpu0*:+

AF1AF0AFAF0AF1 AF1

6 / 29

A LL EN

+ /. _&_ + `' _ Y?e [ /,4 ´ /. ; ; ; ; /,4Õ /.2 + 4 ` /. YAs [ `&` + _'

CH3

C

H

CH2CH3

kmlmafjmpgl_rgmlAj0 fn

AF1

AF1AF0AFAF0AF0Aj &0gqmkcpq' ( )

Aj ( AF 1AF 0AFAFAF 1 &2gqmkcpq' ( AF1 ) Aj

AF1AF0AAF0AF1 )

AF1 AF0Aj AF1

Corporate Office : ALLEN CAREER INSTITUTE, “SANKALP”, CP-6, INDRA VIHAR, KOTA-324005 PHONE : +91 - 744 - 2436001, Fax : +91-744-2435003, E-mail: info@allen.ac.in Website: www.allen.ac.in

AF1AF0AAF 0AF1

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PAPER - 2

370

?kmlerfcdmjjmugle*rfclsk`cpmd amknmslbqrf_ra_lpc_arugrfNAj3rmegtcNMAj1 gq M0* AM0* QM0* F0M* F0QM2 * N2M/.

370 Cpu0"*6+ QM0*F0M*F0QM2*N2M/. NAj3)F0M ¾®NMAj1)0FAj 4NAj3)N2M/. ¾®/.NMAj1 F0QM2)0NAj3 ¾®0NMAj1)QM0Aj0)0FAj QM0)NAj3 ¾®NMAj1)QMAj0

380 380 Rfclsk`cp mdfcv_eml_jd_acqrf_rnpcqclrgl_rpsla_rcbmar_fcbpmlgq, Cpu0"*:+

Gl_rpsla_rcbmar_fcbpml*rfcpc_pc/2d_acq&6pcesj_pfcv_eml_j_lb4qos_pc'*14cbecq_lb02 tcprgacq, 390 Rfctmjskc&glkJ'md.,/K?eLM1pcosgpcbdmpamknjcrcnpcagngr_rgmlmdafjmpgbcgmlqnpcqclrgl 1.kJmd.,./KqmjsrgmlmdYAp&F0M'3Aj[Aj0*_qqgjtcpafjmpgbcgqajmqcrm,

**390 Cpu0*8+ kgjjgkmjcq md ?eLM1 ; 0Õ kgjjgkmjcq md &Ap&F0M'3Aj'Aj0 .,/ Õ T ; 1. Õ 0 Õ .,./ ; .,4 T;4kJ
**

3:0 Rfcrmr_jlsk`cpmdamlrpg`srgleqrpsarspcqqfmuglefwncpamlhse_rgml&gltmjtgleAF`mlbq'dmprfc dmjjmuglea_p`ma_rgmlgq, H3C Å CH2CH3

3:0

**Cpu0"*8+ Rfcamlrpg`srglefwncpamlhse_rgleqrpsarspcq&gltmjtgleAF`mlbq'_pc;4
**

Corporate Office : ALLEN CAREER INSTITUTE, “SANKALP”, CP-6, INDRA VIHAR, KOTA-324005 PHONE : +91 - 744 - 2436001, Fax : +91-744-2435003, E-mail: info@allen.ac.in Website: www.allen.ac.in

A LL EN

Octahedron

Truncated octahedron

7 / 29

**IIT-JEE 2011 EXAMINATION
**

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PAPER - 2

Lm,mdaF;4

H H–C H C

+

H C – CH3 H H

UGEVKQPKX"<"*Vqvcn"Octmu"<"38+ *Ocvtkz/Ocvej"V{rg+ RfgqQcargmlamlr_glq"4"swguvkqpu,C_afoscqrgmlf_qhqwt"uvcvgogpvu"&?*@*A_lbB'egtclgl Eqnwop"K_lbdgtcqr_rckclrq&n*o*p*q_lbr'glEqnwop"KK,?lwegtclqr_rckclrglAmjsklGa_lf_tc amppcark_rafgleugrfQPGmpOQTG"qr_rckclr&q'egtclglAmjsklGG,Dmpcv_knjc*gddmp_egtcl oscqrgml*qr_rckclr@k_rafcqugrfrfcqr_rckclrqegtclglo_lbp*rfcldmprfcn_prgasj_poscqrgml*_e_glqr qr_rckclr@*b_piclrfc`s``jcqamppcqnmlbglermo_lbpglrfcMPQ, 3;0 K_rafrfcrp_lqdmpk_rgmlqgl Eqnwop/Kugrf_nnpmnpg_rcmnrgmlgl Eqnwop/KK Eqnwop/K Eqnwop/KK

&?' &@' &A' &B'

3;0

Cpu0"*C+®*r."t."u+"="*D+®*t."u+"="*E+®*v+"="*F+®*s."v+ AM0&q' ¾® AM0&e' nf_qcrp_lqgrgml DF < .* DQ < .

8 / 29

A LL EN

AM0&q' ® AM0&e' &n' A_AM1&e' ® A_M&q' ) AM0&e' &o' 0F} ® F0&e' &p' N&ufgrc* qmjgb' ® N&pcb*qmjgb' &q' &r'

DQgqnmqgrgtc

nf_qcrp_lqgrgml

_jjmrpmngaaf_lec

DFgqnmqgrgtc

DQgqlce_rgtc

**IIT-JEE 2011 EXAMINATION
**

(HELD ON : 10 - 04 - 2011)

PAPER - 2

420

**K_rafrfcpc_argmlqglEqnwop/Kugrf_nnpmnpg_rcrwncqmdqrcn-pc_argtcglrcpkcbg_rcgltmjtcbglrfcqc pc_argmlq_qegtclglEqnwop/KK Eqnwop/K H 3C O &?' O
**

aq NaOH ¾¾¾¾ ®

Eqnwop/KK

O

&n' Lsajcmnfgjgaqs`qrgrsrgml

O

O

CH 3MgI CH2CH2CH2Cl ¾¾¾ ¾ ®

&A'

A LL EN

O

18 O

H 2SO 4 ® CH2CH2CH2OH ¾¾¾

&@'

CH3

&o' Cjcarpmnfgjgaqs`qrgrsrgml

18

&p' Bcfwbp_rgml

&B'

CH2CH2CH2C(CH3)2 OH

H 2SO 4 ¾¾¾ ®

&q' Lsajcmnfgjga_bbgrgml

H3 C

CH3

&r' A_p`_lgml

420

Cpu0"*C+®*t.u.v+"="*D+®*r."u+"="*E+®*t."u+"="*F+®*s."t+

9 / 29

**IIT-JEE 2011 EXAMINATION
**

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PAPER - 2

RCTV"/KK"*RJ[UKEU+ UGEVKQPK"<"*Vqvcn"Octmu"<"46+ *Ukping"Eqttgev"Cpuygt"V{rg+ This section contains :"ownvkrng"ejqkeg"swguvkqpu. Each question has four choices (A), (B), (C) and (D), out of which QPN[" QPG is correct. 430 A light ray traveling in glass medium is incident on glass-air interface at an angle of incidence q. The reflected (R) and transmitted (T) intensities, both as function of q, are plotted. The correct sketch is

100% T Intensity

100% T Intensity R

(A)

(B)

R q 90%

A LL EN

0

0 q

100% Intensity

90%

100% Intensity

T

T

(C)

(D)

R

R

0

q

90%

0

q

90%

Cpu0 *E+ When q =0°, maximum light is transmitted. At q > qC (critical angle), no further light is transmitted 440 A wooden block performs SHM on a frictionless surface with frequency, n0. The block carries a charge r +Q on its surface. If now a uniform electric field E is switched-on as shown, then the SHM of the block will be

+Q

\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\

E

(A) of the same frequency and with shifted mean position (B) of the same frequency and with the same mean position (C) of changed frequency and with shifted mean position (D) of changed frequency and with the same mean position Cpu0"*C+ Time period of spring block system depends on spring constant and mass of block. On applying electric field only the equilibrium position gets shifted.

10 / 29

The reading on the main scale is 2. A bullet of mass 0. 100 ´ DP = æ + ç ÷ ´ 100 pr è P M r ø 3 M Dr = least count = 0. CP-6.72 0. The diameter of the ball is measured with a screw gauge.9% (B) 2.5 mm and there are 50 divisions on the circular scale. the relative percentage error in the density is (A) 0. The ball hits the ground at a distance of 20 m and the bullet at a distance of 100 m from the foot of the post. the ball and bullet travel independently.4% (C) 3. If the measured mass of the ball has a relative error of 2%.in Website: www.01 ö DP æ ´ 100 = 2% + ç 3 ´ ÷ ´ 100 = 3.2 u + 0.01 kg.2011) PAPER .2% Cpu0 *E+ P= DM 3Dr ö 4 3 .01 Þ r = 2.5 mm and that on the circular scale is 20 divisions. The initial velocity V of the bullet is (B) 250 2 m/s (C) 400 m/s (D) 500 m/s Cpu0 *F+ 0.2436001.ac. whose pitch is 0. hits the centre of the ball.04 . “SANKALP”.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .2 450 The density of a solid ball is to be determined in an experiment.in 11 / 29 . Range for ball = u × t Þ 20 = u × 1 Þ u = 20 m/s Þ V = 500 m/s 470 Which of the field patterns given below is valid for electric field as well as for magnetic field? (A) (B) (C) (D) Cpu0 *E+ Magnetic field lines and induced electric field lines always from closed loop.1% (D) 4. After the collision.01 V = 0. Corporate Office : ALLEN CAREER INSTITUTE.2 kg rests on a vertical post of height 5m.01 × 5 u Time of flight t = 1 s.allen.744 . Fax : +91-744-2435003. INDRA VIHAR. traveling with a velocity V m/s in a horizontal direction.1% è P 2070 ø 460 (A) 250 m/s A LL EN V m/s 0 20 100 A ball of mass 0.ac. E-mail: info@allen. KOTA-324005 PHONE : +91 .

Fax : +91-744-2435003.a) = 2x 2 ( b .a) Corporate Office : ALLEN CAREER INSTITUTE. 5p 6 (D) A. 4p 3 (C) 3 A.in 12 / 29 .744 .ac.2 480 A point mass is subjected to two simultaneous sinusoidal displacements in x-direction. INDRA VIHAR. m 0 NI æ b ö ln ç ÷ (C) è aø 2b I a b X (D) Cpu0 *C+ Taking an elemental strip of radius x and width dx.allen. “SANKALP”. x1 ( t ) = A sin wt 2p ö æ wt + ÷ . E-mail: info@allen. p 3 2p /3 A x1(t) 49.04 .IIT-JEE 2011 EXAMINATION (HELD ON : 10 . KOTA-324005 PHONE : +91 .2436001. The spiral has inner radius a and outer radius b.a÷ ø 2b x1(t) + x2(t) + x3(t) = 0 x3(t) has to be such that resultant is zero. CP-6. The values of B and f are (A) Cpu0 *D+ x2(t) A 2 A. 4p from x1(t) anticlockwise.2011) PAPER . Adding a third sinusoidal displacement x3 ( t ) = B sin ( wt + f) brings the and x2 ( t ) = A sin ç è 3ø mass to a complete rest.a ø m 0 NI æ b + a ö ln ç è b . The Zcomponent of the magnetic field at the center of the spiral is So it should make (A) (B) m 0 NI æ bö ln ç ÷ è aø ( ) 2 b-a Y A LL EN m 0 NI æ b + aö ln ç ÷ 2 ( b .a) è b . 3p 4 (B) A. Area of strip = 2px dx Y Number of turns through area = N dx b-a I a b x X ò dB = ò a b m0 N æ bö Idx m 0 NI ln ç ÷ è aø ( b .in Website: www.ac. The spiral lies in the X-Y plane and a steady current I flows through the wire. 3 A long insulated copper wire is closely wound as a spiral of N turns.

b. They are fully immersed in a fluid of density dF. (B) The Gauss law can be used to calculate the field distribution around an electric dipole. Each question has four choices (A). E-mail: info@allen. then the sign of the two charges is the same. KE = mv2. “SANKALP”. therefore (C.2 4:0 A satellite is moving with a constant speed V in a circular orbit about the earth. (D) The work done by the external force in moving a unit positive charge from point A at potential VA to point B at potential VB is (VB VA) Cpu0 *EF+ The field distribution for a dipole can not be calculated by using Gauss law only. PE of object = mv2 2 At the time of ejection KE + PE = 0 to make it escape from gravitational pull. (C) If the electric field between two point charges is zero somewhere. Fax : +91-744-2435003.04 . Therefore a. the kinetic energy of the object is (A) 1 mV 2 2 (B) mV2 (C) 3 mV 2 2 (D) 2mV2 Cpu0 *D+ 1 2 mv when it moves with satellite . (C) and (C) dA > dF (D) dA + dB = 2dF Which of the following statement(s) is/are correct? (A) If the electric field due to a point charge varies as r2.ac. At the time of its ejection. 2vdFg = v (dA+dB)g dA + dB = 2dF.744 . then the Gauss law will still be valid. The arrangement is possible only if (A) dA < dF (B) dB > dF Cpu0 *CDF+ FBuoyant = (ma + mB)g .in Website: www.0 Two solid spheres A and B of equal volumes but of different densities dA and dB are connected by a string. CP-6.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . (B). An object of mass m is ejected from the satellite such that it just escapes from the gravitational pull of the earth. KE of object = UGEVKQPKK"<"*Vqvcn"Octmu"<"38+ *Ownvkrng"Eqttgev"Cpuygt"V{rg+ (D) out of which QPG"qt"OQTG may be correct. They get arranged into an equilibrium state as shown in the figure with a tension in the string.D) Corporate Office : ALLEN CAREER INSTITUTE. 4. INDRA VIHAR.2011) PAPER .2436001.in 13 / 29 .5 instead of r2.ac.allen. KOTA-324005 PHONE : +91 . d 520 A LL EN A B This section contains 6"ownvkrng"ejqkeg"swguvkqpu.

The voltage across AB in volts is 6V 1W A 3V 2W B Cpu0*7+ 6 3 15 + 1 2 = 2 =5 vAB = 1 1 3 + 1 2 2 14 / 29 A LL EN 1m/s Corporate Office : ALLEN CAREER INSTITUTE. CP-6.75 m and goes vertically up with velocity 10 m/s. UGEVKQPKKK"<"*Vqvcn"Octmu"<"46+ *Kpvgigt"Cpuygt"V{rg+ This Section contains "8"swguvkqpu." ranging from 0 to 9. E-mail: info@allen. Which of the following is/are true? A B (A) I R > IR A B (B) I R < IR (C) VCA > VCB (D) VCA < VCB Cpu0 *DE+ XC decreases therefore impedence decreases and current increases. (A) when C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. The current IR through the resistor and voltage VC across the capacitor are compared in the two cases. The answer to each of the questions is a ukping/fkikv"kpvgigt. hits the ring at a height of 0. INDRA VIHAR. KOTA-324005 PHONE : +91 .ac.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .2 530 A series R-C circuit is connected to AC voltage source.ac. 550 Two batteries of different emfs and different internal resistances are connected as shown.04 .allen. Immediately after the collision 10m/s 20m/s 0. Consider two cases . The bubble corresponding to the correct answer is to be darkened in the ORS. A small ball of mass 0. “SANKALP”.2011) PAPER .in Website: www. moving with velocity 20 m/s in the opposite direction.5 m is rolling without slipping on a horizontal plane with velocity 1 m/s.1 kg. Fax : +91-744-2435003.2436001.in .75m (A) the ring has pure rotation about its stationary CM (B) the ring comes to a complete stop (C) friction between the ring and the ground is to the left (D) there is no friction between the ring and the ground Cpu0 *CE+ Since momentum of ball and ring has same magnitude but they are opposite in direction and final momentum of ball after the collision in horizontal direction is zero. therefore the ring has pure rotation about its stationary CM just after collision (assuming nonimpulsive friction).744 . 540 A thin ring of mass 2 kg and radius 0. IB > IA As IB increases the voltage across R increases therefore VC decreases.

A train is moving along a straight line with a constant acceleration a. KOTA-324005 PHONE : +91 . m2 = R=6cm m =7/4 m =4/3 7 m m m .04 .m1 .15 m inside the train to catch the ball back at the initial height. u = 24.5 R = ÷ è wc ø 500 ´ C 250 R 250 t = 4 millisecond. x =2 R=6cm Denser m =7/4 Rarer 21 h I1 m =4/3 Corporate Office : ALLEN CAREER INSTITUTE. Consider oil to act as a thin lens.15 = 5t 580 A LL EN 2v y g = 2´5 3 = 3 10 1 1 1 æ 1 ö sec 0. Oil of 3 S m =1.25 .2436001.0 After solving v = 21 Now for second refraction : 21 = 16 h= ( 21/16 ) So.2 560 A series R-C combination is connected to an AC voltage of angular frequency w=500 radian/s.1 = 2 4 v u R S m =1. at an angle of 60° to the horizontal. is Cpu0 *7+ Ykvj"tgurgev"vq"vtckp"< Velocity : Acceleration : 2 1 2 at Þ a =5 m/s2 2 Water (with refractive index = 4 ) in a tank is 18 cm deep. CP-6. If the impedance of the R-C circuit is R 1. The location of its image is at x cm above the bottom of the tank. from bottom 18 16 = 2 So.ac. Fax : +91-744-2435003.in Website: www. INDRA VIHAR.25 R = R + ç è wc ÷ ø 2 2 2 2 T= 1. t = 4 57. The acceleration of the train.2011) PAPER . 2 .allen. R = + 6. E-mail: info@allen.ac.744 . The boy has to move forward by 1. A boy standing in the train throws a ball forward with a speed of 10 m/s. the time constant (in millisecond) of the circuit is Cpu0 *6+ æ 1 ö 1.25 R = ç .IIT-JEE 2011 EXAMINATION (HELD ON : 10 . “SANKALP”. RC = . An object S is placed 24 cm above water surface.0 7 refractive index lies on water making a convex surface of radius 4 of curvature R = 6 cm as shown.in 15 / 29 . C = . 0. Then x is Cpu0 *4+ First refraction: m1 =1. in m/s2.

44 4 = ÞN=4 9 10 v2 = 5:0 A silver sphere of radius 1 cm and work function 4.6 16 / 29 A LL EN Corporate Office : ALLEN CAREER INSTITUTE. E-mail: info@allen. CP-6.allen. As photoelectrons are emitted.2436001.ac.6 10 ç ÷ è 200 ø 1 /100 2 15 ´ 10 7 = N 1. The value of Z is Cpu0 *9+ ( Ne) K hc .kx 2 = 0 .mv 2 2 2 1. Initially the block is at rest and the spring is un-stretched.in Website: www.IIT-JEE 2011 EXAMINATION (HELD ON : 10 .in \\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\ .18 kg is attached to a spring of force-constant 2 N/m.04 .2011) PAPER .ac.7 1.7 eV is suspended from an insulating thread in freespace. An impulse is given to the block as shown in the figure. It is under continuous illumination of 200 nm wavelength light.744 . Fax : +91-744-2435003. Then N is Cpu0 *6+ 1 1 -mmgx .06 m and comes to rest for the first time. KOTA-324005 PHONE : +91 .6 ´ 10 -19 ) 9 ´ 10 9 æ 1240 ö -19 ´ = 4.2 590 A block of mass 0. The coefficient of friction between the block and the floor is 0. The initial velocity of the block in m/s is V= N/10.f = eV = e l R N (1. the sphere gets charged and acquires a potential. INDRA VIHAR. The maximum number of photoelectrons emitted from the sphere is A × 10z (where 1 < A < 10). “SANKALP”.1. The block slides a distance of 0.

v Hqt"*C+""< In process AB (isobaric compression) Work is negative. Match them with each of the processes given in Eqnwop"K. Process D®A (s) (t) Heat is gained.04 . darken the bubbles corresponding to q and r in the ORS. Fax : +91-744-2435003. then for the particular question. DU is positive . DQ is positive Hqt"*F+""< DA Process (V = decreases Isothermal) Work is negative. B. “SANKALP”. P 3P B A Eqnwop"K (A) (B) (C) (D) Cpu0 *C+"r. P 3P B A 1P 0 C 1V 3V D 9V V 17 / 29 . DQ is negative Hqt"*D+"< BC process (Isochoric) Work is zero.v"*D+"r. INDRA VIHAR.t"*E+"s.in A LL EN 1P 0 C D 1V 3V 9V V Eqnwop"KK Process A®B (p) Internal energy decreases.allen. C and D) given in Eqnwop"K and five statements (p. DQ is negative Corporate Office : ALLEN CAREER INSTITUTE. if for a given question.2011) PAPER .0 One mole of a monatomic ideal gas is taken through a cycle ABCDA as shown in P-V diagram.t.in Website: www. E-mail: info@allen. Any given statement in Column I can have correct matching with QPG or OQTG"statement(s) given in Column II.744 . KOTA-324005 PHONE : +91 . For example. Process C®D (r) Heat is lost. DQ is negative Hqt"*E+""< CD Process (Isobaric expansion) Work is negative. q. statement B matches with the statements given in q and r. Work is done on the gas. DU is negative . Each question has hqwt"uvcvgogpvu"(A. 5.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . s and t) in Eqnwop"KK. CP-6. against statement B.u"*F+"t. Process B®C (q) Internal energy increases. DU is zero . Eqnwop"KK gives the characteristics involved in the cycle.2436001.ac.2 UGEVKQPKX"<"*Vqvcn"Octmu"<"38+ *Ocvtkz/Ocvej"V{rg+ This Section contains "4"swguvkqpu.ac. DU is negative . r.

v"*D+"r. each of the same length L.u"*E+"s. CP-6.ac.t Hqt"*C+ : Hqt"*D+": Hqt"*E+ : Hqt"*F+ : 18 / 29 A LL EN 0 L (C) Stretched wire clamped at both ends (r) lf=L Stretched wire clamped at both ends (s) lf = 2L and at mid-point 0 L (t) lf = 4L L/2 Sound wave is longitudinal wave lF = L Þ lF = 4L 4 Sound wave is longitudinal wave lF = L Þ lF = 2L 2 String wave is transverse lF = L Þ lF = 2L 2 lF = L Þ so (q & r) Corporate Office : ALLEN CAREER INSTITUTE.2 620 Col um n I shows four systems.ac. The lowest possible natural frequency of a system is called its fundamental frequency. KOTA-324005 PHONE : +91 . Match each system with statements given in "Eqnwop"KK describing the nature and wavelength of the standing waves.in Website: www.IIT-JEE 2011 EXAMINATION (HELD ON : 10 . INDRA VIHAR.744 .2011) PAPER . “SANKALP”. for producing standing waves.2436001. Eqnwop"K (A) Pipe closed at one end Eqnwop"KK (p) Longitudinal waves 0 L (B) Pipe open at both ends (q) Transverse Waves 0 L (D) Cpu0 *C+"r.04 .u"*F+"s.in . Fax : +91-744-2435003. whose wavelength is denoted as lf.allen. E-mail: info@allen.

v+ lp5 lp5 0000*k+ 0000*kk+ 3 0" Vjgp" d" gswcnu 6 *C+" *D+" 3 6 3 3 4 *E+" y 3 5 *F+" 3 6 Q Þ Þ Þ T3"T4"?" d 4 4 ò *3 .*3 ." *D+." qwv" qh" yjkej" QPN[" QPG" ku" eqttgev0 690 Vjg" xcnwg" qh" 1 5 *C+" np 6 4 Cpu0*C+ lp5 z ukp z 4 ò ukp z 4 + ukp*np 8 .0) x æ *3 .ac.2436001.d+5 = 5 34 3 4 Þ *3" " d+5" ?" Þ 3" " d" ? Þ d= 3 4 Corporate Office : ALLEN CAREER INSTITUTE.ac.z+ fz = 2 d d 3 3 6 Þ R1 R R2 0 x=b 2 (1. “SANKALP”.v+ fv Þ K= ò 4 lp 4 ukp*lp8 . CP-6.d+5 3 -í .IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER .v+ + ukp v Cffkpi" gswcvkqp" *k+" (" *kk+ lp5 6:0 3 æ5ö 3 Þ 4K = ò fv Þ K = lp ç ÷ 4 lp4 6 è4ø Ngv"vjg"uvtckijv"nkpg"z"?"d"fkxkfg"vjg"ctgc"gpenqugf"d{"{"?"*3""z+4.z+5 ö æ *3 .d+5 = Þ 5 5 6 3 : 4 3 *3 .z+ fz .T 4 = 6:0 5 6 Cpu0*D+ A LL EN 3 ukp v K= ò fv 4 lp 4 ukp v + ukp*lp8 .allen.ý= 5þ 5 6 î 5 3 2 3 .d+5 3 ü *3 ."{"?"2"cpf"z"?"2"kpvq"vyq"rctvu T3 *2 £ z £ d+ f" cpf" T 4 *d £ z £ 3+ " uwej" vjcv" T3 . Fax : +91-744-2435003.z 4 + fz " ku np 4 1 5 *D+" np 4 4 np 5 *E+" np 690 5 4 *F+" np 1 8 5 4 z ukp z 4 K= ò fz =" rwv" z4" ?" v" Þ" 4zfz" ?" fv 4 4 + ukp z ukp* l p8 z + lp4 Þ 3 ukp*lp8 . INDRA VIHAR." *E+ cpf" *F+. E-mail: info@allen.ò *3 .744 .z+ 5 ö 3 -ç ÷ +ç ÷ = è 5 ø2 è 5 ø d 6 ì *3 .in 19 / 28 .in Website: www.1 RCTV"/"KKK"*OCVJGOCVKEU+ UGEVKQPK"<"*Vqvcn"Octmu"<"43+ *Ukping"Eqttgev"Cpuygt"V{rg+ Vjku" ugevkqp" eqpvckpu" 9" ownvkrng" ejqkeg"swguvkqpu0" Gcej" swguvkqp" jcu" hqwt" ejqkegu" *C+. KOTA-324005 PHONE : +91 .

d = k . *C+" 3 *D+" 4 *E+" 5 *F+ "6 20 / 28 Corporate Office : ALLEN CAREER INSTITUTE.l + m "cpf" e = k- l-m c d r " ku" 3 .2436001.0 r r r r "kp"vjg"rncpg"qh" r "cpf" r .5 *C+" *D+" -5k l-m k .in . E-mail: info@allen.5 l + 5m Cpu0*E+ r r r x = zc + {d + {+ 0000*k+ = k*z + {+ + l*z . "dg"vjtgg"xgevqtu0"C"xgevqt" x Ngv" c = k + l + m."ykvj" a > b0"Kh"cp"?" ap"" bp"hqt"p" ³"3.ac.{+ + m*z - *E+" 5k l + 5m *F+" k + 5 l .IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER . CP-6."vjgp"vjg"xcnwg qh" c32 .0 .5m r 3 = Ikxgp" .ac.1 6.in Website: www.4c : " ku 4c . KOTA-324005 PHONE : +91 . INDRA VIHAR. Fax : +91-744-2435003.allen." x0e 5 720 Vjgp" z2" ku *C+" 720 3 8 A LL EN ( 4z ) np 4 z+{-z+{-z-{ 3 = 5 5 {" " z" ?" 3 Þ z" " {" ?" 3 0000*kk+ r - wukpi"*kk+" kp"*k+" yg"igv" x = *z + {+k l + *z + {+m Ngv" *z2.lp4 ý l l l í Þ î lp4 þ Þ lpz" ?" " lp4 Þ 730 z= 3 4 Ngv" a"cpf" b"dg"vjg"tqqvu"qh"z4""8z"" 4"?"2." ku" ikxgp" d{ yjqug" rtqlgevkqp" qp" e 5 6.744 . “SANKALP”. "{2+" dg" vjg" uqnwvkqp" qh" vjg" hqnnqykpi" gswcvkqpu Þ = *5{+np 5 5npz" ? "4np{ 3 5 *D+" *E+" Cpu0*E+ 3 4 *F+ "8 ( 4z ) lp4 = *5{+ l p 5 Þ lp4" *lp4" -" lpz+" ?" lp5*lp5" -" lp{+ 00000*k+ 5lpz" ? "4lp{ Þ *lpz+"*lp5+" ?" *lp{+" *lp4+ 00000*kk+ wukpi" *kk+" kp" *k+ *lpz+*lp5+ ö æ Þ lp4*lp4-lpz+? lp5 ç lp5 + ÷ lp4 è ø ì lp 4 5 ü 4 4 p 4 p 5 = pz .

2436001."4+" ku"kpenkpgf"cv"cp"cping"82²"vq"vjg"nkpg" 5z + { = 3 0"Kh"N cnuq" kpvgtugev" vjg" z/czku.allen.z + 5 + 4 5 = 2 740 Cpu0" *D+ A LL EN gswcvkqp" qh" nkpg" N" yjgp" q = p .4+ . + a: 08a .4+ 4*a. Fax : +91-744-2435003. KOTA-324005 PHONE : +91 .0 3 JK 3x+y=1 gswcvkqp" qh" nkpg" N" yjgp" q" ?" 2.4c : a32 .equ q = 4 equ q " cpf" S = q < ukp q + equ q = 4 ukp q " dg" vyq" ugvu0" Vjgp *C+" R Ì S " cpf" S .in 21 / 28 . + = 740 *C+" { + 5z + 4 .b32 .1 730 Cpu0" *E+ a. 5 {+4= 5*z .1) p Nkpg" N" jcu" vyq" rquukdng" unqrgu" ykvj" kpenkpcvkqp=" q = .b: 08b =5 4*a. + = a: *a4 . .5z + 4 + 5 5 = 2 *F+" 5{ + z . {" ?" 4" *tglgevgf+ \ 750 tgswktgf" nkpg" N" ku { .b: + = 4c .4*a: . CP-6.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER .5z + 4 + 5 5 = 2 Ngv" R = q < ukp q . .in Website: www." vjgp" vjg" gswcvkqp" qh" N" ku *D+" { . INDRA VIHAR.5+ C"uvtckijv"nkpg"N"vjtqwij"vjg"rqkpv"*5. “SANKALP”."equ "q" ?" 4 ukpq Þ vcp q = 3 = 4 +3 4 -3 000*kk+ htqo" *k+" (" *kk+ Þ " R?S Corporate Office : ALLEN CAREER INSTITUTE.5z + 4 + 5 5 = 2 GH 1 .744 . 4*a .b: *b4 .ac.ac.R ¹ Æ *E+" R Ì / S *D+" S Ì / R *F+ "R "? "S { } { } 750 Cpu0*F+ R "? "}q" <" ukpq" " equq" ?" 4 " equq Þ vcpq" ?" 4 -3 000*k+ S "? "}q" <" ukpq" .b.b" ctg" tqqvu" qh" z4" "8z " "4 "? "2 Þ a4" "8a" 4 "? "2 "( "b4" "8b" "4 "? "2 c 2 ." q = 2 5 \ 2p/3 Þ { .b.b. . E-mail: info@allen.5 + 4 5 = 2 (0.5 5 = 2 *E+" 5{ .

INDRA VIHAR." "" z." vjgp" O4P4*OVP+3" *OP3+V" ku "gswcn "vq "/ *C+" O4 *D+" P4 *E+" O4 *F+" OP Uqn0 Cpu0" *E+ *Eqoogpv"<"Cnvjqwij"5"Ù"5"umgy"u{oogvtke"ocvtkegu"ecp"pgxgt"dg"pqp/ukpiwnct0"Vjgtghqtg"vjg kphqtocvkqp"ikxgp"kp"swguvkqp" ku"ytqpi0" Pqy"kh" yg"eqpukfgt"qpn{"pqp" ukpiwnct"umgy"u{oogvtke ocvtkegu" O"(" P.*d0e+c r + 4 + ." qwv" qh" yjkej" QPG" qt" OQTG" oc{" dg" eqttgev0 760 "cpf" .in A LL EN *z + j+ . *z+ *z+ + *j+ ." vjgp *C+" *z+" ku" fkhhgtgpvkcdng" qpn{" kp" c" hkpkvg" kpvgtxcn" eqpvckpkpi" |gtq *D+" *z+" ku" eqpvkpwqwu" "" z" Î" T *E+" )*z+" ku" eqpuvcpv" "" z" Î" T *F+" *z+" ku" fkhhgtgpvkcdng" gzegrv" cv" hkpkvgn{" ocp{" rqkpvu Uqn0 Cpu0" *D." *E+ cpf" *F+.E+ *z" -" {+" ?" *z+" -" *{+ *2+"?" 2 770 )*z+" ?" nko j ®2 = nko j ®2 *j+ *2 + j+ . CP-6.F+ r x = 6 l* l .ac. *z+ = nko j ®2 j j r r c= k+ l + 4m d= k + 4 l+ m r r r rr r rr r r x = l**c ´ d+ ´ e+ = l**c0e+d . *2+ = nko j ® 2 j j )*z+" ?" )*2+" ?" m" *m" ku" eqpuvcpv+ Þ *z+" ?" mz."cpf""rgtrgpfkewnct"vq"vjg Vjg""xgevqt*u+"yjkej"ku1ctg"eqrncpct"ykvj"xgevqtu" k+ l + 4m k + 4 l+ m " ku1ctg xgevqt" k+ l+ m *C+" l. E-mail: info@allen." vjgp" vjg" uqnwvkqp" ku/+ Ikxgp OV" ? "O PV" ? "P OP" ?" PO 22 / 28 Corporate Office : ALLEN CAREER INSTITUTE.allen. Fax : +91-744-2435003.6*k x = l]6*k l + m+ l + 4m+_ .1 UGEVKQPKK"<"*Vqvcn"Octmu"<"38+ *Ownvkrng"Eqttgev"Cpuygt"V{rg+ Vjku" ugevkqp" eqpvckpu" 6" ownvkrng" ejqkeg"swguvkqpu0" Gcej" swguvkqp" jcu" hqwt" ejqkegu" *C+.in Website: www.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER ." {" Î" T0 Kh" *z+" ku" fkhhgtgpvkcdng" cv" z" ?" 2." *D+.m *D+" - k+ l *E+" k- l r e " ?" k+ l+ m *F+" -l + m Uqn0 Cpu0" *C.2436001.744 . KOTA-324005 PHONE : +91 .ac.m+ Ngv " "< "T "®" T" dg" c" hwpevkqp" uwej" vjcv *z" -" {+" ?" *z+" -" *{+. “SANKALP”." jgpeg" *z+" ku" eqpvkpwqwu" cpf" )*z+" ku" eqpuvcpv" "" z" Î" T 780 Ngv"O"cpf"P"dg"vyq"5"Ù"5"pqp/ukpiwnct"umgy/u{oogvtke"ocvtkegu"uwej"vjcv"OP"?"PO0"Kh"RV"fgpqvgu vjg" vtcpurqug" qh" R.

in Website: www.in A LL EN gnnkrug" ku" z 4 {4 + =3 44 3 3 = 6 5 5 = 6 4 6 5 d4 = c4 Þ 5d4" ? "c4 00000000000*3+ Þ c4" ? "5 000000000000*4+ Þ z4" " 5{4" ? "5 23 / 28 .allen. 2 ÷ º ( ±4.744 . 2+ 5 =3 c4 htqo" *3+" (" *4+ d4" ? "3 gswcvkqp" qh" j{rgtdqnc" ku" z 4 {4 =3 5 3 3 = 5 6 5 geegpvtkekv{" qh" j{rgtdqnc" = 3 + 4 æ ö hqewu" qh" j{rgtdqnc" ?" ç ± 50 . CP-6.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER .1 ceeqtfkpi" vq" swguvkqp" O4P4*OVP+3" *OP3+V ? "O4P4P3*OV+3*P3+VOV ? "O P P *O+ *P + *O+ ?" O4" P "O3" P3" O ? " "O4" P "P3" O3" O ?" O4 790 4 4 3 3 V 3 é OP = PO ê -3 -3 ê *OP+ = *PO+ ê P -3O -3 = O -3P -3 ë z 4 {4 Ngv" vjg"geegpvtkekv{"qh" vjg"j{rgtdqnc" 4 .2+ z4 { 4 =3 5 4 7 5 4 *F+" vjg" gswcvkqp" qh" vjg" j{rgtdqnc" ku" z " " 5{4" ? "5 Uqn0 Cpu0" *D. Fax : +91-744-2435003.F+ *E+" vjg" geegpvtkekv{" qh" vjg" j{rgtdqnc" ku" z 4 {4 j{rgtdqnc" ku" 4 . “SANKALP”.4 = 3 "dg"tgekrtqecn"vq"vjcv"qh"vjg"gnnkrug"z4"-"6{4"?"60 c d Kh" vjg" j{rgtdqnc" rcuugu" vjtqwij" c" hqewu" qh" vjg" gnnkrug. 2 ) 5 ø è Corporate Office : ALLEN CAREER INSTITUTE. KOTA-324005 PHONE : +91 .4 = 3 c d Ikxgp geegpvtkekv{" qh" gnnkrug" ?" 3 - geegpvtkekv{" qh" j{rgtdqnc" ?" 3 + Þ d4 3 = c4 5 cnuq" j{rgtdqnc" rcuugu" vjtqwij" hqek" qh" gnnkrug" * ± 5.2436001. E-mail: info@allen." vjgp" / *C+" vjg" gswcvkqp" qh" vjg" j{rgtdqnc" ku" *D+" c" hqewu" qh" vjg" j{rgtdqnc" ku" *4.ac.ac. INDRA VIHAR.

KOTA-324005 PHONE : +91 ." 8M."| "? "3 4M ". “SANKALP”.0 c ". Fax : +91-744-2435003.+ ukpeg" Ko*w+ "@ "2 4 4 Kh "c "? "4 "? "M Þ d" ?" 34" " (" e" ?" 36 24 / 28 Corporate Office : ALLEN CAREER INSTITUTE." *E+" cpf" *F+."9e "? "2 Þ c "? "M. "e "? "9M Cpu0" *F+ *M." qwv" qh" yjkej" QPN[" QPG" ku" eqttgev0 Rctcitcrj" hqt" Swguvkqp" 7:" cpf" 82 Ngv" c." vjgp" å ç + ÷ ku/ bø p= 2 è a ¥ 4 A LL EN p é3 ."d "."vjgp"vjg"xcnwg"qh"9c-d-e ku *C+" 2 *D+" 34 *E+" 9 *F+ "8 5 Ngv" w" dg" c" uqnwvkqp" qh" z " " 3" ?" 2" ykvj" Ko*w+" @" 20" Kh" c" ?" 4" ykvj" d" cpf" e" ucvkuh{kpi" *G+.allen.0 xcnwg" qh" 820 5 3 5 + d + e " ku" gswcn" vq" / c w w w *C+" 4 *D+" 4 *E+" 5 *F+" 5 Ngv" d" ?" 8. CP-6."{ "."4d ".e+.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER ."8M " "9M "? "3 *Q rqkpv" nkgu" qp"vjg" rncpg+ Þ M "? "3 Þ 9c "."ykvj"tghgtgpeg"vq"*G+."e "? "9M ".ac.1 UGEVKQPKKK" <" *Vqvcn" Octmu" <" 37+ *Rctcitcrj"V{rg+ Vjku"ugevkqp"eqpvckpu"4"rctcitcrju0"Dcugf"wrqp"qpg"qh"vjg"rctcitcrj."5e "? "2 9c "." vjgp" vjg *C+" 8 Uqn0 *D+" 9 8 9 " Rctcitcrj" hqt" Swguvkqp" 7:" vq" 82 *E+" *F+" ¥ 7:0 7." *D+. E-mail: info@allen." 9M+ 4z ".in . "d "? "8M "." w."9d ". INDRA VIHAR." ykvj" c" cpf" e" ucvkuh{kpi" *G+0" Kh" a" cpf" b" ctg" vjg" tqqvu" qh" vjg" swcftcvke" gswcvkqp æ3 3ö cz " -" dz" -" e" ?" 2.":d ". 9ù ú [c d e] ê ê: 4 9 ú = [ 2 2 2 ] 000*G+ ê ú 9 5 9 ë û Kh"vjg"rqkpv"R*c.744 ."8M " "9M "? "8 Cpu0" *C+ z5" "3 "? "2 Þ z" ?" 3.ac."nkgu"qp"vjg"rncpg"4z"-"{"-"|"?"3.c "." 5"ownvkrng"ejqkeg"swguvkqpu cpf"dcugf"qp"vjg"qvjgt"rctcitcrj" 4"ownvkrng"ejqkeg"swguvkqpu"jcxg"vq"dg"cpuygtgf0"Gcej"qh"vjgug swguvkqpu"jcu" hqwt" ejqkegu" *C+. w4 3 k 5 w= .d" cpf" e" dg" vjtgg" tgcn" pwodgtu" ucvkuh{kpi 7:0 7.d."9e "? "2 .in Website: www.2436001.

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4) Uqn0 Cpu0 "4 A D3" ?"ctgc" qh" D" RCC) y = 8x (1/2.2436001. Fax : +91-744-2435003." cpf" D4" dg" vjg" ctgc" qh" vjg" vtkcping" hqtogf" d{ è4 ø D3 ftcykpi" vcpigpvu" cv" R" cpf" cv" vjg" gpf" rqkpvu" qh" vjg" ncvwu" tgevwo0" Vjgp" D " ku 4 (2. INDRA VIHAR.in A LL EN p Uqn0 Cpu0 ".in Website: www."000000000000.000000000.1)d] Sm = 2 n Sn [2a1 + (n ."ngv"o"?"7p0"Kh" U "fqgu"pqv"fgrgpf"qp"p.0"Vjg"dwddng"eqttgurqpfkpi"vq"vjg"eqttgev"cpuygt"ku"vq"dg"fctmgpgf"kp"vjg"QTU0 850 Ngv"c3.ac.d) + 5nd] = Sn [(2a1 ."vjgp"c4"ku p c3" ? "5 " "= " " "Ur" ? å a i """ 3" £" p" £" 42 i =1 o" ?" 7p m [2a1 + (m .c4.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER . CP-6."c322 ®"CR Uo " vq" dg" kpfgrgpfgpv" qh" p Up P Þa=2 3 " *D3+ 4 A' (2.allen. Kh " "f "? "2 " " " " Þ c4" ? "c3" ? "5 Eqpukfgt" vjg" rctcdqnc" {4" ?" :z0" Ngv" D3" dg" vjg" ctgc"qh" vjg" vtkcping"hqtogf" d{" vjg" gpf" rqkpvu" qh" kvu æ3 ö ncvwu"tgevwo" cpf"vjg" rqkpv" R ç .d) + nd] hqt" 860 \" 4c3" "f "? "2 " " Þ " f" ?" 4c3" Þ f" ?" 8" Þ " c4" ? ". “SANKALP”.""tcpikpi htqo"2"vq".2) 2 3 5 """" ? " 0:0 = 8 4 4 D4" ?" *Wukpi" rtqrgtv{" <" Ctgc" qh" vtkcping" hqtogf" d{" vcpigpvu" ku"cnyc{u"jcnh" qh" qtkikpcn" vtkcping+ 26 / 28 Corporate Office : ALLEN CAREER INSTITUTE.c5. "qt "5 *Eqoogpv"<"Vjg"kphqtocvkqp"cdqwv"vjg"eqooqp"fkhhgtgpeg"k0g0"|gtq"qt"pqp/|gtq"ku"pqv"ikxgp"kp vjg" swguvkqp0" Jgpeg" vjgtg" ctg" vyq" rquukdng" cpuygtu+ Eqpukfgt" f" ¹" 2" vjg" uqnwvkqp" ku c3."c4. KOTA-324005 PHONE : +91 .ac. E-mail: info@allen."c5.744 . 4 ÷ qp" vjg"rctcdqnc.c322"dg"cp"ctkvjogvke"rtqitguukqp"ykvj"c3"?"5"cpf" Ur = å c k .3 £ r £ 322 0"Hqt"cp{ k =3 r Uo kpvgigt"p"ykvj"3">"p">"42.–4) .1 UGEVKQPKX"<"*Vqvcn"Octmu"<"4:+ *Kpvgigt"Cpuygt"V{rg+ Vjku"Ugevkqp"eqpvckpu""9"swguvkqpu0"Vjg"cpuygt"vq"gcej"qh"vjg"swguvkqp"ku"c"ukping"fkikv"kpvgigt.1)d] 2 Sm 5[(2a 1 .

" yjgtg" . “SANKALP”.allen..sin 2cos sin n n = 1 n n = 1 Þ" Þ p 3p 2p p 3p 2p sin sin sin sin sin sin n n n n n n sin Þ p= 3 4o 3 3 3 Þ p" ?" .in Website: www.IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER . Fax : +91-744-2435003. E-mail: info@allen. .in 27 / 28 .1 Þ 870 D3 =4 D4 Vjg" rqukvkxg" kpvgigt" xcnwg" qh" p" @" 5" ucvkuh{kpi" vjg" gswcvkqp 3 3 3 = + ku æpö æ 4p ö æ 5p ö ukp ç ÷ ukp ç ÷ ukp ç ÷ èpø è p ø è p ø Uqn0 Cpu0 "9 1 sin p n = 1 1 + 2p 3p sin sin n n Þ"" 1 sin p n - 1 1 = 3p 2p sin sin n n Þ 2cos Þ sin Kh " "M "? "4o Þ Kh " "M "? "4o ".744 ."3 9p = *4o + 3+ p p Rquukdng" xcnwg" qh" p" ku" 9 A LL EN 2p 2p 3p sin = sin n n n 4p 3p 4p 3p = sin Þ = Kp + ( -1) K n n n n p = 4op p 3p p 2p p . KOTA-324005 PHONE : +91 .2436001. INDRA VIHAR. .6 < q < 6 0" Vjgp" vjg" xcnwg"qh" f*vcp q+ è equ4q ø ø è Uqn0 Cpu0 "3 880 ukp q ö -3 æ Ngv" * q+ = ukp a " yjgtg" a = vcp ç ÷ è equ 4q ø Þ Þ Þ Þ 890 vcp a = ukp a = ukp q equ 4q ukp q = vcp q equ q æ æ p p öö çQ q Î ç .ac. ÷ ÷ è 6 6 øø è * q+ = vcp q f* *q++ =3 f*vcp q+ Kh" |" ku" cp{" eqorngz" pwodgt" ucvkuh{kpi" ~|" " 5" " 4k~" >" 4. 0000000 9 9 5 7 æ -3 æ ukp q ö ö p p f * *q++ " ku Ngv" *q+ = ukp ç vcp ç ÷ ÷ . 00000000 4 6 8 Þ Þ p" ?" 9 4o + 3 Þ p" ?" 9. CP-6." vjgp" vjg" okpkowo" xcnwg" qh" ~4|" " 8" -" 7k~ ku Corporate Office : ALLEN CAREER INSTITUTE.ac.

" 3.÷ + 4 è ø 7ö ?" 4" Ù" *fkuvcpeg" dgvyggp" *5."vjgtghqtg"kv"ku"pqv"cp"kfgpvkv{0"Jgpeg"vjgtg ku" cp" gttqt" kp" ikxgp" swguvkqp0" Vjg" eqttgev" kfgpvkv{" owuv" dg/+ 8 ò h*v+fv ? 5zh*z+ z 5 7."c:" .0 Ngv" " <" ]3." 5c5.744 ."3+okp" ? ": " " " "yjgp "c "? "3 Þ 8."Ez Ikxgp" *3+" ?" 4 Þ E "? "3 \ *4+"?" 44" ." c:" cpf" c32" ykvj" c" @"2" ku Uqn0 Cpu0 ": Cu c "@ "2 cpf" cnn" vjg" ikxgp" vgtou" ctg" rqukvkxg jgpeg"eqpukfgtkpi" C0O0"@" I0O0" hqt" ikxgp" pwodgtu" < |z–3–2i| < 2 Re Þ ÷ = ò fz ò fç èzø æ {ö Corporate Office : ALLEN CAREER INSTITUTE."5c5" .{ = z4 fz { = z+E *yjgtg" E" ku" eqpuvcpv+ z Þ { "? "z4" -" Ez \ *z+"?" z4" .–5/2) 7 ?" 4" Ù" " ?" 7" wpkvu0 4 8:0 Vjg" okpkowo" xcnwg" qh" vjg" uwo" qh" tgcn" pwodgtu" c7.z 5 3 z hqt" cnn" z" @" 3. “SANKALP”. INDRA VIHAR. KOTA-324005 PHONE : +91 . " z ³ 3 3 z Pqy" crrn{kpi" Pgyvqp" Ngkdpkv|" vjgqtgo 8 *z+" ?" 5z )*z+" " 5z4" -" 5 *z+ Þ 5 *z+" ?" 5z )*z+" " 5z4 Ngv" {" ?" *z+ Þ Þ z f{ .allen."4 "? "8 28 / 28 A LL EN Þ" zf{ .ac.in . . E-mail: info@allen.÷ + 4ø è (3."c32" .2+" cpf" æ (3.ç 5 . Fax : +91-744-2435003."c6" . .in Website: www.¥+" ®" ]4.1 Im Uqn0 Cpu0 "7 7 ö æ Yg"jcxg" vq" hkpf"okpkowo" xcnwg" qh" 4 | .IIT-JEE 2011 EXAMINATION (HELD ON : 10-04-2011) PAPER ." vjgp" vjg" xcnwg" qh" *4+" ku Uqn0 Cpu0 "8 *Eqoogpv"<"Vjg"ikxgp"tgncvkqp"fqgu"pqv"jqnf"hqt"z"?3.2436001.k ÷ 4 ø è 3 c -7 + c -6 + c -5 + c -5 + c -5 + c : + c32 -7 -6 -5 -5 -5 : 32 9 ³ ( c 0c 0c 0c 0c 0c 0c ) 9 c -7 + c -6 + c -5 + c -5 + c -5 + c : + c32 -7 -6 -5 : 32 ³3 Þ ( c + c + 5c + c + c ) okp ? "9 9 yjgtg" c7" ? "c6" ? "c5" ? "c:" ? "c32" k0g0 "c "? "3 Þ *c7" . "c6.0) ç 5.¥+" dg" c" fkhhgtgpvkcdng" hwpevkqp" uwej" vjcv" h*3+" ?" 40" Kh" 8 ò *v+fv = 5z *z+ .ac.2) ?" 4" Ù" *okpkowo" fkuvcpeg" dgvyggp" |" cpf" rqkpv" ç 5. CP-6.{fz = fz z4 7ö æ (3.

In Section II (Total Marks : 16).1 (Code . for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. 5. New Delhi-110075 Ph. 4. Marks: 240 INSTRUCTIONS 1. MLU. 3. minus one (–1) mark will be awarded. . There are no negative marks in this section. There are no negative marks in this section. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. Solutions for IIT-JEE 2011 PAPER . Dwarka. The question paper consists of 3 parts (Chemistry. In Section IV (Total Marks : 28). Physics and Mathematics). In Section III (Total Marks : 15).DATE : 10/04/2011 Regd. minus one (–1) mark will be awarded. for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. In all other cases. In Section I (Total Marks : 21). In all other cases.-4. Office : Aakash Tower. 2. Sec-11. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened.4) Max. Plot No.: 011-47623456 Fax : 011-47623472 Time : 3 hrs. Each part consists of four sections.

of KCl 3. of solute 1000 mol.05 M (D) 2.Regd.00 M (C) 2. The plot of conductance () versus the volume of AgNO3 is volume (P) (A) (P) Answer (D) Hints : (B) (Q) volume (Q) AgCl(s) + ( Di 3 AgNO3 + KCl KNO Ag+ and K+ have nearly same ionic mobility i on vi s of A sh a ka (C) (R) Ed u volume na o i t ca (R) e rvic e lS td sL . New Delhi-75 Ph.78 M Answer (C) Hints : M wt. (B). Among the following compounds. 4.05 60 1120 1.15 2. wt. (C) and (D) out of which ONLY ONE is correct. The molarity of the solution is (A) 1.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured.IIT-JEE 2011 (Paper-1) PART–I : CHEMISTRY SECTION . wt. Dwarka.15 g/mL. of solute volume of solution (B) 2. 1. 60) in 1000 g of water gave a solution of density 1.) volume (S) (D) (S) conc.: 011-47623417/23 Fax : 47623472 . Plot No. AgNO3(aq.I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. Dissolving 120 g of urea (mol. Office : Aakash Tower. Sector-11.22 M 120 1000 M 2. the most acidic is (A) p-nitrophenol (B) p-hydroxybenzoic acid (C) o-hydroxybenzoic acid (D) p-toluic acid Answer (C) O H C Hints : O –H – O C H O Stabilized by strong intramolecular hydrogen bonding (2) O H O Most acidic Aakash IIT-JEE . Each question has 4 choices (A).

Ba(s) + 3N2 Ba(N3)2 Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl–. CN– and H2O. vi s Extra pure N2 can be obtaine by heating (D i (A) NH3 with CuO (B) NH4NO3 i on of A sh a ka E du i on t a c CH2 a e rvic e S lCl td sL . Office : Aakash Tower. Plot No. square planar and octahedral (C) Square planar. tetrahedral and square planar (B) Tetrahedral.) N CH2 Br O O (C) (NH4)2Cr2O7 (D) Ba(N3)2 Answer (D) Hints : 6. square planar and octahedral Answer (B) Hints : [NiCl4]–2 (tetrahedral) Ni+2 + 4Cl– Ni(CN)4–2 (square planar) Ni+2 + 4CN– Ni(H2O)6+2 (octahedral) Ni+2 + H2O Aakash IIT-JEE . The major product of the following reaction is O C NH C O O C (A) (i) KOH (ii) Br CH2 Cl O C Br (B) N–CH2 C O N C O CH2Cl O C (C) O C (D) N O–CH2– Br N O CH2Cl Answer (A) More reactive site for SN2 O C Hints : O C N H OH C O N K Br C O 5. Dwarka. Sector-11. 4. respectively are (A) Octahedral.: 011-47623417/23 Fax : 47623472 (3) . New Delhi-75 Ph. tetrahedral and octahedral (D) Octahedral.IIT-JEE 2011 (Paper-1) 4.Regd.

Ltone plane in all the possible Amongst the given options the compound(s) in which all the atoms aresin e c conformations (if any). 4. Office : Aakash Tower.IIT-JEE 2011 (Paper-1) 7.: 011-47623417/23 Fax : 47623472 (4) . C2 — C3 bond. New Delhi-75 Ph. neutron 30 14Si 2 Al He4 30 14 Si 1H1 (X) 27 13 Al 4 2 He 30 15 P n 1 0 (Y) 30 14 Si 0 1e (Z) SECTION . (B). Sector-11. proton. (i) and (ii) as shown. Y and Z respectively are 27 13Al (i) (ii) 30 15P +Y 30 14 Si +X (A) Proton.Regd. positron (C) Proton. Each question has four choices (A). Bombardment of aluminium by -particle leads to its artificial disintegration in two ways. Dwarka. is(are) vi H H C—C H 2C CH2 d. Products X. (C) and (D) out of which ONE OR MORE may be correct. ) (A) (C) H2C = C = O Answer (B. Plot No. positron. C) H Hints : vi s (D i H sp2 H H i on a of A s (D) ka i t C—C (B) H—C ca d hE u er SH l a on CH2 H2C = C = CH2 C C H C 2 sp C C C O H All atoms lie in one plane in all conformation H H C C C is nonplanar H H H H H C C Planar H C C H H Non-planar in many conformations due to rotation along.II (Total Marks : 16) (Multiple Correct Answer Type) This section contains 4 multiple choice questions. Aakash IIT-JEE . 8. proton (D) Positron. positron. neutron. neutron Answer (A) Hints : 27 13 +Z (B) Neutron.

Hadsorption for chemical lies between 200-400 kJ/mole. 4.: 011-47623417/23 Fax : 47623472 (5) . C. Extraction of metal from the ore cassiterite involves (A) Carbon reduction of an oxide ore (B) Self reduction of a sulphide ore (C) Removal of copper impurity (D) Removal of iron impurity Answer (A. sufficient activation energy for chemical adsorption is provided.) SnO2 Sn CO If after contain Fe and Cu as impurity. Dwarka. According to kinetic theory of gases (A) Collisions are always elastic (B) Heavier molecules transfer more momentum to the wall of the container (C) Only a small number of molecules have very high velocity (D) Between collisions the molecules move in straight lines with constant velocities Answer (A. Plot No. D) (D Hints : At high temperature. however it is very slow due to higher energy of activation i on s i v i Answer (B. C) Hints : According to Kinetic theory of gases (i) Collisions are always elastic (ii) Momentum transferred on wall by one collision along x component = 2 mvx Fraction of (iii) molecule Velocity 10. New Delhi-75 Ph. B.Regd. Sector-11. 11. D) Hints : (B) Physisorption may transform into chemisorption at high temperature du c a ti lS on a er td sL .IIT-JEE 2011 (Paper-1) 9. Office : Aakash Tower. 1200 1300C Aakash IIT-JEE . Chemisorption of H2 on glass is an endothermic process. The correct statement(s) pertaining to the adsorption of a gas on a solid surface vice is(are) (A) Adsorption is always exothermic hE s a (C) Physisorption increases with increasing temperature ak but chemisorption decreases with increasing temperature A f o (D) Chemisorption is more exothermic that physisorption.

13) H3C H3C C – C H3C C–H Hg /H3O 2+ + (i) NaBH4 O H3C + (ii) dil H H3C C – C H3C CH3 OH H3C H3C C – C – H H3C CH3 –H H3C H C – C – CH3 H3C CH3 H3C H H3C C – C H3C CH3 CH3 H H3C C H3C C CH3 CH3 (i) O3 (ii) Zn–H2O 2 CH3 C O Aakash IIT-JEE . 12 and 13 An acyclic hydrocarbon P. Plot No. 4.) OH (D) CH 3CH 2CH 2CHCH 2CH 3 (Q.III (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs. Dwarka. 12 to Q.IIT-JEE 2011 (Paper-1) SECTION . (i) conc.: 011-47623417/23 Fax : 47623472 (6) . The structure of compound P is (A) CH3CH2CH2CH2 – C C – H (B) H3CH2C – C C – CH2CH3 H3C (C) H – C – C C – CH3 H3C (D) H3C – C – C C – H H3C Answer (D) 13. gave acetone as the only organic product through the following sequence of ractions. Based upon one of the paragraph 2 multiple choice questions and based upon the second paragraph 3 multiple choice questions have to be answered. Office : Aakash Tower. Paragraph for Questions Nos. H2 SO4 (catalytic amount) (–H2 O) (ii) O3 (iii) Zn /H2O O 2 H3C C CH3 P (C6H10) (i) dil. in which Q is an intermediate organic compound. (C) and (D) out of which ONLY ONE is correct. (B). H2SO4 / HgSO4 (ii) NaBH4 /ethanol (iii) dil. The structure of the compound Q is H3C H3C H3C OH (A) H – C – C – CH2CH3 H H3C H3C Answer (B) Hints : OH (C) H – C – CH2CHCH3 vi s (D i i on of A sh a ka (B) Hd u – C – C – CH3 3C H3C H3C E i on t a c a OH H e rvic e lS td sL . Sector-11. acid Q 12. Each of these questions has four choices (A).Regd. having molecular formula C6H10. New Delhi-75 Ph.

The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metal is Metal (eV) Li 2.7 Cu 4.4 Na 2. Addition of aqueous NH3 dissolves O and gives an intense blue solution. 14 to 16 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N. 4.16) Cu Ag Cu2 Ag (B) Cu (C) Ni (D) Co (B) Zn(NO3)2 (C) Al(NO3)3 (D) Pb(NO3)2 (B) [Al(NH3)4] 3+ and [Cu(NH3)4] 2+ (D) [Ag(NH3)2]+ and [Ni(NH3)6 ] 2+ Ag NaCl AgCl White ppt AgCl NH3 [Ag(NH3 )2 ] Cl Cu2 NH3 Cu(NH3 )2 4 (Blue) M . the solution turns light blue. Sector-11.IIT-JEE 2011 (Paper-1) Paragraph for Questions Nos.62 1034 3 108 300 109 1. New Delhi-75 Ph. The bubble corresponding to the correct answer is to be darkened in the ORS.3 Fe 4. ranging from 0 to 9. The work function () of some metals is listed below.Solution of AgNO3 O . 14.Cu N .3 K 2.14 eV Aakash IIT-JEE . The metal rod M is (A) Fe Answer (B) 15.6 1019 4. Dwarka. The compound N is (A) AgNO3 Answer (A) 16. 14 to Q. Addition of aqueous NaCl to the blue solution gives a white precipitate O.: 011-47623417/23 Fax : 47623472 (7) .3 W 4.Regd. The final solution contains (A) [Pb(NH3)4] 2+ and [CoCl4]2– (C) [Ag(NH3)2]+ and [Cu(NH3)4 ] 2+ Answer (C) Hints : (Q. The answer to each of the questions is a Single-digit integer.2 Mg 3. 17. Plot No.8 Ag 4.7 Pt 6. Office : Aakash Tower.IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions.75 Answer (4) Hints : Energy of incident photon should be higher than work function to slow photoelectric effect Energy of photon = 6.) SECTION .AgCl (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL .

To an evacuated vessel with movable piston under external pressure of 1 atm.0 mol of an unknown compound (vapour pressure 0.IIT-JEE 2011 (Paper-1) 18. 0. Sector-11. A decapeptide (Mol. 75). The number of glycine units present in the decapeptide is Answer (6) Hints : A decapeptide will have (9) peptide linkage Mass of hydrolyzed product is (796 + 162) gm/mole Number of glycine molecule = 0. Office : Aakash Tower..: 011-47623417/23 Fax : 47623472 (8) .32 19. Dwarka. Considering the ideal gas behaviour. at 0°C) are introduced. Wt. Glycine contributes 47. alanine and phenylalanine. Plot No.47 958 6 75 Aakash IIT-JEE .082 273 = 7 litre 0.Regd. Wt. The difference in the oxidation numbers of the two k types as of sulphur atoms in Na2S4O6 is Answer (5) Hints : Structure of S4O62– is v (D i i si o fA no a d hE u i on t a c a e rvic e lS td sL . 4.32 Hints : PHeV = nHeRT V= 0.1 0. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas.) O +5 0 O O–S–S–S–S–O O O Difference in oxidation state is +5 – 0 = +5. New Delhi-75 Ph. 796) on complete hydrolysis gives glycine (Mol.0% to the total weight of the hydrolysed products. 21.68 atm PHe = 0.68 atm. the total volume (in litre) of the gases at 0°C is close to Answer (7) 1 atm 1 atm PT = 1 atm vapour pressure of compound = 0.1 mol of He and 1. The number of sodium bromide molecules involved in the balanced chemical equation is Answer (5) Hints : Br2 2Br – Br2 2Br 5 10e– 5 2 e Br2 + 5Br2 10NaBr + 2NaBrO3 + 6CO2 + 6Na2CO3 3Br2 + 3Na2CO3 5NaBr + NaBrO3 + 3CO2 20.

and spin quantum number. is 2 Answer (9) Hints : 3s 3p 1 2 3d Out of 18 electrons present in 3rd shells. Plot No.I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. Office : Aakash Tower. Sector-11. 4. 24. Each question has 4 choices (A).IIT-JEE 2011 (Paper-1) 22. n = 3. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å. KOH + (E + Z) 1 Total + 2 =5 + (E + Z) + 2 Note : Dehydrobromination of alkyl bromides in the presence of alc.Regd.) (B) 1640 Å (C) 2430 Å (D) 4687 Å 2 = 1215 Å Aakash IIT-JEE . The wavelength of the second spectral line in the Balmer series of singly-ionized helium atom is (A) 1215 Å Answer (A) Hints : 1 1 1 R – 1 4 9 1 1 1 4R – 2 4 16 2 5 1 27 io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . The maximum number of electrons that can have principal quantum number. 1 ms . Hence no rearrangement in alkylchain is possible 23. Will have s PART–II : PHYSICS (D SECTION .: 011-47623417/23 Fax : 47623472 (9) . (B). Dwarka. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is Answer (5) Hints : Br 3-bromo-3-cyclopentylhexane Alc. (C) and (D) out of which ONLY ONE is correct. New Delhi-75 Ph. KOH follows E2 mechanism.

Sector-11.2 ohm Answer (B) Hints : (B) 10.6 v (D i i si o no s ka (C) a fA d hE u i on t a c a e rvic e lS td sL .Regd.5 m. Dwarka.IIT-JEE 2011 (Paper-1) 25.: 011-47623417/23 Fax : 47623472 .8 ohm 27.1 ohm 10. 4. The end corrections are 1 cm and 2 cm respectively for the ends A and B.5 kg is attached to the end of a string having length (L) 0. The galvanometer shows null point when tapping key is at 52 cm mark. A meter bridge is set-up as shown.6 ohm X 10 53 50 X = 10. The maximum possible value of angular velocity of ball (in radian/s) is L m (A) 9 Answer (D) Hints : Tsin = m2l sin max = Tmax ml (B) 18 (C) 27 (D) 36 T = 36 rad/s T sin 26. Office : Aakash Tower.) B (D) 11. The ball is rotated on a horizontal circular path about vertical axis. A 2 F capacitor is charged as shown in the figure. A ball of mass (m) 0. to determine an unknown resistance X using a standard 10 ohm resistor. New Delhi-75 Ph. The percentage of its stored energy dissipated after the switch S is turned to position 2 is 1 S 2 V 2 F 8 F (A) 0% (B) 20% (C) 75% (10) (D) 80% Aakash IIT-JEE . The determined value of X is 10 X A (A) 10. The maximum tension that the string can bear is 324 N. Plot No.

the work done in the process is (A) = 8.IIT-JEE 2011 (Paper-1) Answer (D) Hints : 1 U1 C1V 2 2 q = C1V V C1V q C1 C2 C1 C2 Uf V 5 1 (C1 C2 )V 2 2 1 C1V 2 10 U 100 80% Ui 28. 4. Plot No. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which reflects the sound waves.5 kHz io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL .6 liter of helium gas at STP is adiabatically compressed to 0.75 kHz (D) 7. Dwarka.50 kHz v v u f = f0 v u v 320 10 = 8 320 –10 33 = 8 21 (D 29. Sector-11.7 liter. The speed of sound in air is 320 m/s. New Delhi-75 Ph. The frequency of the siren heard by the car driver is (A) 8.) 9 RT1 8 (B) 3 RT1 2 (C) 15 RT1 8 (D) 9 RT1 2 Answer (A) Hints : T1V1( – 1) = T2V2( – 1) V T2 = T1 1 V2 = 4T1 { = 5/3} = no.: 011-47623417/23 Fax : 47623472 (11) .Regd. of moles = ext = –1 1 4 –R(T2 – T1) 1– 9 = RT1 8 Aakash IIT-JEE . Taking the initial temperature to be T1.50 kHz Answer (A) Hints : (B) 8. Office : Aakash Tower. 5.25 kHz (C) 7.

D) B = mgl mgl . a) (a. where E is a constant. (C) and (D) out of which sL e c i v ONE OR MORE may be correct. A 2 1 ml ml 2 mr 2 2 Hints : Aakash IIT-JEE . ) l Se a n A metal rod of length 'L' and mass 'm' is pivoted at one end. Office : Aakash Tower.II (Total Marks : 16) (Multiple Correct Answer Type) t d. Sector-11. (B). The rod-disc system performs sh displaced position. a) (0. 0. a.IIT-JEE 2011 (Paper-1) . SECTION . Consider two waysuthe is attached.: 011-47623417/23 Fax : 47623472 (12) . New Delhi-75 Ph. r 31.Regd. 4. a. 0) y 2E0 a 2 (C) E 0 a 2 (D) E0 a 2 2 1 A = d1 d 2 2 1 ˆ ˆ ˆ aiˆ – aj ˆ ak ˆ ai aj ak = 2 = E A E is constant = E0a2 This section contains 4 multiple choice questions. Each question has four choices (A). 0) x (A) 2E0a2 Answer (C) Hints : (B) (0. Consider an electric field E E0 x 0 figure) due to this field is z (a. ((case A): The disc is not free c d E to rotate about its center and (case B) the disc is free to rotate about its center. Dwarka. Which of the following statement(s) a SHM in vertical plane after being released from the same k is (are) true? f Aa o n i si o v i (D (A) Restoring torque in case A = Restoring torque in case B (B) Restoring torque in case A < Restoring torque in case B (C) Angular frequency for case A > Angular frequency for case B (D) Angular frequency for case A < Angular frequency for case B Answer (A. 0. A thin odisk of mass 'M' and radius 'R' (< L) is attached atidisc at its center to the free end of the rod. Plot No. The flux through the shaded area (as shown in the 30.

A composite block is made of slabs A. An electron and a proton are moving on straight parallel paths with same velocity. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB(< RA) are kept far apart and each is given charge '+Q'. D) Hints : mv qvB r mv r= qB me < mp re < rp te < tp 2 (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . D and E of different thermal conductivities (given in terms of a constant K) and sizes (given in terms of length. C. Office : Aakash Tower. Then inside (A) E A 0 (B) QA > QB A RB (C) R B A on surface on surface (D) E A EB Answer (A. Then in steady state 0 Heat 1L A 1L 3L 4L (A) Heat flow through A and E slabs are same (B) Heat flow through slab E is maximum 5L 6L B 3K E C 4K 6K D 5K 2K (C) Temperature difference across slab E is smallest (D) Heat flow through C = heat flow through B + heat flow through D Answer (A. Which of the following statement(s) is/are true? (A) They will never come out of the magnetic field region (B) They will come out travelling along parallel paths (C) They will come out at the same time (D) They will come out at different times Answer (B.) p e 34. B. Sector-11.Regd.: 011-47623417/23 Fax : 47623472 (13) . 4. D) Hints : After connection. VA = VB qA qB R R A B Aakash IIT-JEE . Now they are connected by a thin metal wire. D) (D ) Hints : 5K 4L2 K 4L2 3K 4L2 ( B ) 4K 8L2 (C ) (T2 – T1) (T1 – T0 ) = (T2 – T1) + (T2 – T1 ) + 4L L 4L 4L (C) = (B) + (D) 33. B. Dwarka. They enter a semi-infinite region of uniform magnetic field perpendicular to the velocity. C. C. Heat 'Q' flows only from left to right through the blocks. Plot No. L) as shown in the figure. New Delhi-75 Ph. All slabs are of same width.IIT-JEE 2011 (Paper-1) 32.

This is the explanation of high reflectivity of metals. Taking the electronic charge as ‘e’ and the permittivity as ‘0’. Let ‘N’ be the number density of free electrons. New Delhi-75 Ph. where these quantities are in proper SI units (A) 800 nm Answer (B) Hints : = 2c (B) 600 nm (C) 300 nm (D) 200 nm = 2c Ne2 m0 600 nm Aakash IIT-JEE . When the electrons are subjected to an electric field. all the free electrons are set to resonance together and all the energy is reflected. each of mass ‘m’. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons N 4 × 1027 m–3.) s 35. where a part of the energy is absorbed and a part of it is reflected. 35 and 36 A dense collection of equal number of electrons and positive ions is called neutral plasma. use dimensional ice analysis to determine the correct v r expression for p e (A) Ne m 0 Lt d (B) m 0 Ne Answer (C) Hints : ( m–3 C2 Nm–2 –2} {N = kg ms kg C2 = s –2 D io i vi s no ka a A f (C) sh Ne uc Ed m 2 na o i t a lS (D) 0 m 0 Ne 2 36. Each of these questions has four choices (A).IIT-JEE 2011 (Paper-1) EA (inside) = 0 qA > qB A q A RB 2 RB B qB RA 2 RA E A A RB EB B R A SECTION . To sustain the oscillations. Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. Office : Aakash Tower. As approaches p. If the electric field becomes zero.III (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs. Plot No. (C) and (D) out of which ONLY ONE is correct. Take 0 10–11 and m 10–30. the electrons begin to oscillate about the positive ions with a natural angular frequency ‘p’. Sector-11. which is called the plasma frequency. Dwarka. . they are displaced relatively away from the heavy positive ions.Regd. Based upon one of the paragraph 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. 4. a time varying electric field needs to be applied that has an angular frequency . (B).: 011-47623417/23 Fax : 47623472 (14) . Paragraph for Questions Nos.

4. For example. For such systems. Plot No. phase space is a plane in which position is plotted along horizontal axis and momentum is plotted along vertical axis. New Delhi-75 Ph. The phase space diagram is x(t) vs. 37 and 39 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. Then (A) E1 2E2 (C) E1 4E2 Answer (C) (B) E1 2E 2 (D) E1 16E2 Momentum E1 E2 2a a Position Aakash IIT-JEE .) Position Position Answer (D) Hints : p2 x 38. the two circles represent the same oscillator but for different initial conditions. The arrow on the curve indicates the time flow.: 011-47623417/23 Fax : 47623472 (15) . The phase space diagram for simple harmonic motion is a circle centered at the origin. In the figure. and E1 and E2 are the total mechanical energies respectively. Momentum Position 37. Sector-11. Here we consider some simple dynamical systems in one-dimension. The phase space diagram for a ball thrown vertically up from ground is Momentum Momentum (A) Position (B) Position Momentum (D (C) io i vi s no ka a A f (D) s d hE u na o i t a Momentum c e rvic e lS td sL . Office : Aakash Tower.IIT-JEE 2011 (Paper-1) Paragraph for Questions Nos. They are especially useful in studying the changes in motion as initial position and momentum are changed. Dwarka. We use the sign convention in which position or momentum upwards (or to right) is positive and downwards (or to left) is negative. the phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure. p(t) curve in this plane.Regd.

The coefficient of linear thermal expansion of the steel is 10–5/°C.: 011-47623417/23 Fax : 47623472 . Young's modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. Consider the spring-mass system. with the mass submerged in water. The answer to each question is a Single-digit integer.IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. The phase space diagram for one cycle of this system is Momentum Momentum (A) Position (B) Position Momentum (C) Position ( Answer (B) Hints : Because of viscosity of water. Assume that L >> diameter of the wire. Answer (3) D io i vi s no ka a A f s d hE (D) u i on t a c a e rvic e lS Momentum sL t d. The bubble corresponding to the correct answer is to be darkened in the ORS. Dwarka. ) Position Hints : F A y (16) Aakash IIT-JEE . as shown in the figure. Plot No. Steel wire of length 'L' at 40°C is suspended from the ceiling and then a mass 'm' is hung from its free end.IIT-JEE 2011 (Paper-1) Hints : p1 = 2p2 2 1 E2 p2 2 = 4 E1 p1 E1 = 4E2 39. momentum will not be same but less when it returns back. Sector-11. in kg is nearly. Then the value of 'm. The wire is cooled down from 40°C to 30°C to regain its original length 'L'. 4. New Delhi-75 Ph. SECTION . ranging from 0 to 9. Office : Aakash Tower. 40.Regd.

m 3 kg …(ii) 41. A boy is pushing a ring of mass 2 kg and radius 0. then N is i ce Answer (5) Hints : F1 = mg(sin – cos) F2 = mg(sin + cos) = 3F 1 1 = tan 2 10 = N = 5 v (D i i si o fA no a h k as Ed ti o u ca n e al S rv 43. Sector-11. New Delhi-75 Ph.5 m with a stick as shown in the figure. whose mean life is 109s. If we define N = 10 .: 011-47623417/23 Fax : 47623472 (17) . The activity of a freshly prepared radioactive sample is 1010 disintegrations per second. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficient of friction between the stick and the ring is (P/10). The stick applies a force of 2 N on the ring and rolls it without slipping with an acceleration of 0.IIT-JEE 2011 (Paper-1) mg y A …(i) After cooling 10 So. Dwarka.3 m/s2.Regd. A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of friction is . The mass (in mg) of the radioactive sample is Answer (1) Hints : dN – N –1010 dt 1 N 1010 mtotal = N × m1 = 1010 × 109 × 10–25 × 106mg = 1mg 42.) just prevent it from sliding . The value of P is Stick Ground Answer (4) Aakash IIT-JEE . Plot No. The force required to just push it up the inclined plane is 3 times the force required tdto L s down. 4. The mass of an atom of this radioisotope is 10–25 kg. Office : Aakash Tower.

4.5 kg are placed with their centers at the corners of a square of side 4 cm.2 P Using F Fx y 10 …(ii) Fx mg Fy Fs we get P 4 44. Sector-11.Regd. If the magnetic moment of the loop is N0I0 sin(300 t).005 ohm and of radius 0. A wire-loop of resistance 0. The moment of inertia of the system about the diagonal of the square is N × 10–4 kg-m2. Four solid spheres each of diameter 5 cm and mass 0. New Delhi-75 Ph. The current varies as I = I0cos(300 t) where I0 is constant.1 m is placed inside the tube with its axis coinciding with the axis of the tube.IIT-JEE 2011 (Paper-1) Hints : Fx 2 Fy 2 22 4 …(i) (Fx – Fy)r = 2mr 2 = 2mra Fx – Fy = 2ma = 1. Office : Aakash Tower. Plot No. Dwarka.: 011-47623417/23 Fax : 47623472 (18) .) B 0I L = B × r 2 (d / dt ) i Rs Rs I r 20 dI Rs L dt Magnetic moment = i × r 2 = 2 r 40 dI Rs L dt = 6 0 I0 sin(300t) Aakash IIT-JEE . then 'N' is Answer (6) Hints : I B 0 L (D io i vi s no ka a A f s d hEI u i on t a c a e rvic e lS td sL . A long circular tube of length 10 m and radius 0.3 m carries a current I along its curved surface as shown. then N is Answer (9) Hints : IAB = 2 2 md 5 4 2 2 md 2 ma2 = 9 × 10–4 kg–m2 + 2 5 4 2 45.

Four point charges. Sector-11. The system of charges and planar film are in equilibrium. Each question has 4 choices Se(A).Regd. New Delhi-75 Ph. Then N is Answer (3) Hints : (2 × a × ) × c 1/ N . kq 2 Kq 2 1 = 2 2 2 2a 2 a q 2 1 a3 = k 1 2 2 a3 q2 K = 1 q 2 3 a = K PART–III : MATHEMATICS SECTION . Let P { : sin cos (A) P Q and Q – P (C) P Q Answer (D) Hints : We have sin cos 2 cos vice td sL . (C) and (D) out of which ONLY l a ONE is correct. Office : Aakash Tower. on 47.: 011-47623417/23 Fax : 47623472 . (B).) 2 cos } and Q (D i vi s ti u ca d { : sin cos 2 sin } hE s a k (B) Q P f Aa o n (D) P = Q io be two sets. The q2 surface tension of the soap film is . Then sin ( 2 1)cos 1 2 1 sin cos ( 2 1)sin cos 2 sin sin cos 2 sin sin cos sin cos 2 cos and it shows that the given equations and sin cos 2 sin are identical.I (Total Marks : 21) (Single Correct Answer Type) r This section contains 7 multiple choice questions. are rigidly fixed at the four corners of a square planar soap film of side 'a'. 4. and a k where 'k' is a constant.IIT-JEE 2011 (Paper-1) 46. Plot No. Dwarka. each of +q. Hence their solution sets are equal P=Q (19) Aakash IIT-JEE .

y = 0 and x = 0 into two parts R1(0 x b) 1 . New Delhi-75 Ph.) a10 2a8 2a9 Answer (C) Hints : We observe that ( + ) (n –1 – n –1) = n – n + (n – 2 – n–2) 6an – 1 = an – 2an – 2 6 an 2 an 2 an 1 an 2an 2 . 0) According to the question.: 011-47623417/23 Fax : 47623472 (20) . o i on s i v = 0. 4. Le the straight line x = b divide the area enclosed by y = (1 – x)2. ( x 1) dx ( x 1) dx 4 2 2 0 b b 1 1 b 1 (b 1)3 1 3 ( b 1) 0 3 3 4 1 (b 1)3 8 b 1 1 2 b 1 49.Regd. Office : Aakash Tower. n 2 2an 1 3 Putting n = 10. Dwarka. then the value of Let and be the roots of x2 – 6x(– Di2 (A) 1 (B) 2 (C) 3 (D) 4 1 1 2 2 ka a A f s d hE u i on t a c a e rvic e lS td sL . Sector-11. with > . Plot No. we get a10 2a8 3 2a9 Aakash IIT-JEE . Then b equals and R2(b x 1) such that R1 R2 4 (A) 3 4 (B) 1 2 (C) 1 3 (D) 1 4 Answer (B) Hints : The given parabola y = (x – 1)2 is as shown below x=b (1. If an = n – n for n 1.IIT-JEE 2011 (Paper-1) 48.

Let (x0. the given line (0.0 3 1 . Dwarka. then the equation of L is (A) y 3 x 2 3 3 0 (C) (B) y 3 x 2 3 3 0 (D) 3x y 1. 4. A line making an angle 60° with 3x y 1 makes an angle 120° with x-axis and intersects at 3 the given line is either x-axis or different from x-axis.Regd. By observation it is clear that the straight line y 3x 2 3 3 0 is the required line.IIT-JEE 2011 (Paper-1) 50. A straight line L through the point (3. Office : Aakash Tower. If L also intersects 3y x 3 2 3 0 3y x 3 2 3 0 Answer (B) Hints : The question is too simple from the diagram.) m 3 or m 0 Since the line intersects x-axis also. 0 . Second Solution The equation of the line through (–3. hence m 0 consequently m 3 and the required line is y 2 3( x 3) y 3x 2 3 3 0 51. New Delhi-75 Ph. 1) 120° 60° 1 . – 2) is inclined at an angle 60° to the line the x-axis. – 2) may be written as y + 2 = m(x – 3) which will make 60° with 3x y 1 if tan60 m 3 1 3m 3 m 3 1 3m (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . y0) be the solution of the following equations (2 x )ln 2 (3 y )ln3 3ln x 2ln y Then x0 is (A) 1 6 (B) 1 3 (C) 1 2 (D) 6 Aakash IIT-JEE . Plot No.: 011-47623417/23 Fax : 47623472 (21) . Sector-11.

Plot No.Regd. Let a iˆ j i j k be three vectors. Sector-11. is given by 3 ˆ 3k ˆ (A) iˆ 3 j Answer (C) Hints : ˆ (B) 3iˆ 3 ˆ j k ˆ (C) 3iˆ ˆ j 3k ˆ (D) iˆ 3 ˆ j 3k ˆk ˆ and b iˆ j ˆk ˆ is given by A vector in the plane of a iˆ j a b ˆk ˆ ) (iˆ j ˆk ˆ) = (iˆ j ˆ = (1 )iˆ (1 ) ˆ j (1 )k Aakash IIT-JEE .: 011-47623417/23 Fax : 47623472 (22) . New Delhi-75 Ph. y = 3k 3a = 2k + 1 a = 0 and k + 1 = 0 2x = 3a x 1 2 ln 3 52. whose 1 projection on c is . The value of x sin x 2 sin x 2 sin(ln6 x 2 ) dx is ln 2 (A) 1 3 ln 4 2 (B) 1 3 ln 2 2 (C) ln 3 2 Answer (A) Hints : We have ln3 x sin x 2 sin x 2 sin(ln6 x 2 ) 1 = 2 ln 3 dx ln 2 ln 2 sin t i si o dt Div sin t sin(ln 6 t ) ( no ka a A f s d hE uc na o i t a lS ic e rv es . A vector in the plane of a and b .IIT-JEE 2011 (Paper-1) Answer (C) Hints : We have (2x )ln 2 (3y )ln 3 (ln2)log32x = (ln3)log33y log3y2x = log23 (2x) = 3a. Dwarka. b iˆ j ˆk ˆ and c 53. 4. say Also 3lnx = 2lny lnx = lny(log32) logyx = log32 x = 2k.) (D) Lt d 1 3 ln 6 2 1 1 1 3 [ln3 ln2)] ln 2 2 4 2 ˆ ˆ ˆ ˆk ˆ. (3y) = 2a. Office : Aakash Tower.

4. v 3iˆ ˆ j 3k SECTION .IIT-JEE 2011 (Paper-1) 1 ˆ is given to be whose projection on c iˆ ˆ . If f(x) is differentiable at x = 0. x. then (A) The equation of the hyperbola is 2 iv (xD 3 i si o 2 5 3 fA no h 1 be reciprocal to that of the ellipse x2 + 4y2 = 4.II (Total Marks : 16) (Multiple Correct Answer Type) This section contains 4 multiple choice questions. Dwarka. D) Hints : The equation of the given ellipse is (D) The equation of the hyperbola is x2 – 3y2 = 3 x2 y 2 1 4 1 Whose eccentricity e Foci of ellipse are 3. Each question has four choices (A). C) Hints : We have. 54. Aakash IIT-JEE . 0 . Office : Aakash Tower. Let f : be a function such that f(x + y) = f(x) + f(y). 55. Let the eccentricity of the hyperbola x2 y2 a2 b2 passes through a focus of the ellipse. (B). f(x + y) = f(x) + f(y) and f(x) is differentiable at x = 0 Clearly f(x) = kx serves our purpose and hence f(x) is continuous nafor all x and f (x) = k = constant. y . Plot No. If the hyperbola k as a E a du c ti o e rvic e lS td sL . Sector-11. 0) 2 (C) The eccentricity of the hyperbola is Answer (B.: 011-47623417/23 Fax : 47623472 (23) . then (A) f(x) is differentiable only in a finite interval containing zero (B) f(x) is continuous x (C) f(x) is constant x (D) f(x) is differentiable except at finitely many points Answer (B. 0 3 2 Eccentricity of hyperbola = Since given hyperbola x 2 2 3 y2 b2 1 passes through a2 3. New Delhi-75 Ph. (C) and (D) out of which ONE OR MORE may be correct.Regd. hence j k 3 (1 ) (1 ) (1 ) 3 1 3 –1=±1 = 0 or = 2 But = 0 does not serve our purpose ˆ when = 2.) y 1 (B) A focus of the hyperbola is (2. 0 and 3.

4. If PT denotes the transpose of P. 0).Regd. D) Hints : ˆ (B) ˆ j k ˆ (C) iˆ j ˆ (D) ˆ j k Required vector will be parallel or antiparallel to the vectors iˆ jˆ kˆ (iˆ jˆ 2kˆ) (iˆ 2 jˆ kˆ ) ˆ 2k ˆ 4 iˆ 2 j ˆk ˆ 4 iˆ j ˆ 4 ˆ j 4k Aakash IIT-JEE . the equation of the hyperbola is x2 y 2 1 3 1 x2 – 3y2 = 3 Foci of the hyperbola are (± 2. New Delhi-75 Ph. Sector-11. then M 2N 2(M TN) –1(MN –1) T is equal to (A) M 2 (B) – N 2 (C) – M 2 (D) M N Answer (Statement of the question is incorrect) Hints : Every skew-symmetric matrix of odd order is always singular and inverse of a singular matrix does not exist. Office : Aakash Tower. then M 2N 2 (M TN)–1(MN –1) T = M 2N 2 (– MN)–1((N – 1) TM T) = – M 2NM –1(– N –1(– M)) = – M 2 ˆ and iˆ 2 ˆ ˆ . 56. The statement of the given question seems incorrect. and perpendicular to the vector iˆ j ˆk ˆ 57.: 011-47623417/23 Fax : 47623472 (24) .) If there may exist a non-singular skew-symmetric matrix (which does not exist). Plot No. If the matrix is given to be symmetric and non-singular. then MT=M (MN) T = MN (as MN = NM given) M 2 N 2(M T N) –1 (MN –1)T = M 2N 2(M N)–1((NT)–1 M T) –1M) = M 2N 2(N –1 M –1)(N a ka –1M = M 2NM –1N o no =M 2 v (D i i si fA s d hE u i on t a c a e rvic e lS td sL . Let M and N be two 3 × 3 non-singular skew-symmetric matrices such that MN = NM. Dwarka. The vector(s) which is/are coplanar with vectors iˆ ˆ j 2k j k is/are ˆ (A) ˆ j k Answer (A.IIT-JEE 2011 (Paper-1) Hence 3 a 2 0 b2 1 a2 = 3 b2 = a2(e2 – 1) 4 2 1 b 3 1 3 Thus.

III (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs. if tail appears then 2 balls are drawn at random from U1 and put into U2. the probability that head appeared on the coin is (A) 17 23 (B) 11 23 (C) 15 23 (D) 12 23 Answer (D) Hints : Using Baye's theorem. New Delhi-75 Ph.: 011-47623417/23 Fax : 47623472 (25) . 58.IIT-JEE 2011 (Paper-1) SECTION . Plot No. Given that the drawn ball from U2 is white. (B). 3 5 U 1 1 2 H 2 5 3C2 1 T 5C2 2 U1 3C W R WW 2C2 5C2 Probability of drawing white ball from U2 = 1 3 1 2 1 1 3 1 3 2 1 1 s 1 h 1 1 ka 2 5 2 5 2 2 10 2 5 3 2Aa 10 3 1. If head appears then 1 ball is drawn at random from U1 and put into U2. A fair coin is tossed. 4. Dwarka. Office : Aakash Tower.) 3 1 3 1 1 = 10 10 20 5 60 = = 18 6 9 12 1 60 (D i v n i si o of 23 30 59. However. Paragraph for Questions Nos. Based upon one of the paragraph 2 multiple choice questions and based upon the second paragraph 3 multiple choice questions have to be answered. (C) and (D) out of which ONLY ONE is correct. and U2 contains only 1 white ball. The probability of the drawn ball from U2 being white is (A) 13 30 23 30 19 30 11 30 (B) (C) (D) Answer (B) Hints : We have the following tree-diagram under given conditions. Now 1 ball is drawn at random from U2.Regd. 2C1 5C2 WR E a du c RR na ti o e rvic e lS td sL . Sector-11. 58 and 59 Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls. 1 3 1 2 1 2 5 2 5 2 Required probability = 23 30 4 10 12 = 23 = 23 30 Aakash IIT-JEE . Each of these questions has four choices (A).

New Delhi-75 Ph. Let b = 6. 3 a 1 b 3 c = 3 2 1 12 (D 14 i on ivis3 o ka a A f s d hE u i on t a c a e rvic e lS td sL . Dwarka. Sector-11. with reference to (E). then the value of 7a + b + c is (A) 0 Answer (D) Hints : From the given condition. 2a + b + c = 1 a=1 7a + b + c = 6a + (a + b + c) = 6 (B) 12 (C) 7 (D) 6 61. b and c be three real numbers satisfying [a b 1 c] 8 7 9 2 3 7 7 [0 7 0 0] . If and are the roots of the quadratic equation ax2 + bx + c = 0. b. with a and c satisfying (E).Regd. Let be a solution of x3 – 1 = 0 with Im() > 0..: 011-47623417/23 Fax : 47623472 (26) . c = –7 Aakash IIT-JEE . 8b + 7c = –2 b = 12 and c = –14 Thus. Office : Aakash Tower. c). If a = 2 with b and c satisfying (E). Plot No. If the point P(a. then 1 1 n 0 n (A) 6 Answer (B) Hints : (B) 7 (C) 6 7 (D) For b = 6 a + c = –6 a + 7c = –48 a + c = –6 whence a = 1.) (D) –3 = 1 + 3 + 32 =1–3 = –2 62..IIT-JEE 2011 (Paper-1) Paragraph for Questions Nos. a + 8b + 7c = 0 9a + 2b + 3c = 0 7a + 7b + 7c = 0 a+ b+c=0 Also. lies on the plane 2x + y + z = 1. then the value of 3 a 1 b 3 c is equal to (B) 2 (C) 3 (A) –2 Answer (A) Hints : When a = 2 b + c = –2 Also. 4. 60 and 62 Let a.(E) 60.

Plot No. hence + = –6. The bubble corresponding to the correct answer is to be darkened in the ORS.F. ) [2. The answer to each of the questions is a single-digit integer.. New Delhi-75 Ph. | z – 3 – 2i | 2 | 2z – 6 – 4i | 4 4 | (2z – 6 + 5i) – 9i | Aakash IIT-JEE . = e e Solution of the given equation is f (x) 1 x (D i vi o ka a A f s d hE 1 dx u i on t a c a e rvic e lS td sL . then 63. Dwarka. = –7 1 1 6 7 1 1 6 6 1 1 . whose sio I. Sector-11..: 011-47623417/23 Fax : 47623472 (27) . ) be a differentiable function such that f(1) = 2. then the minimum value of | 2z – 6 + 5i | is Answer (5) Hints : From the given condition.IIT-JEE 2011 (Paper-1) and are roots of the given equation ax 2 + bx + c = 0. Let f : [1. we have 6 f ( t ) dt 3 x f ( x ) x 3 1 x 6f(x) = 3f(x) + 3xf (x) – xf (x) – f(x) = x2 3x 2 f ( x ) 1 f (x) x x ln x n x which is linear differential equation.. for x = 1. Office : Aakash Tower. x f ( t ) dt 3 x f ( x ) x 3 for all x 1. 6 7 7 7 n 0 1 7 n 2 SECTION ..) 1 x x x dx c c=1 1 f(x) = x 2 + cx Initially. If z is any complex number satisfying | z – 3 – 2i | 2.IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. If 6 1 the value of f(2) is Answer (6) Hints : From the given condition. f(1) = 2 f(x) = x 2 + x f(2) = 4 + 2 = 6 64..Regd. ranging from 0 to 9. 4.

a100 be an arithmetic progression with a1 = 3 and a . Plot No. ar(ABC) = 2(arPQR) 1 = 22 1 2 2 Aakash IIT-JEE . Dwarka.. du E Consider the parabola = 8x... and o f2 be the area of the triangle formed by drawing tangents at P and n 2 io vis 1 i D ( Then at the end points of the latus rectum. we get k = 25 30 – 5d = 150 – 25d 20d = 120 d=6 a2 = 9 66. 1 p 100 ... 4. on comparing the coefficients of like terms. then a2 is Sn a1 = 3. 2 2 B (2. + ap. Let a1. –4) C Clearly. let m = 5n.. 1 p 100 By the given condition.: 011-47623417/23 Fax : 47623472 (28) . Sector-11.Regd. New Delhi-75 Ph. which is independent of m and n n 6 (n 1) d (m – 1)d) = k(6 + (n – 1)d) 30 + 25nd – 5d = 6k + nkd – kd which is independent of n Hence. If Answer (9) Hints : We have. Sp = a1 + a2 + a3 + . Office : Aakash Tower. 2 on the parabola. .) Answer (2) Hints : R A P 1. Sm Sn 5(6 + m 6 (m 1) d k .IIT-JEE 2011 (Paper-1) || 9i | – | 2z – 6 + 5i || 4 9 – | 2z – 6 + 5i | | 2z – 6 + 5i | 5 Minimum value of | 2z – 6 + 5i | is = 5 Sp 65. 4) y2 = 8x Q (2. For any integer n i i 1 p with 1 n 20. a2. a3. Let 1 be the area of ashthe triangle formed by the end points of its latus rectum k a 1 A and the point P . Sm does not depend on n. is y2 2 i on t a c a e rvic e lS td sL ...

1 1 1 2 3 sin sin sin n n n (D i v n i si o of Let 2 3 3 2 sin sin sin sin sin sin n n n n n n 5 2 4 3 cos cos cos cos cos n n n n n n 9 5 sin sin sin sin 2n 2n 2n n 9 5 sin sin 2n 2n 9 5 (2k 1).: 011-47623417/23 Fax : 47623472 (29) . a 5 a 4 3a 3 1 a8 a10 8 5 4 9 a a a 1 a8 a10 8 a–5 + a–4 + 3a–3 + 1 + a8 + a10 8 min(a–5 + a–4 + 3a–3 + 1 + a8 + a10) = 8 1 a ti o 1 1 c 69. New Delhi-75 Ph. 1. Dwarka. The positive integer value of n > 3 satisfying the equation is u d 2 3 E sin sin sin h n n n k as Answer (7) a A na e rvic e lS td sL . 3a–3.Regd. sin f() = sin tan1 cos 2 x tan1 x sin . Let f () . say 2n 7 n . Sector-11. 4.) Hints : According to the question. a–4. Plot No.IIT-JEE 2011 (Paper-1) sin d (f ()) is sin tan1 67. a8 and a10 with a > 0 is Answer (8) Hints : For a > 0. = sin 1 2x 2 x = 1 x2 sin = = tan cos df () 1 d tan 68. The minimum value of the sum of real numbers a–5. k is an integer 2k 1 us put k = 0 Hence n = 7 Aakash IIT-JEE . where . Then the value of cos 2 4 4 d (tan ) Answer (1) Hints : We have. Office : Aakash Tower.

Solutions to IIT-JEE 2011 PAPER . . There are no negative marks in this section. There are no no negative mark in this section.DATE : 10/04/2011 Regd. Office : Aakash Tower. New Delhi-110075 Ph.-4. minus one (–1) mark will be awarded. for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. each question in this section carries a maximum of 8 marks. The question paper consists of 3 parts (Chemistry. There are no negative marks in this section. Each part consists of four sections. In Section I (Total Marks : 24). Thus.8) Max. Plot No. MLU. 3.2 (Code . for each question you will be awarded 2 marks for each row in which you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY And zero marks otherwise. In Section II (Total Marks : 16). Physics and Mathematics). for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. Marks: 240 Instructions : 1. 5. Sec-11. Dwarka. 4. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. In all other cases. In Section III (Total Marks : 24). 2.: 011-47623456 Fax : 011-47623472 Time : 3 hrs. In Section IV (Total Marks : 16).

N. which is cyclic form of an aldohexose na o i t 2. 4. are u ca dIII E (A) II. The following carbohydrate is H HO HO H (A) A ketohexose (C) An -furanose Answer (B) OH H O H HO OH H (B) An aldohexose (D) An -pyranose OH O Hints : HO HO OH HO — D — Glucopyranose. Oxidation states of the metal in the minerals haematite and magnetite. N (C) L. K3[Fe(CN)6](K). (B). Office : Aakash Tower. Fe2O3 Fe3O4 Fe+3 Fe+2 and Fe+3 e rvic e lS td sL . L. M. K2[Pt(CN)4](O) and [Zn(H2O)6](NO3)2(P) the diamagnetic complexes are (A) K. Sector-11. III in magnetite ak (D) III in haematite and II. M. respectively. O Answer (C) Hints : [Co(NH3)6]Cl3 Na3[Co(OX)3] K2[Pt(CN)4] [Zn(H2O)6](NO3)2 d2sp3 d2sp3 dsp2 sp3d2 diamagnetic diamagnetic diamagnetic diamagnetic Aakash IIT-JEE . M.: 011-47623417/23 Fax : 47623472 (2) . P (B) K. O. Dwarka. Plot No. M.IIT-JEE 2011 (Paper-2) PART–I : CHEMISTRY SECTION .Regd. 1. III in magnetite A f o Answer (D) i on s i v Hints : (D i Haematite Magnetite 3. O. Each question has 4 choices (A).I (Total Marks : 21) (Single Correct Answer Type) This section contains 8 multiple choice questions. III in haematite and III in magnetite (B) II. (C) and (D) out of which ONLY ONE is correct. [Ni(H2O)6]Cl2(N). in haematite and II in magnetite h s a (C) II in haematite and II.) Among the following complexes (K – P). [Co(NH3)6]Cl3(L). Na3[Co(oxalate)3]–3(M). New Delhi-75 Ph. P (D) L.

7 × 10–2 of (D) –1. E° = 1. the cell potential at 25°C is (A) 1. Ni2+.0591 10 6 log 4 1013 0. New Delhi-75 Ph. P(O2) = 0.86 K kg mol ) is sh (A) –2.0591 log107 4 6.86 × 100 1000 Tf 4 1.IIT-JEE 2011 (Paper-2) 4.67 V 2 At [Fe2+] = 10–3 M. HCl followed by addition to an alkaline solution of -naphthol is N(CH3)2 NHCH3 (A) (B) NH2 (C) CH2NH2 H3C (D) Aakash IIT-JEE .1 d guof K3[Fe(CN) 6] (Mol.7 × 10–3 0. Dwarka.: 011-47623417/23 Fax : 47623472 (3) .1 atm and pH = 3.0591 1.67 1. Wt.3 × 10–2 (C) –5. 5.77 V (D) 1.67 7 1.0591 [Fe2 ]2 log 4 pO2 [H ]4 (B) 1.57 4 i on t a c a e rvic e lS td sL .67 1.2 × 10–2 Hints : 0. 329) in 100 g water E –1 (Kf = 1. Passing H2S gas into a mixture of Mn2+. The freezing point (in °C) of a solution containing 0. 4.023 329 100 7.87 V Answer (D) Ecell 1.47 V (C) 1.86 0. Plot No.67 0.1 1000 0. Sector-11.1 329 Tf – Tf = 0 – Tf = 4 × 1.67 0. the one that would form a brilliant colored dye on treatment with NaNO2 in dil. Office : Aakash Tower.Regd.1 (103 )4 0.57 V Hints : 1. Amongst the compounds given. Cu2+ and Hg2+ ions in an acidified aqueous solution precipitates (A) CuS and HgS (C) MnS and NiS (B) MnS and CuS (D) NiS and HgS Answer (A) Hints : Cu+2 and Hg+2 belong with 2nd group of basic radical.) Answer (A) vi s (D i i on ka a A (B) –5. 2 2H O(l) 2Fe(aq) Consider the following cell reaction: 2Fe(s) O 2(g) 4H(aq) .0581 (103 )2 log 4 0.

C and D diamine is obtained which will give polyamide with dicarboxylic acid. Each question has four choices (A). D) Hints : (B) X = CONH2. Aakash IIT-JEE . The correct functional group X and the reagent/reaction conditions Y in the following scheme are na o i t CH2 – R ca O O du E An acetal ash ak A f o on i s i SECTION .) X – (CH2)4 – X (i) Y O O condensation polymer (ii) C – (CH2)4 – C HO OH Heat (A) X = COOCH3. 9. C.Regd. (B). Y = H2/Ni/Heat (D) X = CN. Plot No. Diol will form polyester with dicarboxylic acid. 4. which will react with -naphthol to give an azo dye. The major product of the following reaction is 8. Sector-11.IIT-JEE 2011 (Paper-2) Answer (C) Hints : HO NH2 NaNO /HCl 2 H3C H3C N N – Cl H3C N N OH Brilliant coloured dye Note : Only primary aromatic amines will give benzenediazonium chloride chloride at 0°C. Y = H2/Ni/Heat X (CH2)4 X when x = –COO Me and Y = H2/Ni will give diol. Office : Aakash Tower. (C) and (D) out of which ONE OR MORE may be correct. New Delhi-75 Ph. B. Y = Br2/NaOH Answer (A.II (Total Marks : 16) v (D i e rvic e lS td sL . Dwarka. Y = H2/Ni/Heat (C) X = CONH2. (A) A hemiacetal (C) An ether Answer (B) O 2 RCH OH H (anhydrous) (B) An acetal (D) An ester H – H Hints : :O – CH2 – R : O O –H O O H CH2 R (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions.: 011-47623417/23 Fax : 47623472 (4) . In B.

303 (3 2 0. Sector-11.Regd.303 log250 k k 2. C.4 102 Α 8 0. New Delhi-75 Ph. Office : Aakash Tower. 4. D) Hints : t 2. Dwarka. Plot No. The equilibrium 2CuI CuO CuII in aqueous medium kas at 25°C shifts towards the left in the presence of (A) NO3 MnO 4– Mn2 acidic (B) Cl– Answer (B. The volume (in mL) of 0. The answer to each of the questions is a Single-digit integer. 13. 2N2O5 (g) 4NO2 (g) O2 (g) (A) The concentration of the reactant decreases exponentially with time (B) The half life of the reaction decreases with increasing temperature (C) The half life of the reaction depends on the initial concentration of the reactant (D) The reaction proceeds to 99. D) Hints : MnO4 MnO2 aq (B) 5 electrons in neutral medium (D) 5 electrons in acidic medium n transfer respecitvely. B.1 × V = 2 × 0.693 2. ranging from 0 to 9.IIT-JEE 2011 (Paper-2) 10.) SCN– (D) CN– SECTION .1 M AgNO3 required for complete precipitation of chloride ions present in 30 mL of 0.01 M solution of [Cr(H2O)5Cl]Cl2.: 011-47623417/23 Fax : 47623472 (5) . The bubble corresponding to the correct answer is to be darkened in the ORS. Reduction of the metal centre in aqueous permanganate ion involves (A) 3 electrons in neutral medium (C) 3 electrons in alkaline medium Answer (A.303 A log m 0.6% completion in eight half-life duration Answer (A.III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. Therefore in aqueous and in acidic mediums 3 and 5 electrons tiowill 12. as silver chloride is close to Answer (6) Hints : Applying equation N1V1 = N2V2 0. D) (D i v i si o f Aa o (C) n d hE u ca a e rvic e lS td sL .3010) 11.303log 103 4 2.01 × 30 V 2 30 10 6 100 1 Aakash IIT-JEE . For the first order reaction.

is CH3 C CH3CH2 Answer (8) Hints : H CH2CH3 1 Cl2 Cl * Two + Stereoisomers Total Number = 8 Cl (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . P4O10. The value of "x" is. The number of hexagonal faces that are present in truncated octahedron is Answer (8) Hints : Truncated octahedron contain 14 faces out of that eight are hexagonal and six are square. Office : Aakash Tower. H2SO4. 4. Among the following. H2O. Answer (7) Hints : AgCl Ag Cl x x y Aakash IIT-JEE . 15. Answer (5) Hints : O2. CO2. H2O. H2SO4 and P4O10 convert PCl5 to POCl3. the number of compounds than can react with PCl5 to give POCl3 is O2. SO2.6 × 10–10].: 011-47623417/23 Fax : 47623472 (6) .) Cl * * Four + Stereoisomers One + Cl One 17.1 mol of CuCl [KSP(CuCl) = 1. In 1 L saturated solution of AgCl[KSP(AgCl) = 1. SO2. 18.6 × 10–x.0 × 10–6] is added. Plot No. Dwarka. The maximum number of isomers (including stereoisomers) that are possible monochlorination of the following compound.Regd.IIT-JEE 2011 (Paper-2) 14. New Delhi-75 Ph. The total number of contributing structures showing hyperconjugation (involving C-H bonds) for the following carbocation is H3C CH2CH3 + Answer (7) Hints : H3C + CH2CH3 + 6 more hyperconjugative structures Total number of hyperconjugative structures = 7 16. The resultant concentration of Ag+ in the solution is 1. 0. Sector-11.

Dwarka.(iii) x = 1.6 × 10–4 + 1) y = 10–3 x = 1.6 × 10–7 SECTION .6 10 –4 y(1.6 10–4 x y .6 10–4 y y) 10–6 = y2(1..IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Plot No.(ii) From equation (i) and (ii) K sp1 K sp2 1. q. Sector-11. against statement B. Office : Aakash Tower. New Delhi-75 Ph. For example. s and t) in Column II.6 × 10–10 = x(x + y) CuCl Cu Cl y yx .(i) K sp2 1 10 –6 y(x y) . Each Question has four statements (A..: 011-47623417/23 Fax : 47623472 .. r. if for a given question. darken the bubble corresponding ..6 × 10–4 y K sp1 1. then for that particular question. statement B matches with the statements given in q are r.IIT-JEE 2011 (Paper-2) K sp1 = 1.) to q and r in the ORS. C and D) given in Column I and five statements (p.6 × 10–7 [Ag+] = x = 1. B.Regd. Match the reactions in Column-I with appropriate types of steps/reactive intermediate i ce v r as given in Column-II e Column I Lt d H3C O (A) O aq NaOH (D i vi s o i on fA sh a ka O E du c na o i t a lS Column II (p) Nucleophilic substitution O (B) O CH2CH2CH2Cl CH3Mgl CH3 (q) Electrophilic substitution O CH2CH2CH218OH H2SO4 18 O (C) (r) H2SO4 Dehydration CH2CH2CH2C(CH3)2 (D) OH H3C CH3 (s) (t) (7) Nucleophilic addition Carbanion Aakash IIT-JEE .. 4.6 10 –10 1.. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. s involved in these reactions 19.

C(r. s. Dwarka.IIT-JEE 2011 (Paper-2) Answer : A(r. r) H CH2 O Hints : A. t). O OH H2C O O O Nucleophilic addition O Carbanion O Dehydration –H2O OH O HO – H O B. Sector-11. solid) (D) P( white. Cl CH3MgBr Carbanion O CH3 Cl Nucleophilic substitution O CH3 Nucleophilic addition H . D(q. 4. s.. Plot No. Column I (A) CO 2 (s) CO2 (g) (B) CaCO3 (s) CaO(s) CO2 (g) (C) 2H H2 (g) (p) (q) (r) (s) (t) Column II Phase transition Allotropic change H is positive S is positive S is negative P(red. B(p. i on of A sh a ka E 18 O OH Me Me +H Dehydration Electrophilic substitution H 20. t). .: 011-47623417/23 Fax : 47623472 (8) Dehydration du i on t a c a e rvic e lS H 18 Lt d sO .) . solid) I Aakash IIT-JEE .O . Match the transformations in Column-I with appropriate options in Column-II. New Delhi-75 Ph. H–O C. O H–O Nucleophilic addition 18 H –H +H H H–O O vi s (D i D. s).Regd. Office : Aakash Tower.

4. D(p. B(p.IIT-JEE 2011 (Paper-2) Answer : A(p. Aakash IIT-JEE . If now a uniform electric field E is switched-on as shown. S is –ve because no. 0.Regd. (B). C(p. Mean position will shift to x n 22. s). The reflected v i (R) and transmitted (T) intensities. k o ka a A f s d hE u i on t a c a e rvic e lS td sL . Office : Aakash Tower. During phase transition from solid to liquid or gas. A wooden block performs SHM on a frictionless surface with frequency. then the SHM of the block will be E +Q (A) Of the same frequency and with shifted mean position (B) Of the same frequency and with the same mean position (C) Of changed frequency and with shifted mean position (D) Of changed frequency and with the same mean position Answer (A) Hints : Frequency does not depend on constant external force. are plotted. In 2H PART–II : PHYSICS SECTION . Dwarka. only reflection takes place. t) Hints : Phase is the part which is physically and chemically uniform throughout.: 011-47623417/23 Fax : 47623472 (9) . r. The correct sketch is 100% Intensity T R 90° (B) qE . New Delhi-75 Ph. t). s). When > C. r.I (Total Marks : 24) (Single Correct Answer Type) This section contains 7 multiple choice questions. A light ray travelling in glass medium is incident isio on glass-air interface at an angle of indcidence . Sector-11. both (D as function of . of entities decreases. Plot No.) 100% Intensity T R 90° (A) 0 0 100% Intensity T R 90° (D) 100% Intensity T R 90° (C) 0 0 Answer (C) Hints : When < C partial transmission and reflection will occur. H2. 21. (C) and (D) out of which ONLY ONE is correct. The block carries a charge +Q on its surface. S = +ve. q. Each question has 4 choices (A).

The spiral has inner radius ‘a’ and outer radius ‘b’. Dwarka. 4. The Z-component of the magnetic field at the center of the spiral is Y I a b X (A) 0 NI b ln 2(b a ) a (B) 0 NI ba ln 2(b a ) b a (C) 0 NI b ln 2b a (D) 0 NI b a ln 2b ba Answer (A) Hints : dB 0dNI NI dr 0 2r (b – a ) r 25. 5 6 (D) A. An object of mass m is ejected from the satellite such that it just escapes from the gravitational pull of the earth. New Delhi-75 Ph. At the time of its ejection.) (B) A.IIT-JEE 2011 (Paper-2) 23. 4 3 (C) 3 A.: 011-47623417/23 Fax : 47623472 (10) . A point mass is subjected to two simultaneous sinusoidal displacements in x-direction. Plot No. Sector-11. Adding a third s sinusoidal displacement x3(t ) = B sin(t + ) brings the mass to a o i 3 vi i D complete rest. A long insulated copper wire is closely wound as a spiral of ‘N’ turns. Office : Aakash Tower.Regd. 3 Answer (B) Hints : See the phasor A A 2 /3 /3 t A + /3 C Aakash IIT-JEE . The spiral lies in the X-Y plane and a steady current ‘I ’ flows through the wire. 3 4 Aa d hE u i on t a c a e rvic e lS td sL . 24. x1(t) = A sin t and k as NI b ln B 0 (b – a ) a f 2 no x2 (t ) A sin t . A satellite is moving with a constant speed V in a circular orbit about the earth. the kinetic energy of the object is (A) 1 mV 2 2 (B) mV2 (C) 3 mV 2 2 (D) 2 mV2 Answer (B) Hints : To escape speed Ve 2Vorbital . The values of B and( are (A) 2A.

0.9% (B) 2. t d.01 kg. Sector-11. Office : Aakash Tower.5 mm and there are 50 divisions on the circular scale. 27. The reading on the main scale is 2. Plot No. The ball hits the ground at a distance of 20 m and the bullet at a distance of 100 m from the foot of the post. A bullet of mass 0.2 × 20 + 0.Regd. ) The initial velocity V of the bullet is L es V m/s rvic (D (A) 250 m/s Answer (D) Hints : (B) 250 2 m/s io i vi s 0 no ka a A f s d hE u ca al ti o n Se 20 (C) 400 m/s 100 (D) 500 m/s t 2h 1s g Vball = 20 m/s and Vbullet = 100 m/s By conservation of linear momentum. The diameter of the ball is measured with a screw gauge. After the collision.IIT-JEE 2011 (Paper-2) 26. the ball and bullet travel independently. New Delhi-75 Ph.01 V = 0.: 011-47623417/23 Fax : 47623472 . the relative percentage error in the density is (A) 0. Dwarka.01 × 100 V = 500 m/s 28. 4.5 mm and that on the circular scale is 20 divisions. traveling with a velocity V m/s in a horizontal direction. If the measured mass of the ball has a relative error of 2%.1% (11) (D) 4. hits the centre of the ball. A ball of mass 0.2% Aakash IIT-JEE . The density of a solid ball is to be determined in an experiment.4% (C) 3. whose pitch is 0.2 kg rests on a vertical post of height 5 m. Which of the field patterns given below is valid for electric field as well as for magnetic field? (A) (B) (C) (D) Answer (C) Hints : Induced electric field and magnetic field can form closed loops.

Plot No. Sector-11. 29. (C) and (D) out of which ONE OR MORE may be correct. C) Hints : The data is incomplete.7 = 2% + 1.II (Total Marks : 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions.70 d m v d m 3 r d m r 2% 3 1 2.1 kg. Office : Aakash Tower. (B).75 D io i vi s 20 m/s no ka a A f 10 m/s h s Ed u i on t a c a e rvic e lS 1 m/s (A) The ring has pure rotation about its stationary CM (B) The ring comes to a complete stop (C) Friction between the ring and the ground is to the left (D) There is no friction between the ring and the ground Answer (A.01 mm 50 0.: 011-47623417/23 Fax : 47623472 (12) .) hits the ring at a height of L 0.IIT-JEE 2011 (Paper-2) Answer (C) Hints : r = least count = r 2.01 r 2. td.5 0.75 m and goes vertically up with velocity 10 m/s. A small ball of mass 0.5 m is rolling without slipping on a horizontal plane with velocity 1 m/s.5 mm 20 0. New Delhi-75 Ph.Regd. Immediately after the collision s ( m 0. Each question has four choices (A). A thin ring of mass 2 kg and radius 0. Dwarka.5 2.70 mm 50 r 0.5 mm 0. moving with velocity 20 m/s in the opposite direction. 4. if we assume that the friction is not impulsive during impact then the solution is as follows 2 = –2 × v – (–2 × 1) v=0 Thus centre of mass becomes stationary Aakash IIT-JEE .20 mm 2.11% SECTION .11% = 3.

5) 2 (0.Regd.5 + 0.5 = 0. Plot No. (A) when C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. 4. B. Sector-11.5 – 1 4 0.5 instead of r –2.732 – 0.5) 2 2 2 1. Dwarka. Office : Aakash Tower. 1 Ns 3 1 1 2 1 – 2 (0. C) Aakash IIT-JEE . New Delhi-75 Ph. then the Gausss law will still be valid (B) The Gauss law can be used to calculate the field distribution around an electric dipole.) as shown in the figure with a tension in the string. (D io i vi s no k as a fA B d hE uc na o i t a lS ic e rv es (B) dB > dF (D) dA + dB = 2dF vdF g vd A g vdB g vdF g Also. The arrangement is possible only if Lt d A (A) dA < dF (C) dA > dF Answer (A. Which of the following statement(s) is/are correct? (A) If the electric field due to a point charge varies as r –2. The solid spheres A and B of equals volume but of different densities dA and dB are connected by a string.: 011-47623417/23 Fax : 47623472 (13) . The y are fully immersed in a fluid of density dF. A series R-C circuit is connected to AC voltage source. Which of the following is/are true? A B (A) IR IR A B (C) VC VC A B (B) IR IR A B (D) VC VC Answer (B.5 0.e. The current IR through the resistor and voltage VC across the capacitor are compared in the two cases. They get arranged into an equilibrium state . anticlockwise) 1 – 0. D) Hints : For string to be taught. then the sign of the two charges is the same (D) The work done by the external force in moving a unit positive charge from point A at potential VA to point B at potential VB is (VB – VA) Answer (C) Hints : + + 31.5 2 Ns v 30. (C) If he electric field between two point charges is zero somewhere.IIT-JEE 2011 (Paper-2) Taking angular impulse about centre of mass of ring. vd F g vdF g vd A g vd B g 32. Consider two cases.433 >0 (i.

An impulse is given to the block as shown in the figure.0 = 7/4 = 4/3 Answer (2) Aakash IIT-JEE . The location of its image is at 'x' cm above the bottom of the tank.18 v 2 0. Office : Aakash Tower.3v 12 10 2 v 40 102 0. SECTION . New Delhi-75 Ph. The coefficient of friction between the block and the floor is 0. Then N is Answer (4) Hints : 1 1 mv 2 mgx kx 2 2 2 1 1 0. Oil of refractive index lies on water making a convex 3 4 surface of radius of curvature 'R = 6 cm' as shown. Initially the block is at rest and the spring is un-stretched.4 m/s 34. Dwarka. 33. The initial velocity of the block in m/s is V = N/10.Regd. Then 'x' is S R = 6 cm = 1.9v 2 144 104 0. The answer to each of the questions is a Single-digit integer. Consider oil to act as a thin lens. Water (with refractive index = (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . Plot No.III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. The block slides a distance of 0.: 011-47623417/23 Fax : 47623472 (14) .18 kg is attached to a spring of force-constant 2 N/m. current is less.) 4 7 ) in a tank is 18 cm deep.06 2 (0. Sector-11.06 m and comes to rest for the first time. An object 'S' is placed 24 cm above water surface. A block of mass 0. The bubble corresponding to the correct answer is to be darkened in the ORS. 4. ranging from 0 to 9.06)2 2 2 108 104 36 104 0.18 10 0.IIT-JEE 2011 (Paper-2) Hints : XC XC 1 C 1 C C = KC When XC is more.1. but VC is more.1 0.

A silver sphere of radius 1 cm and work function 4.7 eV is suspended from an insulting thread in free-space. A series R-C combination is connected to an AC voltage of angular frequency = 500 radian/s. The value of Z is Answer (7) Hints : hc ev 0 v0 ne 40 r 1240 xne eV 4.5 102 9 1.7eV 200 40 r 6. Plot No. It is under continuous illumination of 200 nm wavelength light. New Delhi-75 Ph. As photoelectrons are emitted.: 011-47623417/23 Fax : 47623472 (15) .2 – 4.25 R R2 + XC2 = 1. The maximum number of photoelectrons emitted from the sphere is A × 10Z (where 1 < A < 10).25 .7 n 9 199 eV 10 –19 n 1. 500 Aakash IIT-JEE .Regd. 4.IIT-JEE 2011 (Paper-2) S 24 cm Hints : 7/4 I 18 cm 4/3 x 7 1 4/3 1 4 (18 x ) 24 6 4 1 3 1 – 3(18 – x ) 24 24 12 48 54 3 x 3x = 6 x = 2 cm 35. the time constant (in millisecond) of the circuit is Answer (4) Hints : Z= 2 R 2 XC 1.) 36. Dwarka. the sphere gets charged and acquires a potential.04 107 7 (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . Office : Aakash Tower. If the impedance of the R-C circuit is R 1. Sector-11.25 R2 XC2 = XC = R2 4 R 2 1 R c 2 RC = 2 2 s = 4 ms.6 1010 1.6 10 –2 1.

each of the same L. Each Question has four statements al(A. is Answer (5) Hints : 2 10sin60 3s g g 1 R = 1. Column I shows four systems. Plot No. Match each vis II describing the nature whose i system with statements given in Column and wavelength of the standing waves. D ( Column I (A) Pipe closed at one end (p) Column II Longitudinal waves t d. r. for producing standing waves. d E q are r. 4. Any given statement in Column uca statement B matches with the statements given in statement(s) given in Column II. f 39.: 011-47623417/23 Fax : 47623472 (16) . q.15 m inside the train to catch the ball back at the initial height. then for that particular question. The lowest possible n o length o i natural frequency of a system is called its fundamental frequency.15 m = u x t – at 2 2 1 1. A boy standing in the train throws a ball forward with a speed of 10 m/s. C and D) given in Column I and five This section contains 2 questions. The boy has to move forward by 1. against statementa B. Dwarka.IIT-JEE 2011 (Paper-2) 37. A train is moving along a straight line with a constant acceleration a. For example. Office : Aakash Tower. The voltage across AB in volts is 1 6V A Answer (5) 6 3 7. SECTION . if for a given question. shdarken the bubble corresponding to q and r in the ORS. at an angle of 60° to the horizontal. Two batteries of different emfs and different internal resistance are connected as shown.15 = 10cos60 3 – a 3 2 a = 5 m/s2 2uy T= 2 38. The acceleration of the train.Regd. wavelength is denoted as f. n o ti I can have correct matching with ONE or MORE statements (p. s and t) in Column II. Sector-11.5 5 V= 1 2 1 1 3 1 2 2 B 2 3V Hints : S B.IV (Total Marks : 16) L es (Matrix-Match Type) rvic e k ) Aa 0 L (q) Transverse waves (B) Pipe open at both ends 0 L (r) f = L (C) Stretched wire clamped at both ends 0 L (s) f = 2L (D) Stretched wire clamped at both ends and at mid-point 0 L L /2 (t) f = 4L Aakash IIT-JEE . in m/s2. New Delhi-75 Ph.

W = B A C 1V 3V D V 9V Column II (p) Internal energy decreases (q) Internal energy increases (r) Heat is lost (s) Heat is gained (t) Work is done on the gas Lt d . volume does not change In CD temperature and volume increase es In DA final temperature equals initial temperature. Office : Aakash Tower. In BC temperature decreases. Match them with each of the processes given in Column I. P 3P 1P 0 Column I (A) Process A B (B) Process B C (C) Process C D (D) Process D A Answer : A(p. B(p. ) O (0. 4 4 t2 t . ) be the point intersecting the line-segment joining O(0.I (Total Marks : 24) (Single Correct Answer Type) This section contains 8 multiple choice questions. In strings.0) X 4 = (2)2 2 = Locus of (. Then (B) y2 = 2x (C) y2 = x (D) x2 = 2y d hE u ca al ti o n Se (D on o t2 0 2t 0 . t) Hints : In AB temperature and volume are decreasing. 2t) 3 1 P(. Let (x. 2t) in the ratio 1 : 3. Aakash IIT-JEE . 0) to (x. s). Least distance between node and antinode is /4 and between two nodes is /2 40. B(p. r. Also.IIT-JEE 2011 (Paper-2) Answer : A(p.) pdV . s). C(q. 4 2 Q(t2. Let P be the point that divides the line segment from (0. Each question has four choices (A). (C) and (D) out of which ONLY ONE is correct. r). New Delhi-75 Ph. y) be any point on the parabola y2 = 4x. Q = U + W PART–III : MATHEMATICS k as a fA i SECTION ivis . Plot No. fixed end is antinode. Then the locus of P is (A) x2 = y Answer (C) Hints : Let P(. D(q. Sector-11. y) in the ratio 1 : 3. t). r) Hints : In organ pipes. transverse waves exist. C(q. volume decreases rvic For all processes use U = nCvT. s). 4. Open end is antinode. ) is y 2 = x. (B). 0) and Q(t2.: 011-47623417/23 Fax : 47623472 (17) . Dwarka. One mole of a monatomic ideal gas is taken through a cycle ABCDA as shown in the P-V diagram. 41. D(r. longitudinal wares exist. t).Regd. Column II gives the characteristics involved in the cycle.

Plot No. Dwarka. Office : Aakash Tower. 3) to the given hyperbola a2 x b 2 y a2 b 2 6 3 x2 a2 y2 b2 1 is Y which meets x-axis at (9.Regd. If the normal at the point P intersects the x-axis at (9. b 3i b 3i Aakash IIT-JEE . Let P(6. Sector-11. 3) N O (9. 0). 4.: 011-47623417/23 Fax : 47623472 (18) . have one root in common is (A) 2 Answer (B) Hints : (B) i 3 o i on s i 2 2 v Let be a common root between (Di given equations x + bx – 1 = 0 and x + x + b = 0 2 b2 1 2 1 1 b 1 b ka a A f s i 5 (C) d hE u i on t a c a e rvic e lS td sL . 3) be a point on the hyperbola then the eccentricity of the hyperbola is (A) 5 2 x2 a2 y2 b2 1 . 0) X b2 3 1 2 e2 2 a e 3 2 43. A value of b for which the equations x2 + bx – 1 = 0 x2 + x + b = 0.IIT-JEE 2011 (Paper-2) 42.) (D) 2 b2 1 1 b and 1 b 1 b 2 b2 1 1 b 1 b 1 b b2 1 (1 b )2 1 b b2 – b3 + 1 – b = 1 + 2b + b2 b3 + 3b = 0 b 0. 0). (B) 3 2 (C) 2 (D) 3 Answer (B) Hints : The equation of the normal at P(6. New Delhi-75 Ph. hence 9a2 a2 b2 6 P(6.

0) if (– 1 – h)2 + 4 = h2 (h. b and c is either or 2. c = 1 × 1 × 2 = 2 If a = If a = 2. 2) Thus the equation of the circle is 5 5 2 x ( y 2) 2 2 2 2 which passes through (– 4. Plot No. Office : Aakash Tower. 2) can be put in the form (x – h)2 + (y – 2)2 = h2 which will pass through (– 1.: 011-47623417/23 Fax : 47623472 (19) . 0) Total number of distinct matrices in the given set akS = 4. of A n io The circle passing through the point (–1. 1 M 2 a 1 b c 1 (B) 6 (C) 4 (D) 8 0 |M| = a 2 1 b c 1 c 1 2 = –(a – 2 – b – c – ) + 2(ac – 2c – b – c – 1) = –(a + c) + ac2 + 1 a + c 1. 2) also passes through the point i D ( 3 5 3 5 (A) . c are or 2 a=c c= Number of ways of selecting a. Then the number of distinct matrices in the set S is (A) 2 Answer (C) Hints : We have. ac 1 Since a. then number of ways = 1 × 1 × 1 = 2 45. b. 2 2 (D) (–4. 0) Aakash IIT-JEE . 0) 5 h= 2 (0.IIT-JEE 2011 (Paper-2) 44. 0 2 (B) . b.Regd. as d hE u i on t a c a e rvic e lS td sL . Sector-11.) Answer (D) Hints : The equation of the circle directing y-axis at (0. 2 2 (C) . Dwarka. New Delhi-75 Ph. 2) 2 2 (– 1. Let 1 be a cube root of unity and S be the set of all non-singular matrices of the form 1 2 a 1 b c 1 where each of a. 4. 0) vis and touching the y-axis at (0.

. 1 . . where (fog)(x) = f(g(x)).Regd.. Sector-11.: 011-47623417/23 Fax : 47623472 . x f(g(g(f(x)))) = g(g(f(x))) g(f(x)) = g(x2) = sinx2 g(g(f(x))) = g(sinx2) = sin(sinx2) f(g(g(f(x)))) = (sin(sinx2))2 (20) Aakash IIT-JEE . ].. Let f(x) = x 2 and g(x) = sin x for all x .-G. 1.} (D) 2n. is (A) n . lim 1 x ln(1 b2 ) x 2b sin2 . x = –1. If lim [1 x ln(1 b )] 2b sin . Let f : [–1. Plot No. x = 2. then the value of is x 0 (A) 4 (B) 3 (C) 6 (D) 2 Answer (D) Hints : We have. Office : Aakash Tower.. n {. 4. 1. 0.. 2. 2. . ) e x 0 lim x ln(1 b2 ) x 2b sin2 1 + b2 = 2bsin2 2b But 1 + b2 2b. 2. –1. Let R1 and R2 be the area of the region bounded by y = f(x). x 0 1 b > 0 and (– . by A. ) be a continuous function such that f(x) = f(1 – x) for all x [–1. b > 0 and (–. Hence sin = ± 1 2 47. Then (A) R1 = 2R2 Answer (C) Hints : We have... n {. .IIT-JEE 2011 (Paper-2) 2 1/ x 2 46.. –2..M. 2.. f(x) = x2 and g(x) = sinx. 2. .} Answer (A) Hints : We have. Then the set of all x satisfying (fogogof ) (x) = (gogof ) (x).} (C) 2n ..M. 2]...} 2 (B) n.. New Delhi-75 Ph. Dwarka. 1. n {0. 2 1 x f ( x ) dx .) (D) 3R1 = R2 2R1 = R2 48. 0. inequality. 2 (B) R1 = 3R2 (C) 2R1 = R2 R1 1 x f ( x )dx (1 x )f (1 x )dx 1 2 2 1 2 xo f (1 x )d x x f (1 x )id on 1 s i v (D i = R2 – R1 ka a A f s d hE u i on t a c a e rvic e lS td sL . 2] [0. n {1 . and the x-axis.

1) and f (b ) (C) f = f –1 on (0. (C) and (D) out of which ONE or MORE may be correct.. Plot No.IIT-JEE 2011 (Paper-2) (sin sinx2)2 = sin(sinx2) sin(sinx2) = 0 or sin(sinx2) = 1 x2 = n x = n . then L is given by (A) y – x + 3 = 0 (C) y + x – 15 = 0 Answer (A.: 011-47623417/23 Fax : 47623472 (21) . – 3 (B) y + 3x – 33 = 0 (D) y – 2x + 12 = 0 Aakash IIT-JEE . 50.} But sin(sinx2) = 1 is not possible hence sinx2 = 0 SECTION . Office : Aakash Tower. 1) defined by f (x) bx . New Delhi-75 Ph.. Dwarka.II (Total Marks : 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions. 1) be defined by f (x) bx 1 bx where b is a constant such that 0 < b < 1. Let L be a normal to the parabola y2 = 4x. 1) Answer (A) Hints : Let f : (0. 49.) f(x) is strictly increasing x (0.. Each question has four choices (A). 4. If L passes through the point (9..Regd. 1) is into function. and hence its increase does not exist. 2. 1) (B) f f –1 on (0. Then (A) f is not invertible on (0. 1 . (B).. Sector-11. 2. 1) It is obvious that f(x) does not take all real values for 0 < b < 1 f : (0. n {0. 6) if 6 = 9m – 2m – m3 m3 – 7m + 6 = 0 m = 1. Let f : (0. 3. 6). 1) and f (b ) (D) f –1 is differentiable on (0. B. where 0 < b < 1 1 bx 1 f (0) 1 f (0) We observe that f ( x ) 1 b 2 (1 bx )2 0 (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . D) Hints : The equation of the normal to the given parabola y2 = 4x in slope form is y = mx – 2m – m3 which will pass through (9.

x 1 3 2 We have.IIT-JEE 2011 (Paper-2) Consequently the equation of the normal L is y=x–3 or y = 2x – 12 or y = – 3x + 33 51.) Let us draw the graph of the given function – 2 (0. C. New Delhi-75 Ph. If x . ln x. B. x 1. Dwarka. 4. ln x. x 0 2 0 x 1 x 1. y–x+3=0 y – 2x + 12 = 0 y + 3x – 33 = 0 then (A) f (x) is continuous at x 2 (B) f (x) is not differentiable at x = 0 (D) f (x) is differentiable at x (C) f (x) is differentiable at x = 1 Answer (A. x 2 . Office : Aakash Tower. x 0 2 0 x 1 x 1. 2 f ( x ) cos x. (1. 1) From graph we observe that all the options are correct. h 0 lt f h lt h 0 h 0 2 2 2 lt f h lt cos h 0 h 0 2 h0 2 f 0 2 2 2 f(x) is continuous at x = 2 (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . Sector-11. x 2 f ( x ) cos x. 0) Aakash IIT-JEE . Plot No.: 011-47623417/23 Fax : 47623472 (22) .Regd. D) Hints : The given function f is defined as x 2 .

P (F ) 5 5 3 4 . P (F ) 5 5 (B) P (E ) (D) P (E ) 1 2 . Y y = (x – 1)4 y = –6x2 – 5x + 2 O (1.Regd. The answer to each of the questions cais a single-digit integer. Let E and F be two independent events. Plot No.: 011-47623417/23 Fax : 47623472 (23) .III (Total Marks : 24) (Integer Answer Type) na o i t This section contains 6 questions. Dwarka. If P(T ) denotes the probability of occurrence of the event T. The number of distinct real roots of x4 – 4x3 + 12 of x n io Answer (2) vi s i D ( Hints : The given equation is x4 – 4x 3 + 12x 2 + x – 1 = 0 x4 – 4x 3 + 6x 2 – 4x + 1 + 6x 2 + 5x – 2 = 0 (x – 1)4 = –6x 2 – 5x + 2 e rvic e lS td sL . there are two solutions of the given equation. ranging from 0 to 9. 4. The probability that exactly one of them occurs is of none of them occurring is (A) P (E ) (C) P (E ) Answer (A.IIT-JEE 2011 (Paper-2) 52. Aakash IIT-JEE . Office : Aakash Tower. as h k a 2 + x – 1 = 0 is A 53. 0) X Clearly. it is sufficient to find the number of point of intersections of the given curve y = (x – 1)4 and y = –6x 2 – 5x + 2.) In order to find the number of solutions of the given equations. P (F ) 5 5 P (E c F c ) (1 P (E ))(1 P (F )) 2 25 Solving these equations. P ( E ) P ( F ) 2P (E F ) 11 25 11 and the probability 25 2 . New Delhi-75 Ph. D) Hints : We have. P (F ) 5 5 2 1 . Sector-11. then 25 4 3 . P (F ) 5 5 or P (E ) SECTION . The du E bubble corresponding to the correct answer is to be darkened in the ORS. P (F ) 5 5 3 4 . we shall get P (E ) 4 3 .

and M 1 0 0 3 0 1 1 12 Then the sum of the diagonal entries of M is Answer (9) Hints : a11 a M Let 21 a31 a12 a22 a32 a13 a23 be the given matrix. we get a33 = 7 no ka a A f s d hE u i on t a c a e rvic e lS td sL . New Delhi-75 Ph. M 1 0 1 12 a11 + a12 + a13 = 0 a21 + a22 + a23 = 0 a31 + a32 + a33 = 12 Using above results.Regd. Let M be a 3 × 3 matrix satisfying 0 1 1 1 1 0 M 1 2 . M 1 1 0 1 a11 – a12 = 1 a21 – a22 = 1 a31 – a32 = –1 a11 = 0 io vi s Using above equations. M 1 1 . Office : Aakash Tower. Plot No.) Finally. a33 Using the given conditions. 4. the sum of elements of leading diagonals = a11 + a22 + a33 =0+2+7 =9 Aakash IIT-JEE . Dwarka. Sector-11. we shall get i D ( 1 0 Moreover. we have a11 a 21 a31 a12 a22 a32 a13 0 1 a23 1 2 a33 0 3 a12 = –1 a22 = 2 a32 = 3 1 1 Also.IIT-JEE 2011 (Paper-2) 54.: 011-47623417/23 Fax : 47623472 (24) .

. If 3 5 3 1 1 1 1 S 2. 0) 1 . 3 S (0. 6 ) ( 6 . – 6 ) ( 6 . Plot No.b is hE s a ak Answer (9) A f o Hints : We have i on s i v (D i r b cb (r c ) b 0 r c b. 0) (0. then the value of r . Office : Aakash Tower.Regd.b (c 4b ) b ˆ 3k ˆ ) ( iˆ j ˆ) = (3iˆ 6 j =3+6=9 Aakash IIT-JEE . 4 2 4 4 4 8 4 then the number of point(s) in S lying inside the smaller part is Answer (3) Hints : 3 5 3 1 1 We observe that the points 2. b i j and c i 2 j 3k t c b and a uc d r . 0) t d. Hence there c es exactly three points of the set i are v r lie in the smaller part l Se a ˆ ˆ n ˆ ˆ ˆ ˆ ˆ be three given vectors. 4. The straight line 2x – 3y = 1 divides the circular region x2 + y 2 6 into two parts. . . 0) 0 (0. io If r is a vector such that r b 56.IIT-JEE 2011 (Paper-2) 55. 0 r c b Since r a 0 (c b ) a 0 = 4 r . . ) L lie on the opposite side of origin with respect to the given line. .0 2 1 0. . Let a i k . Dwarka.: 011-47623417/23 Fax : 47623472 (25) . . 4 3 4 4 4 (10. . . .a 0. . New Delhi-75 Ph. Sector-11.

x. Dwarka. c. y iv = 0. Then the value of y (2) is Answer (0) Hints : y (x) + y(x)g (x) = g(x)g (x) which is linear differential equation I. Office : Aakash Tower. e g ( x )dx eg ( x ) Solution is y ( x )eg ( x ) e g ( x ) g ( x )g ( x )dx y(x)eg(x) = eg(x)(g(x) – 1) + k where k is a constant of integration For x = 0.) f ( x ) denotes d f (x) and g(x) is a given non-constant dx differentiable function on with g(0) = g(2) = 0. Let e 3 . x . Sector-11. New Delhi-75 Ph.Regd. and a.IIT-JEE 2011 (Paper-2) 57. Plot No. k = 1 For x = 2. Let y (x) + y (x) g (x) o i on s i g ( x )g ( x ). we get |x|2 + |y|2 + |z|2 = 3(|a|2 3 + |b|2 + |c|2) | x |2 | y |2 | z |2 | a |2 | b |2 | c |2 58.F.: 011-47623417/23 Fax : 47623472 (26) . b. y. z be non-zero complex number such that a+b+c=x a b c2 y i a b 2 c | x |2 | y |2 | z |2 Then the value of is | a |2 | b |2 | c |2 Answer (3) Hints : We have | x |2 xx (a b c ) (a b c ) = | a |2 | b |2 | c |2 a(b c ) b(c a ) c (a b ) | y |2 yy (a b c 2 )(a b 2 c ) Similarly | z |2 zz (a b2 c )(a b 2 c ) On adding them. 4. where (D(0) ka a A f s d hE u i on t a c a e rvic e lS td sL . y(2) = 0 Aakash IIT-JEE .

Office : Aakash Tower. D(r) Hints : (A) We have |z| = 1 and z ± 1 z = cos + isin 2z 1 z 2 (D i vi s o i on fA sh a ka E du a n o (s) i t ca (t) e rvic e lS td sL . 1] [1. ) Aakash IIT-JEE . t).IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. B(r. Sector-11. if for a given question.: 011-47623417/23 Fax : 47623472 (27) . 1) (1. statement B matches with the statements given in q and r. For example. C and D) given in Column I and five statements (p. C(r).Regd. f | z | 1. ) 1 f ():0 is 2 (D) If f ( x ) x 2 (3 x 10). q. ) (. ) (B) The domain of the function 8(3)x 2 f ( x ) sin1 2( x 1) is 1 3 1 (C) If f () tan tan 1 tan 1 tan .) (. r. Match the statements given in Column I with the intervals/union of intervals given in Column II Column I (A) The set 2iz : z is a complex number . 59.0] [2. New Delhi-75 Ph. Each question has four statements (A. against statement B. darken the bubbles corresponding to q and r in the ORS. B. then for the particular question. s). ) 2(cos i sin ) 1 (cos i sin )2 = 2(cos i sin ) 1 cos 2 i sin2 1 cos i sin i sin cos i sin = = 1 i i sin sin 1 i 2z Re cosec 2 sin 1 z Df = (– . s and t) in Column II. 0) (0. 1] [1.IIT-JEE 2011 (Paper-2) SECTION . Plot No. Dwarka. x 0. Any given statement in Column I can have correct matching with ONE or MORE statement (s) given in Column II. then f ( x ) is increasing in 3 Answer : A(p. then the set 1 (r) [2. ) (. z 1 is Re 2 1 z Column II (p) (q) (. 4.

3 x 2 1 32( x 1) 1 |8. Dwarka. a = 3x –9 a 1 3x 30 x0 (C) We have 1 f () tan 1 tan 1 tan 1 tan 1 = (1 + tan2) – tan(– tan + tan) + 1(tan2 + 1) = 2(1 + tan2) = 2sec2 Df = [2.IIT-JEE 2011 (Paper-2) (B) For the domain of the given function 1 8. New Delhi-75 Ph. then internal angle of the triangle between a and b is (B) If b a (f ( x ) 3 x )dx a2 b 2 .b j ˆ 3k ˆ and c ˆ (A) If a j 3k 2 3k form a triangle.3 x 32 x 32 x .: 011-47623417/23 Fax : 47623472 (28) . Sector-11. 4. 1 1 9 9 9 8a 9 – a2.) Since f(x) is increasing. Match the statements given in Column I with the values given in Column II Column I Column II (p) 6 ˆ ˆ. Office : Aakash Tower. hence f (x) 0 x 2 as x 0 Df is [2.3x–2| |1 – 32(x–1| 8. Plot No.Regd. ) (D) We have 3 f ( x ) x 2 (3 x 10) 3 f ( x ) x 2 (3 x 10) 3 x 2 2 1 2 = 3 x (3 x 10 2 x ) 2 1 3 15 2 = x ( x 2) 2 1 (D io i vi s no ka a A f s d hE u i on t a c a e rvic e lS td sL . (q) 2 3 then the value of f is 6 Aakash IIT-JEE . ) 60.

Sector-11. a b (f ( x ) 3 x ) dx a 2 b 2 o Keeping a constant and differentiating on both sides w. –1.) f 6 6 sec x dx ln |sec x tan x | . z 1 is given by (t) Answer : A(r). b. 3) (0. 3)B C(0. we get i s i f(b) – 3b = –2b v (D i f(b) = b (C) Using ka a A f s d hE u i on t a c a e rvic e lS td sL . Plot No.Regd.IIT-JEE 2011 (Paper-2) 2 6 sec ( x)dx is (C) The value of In3 7 6 5 (r) 3 1 (D) The maximum value of Arg 1 z (s) | z | 1. 1.: 011-47623417/23 Fax : 47623472 (29) . 0) (D) 1 arg = | arg(1) – arg(1 – z) | 1 z = | arg(1 – z) | But z lies on | z | = 1 Hence. 4. New Delhi-75 Ph. D(s) Hints : (A) We have.t. Office : Aakash Tower. 0. C(s). max| arg(1 – z) | = Aakash IIT-JEE . B(p).r. Dwarka. we get 2 ln 3 5/6 7/6 1 sec x dx (1. 2 3) cos 3 1 2 (B) We have. ˆ 3k ˆ a j ˆ 3k ˆ b j ˆ c 2 3k We observe that ab c | a |2 | b |2 2a b | c |2 4 + 4 + 8 cos = 12 2 A(0.

and the name of centre and sign with pen in the boxes provided. You are allotted 5 minutes specifically for this purpose. No additional sheets will be provided for rough work. 2. Darken the appropriate bubble UNDER each digit of your Registration No. slide rules. On breaking the seals. clipboards. This question Paper contains 36 pages having 69 questions. Blank papers. Physics and Mathematics). pagers and electronic gadgets are NOT allowed. 26569493. In all other cases. The question paper CODE is printed on the right hand top corner of this sheet and on the back page (page No. The ORS also has a CODE printed on its Left and Right parts. 8. calculators. . Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators. 14.FIITJEE Solutions to IIT-JEE-2011 CODE PAPER 1 Time: 3 Hours Please read the instructions carefully. 7. In Section III (Total Marks: 15). In Section IV (Total Marks: 28). Fax 26513942 website: www. DO NOT TAMPER WITH/MULTILATE THE ORS OR THE BOOKLET. B. 4. 9. Write your Name. FIITJEE Ltd. Filling the Right Part of the ORS: 10. Registration No. In Section II (Total Marks: 16). 6. Sarvapriya Vihar. Kalu Sarai. cellular phones.. 15. The question paper consists of 3 parts (Chemistry. minus one (–1) mark will be awarded. please check that all the questions are legible. 5. minus one (–1) mark will be awarded. Question paper format and Marking scheme: 13. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. Make sure the CODE on the ORS is the same as that on this booklet. with a good quality HB pencil. Write your name. There are no negative marks in this section. FIITJEE House.com. If the codes do not match ask for a change of the booklet. 17. There are no negative marks in this section. 3. New Delhi -110016. a machine-gradable Optical Response Sheet (ORS). General: 1.fiitjee. 12. Ph 46106000. In all other cases. The answer sheet. 11. In Section I (Total Marks: 21). for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. Write your name and registration number in the space provided on the back page of this booklet. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. 8 Maximum Marks: 240 INSTRUCTIONS A. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. log tables. 29-A. Each part consists of four sections. registration number and sign in the space provided on the back of this booklet. 36) of this booklet. 16. C. Do not write them anywhere else. is provided separately.

Sarvapriya Vihar.05 M (D) 2. neutron. Y and Z respectively are. The molarity of the solution is (A) 1. 26569493. tetrahedral and square planar (B) tetrahedral.15 × 103 M= × = × = 2. Extra pure N2 can be obtained by heating (A) NH3 with CuO (C) (NH4)2Cr2O7 (D) ∆ Ba ( N 3 ) 2 → Ba + 3N 2 Dissolving 120 g of urea (mol. New Delhi -110016. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl– . are (A) octahedral. Sol. positron (C) proton. square planar and octahedral (C) square planar. proton.fiitjee.com. neutron 30 14 (B) neutron. square planar and octahedral FIITJEE Ltd. 2. Kalu Sarai. (i ) ( ) Al →15 P + Y ii 30 30 Si + X 14 Si + Z (A) proton. 3. (C) and (D) out of which ONLY ONE is correct. CN– and H2O. wt. neutron Sol. Products X. 27 13 (B) NH4NO3 (D) Ba(N3)2 Sol. Each question has four choices (A). positron.IITJEE2011-Paper 1-CPM-2 PAPER-1 [Code – 8] IITJEE 2011 PART . Ph 46106000. positron.15 W 1 120 1. 1.. respectively.00 M (C) 2. (A) 27 4 30 1 13 Al + 2 α →14 Si + 1 p ( X ) 27 13 30 15 30 P → 14 Si + +1 β0 ( Z ) 30 Al + 2 α 4 →15 P + 0 n1 ( Y ) 4. (i) and (ii) as shown.05 M M V ( in L ) 60 1120 Bombardment of aluminium by α-particle leads to its artificial disintegration in two ways.15 g/mL. Fax 26513942 website: www. proton (D) positron.I: CHEMISTRY SECTION – I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. 29-A.22 M (C) Total mass of solution = 1000 + 120 = 1120 g 1120 Total volume of solution in (L) = ×103 1. FIITJEE House. (B). tetrahedral and octahedral (D) octahedral.78 M (B) 2. . 60) in 1000 g of water gave a solution of density 1.

New Delhi -110016.. .IITJEE2011-Paper 1-CPM-3 Sol. FIITJEE House. Among the following compounds. (B) [ NiCl4 ] → Tetrahedral 2− Ni ( CN ) 4 → Square Planar 2− Ni ( H 2 O )6 5. 2+ → Octahedral The major product of the following reaction is O C NH C O O C () → i KOH (ii) Br CH2Cl O C Br (A) C N CH2 O O (B) C N O O C N C O CH2Cl C (C) N O CH2 Br (D) CH2 Cl Sol. (A) O O NH () → i KOH N CH2 Br (ii ) Br CH2 Cl O O [Reason: Due to partial double bond character along C−Br bond prevents the attack of nucleophile at phenylic position] 6.com. 29-A. Sarvapriya Vihar. Ph 46106000. Kalu Sarai. Fax 26513942 website: www. 26569493. the most acidic is (A) p-nitrophenol (B) p-hydroxybenzoic acid (C) o-hydroxybenzoic acid (D) p-toluic acid (C) Due to ortho effect o-hydroxy benzoic acid is strongest acid and correct order of decreasing Ka is COOH OH > > > COOH COOH OH Sol.fiitjee. CH3 OH NO2 FIITJEE Ltd.

Hence conductivity of solution is almost compensated (or slightly increase) by the formation of KNO3.fiitjee. D) SnO 2 + 2C → 2CO + Sn The ore cassiterite contains the impurity of Fe. FIITJEE House.com. Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore (C) removal of copper impurity (D) removal of iron impurity (A. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any). is (are) H H H (A) C H2C C CH2 C O (B) H C C C CH2 (C) H2C Sol. (B). Mn.IITJEE2011-Paper 1-CPM-4 7. SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. After end point conductivity increases more rapidly because addition of excess AgNO3 solution. FIITJEE Ltd. 8. (C) and (D) out of which ONE OR MORE may be correct. C) Along C−C single bond conformations are possible in butadiene in which all the atoms may not lie in the same plane. C. the molecules move in straight lines with constant velocities 9. (D) AgNO3 + KCl ( aq ) → AgCl ( s ) + KNO3 ( aq ) (B) (Q) (D) (S) Initially there is aq. Sarvapriya Vihar. Ph 46106000. Sol. AgCl(s) is formed. W and traces of Cu. AgNO3(aq. KCl solution now as solution of AgNO3 is added. 26569493.. 29-A. (D) H2C C CH2 (B.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. Kalu Sarai. New Delhi -110016. . The plot of conductance ( Λ ) versus the volume of AgNO3 is Λ Λ Λ Λ volume (P) volume (Q) volume (R) volume (S) (A) (P) (C) (R) Sol. Fax 26513942 website: www. According to kinetic theory of gases (A) collisions are always elastic (B) heavier molecules transfer more momentum to the wall of the container (C) only a small number of molecules have very high velocity (D) between collisions. 10. Each question has four choices (A). Amongst the given options.

H 2SO4 ( catalytic amount ) ( i ) dil. The structure of compound P is (A) CH 3 CH 2 CH 2 CH 2 − C ≡ C − H H3C (C) H (B) H 3 CH 2 C − C ≡ C − CH 2 CH 3 H3C (D) H3C C C C CH3 C C C H H3C Sol. however it is very slow due to higher energy of activation (A. in which Q is an intermediate organic compound. (C) and (D) out of which ONLY ONE is correct. H 2SO4 / HgSO4 ( − H2O ) P → Q →2 ( ii ) NaBH 4 / ethanol ( ii ) O3 ( C6 H10 ) ( iii ) dil. D) The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are) (A) Adsorption is always exothermic (B) Physisorption may transform into chemisorption at high temperature (C) Physiosorption increases with increasing temperature but chemisorption decreases with increasing temperature (D) Chemisorption is more exothermic than physisorption. D) Sol. C.. 12 and 13 An acyclic hydrocarbon P. (B) CH3 CH2 CH2 CHCH2 CH3 FIITJEE Ltd. Each of these questions has four choices (A). New Delhi -110016. 29-A. Kalu Sarai. Sarvapriya Vihar.com. (D) The structure of the compound Q is OH H3C (A) H H3C H3C (B) H3C OH C C H OH CH3 C C H CH2 CH3 H3C H3C (C) H H3C OH C CH2CHCH3 (D) H3C Sol. Paragraph for Question Nos. (B). FIITJEE House. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered.IITJEE2011-Paper 1-CPM-5 Sol. 11. B. . B.acid ( iii ) Zn / H 2 O O C CH3 H3C 12. Ph 46106000.fiitjee. Fax 26513942 website: www. gave acetone as the only organic product through the following sequence of reaction. 13. having molecular formula C6H10. SECTION-III (Total Marls : 15) (Paragraph Type) This section contains 2 paragraphs. ( i ) conc. 26569493. (A.

. 29-A. H + H3C C OH CH (Q) CH3 C C ( ) →H3C CH3 H3C H3C ∆ H 2 SO 4 ( conc. While Cu partially oxidizes to Cu(NO3)2 and remaining AgNO3 reacts with NaCl. Addition of aqueous NH3 dissolves O and gives an intense blue solution. 26569493.com. Ph 46106000. (C) AgNO3 + NaCl → AgCl ↓ + NaNO3 (N) ( O) − AgCl + 2NH 3 → Ag ( NH 3 )2 Cl + (D) Ag ( NH 3 )2 and Ni ( NH 3 )6 2+ Cu ( NO3 ) 2 + 4NH 4 OH → Cu ( NH 3 )4 2+ FIITJEE Ltd.) H3C C H3C O+ O C CH3 H3C O3 / Zn / H 2 O ← CH3 C C CH3 CH3 H3C Paragraph for Question Nos.IITJEE2011-Paper 1-CPM-6 Solution for the Q. New Delhi -110016. Addition of aqueous NaCl to the blue solution gives a white precipitate O. 14.fiitjee. Kalu Sarai. 14 to 16 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N.. The compound N is (A) AgNO3 (C) Al(NO3)3 (A) The final solution contains (A) Pb ( NH 3 )4 2+ + (B) Zn(NO3)2 (D) Pb(NO3)2 Sol. Fax 26513942 website: www. H2 SO4 → H3C H HgSO4 O ( i ) NaBH 4 / EtOH ii dil. No. 12 to 13 H3C H3C H3C C C (P) C H3C dil. the solution turns light blue. FIITJEE House. The metal rod M is (A) Fe (C) Ni (B) Cu + 2AgNO3 → Cu ( NO3 ) 2 + 2Ag M N Blue (B) Cu (D) Co Sol. 16. 15. and [ CoCl 4 ] 2− 2+ (B) Al ( NH 3 ) 4 3+ + and Cu ( NH 3 ) 4 2+ (C) Ag ( NH 3 )2 and Cu ( NH 3 )4 Sol. Sarvapriya Vihar.

ranging from 0 to 9.fiitjee. New Delhi -110016. The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is (5) O Na O S S S O S O Na O O S will have oxidation number = +5.IITJEE2011-Paper 1-CPM-7 SECTION-IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. is 2 (9) For principal quantum number (n = 3) Number of orbitals = n2 = 9 1 So. (4) The energy associated with incident photon = hc λ ⇒E= 6. 796) on complete hydrolysis gives glycine (Mol.3 2.4 2. Na. The bubble corresponding to the correct is to be darkened in the ORS. The work function Sol. 2 FIITJEE Ltd. 26569493.e. and spin quantum 1 number.75 photoelectric effect when light of 300 nm wavelength falls on the metal is Metal Li Na K Mg Cu Ag 2. 0 Difference in oxidation number = 5 18. alanine and phenylalanine.. The answer to each of the questions is a single digit integer. Kalu Sarai. Sol.6 × 10−34 × 3 × 108 J 300 × 10−9 6. FIITJEE House. number of metals showing photo-electric effects will be (4). . Mg 20. Li.8 4.2 3. 29-A. n × 75 × 100 = 47 796 ( + 9 ×18 ) ⇒n=6 19. ms = − .6 × 10−34 × 3 × 108 E in eV = = 4.6 ×10−19 So. Glycine contributes 47. number of electrons with ms = − will be 9. i. Ph 46106000. A decapeptide (Mol. Sarvapriya Vihar. 75).3 W 4.16 eV 300 × 10−9 × 1. n = 3. 17. The number of glycine units present in the decapeptide is (6) For n-units of glycine. Wt. ( φ) of some metals is listed below. K.3 φ (eV) Sol.0% to the total weight of the hydrolysed products. Sol.. The maximum number of electrons that can have principal quantum number.com. Fax 26513942 website: www. Wt.7 Pt 6.7 4. The number of metals which will show Fe 4.

0821 × 273 V = 7 litre (unknown compound X will not follow ideal gas equation) Sol. at 0oC) are introduced. number of NaBr molecules = 5 Sol. P = 0. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas. n = 0.32 × V = 0. of alkenes will be = 5 Br Sol. 1 atm He + X For He. Kalu Sarai.32 atm. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is (5) Total no.1 mol of He and 1. . H3C CH2 CH2 C CH2 CH3 alc.1 × 0. Considering the ideal gas behaviour. To an evacuated vessel with movable piston under external pressure of 1 atm. The number of sodium bromide molecules involved in the balanced chemical equation is (5) 3Br2 + 3Na 2 CO3 → 5NaBr + NaBrO3 + 3CO2 So. Fax 26513942 website: www. T = 273 23. Ph 46106000.IITJEE2011-Paper 1-CPM-8 21. V = ?. 0.. the total volume (in litre) of the gases at 0oC is close to (7) For any ideal gas. Sarvapriya Vihar.fiitjee. 29-A. PV = nRT 0.com. New Delhi -110016.68 atm.0 mol of an unknown compound (vapour pressure 0. KOH → H3C CH2 CH2 C CH CH3 (E & Z) H3C CH2 CH C CH2 CH3 or H3C CH2 CH2 C or CH2 CH3 (E & Z) ( only 1) FIITJEE Ltd. FIITJEE House.1.. 26569493. 22.

(A) TVγ-1 = C T1(5.6 liter of helium gas at STP is adiabatically compressed to 0. 26569493.6)2/3 = T2 (0.fiitjee. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 A0. (B). The frequency of the siren heard by the car driver is (A) 8. 26.50 kHZ (A) f= Sol. Sarvapriya Vihar. The wavelength of the second spectral line in the Balmer series of singly-ionized helium atom is (A) 1215 A0 (B) 1640 A0 0 (C) 2430 A (D) 4687 A0 (A) 1 1 1 5R = R − = 6561 4 9 36 1 1 1 3R × 4 = 4R − = λ 16 4 16 λ = 1215A 0 Sol.5 kHz 25. Fax 26513942 website: www. Each question has four choices (A).a) E0 a 2 2 x (0.7)2/3 ⇒ T2 = T1(8)2/3 = 4T1 FIITJEE Ltd.50 kHz (B) 8.com.7 liter.0) y Sol. Taking the initial temperature to be T1. Kalu Sarai. . (C) and (D) out of which ONLY ONE is correct. The flux Consider an electric field E = E 0 x through the shaded area (as shown in the figure) due to this field is (A) 2E0a2 (B) 2E 0 a 2 (C) E0 a2 (D) z (a. (C) (E0) (Projected area ) = E0a2 5.IITJEE2011-Paper 1-CPM-9 PART .0. the work done in the process is 9 3 (A) RT1 (B) RT1 2 8 15 9 (C) RT1 (D) RT1 2 8 Sol. FIITJEE House. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which reflects the sound waves. 24. 29-A. 320 320 + 10 × 8 × 103 × 320 − 10 320 = 8. The speed of sound in air is 320 m/s. New Delhi -110016. Ph 46106000.75 kHz (D) 7.a.0. ˆ where E0 is a constant. 27.25 kHz (C) 7.0) (0.a.II: PHYSICS SECTION – I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions.a) (a..

26569493.6Ω 50 10 Ω B Sol.6 ohm (C) 10. The determined value of A ‘X’ is (A) 10. 29-A. Sarvapriya Vihar. The galvanometer shows null point when tapping-key is at 52 cm mark. Ph 46106000.8 ohm (D) 11. .com. The ball is rotated on a horizontal circular path about vertical axis.5) ω2 = 324 × 4 ω = 1296 = 36 rad / s FIITJEE Ltd. The percentage of its stored energy dissipated after the switch S is turned to position 2 is (A) 0 % (B) 20 % (C) 75 % (D) 80 % 1 2 S V 2µ F 8µ F Sol. The maximum possible value of angular velocity of ball (in radian/s) is (A) 9 (B) 18 (C) 27 (D) 36 m L Sol. + 2 × 25 × 8 2 × 25 × 2 = 2V-q q 4V 2 5 X 29.1 ohm (B) X (48 + 2) = (10) (52 + 1) 530 X= = 10. switch S is turned to position 2 2V − q q = 2 8 8V – 4q = q 8V ⇒q= 5 64V 2 4V 2 ∆ H = V2 . A meter bridge is set up as shown. The end-corrections are 1 cm and 2 cm respectively for the ends A and B. to determine an unknown resistance ‘X’ using a standard 10 ohm resistor. Fax 26513942 website: www. A ball of mass (m) 0. New Delhi -110016.. (D) 324 = 0.2 ohm (B) 10. FIITJEE House.IITJEE2011-Paper 1-CPM-10 ∴ ∆w(work done on the system) = 28. nR∆T 9 = RT1 γ −1 8 A 2 µF capacitor is charged as shown in the figure. Kalu Sarai. The maximum tension that the string can bear is 324 N.5 kg is attached to the end of a string having length (L) 0. 30.5 ω2 (0. (D) Ui = 1 × 2 × V2 = V2 2 qi = 2V Now.fiitjee.5 m.

com. FIITJEE House. Heat ‘Q’ flows only from left to right through the blocks. Consider two ways the disc is attached: (case A). D) RB < RA QA + QB = 2Q kQ A kQ B = RA RB σARA = σBRB 2QR A QA = RA + RB QB = 2QR B RA + RB 0 A 1L B 3K 5L E 6L 33. A composite block is made of slabs A. D) In case A Sol. Ph 46106000. (D) heat flow through C = heat flow through B + heat flow through D.IITJEE2011-Paper 1-CPM-11 SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. (D) Angular frequency for case A < Angular frequency for case B. . 29-A. New Delhi -110016. C. (B).fiitjee. 2K C 4K 6K D 5K FIITJEE Ltd. A thin disk of mass ‘M’ and radius ‘R’ (<L) is attached at its center to the free end of the rod. All slabs are of same width. Now they are connected by a thin metal wire. Then (A) E inside =0 (B) QA > QB A (C) Sol. B.. (C) temperature difference across slab E is smallest. B. σA R B = σB R A (D) E on A surface < E on B surface (A. Then 3L in steady state (A) heat flow through A and E slabs are same. D and E of heat different thermal conductivities (given in terms of a constant K) and sizes (given in terms of length. Fax 26513942 website: www. Kalu Sarai. 4L (B) heat flow through slab E is maximum. ωA < ωB 32. mℓ 2 MR 2 + + Mℓ 2 α A mg(ℓ/2) sin θ + Mg ℓ sin θ = 2 3 In case B mℓ 2 mg (ℓ/2) sin θ + Mg ℓ sin θ = + Mℓ 2 α B 3 τA = τB. (C) and (D) out of which ONE OR MORE may be correct. The rod disc system performs SHM in vertical plane after being released from the same displaced position. C. Sarvapriya Vihar. The disc is not free to rotate about its centre and (case B) the disc is free to rotate about its centre. 31. Each question has four choices (A). 26569493. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB (<RA) are kept far apart and each is given charge ‘+Q’. L) as 1L shown in the figure. (A. Which of the following statement(s) is (are) true? (A) Restoring torque in case A = Restoring torque in case B (B) restoring torque in case A < Restoring torque in case B (C) Angular frequency for case A > angular frequency for case B. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end.

New Delhi -110016. (A. 35 and 36 A dense collection of equal number of electrons and positive ions is called neutral plasma. FIITJEE House. An electron and a proton are moving on straight parallel paths with same velocity. hence time will be different Sol. mε0 Ne (A) (B) mε0 Ne (C) Ne 2 mε 0 (D) mε 0 Ne 2 FIITJEE Ltd. Let ‘N’ be the number density of free electrons. (B). They enter a semiinfinite region of uniform magnetic field perpendicular to the velocity. Kalu Sarai. (C) and (D) out of which ONLY ONE is correct. To sustain the oscillations. C. 29-A. where a part of the energy is absorbed and a part of it is reflected. . (B. Paragraph for Question Nos. Taking the electronic charge as ‘e’ and the permittivity as ‘ε0’. D) Let width of each rod is d 1 4 R1 = . B.fiitjee. SECTION-III (Total Marls : 15) (Paragraph Type) This section contains 2 paragraphs.com. Use dimensional analysis to determine the correct expression for ωp. This is the explanation of high reflectivity of metals. 24kd 2 5 1 3 4 R2 R1 R3 R4 R5 34. 26569493.IITJEE2011-Paper 1-CPM-12 Sol.. R2 = 8kd 3kd 1 4 . Ph 46106000. 35. R4 = R3 = 2kd 5kd 1 R5 = . a time varying electric field needs to be applied that has an angular frequency ω. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. each of mass ‘m’. Sarvapriya Vihar. Which of the following statement(s) is / are true? (A) They will never come out of the magnetic field region. (D) They will come out at different times. If the electric field becomes zero. the electrons begin to oscillate about the positive ions with a natural angular frequency ‘ωp’ which is called the plasma frequency. Each of these questions has four choices (A). Fax 26513942 website: www. D) Both will travel in semicircular path µ (πr 2 ) dI dφ t = E ind = − =− 0 time period of semi circular path dt L dt m is different. C. (B) They will come out travelling along parallel paths. When the electrons are subjected to an electric field. D) or (A. As ω approaches ωp all the free electrons are set to resonance together and all the energy is reflected. (C) They will come out at the same time. they are displaced relatively away from the heavy positive ions.

They are especially useful in studying the changes in motion as initial position and momenum are changed. We use the sign convention in which positon or momentum upwards (or to right) is positive and downwards (or to left) is negative. Fax 26513942 website: www. Then (A) E1 = 2E 2 (B) E1 = 2E2 (C) E1 = 4E2 (D) E1 = 16E2 Momentum E1 E2 2a a Position Sol. (C) E ∝ A2 FIITJEE Ltd. 38. In the figure. Paragraph for Question Nos. For example. . (C) Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons N ≈ 4 × 1027 m-3. For such systems. Taking ε0 = 10-11 and mass m ≈ 10-30. 29-A. 37 to 39 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. the phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure. New Delhi -110016. Kalu Sarai.IITJEE2011-Paper 1-CPM-13 Sol. phase space is a plane in which position is plotted along horizontal axis and momentum is plotted along vertical axis. Ph 46106000. Here we consider some simple dynamical systems in onedimension. (D) The phase space diagram for simple harmonic motion is a circle centered at the origin. where these quantities are in proper SI units. 37. The phase space diagram for a ball thrown vertically up from ground is Momentum Momentum Momentum Position (A) Position (B) Position Momentum Momentum (C) Position (D) Position Sol. 36. and E1 and E2 are the total mechanical energies respectively. The phase space diagram is x(t) vs. Sarvapriya Vihar. the two circles represent the same oscillator but for different initial conditions. p(t) curve in this plane.com. 26569493. FIITJEE House.. (A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm (B) ω = 2πc / λ Sol.fiitjee. The arrow on the curve indicates the time flow.

The phase space diagram for one cycle of this system is (A) Momentum (B) Momentum Position Position (C) Momentum (D) Momentum Position Position Sol.fiitjee. ranging from 0 to 9. Kalu Sarai.4 N and (fs − fK)R = Iα. The bubble corresponding to the correct is to be darkened in the ORS.com.. A boy is pushing a ring of mass 2 kg and radius 0. The answer to each of the questions is a single digit integer.IITJEE2011-Paper 1-CPM-14 39. The value of P is Ground Stick Sol. a = Rα ∴ fK = 0. . Ph 46106000. 40. Fax 26513942 website: www. with the mass submerged in water. as shown in the figure.8 N P So. (B) SECTION-IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. Consider the spring-mass system. Sarvapriya Vihar.3 m/s2. FIITJEE House. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficeint of friction between the stick and the ring is (P/10). 29-A.5 m with a stick as shown in the figure. µ = = 0.4 10 P=4 R a N α fk fs Mg FIITJEE Ltd. (4) Now N − fs = ma ∴ fs = 1. 26569493. New Delhi -110016. The stick applies a force of 2N on the ring and rolls it without slipping with an acceleration of 0.

r a 42. MgL = Lα∆T YA 43. then N is (5) mg(sin θ + µcosθ) = 3mg(sinθ − µcosθ) ∴ µ = 0. then N is (9) 2 2 a 2 I = 2 × mr 2 + 2 mr 2 + m 5 2 5 −4 2 I = 9 × 10 kg-m ∴N=9 Sol. The mass of an atom of this radioisotope is 10−25 kg. m. FIITJEE Ltd. Sarvapriya Vihar.. Four point charges. New Delhi -110016. The force required to just push it up the inclined plane is 3 times the force required to just prevent it from sliding down. The system of charges and planar film are in equilibrium. 45. The surface tension of the soap film is γ.com. where ‘k’ is a constant. (3) 1/ N . Fax 26513942 website: www. Kalu Sarai. and q2 a = k γ Sol. The moment of inertia of the system about the diagonal of the square is N × 10−4 kgm2. Ph 46106000.5 kg are placed with their centers at the corners of a square of side 4 cm.5 ∴N=5 The activity of a freshly prepared radioactive sample is 1010 disintegrations per second. each of +q. The mass (in mg) of the radioactive sample is (1) Sol. 1/3 A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of friction is µ.fiitjee. If we define N = 10 µ. Then the value of ‘m’ in kg is nearly (3) Change in length ∆L = ∴ m ≈ 3 kg Sol. . are rigidly fixed at the four corners of a square planar soap film of side ‘a’. The wire is cooled down from 40°C to 30°C to regain its original length ‘L’. 29-A.IITJEE2011-Paper 1-CPM-15 41. 26569493. Sol. FIITJEE House. Four solid spheres each of diameter 5 cm and mass 0. Assume that L ≫ diameter of the wire. whose mean life is 109 s. Young’s modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. Then N is Since Felectric ∝ q2 ∝ γa a2 q2 ∴ a = k γ ∴N=3 44. The coefficient of linear thermal expansion of the steel is 10−5/°C. Steel wire of lenght ‘L’ at 40°C is suspended from the ceiling and then a mass ‘m’ is hung from its free end.

If the magnetic moment of the loop is Nµ0I0sin(300 t). Fax 26513942 website: www. Kalu Sarai.com.005 ohm and of radius 0. The current varies as I = I0cos(300 t) where I0 is constant. A wire-loop of resistance 0. Ph 46106000. (6) µo I L µ (πr 2 ) dI dφ ∴ E ind = − =− 0 dt L dt E So magnetic moment = ind R Binside = µ0ni = = 6µ0I0sin(300t) Therefore. FIITJEE House. n = 6 2 πr FIITJEE Ltd. Sarvapriya Vihar.3 m carries a current I along its curved surface as shown.fiitjee. 29-A. 26569493. A long circular tube of length 10 m and radius 0. New Delhi -110016.IITJEE2011-Paper 1-CPM-16 dN = λN dt dN dt ∴N= = 1010 ×109 = 1019 atoms λ msample = 10−25 × 1019 kg = 1 mg 46..1 m is placed inside the tube with its axis coinciding with the axis of the tube. . then ‘N’ is I Sol.

whose Let a = ˆ i+ˆ j+ k i+ˆ j+ k i−ˆ j− k projection on c is 1 3 . (B) 1 3 (D) 6 Sol. sinθ = In set Q. Sarvapriya Vihar. Kalu Sarai.com. A vector v in the plane of a and b .fiitjee. Let (x0. 49. is given by ˆ (A) ˆ i − 3ˆ j + 3k ˆ (C) 3ˆ i−ˆ j + 3k ˆ (B) −3ˆ i − 3ˆ j+ k ˆ (D) ˆ i + 3ˆ j − 3k FIITJEE Ltd. y0) be solution of the following equations (2x)ln2 = (3y)ln3 3lnx = 2lny Then x0 is 1 (A) 6 1 (C) 2 (C) (2x)ln2 = (3y)ln3 …(i) 3lnx = 2lny …(ii) ⇒ (logx) (log3) = (logy)log2 (log x )(log 3) ⇒ logy = …(iii) log 2 In (i) taking log both sides (log2) {log2 + logx} = log3{log3 + logy} (log2)2 + (log2) (logx) = (log3)2 + ⇒ (log2)2 − (log3)2 = ⇒ x= 48. New Delhi -110016. Each question has four choices (A). Fax 26513942 website: www. ˆ. 47.III: MATHEMATICS SECTION – I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. 29-A. Then (A) P ⊂ Q and Q − P ≠ ∅ (B) Q ⊄ P (C) P ⊄ Q (D) P = Q (D) In set P. FIITJEE House. (C) and (D) out of which ONLY ONE is correct. 2 2 Let P = {θ : sin θ − cos θ = 2 cos θ} and Q = {θ : sin θ + cos θ = 2 sin θ} be two sets.. .IITJEE2011-Paper 1-CPM-17 PART . b = ˆ ˆ and c = ˆ ˆ be three vectors. (log 3)2 (log x) log 2 from (iii) (log 3) 2 − (log 2)2 (log x) ⇒ −log2 = logx log 2 1 1 ⇒ x0 = . (B). ( ) 2 + 1 cos θ ⇒ tanθ = ) 2 +1 ( 2 − 1 sin θ = cos θ ⇒ tan θ = 1 2 −1 = 2 + 1 ⇒ P = Q. Ph 46106000. 26569493. Sol.

If L also 3y − x + 3 + 2 3 = 0 (D) 3y + x − 3 + 2 3 = 0 Sol. −2) ( ) Let α and β be the roots of x2 – 6x – 2 = 0. A straight line L through the point (3.3x + 1 m ⇒ m+ 3 = ± ( 3 − 3m ) (0. The value of ∫ ln 2 sin x 2 + sin ( ln 6 − x 2 ) x sin x 2 dx is 1 3 ln 2 2 1 3 (D) ln 6 2 1 3 ln 4 2 3 (C) ln 2 (A) Sol. (B) m+ 3 1 − 3m = 3 y =. If an = αn – β n for n ≥ 1. Fax 26513942 website: www. Ph 46106000. −2) is inclined at an angle 60° to the line intersects the x-axis. with α > β . FIITJEE House. 3 ∴ Equation is y + 2 = 3 ( x − 3) 3x − y − 2 + 3 3 = 0 (3. . (B) (A) x2 = t ⇒ 2x dx = dt ln 3 ln 3 sin ( ln 6 − t ) 1 sin t 1 dt and I = ∫ dt I= ∫ 2 ln 2 sin t + sin ( ln 6 − t ) 2 ln 2 sin ( ln 6 − t ) + sin t 2I = ln 3 1 3 1 1dt ⇒ I = ln . ∫ 4 2 2 ln 2 51. (C) v = λ a + µb ˆ +µ ˆ ˆ =λ ˆ i+ˆ j+ k i−ˆ j+ k ( ) ( ) Projection of v on c ˆ⋅ ˆ ( λ + µ ) ˆ −ˆ− ˆ i + (λ − µ) ˆ j + (λ + µ) k v⋅c 1 i j k = 1 = ⇒ |c| 3 3 3 ⇒λ+µ−λ+µ−λ−µ=1⇒µ−λ=1⇒λ=µ−1 ˆ +µ ˆ ˆ = µ 2i ˆ + 2k ˆ −ˆ ˆ v = ( µ − 1) ˆ i+ˆ j+ k i −ˆ j+ k i −ˆ j− k ( ) ( ) ( ) ( ) ˆ v = ( 2µ − 1) ˆ i −ˆ j + ( 2µ − 1) k ˆ−ˆ ˆ.IITJEE2011-Paper 1-CPM-18 Sol.com. 1) 60° ⇒ 4m = 0 ⇒ m = 0 or 2m = 2 3 ⇒ m = ⇒ 52. At µ = 2. Sarvapriya Vihar. v = 3i j + 3k ln 3 50. then the equation of L is (A) y + 3x + 2 − 3 3 = 0 (B) y − 3x + 2 + 3 3 = 0 (C) 3x + y = 1 . then the value of is (A) 1 (C) 3 (B) 2 (D) 4 a10 − 2a 8 2a 9 FIITJEE Ltd. 26569493.. Kalu Sarai. New Delhi -110016.fiitjee. 29-A.

y ∈ R. 29-A.. 26569493. (B). FIITJEE Ltd. y = 0 and x = 0 into two parts R1(0 ≤ x 1 ≤ b) and R2(b ≤ x ≤ 1) such that R1 − R2 = . C) ∵ f(0) = 0 and f′(x) = lim = = lim h →0 h →0 f (x + h ) − f (x) h f (h) = f′(0) = k(say) h ⇒ f(x) = kx + c ⇒ f(x) = kx (∵ f(0) = 0). 2 3 12 8 3 SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. FIITJEE House. Fax 26513942 website: www. 2a 9 Let the straight line x = b divides the area enclosed by y = (1 − x)2. (B. Let f: R → R be a function such that f(x + y) = f(x) + f(y).fiitjee. Kalu Sarai. If f(x) is differentiable at x = 0. (C) an = αn − β n α2 − 6α − 2 = 0 Multiply with α8 on both sides ⇒ α10 − 6α9 − 2α8 = 0 …(i) …(ii) similarly β 10 − 6β9 − 2β8 = 0 (i) and (ii) ⇒ α10 − β 10 − 6(α9 − β 9) = 2(α8 − β 8) a − 2a 8 ⇒ a10 − 6a9 = 2a8 ⇒ 10 =3. New Delhi -110016. Sol. 1 4 ⇒ ⇒ ( x − 1) 3 3 b − 0 ( x − 1)3 3 1 R1 o b 1 = 4 3 R2 b 1 ( b − 1) 1 ( b − 1) 1 + −0 − = 3 3 3 4 3 2 ( b − 1) 1 1 1 ⇒ =− ⇒ (b – 1)3 = – ⇒ b = .IITJEE2011-Paper 1-CPM-19 Sol. Ph 46106000. then (A) f(x) is differentiable only in a finite interval containing zero (B) f(x) is continuous ∀ x ∈ R (C) f′(x) is constant ∀ x ∈ R (D) f(x) is differentiable except at finitely many points Sol. ∀ x. . 54. Each question has four choices (A). Then b equals 4 3 1 (A) (B) 4 2 1 1 (C) (D) 4 3 (B) ∵ ∫ (1 − x ) dx − ∫ (1 − x ) dx = 2 2 0 b b 1 53.com. Sarvapriya Vihar. (C) and (D) out of which ONE or MORE may be correct.

. 0). If the a 2 b2 hyperbola passes through a focus of the ellipse. Let M and N be two 3 × 3 non-singular skew symmetric matrices such that MN = NM. 0 . 0 ≡ (2. 29-A. New Delhi -110016. (C) MN = NM M2N2(MTN)−1(MN−1)T M2N2N−1(MT)−1(N−1)T. and perpendicular to the vector The vector(s) which is/are coplanar with vectors ˆ i+ˆ j + 2k i + 2ˆ j+ k ˆ ˆ is/are i+ˆ j+ k ˆ (A) ˆ j− k (C) ˆ i −ˆ j (B) −ˆ i+ˆ j ˆ (D) −ˆ j+ k Sol.IITJEE2011-Paper 1-CPM-20 55. r ⋅ c = 0 ⇒ λ + µ = 0 ⇒ r a b = 0 .com. Fax 26513942 website: www.(MT)−1(N−1)TMT = −M2. then (A) the equation of the hyperbola is x2 − y2 x 2 y2 − =1 3 2 5 3 (B) a focus of the hyperbola is (2. Let the eccentricity of the hyperbola = 1 be reciprocal to that of the ellipse x2 + 4y2 = 4. 0) (D) the equation of the hyperbola is x2 – 3y2 = 3 (C) the eccentricity of the hyperbola is Sol. Kalu Sarai. 56.NMM−1N−1M = −MNN−1M = −M2. Sarvapriya Vihar. FIITJEE House.fiitjee. Ph 46106000. D) Ellipse is x 2 y2 + =1 2 2 12 12 = 22 (1 − e2) ⇒ e = 3 2 2 4 ⇒ b2 = a 2 − 1 ⇒ 3b2 = a2 3 3 ∴ eccentricity of the hyperbola is Foci of the ellipse are ( 3. 0 ) ( ) 3 = 1 ⇒ a2 = 3 and b2 = 1 2 a ∴ Equation of hyperbola is x2 − 3y2 = 3 2 Focus of hyperbola is (ae. FIITJEE Ltd. (A. ˆ and ˆ ˆ . Hyperbola passes through ( ) 3. If PT denotes the transpose of P.N(M)−1(NT)−1MT = +M2NM−1N−1MT = −M.MT = M2N. 0) ≡ 3 × . D) ˆ and ˆ ˆ is r = ( λ + µ ) ˆ ˆ Any vector in the plane of ˆ i+ˆ j + 2k i + 2ˆ j+ k i + ( λ + 2µ ) ˆ j + ( 2λ + µ ) k Also. then M2N2 (MTN)–1 (MN–1)T is equal to (A) M2 (B) – N2 2 (C) – M (D) MN Sol. 0 and − 3. 26569493. (B. 3 57. .

b and c be three real numbers satisfying [ a b c ] 8 2 7 = [0 0 0] 7 3 7 60. 29-A. Paragraph for Question Nos. 2 5 2 5 2 2 3 C2 C2 2 C2 3 2 59. (D) a + 8b + 7c = 0 9a + 2b + 3c = 0 FIITJEE Ltd. Based upon one of paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. A fair coin is tossed. Now 1 ball is drawn at random from U2. lies on the plane 2x + y + z = 1.fiitjee. 23 / 30 23 W P (W / T ) ⋅ P ( T ) + ( W / H ) ⋅ P ( H ) Paragraph for Question Nos. Sarvapriya Vihar. Fax 26513942 website: www. Ph 46106000. Each of these questions has four choices (A). and U2 contains only 1 white ball. the probability that head appeared on the coin is 17 11 (A) (B) 23 23 15 12 (C) (D) 23 23 (D) Sol. (B). 13 2 1 ×1 + × 12 P( W / H) × P( H) H 25 5 2 P = = = . If head appears then 1 ball is drawn at random from U1 and put into U2. New Delhi -110016. ……(E) If the point P(a. with reference to (E). (C) and (D) out of which ONLY ONE is correct. 26569493. c). The probability of the drawn ball from U2 being white is 13 (A) (B) 30 19 (D) (C) 30 (B) H → 1 ball from U1 to U2 T → 2 ball from U1 to U2 E : 1 ball drawn from U2 P/W from U2 = 23 30 11 30 Sol. 60 to 62 1 9 7 Let a.. However. FIITJEE House.com. 1 3 1 2 1 1 3 C 2 1 2 C 2 1 1 3 C1 ⋅2 C1 2 23 × × 1 + × × + × 5 × 1 + × 5 × + × 5 × = 30 . if tail appears then 2 balls are drawn at random from U1 and put into U2. b. Kalu Sarai. 58 to 59 Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls. Given that the drawn ball from U2 is white. 58. then the value of 7a + b + c is (A) 0 (B) 12 (C) 7 (D) 6 Sol. .IITJEE2011-Paper 1-CPM-21 SECTION-III (Total Marls : 15) (Paragraph Type) This section contains 2 paragraphs.

0) C (2. a ω ω ω ω ω ω Let b = 6. The bubble corresponding to the correct is to be darkened in the ORS. ∑ 1 1 α +β n =0 n is (B) 7 (D) ∞ (A) 6 6 (C) 7 Sol. Let ∆1 be the area of the triangle formed by the end points of its latus rectum 1 and the point P .fiitjee. with a and c satisfying (E). Consider the parabola y2 = 8x. then ∞ Sol. and ∆2 be the area of the triangle formed by drawing tangents at P 2 ∆ and at the end points of the latus rectum. Then 1 is ∆2 Sol. 2) P(1/2. New Delhi -110016. If α and β are the roots of the quadratic equation ax2 + bx + c = 0.2. −4) FIITJEE Ltd. 0) x=−2 M (2. (B) ax2 + bx + c = 0 ⇒ x2 + 6x – 7 = 0 ⇒ α = 1. 2 on the parabola. 62. α + β = 1 7 n =0 n =0 ∞ n ∑ ∞ n SECTION-IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. Kalu Sarai. c = – 14 3 1 3 3 1 3 + b + c = 2 + 12 + −14 = –2. β = – 7 ∑ 1 1 1 1 − = 7. b = 6. Ph 46106000. Fax 26513942 website: www. 61. 29-A. Let ω be a solution of x3 – 1 = 0 with Im( ω) > 0. 2) (0. 63.com.. The answer to each of the questions is a single digit integer. If a = 2 with b and c satisfying (E). c = – 7. b and c satisfies (E) b = 12. then the value of 3 1 3 + + is equal to ωa ωb ωc (A) –2 (B) 2 (C) 3 (D) – 3 (A) a = 2. (2) y2 = 8x = 4. 26569493.x ∆LPM =2 ∆ABC ∆1 =2 ∆2 L A (2.IITJEE2011-Paper 1-CPM-22 a+b+c=0 Solving these we get b = 6a ⇒ c = – 7a now 2x + y + z = 0 ⇒ 2a + 6a + (–7a) = 1 ⇒ a = 1. . FIITJEE House. Sarvapriya Vihar. 4) B(0. ranging from 0 to 9.

y = 2 ⇒ 2 = 1 + c ⇒ c = 1 ⇒ y = x2 + x ⇒ f(x) = x2 + x ⇒ f(2) = 6.IITJEE2011-Paper 1-CPM-23 64. (7) π 2π 2π 3π π 2sin cos sin − sin 1 1 1 n n n n n = 1 ⇒ =1 − = π 3π 2π π 3π π 3π 2π sin sin sin sin sin sin sin sin n n n n n n n n 4π 3π 4π 3π ⇒ sin = sin ⇒ + = π ⇒ n = 7. ∞) → [2. sin θ π π sin tan −1 .. New Delhi -110016.fiitjee. d ( tan θ ) d ( tan θ ) =1. . π π d sin θ Let f(θ) = sin tan −1 . = 1 x dx x dx x integrating y = x+c x Put x = 1. (6) 6 f ( t ) dt = 3x f(x) – x3 ⇒ 6f(x) = 3f(x) + 3xf′(x) – 3x2 1 ∫ x ⇒ 3f(x) = 3xf′(x) – 3x2 ⇒ xf′(x) – f(x) = x2 dy dy 1 − y = x2 ⇒ − y = x …(i) ⇒ x dx dx x I. 66. 26569493. Ph 46106000. Let f: [1. ∞) be a differentiable function such that f(1) = 2. If 6 f ( t ) dt = 3xf ( x ) − x 3 for all x ≥ 1 ∫ x 1. = e ∫ − x dx = e − loge x 1 x 1 Multiplying (i) both sides by 1 dy 1 d 1 − 2 y = 1⇒ y. where θ ∈ − . then the value of f(2) is Sol. where − 4 < θ < 4 . 65. FIITJEE House. n n n n sin FIITJEE Ltd.com. Fax 26513942 website: www. Then the value of d ( tan θ ) ( f ( θ ) ) is cos 2θ (1) Sol. 4 4 cos 2θ sin θ sin tan −1 2 2cos θ − 1 = sin ( sin −1 ( tan θ ) ) = tan θ. 29-A. Kalu Sarai.F. Sarvapriya Vihar. The positive integer value of n > 3 satisfying the equation 1 1 1 = + is π 2π 3π sin sin sin n n n Sol.

a1 = 3. then the minimum value of |2z – 6 + 5i| is (5) Length AB = 5 2 ⇒ Minimum value = 5. If ∑a i =1 p i . 2) B (3. (9) a1. 26569493. New Delhi -110016. a2.IITJEE2011-Paper 1-CPM-24 67. a–4. then a2 is Sn Sol. 0) C (3. FIITJEE House. .. If z is any complex number satisfying |z – 3 – 2i| ≤ 2. Sol. a100 be an arithmetic progression with a1 = 3 and Sp = n with 1 ≤ n ≤ 20. 1 ≤ p ≤ 1 00 5n ( 6 + ( 5n − 1) d ) Sm S5n = = 2 n Sn Sn ( 6 − d + nd ) 2 Sm is independent of n of 6 − d = 0 ⇒ d = 6.fiitjee. Sp = ∑a i =1 p i . 1 ≤ p ≤ 100. a8 and a10 with a > 0 is (8) a −5 + a −4 + a −3 + a −3 + a −3 + a 8 + a10 + 1 ≥1 8 minimum value = 8. let m = 5n. … a100 is an A. Let a1. a3. a2. a3. 0) A(3. Kalu Sarai. Sarvapriya Vihar. 29-A. The minimum value of the sum of real numbers a–5. …. Sol.com. For any integer Sm does not depend on n. 1. 3a–3. Fax 26513942 website: www.P. (0. −5/2) 69. Ph 46106000. FIITJEE Ltd. Sn 68.

Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators. 8. Kalu Sarai.FIITJEE Solutions to IIT-JEE-2011 CODE PAPER 2 Time: 3 Hours Please read the instructions carefully. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. please check that all the questions are legible. B. slide rules. 36) of this booklet. Make sure the CODE on the ORS is the same as that on this booklet. Physics and Mathematics).. This question Paper contains 36 pages having 69 questions. 3. If the codes do not match ask for a change of the booklet. Sarvapriya Vihar. Registration No.fiitjee. Filling the Right Part of the ORS: 10. 26569493. 17. 16. 9. New Delhi -110016. for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise There are no negative marks in this section. calculators. 5. In Section IV (Total Marks: 16). The question paper consists of 3 parts (Chemistry. The ORS also has a CODE printed on its Left and Right parts. 12. and the name of centre and sign with pen in the boxes provided.com. In Section I (Total Marks: 24). In Section III (Total Marks: 24). Do not write them anywhere else. Each part consists of four sections. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. with a good quality HB pencil. 29-A. Blank papers. You are allotted 5 minutes specifically for this purpose. for each question you will be awarded 2 marks for each row in which you have darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. FIITJEE Ltd. Fax 26513942 website: www. 7. minus one (–1) mark will be awarded. General: 1. C. Question paper format and Marking scheme: 13. 14. 4. 11. On breaking the seals. 15. DO NOT TAMPER WITH/MULTILATE THE ORS OR THE BOOKLET. There are no negative marks in this section. clipboards. a machine-gradable Optical Response Sheet (ORS). pagers and electronic gadgets are NOT allowed. 6. cellular phones. log tables. In all other cases. Write your Name. There are no negative marks in this section. The answer sheet. FIITJEE House. Thus each question in this section carries a maximum of 8 Marks. Ph 46106000. Darken the appropriate bubble UNDER each digit of your Registration No. 5 Time: 3 Hours Maximum Marks: 240 INSTRUCTIONS A. 2. is provided separately. No additional sheets will be provided for rough work. The question paper CODE is printed on the right hand top corner of this sheet and on the back page (page No. . Write your name and registration number in the space provided on the back page of this booklet. In Section II (Total Marks: 16).

The freezing point (in oC) of a solution containing 0.1 g of K3[Fe(CN)6 (Mol. FIITJEE House.86 K kg mol−1) is (A) −2. Kalu Sarai.IITJEE2011-Paper 2-CPM-2 PAPER-2 [Code – 5] IITJEE 2011 PART . 2. (C) and (D) out of which ONLY ONE is correct. HCl followed by addition to an alkaline solution of β -naphthol is N(CH3 )2 NHCH3 (A) NH2 (B) CH2 NH2 (C) H3C (D) Sol. . Each question has four choices (A). the one that would form a brilliant colored dye on treatment with NaNO2 in dil. Fax 26513942 website: www.3 ×10−2 M W 329 100 Tf' = −2.3 × 10−2 (B) −5. 26569493. 29-A. Sarvapriya Vihar.2 × 10−2 (C) −5.fiitjee. 1. 329) in 100 g of water (Kf = 1. New Delhi -110016..7 × 10 (A) + K3 Fe ( CN )6 → 3K + Fe ( CN )6 i=4 m 1000 0.1 1000 ∆Tf = K f × i × × = 1. (B).3 × 10−2 3− Sol.I: CHEMISTRY SECTION – I (Total Marks : 24) (Single Correct Answer Type) This Section contains 8 multiple choice questions. Wt.86 × 4 × × = 2. Ph 46106000.7 × 10−2 −3 (D) −1. Amongst the compounds given. (C) H3C NaNO2 + HCl → H3C NH2 Oo C − 5o C N N Cl HO HO H H3C N N Cl + OH ( coupling ) → H3C − N N ( β − Nepthol ) Brilliant Colour Dye FIITJEE Ltd.com.

P (C) L. respectively. are (A) II. III in haematite and II in magnetite (C) II in haematite and II. (B) Oxidation states of the metal in the minerals haematite and magnetite. (B) R (B) an acetal (D) an ester + H O + O H O O Acetal O CH2 R 4. III in magnetite (D) Haematite : Fe2O3 : 2x + 3 × (-2) = 0 x =3 Magnetite : Fe3O4 [an equimolar mixture of FeO and Fe2O3] FeO : x – 2 = 0 ⇒ x = 2 Fe2O3 : x = 3 Among the following complexes (K−P) K3[Fe(CN)6] (K). FIITJEE Ltd. Na3[Co(oxalate)3] (M). Ph 46106000. Fax 26513942 website: www. [Co(NH3)6]Cl3 (L). L : [Co(NH3)6]Cl3 M : Na3[Co(Ox)3] O : K2[Pt(CN)4] P : [Zn(H2O)6](NO3)2 Sol. 6. 26569493.com. The following carbohydrate is H OH H O HO HO OH H OH H (B) an aldohexose (D) an α-pyranose H (A) a ketohexose (C) an α-furanose Sol. 6. K2[Pt(CN)4] (O) and [Zn(H2O)6](NO3)2 (P) (A) K. O. New Delhi -110016.fiitjee. M. The major product of the following reaction is RCH 2 OH → H⊕ ( anhydrous ) O (A) a hemiacetal (C) an ether Sol. M. O (C) Following compounds are diamagnetic. . N (B) K.IITJEE2011-Paper 2-CPM-3 3. III in haematite and III in magnetite (B) II. Sarvapriya Vihar. M. 29-A. 5. P (D) L. L. O. III in magnetite (D) III in haematite and II. M.. N. FIITJEE House. [Ni(H2O)6]Cl2 (N). Kalu Sarai.

Bi+3. the cell potential at 25oC is (A) 1. Sol. Consider the following cell reaction: 2Fe(s ) + O 2( g ) + 4H + ( aq ) → 2Fe 2 + ( aq ) + 2H 2 O( ℓ ) E o = 1. of moles of electron involved) From Nernst’s equation.1× (10− 3 ) = 1. FIITJEE House. Y = Br2/NaOH (B) X = CONH2. Ni2+. Fax 26513942 website: www.. Cu2+ and Hg2+ ions in an acidified aqueous solution precipitates (A) CuS and HgS (B) MnS and CuS (C) MnS and NiS (D) NiS and HgS (A) H2S in presence of aqueous acidified solution precipitates as sulphide of Cu and Hg apart from Pb+2. In neutral medium − MnO− → MnO2 + 4OH − 4 + 2H 2 O + 3e Hence.0591 log = 1.0591 Ecell = E o log Q cell − n 2 10−3 ) ( 0. Ph 46106000.87 V (D) 1.77 V (C) 1. .fiitjee. P(O2) = 0. Sb+3 and Sn+2. Y = H2/Ni/heat (C) X = CONH2.57 V Sol. (D) 2Fe ( s ) + O 2 ( g ) + 4H + ( aq ) → 2Fe+2 ( aq ) + 2H 2 O ( ℓ ) N = 4 (no. Passing H2S gas into a mixture of Mn2+. Y = H2/Ni/heat FIITJEE Ltd. 8.IITJEE2011-Paper 2-CPM-4 7. The correct functional group X and the reagent/reaction conditions Y in the following scheme are () X − ( CH 2 ) 4 − X → condensation polymer i Y O O ( ii ) HO C (CH2 ) 4 heat C OH (A) X = COOCH3.com.67 V At [Fe2+] = 10-3 M. Kalu Sarai.1 atm and pH = 3. number of electron loose in acidic and neutral medium 5 and 3 electrons respectively. 0. Each question has four choices (A).47 V (B) 1. Sarvapriya Vihar. New Delhi -110016. 9.67 – 0. As+3.106 = 1. (C) and (D) out of which ONE OR MORE may be correct. Y = H2/Ni/heat (D) X = CN. Cd+2.67 − 4 4 0. (B). 29-A. 10.57 V {∵ H + − pH = 10 } SECTION – II (Total Marks : 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions. Reduction of the metal centre in aqueous permanganate ion involves (A) 3 electrons in neutral medium (B) 5 electrons in neutral medium (C) 3 electrons in alkaline medium (D) 5 electrons in acidic medium (A. 26569493. D) In acidic medium − M nO 4 + 8H + + 5e − → M n 2 + + 4H 2 O Sol.

(A.303 100 t 99.693 Also. t1/2 = . FIITJEE House.303 0.6% completion in eight half-life duration Sol. Fax 26513942 website: www. D) For first order reaction [A] = [A]0e–kt Hence concentration of [NO2] decreases exponentially. ∆ Hoffmann Bromamide Reaction O H2N (CH2)4 NH2 HO C (CH2)4 O C OH Polyamide O H2 / Ni N ≡ C − ( CH 2 )4 − C ≡ N → H 2 N − CH 2 − ( CH 2 ) − CH 2 − NH 2 O HO C (CH2)4 C OH Polyamides 11.. 0. B.IITJEE2011-Paper 2-CPM-5 Sol. (A. (B. C. Cu 2 + + 2CN − → Cu ( CN ) 2 2Cu ( CN )2 → 2CuCN + ( CN )2 FIITJEE Ltd. New Delhi -110016.4 ) = 8 × K K The equilibrium 2Cu I ⇌ Cu o + Cu II in aqueous medium at 25oC shifts towards the left in the presence of − (A) NO3 (B) Cl− (D) CN− 12. . X may be − C− OR or − C− NH 2 or −C ≡ N O O H3CO C (CH2)4 O H2N C (CH2 )4 O C OH O C OH Polyamide Poly − ester O H 2 / Ni → OH − H 2 C ( CH 2 ) 4 − CH 2 − OH C OCH3 O H 2 / Ni NH2 → H 2 N − CH 2 ( CH 2 )4 − CH 2 − NH 2 HO C (CH2 )4 O HO C (CH2)4 C Br2 / OH − . B.6 = log K 0.6 = = 8 t1/ 2 ( 2.com. O || O || Hence. (C) SCN− Sol. Ph 46106000.693 t 99. Which is independent of concentration and t1/2 decreases with the increase of K temperature. Sarvapriya Vihar. D) Cu2+ ions will react with CN− and SCN− forming [Cu(CN)4]3− and [Cu(SCN)4]3− leading the reaction in the backward direction. 29-A. Kalu Sarai. C. D) Condensation polymers are formed by condensation of a diols or diamine with dicarboxylic acids. 26569493.fiitjee.4 2. 2. For the first order reaction 2N 2 O5 ( g ) → 4NO 2 ( g ) + O 2 ( g ) (A) (B) (C) (D) the concentration of the reactant decreases exponentially with time the half-life of the reaction decreases with increasing temperature the half-life of the reaction depends on the initial concentration of the reactant the reaction proceeds to 99.

ranging from 0 to 9. Sarvapriya Vihar. 29-A.fiitjee. CuCl2 + Cu → 2CuCl ↓ SECTION-III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. 13.. Ph 46106000. The total number of contributing structure showing hyperconjugation (involving C−H bonds) for the following carbocation is H3C CH 2 CH 3 Two Enantiomeric pairs = 4 1 1 FIITJEE Ltd.com. New Delhi -110016. FIITJEE House. . The bubble corresponding to the correct answer is to be darkened in the ORS. (8) CH2 CH3 CH3 CH3 CH2 C CH2 CH2 Cl Enantiomeric pair = 2 H CH3 CH3 CH2 C CHCH3 H CH3 CH3 CH2 C CH2 CH3 Cl CH2 Cl CH3 CH2 C CH2 CH3 H Total = 2 + 4 + 1 + 1 = 8 14. The answer to each of the questions is a single-digit integer. 26569493. The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following compound is CH3 C CH3 CH2 H Sol. Fax 26513942 website: www.IITJEE2011-Paper 2-CPM-6 CuCN + 3CN − → Cu ( CN )4 3− 3− Cu 2 + + 4SCN − → Cu ( SCN )4 2+ Cu also combines with CuCl2 which reacts with Cu to produce CuCl pushing the reaction in the backward direction. Kalu Sarai.

1 M AgNO3 required for complete precipitation of chloride ions present in 30 mL of 0. B. Sol.6 × 10-6 = y(x + y) … (ii) On solving (i) and (ii) [Ag+] = 1. if for a given question. The value of “x” is (7) Let the solubility of AgCl is x mollitre-1 and that of CuCl is y mollitre-1 Sol. solid ) → P( red. FIITJEE House. the number of compounds than can react with PCl5 to give POCl3 is O2. darken the bubbles corresponding to q and r in the ORS. 19.6 × 10 -10 = x(x + y) … (i) Similarly Ksp of CuCl = [Cu+][Cl-] 1. For example. as silver chloride is close to (6) Number of ionisable Cl− in [Cr(H2O)5Cl]Cl2 is 2 ∴ Millimoles of Cl− = 30 × 0. 15.0 × 10−6] is added.6 = 0. ..6 ∴ Millimoles of Ag+ required = 0. 26569493. 17. q. H2SO4. Sarvapriya Vihar. SO2. H2O. r. Kalu Sarai. The resultant concentration of Ag+ in the solution is 1.IITJEE2011-Paper 2-CPM-7 Sol. New Delhi -110016. Ph 46106000. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. 0. (6) 6 × H−atoms are there Among the following.6 × 10-7 ∴ x=7 18.6 × 10−x.01 M solution of [Cr(H2O)5Cl]Cl2. 16. P4O10 (5) The volume (in mL) of 0. Fax 26513942 website: www.1 V V = 6 ml In 1 L saturated solution of AgCl [Ksp(AgCl) = 1. AgCl ↽ ⇀ Ag + + Cl − x x + − ⇀ CuCl ↽ Cu + Cl y y ∴ Ksp of AgCl = [Ag+][Cl–1] 1. Sol.6 ∴ 0. then for the particular question. The number of hexagonal faces that are present in a truncated octahedron is (8) SECTION-IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Match the transformations in column I with appropriate options in column II Column I Column II (A) CO 2 ( s ) → CO 2 ( g ) (p) phase transition (B) (C) (D) CaCO3 ( s ) → CaO ( s ) + CO 2 ( g ) 2H i→ H 2 ( g ) (q) (r) (s) (t) allotropic change ∆H is positive ∆S is positive ∆S is negative P( white. CO2. against statement B.1 mol of CuCl [Ksp(CuCl) = 1.6 × 10−10].com. solid ) FIITJEE Ltd. statement B matches with the statements given q and r.01 × 2 = 0. Sol. Each question has four statements (A. C and D) given in Column I and five statements (p. s and t) in Column II. 29-A.fiitjee.

q. t) (B) → (p. t) Match the reactions in column I with appropriate types of steps/reactive intermediate involved in these reactions as given in column II Column I Column II O H3C O O (A) aq. (A) → (p. Sarvapriya Vihar. r. FIITJEE House. s) (C) → (r. Fax 26513942 website: www.fiitjee.IITJEE2011-Paper 2-CPM-8 Sol. 29-A. New Delhi -110016. Ph 46106000. 26569493. . s) (C) → (t) (D) → (p. Kalu Sarai.com.. (A) → (r. s) (B) → (r. s. r) FIITJEE Ltd. NaOH → (p) Nucleophilic substitution O O (B) CH2 CH2CH2Cl → CH 3 MgI (q) CH3 Electrophilic substitution O 18 CH2 CH2CH2OH → H 2 SO 4 18 O (C) (r) Dehydration CH2 CH2 CH2 C(CH3 )2 (D) OH H 2 SO 4 → (s) H3C CH3 Nucleophilic addition (t) Sol. 20. s) Carbanion (D) → (q.

.fiitjee. Sarvapriya Vihar. . If the measured mass of the ball has a relative error of 2 %. the relative percentage error in the density is (A) 0. The ball hits the ground at a distance of 20 m and the bullet at a distance of 100 m from the foot of the post. After the collision.01 × 100 + 0.5 mm and there are 50 divisions on the circular scale.2 kg rests on a vertical post of height 5 m. Which of the field patterns given below is valid for electric field as well as for magnetic field? (A) (B) (C) (D) Sol.com. hits the centre of the ball.4 % (C) 3. The density of a solid ball is to be determined in an experiment.01 V = 0. Fax 26513942 website: www.II: PHYSICS SECTION – I (Total Marks : 24) (Single Correct Answer Type) This Section contains 8 multiple choice questions. Each question has four choices (A). traveling with a velocity V m/s in a horizontal direction. New Delhi -110016. (C) A ball of mass 0.01 kg. Ph 46106000. Kalu Sarai. 21. 22. A bullet of mass 0.1 % (D) 4.2 % (C) diameter = 2. 26569493. 0. The velocity V of the bullet is (A) 250 m/s (C) 400 m/s (B) 250 2 m/s (D) 500 m/s V m/s 0 20 100 Sol.5 × 20 50 FIITJEE Ltd. (D) 5= 1 (10)t 2 ⇒ t = 1 sec 2 vball = 20 m/s vbullet = 100 m/s 0. The diameter of the ball is measured with a screw gauge. the ball and bullet travel independently. (B). FIITJEE House.2 × 20 v = 100 + 400 = 500 m/s 23.IITJEE2011-Paper 2-CPM-9 PART . The reading on the main scale is 2.9 % (B) 2. whose pitch is 0. (C) and (D) out of which ONLY ONE is correct.5 mm and that on the circular scale is 20 divisions. 29-A.5 + Sol.

Kalu Sarai. Ph 46106000.. both as function of θ. 25. 26569493. At the time of its ejection.com. The correct sketch is (A) (B) E +Q Sol. The block carries a charge +Q on its surface. the kinetic energy of the object is 1 (A) mV 2 (B) mV2 2 3 (C) mV 2 (D) 2mV2 2 FIITJEE Ltd.01 =2+3× ×100 2. New Delhi -110016. (A) A light ray travelling in glass medium is incident on glass-air interface at an angle of incidence θ. (B) of the same frequency and with the same mean position (C) of changed frequency and with shifted mean position.70 mm dr dm % error = + 3 × 100 r m 0. A satellite is moving with a constant speed ‘V’ in a circular orbit about the earth. Intensity Intensity R θ 90° 0 θ 90° (C) After total internal reflection. If now a uniform electric field E is switched-on as shown. FIITJEE House. 100% Intensity 100% T R 0 θ Intensity T 90° R 0 θ 90° (C) (D) 100% T 100% T R 0 Sol. (D) of changed frequency and with the same mean position. then the SHM of the block will be (A) of the same frequency and with shifted mean position. An object of mass ‘m’ is ejected from the satellite such that it just escapes from the gravitational pull of the earth. Fax 26513942 website: www.1 % 24. ν0. . Sarvapriya Vihar. 26.IITJEE2011-Paper 2-CPM-10 = 2. there is no refracted ray. are plotted.fiitjee. 29-A. A wooden block performs SHM on a frictionless surface with frequency.70 = 3. The reflected (R) and transmitted (T) intensities.

New Delhi -110016. Adding a third sinusoidal displacement x3(t) = B sin (ωt + φ) brings the mass to a 3 complete rest. The spiral has inner radius ‘a’ and outer radius ‘b’. 4 3 5π π (C) 3 A. The spiral lies in the XY plane and a steady current ‘I’ flows through the wire. (B) mV 2 GMm GMm = ∴ mV2 = 2 r r r A long insulated copper wire is closely wound as a spiral of ‘N’ turns. FIITJEE House. A point mass is subjected to two simultaneous sinusoidal displacements in x-direction. . 26569493. Fax 26513942 website: www. 2π/3 4π/3 FIITJEE Ltd. Kalu Sarai. The values of B and φ are 3π 4π (B) A. (A) 2 A. Ph 46106000. (A) ∫ 2r(b − a) dr a b µ 0 IN = µ 0 IN b dr µ IN b = 0 ln ∫ 2(b − a) a r 2(b − a) a 28. x1(t) = A sin ωt and 2π x2(t) = A sin ωt + .com.. The Z-component of the magnetic field at the centre of the spiral is µ0 NI b (A) ln 2(b − a) a µ0 NI b+a (B) ln 2(b − a) b − a Y 27.IITJEE2011-Paper 2-CPM-11 Sol. I a b X µ 0 NI b ln 2b a µ 0 NI b + a (D) ln 2b b−a (C) Sol.fiitjee. 29-A. 6 3 (B) 2π/3 Sol. (D) A. Sarvapriya Vihar.

Two solid spheres A and B of equal volumes but of different densities dA and dB are connected by a string. Kalu Sarai.5 instead of r−2. (D) there is no friction between the ring and the ground. (B) The Gauss law can be used to calculate the field distribution around an electric dipole (C) If the electric field between two point charges is zero somewhere.75 m 1 m/s Sol. (A.com. The current IR through the resistor and voltage VC across the capacitor are compared in the two cases. (C) or (C. Sol.75 m and goes vertically up with velocity 10 m/s. FIITJEE House. Each question has four choices (A). 26569493. (B). 32. D) A 2dF Vg B 30. (D) The work done by the external force in moving a unit positive charge from point A at potential VA to point B at potential VB is (VB − VA). They get arranged into an equilibrium state as shown in the figure with a tension in the string. 10 m/s 20 m/s 0. 31.. Which of the following is/are true? B B (A) I A (B) I A R > IR R < IR A B (B) VC > VC A B (D) VC < VC FIITJEE Ltd. moving with velocity 20 m/s in the opposite direction hits the ring at a height of 0.5 m is rolling without on a horizontal plane with velocity 1 m/s. They are fully immersed in a fluid of density dF. (C) friction between the ring and the ground is to the left. (A) when C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. (B) the ring comes to a complete stop.fiitjee. then the Gauss law will still be valid.IITJEE2011-Paper 2-CPM-12 SECTION – II (Total Marks : 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions. The arrangement is possible only if (A) dA < dF (B) dB > dF (C) dA > dF (D) dA + dB = 2dF A B Sol. 29-A. B. Ph 46106000. (dA +dB)Vg A thin ring of mass 2 kg and radius 0. A small ball of mass 0. 29. then the sign of the two charges is the same. Immediately after the collision (A) the ring has pure rotation about its stationary CM. Which of the following statement(s) is/are correct? (A) If the electric field due to a point charge varies as r−2. . (C) and (D) out of which ONE OR MORE may be correct. Sarvapriya Vihar. Consider two cases.1 kg. D*) (D) is correct if we assume it is work done against electrostatic force A series R-C circuit is connected to AC voltage source. New Delhi -110016. (C) During collision friction is impulsive and immediately after collision the ring will have a clockwise angular velocity hence friction will be towards left. Fax 26513942 website: www.

The value of ‘Z’ is (7) Stopping potential = Sol. the sphere gets charged and acquires a potential. 29-A.7 eV = 1.15 m inside the train to catch the ball back at the initial height. Ph 46106000. A train is moving along a straight line with a constant acceleration ‘a’.5 eV Kq V= = 1.7 eV is suspended from an insulating thread in freespace. It is under continuous illumination of 200 nm wavelength light. . Sarvapriya Vihar.05 × 107 9 × 109 × 1.5 × 10−2 n= = 1. ranging from 0 to 9.15 = 5 3 − a 2 ⇒ a ≈ 5 m/s2 0 = 10 …(i) …(ii) FIITJEE Ltd. A series R-C combination is connected to an AC voltage of angular frequency ω = 500 radian/s.fiitjee. As photoelectrons are emitted. 3 1 t − 10t 2 2 2 t = 3 sec 3 ⇒ 1. Fax 26513942 website: www. New Delhi -110016. The maximum number of photoelectrons emitted from the sphere is A × 10z (where 1 < A < 10). at an angle of 60° to the horizontal.25 = R 2 + ωC RC = 4 ms 34.IITJEE2011-Paper 2-CPM-13 Sol. The acceleration of the train. The boy has to move forward by 1. If the impedance of the R-C circuit is R 1.com. C) V I= Z I 2 2 V 2 = VR + VC = (IR) 2 + ωC 1 z2 = R 2 + ωC 2 2 SECTION-III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. 1 R 1. FIITJEE House. in m/s2.25 . 26569493.6 × 10−19 Z=7 35. The bubble corresponding to the correct answer is to be darkened in the ORS.2 eV − 4. Kalu Sarai. The answer to each of the questions is a single-digit integer. 33.5 r 1.. (B. the time constant (in millisecond) of the circuit is (4) Sol. A boy standing in the train throws a ball forward with a speed of 10 m/s. is (5) Sol. hc −W λ = 6. 2 A silver sphere of radius 1 cm and work function 4.

Oil of 3 S R = 6 cm µ = 1. FIITJEE House. (5) i= 3 = 1 ampere 3 VA − 6 + 1 − VB = 0 VA − VB = 5 38.0 µ = 7/4 µ = 4/3 7 lies on water making a convex surface of radius of 4 curvature ‘R = 6 cm’ as shown. Kalu Sarai. B Sol. The voltage across AB in volts is A 3V 2Ω 6V 1Ω Sol. . A block of mass 0. Initially the block is at rest and the spring is un-stretched. 29-A.06 m and comes to rest for the first time. An impulse is given to the block as shown in the figure. Fax 26513942 website: www. 26569493. Sarvapriya Vihar.1. An object ‘S’ is placed 24 cm above water surface.com. The coefficient of friction between the block and the floor is 0.18 kg is attached to a spring of force-constant 2 N/m.. The block slides a distance of 0.fiitjee. New Delhi -110016. Then ‘x’ is Sol.IITJEE2011-Paper 2-CPM-14 36. Consider oil to act as a thin lens. Water (with refractive index = refractive index 4 ) in a tank is 18 cm deep. (2) 7 −1 7 1 − = 4 ⇒ V1 = 21 cm 4V1 −24 6 4/3 7/4 − =0 V2 21 V2 = 16 cm x = 18 − 16 = 2 cm FIITJEE Ltd. Ph 46106000. The location of its image is at ‘x’ cm above the bottom of the tank. The initial velocity of the block in m/s is V = N/10. 37. Then N is (4) Applying work energy theorem 1 1 − kx 2 − µmgx = − mV 2 2 2 4 ⇒ V= 10 N=4 Two batteries of different emfs and different internal resistances are connected as shown.

t) (B) → (p.com.IITJEE2011-Paper 2-CPM-15 SECTION-IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. 26569493. Fax 26513942 website: www. (A) → (p. Column I Column II (A) Pipe closed at one end (p) Longitudinal waves O L 40. s and t) in Column II. t) (B) → (p. Column II give the characteristics involved in the cycle. r) λf = 4L FIITJEE Ltd. darken the bubbles corresponding to q and r in the ORS. t) Isobaric compression Process A → B → Isochoric process Process B → C → Isobaric expansion Process C → D → Polytropic with TA = TD Process D → A → Column I shows four systems. For example. Heat is lost Heat is gained Work is done on the gas Sol. One mole of a monatomic gas is taken through a cycle ABCDA as shown in the P-V diagram. Each question has four statements (A. Sarvapriya Vihar. 29-A. Match them with each of the processes given in Column I. for producing standing waves.fiitjee. s) (D) (q. FIITJEE House. 39. s) (D) (r. s) (C) → (q. (A) → (p. if for a given question. q. P 3P B A 1P 0 C 1V 3V D 9V V (A) (B) (C) (D) Column I Process A → B Process B → C Process C → D Process D → A (p) (q) (r) (s) (t) Column II Internal energy decreases Internal energy increases.. New Delhi -110016. r. Kalu Sarai. statement B matches with the statements given q and r. each of the same length L. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. r. The lowest possible natural frequency of a system is called its fundamental frequency. C and D) given in Column I and five statements (p. then for the particular question. against statement B. r) (C) → (q. (B) Pipe open at both ends O L (q) Transverse waves (C) Stretched wire clamped at both ends O L (r) λf = L (D) Stretched wire clamped at both ends and at mid-point O L/2 L (s) λf = 2L (t) Sol. . Match each system with statements given in Column II describing the nature and wavelength of the standing waves. B. Ph 46106000. whose wavelength is denoted as λf.

where (f o g) (x) = f(g(x)).} (C) (B) ± nπ . 2] → [0. Let R1 = −1 ∫ xf (x)dx . ... is (A) ± nπ . n ∈ {1.III: MATHEMATICS SECTION – I (Total Marks : 24) (Single Correct Answer Type) This Section contains 8 multiple choice questions. and the x-axis. .. 29-A. − 1.. . − 1. 26569493. FIITJEE House. 0. π 3 π (D) ± 2 ) = 2b sin 2 θ 1 + b2 ⇒ sin2 θ = 2b 1 + b2 ≥1 ⇒ sin2 θ = 1 as 2b e ln 1+ b2 (D) ( θ = ±π/2. and R 2 2 be the area of the region bounded by y = f(x). (C) and (D) out of which ONLY ONE is correct. 1. Kalu Sarai.fiitjee. π]. Each question has four choices (A). x = −1.. (A) (fogogof) (x) = sin2 (sin x2) (gogof) (x) = sin (sin x2) ∴ sin2 (sin x2) = sin (sin x2) ⇒ sin (sin x2) [sin (sin x2) − 1] = 0 FIITJEE Ltd. b > 0 and θ ∈ (−π. Then (B) R1 = 3R2 (D) 3R1 = R2 (A) R1 = 2R2 (C) 2R1 = R2 Sol.. .. 43.com. n ∈ {.} π + 2nπ. 2]. 2.1... Let f(x) = x2 and g(x) = sinx for all x ∈ R. −2. New Delhi -110016... 2. n ∈ {0. 2 If lim 1 + x ln (1 + b ) x→0 1/ x = 2bsin2θ... ∞) be a continuous function such that f(x) = f(1 − x) for all x ∈[−1. 2.. Then the set of all x satisfying (f o g o g o f) (x) = (g o g o f) (x).. 2.. 41. 42.} 2 Sol.IITJEE2011-Paper 2-CPM-16 PART . n ∈ {. Ph 46106000. Sarvapriya Vihar. 0... (B). Fax 26513942 website: www. x = 2. then the value of θ is (B) ± π 4 π (C) ± 6 (A) ± Sol..} (D) 2 nπ.1. (C) R1 = 2 −1 ∫ xf ( x ) dx = 2 −1 ∫ ( 2 − 1 − x ) f ( 2 − 1 − x ) dx 2 −1 2 = −1 ∫ (1 − x ) f (1 − x ) dx = ∫ (1 − x ) f ( x ) dx −1 Hence 2R1 = ∫ f ( x ) dx = R 2 2 . −2. . Let f : [−1.

n ∈ I ⇒ sin x2 = 0 ⇒ x2 = nπ ⇒ x = ± nπ . (B) (B) (D) 3 2 3 Equation of normal is (y − 3) = 46. FIITJEE Ltd.. Let P be the point that divides the line segment from (0. . Sarvapriya Vihar. 44. (B) x2 + bx − 1 = 0 x2 + x + b = 0 … (1) Common root is (b − 1) x − 1 − b = 0 b +1 ⇒x= b −1 This value of x satisfies equation (1) ⇒ ( b + 1) b + 1 + +b =0 2 ( b − 1) b − 1 2 ⇒b= 3i. FIITJEE House. 1. − 3i.IITJEE2011-Paper 2-CPM-17 ⇒ sin (sin x2) = 0 or 1 ⇒ sin x2 = nπ or 2mπ + π/2. y) be any point on the parabola y2 = 4x. 0 . New Delhi -110016. n ∈ {0. …}. 2 ( 2b 2b 2 2 A value of b for which the equations x2 + bx − 1 = 0 x2 + x + b = 0. x2 a2 0). If the normal at the point P intersects the x-axis at (9. 3) be a point on the hyperbola (h. where m. k) P (4h.fiitjee. (A) (C) Sol. Let (x. then the eccentricity of the hyperbola is 5 2 2 − y2 b2 = 1 . 2. 0) to (x. 29-A.com. −a 2 a2 3 x − 6) ⇒ =1 ⇒ e = . have one root in common is (A) − 2 (C) i 5 (B) −i 3 (D) 2 Sol. Ph 46106000. O (0. Fax 26513942 website: www. 4k) Q Sol. 26569493. Kalu Sarai. 0) 45. y) in the ratio 1 : 3. Then the locus of P is (A) x2 = y (B) y2 = 2x 2 (C) y = x (D) x2 = 2y (C) y2 = 4x and Q will lie on it ⇒ (4k)2 = 4 × 4h ⇒ k2 = h ⇒ y2 = x (replacing h by x and k by y) Let P(6.

π π x≤− −x − 2 . ω) and (ω. − 4 ∴ Circle passes through (− 4. x >1 (A) f(x) is continuous at x = − π/2 (C) f(x) is differentiable at x = 1 (A. b. B.. Then the number of distinct matrices in the set S is (A) 2 (B) 6 (C) 4 (D) 8 (A) For being non-singular 1 a b b 1 c . (C) and (D) out of which ONE OR MORE may be correct. 26569493. 0 2 2 3 5 (C) − . 2 (A) − . 48. ω). 29-A. 1 Let ω ≠ 1 be a cube root of unity and S be the set of all non-singular matrices of the form ω ω2 where each of a. Kalu Sarai.IITJEE2011-Paper 2-CPM-18 47. ω. Each question has four choices (A). c) is 2. 49. . 2) also passes through the point 3 5 (B) − .e. − < x ≤ 0 . ω ω2 1 c ≠0 ω 1 ⇒ acω2 − (a + c)ω + 1 ≠ 0 Hence number of possible triplets of (a.fiitjee. (ω. Fax 26513942 website: www. π lim + f ( x ) = cos − = 0 π 2 x →− 2 FIITJEE Ltd. D) lim − f ( x ) = 0 = f ( −π / 2 ) x →− π 2 (B) f(x) is not differentiable at x = 0 (D) f(x) is differentiable at x = −3/2 Sol. i. (D) (−4. ω2. The circle passing through the point (−1. b. then 2 0 < x ≤1 x − 1. FIITJEE House. ω 1 a Sol. SECTION – II (Total Marks : 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions. 2 π If f ( x ) = − cos x. 0) Sol. and c is either ω or ω2. ln x. (B). Sarvapriya Vihar. 0) and touching the y-axis at (0. 0) ∴1+4−λ=0⇒λ=5 ∴ x2 + y2 + 5x − 4y + 4 = 0 Put y = 0 ⇒ x = − 1.com. 0) 2 2 (D) Circle touching y-axis at (0. C. Ph 46106000. New Delhi -110016. 2) is (x − 0)2 + (y − 2)2 + λx = 0 passes through (− 1.

D) y2 = 4x Equation of normal is y = mx – 2m – m3. 1) 1 f ′ (0) Sol. FIITJEE House. 2. y – 2x + 12 = 0. 1) → R be defined by f (x) = (A) f is not invertible on (0. B. Let E and F be two independent events. y + 3x – 33 = 0. It passes through (9.. Fax 26513942 website: www. Let f : (0. sin x. If P(T) denotes the probability of occurrence of the event T. then L is given by (A) y − x + 3 = 0 (B) y + 3x − 33 = 0 (C) y + x − 15 = 0 (D) y − 2x + 12 = 0 Sol. Let L be a normal to the parabola y2 = 4x. Then 1 − bx 1 (B) f ≠ f−1 on (0. 25 1 2 (B) P( E) = . P( F) = 5 5 2 1 (C) P( E) = . New Delhi -110016. The probability that exactly one of them occurs is probability of none of them occurring is then 52. x >1 Clearly. f (x) is not differentiable at x = 0 as f´(0−) = 0 and f´(0+) = 1. f (x) is differentiable at x = 1 as f′ (1–) = f′ (1+) = 1. 1) and f ′ ( b ) = b−x . 51. −π / 2 < x ≤ 0 f ′( x ) = 0 < x ≤1 1. 26569493. P( F) = 5 5 3 4 (D) P( E) = . where be is a constant such that 0 < b < 1. 29-A. P( F) = 5 5 (A) P( E) = FIITJEE Ltd. 1/ x. If L passes through the point (9. 1) and f ′ ( b ) = f ′ (0) (D) f−1 is differentiable on (0.IITJEE2011-Paper 2-CPM-19 x ≤ −π / 2 −1. 50. P( F) = 5 5 4 3 .com. Sarvapriya Vihar. – 3 ⇒ y – x + 3 = 0. 1) (C) f = f−1 on (0. (A. Ph 46106000.fiitjee. Kalu Sarai. 6) ⇒ m3 – 7m + 6 = 0 ⇒ m = 1. 6). 11 and the 25 2 . . (A) b−x 1 − bx b−y b−x Let y = ⇒x= 1 − by 1 − bx f(x) = 0<x<1⇒0< b−y <1 1 − by b−y 1 > 0 ⇒ y < b or y > 1 − by b b−y 1 –1<0⇒–1<y< 1 − by b ∴ – 1 < y < b.

FIITJEE House. − lie inside. 4 2 4 4 4 8 4 then the number of point(s) in S lying inside the smaller part is Sol. If 3 5 3 1 1 1 1 S = 2. New Delhi -110016. (A. 4 4 4 L: 2x –3y –1 S: x2 + y2 – 6 FIITJEE Ltd. we get 4 3 3 4 e = . . (9) r ×b = c×b taking cross with a a × ( r × b) = a × (c × b) (a ⋅ b) r − (a ⋅ r ) b = a × ( c × b) ˆ + 6ˆ ˆ ⇒ r = −3i j + 3k r ⋅b = 3+6 = 9. Sarvapriya Vihar.IITJEE2011-Paper 2-CPM-20 Sol. D) Let P (E) = e and P (F) = f 11 P (E ∪ F) − P (E ∩ F) = 25 11 ⇒ e + f − 2ef = 25 2 P ( E ∩ F) = 25 2 ⇒ (1 − e) (1 − f) = 25 2 ⇒ 1 − e − f + ef = 25 From (1) and (2) 12 7 ef = and e + f = 25 5 Solving. . Fax 26513942 website: www. 54. . 26569493. then the value of r ⋅ b is Sol. 1 3 1 ∴ 2. . 5 5 5 5 … (1) … (2) SECTION-III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. − . . b = −ˆ ˆ be three given vectors. (2) L: 2x – 3y – 1 S: x2 + y2 – 6 If L1 > 0 and S1 < 0 Then point lies in the smaller part. . 29-A. The bubble corresponding to the correct answer is to be darkened in the ORS. f = .fiitjee. f = or e = . and . The answer to each of the questions is a single-digit integer. The straight line 2x − 3y = 1 divides the circular region x2 + y2 ≤ 6 into two parts. ˆ . . If r is a vector such that r × b = c × b Let a = −ˆ i−k i + j and c = ˆ i + 2ˆ j + 3k and r ⋅ a = 0 . Kalu Sarai. ranging from 0 to 9.com. Ph 46106000. 53..

and a. c. . df (x ) and g(x) is a given nondx constant differentiable function on R with g(0) = g(2) = 0. x. z be non-zero complex numbers such that a+b+c=x a + b ω + c ω2 = y a + b ω2 + c ω = z. Let y′(x) + y(x)g′(x) = g(x)g′(x). M −1 = 1 . (1) + 1 y(2) = 0. y. 1 = (0 – 1) . 26569493. where f′(x) denotes 57. New Delhi -110016. then x = 3a y = a (1 + ω + ω2) = a (1 + i 3 ) z = a (1 + ω2 + ω) = a (1 + i 3 ) ∴ |x|2 + |y|2 + |z|2 = 9 |a|2 + 4 |a|2 + 4 |a|2 = 17 |a|2 ∴ | x |2 + | y |2 + | z |2 |a| +|b| +|c| 2 2 2 = 17 3 ( 2 π / 3) Note: However if ω = ei 56. Kalu Sarai. .. Ph 46106000. Let ω = eiπ/3. and M 1 = 0 . (0) y′(x) + y(x) g′(x) = g(x) g′(x) ⇒ eg(x) y′(x) + eg(x) g′(x) y(x) = eg(x) g(x) g′(x) d ( y ( x ) eg( x ) ) = eg(x) g(x) g′(x) ⇒ dx ∴ y(x) = eg(x) = = t ∫e g( x ) g ( x ) g ′ ( x ) dx ∫ e tdt . 1 + c ⇒ c = 1 Put x = 2 ⇒ y(2) . x ∈ R. Sarvapriya Vihar. Then the value of y(2) is Sol. b. where g(x) = t = (t – 1) et + c ∴ y(x) eg(x) = (g(x) – 1) eg(x) + c Put x = 0 ⇒ 0 = (0 – 1) . Then the value of x +y +z a +b +c 2 2 2 2 2 2 is Sol. 58.IITJEE2011-Paper 2-CPM-21 55.com.fiitjee. Sol. y(0) = 0. Fax 26513942 website: www. c If we consider a = b = c. (3) The expression may not attain integral value for all a. FIITJEE House. The number of distinct real roots of x4 − 4x3 + 12x2 + x − 1 = 0 is (2) Let f (x) = x4 − 4x3 + 12x2 + x − 1 = 0 f′ (x) = 4x3 − 12x2 + 24x + 1= 4 (x3 − 3x2 + 6x) + 1 f″ (x) = 12x2 − 24x + 24 = 12 (x2 − 2x + 2) f″(x) has 0 real roots f (x) has maximum 2 distinct real roots as f (0) = –1. 29-A. Let M be a 3 × 3 matrix satisfying 0 −1 1 1 1 0 M 1 = 2 . then the value of the expression = 3. b. 0 3 0 −1 1 12 Then the sum of the diagonal entries of M is FIITJEE Ltd.

. if for a given question. against statement B. For example. s and t) in Column II. q.fiitjee. 29-A. Match the statements given in Column I with the values given in Column II Column − I (A) Column − II (p) ˆ . SECTION-IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. z ≠ 1 is given 1− z by (s) (t) Sol. Fax 26513942 website: www. C and D) given in Column I and five statements (p. 59. statement B matches with the statements given q and r.. then for the particular question. d = 3. (A) → (q) (B) → (p) a − b = −1 + 3 = 2 (C) → (s) (D) → (t) π 2 a = 2. Sarvapriya Vihar. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. b = 2 cosθ = 2 1 = 2× 2 2 FIITJEE Ltd. FIITJEE House. Each question has four statements (A. Kalu Sarai.com. B. Ph 46106000. (9) a b c Let M = d e f g h i 0 −1 M 1 = 2 ⇒ b = − 1. New Delhi -110016. then the value of f is 6 (q) 2π 3 π 3 π (C) The value of π2 ln 3 5/ 6 ∫ sec ( πx ) dx is (r) 7/6 (D) 1 The maximum value of Arg for |z| = 1. darken the bubbles corresponding to q and r in the ORS. (A).IITJEE2011-Paper 2-CPM-22 Sol. 26569493. b = −ˆ ˆ and c = 2 3k ˆ form a triangle. h = 3 0 3 1 1 M −1 = 1 ⇒ a = 0. r. then If a = ˆ j + 3k j + 3k the internal angle of the triangle between a and b is b π 6 (B) If ∫ ( f ( x ) − 3x ) dx = a a 2 π − b 2 . g = 2 0 −1 1 0 M 1 = 0 ⇒ g + h + i = 12 ⇒ i = 7 1 12 ∴ Sum of diagonal elements = 9. e = 2.

z ≠ ±1 is (B) 8(3) x − 2 The domain of the function f (x ) = sin −1 is 1 − 32( x −1) (q) (C) 1 tan θ 1 If f (θ) = − tan θ 1 tan θ . ∞) } (r) [2. ln 3 6 6 6 6 (D). (A). 29-A. (A) → (s) (B) → (t) (C) → (r) 2i(x + iy) 2i(x + iy) z= = 1 − (x + iy) 2 1 − (x 2 − y 2 + 2ixy) Using 1 − x2 = y2 2ix − 2y 1 Z= =− . then f(x) is increasing in Sol. 1 1 ⇒z=1– 1− z u 1 |z| = 1 ⇒ 1 − = 1 u ⇒ |u – 1| = |u| ∴ locus of u is perpendicular bisector of line segment joining 0 and 1 π ⇒ maximum arg u approaches but will not attain. x ≥ 0. 5/6 π2 ln ( sec πx + tan πx ) 7 / 6 ln 3 π (C)..com.fiitjee. 3 3 3 2 (B). 2 Let u = Match the statements given in Column I with the intervals/union of intervals given in Column II 60. ∞) (−∞. 0) ∪ (0. ∞) (−∞. −1] ∪ [1. Column − I (A) Column − II (p) (−∞.IITJEE2011-Paper 2-CPM-23 θ= b π 2π 2π but its as its opposite to side of maximum length. Fax 26513942 website: www. Sarvapriya Vihar. . 26569493. ∫ ( f ( x ) − 3x ) dx = a ∫ a a b − b2 f ( x ) dx = 3( 2 −a 2 + b 2 b − a 2 ) + a 2 − b2 = 2 2 ⇒ f(x) = x. −1) ∪ (1. FIITJEE House. Ph 46106000. New Delhi -110016. π 5π 5π 7π 7π − ln sec + tan = ln sec + tan = π. ∞) (D) If f(x) = x3/2(3x − 10). Kalu Sarai. . ∞) 2iz The set Re 2 1− z : z is a complex number . then the set −1 − tan θ 1 { f (θ) : 0 ≤ θ < π is 2 (s) (t) (−∞. y 2y 2 − 2ixy (D) → (r) FIITJEE Ltd. z = 1. 0] ∪ [2.

R1 → R1 + R3 0 f (θ) = − tan θ 0 1 − tan θ 2 2 tan θ 1 −1 2 (D). 3x − 3x − 2 +1 ≥ 0 Case −II: 1 − 32x − 2 (3x − 2 − 1)(3x + 1) ⇒ ≥0 (3x ⋅ 3x − 2 − 1) ⇒ x ∈ (− ∞. FIITJEE House. 1 1 ≤ −1 or − ≥ 1 . Kalu Sarai. ⇒ − 1≤ 1 − 32x − 2 3x − 3x − 2 −1 ≤ 0 Case −I: 1 − 32x − 2 (3x − 1)(3x − 2 − 1) ⇒ ≥0 (32x − 2 − 1) ⇒ x ∈ (− ∞.fiitjee. y y For domain 8 ⋅ 3x − 2 ≤1 −1≤ 1 − 32(x −1) 3x − 3x − 2 ≤1. 29-A. 3 1/ 2 15 1/ 2 3/ 2 f´(x) = ( x ) ( 3x − 10 ) + ( x ) × 3 = ( x ) ( x − 2) 2 2 Increasing. ∞) So.IITJEE2011-Paper 2-CPM-24 ∵ –1 ≤ y ≤ 1 ⇒ – (B). when x ≥ 2. 0] ∪ [2. = 2 (tan θ + 1) = 2 sec θ. x ∈ (− ∞. (C).com.. ∞). Sarvapriya Vihar. New Delhi -110016. 1) ∪ [2. FIITJEE Ltd. Ph 46106000. . ∞). 0] ∪ (1. Fax 26513942 website: www. 26569493.

minus one (–1) mark will be awarded. calculators. DO NOT TAMPER WITH/MULTILATE THE ORS OR THE BOOKLET. This Question Paper contains 69 questions. The question paper consists of 3 parts (Chemistry. 3. 16. The answer sheet. slide rules. No additional sheets will be provided for rough work. 9. Write your name and registration number in the space provided on the back page of this booklet. 12. There are no negative marks in this section. . Write your Name. minus one (–1) mark will be awarded. 11. Registration No. Each part consists of four sections. a machine-gradable Optical Response Sheet (ORS). 4. In Section IV (Total Marks: 28). for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. In all other cases. In all other cases. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. 7. The question paper CODE is printed on the right hand top corner of this sheet. 14. 6. cellular phones. log tables. Darken the appropriate bubble UNDER each digit of your registration No. Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators. Make sure the CODE on the ORS is the same as that on this booklet. 15. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In Section III (Total Marks : 15). with a good quality HB pencil. is provided separately. In Section I (Total Marks: 21). please check that all the questions are legible. Filling the Right Part of the ORS: 10. 5. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. Blank papers. Physics and Mathematics). 2. clipboards. pagers and electronic gadgets are NOT allowed. 8. There are no negative marks in this section. If the codes do not match. 17. You are allotted 5 minutes specifically for this purpose. In Section II (Total Marks: 16). Do not write them anywhere else. Question paper format and Marking Scheme: 13. C.® (Code: 6) Time: 3 Hours SOLUTIONS TO IIT-JEE 2011 Paper-I Maximum Marks: 240 Please read the instructions carefully. and the name of centre and sign with pen in the boxes provided. INSTRUCTIONS A. The ORS also has a CODE printed on its Left and Right parts. General: 1. B. ask for a change of the booklet. On breaking the seals.

T. the most acidic is (A) p-nitrophenol (C) o-hydroxybenzoic acid (B) p-hydroxybenzoic acid (D) p-toluic acid 1 F = 96500 C mol–1 1 eV = 1. Extra pure N2 can be obtained by heating (A) NH3 with CuO (C) (NH4)2Cr2O7 Nitrogen gas is obtained in the following reactions: 2NH3(g) + 3CuO(s) (NH4)2 Cr2O7(s) Ba(N3)2(s) ∆ ∆ ∆ (B) NH4NO3 (D) Ba(N3)2 Sol.: 2653 7392/93/94/95 Fax: 2653 7396 . Correct choice: (C) The major product of the following reaction is O C NH C O O (A) C N—CH2 C O O (C) C N O—CH2 Br (i) KOH (ii) Br CH2Cl 2. New Delhi-110 016 Ph. Chennai-600 017 Delhi Office: 50-C. (B).626 × 10–34 Js c = 3. Head Office: 12. Br (B) ® O C N C O O C N O CH2Cl (D) CH2Cl O O C C O O C C O N K+ H2O – + Sol. Nagar. Note: Questions with (*) mark are from syllabus of class XI. Each question has four choices (A).: o-Hydroxybenzoic acid is most acidic among the given compounds due to ortho effect and stabilization of its conjugate base by intramolecular hydrogen bonding.® IIT−JEE 2011 SOLUTIONS 2 SOLUTIONS TO IIT-JEE 2011 CHEMISTRY: Paper-I (Code: 6) PART – I Useful Data R = 8.0 × 108 m s–1 SECTION – I (Total Marks: 21) (Single Correct Answer Type) This section contains 7 multiple choice questions.602 × 10–19 J NA = 6.: N2(g) + 3Cu(s) + 3H2O(g) N2(g) + Cr2O3(s) + 4H2O(g) Ba(s) +3N2(g) Brilliant Tutorials Pvt. out of which ONLY ONE is correct. (C) and (D).206 × 10–2 L atm K–1 mol–1 h = 6. Ltd.314 JK–1 mol–1 or 8.022 × 1023 Sol. Masilamani Street. Among the following compounds. Kalu Sarai (Behind Azad Apartments). *1.: C NH + KOH C O O C C N K+ Br – + CH2—Cl N—CH2 Br O Correct choice: (A) 3.

it does not contribute to conductivity.: 1120 120 = 2. Y and Z respectively are 27 13 Al (ii) 30 15 P +Y (i) 30 14 Si +X 30 14 Si +Z (A) proton.® IIT−JEE 2011 SOLUTIONS Extra pure N2 is obtained by heating Ba(N3)2 in vacuum as no gaseous by-product is formed in the reaction.: When AgNO3 is added to KCl. whereas it forms [Ni(CN)4]2– with CN– and [Ni(H2O)6]2+ with H2O.: 4 2 He 30 14 Si + 1 1H (X) 30 14 Si + 0 e +1 (Z) Correct choice: (A) 6.: Correct choice: (B) 5. The molarity of the solution is (A) 1. (C) square planar.78 M (B) 2. Number of moles of solute = 1. square planar and octahedral respectively. T. (D) octahedral. after the point of equivalence. proton (D) positron. Ltd. CN– and H2O. positron. Masilamani Street. positron. tetrahedral and octahedral. Chennai-600 017 Delhi Office: 50-C. tetrahedral and square planar. Sol. The hybridisation of Ni2+ in [NiCl4]2–. Correct choice: (D) 3 4. Ni(CN)4]2– and [Ni(H2O)6]2+ is sp3. Ni2+ forms [NiCl4]2– with Cl–. the shapes of [NiCl4]2–. AgNO3 (aq. neutron 30 15 P + 1 n 0 (Y) Sol.: 2653 7392/93/94/95 Fax: 2653 7396 . ml .05 M 1120 Molarity of solution = Correct choice: (C) 7. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl–.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. Volume of solution = Sol. positron (C) proton.00 M (C) 2. Bombardment of aluminium by α-particle leads to its artificial disintegration in two ways. [Ni(CN)4]2– and [Ni(H2O)6]2+ are tetrahedral.05 M (D) 2. Hence.15 = 2. square planar and octahedral. respectively. (i) and (ii) as shown.22 M Mass of solution = 1120 g.15 60 2 ×1000 ×1. Kalu Sarai (Behind Azad Apartments). Dissolving 120 g of urea (molecular weight 60) in 1000 g of water gave a solution of density 1.e. the first part of the curve shows no increase in conductivity as there is only replacement of − − Cl– ions with NO 3 ions. The plot of conductance (Λ) versus the volume of AgNO3 is Λ Λ Λ Λ Volume Volume Volume ® Volume (P) (A) (P) (C) (R) (Q) (R) (B) (Q) (D) (S) (S) Sol. neutron 27 13 Al 4 2 He (B) neutron. As the AgCl is precipitated. Products X. because of increase in concentration of Ag+ and NO 3 Correct choice: (D) Brilliant Tutorials Pvt.15 g/mL. square planar and octahedral. Nagar. . (B) tetrahedral. Head Office: 12. conductivity increases − ions. New Delhi-110 016 Ph. (Ionic conductivity of Cl– ions is 76 and that of NO 3 ions is 71). neutron. proton. are (A) octahedral. dsp2 and sp3d2 respectively.. The second part of the curve i.

g. having molecular formula C6H10.: This section contains 2 paragraphs. Masilamani Street. (B). New Delhi-110 016 Ph. Each of these questions has four choices (A).® IIT−JEE 2011 SOLUTIONS 4 SECTION – II (Total Marks: 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. Kalu Sarai (Behind Azad Apartments).: SnO2 is reduced to the metal by heating with carbon at 1200–1300°C in an electric furnace. Heavier molecules transfer more momentum to the wall of container. Correct choice: (A). Paragraph for Question Nos. H2SO4/HgSO4 O 2 H 3C C CH3 Q Brilliant Tutorials Pvt. adsorption of H2 on glass surface is endothermic. As per kinetic theory of gases. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any). According to Maxwell’s distribution only a small number of molecules have very high velocity. Head Office: 12. gave acetone as the only organic product through the following sequence of reaction.: Sol. Chemisorption is more exothermic than physiosorption as the formation of covalent bonds in former case results in release of energy. (B). Sol. T. It is purified by liquation and poling.3-butadiene are planar. 12 to 13 An acyclic hydrocarbon P. (B) & (C) SECTION − III (Total Marks: 15) (Paragraph Type) *10.: 2653 7392/93/94/95 Fax: 2653 7396 ® 9. Each question has four choices (A). (C) & (D) Amongst the given options. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are) (A) Adsorption is always exothermic. Structures (B) and (C) are also planar. (B). acid P (i) dil. however it is very slow due to higher energy of activation. (C) only a small number of molecules have very high velocity. Sol. 8. (B) Physisorption may transform into chemisorption at high temperature. Propadiene has terminal hydrogens lying perpendicular to each other and hence don’t lie in the same plane. (B) heavier molecules transfer more momentum to the wall of the container. Chennai-600 017 Delhi Office: 50-C. Adsorption of a gas on the surface of a solid is generally exothermic but not always. is (are) H H H (A) (B) H–C≡C–C C–C CH2 H2C CH2 (D) H2C=C=CH2 (C) H2C=C=O Both s-cis and s-trans structures of 1. moving in random motion colliding with each other as well as with the walls of container. (D) Chemisorption is more exothermic than physisorption.: *11. Molecules travel in straight lines in between the collisions. The crude metal is heated gently on a sloping hearth when pure tin flows down leaving behind iron and copper as impurities. Correct choice: (B) & (D) Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (C) removal of copper impurity (B) self-reduction of a sulphide ore (D) removal of iron impurity Sol. in which Q is an intermediate organic compound. Nagar. The crude tin contains impurities. Correct choice: (A). (D) between collisions. the molecules move in straight lines with constant velocities. (C) and (D) out of which ONE OR MORE may be correct. Collisions between such particles are taken to be perfectly elastic. e. (C) & (D) According to kinetic theory of gases (A) collisions are always elastic. Ltd. Based upon one of the paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. (i) conc. . H2SO4 (catalytic amount) (–H2O) (ii) O3 (iii) Zn/H2O (C6H10) (ii) NaBH4/ethanol (iii) dil. Physiosorption may transform into chemisorption at high temperature because chemisorption involves energy barrier. gas molecules are presumed to be point particles. Correct choice: (A). (C) and (D) out of which ONLY ONE is correct. (C) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature.

Masilamani Street. Cu+2 + 4NH3 Ag+ + 2NH3 Intense blue solution Soluble solution [Cu(NH3)4]+2 [Ag(NH3)2]+ Correct choice: (B) Brilliant Tutorials Pvt. T.: Blue Solution As AgNO3 solution is concentrated so. New Delhi-110 016 Ph. 12 & 13 CH3 C—C≡CH (P) CH3 CH3 C—CH + 1) HgSO4/H+ CH3 2) NaBH4/EtOH 3) dil. AgNO3 + NaCl White ppt (O) AgCl + NaNO3 (2) On addition of aqueous NH3.: Solution for Question No. The metal rod M is (A) Fe (C) Ni (1) Cu + 2AgNO3 (M) (N) (B) Cu (D) Co Cu(NO3)2 + 2Ag Sol.® IIT−JEE 2011 SOLUTIONS *12. Addition of aqueous NH3 dissolves O and gives an intense blue solution. Nagar. Addition of aqueous NaCl to the blue solution gives white precipitate O. H2SO4 (catalytic Amt) (–H2O) O3 Zn/H2O 2 C=O . 14. Ltd. on addition of NaCl. 5 The structure of compound P is (A) CH3CH2CH2CH2–C≡C–H (C) H3C H–C–C≡C–CH3 H3C (B) H3CH2C–C≡C–CH2CH3 H3C (D) H3C–C–C≡C–H H3C O C—C—CH3 OH C—CH—CH3 (Q) Sol. acid CH3 CH3 CH 3 CH3 CH 3 CH3 CH3 CH3 CH 3 Methyl Shift CH3 –H+ CH3 CH3 CH3 CH3 Acetone Correct choice: (D) *13. the solution turns light blue. Kalu Sarai (Behind Azad Apartments). 14 to 16 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N. The structure of the compound Q is (A) H3C OH H–C–C–CH2CH3 H3C H OH H3C (B) H3C–C–C–CH3 H3C H OH OH H3C (C) H–C–CH2CHCH3 H3C (D) CH3CH2CH2CHCH2CH3 Correct choice: (B) Paragraph for Question Nos. Chennai-600 017 Delhi Office: 50-C. Head Office: 12.: 2653 7392/93/94/95 Fax: 2653 7396 ® C=C CH3 CH 3 CH3 C—CH—CH3 CH3 + Conc.

The number of glycine units present in the decapeptide is For hydrolysis of a peptide number of water molecules required = (n –1). Correct choice: (A) The final solution contains (A) [Pb(NH3)4]2+ and [CoCl4]2– (C) [Ag(NH3)2]+ and [Cu(NH3)4]2+ (B) [Al(NH3)4]3+ and [Cu(NH3)4]2+ (D) [Ag(NH3)2]+ and [Ni(NH3)6]2+ Sol.: Correct choice: (C) SECTION−IV (Total Marks: 28) Integer Answer Type This section contains 7 questions.1 mol of He and 1.0821 × 273 ∴ V = 7 litres.: 16. Glycine contributes 47. ∴ The answer is 7. Chennai-600 017 Delhi Office: 50-C. Sol.: The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is The following possible alkenes will be formed for the given reaction: Br CH–CH3 CH2CH2CH3 CH2–CH3 CH2CH2CH3 CH2–CH3 CH2CH2CH3 CH2CH2CH3 CH2CH3 CH–CH2CH3 CH2CH3 ∴ The answer is 9. 0.26 =6 75 *19. Nagar. If V is the total volume of gases at 0°C then 0.0% to the total weight of the hydrolysed products. 18. Kalu Sarai (Behind Azad Apartments).68 atm. The compound N is (A) AgNO3 (C) Al(NO3)3 6 (B) Zn(NO3)2 (D) Pb(NO3)2 Sol.26 Number of glycine units in the decapeptide = ∴ The answer is 6. A decapeptide (molecular weight 796) on complete hydrolysis gives glylcine (molecular weight 75). for a decapeptide total H2O molecules needed = 9. The bubble corresponding to the correct answer is to be darkened in the ORS. KOH CH3–CH=C–CH2CH2CH3 CH3CH2–C=CH–CH2CH3 CH3CH2–C–CH2CH2CH3 ® *17. Brilliant Tutorials Pvt. Now total molecular mass of all amino acids forming the decapeptide = 796 + 9 (18) = 796 + 162 = 958 Mass contribution of Glycine = 47 % of 958 = 450.68 atm. New Delhi-110 016 Ph.. alanine and phenylalanine. T.32 × V = 0. Vapour pressure of unknown compound at 0°C = 0. Head Office: 12. Partial pressure of He = 1 – 0.® IIT−JEE 2011 SOLUTIONS 15.68 = 0. CH3CH2–C–CH2CH2CH3 Alc. So. Considering the ideal gas behaviour.: To an evacuated vessel with movable piston under external pressure of 1 atm. at 0°C) are introduced. Where n is number of peptide linkages. Ltd.0 mol of an unknown compound (vapour pressure 0. the total volume (in litre) of the gases at 0°C is close to External pressure = 1 atm.32 atm. Sol. Sol.: 2653 7392/93/94/95 Fax: 2653 7396 . The answer to each questions is a single digit integer ranging from 0 to 9.1 × 0. Masilamani Street.: 450.

Nagar.: 23.75 Sol. Kalu Sarai (Behind Azad Apartments). Na. ms = –1/2. So. Ltd. Brilliant Tutorials Pvt.1 eV. New Delhi-110 016 Ph.4 Na 2. Sol.7 Cu 4.1 eV = 6. Mg have work function (φ) less than 4. The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metal is Metal φ (eV) Li 2. is Total number of electrons in 3rd shell = 2 × (32) = 18. The number of sodium bromide molecules involved in the balanced chemical equation is 3Na2CO3 + 3Br2 → 5NaBr + NaBrO3 + 3CO2 This is disproportionation reaction of bromine.® IIT−JEE 2011 SOLUTIONS 7 *20.3 W 4.634 ×10 −34 × 3 ×10 8 Now. 22. Head Office: 12. K. they will show photoelectric emission.6 × 10–19 J = 6. Masilamani Street. 9 electrons have ms = +1/2 and 9 electrons have ms = –1/2.6 ×10 −19 1.7 Pt 6. Li.2 Mg 3. ∴ The answer is 5. and spin quantum number. Now.: 2653 7392/93/94/95 Fax: 2653 7396 ® .: Energy of incident radiation = hc λ 300 ×10 −9 = 6.6 ×10 −19 = 4. *21.3 K 2.: The maximum number of electrons that can have principal quantum number. n = 3. The work function (φ) of some metals is listed below. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas. Sol. Sol. ∴ The answer is 9. T. ∴ The answer is 4.: The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is Na2S4O6 (Sodium tetrathionate) has structure Na O—S—S—S—S—O Na O +5 + – O o o O O – + +5 Difference between oxidation numbers of the two different sulphur atoms = 5 – 0 = 5 ∴ The answer is 5.3 Fe 4. Chennai-600 017 Delhi Office: 50-C. Five molecules of NaBr are involved in the reaction.8 Ag 4.

New Delhi-110 016 Ph.: Initial charge q2µf = 2V After shifting. T. 24. (C) and (D) out of which ONLY ONE is correct. Kalu Sarai (Behind Azad Apartments).: 320 + 10 ν′ = 8 kHz = 8.5 kHz 320 − 10 Correct choice (A) Brilliant Tutorials Pvt. The percentage of its stored energy dissipated after the switch S is turned to position 2 is (A) 0 % (C) 75 % (B) 20 % (D) 80 % V 2µF 8µF 1 2 S Sol. The determined value of ‘X’ is (A) 10.: Effective length of the wire l0 = 100 + (1 + 2) = 103 cm Balancing length (l) = 52 + 1 = 53 cm X = Rl 10 × 53 = l 0 − l 103 − 53 = 530 50 = 10.8 ohm (B) 10.1 ohm A X 10 Ω B Sol. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which reflects the sound waves. Each question has four choices (A).75 kHz (D) 7. Ltd.50 kHz (B) 8. Chennai-600 017 Delhi Office: 50-C.25 kHz (C) 7.50 kHz Sol. Head Office: 12. (B). A 2 µF capacitor is charged as shown in figure. A meter bridge is set-up as shown. V common potential = 5 1 2 2 U i = × 2 ×V = V 2 Uf = 1 V2 V ×10 × = 2 5 5 Ui −U f Ui 2 ∴% loss of energy × 100 = 80% Correct choice: (D) *26. The end-corrections are 1 cm and 2 cm respectively for the ends A and B.6 Ω Correct choice: (B) 25. The speed of sound in air is 320 m/s. Nagar.2 ohm (C) 10. Masilamani Street.® IIT−JEE 2011 SOLUTIONS 8 SOLUTIONS TO IIT-JEE 2011 PHYSICS: Paper-I (Code: 6) PART – II SECTION – I (Total Marks: 21) (Single Correct Answer Type) This Section contains 7 multiple choice questions. The frequency of the siren heard by the car driver is (A) 8.6 ohm (D) 11. to determine an unknown resistance ‘X’ using a standard 10 ohm resistor.: 2653 7392/93/94/95 Fax: 2653 7396 ® . The galvanometer shows null point when tapping-key is at 52 cm mark.

7 liter.a. 9 5. Kalu Sarai (Behind Azad Apartments). Chennai-600 017 Delhi Office: 50-C. Head Office: 12.0) X (0. Nagar.: Tcosθ = mg T sinθ = ml sinθ ω2 ∴ T = mlω2 Tmax = mlω 2 max L T m 324 = 0.: Projected area on the y – z plane = a2 ∴ flux = E0 a2 Correct choice: (C) 29.: 2653 7392/93/94/95 Fax: 2653 7396 .0. The ball is rotated on a horizontal circular path about vertical axis.5 × 0.0. r ˆ . the work done in the process is (A) 9 R T1 8 γ −1 (B) 5.5 m.® IIT−JEE 2011 SOLUTIONS *27. The maximum possible value of angular velocity of ball (in radian/s) is (A) 9 (B) 18 (C) 27 L m (D) 36 Sol. where E0 is a Consider an electric field E = E0 x constant. New Delhi-110 016 Ph. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å.6 3 = × R × (4T1 − T1 ) 22. Masilamani Street. A ball of mass (m) 0.7 5 −1 3 R T1 2 (C) 15 R T1 8 (D) 9 R T1 2 Sol.: V T2 = T1 1 V2 = 4 T1 = 9 RT1 8 W = |– nCv ∆T| 5.4 2 Correct choice: (A) 28. The maximum tension that the string can is bear is 324 N.a) (a. The wavelength of the second spectral line in the Balmer series of singly-ionized helium atom is (A) 1215 Å (B) 1640 Å (C) 2430 Å (D) 4687 Å 1 1 5 2 1 = R (1) − = R λ1 4 9 36 1 1 1 3 = R (2)2 − = R λ2 4 16 4 Sol.5 kg is attached to the end of a string having length (L) 0.0) Y 2 Sol.5 ω2 max θ ω2 max = 324 × 100 25 ω max = 18 × 2 = 36 Correct choice: (D) Brilliant Tutorials Pvt. Ltd. The flux through the shaded area (as shown in the figure) due to this field is (A) 2 E 0 a 2 (C) E0 a 2 (B) (D) 2 E0 a 2 E0 a 2 Z (a.6 liter of helium gas at STP is adiabatically compressed to 0. Taking the initial temperature to be T1.: λ2 5 = ⇒ λ2 = 1215 Å λ1 27 Correct choice: (A) *30.a.6 3 = T1 0.a) ® (0. T.

(C) and (D) out of which ONE OR MORE may be correct. Nagar. Equivalent diagram is shown. Masilamani Street. (D) heat flow through C = heat flow through B + heat flow through D. New Delhi-110 016 Ph. (C). Sol.: σ A RB = σ B RA (A) Electric field inside the spherical shell is zero Q A C AV R (B) = = A QB C BV RB (C) ® 32. (B). Q1 L 2K Q Q2 2 L Q3 L 2K 2K L 0 1L A 1L 2K 3L 4L D 5K 5L 6L 3K E 4K 6K heat B C Sol. They enter a semi-infinite region of uniform magnetic field perpendicular to the velocity. Each question has four choices (A). πm Both follow semicircular path in the magnetic field for the time t = qB Correct choices: (B). Head Office: 12. (D) They will come out at different times. (C). (C) They will come out at the same time. Heat ‘Q’ flows only from left to right through the blocks. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB (< RA) are kept far apart and each is given charge ‘+Q’. (D) inside (A) E A =0 (B) QA > QB on surface on surface (D) E A < EB Sol. Then RA RB solid +Q (C) VA = VB ⇒ σ A RA = σ B RB ⇒ (D) σ A RB = σ B RA shell E A σ A RB = = EB σ B RA Correct choices: (A). T. (B). (C) temperature difference across slab E is smallest. D and E of different thermal conductivities (given in terms of a constant K) and sizes (given in terms of length. A composite block is made of slabs A. (D) (Option (B) can be correct) Brilliant Tutorials Pvt.: 3K 4K 5K 4L 6K 6K 6K L 2 KLd 3KLd 6 KLd 35 Kd∆T + + = Heat current Q1 = ∆T 4L L L 4 2 K (2 L )d 4 K (2 L )d 6 K (2 L )d Q2 = ∆T + + = 18Kd∆T 4L L L 2 KLd 5KLd 6 KLd 37 Kd∆T Q3 = ∆T + + = 4L L L 4 Clearly Q2 = Q1 + Q3 (A) Q A = QE = Q1 + Q2 + Q3 (C) ∆T = QR = Ql is least for E KA Q1 Q2 Q3 Correct choices: (A). Chennai-600 017 Delhi Office: 50-C. L) as shown in the figure. B. (B) heat flow through slab E is maximum.: 2653 7392/93/94/95 Fax: 2653 7396 . Kalu Sarai (Behind Azad Apartments).® IIT−JEE 2011 SOLUTIONS SECTION – II (Total Marks: 16) (Multiple Correct Answer Type) 10 This section contains 4 multiple choice questions. Ltd. 31. Which of the following statement(s) is/are true? (A) They will never come out of the magnetic field region. Then in steady state (A) heat flow through A and E slabs are same.: An electron and a proton are moving on straight parallel paths with same velocity. C. (B) They will come out traveling along parallel paths. (D) *33. Now they are connected by a thin metal wire. All slabs are of same width.

35 to 36 A dense collection of equal number of electrons and positive ions is called neutral plasma. (C) and (D) out of which ONLY ONE is correct. the electrons begin to oscillate about the positive ions with a natural angular frequency ‘ωp’. Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. This is the explanation of high reflectivity of metals. Kalu Sarai (Behind Azad Apartments). Ltd. (A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm Sol. Each of these questions has four choices (A). where these quantities are in proper SI units. (D) SECTION − III (Total Marks: 15) (Paragraph Type) This section contains 2 paragraphs. (B). Based upon one of the paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons N ≈ 4 × 1027 m–3. 35.: Ne 2 L−3 A2T 2 = mε 0 M M −1 L−3 A2T 4 Correct choice: (C) = [T–1] 36. Paragraph for Question Nos. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end. (D) Angular frequency for case A < Angular frequency for case B. Frequency of oscillation of physical pendulum is T = 2π Sol.: I mgd Q IA > IB ∴ ωA < ωB Correct choices: (A).: Ne 2 c = ω p = 2πν = 2π mε 0 λ ≈ 600 nm Ne 2 Correct choice: (B) λ = 2πc mε 0 Brilliant Tutorials Pvt. Chennai-600 017 Delhi Office: 50-C. Taking the electronic charge as ‘e’ and the permittivity as ‘ε0’. they are displaced relatively away from the heavy positive ions. T. a time varying electric field needs to be applied that has an angular frequency ω.: 2653 7392/93/94/95 Fax: 2653 7396 . Take ε0 ≈ 10–11 and m ≈ 10–30. which is called the plasma frequency. When the electrons are subjected to an electric field. all the free electrons are set to resonance together and all the energy is reflected. New Delhi-110 016 Ph.® IIT−JEE 2011 SOLUTIONS 11 *34. (C) Angular frequency for case A > Angular frequency for case B. As ω approaches ωp. where a part of the energy is absorbed and a part of it is reflected. Masilamani Street. Which of the following statement(s) is (are) true? (A) Restoring torque in case A = Restoring torque in case B. each of mass ‘m’. The rod-disk system performs SHM in vertical plane after being released from the same displaced position. If the electric field becomes zero. Let ‘N’ be the number density of free electrons. (B) Restoring torque in case A < restoring torque in case B. A thin disk of mass ‘M’ and radius ‘R’ (< L) is attached at its center to the free end of the rod. use dimensional analysis to determine the correct expression for ωp. Head Office: 12. (A) ® Ne mε 0 (B) mε 0 Ne (C) Ne 2 mε 0 (D) mε 0 Ne 2 Sol. To sustain the oscillations. Consider two ways the disk is attached: (case A) The disk is not free to rotate about its centre and (case B) the disk is free to rotate about its centre. Nagar.

Chennai-600 017 Delhi Office: 50-C. Nagar. For such systems. phase space is a plane in which position is plotted along horizontal axis and momentum is plotted along vertical axis. Ltd. The phase space diagram for simple harmonic motion is a circle centered at the origin. The arrow on the curve indicates the time flow. They are especially useful in studying the changes in motion as initial position and momentum are changed. The phase space diagram is x(t) vs.® IIT−JEE 2011 SOLUTIONS Paragraph for Question Nos. p(t) curve in this plane. The phase space diagram for a ball thrown vertically up from ground is Momentum Momentum (A) Position (B) Position Momentum Momentum (C) Position (D) Position Sol. T. Here we consider some simple dynamical systems in one-dimension. Head Office: 12. the two circles represent the same oscillator but for different initial conditions. We use the sign convention in which position or momentum upwards (or to right) is positive and downwards (or to left) is negative. ⇒ p = m V 02 − 2 gy ⇒ p 2 = m 2 V02 − 2 gy ( ) Momentum E1 2a a Position Correct choice: (D) *38. the phase space diagram for a particle moving with constant velocity is a straight line as shown in figure. In the figure. and E1 and E2 are the total mechanical energies respectively.: Ball thrown vertically up.: 2653 7392/93/94/95 Fax: 2653 7396 . Masilamani Street. Then (A) E1 = 2 E 2 (C) E1 = 4 E 2 (B) E1 = 2 E 2 (D) E1 = 16 E 2 ® E2 Sol. Kalu Sarai (Behind Azad Apartments). Momentum Position *37. For example. New Delhi-110 016 Ph.: E= p2 2m p2 + x2 = a2 2mE + x2 = a2 2mE2 = a2 2mE1 = 4a2 E1 =4 E2 Correct choice: (C) Brilliant Tutorials Pvt. 37 to 39 12 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems.

If the magnetic moment of the loop is N µ0 I 0 sin(300t ) . Ltd. The phase space diagram for one cycle of this system is Momentum Momentum (A) Position (B) ® Position Momentum Momentum (D) (C) Position Position Sol. φ = BA φ= µ 0 I 0 cos(300t )× πr 2 L Brilliant Tutorials Pvt. the momentum starts increasing in negative direction (with energy dissipation) and gradually returns back to less positive position as pf < pi (due to energy dissipation). with the mass submerged in water. 40. Kalu Sarai (Behind Azad Apartments). The bubble corresponding to the correct answer is to be darkened in the ORS.3 m carries a current I along its curved surface as shown. Masilamani Street. as shown in the figure. The current varies as I = I0 cos(300 t) where I0 is constant. Nagar. The answer to each question is a single-digit integer. Chennai-600 017 Delhi Office: 50-C. Correct choice: (B) SECTION − IV (Total Marks: 28) (Integer Answer Type) This section contains 7 questions.® IIT−JEE 2011 SOLUTIONS 13 *39.005 ohm and of radius 0. New Delhi-110 016 Ph. ∫ B. then ‘N’ is I Sol. Head Office: 12.: From extreme positive position (of x). T.: 2653 7392/93/94/95 Fax: 2653 7396 . A wire-loop of resistance 0. A long circular tube of length 10 m and radius 0. Consider the spring-mass system.: From Ampere’s circuital law.1 m is placed inside the tube with its axis coinciding with the axis of the tube.dl = µ B= 0 I l L l µ0 I L Now. ranging from 0 to 9.

® IIT−JEE 2011 SOLUTIONS ∴ e=− dφ 300πµ0 I 0 r 2 sin (300t ) = dt L 300. The mass (in mg) of the radioactive sample is − dN = λN dt dN 1 1 –1 s = 1010 . The coefficient of linear thermal expansion of the steel is 10–5 / oC.π 2 r 4 µ 0 I 0 sin (300t ) LR 14 As. − ∴ N= Total mass = 10–25 × 1019 kg = 1 mg ∴ The answer is 1 *43. T. Nagar. whose mean life is 109 s. Then the value of ‘m in kg is nearly Sol.5 × ×10 − 4 + 2 × 0.14 kg ∴ The answer is 3 ( ) 2 Brilliant Tutorials Pvt. Ltd.5 kg are placed with their centres at the corners of a square of side 4 cm. λ = = dt t av 10 9 1 dN 19 − = 10 λ dt Sol. Steel wire of length ‘L’ at 40o C is suspended from the ceiling and then a mass ‘m’ is hung from its free end. Masilamani Street.: mg = YAα∆T m= αAY∆T 10 −5 × π 10 −3 × 1011 × 10 = g 10 m = π kg = 3. Young’s modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. The mass of an atom of this radioisotope is 10–25 kg. Head Office: 12.: 2653 7392/93/94/95 Fax: 2653 7396 ® . then N is Sol. Four solid spheres each of diameter 5 cm and mass 0. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second.5 × 8 ×10 − 4 5 4 2 2a 2 I = 9 ×10 −4 kg m2 The answer is 9 ∴ 42. Chennai-600 017 Delhi Office: 50-C. The wire is cooled down from 40oC to 30oC to regain its original length ‘L’. Kalu Sarai (Behind Azad Apartments). New Delhi-110 016 Ph. The moment of inertia of the system about the diagonal of the square is N × 10–4 kg-m2. Assume that L >> diameter of the wire. M = iA = M = 6µ 0 I 0 sin (300t ) ∴ ∴ N =6 The answer is 6 *41.: Given.: I = 4× a 2 MR 2 + 2M 2 5 2 5 I = 4 × × 0.

N = 10 µ = 5 ∴ The answer is 5 Sol. then N is F1 = mg(sinθ + µ cosθ) F2 = mg (sinθ – µ cosθ) F As. each of +q. The value of P is Ground Stick Sol. where ‘k’ is a Sol.8 N But f2 = µF f µ = 2 = 0 .4 N From (ii) Ia f1 – f2 = 2 = ma R f2 = f1 – ma = 1.5 m with a stick as shown in the figure. The surface q2 tension of the soap film is γ.® IIT−JEE 2011 SOLUTIONS 44. New Delhi-110 016 Ph.3 m/s2. The stick applies a force of 2 N on the ring and rolls it without slipping with an acceleration of 0.6 = 1. and a = k γ constant. Head Office: 12. are rigidly fixed at the four corners of a square planar soap film of side ‘a’.: 2 kq 2 a 2 +2 kq 2 2 2a q γ 2 2 = 2 γa ⇒ a3 ∝ 1 kq 2a 2 kq 2 a2 2 kq 2 a2 kq 2 a2 kq 2 2a 2 kq 2 a2 q2 3 a∝ γ ∴ The answer is 3 *45. 1 = 3 F2 sin θ + µ cos θ =3 sin θ − µ cos θ 1+ µ ⇒ = 3 ⇒ µ = 1/2 1− µ Now. A block is moving on an inclined plane making an angle 45o with the horizontal and the coefficient of friction is µ. The force required to just push it up the inclined plane is 3 times the force required to just prevent it from sliding down.: ® F1 mg sinθ f m θ F2 mg sinθ m θ f ⇒ *46. Ltd.6 = 0. Then N is 1/ N . If we define N = 10 µ. Kalu Sarai (Behind Azad Apartments).: 2653 7392/93/94/95 Fax: 2653 7396 . The system of charges and planar film are in equilibrium. F – f1 = ma …(i) (f1 – f2)R = Iα …(ii) a = αR From (i) f1 = F – ma = 2 – 0. A boy is pushing a ring of mass 2 kg and radius 0. T.4 – 0.: FBD of the ring is shown in figure. Chennai-600 017 Delhi Office: 50-C. Nagar. 15 Four point charges.4 F Now. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficient of friction between the stick and the ring is (P / 10). Masilamani Street. P = 10 µ = 4 ∴ The answer is 4 F a N1 α mg f2 f1 Brilliant Tutorials Pvt.

Then x 0 is (A) 1 6 (B) (D) 6 Sol. New Delhi-110 016 Ph. Each question has four choices (A).® IIT−JEE 2011 SOLUTIONS 16 SOLUTIONS TO IIT-JEE 2011 MATHEMATICS: Paper-I (Code: 6) PART – III SECTION – I (Total Marks: 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. Masilamani Street.6α − β8 . then the value of (A) 1 (B) 2 (C) 3 *47. T. –2) is inclined at an angle 60º to the line then the equation of L is (A) y + 3 x + 2 − 3 3 = 0 (B) y − 3 x + 2 + 3 3 = 0 (C) 3 y − x + 3 + 2 3 = 0 y-axis Sol. (D) 3 y + x − 3 + 2 3 = 0 =3 Correct choice: (C) *48. –2) π/3 Correct choice: (B) ® x-axis 1 3 (C) 1 2 α10 − β10 − 2(α8 − β8 ) *49. Nagar.6β 2 ( α 9 − β9 ) = [Q α 2 − 6α − 2 = 0 & β2 − 6β − 2 = 0 ] 3 x + y = 1. Ltd..: a10 − 2a8 2a9 = 2( α 9 − β9 ) = α8 (α 2 − 2) − β8 (β2 − 2) 2 ( α 9 − β9 ) α8 .: Equation will be y + 2 = 3 ( x − 3) ⇒ 3x + y = 1 y − 3x + 2 + 3 3 = 0 2π/3 O π/3 π/3 P (3. (i) …. a10 − 2a8 is 2a 9 (D) 4 Sol. A straight line L through the point (3. Chennai-600 017 Delhi Office: 50-C. (C) and (D) out of which ONLY ONE is correct. we get ln x = − ln 2 ⇒ x = Correct choice: (C) Brilliant Tutorials Pvt. (ii) and (ln 3) (ln x) = (ln 2)(ln y ) 1 2 From equation (i) and (ii). Let α and β be the roots of x 2 − 6 x − 2 = 0.: 2653 7392/93/94/95 Fax: 2653 7396 . Kalu Sarai (Behind Azad Apartments).: Taking log in both equations (ln 2) 2 + (ln 2)(ln x) = (ln 3) 2 + (ln 3)(ln y ) …. If L also intersects the x-axis. (B).. Head Office: 12. If a n = α n − β n for n ≥ 1. y 0 ) be the solution of the following equations ( 2 x) ln 2 = (3 y ) ln 3 3 ln x = 2 ln y . with α > β. Let ( x 0 .

y = 0 and x = 0 into two parts R1 (0 ≤ x ≤ b) and R 2 (b ≤ x ≤ 1) such that R1 − R 2 = 1 .c 1 ⇒ (λ + µ ) − (λ − µ ) − ( λ + µ ) = 1 ⇒ µ − λ = 1 r = |c | 3 r ˆ ˆ− ˆ v = (1 + 2λ)i j + (1 + 2λ )k λ =1 Then take Correct choice: (C) *52. Let P = θ : sin θ − cos θ = 2 cos θ and Q = θ : sin θ + cos θ = 2 sin θ be two sets. The value of ln 2 ∫ ln 3 2 x sin x 2 sin x + sin(ln 6 − x 2 ) (B) dx is 3 2 1 3 ln 6 2 1 3 (A) ln 4 2 Sol. Nagar. r r ˆ ˆ ˆ r ˆ ˆ ˆ r ˆ ˆ ˆ r r Let a = i − j − k be three vectors. Then (A) P ⊂ Q and Q − P ≠ ∅ (B) Q ⊄ P (C) P ⊄ Q (D) P = Q { } { } Sol. Head Office: 12. Chennai-600 017 Delhi Office: 50-C. A vector v in the plane of a and b . is given by 3 ˆ ˆ−3ˆ (A) i j + 3k r r r v = λa + µb ˆ ˆ−3ˆ (B) − 3i j−k ˆ ˆ− ˆ (C) 3i j + 3k ˆ ˆ+3ˆ (D) i j − 3k Sol. Let the straight line x = b divide the area enclosed by y = (1 − x) 2 . New Delhi-110 016 Ph.: Now So ˆ (λ + µ) ˆ+ ˆ = (λ + µ)i j (λ − µ ) + k rr v .: and Hence.: 1 3 ln 2 2 (C) ln (D) Put x 2 = t ⇒ 2 x dx = dt I= 1 2 ln 3 ln 2 ∫ sin t + sin(ln 6 − t ) dt ∫ f ( x)dx =∫ f (a + b − x)dx a a ln 3 ln 2 b b sin t Using property ⇒ 2I = ⇒ I= 1 3 ln .: 2653 7392/93/94/95 Fax: 2653 7396 ® 1 2 ∫ dt = 2 (ln 3 − ln 2) 1 . Kalu Sarai (Behind Azad Apartments). T. Then b equals 4 1 2 (C) 1 3 (D) 1 4 (A) 3 4 (B) Brilliant Tutorials Pvt. whose projection on + j + k . sin θ − cos θ = 2 cos θ ⇒ tan θ = 2 + 1 sin θ + cos θ = 2 sin θ ⇒ tan θ = 1 2 −1 = 2 +1 P=Q Correct choice: (D) 53.® IIT−JEE 2011 SOLUTIONS 17 50. Ltd. b = i − j + k and c = i r 1 c is . Masilamani Street. 4 2 Correct choice: (A) 51.

and perpendicular to the vector i ˆ is/are ˆ+ ˆ ˆ+2ˆ ˆ+ ˆ The vector(s) which is/are coplanar with vectors i j + 2k j+k j+k ˆ (A) ˆ j−k ˆ ˆ+k (B) − i ˆ− ˆ (C) i j ˆ (D) − ˆ j+k Sol. (B). then M 2 N 2 ( M T N ) −1 ( MN −1 ) T is equal to (A) M 2 (B) − N 2 (C) – M 2 (D) MN (The order can not be 3 × 3 as it will be singular matrix. out of which ONE OR MORE may be correct.: ∫ 0 ( x − 1) 2 dx − ( x − 1) 2 dx = b ∫ 1 4 1 0 1 ⇒ ( x − 1) 3 2 3 b − 0 3 ( x − 1) 3 3 1 = b 1 4 b ⇒ or (b − 1) 1 =− 3 12 −1 1 ⇒b= 2 2 b −1 = . Kalu Sarai (Behind Azad Apartments). Correct choice: (C) Sol. Ltd. Each question has four choices (A). T. parallel to ( ˆ j−k Correct choice: (A). Head Office: 12. N are skew symmetric) 55.: Required vector r d = λ( a × (b × c)). Chennai-600 017 Delhi Office: 50-C. where n ∈ N ) M 2 N 2 ( M T N ) −1 ( MN −1 ) T = − MN MN ( MN ) −1 ( MN −1 ) T = − MN (( N T ) −1 M T ) = −( MN N −1 M ) = −M 2 .: 2653 7392/93/94/95 Fax: 2653 7396 ® . Let M and N be two 3 × 3 non-singular skew-symmetric matrices such that MN = NM . Nagar. Correct choice: (B) SECTION – II (Total Marks: 16) (Multiple Correct Answer Type) This section contains 4 multiple choice questions.® IIT−JEE 2011 SOLUTIONS b 1 18 Sol. New Delhi-110 016 Ph. Solving the problem taking order as 2n × 2n .: (as MN = NM ) (as M. ˆ + ( x + 2 y) ˆ = ( x + y )i j + (2 x + y )k Brilliant Tutorials Pvt. 54. Masilamani Street. (D) Alternative r ˆ and i ˆ. where λ is a real number r ˆ ˆ ˆ a =i + j+k r ˆ ˆ+ ˆ b =i j + 2k ∴ r ˆ ˆ c =i + 2ˆ j+k r ˆ) d = −4λ ( ˆ j−k ˆ) Hence. (C) and (D). ˆ and i ˆ . If P T denotes the transpose of P. ˆ+ ˆ ˆ+2ˆ Let c is coplanar with vectors i j + 2k j+k So r ˆ) + y (i ˆ) ˆ+ ˆ ˆ+2ˆ c = x(i j + 2k j+k ˆ.

0) 2 2 3 eccentricity of hyperbola e1 = b 2 = a 2 (e1 − 1) 2 4 a2 b 2 = a 2 − 1 = 3 3 a 2 = 3b 2 Since hyperbola passes through a focus (± 3 .: Given equation of hyperbola x2 a 2 − y2 b 2 = 1. where a 2 = 4. Let the eccentricity of the hyperbola through a focus of the ellipse.: 2653 7392/93/94/95 Fax: 2653 7396 ® . then (A) the equation of the hyperbola is x2 a 2 − y2 b2 = 1 be reciprocal to that of the ellipse x 2 + 4 y 2 = 4. b 2 = 1 4 1 e= So So 3 . If the hyperbola passes x2 y2 − =1 3 2 5 3 (B) a focus of the hyperbola is (2. (D) *56. ˆ+ ˆ Since. 0) . and foci (± 3 . 0) of ellipse So 3 a2 − 0 b2 =1 ⇒ a2 = 3 ⇒ b2 =1 So equation of hyperbola is x 2 − 3y 2 = 3 x2 y2 − =1 3 1 Foci of hyperbola (± ae. 0) (D) the equation of the hyperbola is x 2 − 3 y 2 = 3 (C) the eccentricity of the hyperbola is Sol. Ltd. Chennai-600 017 Delhi Office: 50-C. Masilamani Street.® IIT−JEE 2011 SOLUTIONS r ˆ. eccentricity of ellipse x2 y2 + = 1. c is ⊥ to vector i j+k 19 So ⇒ x + y + x + 2 y + 2x + y = 0 y = −x r ˆ) − x(i ˆ) ˆ+ ˆ ˆ+2ˆ c = x(i j + 2k j+k ˆ) = x(− ˆ j+k If x = 1 ˆ = −ˆ j+k ˆ If x = −1 = ˆ j−k Correct choice: (A). T. 2 3 . 0) ⇒ ⇒ (± 3 × (±2. Kalu Sarai (Behind Azad Apartments). New Delhi-110 016 Ph. Head Office: 12. Nagar. 0) Correct choice: (B). (D) Brilliant Tutorials Pvt.

: 2653 7392/93/94/95 Fax: 2653 7396 ® x = y = 0 ⇒ f (0) = 2 f (0) ⇒ f (0) = 0 f ( x + h) − f ( x ) f ' ( x) = lim h→0 h f ( x ) + f ( h ) − f ( x ) − f ( 0) = lim h →0 h f ( h ) − f ( 0) = lim h→0 h (as f ( x) is differentiable at x = 0 ) . A fair coin is tossed. the probability that head appeared on the coin is (A) 17 23 (B) 11 23 (C) 15 23 (D) 12 23 Brilliant Tutorials Pvt. Chennai-600 017 Delhi Office: 50-C. Let f : R → R be a function such that f ( x + y ) = f ( x) + f ( y ). ∀x. y ∈ R 20 Sol. Nagar. then (A) f ( x) is differentiable only in a finite interval containing zero (B) f ( x) is continuous ∀ x ∈ R (C) f ' ( x) is constant ∀ x ∈ R (D) f ( x) is differentiable except at finitely many points f :R→ R f ( x + y ) = f ( x ) + f ( y ) ∀ x. Head Office: 12. Now 1 ball is drawn at random from U 2 . Based upon one of the paragraphs 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. New Delhi-110 016 Ph. . 58 to 59 Let U 1 and U 2 be two urns such that U 1 contains 3 white and 2 red balls. Masilamani Street. If f ( x) is differentiable at x = 0. Correct choice: (B). (C) SECTION − III (Total Marks: 15) (Paragraph Type) This section contains 2 paragraphs. Ltd.: Required probability 3 2 2 3 C C 1 1 3C C C1 × 2 C1 2 1 1 × × 5 1 + 5 1 × + × 5 2 ×1 + 5 2 × + 5 3 2 C1 2 C2 3 C2 2 C2 C1 = = 1 3 1 3 1 12 + + + + 2 5 5 10 30 30 23 30 Correct choice: (B) 59. Kalu Sarai (Behind Azad Apartments). If head appears then 1 ball is drawn at random from U 1 and put into U 2 . However. (C) and (D) out of which ONLY ONE is correct. Paragraph for Questions Nos. (B). Given that the drawn ball from U 2 is white.: f ' ( x) = f ' (0) ⇒ f ( x) = xf ' (0) + c f ( 0) = 0 ⇒ c = 0 ⇒ f ( x ) = x f ' ( 0 ) ⇒ f ' ( x) is constant ∀ x ∈ R. and U 2 contains only 1 white ball. y ∈ R. The probability of the drawn ball from U 2 being white is (A) 13 30 (B) 23 30 (C) 19 30 (D) 11 30 Sol. if tail appears then 2 balls are drawn at random from U 1 and put into U 2 . T. 58.® IIT−JEE 2011 SOLUTIONS 57. Each of these questions has four choices (A).

If a = 2 with b and c satisfying (E). with reference to (E). b and c be three real numbers satisfying 1 9 7 [a b c] 8 2 7 = [0 0 0] ……………….: As ⇒ ⇒ 7a + b + c = 6 3 ωa 1 ωb 3 ωc Correct choice: (D) 61. Chennai-600 017 Delhi Office: 50-C. then the value of 7 a + b + c is (A) 0 1 9 7 8 2 7 =0 7 3 7 equation E has non trivial solution ( a . with a and c satisfying (E).: 2653 7392/93/94/95 Fax: 2653 7396 . Nagar. b. then the value of equal to (A) –2 (B) 2 (C) 3 + + is ® (D) –3 Sol. then n ∑ Sol. = 6 7 n =0 1− 7 ∞ n Correct choice: (B) Brilliant Tutorials Pvt. Ltd. Kalu Sarai (Behind Azad Apartments). 7 λ ) Point satisfies the plane −2λ − 6λ + 7λ = 1 ⇒ λ = −1 (a. Correct choice: (A) 62. Let b = 6. − 6λ . c = −7 (B) 7 (C) 6 7 (D) ∞ x 2 + 6x − 7 = 0 1 1 −6 6 = + = α β −7 7 ⇒ ∑ 1 6 =7. b. 60 to 62 21 Sol.: 1 1 α + β n =0 ∞ (A) 6 b = 6 ⇒ a = 1. c). Masilamani Street. lies on the plane 2 x + y + z = 1. New Delhi-110 016 Ph. b. If α and β are the roots of the quadratic equation ax 2 + bx + c = 0. 6.(E) 7 3 7 60.: Let a. c ) ≡ ( − λ . − 7) (B) 12 (C) 7 (D) 6 Sol. T. Let ω be a solution of x 3 − 1 = 0 with Im(ω) > 0 .® IIT−JEE 2011 SOLUTIONS 1 4 × 12 E1 2 5 P = = 1 4 1 22 23 A × + × 2 5 2 30 Correct choice: (D) Paragraph for Questions Nos. c) ≡ (1.: If a = 2 ⇒ b = 12. Head Office: 12. c = −14 3 ω 2 + 1 ω 12 + 3 ω −14 = 1 + 3(ω + ω 2 ) = −2 . If the point P(a.

ranging from 0 to 9.: *(To get the correct equation which satisfies f (1) = 2 .: The minimum value of the sum of real numbers a −5 . The bubble corresponding to the correct answer is to be darkened in the ORS.t. then the 1 ∫ x value of f (2) is Sol. ≥ G. Nagar. Sol.3a −3 . the question should have been 6 f (t )dt = 3 x f ( x) − x 3 − 5 ) 1 ∫ x Differentiate both sides w. Ltd. 2) X N O (2. Head Office: 12. 0) (3. Chennai-600 017 Delhi Office: 50-C. 8 a4 + 1 a3 + a 8 + a 10 + 1 ≥ 8 (by using A.r.M. New Delhi-110 016 Ph. Masilamani Street. Kalu Sarai (Behind Azad Apartments). T. then the minimum value of | 2 z − 6 + 5i | is 2| z − 3+ As ⇒ 5 9 9i i | = 2 | z − 3 − 2i + i | ≥ 2 || z − 3 − 2i | − | || 2 2 2 9 5 ≥ 2 2 || z − 3 − 2i | − 2| z −3+ 5 i| ≥ 5 2 Alternative It is also clear from the figure Y ® M 5/2 sin θ Let f (θ) = sin tan −1 cos 2θ d . Then the value of ( f (θ)) is 4 4 d (tan θ) (3.)) 64. *63. Sol. ∞ ) → [2. a 8 and a 10 with a > 0 is a −5 + a −4 + 3a −3 + 1 + a 8 + a 10 ⇒ ⇒ 1 a 1 5 + + 1 a 1 4 + + 3 a3 1 a3 + 1 + a 8 + a 10 + 1 a3 a5 Ans. 1. If z is any complex number satisfying | z − 3 − 2i | ≤ 2. ∞ ) be a differentiable function such that f (1) = 2. The answer to each of the questions is a single-digit integer. a −4 . Let f : [1. Sol.M. where − π < θ < π .: 2653 7392/93/94/95 Fax: 2653 7396 . –5/2) 66.® IIT−JEE 2011 SOLUTIONS SECTION − IV (Total Marks: 28) (Integer Answer Type) 22 This section contains 7 questions. x we get 6 f ( x) = 3xf ' ( x) + 3 f ( x) − 3x 2 From differential equation dy 6 y = 3x + 3 y − 3x 2 dx Brilliant Tutorials Pvt. 4 4 *65. If 6 f (t ) dt = 3 x f ( x) − x 3 for all x ≥ 1. 1 ⇒ π π as θ ∈ − .: sin θ = sin −1 sin θ tan −1 cos 2θ 2 1 − sin θ = sin −1 (tan θ) −1 sin θ = sin(sin −1 (tan θ)) = tan θ sin tan θ cos 2 d ⇒ ( f (θ)) = 1 d (tan θ) Ans.

: ∆1 = 2 since the area of the triangle formed by 3 points on a parabola is twice the area of the triangle formed by the ∆2 tangents at these points. a100 be an arithmetic progression with a1 = 3 and S p = 1 ≤ n ≤ 20. Let a1 . Chennai-600 017 Delhi Office: 50-C. let m = 5n. New Delhi-110 016 Ph. a 2 . and ∆ 2 be the area of the triangle formed by drawing tangents at P and at the end points of the 2 ∆ latus rectum. Nagar. Let ∆ 1 be the area of the triangle formed by the end points of its latus rectum and the point 1 P . 2 on the parabola.. a 3 . 1 ≤ p ≤ 100.: 3π 2π sin + sin n 1 n = 2 π 3π π sin . Consider the parabola y 2 = 8 x. Head Office: 12. If Sm does not depend on n. 7 *68. T. 2 Brilliant Tutorials Pvt. Masilamani Street. sin sin n n n 4π 3π − sin =0 ⇒ sin n n 7π π = ⇒ 2n 2 n=7. then a 2 is Sn ® ∑ a .: 2653 7392/93/94/95 Fax: 2653 7396 .. Kalu Sarai (Behind Azad Apartments). ..® IIT−JEE 2011 SOLUTIONS dy − 3 y = 3x 2 dx dy y − = x ⇒ f ( x) = x 2 + x ⇒ dx x ⇒ f (2) = 4 + 2 = 6 Ans. 9 *69. Ans. Ltd. i i =1 p For any integer n with Sol. The positive integer value of n > 3 satisfying the equation 1 1 1 = + is π 2π 3π sin sin sin n n n Sol. Ans. 6 ⇒ 3x 23 *67. Then 1 is ∆2 Sol.: m {2a1 + (m − 1)d } Sm = 2 n Sn {2a1 + (n − 1)d } 2 6 + (5n − 1)d = 5 6 + (n − 1)d 6 − d + 5nd = 5 6 − d + nd This will be independent of n if d =6 ∴ a2 = 3 + 6 = 9 Ans.

A. T. You are allotted 5 minutes specifically for this purpose. Write your Name. Write your name and registration number in the space provided on the back page of this booklet. 14. 6. There are no negative marks in this section. for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. Filling the Right Part of the ORS: 10. This Question Paper contains 60 questions. The ORS also has a CODE printed on its Left and Right parts. Kalu Sarai (Behind Azad Apartments). for each question you will be awarded 2 marks for each row in which you have darkened ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. cellular phones. Ltd. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators. log tables. In Section IV (Total Marks: 16). In all other cases. is provided separately. On breaking the seals. The answer sheet. General: 1. 7. please check that all the questions are legible. Make sure the CODE on the ORS is the same as that on this booklet. 12.: 2653 7392/93/94/95 Fax: 2653 7396 ® INSTRUCTIONS . and the name of centre and sign with pen in the boxes provided.® IIT−JEE 2011 SOLUTIONS ® 24 (Code: 2) SOLUTIONS TO IIT-JEE 2011 Paper-II Time: 3 Hours Maximum Marks: 240 Please read the instructions carefully. 16. In Section III (Total Marks: 24). Chennai-600 017 Delhi Office: 50-C. New Delhi-110 016 Ph. There are no negative marks in this section. 11. No additional sheets will be provided for rough work. 3. pagers and electronic gadgets are NOT allowed. a machine-gradable Optical Response Sheet (ORS). B. Question paper format and Marking Scheme: 13. DO NOT TAMPER WITH/MULTILATE THE ORS OR THE BOOKLET. Do not write them anywhere else. 15. 9. Registration No. Blank papers. If the codes do not match. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. 8. In Section II (Total Marks: 16). with a good quality HB pencil. calculators. Each part consists of four sections. Masilamani Street. slide rules. 2. C. There are no negative marks in this section. Physics and Mathematics). Brilliant Tutorials Pvt. 5. The question paper CODE is printed on the right hand top corner of this sheet. minus one (–1) mark will be awarded. clipboards. Nagar. 4. In Section I (Total Marks: 24). 17. ask for a change of the booklet. Head Office: 12. The question paper consists of 3 parts (Chemistry. Darken the appropriate bubble UNDER each digit of your registration No.

602 × 10–19 J NA = 6.022 × 1023 SECTION – I (Total Marks: 24) (Single Correct Answer Type) This section contains 8 multiple choice questions. At [Fe2+] = 10–3 M.57 V.314 JK–1 mol–1 or 8. the cell potential at 25°C is (A) 1. Ni2+.0 × 108 m s–1 1 F = 96500 C mol–1 1 eV = 1. [Co(NH3)6]Cl3 (L). Passing H2S gas into a mixture of Mn2+.: 2653 7392/93/94/95 Fax: 2653 7396 ® Note: Questions with (*) mark are from syllabus of class XI. Among the following complexes (K–P). Correct choice: (A) Consider the following cell reaction: 2+ 2Fe (s ) + O 2( g ) + 4H ( aq ) → 2Fe ( aq ) + 2H2O(l) .67 – = 1.67 V + Sol. New Delhi-110 016 Ph.® IIT−JEE 2011 SOLUTIONS 25 SOLUTIONS TO IIT-JEE 2011 CHEMISTRY: Paper-II (Code: 2) PART – I Useful Data R = 8. K2[Pt(CN)4] (O) and [Zn(H2O)6](NO3)2 (P) the diamagnetic complexes are (A) K. M. So. Cu2+ and Hg2+ ions in an acidified aqueous solution precipitates (A) CuS and HgS (B) MnS and CuS (C) MnS and NiS (D) NiS and HgS Cu2+ and Hg2+ belong to group II. they will precipitate as CuS and HgS respectively because their solubility product values are low. O.059 log 107 4 0. O.C.059 × 7 = 1. Na3[Co(oxalate)3] (M). on passing H2S gas.: Ligand Strong field ligand Strong field ligand Strong field ligand Weak field ligand Strong field ligand Weak field ligand 0 Magnetic character Paramagnetic Diamagnetic Diamagnetic Paramagnetic Diamagnetic Diamagnetic 3d54s0 3d 4s 3d 4s 10 8 6 Co3+ 2+ 3d64s0 0 Pt2+ Zn 2+ 5d86s0 3d 4s 0 Correct choice: (C) 2.57 V Sol. M. M. Each question has four choices (A).626 × 10–34 Js c = 3. M.87 V (D) 1. T. P (D) L. 1. (B). [Ni(H2O)6]Cl2 (N).67 – = 1.: Ecell = 1.206 × 10–2 L atm K–1 mol–1 h = 6.47 V (B) 1.67 – 0. E° = 1. Masilamani Street. N (B) K.1 0.1 atm and pH = 3.1 4 Correct choice: (D) Brilliant Tutorials Pvt. Head Office: 12. K3[Fe(CN)6] (K). L. N. P E. Chennai-600 017 Delhi Office: 50-C. (10 −3 ) 2 0. in acidified aqueous solution. (K) (L) (M) (N) (O) (P) Fe3+ Co Ni 3+ Sol.: 3. Ltd.77 V (C) 1.059 log 4 (10 −3 ) 4 × 0. Nagar. Kalu Sarai (Behind Azad Apartments). P(O2) = 0. (C) and (D) out of which ONLY ONE is correct. .67 – = 1. O (C) L.

Masilamani Street. Amongst the compounds given.: (C) an α-furanose Aldohexose Correct choice: (B) Brilliant Tutorials Pvt. Sol. the one that would form a brilliant colored dye on treatment with NaNO2 in dil.3 × 10–2 ⇒ Tf = 0 – 2.® IIT−JEE 2011 SOLUTIONS 26 4.7 × 10–3 ∆Tf = i × Kf × m ∆Tf = 4 × 1. Head Office: 12.86 K kg mol–1) is (A) –2. Nagar. HOCH 2R . The major product of the following reaction is RCH2OH O H+ (anhydrous) (A) a hemiacetal (C) an ether (B) an acetal (D) an ester H O ⊕ Sol. The freezing point (in °C) of a solution containing 0. Ltd.7 × 10–2 (D) –1.3 × 10–2 °C.1× 1000 = 2.2 × 10–2 (C) –5.: 2653 7392/93/94/95 Fax: 2653 7396 .: H3 C NaNO2 + HCl + − N2 Cl HO ® CH2NH2 OH N=N Red dye CH3 H3 C Correct choice: (C) 6.. The following carbohydrate is H HO HO H H HO H OH OH HO (A) a ketohexose (B) an aldohexose (D) an α-pyranose Sol.1 g of K3[Fe(CN)6] (molecular weight 329) in 100 g of water (Kf = 1.3 × 10–2 (B) –5. –H ⊕ H O O—CH2R H ⊕ O OCH2R Acetal Correct choice: (B) 7. New Delhi-110 016 Ph.: O H+ H O ⊕ . HCl followed by addition to an alkaline solution of β-naphthol is N(CH3)2 NHCH3 (B) (A) NH2 (C) H3C (D) NH2 Sol.86 × 0. Kalu Sarai (Behind Azad Apartments). Chennai-600 017 Delhi Office: 50-C.26 × 10–2 329 × 100 ≈ 2.. T.: Correct choice: (A) 5.

Chennai-600 017 Delhi Office: 50-C. (III) in magnetite. (III) in magnetite.4% left. Oxidation states of the metal in the minerals haematite and magnetite.303 log t [A] t [A] 0 0. (B) (II). Masilamani Street. (C) and (D) out of which ONE or MORE may be correct. (B) & (D) Brilliant Tutorials Pvt.: (A) [A ]t = [A]0 e − kt [A ] t ⇒ concentration after time ‘t’ [A]0 = initial concentration (B) Rate const ‘k’ increases with temperature.: 2653 7392/93/94/95 Fax: 2653 7396 . Ltd. 9. (B) the half-life of the reaction decreases with increasing temperature.6% completed ⇒ 0. Nagar. Kalu Sarai (Behind Azad Apartments). Head Office: 12. (D) (III) in haematite and (II). Sol.303 log = t1/ 2 t [ A] 0 / 256 t = 8t1 / 2 Correct choice: (A).6% completion in eight half-life duration. New Delhi-110 016 Ph. The equilibrium in aqueous medium at 25oC shifts towards the left in the presence of − (A) NO 3 (B) Cl − ® 2Cu+ Cuo + Cu2+ (C) SCN − (D) CN − Sol. (III) in haematite and (III) in magnetite. (C) the half-life of the reaction depends on the initial concentration of the reactant.® IIT−JEE 2011 SOLUTIONS 27 *8. Each question has four choices (A). (D) if 99. (D) the reaction proceeds to 99. k= [A] 0 2. 2CuSO 4 + 2 NaCl + SO 2 + 2H 2 O → 2CuCl + Na 2 SO 4 + 2H 2 SO 4 2CuSO 4 + 2 NaCN + SO 2 + 2H 2 O → 2CuCN + Na 2 SO 4 + 2H 2 SO 4 2CuSO 4 + 2 NaCNS + SO 2 + 2H 2 O → 2CuCNS + Na 2 SO 4 + 2H 2 SO 4 Correct choice: (B). (III) in haematite and (II) in magnetite. For the first order reaction 2 N 2 O 5 (g ) → 4 NO 2 (g ) + O 2 (g) (A) the concentration of the reactant decreases exponentially with time. are (A) (II). (C) & (D) 10. Haematite: Fe 2 O 3 III III II Sol.693 2. (C) (II) in haematite and (II). T.: Magnetite: Fe3O4 → Fe2O3 + FeO Correct choice: (D) SECTION – II (Total Marks: 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions. respectively.: Cuprous compounds can be obtained by passing SO2 through a solution containing copper sulphate and sodium salt. (B).

The resultant concentration of Ag+ in the solution is 1. m moles of Ag+ required to precipitate all Cl– ions is equal to m moles of Cl–. Reduction of the metal centre in aqueous permanganate ion involves (A) 3 electrons in neutral medium (B) 5 electrons in neutral medium (C) 3 electrons in alkaline medium (D) 5 electrons in acidic medium In neutral and alkaline media − MnO 4 + 2H 2 O + 3e − → MnO 2 + 4OH − In acidic medium − + 8H + + 5e − → Mn +2 + 4H 2 O MnO 4 Sol. Chennai-600 017 Delhi Office: 50-C.6 × 10 −10 = 1. T.26 × 10–5 M S CuCl = K sp = 1× 10 −6 = 1 × 10–3 M AgCl Ag+ + Cl–3 x – 10 + (1. New Delhi-110 016 Ph.01 M solution of [Cr(H2O)5Cl]Cl2.1 × V = 30 × 2 × 0. Correct choice: (A). Kalu Sarai (Behind Azad Apartments).01 . as silver chloride is close to [Cr (H 2 O) 5 Cl]Cl 2 →[Cr ( H 2 O) 5 Cl]+2 + 2Cl − ∴ m moles of Cl − = 30 × 2 × 0.: In 1 L saturated solution of AgCl [Ksp(AgCl)=1. Nagar. The bubble corresponding to the correct answer is to be darkened in the ORS. ∴ 0.6 × 10–7 ∴ x=7 ∴ The answer is 7. Sol. (C) & (D) 12.1 M AgNO3 required for complete precipitation of chloride ions present in 30 mL of 0.6 × 10–10]. Masilamani Street. Y = Br2/NaOH (B) X = CONH2.01 On adding AgNO3. ranging from 0 to 9.6 × 10–x.: Correct choice: (A).: 2653 7392/93/94/95 Fax: 2653 7396 ® . The value of “x” is S AgCl = K sp = 1.: The volume (in mL) of 0.: (A) CH3OOC—(CH2)4—COOCH3 (B) H2NOC—(CH2)4—CONH2 (C) H2NOC—(CH2)4—CO—NH2 (D) NC—(CH2)4—CN H2/Ni/∆ HO—CH2—(CH2)4—CH2—OH H2N—CH2—(CH2)4—CH2—NH2 H2N—(CH2)4—NH2 H2/Ni/∆ Br2/NaOH H H2N—CH2— (CH2)4—CH2—NH2 There is a formation of condensation products with acid and amine or alcohol.® IIT−JEE 2011 SOLUTIONS 11.1 mol of CuCl [Ksp(CuCl) = 1. Ltd.6 ×10 −10 10 − 3 = 1.26 × 10–5) ≈10–3 ∴ [Ag + ] = K sp (AgCl) [Cl − ] = 1. 0. Sol. The answer to each of the questions is a single-digit integer. *14. *13. ∴ V(AgNO3) = 6 ml ∴ The answer is 6. Y = H2/Ni/heat H2/Ni/∆ Sol. Y = H2/Ni/heat (D) X = CN. Y = H2/Ni/heat (C) X = CONH2. (C) & (D) SECTION−III (Total Marks: 24) (Integer Answer Type) This section contains 6 questions.0 × 10–6] is added. Brilliant Tutorials Pvt. Head Office: 12. (B). The correct functional group X and the reagent/reaction conditions Y in the following scheme are X—(CH2)4—X (i) Y (ii) 28 O C—(CH2)4—C HO OH heat O condensation polymer (A) X = COOCH3.

the number of compounds that can react with PCl5 to give POCl3 is O2.: Total number of hyperconjugation structures is one more than the total number of α-H atoms. ∴ The answer is 7. is CH3 CH3CH2 H CH2CH3 C CH3 CH2Cl CH3 Sol. PCl5 + H2O (insufficient) → POCl3 + 2HCl 2PCl5 + H2SO4 or SO2(OH)2 → SO2Cl2 + 2POCl3 + 2HCl. P4O10 PCl5 reacts with each of SO2. r. Kalu Sarai (Behind Azad Apartments). Nagar.: (i) CH3CH2 Cl CH2CH3 C (ii) CH3CH2 H CH2CH3 C (iii) CH3CH2 *C CH3 CH3 H CH Cl * (iv) CH3CH2 *C—CH 2— CH2Cl H 4-optical isomers 2-optical isomers ∴ The answer is 8. Chennai-600 017 Delhi Office: 50-C. Match the reactions in column I with appropriate types of steps/reactive intermediate involved in these reactions as given in column II. Masilamani Street. NaOH O (p) Column II Nucleophilic substitution (A) O O CH2CH2CH2Cl CH3MgI (q) Electrophilic substitution (B) O CH3 18O (C) (D) CH2CH2CH2OH CH2CH2CH2C(CH3)2 OH 18 H2SO4 (r) (s) Dehydration Nucleophilic addition H2SO4 H 3C CH3 (t) Carbanion Brilliant Tutorials Pvt. H2O. 29 The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following compound. statement B matches with the statements given in q and r. H2O. For example. Among the following. darken the bubbles corresponding to q and r in the ORS. against statement B.: 16. The total number of contributing structures showing hyperconjugation (involving C–H bonds) for the following carbocation is Sol. PCl5 + SO2 → SOCl2 + POCl3 6PCl5 + P4O10 → 10POCl3 ∴ The answer is 4. Sol. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II.: 18. T. New Delhi-110 016 Ph. if for a given question. q. H2SO4 and P4O10 to form POCl3. CO2. SECTION − IV (Total Marks : 16) (Matrix − Match Type) This section contains 2 questions. Sol. Ltd. Column I H3C O O aq. The number of hexagonal faces that are present in a truncated octahedron is The answer is 8.: 2653 7392/93/94/95 Fax: 2653 7396 ® H3C ⊕ CH2CH3 . Each question has four statements (A. *17. B. s and t) in Column II. Head Office: 12. 19.® IIT−JEE 2011 SOLUTIONS 15. C and D) given in Column I and five statements (p. H2SO4. then for the particular question. SO2.

(B) – (p). Masilamani Street. (C) – (t) .® IIT−JEE 2011 SOLUTIONS Sol. (D) – (q). (s) . (s) . Kalu Sarai (Behind Azad Apartments). (r).: (A) – (p). (C) – (r). 30 Column I (A) (B) CO 2 (s) → CO 2 (g) CaCO 3 (s) → CaO(s) + CO 2 (g ) (p) (q) (r) (s) (t) phase transition allotropic change ∆H is positive ∆S is positive ∆S is negative Column II (C) 2H • → H 2 (g ) (D) P( white. (s). Ltd. New Delhi-110 016 Ph. solid ) → P( red. T. (t) . solid ) Sol. Nagar.: 2653 7392/93/94/95 Fax: 2653 7396 ® . Chennai-600 017 Delhi Office: 50-C. (r). (A) – (r). (s) .: *20. (t) Brilliant Tutorials Pvt. (r) Match the transformations in column I with appropriate options in column II. (s) . (D) – (q). Head Office: 12. (B) – (p).

An object of mass ‘m’ is ejected from the satellite such that it just escapes from the gravitational pull of the earth. Masilamani Street. 3π 4 (B) A. The spiral lies in the X-Y plane and a steady current ‘I’ flows through the wire.: 2653 7392/93/94/95 Fax: 2653 7396 . dN = dr µ NI b B= 0 ln 2(b − a ) a ⇒ µ IN dB = 0 2(b − a ) ∫ a b dr r r ⇒ Correct choice: (A) *23.: dB = . Kalu Sarai (Behind Azad Apartments). Nagar. π 3 Sol.: r Fnet = 0 r r r ⇒ a1 + a 2 + a 3 = 0 By phasor addition 4π ∴ B = A and φ = 3 Correct choice: (B) Aω2 φ Bω2 2π/3 Aω2 Brilliant Tutorials Pvt.® IIT−JEE 2011 SOLUTIONS 31 SOLUTIONS TO IIT-JEE 2011 PHYSICS: Paper-II (Code: 2) PART – II SECTION – I (Total Marks: 24) (Single Correct Answer Type) This section contains 8 multiple choice questions. Ltd. 5π 6 (D) A. 4π 3 (C) 3 A. Head Office: 12. A point mass is subjected to two simultaneous sinusoidal displacements in x-direction. Each question has four choices (A). (B). New Delhi-110 016 Ph. The values of B and φ are (A) 2 A. A satellite is moving with a constant speed ‘V’ in a circular orbit about the earth. *21. A long insulated copper wire is closely wound as a spiral of ‘N’ turns. T.: To move object to infinity K= GMm = mV 2 r − Correct choice: (B) 22. 2π x1(t) = Asinωt and x2(t) = A sin ωt + . the kinetic energy of the object is (A) 1 mV 2 2 (B) mV 2 GMm +K =0 r GM V = r (C) 3 mV 2 2 (D) 2mV 2 Sol. At the time of its ejection. Chennai-600 017 Delhi Office: 50-C. The spiral has inner radius ‘a’ and outer radius ‘b’. The Z-component of the magnetic field at the center of the spiral is (A) (C) µ0 N I b ln 2(b − a ) a µ0 N I b ln 2b a µ 0 dNI 2r N dr b−a Y ® I b (B) (D) µ0 N I b + a ln 2(b − a ) b − a µ0 N I b + a ln 2b b−a a X Sol. Adding a third sinusoidal displacement x3(t) = Bsin(ωt + φ) brings the mass to a 3 complete rest. (C) and (D) out of which ONLY ONE is correct.

5 + 0. of div.5 = = 0. After the collision. Nagar.2 u ball Correct choice: (D) *26.: Pitch 0 .2 % LC = Sol. The diameter of the ball is measured with a screw gauge.01 mm No.5 mm and that on the circular scale is 20 divisions. the ball and bullet travel independently. = 2% + 3 × 0.01 × 100% 2. ⇒ V = 500 m/s The density of a solid ball is to be determined in an experiment.70 = 3 .4 % (C) 3. 32 Which of the field patterns given below is valid for electric field as well as for magnetic field? (A) (B) (C) (D) Sol. Correct choice: (A) E +Q Sol. by conservation of momentum 0. Ltd. traveling with a velocity V m/s in a horizontal direction. hits the centre of the ball. Correct choice: (C) *25. Chennai-600 017 Delhi Office: 50-C.70 mm ∆ρ ∆m 3∆d ×100% = ×100% + ×100% m d ρ Correct choice: (C) *27. (A) 250 m/s (C) 400 m/s Sol.01 × 20 = 2.: Induced electric field is nonconservative. The block r carries a charge +Q on its surface. If now a uniform electric field E is switched-on as shown.: 2653 7392/93/94/95 Fax: 2653 7396 . A bullet of mass 0.: (B) 250 2 m/s (D) 500 m/s 2h g 2×5 10 ⇒ u ball = 20 m/s ® 0 20 A ball of mass 0.2 kg rests on a vertical post of height 5 m.® IIT−JEE 2011 SOLUTIONS 24. New Delhi-110 016 Ph.01 V = 0. whose pitch is 0. The initial velocity V of the bullet is V m/s 100 R=u ⇒ 20 = u ball 100 = ubullet 2×5 ⇒ u bullet = 100 m/s 10 Now.01 u bullet + 0.: Brilliant Tutorials Pvt.5 mm and there are 50 divisions on the circular scale. T. The ball hits the ground at a distance of 20 m and the bullet at a distance of 100 m from the foot of the post. Kalu Sarai (Behind Azad Apartments). on circular scale 50 Reading of diameter = MSR + LC × CSR = 2. v0.1 % A wooden block performs SHM on a frictionless surface with frequency. the relative percentage error in the density is (A) 0. The reading on the main scale is 2. Masilamani Street.1 % (D) 4. Head Office: 12. If the measured mass of the ball has a relative error of 2%. then the SHM of the block will be (A) of the same frequency and with shifted mean position (B) of the same frequency and with the same mean position (C) of changed frequency and with shifted mean position (D) of changed frequency and with the same mean position Electric field will shift the mean position and frequency will remain same.9 % (B) 2.01 kg.

Head Office: 12.: Brilliant Tutorials Pvt. Chennai-600 017 Delhi Office: 50-C. (D) The work done by the external force in moving a unit positive charge from point A at potential VA to point B at potential VB is (VB – VA) The work done by the external force in moving a unit positive charge from point A at potential VA to point B at potential VB is (VB – VA) only when motion of charge particle is without acceleration. Which of the following is/are true? A B > IR (A) I R A B (B) I R < IR (C) VCA > VCB ® 900 (D) VCA < VCB Sol. ∴ IT < 100% At θ = θc I transmitted = 0 and I reflected = 100% Correct choice: (C) SECTION – II (Total Marks : 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions.: 2653 7392/93/94/95 Fax: 2653 7396 . both as function of θ. New Delhi-110 016 Ph. The reflected (R) and transmitted (T) intensities. Ltd. then the sign of the two charges is the same. (C) and (D) out of which ONE OR MORE may be correct. X2 = ⇒ X2 = 1 ωC 4 ωC 4 X 12 . Since nothing is given about motion. Kalu Sarai (Behind Azad Apartments). then the Gauss law will still be valid. Consider two cases. 29.5 instead of r –2. are plotted. VC = I rms X C Correct choices: (B). I rms = 16 E rms R2 + X 2 Z 1 = R 2 + X 12 . Each question has four choices (A). (C) If the electric field between two point charges is zero somewhere. Which of the following statement(s) is/are correct? (A) If the electric field due to a point charge varies as r –2. Masilamani Street. 33 A light ray traveling in glass medium is incident on glass-air interface at an angle of incidence θ.: At θ = 0 partial reflection will occur. The correct sketch is 100% T Intensity (A) (B) Intensity 100% T R θ 90 0 R θ 900 0 0 100% T Intensity (C) (D) R θ 90 0 100% T Intensity R θ 0 0 Sol. Nagar. (A) when C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. so option (D) is incorrect. Correct choice: (C) Sol. (B). A series R-C circuit is connected to AC voltage source. The current IR through the resistor and voltage VC across the capacitor are compared in the two cases. Z 2 = R 2 + B A > IR and VCA > VCB ∴ IR .: X1 = X 1 1 . (B) The Gauss law can be used to calculate the field distribution around an electric dipole. (C) 30.® IIT−JEE 2011 SOLUTIONS 28. T.

Here.: A block of mass 0. (C) friction between the ring and the ground is to the left. They get arranged into an equilibrium state as shown in the figure with a tension in the string. (D) SECTION – III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. 34 A thin ring of mass 2 kg and radius 0.75m 1 m/s Sol. as F = VdF g. A small ball of mass 0. Initially the block is at rest and the spring is un-stretched. (i) …. MA = VdA and MB = VdB From (i) & (ii).5 m is rolling without slipping on a horizontal plane with velocity 1 m/s. Sol. So. (B) the ring comes to a complete stop.1 kg. The block slides a distance of 0. from (iii) d B > d F and d A > d F Correct choices: (A). hits the ring at a height of 0. Nagar.® IIT−JEE 2011 SOLUTIONS *31. The bubble corresponding to the correct answer is to be darkened in the ORS.: F F T A T B MBg here F is upthrust force MAg F = T + M Ag F + T = MBg ….: Friction between ring and surface is impulsive. Chennai-600 017 Delhi Office: 50-C. Sense of rotation will not change. T = B g . Ltd. They are fully immersed in a fluid of density dF. Masilamani Street. Immediately after the collision (A) the ring has pure rotation about its stationary CM. Kalu Sarai (Behind Azad Apartments). *33. The coefficient of friction between the block and the floor is 0.75 m and goes vertically up with velocity 10 m/s. The arrangement is possible only if (A) dA < dF (C) dA > dF (B) dB > dF (D) dA + dB = 2dF ® A B Sol. T. (iii) Vd F g = 2 2 M −MA Also. (B). (D) there is no friction between the ring and the ground. F = 2 V (d A + d B ) g d + dB ⇒ ⇒ dF = A ….1. Two solid spheres A and B of equal volumes but of different densities dA and dB are connected by a string.18 kg is attached to a spring of force-constant 2 N/m. The initial velocity of the block in m/s is V = N/10. The answer to each question is a single-digit integer. An impulse is given to the block as shown in the figure. Correct choice: (C) *32.06 m and comes to rest for the first time. Then N is 1 1 mV 2 = kx 2 + µ mg x 2 2 Brilliant Tutorials Pvt. ranging from 0 to 9. 10 m/s 20 m/s 0.: 2653 7392/93/94/95 Fax: 2653 7396 . moving with velocity 20 m/s in the opposite direction. (ii) (M A + M B ) g . New Delhi-110 016 Ph. T > 0 ⇒ d B > d A 2 Also. Head Office: 12. friction will act towards left.

The location of its image is at ‘x’ cm above the bottom of the tank. Two batteries of different emfs and different internal resistances are connected as shown. Kalu Sarai (Behind Azad Apartments). 4 7 ) in a tank is 18 cm deep. Then ‘x’ is Water (with refractive index = S µ=1. Chennai-600 017 Delhi Office: 50-C. T. Oil of refractive index lies on water making a convex surface 3 4 of radius of curvature ‘R = 6 cm’ as shown.: 2Ω V= E1 r2 + E 2 r1 =5V r1 + r2 The answer is 5. Head Office: 12.: Applying refraction formula at air-oil interface (7 4) − 1 = (7 4) − 1 ⇒ v = 21 cm 1 v1 6 − 24 Again refraction at oil-water interface (4 3) − (7 4) = 0 ⇒ v = 16 cm 2 21 v2 ∴ From bottom.® IIT−JEE 2011 SOLUTIONS k x2 = 0.: A series R-C combination is connected to an AC voltage of angular frequency ω = 500 radian/s.25 . The answer is 4. ∴ Brilliant Tutorials Pvt.0 R = 6cm µ=7/4 µ=4/3 Sol.5 R Also. The voltage across AB in volts is 6V A 1Ω B 3V Sol.4 m/s m 35 V = 2µg x + Q N = 10V = 4 ∴ 34. ∴ 35. Sol. An object ‘S’ is placed 24 cm above water surface.: 2653 7392/93/94/95 Fax: 2653 7396 ® . If the impedance of the R-C circuit is R 1. Consider oil to act as a thin lens. New Delhi-110 016 Ph. the time constant (in millisecond) of the circuit is 2 2 Z 2 = R2 + X c ⇒ 1. Ltd.25 R 2 = R 2 + X c ∴ X = 0. x = 18 − 16 = 2 cm ∴ The answer is 2. Masilamani Street. RC = 1 = 0 . 36.5 R ωC 1 = 4 × 10−3 s = 4 ms 0.5ω The answer is 4. Nagar.

It is under continuous illumination of 200 nm wavelength light. Match each system with statements given in Column II describing the nature and wavelength of the standing waves. in m/s2.2 eV. 36 Sol. darken the bubbles corresponding to q and r in the ORS. C and D) given in Column I and five statements (p. a Xbt = −a . whose wavelength is denoted as λf.7 eV is suspended from an insulating thread in free-space. X bt = 1. r. As photoelectrons are emitted. then for the particular question. The answer is 5. Chennai-600 017 Delhi Office: 50-C. t. B.15 m X bt ∴ SECTION − IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. A boy standing in the train throws a ball forward with a speed of 10 m/s. Masilamani Street. Ltd. q. (B) – p. The acceleration of the train. Nagar. each of the same length L.: A silver sphere of radius 1 cm and work function 4. Column I (A) Pipe closed at one end (p) Column II Longitudinal waves 0 (B) Pipe open at both ends L (q) 0 L (C) Stretched wire clamped at both ends 0 L (r) (s) (D) Stretched wire clamped at both ends and at mid-point 0 L/2 L (t) Ans. s. T. Sol. (C) – q.: (A) – p. at an angle of 60o to the horizontal.5 V = 1 ne ∴ n = 1. statement B matches with the statements given in q and r.15 m inside the train to catch the ball back at the initial height. The boy has to move forward by 1. The value of ‘Z’ is hc 1240 = = 6.2 − 4. is u Xbt = u cos θ = 5 m/s.7 = eV0 E= λ 200 V0 = 1. New Delhi-110 016 Ph. Z = 7 ∴ *38. The lowest possible natural frequency of a system is called its fundamental frequency. the sphere gets charged and acquires a potential. The maximum number of photoelectrons emitted from the sphere is A × 10Z (where 1 < A < 10). s and t) in Column II.: A train is moving along a straight line with a constant acceleration ‘a’. Kalu Sarai (Behind Azad Apartments).: 2653 7392/93/94/95 Fax: 2653 7396 ® Transverse waves λf = L λf = 2L λf = 4L From. For example. against statement B. r Brilliant Tutorials Pvt. E = φ + eV0 ⇒ 6. Head Office: 12. *39. (D) – q.04 × 107 4πε 0 r This gives. for producing standing waves. Column I shows four systems. if for a given question. The answer is 7. Each question has four statements (A.® IIT−JEE 2011 SOLUTIONS 37. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. s. = u Xbt T + 1 a Xbt T 2 2 2u sin θ = 3 s T = g ∴ a = 5 m/s2 .

(r) (s) (t) Column I (A) Process A → B (B) Process B → C (C) Process C → D (D) Heat is lost. t Brilliant Tutorials Pvt. T. Nagar.: (A) – p. t. Work is done on the gas. s. r. Chennai-600 017 Delhi Office: 50-C. P 3P B A 1P C 0 1V 3V D 9V V Column II (p) Internal energy decreases. (D) – r. (B) – p. (C) – q. Process D → A Sol. New Delhi-110 016 Ph. r.: 2653 7392/93/94/95 Fax: 2653 7396 ® . Match them with each of the processes given in Column I. Ltd. Column II gives the characteristics involved in the cycle.® IIT−JEE 2011 SOLUTIONS 37 *40. (q) Internal energy increases. Head Office: 12. Kalu Sarai (Behind Azad Apartments). One mole of a mono atomic ideal gas is taken through a cycle ABCDA as shown in the P-V diagram. Heat is gained. Masilamani Street.

: 2653 7392/93/94/95 Fax: 2653 7396 . A value of b for which the equations x 2 + bx − 1 = 0 x2 + x + b = 0 . Nagar. Ltd. Let ω ≠ 1 be a cube root of unity and S be the set of all non-singular matrices of the form 1 ω 2 ω a b 1 c . Masilamani Street. ω 1 where each of a. number of distinct matrices = 2 Correct choice: (A) Brilliant Tutorials Pvt. Chennai-600 017 Delhi Office: 50-C.: (B) − i 3 (C) i 5 (D) 2 ⇒ And α 2 + bα − 1 = 0 α +α+b = 0 2 …(i) …(ii) b +1 b −1 Subtracting we get (b − 1)α = 1 + b ⇒ α = Substituting the value of α in equation (i) ⇒ ⇒ b +1 b +1 + b −1 = 0 b −1 b −1 b 3 + 3b = 0 ⇒ b = ± 3i. T. have one root in common is (A) − 2 Sol. b and c is either ω or ω 2 . *41. New Delhi-110 016 Ph. Each question has four choices (A). out of which ONLY ONE is correct.: 1 det ω ω 2 a b 1 c ω 1 (B) 6 (C) 4 ® Let α be the common root (D) 8 = 1 − ωc + a (ω 2 c − ω) + b(ω 2 − ω 2 ) = 1 + acω 2 − ω(a + c) Case I : Case II : If a = ω and c = ω ⇒ 1 + ω − 2ω 2 = −3ω 2 ≠ 0 If a = ω and c = ω 2 ⇒ 1 + ω 2 + ω = 0 Case III : If a = ω 2 and c = ω ⇒ 1 + ω 2 + ω = 0 Case IV : If a = ω 2 and c = ω 2 ⇒ 1 + 1 − 2ω 3 = 0 Hence.® IIT−JEE 2011 SOLUTIONS 38 SOLUTIONS TO IIT-JEE 2011 MATHEMATICS: Paper-II (Code: 2) PART – III SECTION – I (Total Marks : 24) Single Correct Answer Type This section contains 8 multiple choice questions. Head Office: 12. (B). Kalu Sarai (Behind Azad Apartments). Then the number of distinct matrices in the set S is (A) 2 Sol. 0 2 Correct choice: (B) 42. (C) and (D) for its answer.

Ltd. 0) and touching the y-axis at (0. 2) (0. R 2 = −1 ∫ f ( x)dx 2 Hence. 2) 5 25 Circle is x + + ( y − 2) 2 = 2 4 Correct choice: (D) 44. 2) also passes through the point 3 (A) − . then the value of θ is (B) ± π 3 (C) ± π 6 (A) ± π 4 lim 1 + x ln 1 + b 2 x →0 2 1 lim x ln(1+ b )× x ® (D) ± π 2 Sol.® IIT−JEE 2011 SOLUTIONS 39 *43. Nagar.: 2653 7392/93/94/95 Fax: 2653 7396 . Head Office: 12. 2 2 (D) ( −4.: −5 2 (h. x = 2 . Then (A) R1 = 2 R2 (B) R1 = 3R2 2 (C) 2 R1 = R2 (D) 3R1 = R2 Sol. and R 2 2 be the area of the region bounded by y = f ( x).: [ ( )] 1 x = e x →0 ⇒ ⇒ ⇒ ⇒ ⇒ ⇒ = 1+ b 2 1 + b 2 = 2b sin 2 θ sin 2 θ = 1+ b2 1 1 = + b 2b 2b 1 +b ≥ 2 b sin 2 θ ≥ 1 sin θ = ±1 θ=± π 2 Correct choice: (D) 45. T.: R1 = −1 ∫ x f ( x)dx 2 ⇒ R1 = (1 − x) f ( x)dx −1 ∫ ⇒ 2 R1 = −1 ∫ 2 f ( x)dx. 0 2 ( x − h ) 2 + ( y − 2) 2 = h 2 (h + 1) 2 + 4 = h 2 ⇒ h = 2 5 (B) − . Let f : [−1. 2] . Chennai-600 017 Delhi Office: 50-C. b > 0 and θ ∈ ( − π. ∞) be a continuous function such that f ( x) = f (1 − x) for all x ∈ [−1. π] . 2 R1 = R 2 Correct choice: (C) Brilliant Tutorials Pvt. New Delhi-110 016 Ph. and the x-axis. Let R1 = −1 ∫ x f ( x) dx . x = −1. The circle passing through the point (–1. 2 2 3 5 (C) − . Kalu Sarai (Behind Azad Apartments). If lim 1 + x ln(1 + b 2 ) x →0 [ ] 1 x = 2b sin 2 θ. Masilamani Street. 2] → [0. 0) Sol.

: Since normal meet x-axis at (9.. Then the locus of P is (A) x 2 = y (B) y 2 = 2 x (C) y 2 = x (D) x 2 = 2 y ® Sol. − 1. 2.® IIT−JEE 2011 SOLUTIONS 40 46. 0) X y2=4x R (x. n ∈ {. n ∈ {0. 1.. k) O (0. 1.. Then the set of all x satisfying ( f o g o g o f ) ( x) = ( g o g o f )( x ) . y ⇒ y = 4k 4 Y 3 P 1 (h. 1. .} (C) π + 2nπ... Head Office: 12.. is (A) ± n π . k ∈ integer 2 sin x 2 = 0 only x 2 = nπ ⇒ x = ± nπ where n ∈{0. .. New Delhi-110 016 Ph. 3) be a point on the hyperbola eccentricity of the hyperbola is (A) 5 2 x−6 6/a 2 x2 a2 − y2 b2 = 1 . . Masilamani Street.. 2. 0.. − 1.: π . y ) in the ratio 1 : 3.. 0. then the (B) =− y −3 3 / b2 3 2 (C) 2 (D) 3 Sol. k) be the point which divides OR in ratio 1 : 3 ⇒ h= k= 3 .−2. ..−2..: 2653 7392/93/94/95 Fax: 2653 7396 ..} Correct choice: (A) *47.} 2 sin 2 (sin x 2 ) = sin(sin x 2 ) ⇒ ⇒ ⇒ sin(sin x 2 ) = 0 or 1 sin x 2 = kπ or ( 4k + 1) (B) ± n π . Let ( x..} Sol.} (D) 2nπ. If the normal at the point P intersects the x-axis at (9..... . 1. Let P be the point that divides the line segment from (0.. n ∈ {1. Nagar..: Let P(h.... Kalu Sarai (Behind Azad Apartments). Ltd.. where ( f o g ) ( x) = f ( g ( x)) . y) Since R lie on the y 2 = 4 x ⇒ ⇒ ( 4 k ) 2 = 4( 4 h ) k2 = h ⇒ Locus of P is y 2 = x Correct choice: (C) *48. 2. 0) to ( x. Chennai-600 017 Delhi Office: 50-C. 2... T. y ) be any point on the parabola y 2 = 4 x . 0). n ∈ {.0 + 1 . 0) so 9 = 6b a2 +6 ∴ b2 a2 = 1 2 1 = 2 3 2 e = 1+ Correct choice: (B) Brilliant Tutorials Pvt. Let f ( x) = x 2 and g ( x) = sin x for all x ∈ R . 2.0 + 1 . Let P (6. x ⇒ x = 4h 4 3 ..

T. (C) and (D) for its answer. (D) 51. we get x = or x= 4 3 . Head Office: 12. 1. Kalu Sarai (Behind Azad Apartments). Let E and F be two independent events. therefore f −1 ( x) does not exists. 49.: Any normal is y = mx − 2m − m ⇒ ⇒ ⇒ 6 = 9m − 2m − m 3 m 3 − 7m + 6 = 0 m = −3. Let f : (0. where b is a constant such that 0 < b < 1 . Each question has four choices (A). out of which ONE OR MORE may be correct. 5 5 Correct choice: (A). New Delhi-110 016 Ph. Nagar. (D) *50. Correct choice: (A) Brilliant Tutorials Pvt.® IIT−JEE 2011 SOLUTIONS 41 SECTION – II (Total Marks : 16) Multiple Correct Answer(s) Type This section contains 4 multiple choice questions. 1) and f ′(b) = Sol. Ltd. 1) (C) f = f −1 on (0. If P (T ) denotes the probability of occurrence of the event T . (B). 1) and f ′(b) = 1 f ′(0) (D) f −1 is differentiable on (0.: Let P( E ) = x and P( F ) = y ⇒ and ⇒ x + y − 2 xy = 11 25 2 25 …(i) (1 − x)(1 − y ) = x + y − xy = 23 25 3 4 . 1) 1 ′ f ( 0) Correct choice: (A). Then 1 − bx (B) f ≠ f −1 on (0. Let L be a normal to the parabola y 2 = 4 x . (B). y= 5 5 …(ii) Solving. P( F ) = 5 5 11 and the probability of none 25 4 3 . y = x − 3 and y = 2 x − 12 b−x . P ( F ) = 5 5 (C) P ( E ) = 2 1 . f ( x) is into. If L passes through the point (9. The probability that exactly one of them occurs is of them occurring is (A) P ( E ) = 2 . Chennai-600 017 Delhi Office: 50-C. y= . b) ⊂ R Hence. P( F ) = 5 5 3 4 (D) P ( E ) = . 1) → R be defined by f ( x) = (A) f is not invertible on (0. 2 ∴ Normals are y = −3 x + 33. Masilamani Street. then L is given by (A) y − x + 3 = 0 (B) y + 3x − 33 = 0 3 (C) y + x − 15 = 0 ® x (1 − y ) + y (1 − x) = 11 25 (D) y − 2 x + 12 = 0 Sol. then 25 1 2 (B) P ( E ) = . P( F ) = 5 5 Sol. 6).: As f ( x) is one to one but its range is (−1.: 2653 7392/93/94/95 Fax: 2653 7396 .

New Delhi-110 016 Ph. 2 d f ( x) and g ( x) is a given non-constant dx 54. Ans. then 2 0 < x ≤1 x − 1.® IIT−JEE 2011 SOLUTIONS 42 52.: dy + g ' ( x) y = g ( x) g ' ( x) dx y e g ( x ) = e g ( x ) g ( x) g ' ( x )dx ∫ Brilliant Tutorials Pvt. x ∈ R . Chennai-600 017 Delhi Office: 50-C. Then the value of y (2) is Sol. x x >1 ln . in the ORS is to be bubbled. Kalu Sarai (Behind Azad Apartments). π π x≤− − x − 2 . y (0) = 0. Let y′( x ) + y ( x) g ′( x) = g ( x) g ′( x).: 2653 7392/93/94/95 Fax: 2653 7396 ® π π f − = 0 ∴ f ( x) is continuous at x = − 2 2 . (C). 2 − cos x − π < x ≤ 0 If f ( x) = . (A) f ( x) is continuous at x = − π 2 (B) f ( x) is not differentiable at x = 0 (D) f ( x) is differentiable at x = − 3 2 (C) f ( x) is differentiable at x = 1 Sol. The correct digit below the question no. RHD = 1 f ( x) is differentiable at x = 1 x=− 3 3 : LHD = RHD = sin − 2 2 −3 2 At ∴ At ∴ f ( x) is differentiable at x = Correct choice: (A). 2 x = 0 : LHD = sin 0 = 0 RHD = 1 ∴ f ( x) is not differentiable at x = 0 x = 1 : LHD = 1. (D) SECTION − III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions.: The number of distinct real roots of x 4 − 4 x 3 + 12 x 2 + x − 1 = 0 is Let f ( x) = x 4 − 4 x 3 + 12 x 2 + x − 1 f ' ( x) = 4 x 3 − 12 x 2 + 24 x + 1 f " ( x ) = 12 x 2 − 24 x + 24 = 12( x 2 − 2 x + 2) > 0 ⇒ ⇒ f ( x) has exactly 1 point of minima and f (0) is – 1 f ( x) has two distinct real roots. (B). T. 53. Nagar. Sol.: At and At x=− π : LHL = RHL = 0. Masilamani Street. Head Office: 12. ranging from 0 to 9. Ltd. where f ′( x) denotes differentiable function on R with g (0) = g (2) = 0 . The answer to each question is a single-digit integer.

Ltd. M − 1 = 1 . a = 0 . New Delhi-110 016 Ph.® IIT−JEE 2011 SOLUTIONS = ( g ( x) − 1)e g ( x ) + c y = g ( x) − 1 + c e − g ( x ) Put x = 0 0 = −1 + c ⇒ c = 1 Put x = 2 y (2) = −1 + e −0 = −1 + 1 = 0 Ans. Kalu Sarai (Behind Azad Apartments).: ∴ 0 − 1 M 1 = 2 3 0 a 2 = −1 b2 = 2 c2 = 3 …(i) ⇒ 1 1 Again. b = −i ˆ be three given vectors. r r then the value of r . M − 1 = 1 − 1 0 a1 − a 2 = 1 b1 − b2 = 1 c1 − c 2 = −1 ⇒ a1 = 1 + a 2 = 1 + (−1) = 0 b1 = 1 + b2 = 1 + 2 = 3 c1 = −1 + c 2 = −1 + 3 = 2 Also ⇒ ∴ c1 + c 2 + c 3 = 12 c 3 = 12 − c1 − c 2 = 12 − 2 − 3 = 7 Required sum is = a1 + b2 + c 3 = 0+2+7 =9 Ans. 9 56. Nagar. Head Office: 12. c = i +2ˆ j + 3k r r r r r ×b − c ×b = 0 r r r (r − c ) × b = 0 Brilliant Tutorials Pvt. b is r r r ˆ ˆ . Masilamani Street. If r ˆ−k ˆ+ ˆ + 2ˆ j and c = i j + 3k Let a = −i is a vector such that r × b = c × b and r . 0 43 55.: ® . 1 0 1 1 0 − 1 Let M be a 3 x 3 matrix satisfying M 1 = 2 . and M 1 = 0 .: 2653 7392/93/94/95 Fax: 2653 7396 Sol. Then the sum of the diagonal entries of 12 1 − 1 3 0 0 M is Let M be a1 b1 c1 a2 b2 c2 a3 b3 c3 Sol. T. b = −i ˆ ˆ−k ˆ+ ˆ a = −i j. r r r ˆ r r r r r r r ˆ . Chennai-600 017 Delhi Office: 50-C.

® IIT−JEE 2011 SOLUTIONS ⇒ So r r r So r − c || b r r r r − c = λb r r r ˆ ) + λ ( −i ˆ+2ˆ ˆ+ ˆ r = c + λb = (i j + 3k j) 44 ˆ ˆ + (2 + λ) ˆ ˆ = (1 − λ)i r j + 3k rr r . . New Delhi-110 016 Ph. T. 0) (0. line 2 x − 3 y − 1 = 0 3 Case I 2. 4 = 2× 2 − 3× 1 1 Case II . λ = 4 r ˆ ˆ + ( 2 + 4) ˆ r = (1 − 4)i j + 3k r ˆ ˆ + 6ˆ r = −3i j + 3k r r ˆ). 0) in equation 2 x − 3 y − 1 = 0 So = 2 × 0 − 3 × 0 − 1 = − ve Since points are in smaller region. . lies inside the circle 4 4 4 8 4 Put value of O (0.b = (−3i j + 3k j) = 3+ 6 = 9 rr r . .t. then the number of point(s) in S lying inside the smaller part is 4 2 4 4 4 8 4 Sol. Kalu Sarai (Behind Azad Apartments). . Nagar.: Only points 1 3 1 1 1 2. If 3 5 3 1 1 1 1 S = 2. Head Office: 12. Ltd.r. − .b = 9 So Ans. –1/3) x2 + y2 = 6 2 x – 3y = 1 2 3 + − 1 = + ve 4 4 1 1 Case III . Chennai-600 017 Delhi Office: 50-C.a = 0 ⇒ ⇒ −(1 − λ ) + 0 − 1× 3 = 0 −1 + λ − 3 = 0. . 9 *57. So points should be opposite to origin w.0) (1/2. 8 4 = 2× = = 1 1 − 3× −1 8 4 2 3 − −1 8 4 2−6−8 = − ve 8 Brilliant Tutorials Pvt. . − 4 4 = 2× = 1 1 − 3× − −1 4 4 3 9 − 1 = 3 − > 0 + ve 4 4 (0.: 2653 7392/93/94/95 Fax: 2653 7396 .(−i ˆ + 6ˆ ˆ+ ˆ r . The straight line 2x − 3y = 1 ® x2 + y2 ≤ 6 divides the circular region into two parts. Masilamani Street. . . − and .

® IIT−JEE 2011 SOLUTIONS 45 1 3 1 Out of these 3 points only 2. | z | = 1. ∞) *(C) (r) [2. Nagar.: (A) – (s).) But . C and D) given in Column I and five statements (p. b. x = 3. ∞) (B) 8(3) x − 2 is The domain of the function f ( x) = sin −1 1 − 32( x −1) 1 tan θ 1 π If f (θ) = − tan θ 1 tan θ . 0] ∪ [2. c. a. r. ∞) (D) (s) (t) (− ∞. x. s and t) in Column II. Masilamani Street. x = 1.: Value of this expression does not come out to be constant as it depends on choice of a.: 2653 7392/93/94/95 Fax: 2653 7396 . against statement B. If we take ω = e i 2π 3 then it is constant and equal to 3. . y. statement B matches with the statements given in q and r. c = 1. − lie inside the smaller part as origin (0. Match the statements given in Column –I with the intervals/union of intervals given in Column-II. Column I *(A) ® Column II (p) 2i z The set Re 2 1− z : z is a complex number. y = −1 + 3i. (B) – (t). B. (A) 2i 2iz Re Re = 1 1− z 2 −z z Brilliant Tutorials Pvt. darken the bubbles corresponding to q and r in the ORS 59. Each question has four statements (A. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. y = z = 1 + 3i then expression is equal to 17 . 2 *58. New Delhi-110 016 Ph. For example. Head Office: 12. if for a given question. SECTION − IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. z = −1 + 3i then expression is equal to 3 etc. b = 1. T. then f ( x) is increasing in (q) (− ∞. 0) ∪ (0. then for that particular question. ∞) Sol. . (D) – (r). z ≠ ±1 is ( − ∞. Ltd. Then the value of | x |2 + | y |2 + | z |2 | a |2 + | b |2 + | c |2 is *Sol. Kalu Sarai (Behind Azad Apartments). − 1) ∪ (1. ∞) (− ∞. Let ω = eiπ / 3 and. − 1] ∪ [1. q. x ≥ 0 . c. 3 Similarly a = −1. (C) – (r). b. then the set f (θ) : 0 ≤ θ < is 2 1 −1 − tan θ If f ( x) = x3 / 2 (3x − 10). 0) and these points lie on opposite side of 4 4 4 line 2 x − 3 y − 1 = 0 Ans. Chennai-600 017 Delhi Office: 50-C. (For example if a = b = c. z be non-zero complex numbers such that a+b+c = x a + bω + cω2 = y a + bω2 + cω = z .

3 x + 9 − 3 2 x (3 + 3 x )(3 − 3 x ) (3 2 x − 8. Nagar. 0] ∪ [2. ∞) (B) 46 −1 ≤ 8 . Chennai-600 017 Delhi Office: 50-C. ∞ ) 8 .3 x 9 − 32x −1 ≤ 0 8 . 0] ∪ (1.3 x 9 − 32x +1 ≥ 0 ≥0 ≥0 ≥0 ≥0 …(i) 8.3 x + 3 x − 9 3 x (3 x − 9) + (3 x − 9) x ∈ ( −∞.3 x − 9) (3 + 3 x )(3 x − 3) 3x − 3 3x − 3 3 2 x − 9. Masilamani Street.3 x − 9 + 3 2 x 9 − 32x Case II: ≤0 3 2 x + 83 x − 9 (3 + 3 x )(3 − 3 x ) 3 − 3x ≤0 ≤0 3 2 x + 9 .3 x 9 − 32 x ≤1 Case I: 8 . Head Office: 12.3 x / 9 1− 32x 9 ≤1 −1 ≤ 8 . ∞ ) (D) f ( x) = ( x) 3 / 2 (3 x − 10). T. ∞) (C) f (θ) = 1(1 + tan 2 θ) + tan θ(0) + 1(1 + tan 2 θ) = 2 sec 2 θ ≥2 So solution is [2. New Delhi-110 016 Ph. x ≥ 0 f ( x) = 3. ∞) Brilliant Tutorials Pvt.: 2653 7392/93/94/95 Fax: 2653 7396 ® .3 x − 3 x − 9 (3 x − 1)(3 x + 9) 3 − 3x ≤0 …(ii) x ∈ ( −∞. − 1] ∪ [1. 1) ∪ [ 2.x 5 / 2 − 10 x 3 / 2 f ' ( x) = 3 × 5 3/ 2 3 15 3 / 2 30 1 / 2 x − 10 × x 1 / 2 = x − x 2 2 2 2 Since f ( x) is an increasing function f ' ( x) ≥ 0 ⇒ 15 x ( x − 2) ≥ 0 ⇒ ( x − 2) ≥ 0 ⇒ x ≥ 2 2 x ∈ [2. Ltd. Kalu Sarai (Behind Azad Apartments).® IIT−JEE 2011 SOLUTIONS 2i 2i = Re = Re = − cosec θ z−z − 2i sin θ Real part ∈ (−∞. ∞) So common solution is x ∈ (−∞.

Nagar.( ˆ ˆ) = ( ˆ ˆ) ( ˆ ˆ) cos θ (ˆ j + 3k j − 3k j + 3k j − 3k cos θ = − b r b 1 2π ⇒ θ= 2 3 b2 − a2 ⇒ f ( x) = x 2 (B) ∫ a f ( x)dx = π π f = 6 6 (C) Let x = t + 1 ⇒ 1/ 6 π2 ln 3 −1 / 6 1/ 6 ∫ sec(π + π t )dt 1/ 6 0 = 2π 2 = ln 3 (D) ∫ sec πt dt = ln 3 | ln(sec πt + tan πt ) | 0 2π π Let z = e iθ ⇒ 1 − z = 1 − cos θ − i sin θ = 2 sin θ θ θ sin − i cos 2 2 2 sin ⇒ 1 = 1− z 1 = θ θ θ 2 sin sin − i cos 2 2 2 θ θ + i cos 2 2 θ 2 sin 2 = θ 1 i + cot 2 2 2 ∴ ⇒ 1 1 lies on x = 1− z 2 π θ 1 as cot → ± ∞ . (D) – (t). then the If a = ˆ j + 3k j + 3k = 2 3k r r internal angle of the triangle between a and b is Column II (p) (A) π 6 2π 3 (B) If ∫ ( f ( x) − 3x) dx = a a 5/ 6 7/6 b 2 π − b 2 . New Delhi-110 016 Ph. Masilamani Street. Ltd. then the value of f is 6 (q) (C) π2 The value of ln 3 ∫ sec(πx) dx is (r) π 3 π π 2 *(D) ® (t) 1 The maximum value of Arg for | z | = 1. arg tends towards 2 2 − 1 z Brilliant Tutorials Pvt. Column I r r r ˆ. z ≠ 1 is given by 1− z (s) Sol. 47 Match the statements given in Column –I with the values in Column-II. Kalu Sarai (Behind Azad Apartments).: (A) – (q). Head Office: 12. T. (B) – (p).: 2653 7392/93/94/95 Fax: 2653 7396 .® IIT−JEE 2011 SOLUTIONS 60. (C) – (s). b = − ˆ ˆ and c ˆ form a triangle. Chennai-600 017 Delhi Office: 50-C. r r r (A) As a + b = c r r So angle between a and b is r a θ r c ˆ).

Masilamani Street. Nagar. Head Office: 12. T.: 2653 7392/93/94/95 Fax: 2653 7396 ® .® IIT−JEE 2011 SOLUTIONS 48 BREAK UP 1 (LEVEL OF DIFFICULTY) CHEMISTRY PAPER 1 DIFFICULT 24% MODERATE 36% EASY 40% CHEMISTRY PAPER 2 DIFFICULT 28% EASY 24% MODERATE 48% CHEMISTRY COMBINED DIFFICULT 26% MODERATE 42% EASY 32% Brilliant Tutorials Pvt. Ltd. Chennai-600 017 Delhi Office: 50-C. Kalu Sarai (Behind Azad Apartments). New Delhi-110 016 Ph.

Ltd.: 2653 7392/93/94/95 Fax: 2653 7396 ® . Nagar. Chennai-600 017 Delhi Office: 50-C. Masilamani Street. Kalu Sarai (Behind Azad Apartments).® IIT−JEE 2011 SOLUTIONS 49 BREAK UP 1 (LEVEL OF DIFFICULTY) PHYSICS PAPER 1 DIFFICULT 15% MODERATE 34% EASY 51% PHYSICS PAPER 2 DIFFICULT 10% EASY 51% MODERATE 39% PHYSICS COMBINED DIFFICULT 13% MODERATE 37% EASY 50% Brilliant Tutorials Pvt. New Delhi-110 016 Ph. T. Head Office: 12.

Nagar. Head Office: 12.: 2653 7392/93/94/95 Fax: 2653 7396 ® .® IIT−JEE 2011 SOLUTIONS 50 BREAK UP 1 (LEVEL OF DIFFICULTY) MATHEMATICS PAPER 1 DIFFICULT 5% MODERATE 62% EASY 33% DIFFICULT 5% MATHEMATICS PAPER 2 MODERATE 52% EASY 43% MATHEMATICS COMBINED DIFFICULT 5% EASY 38% MODERATE 57% Brilliant Tutorials Pvt. Chennai-600 017 Delhi Office: 50-C. T. Kalu Sarai (Behind Azad Apartments). Ltd. New Delhi-110 016 Ph. Masilamani Street.

T. Masilamani Street. Kalu Sarai (Behind Azad Apartments). Head Office: 12. Nagar.: 2653 7392/93/94/95 Fax: 2653 7396 ® .® IIT−JEE 2011 SOLUTIONS 51 BREAK UP 2 (XI-XII) CHEMISTRY PAPER 1 XII 59% XI 41% CHEMISTRY PAPER 2 XI 29% XII 71% CHEMISTRY COMBINED XII 65% XI 35% Brilliant Tutorials Pvt. New Delhi-110 016 Ph. Chennai-600 017 Delhi Office: 50-C. Ltd.

Nagar. Masilamani Street.: 2653 7392/93/94/95 Fax: 2653 7396 ® .® IIT−JEE 2011 SOLUTIONS 52 BREAK UP 2 (XI-XII) PHYSICS PAPER 1 XII 48% XI 52% PHYSICS PAPER 2 XII 42% XI 58% PHYSICS COMBINED XII 45% XI 55% Brilliant Tutorials Pvt. Head Office: 12. Kalu Sarai (Behind Azad Apartments). New Delhi-110 016 Ph. Chennai-600 017 Delhi Office: 50-C. T. Ltd.

®

IIT−JEE 2011 SOLUTIONS

53

BREAK UP 2 ( XI-XII)

MATHEMATICS PAPER 1

XII 55%

XI 45%

MATHEMATICS PAPER 2

XI 38%

XII 62%

MATHEMATICS COMBINED

XII 58%

XI 42%

Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017 Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

®

®

IIT−JEE 2011 SOLUTIONS

54

**BREAK UP 3 (TOPICWISE/PARTWISE)
**

CHEMISTRY PAPER 1

INORGANIC 37%

PHYSICAL 33% ORGANIC 30%

CHEMISTRY PAPER 2

INORGANIC 27%

PHYSICAL 37%

ORGANIC 36%

CHEMISTRY COMBINED

INORGANIC

32%

PHYSICAL 35%

ORGANIC 33%

Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017 Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

®

®

IIT−JEE 2011 SOLUTIONS

55

**BREAK UP 3 (TOPICWISE/PARTWISE)
**

PHYSICS PAPER 1

OPTICS 0% MODERN PHYSICS 16% ELECTRO‐ MAGNETISM 31%

MECHANICS 35%

HEAT & THERMO‐ DYNAMICS 9%

MODERN PHYSICS 5%

PHYSICS PAPER 2

OPTICS 9%

MECHANICS 31%

ELECTRO‐ MAGNETISM 28%

HEAT & THERMO‐ DYNAMICS 10%

SHM & WAVE MOTION 17%

PHYSICS COMBINED

OPTICS 5% MODERN PHYSICS 11%

MECHANICS 32%

ELECTRO‐ MAGNETISM 29%

HEAT & THERMO‐ DYNAMICS 10%

SHM & WAVE MOTION 13%

Brilliant Tutorials Pvt. Ltd. Head Office: 12, Masilamani Street, T. Nagar, Chennai-600 017 Delhi Office: 50-C, Kalu Sarai (Behind Azad Apartments), New Delhi-110 016 Ph.: 2653 7392/93/94/95 Fax: 2653 7396

®

SHM & WAVE MOTION 9%

®

IIT−JEE 2011 SOLUTIONS

56

**BREAK UP 3 (TOPICWISE/PARTWISE)
**

MATHEMATICS PAPER 1

TRIGONO‐ METRY 14% CO‐ CALCULUS ORDINATE 17% 14%

VECTORS & 3D 9%

ALGEBRA 46%

VECTORS & 3D 8%

MATHEMATICS PAPER 2

®

TRIGONO‐ METRY 3% ALGEBRA 28% CO‐ ORDINATE 20% CALCULUS 41%

TRIGONO‐ METRY 9% VECTORS & 3D 9%

MATHEMATICS COMBINED

CALCULUS 29%

ALGEBRA 36%

CO‐ ORDINATE 17%

**MODEL SOLUTIONS TO IIT JEE 2011
**

Paper I

1 A 8 A, B, D 12 D 17 9 18 5 19 5 2 D 3 A 9 A, D 13 B 4 B 5 D 10 A, C, D 14 B 20 4 15 A 21 6

O C N C O 4. is tetrahedral, [Ni(CN)4] [NiCl4] 2+ planar & [Ni(H2O)6] is octahedral.

2– 2–

6 C

7 C 11 A, B, C

16 C 22 5 23 7

Section I

1.

27 Al + 4 He → 30 P + 1n( Y ) 13 2 15 0

↓

↓

CH2

Br

30 Si + 1H( X ) 30 Si + 0 e( Z ) 14 1 14 1

2.

Since the mobility of K is nearly same as that of + Ag which it replaces, the conductance will remain as more or less constant and will increase only after the end point.

+

is square

O

3.

5.

C NH C O O C NK C O

8.

Br CH2 Cl KOH

**Ba(N3)2 → Ba + 3N2 Very pure N2 is produced by the thermal decomposition of Barium or sodium azide. M=
**

2 × 1.15 × 1000 1120 = 2.05 M

6.

7.

o-hydroxy benzoic acid: pKa = 2.99 p–hydroxy benzoic acid: 4.58 p–toluic acid = 4.34 p–nitrophenol = 7.15

Section II

Adsorption is always exothermic. Chemisorption is more exothermic than physisoprtion and it requires activation energy.

9.

A, D

Section IV

10. Cassiterite contain 0.5 – 10% of metal as SnO2 the rest being impurities of pyrites of Fe, Cu & wulframite. 11. In a, b & c all atoms are in the same plane.

17. Maximum no. of electron with n = 3 is 18, of which are having −1 spin 2

18. 3Na2CO3 + 3Br2 → 5NaBr + NaBrO3 + 3CO2 19.

Section III

H3C H3C C H3C H 3C H3C C

H3C

12.

C (P)

C O OH

CH

dil.H2SO4 HgSO 4

**Br CH3 CH 2 C CH2 CH 2 CH3
**

alc.KOH

CH3

(i) NaBH4 (ii) dil.acid

H 3C H3C C H3C

CH3 CH

C

CH 2

CH2

CH3 (2 isomers)

C H OH C H

CH 3 (Q)

CH3 CH2

H+ (-H2 O)

C

CH

CH2

CH3 (2 isomers)

H3C C 13. H3C H3C

CH3

CH3 CH2

C

CH2

CH 2

CH3 (1 isomer)

H 3C H3C C H3C

C H (2°) CH3

CH3

1, 2-shift of -CH3

20. hυ = CH3

-H

+

6.626 × 10−34 × 3 × 108 300 × 10 −9 × 1.6 × 10 −19 = 4.14 eV

H3C C H 3C

CH3 CH3 C

C H

C

CH3 ozonolysis CH3

O 2 H 3C C CH3

E = hυ – hυ0 For Li, Na, K and Mg hυ0 values are less than 4.14 eV 21. Let the number of glycine units be x Total mass of the hydrolysed products = 796 + 9 × 18 = 958 75 x × 100 % by mass of glycine = = 47 958 ∴x=6

− 22. S4O2 6 has sulphur atoms with oxidation states

14. 2AgNO3 + Cu → Cu(NO3)2 +

1 Ag 2

The metal dipped is Cu. 2+ Blue colour due to formation of Cu 15. The solution in which the metal is dipped in AgNO3. 16. The deep blue colour due to formation of 2+ [Cu(NH3)4] and the white precipitate of AgCl + dissolve due to formation of [Ag(NH3)2]

‘0’ & +5. 23. Vol. of 0.1 mole at 0.32 atm = 2.24 =7L 0.32

PART II 24 D 31 B, D 25 D 26 D 32 A, B, C, D 35 C 40 3 41 5 42 6 36 B 27 A 28 A 33 A, B, C, D 37 D 43 3 38 C 44 9 39 B 45 4 46 1 29 A 30 B 34 A

Section I

24. x component of area vector is a2 2 ∴φ = E 0a 2 2

2

1 1 1 = Z2R − 2 2 λ2 4 2 5 36 λ2 = λ1 × × 22 3 16

0

25. T sinθ = mω Lsinθ ω=

324 0 .5 × 0 .5

T L θ

= 1215 A

30. X 52 + 1 = 10 48 + 2

= 36

mg

**26. Position (1): Let charge on 2 µF be Q. Then energy =
**

Q2 µJ 4 Q2 µJ 20

proton

Section II

31.

electron •B

**Position (2): Ceq = 10 µF Total charge = Q. ∴ Energy = Loss % = 80% 27. n =
**

1 (Θ 22.4 λ = 1 mole) 4 1 3 W = nCV∆T = × R.∆T 4 2 1 1 T1V1γ − = T2V2γ − ⇒ T2 = 4T1 ∴ ∆T = 3T1 f v × 28. f’ = 1 + 0 vs c 1− c 8 × (320 + 10 ) = 320 − 10

T=

2πm , different for them. qB

32.

**dQ is same for A and E and both are maximum. dt λ Thermal resistances are as below. KA
**

RB RC RA RD RE

29.

1 1 1 = R 2 − 2 λ1 3 2

1 4 1 4 , RB = , RC = , RD = 8 3 2 5 1 . So C is also correct. RE = 24 RA =

1 . 4 D also correct Θ RB parallel RD is equal RC Note: It is assumed that there is no radiation loss.

(Θ Eq.R (RC, RB, RD) is

q2 ⇒a= r ⇒N=3

1/ 3

4+ 2 16 πε0

33. On interconnecting V same Q Q ⇒ A = B ∴ (B) correct. R A RB V=

**σR is standard formula ε0
**

V V , EB = RA RB

**41. Fd = mg sinθ − µmg cosθ Fu = mg sinθ + µmg cosθ Fu = 3Fd 1 ⇒µ= 2 1 ∴ N = 10 µ = 10 × = 5 2 42.
**

L x x x x x x x x B −−−−−−−−−−

∴ (C) correct

V same ⇒ EA =

∴ (D) correct.

34. Under case (B) eventhough the disc is free to rotate, it will not rotate. ∴ Cases (A) and (B) are identical in all respects. µ0 Ι L

B=

Section III

e2 3 35. [N] = L− = Force × area ε0

36. Find ω by the given formula c λ= ω 2π 37. As ball goes up, x is positive and increasing, v is positive and decreasing. Symmetrical for ball coming down.

**µ0 πr 2gΙ L dφ E 2 − = E, i = ; M = iπr dt R ⇒N=6
**

φcoil = Bπr =

2

43. ∆λ =

38. At x = 0, E = K.E =

p2 2m

MgL AY L’ = L + ∆λ L' Mg ⇒ = 1 + L AY L'−L α= (L × 40 − L'×30 ) Mg = Mg AY 40 − 1 + 30 AY Solving, we get M ≅ 3 kg

∴ E varies as p ∴ E1 = 4E2

2

2 2 4 44. N × 10− = 2 mr 2 + md2 + 2 mr 2 ; 5 5 Here d = r= 4 2 2 2 × 10− = 2 2 × 10− m 2

39. Starting from positive positions (i.e. in air), amplitude in air will be more than amplitude in water. Momentum is negative for downward journey. Also water produces damping. ⇒ graph is spiralling in.

5 1 2 × 10− m; m = kg 2 2 ⇒N=9

Section IV

40. U = q2 2 4 + 2 + 2a r 4πε0a dU =0 da

45.

a = 0.3 α 2N

[

]

f2 f1

For equilibrium,

f2 = 0.2 = 0.4.4 10 .8 ⇒ µ. A0 = |−λN0| = 10 ∴ N0 = s− 1 1010 λ 10 9 19 = 10 × 10 = 10 .3 = .α= f1R − f2R 2 mR f1 − f2 2 − f1 ⇒ = a = 0 .8 ⇒ µ = 0.m=2 m m ⇒ f1 = 1.α= a R ∴ M = mN0 = 10− × 10 kg 25 19 6 = 10− × 10 × 10 mg = 1 mg 25 19 46.

A=C Projection of 3i − j + 3k on C 3 + 1− 3 1 = = 3 3 48.D 61 A 67 1 = 52 D 53 C 57 B.C 54 QUESTION INCORRECT 58 B 63 7 64 9 62 B 68 2 (b − 1)3 1 + 3 3 1 1 69 5 Section I ρ 47. 2(b − 1)3 1 1 + = 3 3 4 1 ⇒b= satisfies the above equation. t = ln2 ln 3 . t = ln3 ln 3 x 0 b 1 x= ⇒I= b ∫ R1 = ( x − 1) 2 ∫ (x − 1) dx = 0 b 3 3 = 1 2 ln 2 ln 3 t sin t 1 × dt sin t + sin(ln 6 − t ) 2 t ∫ ln 2 sin t dt sin t + sin (ln 6 − t ) 0 . y Let I = Set x = t 1 dx = dt 2 t x= ∫ ln 2 x sin x 2 sin x 2 + sin (ln 6 − x 2 ) dx ln 2 . v = 0 1 1 A 1 1 −1 1 = 0 B C 0 2 −1 1 = 0 B C ( x − 1)3 R2 = ( x − 1) dx = 3 b b ∫ 2 R1 − R2 = 1 gives = 0 − 4 3 (b − 1) 3 2 ⇒ 1 A ⇒ 2 (− C − B) + 2 (B + A) = 0 ⇒A=C For the vector in (C).PART III 47 C 48 B 49 B 55 B. Let v = Ai + B j + C k a×b. y + 2 = m (x – 3) and m = y+2= y3 3 (x – 3) ( ) 3 x+2+3 3 =0 ln 3 50. 2 49.D 59 D 65 8 60 D 66 6 50 A 51 C 56 A.

“ Let M and N be two nonsingular skewsymmetric matrices…………” The solution is 2 2 -1 -1 -1 T M N (M N) (MN ) 2 2 -1 -1 T T = M N (-MN) (N ) M 2 2 -1 -1 -1 T -1 = M N (-N M ) (N ) (-M) 2 2 -1 -1 -1 = M N N M (-N) M 2 2 -1 -1 -1 2 -1 -1 =-M N N M N M=-M NM N M 2 -1 = .0) 2 x2 a 2 2I = = 1 2 ln 3 ∫ dt ln 2 1 3 log 2 2 1 I = log 3 2 4 51. 0) ( 3. . Its inverse does not exist. k − j coplanar with the given vectors 1 −1 0 1 0 0 and ± 1 1 2 = ± 1 1 3 ≠ 0 1 2 1 0 1 −1 = α8 (α 2 − 2) − β8 (β2 − 2) 2(α9 − β9 ) α8 .6α − β8 6β 2 α9 − β9 6(α9 − β9 ) 2(α9 − β9 ) (A) and (D) true.M N (N M) M 2 -1 = . For e= π 52. 57.0). P = θ : sin θ − = cos θ 4 3π ⇒P = θ : cos θ = cos − θ 4 3π ∴ P = θ : θ = 2nπ ± − θ 4 3π = θ : θ = nπ + 8 π π Q = θ : θ − = 2nπ ± − θ 4 2 3π = θ : θ = nπ + 8 ∴P=Q a10 − 2a8 2a9 ∴ for ⇒ − y2 b2 = 1. log x log 2 = log y log 3 ⇒ log x = k log 2 ⇒ x = 2 k log y = k log 3 ⇒ y = 3 k (2 )log 2 = (3 )log 3 k +1 k +1 k +1 2log 2 ⇒ k +1 = 3log 3 ⇒ ( k +1) (log2) = (k+1) (log 3) k = −1 1 ⇒ x0 = 2− = 12 2 2 55. j − k = i + j + k (i + j + 2k) & k − j = i + j +2k (i + 2j +k) ∴ j − k. Therefore there is NO SOLUTION TO THIS QUESTION.= 1 2 ln 3 ∫ sin(ln 6 − t ) dt sin (ln 6 − t ) + sin t But if The question is reframed in the following manner. = α10 − β10 − 2 α 8 − β8 2α −β ( 9 ( 9 ) ) 56. f (x +y) = f (x) +f(y) ⇒ f(x) = kx f(x) is continuous ∀ x ∈R and f’ (x) = k = ( ) = =3 Section II 54.M N(M N) M 2 -1 -1 =-M NN M M 2 =-M Choice (c) x 2 y2 + =1 4 1 3 and focus = (± 3 . b = 1 x2 − y2 = 1 3 2 ∴ required hyperbola is 53. a 2 = 3. Skew symmetric matrix of order 3 is singular. e = 2 3 b a 2 2 = 1 3 Substitution Focus (2.

x − 1 = 0 and Im(ω) > 0 ⇒ ω = − 3 1 3 +i 2 2 a = 2 ⇒ 2 + 8b + 7c = 0 14 + 7b + 7c = 0 (taking first and third columns) Solving we get b = 12 and c = − 14 3 1 3 ∴ The equation in 2 + 12 + −14 ω ω ω 2 = 3ω + 1 + 3ω 2 = 3 (ω + ω ) + 1 = − 2 Correct choice (a) 62. Probability 1 3 2 1 3 1 1 3 2 = × 1+ × + × 1+ × + × 2 5 5 2 10 10 3 5 3 = 1 3 1 3 1 2 + + + + 2 5 5 10 30 5 1 46 23 = × = 2 30 30 1 3 1 2 5 ×1+ 5 × 2 2 59.Section III For problems (58) and (59) 3 5 1 ∞ n =0 a + 48 + 7c = 0 a+6+c=0 Solving a = 1 and c = . Taking 1 and 3 columns we get st rd 5n [6 + (5n − 1) (a2 − 3)] sm 64. θ = n 1 1 1 = + sin θ sin 2θ sin 3θ 1 1 1 − = sin θ sin 3θ sin 2θ sin 3θ − sin θ 1 = sin θ sin 3θ sin 2θ 2 cos 2θ 1 = sin 3θ sin 2θ ⇒ 2 sin2θ cos2θ = sin3θ sin4θ −sin3θ = 0 7θ θ ⇒ 2 cos sin = 0 2 2 7π π ⇒ 2 cos sin =0 2n 2n 7π π = (2k + 1) 2n 2 7 2k + 1 For positive integral values of n k = 0 or 3 put k = 0. n = 7 ⇒n= 1R+1W 3 5 58. 7(a + b+ c) = 0 . b = 6. b + c = −1 ∴ 7a + b + c = 7 − 1 = 6 61. 2 ∴ The equation is x + 6x – 7 = 0 1 1 α+β 6 ∴ + = = <1 α β αβ 7 W 1 2 H ∑ α + β a = 1− r 1 1 n (is an infinite geometric progression) = 1 1− 6 7 =7 R 2 5 1 2 T 1 2 2W 1 10 2R 1 3 10 2 3 1 3 Section IV π 63. a2 = 9 . Probability = 23 30 12 = 23 60.7. 9 − a2 + a2 − 3 9 − a2 + 2 (a2 − 3 ) is independent of n 4a2 − 6 9a2 − 21 = 6 a2 + 3 (2a2 − 3) (a2 + 3) = (3a2 − 7) 2a2 2 − 24a2 + 54 = 0 a2 2 − 12a2 + 27 = 0 a2 ≠ 3. ⇒ a + b + c = 0 also 2a + b + c = 1 ⇒ a = 1. = 2 n sn [6 + (n − 1) (a2 − 3) 2 9 − a2 + 5n (a2 − 3) =5 9 − a2 + n (a2 − 3 ) ∴ 9 − a2 + 5 (a2 − 3) (9 − a2 ) + 10(a2 − 3 ) = . m = 5n.

of tangent at (2. F = − dx x 2 1 (4+4) (−4 −2) (2 −4) = 6 8 . of tangent at .2 Eqn. −1) 1 −2 0 1 ∆2 = 1 1 3 = −3 = 3 2 1 −1 −1 ∴ ∆1 6 = =2 ∆2 3 67. 3. Extremum point of latus rectum are (2.2 cos 2θ = cos 2θ cos 2θ + sin θ cos 2θ 2 = sin θ cos θ − sin2 θ + sin2 θ 2 −5 2 5 minimum of 2 z − 3 + i 2 3.3) and of (2) and (3) is (−1.4) is y = x +2 _______(1) Eqn.2 2 ∆1 = = 1 (y1 −y2) (y2−y3) (y3−y1) 8a 66. 6 f ( t )dt = 3x f(x) – x 1 ∫ x 6f(x) = 3xf’(x) + 3f(x) – 3x 2 f(x) = xf’(x) – x dy y= x − x2 dx dy dy y x − y = x2 ⇒ − =x dx dx x 1 I. f(θ) = sin tan -1 = tan tan−1 1 + tan2 (tan sin θ sin θ cos 2θ sin θ cos 2θ −1 sin θ 69. of tangent at (2. d(f ( θ)) =1 ⇒ d(tan θ) = tan θ 5 = 2 + 2 − 2 = 5 2 . ( ( ) 3 ) 1 8 =1 68. 0). −4) is −y = x +2 _____(2) 1 Eqn. a −5 + a −4 + a −3 + a −3 + a −3 + 1 + a8 + a10 8 ≥ a−5a− 4 a−3 13 a8a10 ⇒ minimum value of sum = 8. Point of intersection of (1) and (2) is (1.4) and (2.2 is y = 2x +1 _____(3) 2 ∫ e 1 1 = x dx = x + c x x y = x(x + c) = f(x) f(1) = 2 ⇒ 2 = 1 + c ⇒ c = 1 ∴ f(x) = x(x + 1) ⇒ f(2) = 6 ∴ y.65. ∫ Tangent at the extremities of latus rectum intersect directrix at (−2.−4) 1 ∴ Area of triangle so formed with .

693 t1 2 5. q.P = –2. 2+ 2+ Cu & Hg ions belong to group II of qualitative analysis. s. . X–(CH2)4–X is converted to a diamine which can form condensation polymer with adipic acid. t Section I 1.MODEL SOLUTIONS TO IIT JEE 2011 Paper II 1 C 9 C.06 log 4 [Fe2+ ]2 0. D 14 6 19 15 4 PART I 4 5 A D 11 A. s C – r. r. OCH2R Cu +2 is reduced to Cu +1 by CN & SCN – – 4.023 –2 F. In (A). s D – q.57 V = 0. D 13 8 2 D 3 B 10 A. CuS & HgS are insoluble in dilute mineral acids. Haematite is Fe2O3. t B – p. K = 0. Na3[Co(ox)3]. ∆Tf = i × Kf × m 7. & Aromatic primary amines form diazonium salt with NaNO2 and HCl at low temperature which couples with β–naphthol to form coloured azo dye. r A – p. r. PO2 × [H+ ]4 0. s C–t D – p. In (B). D 8 B 17 18 6 8 20 A – r. The structure given is that of β–D–glucose. X−(CH2)4–X is converted to a diol which gives polyester. s B – r.67 + 0. Oxidation state of Fe is +2 and +3. B. B. Ecell = E0 cell + = 4 × 1.015 × 7 = 1. Section II 3.1 × (10 −3 )4 (10 −3 )2 6.015 log = 1.86 × 0. 11.3 × 10 ° C 8.67 – 0. [Co(NH3)6]Cl3. 10. C. [K2Pt(CN)4] [Zn(H2O)6](NO3)2 are diamagnetic. D 16 7 6 C 7 A 12 A. (C) and (D). 2. C. 1 × 10 329 = 1. RCH2OH H+ O O 9. Oxidation state of Fe is +3 Magnetite is Fe3O4.

PCl5 + SO2 → POCl3 + SOCl2 PCl5 + H2O → POCl3 + 2HCl PCl5 + H2SO4 → SO2Cl2 + 2POCl3 + 2HCl 6PCl5 + P4O10 → 10POCl3 16. (36 edges and 24 vertices) 14.6 0 . (C) involves association (D) white phosphorous is converted to the polymeric red allotropic form as heating.6 Vol. A truncated octahedrous has 8 hexagonal and 6 square faces. ClCH2 CH2 C H CH2 CH3 (2 isomers) CH3 H 2+ CH 3 C H CH2 12.01 × 2 = 0. [Cl ] from CuCl = 10− + – Ksp(AgCl) = [Ag ] [Cl ] – 3 (2 different chiral carbon . (C) involves nucleophilic addition and dehydration.6 × 10 −10 10 −3 – = 1. 20.1 M AgNO3 = = 6 mL 0 .3 0 .4 2 R = R0e -kt CH3 18. 15.4 isomers) CH3 CH3 (1 isomer) CH3 CH2 C CH2 Cl CH2Cl CH3 CH2 C H CH2 CH3 (1 isomer) Section IV 19. (A) is intramolecular aldol condensation (B) involves Grignard reagent addition. t1 100 = 8t 1 t = 2 log 0 . Millimoles of Cl = 30 × 0.K increases with increase of temperature and hence half life decreases. (B) is exothermic and a gaseous product is formed from a solid. To carbonyl compound. (A) involves transition from solid to gas phase with the absorption of heat.1 . Different solids are considered as different phases. [Ag ] = + 1. There are six C – H bonds that can involve in hyperconjugation. of 0. MnO4− → Mn (acid medium) MnO4− → MnO2 (Neutral and aqueous mediums) CH3 C Cl Section III 13.6 × 10 –7 17. (D) involves dehydration and intramolecular Friedel–Craft reaction.

01 V’ + 0. Take dr at r No. t B – p. r C – q. Θ At θ = 0.01 mm diameter = 2. of turns = ∴ V’ = 100. s D – r. D 36 5 26 D 27 C 32 28 A A.70 24. B. Section IΙ 29. L.C = 0.01 V = 0. V’’ = 20 ∴ V = 500 27. 100% reflected.PART II 21 B 22 B 29 B. If non-conservative induced electric field this pattern is possible. s D – q. R ZA A XC N. t B – p. D 37 4 40 38 4 35 5 A – p. (B or C) But C is correct.70 ∆ρ 3∆dia ∆m = + ρ dia m 3 % error = + 2 = 3. 28. C 33 2 23 C 30 A. (b − a ) 2r µ N. 0. r Section I 21.1% 2. Phasor: A Resultant π/3 A ∴ Required 25. t −dB = B= ∫ µ0N i dr. R≠0 26.dr (b − a) . kx0 = QE ∴ Equilibrium shifted. Escape KE = and V = GMm r 24 A 25 C 31 C. T + R = 100.i b dB = 0 ln 2(b − a ) a GM r Eliminate r 22. K At equilibrium position. T = 2π m holds.70 mm 1 % error = 2. At θc. s C – q.2 V’’ But time of fall = 2h =1 g 4π A sin ωt + 3 23. r. C 34 7 39 A – p.

1 surface µ µ µ − µ1 − 1+ 2 = 2 u v R 7 7 − 1 1 4 4 − + = (− 24 ) V1 6 st 30.7 = 1. ω of ring increases after collision ⇒ slip ⇒ friction towards left.21 − 4.18 kg. for conservation of angular momentum. Knowledge based.25 R ⇒ XC = 0.5 R × 500 250 R ⇒v= 1 τ = RC = KE = 6.15 2 1 (u = 10 m s− ) 2 ⇒ a = 5 m s− (u cosθ) T = 36.5 V for stopping electrons.06 m 2 ⇒ v = 0.21 eV 200nm 0. hυ = 1242 eV nm = 6. r 1 s = 4 ms 250 Section IV 39.5 × 10 −2 9 × 10 7 ( ) = Ne 9 ∴ N = 1 × 10 40. ∴q= 1.16 Section IΙΙ 4 4 7 7 − −1 1 3 3 4 4 33.25 R − R 2 = 0. Linear momentum in the horizontal direction is zero before and after collision ⇒ CM is stationary.51 eV kq = 1. Z = R + XC 2 2 2 ⇒ XC = 1. 2 g = 10 m s− . T = XB C 2u sin 60° 2 × 10 × 3 = = 3 s g 10 × 2 1 A < XC Cω ⇒ ZB < ZA XB C = A A B ⇒ ΙB R > ΙR and VC > VC 1 2 aT + 1. − = + v − 24 6 ∞ ⇒ v = 16 from top surface of liquid ⇒ 2 cm from bottom surface of liquid 34. µ = 0.04 = 0.5 R 1 1 1 ⇒C= = = XCω 0.1. 32. S = 0. 31. Knowledge based. VdA + VdB = 2VdF = 0 ∴ dA + dB = 2dF Obviously dA < dF and dB > dF ⇒ v1 = 21 cm nd 2 surface nd (Θ R = ∞ for 2 surface) 7 4 4 − + =0 21 3 v 2 ⇒ v2 = 16 cm ⇒ x = 18 − 16 = 2 cm 1 1 2 2 mv = µmg S + kS 2 2 m = 0. +q1 (or −q1) d • E=0 +q2 (−q2) W agent = ∆U = q(V2 − V1) = 1 × (VB − VA) = (VB − VA) 37. .16 = 0.R ZB 35.12 + 0.4 m s− 4 = ⇒N=4 10 2 2 2 38.

0) 9a = a2 + b2 (1) sec θ a sec θ = 6 6 sec θ = a (1) reduces 43. B. D 55 3 56 1 57 2 60 58 9 A–q B– p C–s D–s = f(sin(sin(x ) 2 2 = sin (sin(x ) 2 gogof(x) = gog(x ) 2 = g(sin(x) 2 = sin(sin (x )) 2 2 2 ∴ sin (sin(x ) = sin sin (x ) 2 2 ⇒ sin(sin(x ) (sin sin(x ) −1) = 0 2 2 ⇒ sin(sin(x ) = 0 or sin (sin(x ) = 1 2 2 ⇒ sin(x ) = 0 sin (x ) 2 ⇒ x = nπ ∴x=± nπ n = {0.acω ≠ 0 (1 .aω .cω) ≠ 0 1 1 2 2 ⇒a≠ =ω and c ≠ =ω ω ω 2 ∴ a = c =ω and b = ω pr ω Hence there are two such matrices. r. Let the point be ‘θ’ Normal at θ is ax by + = a2 + b2 sec θ tan θ Normal passes thro (9. g = 2 2 2 Circles is x + y + 5x − 4y + 4 = 0 (−4. 2 ……. B. Let α denote the common root 2 α + bα − 1 = 0 2 α +α+b=0 bα − 1 = α + b α (b − 1) = b + 1 b +1 α= b −1 2 2 2 (b + 1) + b(b − 1) − (b − 1) = 0 2 4b + b(b − 1) = 0 2 4+b =0 2 b =−3 b=±I 3 44 A 45 46 B C 51 A. 0) → − 2g + c = −1(1) Passes thro (0. 45. s B – r.cω .PART III 41 B 49 A.cω) (1 . C. Let the circle be 2 2 x + y + 2gx + 2fy + c = Passed thro (−1.} 2 1 44. t C–r D–r Section I 41. 0) satisfies the equation 2 ⇒ 1 . 1. D 54 2 59 A – p.. fogogo f(x) 2 = fogog(x ) 2 = fog(sin(x) . 2) →4f + c = − 4→(2) g2 + f 2 − c = g f −c=0 2 f =c 2 4f + f = − 4 2 (f + 2) = 0 ⇒ f = −2 ⇒ c = − 4 − 4f = 4 5 2g = 5. for non-singular matrics. D 47 48 D C 52 A. ω ϖ2 2 a b 1 c ≠0 ω 1 42. D 53 9 42 D 43 A 50 C.

2t) 2 = a + a (e − 1) 3 2 =1+e −1 2 2 =e e= P 0 (0. Which is of the form 1α ex →0 = e = lim ( f ( x )−1) g( x ) (1+ x log(1+ b 2 )−1) 1 x E∩P x log(1+ b 2 ) x e 2 = elog(1+b 2 ) 2 ∴ 1 + b = 2b sin θ 1+ b sin θ = 2b 2 2 Since b > 0 π ∴θ=± 2 f (x) = f(x) (1 − bx )(−1) + (b − x )b f’(x) = (1 − bx )2 .9a× a 2 2 =a +b 6 48. A 3a 2 2 =a +b 2 2 2 2 2 (t . Let y = b−x 1 − bx ⇒ (1 – bx) y = b – x ⇒x(1 – by) = b – y b−y ⇒ x= 1 − by -1 ( ) ( 2 25 ) ( ) ∫ (1− x) f (1 − x) dx 1 P(E∪F) = P(E ∩ F ) + P(F ∩ E ) + P(E ∩ F) = −1 ∫ (1 − x) f ( x) dx −1 2 −1 ∫ 2 f ( x ) dx − ∫ 2 E E∩F F∩E F xf ( x ) dx = R2 − R1 2R1 = R2 47. y OP 1 = PA 3 Let P be (x. 0 3 2 46. y) X= 1 2 x= −1 0 1 2 x t2 2t .Y= 4 4 Lows of P is 2 4X = 4Y 2 ⇒Y =X Section II f(x) = f(1 −x) 1 ⇒ curve is symmetrical about x = 2 R1 = 2 49. P E ∩ F + P F ∩ E = Also P E ∩ F = ( ) ( ) ∫ xf ( x ) dx 1 2 ( ) 11 25 = 2 ∫ (−1 + 2 − x) f (−1 + 2 − x) dx 1 But P E ∩ F = P E ∩ F = P E ∪ F 2 23 ∴ P(E∩F) = 1 − = 25 25 2 23 P(E∪F) = 1 − = 25 25 (refer figure) 23 11 ∴ = + P(E ∩ F ) 25 25 12 ∴ P(E ∩ F ) = = P(E ) × P(F ) 25 From the options 3 4 P(E) = and P(F) = 5 5 or 4 3 P(E) = and P(F) = 5 5 50.

e y(x) e = e + c y(0) = 0 as g(0) = 0 ⇒ C = 0 g(2) g(2) ∴ y(2) e = e + 0 ⇒ y (2) = 1 57. y = A. M = b1 b2 b3 c c c 3 1 2 0 − 1 M 1 = 2 ⇒ a2 = .1 ⇒ c1 = 2 . Let A = ai + bj + ck P 1=i+j+k P1 = 0 2 2 P2 = i + wj + w k P3 = i + w j + wk 2 P2 = 0 P3 = 0 2 2 Them x = A. Origin lies on the side 2x – 3y . P2 z = A.f’(b) = − 1 − b2 1 = 2 22 b −1 1 − b ( ) ( ) 1 0 M = 1 = 0 ⇒ 2 + 3 + c3 = 12 1 12 ⇒ c3 = 7. b2 = 2. Normal at ‘t’ is 3 y + xt = 2t + t 3 6 + 9t = 2t + t 3 t − 7t − 6 = 0 t = − 1. ∴ The remaining 2 points lie on the smaller intersection. 2 2 ⇒ f(x) is differentiable there. satisfies the inequality 2 4 8 4 2x – 3y – 1 < 0.1. − 6 − 6 6 All points ∈ S lies inside the circle. Let y(x) = n as g (x) = u ∴ The given equation becomes du + udu = udu dy u u ⇒ + u = v ⇒ ue = e +c du g(x) g(x) i. x − 4x + 12x + x − 1 = 0 f(0) < 0. P3 x + y +z a +b +c 2 2 2 2 2 2 2 2 2 2 A P1 + P2 + P3 = 2 A =3+0+0=3 56. f(1) > 0 ∴ one root in (0. 55. And y + 3x = 33 And y − 2x = −12 π− 52. A1 + b 2 + c 3 = 0 + 2 + 7 = 9 54. f − =0 2 −π + −π f = − cos =0 2 2 (A) is true f(x) is continuous at x = 0 f’(0 ) = 0 + f’(0 ) = 1 (B) is true F(x) is continuous at x = 1 f’(1 ) = 1 + f’(1 ) = 1 f(x) is differentiable at x = 1. 22 11 = =1 14 7 −π −3 x= lies in − ∞. 1) 1 3 2 f (x) = 4x − 12x + 24x + 1 11 2 f (x) = 12(x − 2x +2) > 0 1 ⇒ f (x) is increasing 4 3 2 Section III a1 a2 a3 53. t = 3 Normal are Y − x = − 3. since f(x) is a linear function in that interval (D) is true. (c) is true. and .< 0 The smaller intersection Is on 2x – 3y – 1 > 0 6 2x – 3y = 1 f’(0) = − 1 + b2 1 = 1 f ' (b ) 51. P1 . except 5 3 1 1 . c2 = 3 0 3 1 1 M − 1 = 1 ⇒ a1 + 1 = 1 ⇒ a1 = 0 0 − 1 C1 – 3 = . t = − 2.

. 3 1 1 1 y∈ 0. (a) cos θ = ∴θ= π 3 π 2π = 3 3 −1 + 3 1 = 4 2 ∴ required angle is π - (b) ∫ (f ( x) − 3x )dx = a a x 2 − x2 f(x) – 3x = . a = c .a = −4 + m.∴ it has exactly one root ⇒ f(x) may have almost 2 distinct roots Since real roots are even in number f(x) has 2 distinct real roots 58. (a).2x ⇒ f(x) = x π π ∴ f = 6 6 5 π log[sec πx + tan πx ]7 6 = π log 3 6 8 2 ⇒ y ≤ 1− y2 if 1 −y ≥ 0 3 2 3y + 8y − 3 ≤ 0 i. m = 4 r = c + 4b − cos θ − sin θ cos θ = − cos θ − sin θ = 2 cos θ cos θ 3 x2 3 = 2 sec 2 θ ∈ [2. ∴ x ∈ ( − ∞. −1]U[1. (a) Re 1 − z2 = 3 x 2 − 10 x 2 f’(x) = 2i Re 1 − z z 2i = Re z−z 1 = Re (− Ιm z ) 1 = − Im z (b) Put y = 3 8 < y −1 3 ≤ 1 1 − y2 ⇒ 8 xy ≤ 1 − xy 2 3 x -1 15 2 x − 15 x 2 x = 15 x − 1 ≥ 0 2 If x ≥ 2. a + m b . b = c .b + 4 b 2 =1+8=9 ∈ (−∞. 1] 2 3y +ay − y − 3 ≤ 0 1 (3y − 1) (y +3) ≤ 0 y ∈ − 3. ∞) (c) 1 cos3 θ 1 cos3 θ cos θ − sin θ 0 − sin θ sin θ cos θ 0 cos θ cos θ sin θ` 2 cos θ sin θ cos θ (r − c) × b = 0 r = c +mb 0 = r . 0] ∪ [ z. = 3− ≤ 3 3 x≤0 8 2 y ≤ y 2 − 1 if 1− y ≤ 0 3 2 3y − 8y − 3 ≥ 0 2 3y − 9y + y − 3 ≥ 0 (3y +1) (y− 3) ≥ 0 y≥3 x 1 ⇒3 − ≥3 x ≥ 2 (r. 60. ∞) (d) (3x – 10) 5 3 3 Section IV 2iz 59. t) (c) (d) 1 Arg = Arg(z − 1) z − 1 Maximum value = π. ∞ ) r .e y∈ [−1.

please check that all the questions are legible. 12. Darken the appropriate bubble UNDER each digit of your Registration No. C. 2. The question paper consists of 3 parts (Chemistry. In Section IV (Total Marks: 28). calculators. clipboards. 5. slide rules. 3. In all other cases. There are no negative marks in this section. 6. This Question Paper contains having 69 questions. Filling the Right Part of the ORS: 10. is provided separately. log tables. pagers and electronic gadgets are NOT allowed. The answer sheet. On breaking the seals. Write your name and registration number in the space provided on the back page of this booklet. 4. 9. There are no negative marks in this section. Physics and Mathematics). 7. 16. In all other cases. ask for a change of the booklet. cellular phones. DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators. In Section Il (Total Marks: 16). The ORS also has a CODE printed on its Left and Right parts.QUESTIONS AND SOLUTIONS OF IIT-JEE 2011 Date : 11-04-2011 Duration : 3 Hours Max. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. Do not write them anywhere else. B. If the codes do not match. Each part consists of four sections. with a good quality HB pencil. 8. Blank papers. You are allotted 5 minutes specifically for this purpose. 11. Question paper format and Marking Scheme: 13.1 Please read the instructions carefully. No additional sheets will be provided for rough work. for each question you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. for each question you will be awarded 3 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. Registration No. General : 1. INSTRUCTIONS A. Make sure the CODE on the ORS is the same as that on this booklet. The question paper CODE is printed on the right hand top corner of this sheet and on the back page of this booklet. Write your Name. and the name of centre and sign with pen in the boxes provided. Write your Name registration number and sign in the space provided on the back page of this booklet. 15. In Section I (Total Marks: 21). In Section III (Total Marks: 15). for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise. minus one (-1) mark will be awarded. DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET. a machine-gradable Optical Response Sheet (ORS). 14. 17. minus one (-1) mark will be awarded. . Marks : 240 PAPER .

626 × 10–34 Js 1 eV = 1.206 × 10–2 L atm K–1 mol–1 1 F = 96500 C mol–1 h = 6.314 JK–1 mol–1 or 8.022 × 1023 RESONANCE J10411Page # 2 .Useful Data : R = 8.602 × 10–19 J c = 3.0 × 108 m s–1 NA = 6.

Cl– being weak field ligand does not compel for pairing of electrons. complex has square planar gemetry. (A). Extra pure N2 can be obtained by heating (A) NH3 with CuO (C) (NH4)2Cr2O7 Ans. tetrahedral and square planar (B) tetrahedral. Ni+2 + 4Cl– [NiCl4]2– SP 3 [NiCl4]2– = 3d8 confiuration with Nickel in + 2 Oxidation state. are (A) octahedral. 2. Each question has four choices. (B) Sol. So. tetrahedral and octahedral (D) octahedral. complex has tetrahedral geometry Ni+2 + 4Cl– [Ni(CN)4]2– [Ni(CN)4]2– = 3d8 configuration with nickel in + 2 oxidation state. square planar and octahedral Ans.SECTION . square planar and octahedral (C) square planar. (B). (D) (B) NH4NO3 (D) Ba(N3)2 Ba (N3)2 Ba + 3N2 Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl–.I (Total Marks : 21) (Single Correct Answer Type) CHEMISTRY This section contains 7 multiple choice questions. Hence. respectively. Hence. 1. RESONANCE J10411Page # 3 . CN– being strong field ligand with comples for pairing of electrons. CN– and H2O. So. (C) and (D) out of which ONLY ONE is correct. Sol.

3. neutron. positron (C) proton. Dissolving 120 g of urea (mol.05 M (D) 2.22 M Ans.78 M (B) 2. + 4. wt. The molarity of the solution is : (A) 1.CHEMISTRY Ni+2 + 6H2O [NI(H2O)6]+2 [Ni(H2O)6] = 3d8 configuration with nickel in + 2 oxidation state. So. (I) and (ii) as shown. As with 3d8 configuration two d-orbitals are not available for d2sp3 hybridisation. positron. positron. Y and Z respectively are. proton (D) positron.15 g/mL. 60) in 1000 g of water gave a solution of density 1. hybridisation of Ni (II) is sp3d2. Note : With water as ligand Ni (II) forms octahedral complexes. (A) proton. (C) RESONANCE J10411Page # 4 .00 M (C) 2. neutron Ans. Products X. Bombardment of aluminum by -particle leads to its artificial disintegration in two ways. (A) (B) neutron. neutron Sol. proton. As Ni (II) with six co-ordination will have octahedral geometry.

(C) RESONANCE J10411Page # 5 . Mole = 120 =2 60 mass of solution = 1120 g V= 1120 112 = L 1. AgNO3 (aq. (D) (B) Q (C) (R) (D*) (S) Sol. the most acidic is : (A) p-nitrophenol (B) p-hydroxybenzoic acid (C) o-hydroxybenzoic acid (D) p-toluic acid Ans.CHEMISTRY Sol.15 1000 115 M= 2 115 = 2.05 mol/litre 112 5. 6. The plot of conductance () versus the volume of AgNO3 is : (A) (P) Ans. Among the following compounds.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured.

CHEMISTRY Sol. (A) Sol. 7. RESONANCE J10411Page # 6 . The major product of the following reaction is : (A) (B) (C) (D) Ans. Due to intramolecular hydrogen bonding in conjugate base of o-Hydroxybenzoic acid. it is strongest acid.

(C) and (D) out of which ONE or MORE may be correct. Which then floats to the surface. (A. Sol. SnO2 + 2C Sn + 2CO Fe + O2 FeO The correct statement(s) pertiaining to the adsorption of a gas on a solid surface is (are) (A) Adsorption is always exothermic (B) Physisorption may transform into chemisorption at high temperature (C) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature (D) Chemisorption is more exothermic than physisorption. 8. (A) Fact (B) P = MV = M 3RT = M 3MRT (C) Max well distribution (D) Fact RESONANCE J10411Page # 7 . the molecules move in straight lines with constant velocities. Sol. (B). C. (A. D) 10. According to kinetic theory gases (A) collisions are always elastic (B) heavier molecules transfer more momentum to the wall of the container (C) only a small number of molecules have very high velocity (D) between collisions. Sol. D) Important ore of tin is cassiterite (SnO2).CHEMISTRY SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. Ans. Ans. Each question has four choices (A). however it is very slow due to higher energy of activation. (A) H = –ve for adsorption (B) fact (D) chemical bonds are stronger than vander waal’s forces so chemical adsorption is more exothermic. B. which is removed by blowing air through the molten mixture to oxidise FeO. The product often contains traces of Fe. SnO2 is reduced to metal using carbon at 1200 – 1300°C in an electric furnace. B. (A. Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore (C) removal of copper impurity (D) removal of iron impurity Ans. D) 9.

) Solution containing white ppt. (12). (B). Each of these questions has four choices (A). Addition of aqueous NaCl to the blue solution gives a white precipitate O. 13. AgNO3 + NaCl AgCl + NaNO3 (O) (white ppt. Addition of aqueous NH3 dissolves O and gives an intense blue solution. (A) (B) Zn(NO3)2 (C) Al(NO3)3 (D) Pb(NO3)2 14. C) In (B) (B) H–C (D) H2C=C=CH2 and (C) CH2 == C == O all atoms are always in same plane. (13) & (14) Cu(M) + AgNO3 (aqueous colorless solution) Resultant solution (Cu(NO3)2 + AgNO3 (N) (blue solution) Note : Here it is considered that complete AgNO3 is not utilized in the reaction. of AgCl also contains Cu(NO3)2. (C) and (D) out of which ONLY ONE is correct. 12 and 14 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N the solution turns light blue. is (are) (A) (C) H2C=C=O Ans. (B. SECTION – Ill (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs. RESONANCE J10411Page # 8 .CHEMISTRY 11. (B) (B) Cu (C) Ni (D) Co The compound N is : (A) AgNO3 Ans. 12. Based upon one of the paragraphs 3 multiple choice questions and based on the other paragraph 2 multiple choice questions have to be answered. Amongst the given options. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any). Paragraph for Question Nos. The metal rod M is : (A) Fe Ans. (C) (B) [Al(NH3)4]3+ and [Cu(NH3)4]2+ (D) [Ag(NH3)2]+ and [Ni(NH3)6]2+ Sol. The final solution contains (A) [Pb(NH3)4]2+ and [CoCl4]2– (C) [Ag(NH3)2]+ and [Cu(NH3)4]2+ Ans. Sol.

16. (D) The structure of the compound Q is (A) (B) (C) (D) Ans. 15 and 16 An acyclic hydrocarbon P.) [Cu(NH3)4] (NO3)2 (deep blue coloration) So. Metal rod M is Cu. The compound N is AgNO3 and the final solution contains [Ag(NH3)2]+ and [Cu(NH3)42+ Paragraph for Question Nos.) + 4NH3 (aq. gave acetone as the only organic product through the following sequence of reactions. (15 & 16) (B) RESONANCE J10411Page # 9 . in which Q is an intermediate organic compound. having molecular formula C6H10. Sol. 15.) [Ag(NH3)2]+ Cu(NO3)2 (aq. The structure of compound P is (A) CH3CH2CH2CH2–CC–H (B) H3CH2C–CC–CH2CH3 (C) (D) Ans.CHEMISTRY Which developed deep blue colouration with aqueous NH3 solution AgCl (white) + 2NH3 (aq.

9 Sol. 17.IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. 19. Li. Sol.3 Fe 4.4 Na 2. ranging from 0 to 9. The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metal is Metal f (eV) Li 2.2 Mg 3.3 W 4. Mg can show photoectric effect. RESONANCE J10411Page # 10 . The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is Ans.8 Ag 4. 2 So. K. The answer to each of the questions is a single-digit integer. 1 will be 1 + 3 + 5 = 9. 5NaBr + NaBrO3 + CO2 3Br2 + 3Na2CO3 The maximum number of electrons that can have principal quantum number.7 Cu 4.7 Pt 6.CHEMISTRY SECTION . Na. is Ans. The number of sodium bromide molecules involved in the balanced chemical equation is Ans. 5 Sol. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas. 5 Sol. The work function () of some metas is listed below. n = 3. ms = –1/2.13 ev 3000 Photoelectric effect can take place only if Ephoton Thus. and spin quantum number. The bubble corresponding to the correct answer is to be darkened in the ORS. electrons with spin quantum number = – 20. Ephoton = 4 12400 = 4. 18.3 K 2.75 Ans.

The number of glycine units present in the decapeptide is Ans. 7 PHe = 1 – 0.0 % to the total weight of the hydrolysed products.1 0.0821 273 = =7 P 0.1 mol of He and 1. Total 5 products. alanine and phenylalanine. 22.32 Sol..68 = 0. Considering the ideal gas behaviour.32 atm V=? n = 0.1 . Sol. A decapeptide (Mol. Wt. To an evacuated vessel with movable piston under external pressure of 1 atm.CHEMISTRY 21. at 0ºC) are introduced. Glycine contributes 47. 0. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is Ans.68 atm. 6 Molecular weight of decapeptide = 796 g/mol Total bonds to be hydrolysed = (10 – 1) = 9 per molecule Total weight of H2O added = 9 × 18 = 162 g/mol Total weight of hydrolysis product = 796 + 162 = 958 g Total weight % of glycine (given) = 47% Total weight of glycine in product = 958 47 g = 450 g 100 Molecular weight of glycine = 75 g/mol Number of glycine molecule = 450 = 6. V= nRT 0. Wt. the total volume (in litre) of the gases at 0°C is close to Ans. 796) on complete hydrolysis gives glycine (Mol. 75). 75 RESONANCE J10411Page # 11 .0 mol of an unknown compound (vapour pressure 0. 5 Sol. 23.

75 kHz (D) 7. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which reflects the sound waves.I (Total Marks : 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. The frequency of the siren heard by the car driver is (A) 8.51 kHz 8. the work done in the process is : (A) 9 RT1 8 (B) 3 RT1 2 (C) 15 RT1 8 (D) 9 RT1 2 Ans. Number of moles of He = Now 1 4 T1 (5. (C) and (D) out of which ONLY ONE is correct.7 liter.25 kHz (C) 7. (A) Sol.7) – 1 1 T1 = T2 8 2/3 RESONANCE J10411Page # 12 . 8× 8. Sol. (A) (B) 8.6 liter of helium gas at STP is adiabatically compressed to 0. 24. The speed of sound in air is 320 m/s.PHYSICS PART .50 kHz Ans. Taking the initial temperature to be T1.II SECTION . Each question has four choices (A).5 kHz 5.6) – 1 = T2 (0. (B).50 kHz finisident = freflected = 320 × 8 kHz 320 10 fobserved = 330 310 320 10 freflected 320 = = 25.

PHYSICS 4T1 = T2 Work done = – nR[T2 T1 ] 1 1 R [3T1 ] 4 =– 2 3 9 = – RT1 8 26. ˆ . The flux through the shaded area (as shown in Consider an electric field E E 0 x the figure) due to this field is : (A) 2E0a 2 (B) 2 E0a 2 (C) E0a 2 (D) E 0a 2 2 Ans. (C) Sol. flux = (E0 cos 45°) × area) = E0 2 a 2a = E0a2 RESONANCE J10411Page # 13 . where E0 is a constant.

5 18 = 36 rad/sec.5 0.5 = 324 0.5 × 2 2 = 324 0 . 1 1 5 2 1 RZH 4 9 = R(1)2 H2 36 1 1 3 2 1 RZHe = R(4) He 4 16 16 He 1 16 5 5 H2 4 3 36 27 5 × 6561 = 1215 Å 27 He = 28.5 kg is attached to the end of a string having length (L) 0.5 = RESONANCE J10411Page # 14 .PHYSICS 27.5 0 . (A) (B) 1640 Å (C) 2430 Å (D) 4687 Å Sol. T sin = m Lsin2 324 = 0.5 × 0.5 m. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å. The wavelength of the second spectral line in the Balmer series of singly ionized helium atom is : (A) 1215 Å Ans. The ball is rotated on a horizontal circular path about vertical axis. The maximum possible value of angular velocity of ball (in radian/s) is : (A) 9 Ans. A ball of mass (m) 0. 0 . (D) (B) 18 (C) 27 (D) 36 Sol. The maximum tension that the string can bear is 324 N.

(D) Sol. Vcommon = 5 2 Uf = V 1 (2 + 8) 2 5 2 V2 V2 Ui Uf 5 100 100 = Ui V2 4 100 = 80% Ans.8 ohm (D) 11. Ui = V 1 (2)V 2 . A meter bridge is set-up as shown.6 30. The percentage of its stored energy dissipated after the switch S is turned to position 2 is (A) 0% (B) 20% (C) 75% (D) 80% Ans.MATHEMATICS 29. A 2F capacitor is charged as shown in figure. The galvanometer shows null point when tapping-key is at 52 cm mark. (B) Sol. 5 RESONANCE J10411Page # 15 . The determined value of ‘X’ is (A) 10.2 ohm Ans. The end-corrections are 1 cm and 2 cm respectively for the ends A and B.1 ohm 1 x 53 x 2 R 50 10 x = 10. 1 = 52 + 1 = 53 cm 2 = 48 + 2 = 50 cm (B) 10.6 ohm (C) 10. to determine an unknown resistance ‘X’ using a standard 10 ohm resistor.

QA + QB = 2Q . (A).(ii) KQ A KQB RA RB RA (i) and (ii) QA = QB R B RA QB 1 R B = 2Q 2Q R B = R R RA A B 1 R B 2Q & QB = & 2Q RA QA = R R A B RB A Q A / 4R 2 A = 2 RA B QB / 4RB A EA = 0 EA < EB QA > QB using (ii) B & EB = 0 (at surface) A < B RESONANCE J10411Page # 16 .. Then (A) Einside 0 A Ans...(i) . A spherical metal shell A of radius RA and a solid metal sphere B of radius RB (< RA) are kept far apart and each is given charge ‘+Q’.MATHEMATICS SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. (C). (B). (B). Now they are connected by a thin metal wire. Each question has four choices (A). 31. (C) and (D) out of which ONE or MORE may be correct. (D) (B) QA > QB A RB (C) R B A surface (D) E on A on surface EB Sol..

(B) They will come out travelling along parallel paths. Which of the following statement(s) is/are true? (A) They will never come out of the magnetic field region. tp = 2 RP 2 mp v 2mp v eBv eB ( 2 2)m e v ( 2 2)m e (2 2) R e = eBv eB v te = te tp RESONANCE J10411Page # 17 . They enter a semi-infinite region of uniform magnetic field perpendicular to the velocity. Ans. (B).PHYSICS 32. (D) Sol. (C) They will come out at the same time. An electron and a proton are moving on straight parallel paths with same velocity. (D) They will come out at different times.

C. A composite block is made of slabs A. (C). heat flow through A and E are same. Then in steady state (A) heat flow through A and E slabs are same (B) heat flow through slab E is maximum (C) temperature difference across slab E is smallest (D) heat flow through C = heat flow through B + heat flow through D. T = i × R ‘i’ is same for A and E but R is smallest for E. D: iB = R B T iC = R C T T iD = R D if ic = iB + iD Hence 1 1 1 R C RB R D 8KA 3KA 5kA RESONANCE J10411Page # 18 .PHYSICS 33. (D) At steady state. Sol. All slabs are of same width. D and E of different thermal conductivities (given in terms of a constant K) and sizes (given in terms of length. A: C: (A). L) as shown in the figure. Heat ‘Q’ flows only from left to right through the blocks. B. Ans.

A thin disk of mass ‘M’ and radius ‘R’ (<L) is attached at its center to the free end of the rod. (C) and (D) out of which ONLY ONE is correct.PHYSICS 34. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end. (A). (D) Angular frequency for case A < Angular frequency for case B. (B). The rod-disc system performs SHM in vertical plane after being released from the same displaced position. RESONANCE J10411Page # 19 . Consider two ways the disc is attached: (case A). Based upon one of the paragraphs 3 multiple choice questions and based on the other paragraph 2 multiple choice questions have to be answered. T = 2 A > B A < B mgd SECTION — III (Total Marks :15) (Paragraph Type) This section contains 2 paragraphs. The disc is not free to rotate about its center and (case B) the disc is free to rotate about its center. Each of these questions has four choices (A). Ans. Sol. Which of the following statement(s) is (are) true? (A) Restoring torque in case A = Restoring torque in case B (B) Restoring torque in case A < Restoring torque in case B (C) Angular frequency for case A > Angular frequency for case B. (D) torque is same for both the cases.

The phase space diagram is x(t) vs. For such systems. upwards (or to right) is positive and downwards (or to left) is negative. 35.PHYSICS Paragraph for Question Nos. We use the sign convention in which position or momentum. The phase space diagram for a ball thrown vertically up from ground is : Momentum Momentum (A) Position (B) Position Momentum Momentum (C) Position (D) Position Ans. 35 to 37 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. phase space is a plane in which position is plotted along horizontal axis and momentum is plotted along vertical axis. p(t) curve in this plane. (D) RESONANCE J10411Page # 20 . the phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure. They are especially useful in studying the changes in motion as initial position and momentum are changed. Here we consider some simple dynamical systems in one-dimension. For example. The arrow on the curve indicates the time flow.

the two circles represent the same oscillator but for different initial conditions.PHYSICS Sol. 36. and E1 and E2 are the total mechanical energies respectively. Then (A) E1 2 E 2 Ans. The phase space diagram for simple harmonic motion is a circle centered at the origin. In 2nd case amplitude of SHM is 2a Total energy = 1 k(amplitude)2 2 E1 = 1 k(2a)2 2 1 k(a)2 2 E2 = E1 4 E 2 RESONANCE J10411Page # 21 . (B) E1 2 E 2 (C) E1 4 E 2 (D) E1 16 E 2 In 1st case amplitude of SHM is a. (C) Sol. In the figure.

.(i) 1 m 1 m2 ( A )2 2 So energy E1 = 1 m 2 (2a)2 2 1 1 ( 4a 2 ) 2m 2a 2 m = = Comparing (i) and (iii) A=a (m)2 = 1 m2 = 1 m So E2 = 1 a2 1 a2 1 1 1 m 2 A 2 = a 2 = 2 2 m 2 m2 2 m E1 So E 4 E1 = 4E2 2 RESONANCE J10411Page # 22 ..(iii) .....(ii) .PHYSICS Alternative : Linear momentum P = mv = m A 2 x 2 P2 = m22 (A2 – x2) P2 + (m)2x2 = m22A2 Equation of circle (bigger) P2 + x2 = (2a)2 P2 + x2 = 4a2 Equation of circle (smaller) P2 + x2 = a2 Comparing (i) and (ii) Amplitude and (m)2 = 1 A = 2a m2 = .

(B) Sol. with the mass submerged in water.PHYSICS 37. as shown in the figure. The phase space diagram for one cycle of this system is : Momentum (A) Position (B) (C) (D) Ans. Consider the spring-mass system. Linear momentum P = mv 2 2 = m A x P2 + m22x2 = m22A2 represents a circle on P–x diagram with radius of circle R = A ( m22 = 1) of spring mass system remains constant and equal to k m RESONANCE J10411Page # 23 .

PHYSICS

Amplitude of oscillation inside liquid will decrease due to viscous force So radius of circular arcs will decrease as position change Correctly shown in option B

Paragraph for Question Nos. 38 and 39 A dense collection of equal number of electrons and positive ions is called neutral plasma. Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. Let ‘N’ be the number density of free electrons, each of mass ‘m’. When the electrons are subjected to an electric field, they are displaced relatively away from the heavy positive ions. If the electric field becomes zero, the electrons begin to oscillate about the positive ions with a natural angular frequency ‘p’, which is called the plasma frequency. To sustain the oscillations, a time varying electric field needs to be applied that has an angular frequency , where a part of the energy is absorbed and a part of it is reflected. As approaches p all the free electrons are set to resonance together and all the energy is reflected. This is the explanation of high reflectivity of metals. 38. Taking the electronic charge as ‘e’ and the permitlivity as ‘0’, use dimensional analysis to determine the correct expression for p.

(A) Ans. (C)

Ne m 0

(B)

m 0 Ne

(C)

Ne 2 m 0

(D)

m 0 Ne 2

1

Sol.

Ne 2 m 0

L

3

Q2 Q

2 2

M

1 T

L F

So only (C) is dimensionally correct

RESONANCE

J10411Page # 24

PHYSICS

39. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons

1 N 4 x 1027 m–3. Take 0 10–11 and m 10–30, where these quantities are in proper SI units. s. (A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm

Ans. (B) Sol. For resonance

= P =

Ne 2 m 0

4 10 27 (1.6 10 19 )2 10 30 10 11

= 3.2 × 1015 f=

3.2 1015 1 × 1015 2 2 3.14 2

3 10 8 c = = 1 1015 f 2

600 nm

**SECTION – IV (Total Marks : 28)
**

(Integer Answers Type)

This sections contains 7 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to be darkened in the ORS. 40. A boy is pushing a ring of mass 2 kg and radius 0.5 m with a stick as shown in the figure. The stick applies a force of 2 N on the ring and rolls it without slipping with an acceleration of 0.3 m/s2. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficient of friction between the stick and the ring is (P/10). The value of P is

RESONANCE

J10411Page # 25

PHYSICS

Sol.

Note : If net force applied by the rod is considered to be 2 N.

f '2 F 2 2

FR – f'R = 2mR2

...(i)

a R

...(ii)

F – f' = 2ma = 1.2 From (i) & (ii) (1.2 + f ')2 + f '2 = 22 2f '2 + 2.4f ' + 1.44 = 4 f '2 + 1.2f ' + 0.72 – 2 = 0 f '2 + 1.2f ' – 1.28 = 0 f' =

1.2 1.44 4 (1.28 ) 2

= 0.6 ± 0.36 1.28 = –0.6 ± = 0.68 From eq. (2) F = 1.88 =

0.68 P = 1.88 10

1.64

P = 3.61 4

Ans.

Note : In Hindi friction force is aksed, so the answer is P = 6.8. (for Hindi)

Note : But if only normal reaction applied by the rod is considered to be 2 N.

RESONANCE

J10411Page # 26

PHYSICS

Law a = R 0.3 = [0.5] =

3 rad/s 5

2 – f = 2 [0.3] f = 2 – 0.6 f - 1.4 Nx ...(i)

....(ii)

c = c fR – 2R = mR2 f – 2 = mR 1.4 – 2 =

2 3 2 5

1.4 – 0.6 = 2µ 0.8 = 2µ = 0.4 =

P 10

P=4

Ans.

Note : In Hindi friction force is aksed, so the answer is P = 8. (for Hindi) 41. A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of friction is . The force required to just push it up the inclined plane is 3 times the force required to just prevent it from sliding down. If we define N = 10 , then N is

Sol.

mg

F1 =

2

mg 2

RESONANCE

J10411Page # 27

PHYSICS

mg

F2 =

2

mg 2

F1 = 3F2 1 + = 3 – 3 4 = 2 =

1 2

Ans.

N = 10 N=5 42.

Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap film of side ‘a’.The surface tension of the soap film is . The system of charges and planar film are in equilibrium, and

q2 a =k

1/ N

, where ‘k’ is a constant. Then N is

Sol.

Surface Tension =

force length

2kq2 kq2 2 2 = × 2 a 2 2a a

1

q2 a = (Some constant)

43.

3

So

N=3

Ans.

Steel wire of length ‘L’ at 40°C is suspended from the ceiling and then a mass ‘m’ is hung from its free end. The wire is cooled down from 40°C to 30°C to regain its original length ‘L’. The coefficient of linear thermal expansion of the steel is 10–5 /°C, Young’s modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. Assume that L >> diameter of the wire. Then the value of ‘m’ in kg is nearly.

Sol.

F L =y A L mg y ( ) A

m= Ans. 3

Ay( ) r 2 y( ) (10 3 )2 1011 10 5 10 = = 3 g g 10

RESONANCE

J10411Page # 28

PHYSICS

44. The activity of a freshly prepared radioactive sample is 10 disintegrations per second, whose mean life is 109 s. The mass of an atom of this radioisotope is 10–25 kg. The mass (in mg) of the radioactive sample is Sol. N = N0 e–t

dN 9 = 1010 = N0 () e 10 t dt

10

at (t = 0) 1010 = N0 10–9 N0 = 1019 mass of sample = N0 10–25 = N0 (mass of the atom) = 10–6 kgm = 10–6 × 103 gm = 10–3 gm = 1 mg Ans. 45. 1

A long circular tube of length 10 m and radius 0.3 m carries a current along its curved surface as shown. A wire-loop of resistance 0.005 ohm and of radius 0.1 m is placed inside the tube with its axis coinciding with the axis of the tube. The current varies as = 0 cos (300 t) where 0 is constant. If the magnetic moment of the loop is N 0 0 sin (300 t), then ‘N’ is

Sol.

Flux through circular ring = (0 ni) r2 =

**0 2 r 0 cos 300 t L
**

d Rdt

i=

i=

0 r 2 0 . sin 300 t × 300 RL

=

r 2 .300 0 0 sin 300 t RL

RESONANCE

J10411Page # 29

PHYSICS

M = . r

2

=

** 2r 4 .300 0 0 sin 300 t RL
**

10 10 4 300 100 10

N=6 Ans.

(Take 2 = 10)

=

46.

Four solid spheres each of diameter N × 10–4 kg-m2, then N is

5 cm and mass 0.5 kg are placed with their centers at the corners of

a square of side 4cm. The moment of inertia of the system about the diagonal of the square is

Sol.

**2 2 2 2 2 = MR 2 + MR Mx 2 5 5 2 2 2 2 = MR 2 + MR 2 + (Mx2) 2 5 5 2 2 = 4 MR + 2mx2 5
**

8 MR 2 + 2mx2 5

=

2 8 0.5 5 2 (0.5) ( 4 2)10 4 = 5 2

5 = 8 × 10–4 5

= 9 × 10–4 = N × 10–4 So, N = 9 Ans.

RESONANCE

J10411Page # 30

MATHEMATICS

PART - III

SECTION - I (Total Marks : 21)

(Single Correct Answer Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

47.

**Let (x0, y0) be the solution of the following equations (2x)n2 = (3y)n3 3nx = 2ny . Then x0 is (A)
**

1 6

(B)

1 3

(C)

1 2

(D) 6

Ans. Sol.

(C)

(2x)n2 = (3y)n3 also n2 n(2x) = n3 n(3y) = n3 (n3 + ny) 3nx = 2ny nx n3 = ny n2 ......... (2)

nxn3 n 2 . n (2x) = n3 n3 n2

......... (1)

by (1) n2 n(2x) = n3 (n3 + ny) n22 n2x = n23 (n2 + nx)

n 2 n 3 (n2x) = 0

n2x = 0 x =

2

2

1 2

n 3

48.

The value of

n 2

**x sin x 2 dx is sin x sin(n6 x 2 )
**

2

(A)

1 3 n 4 2

(B)

1 3 n 2 2

(C) n

3 2

(D)

1 3 n 6 2

Ans. Sol. Put

(A) x2 =t x dx =

dt 2

RESONANCE

J10411Page # 31

.. c 3 1 = ( ) ( ) ( ) For – = 3 3 ˆ j + (2) k = (2+ 1) i – ˆ ˆ 1..dt 1 3 n 4 2 I= 49.(2) adding (1) and (2) 1 2I = 2 n 2 1. (C) ˆ (B) 3 ˆ i 3ˆ jk ˆ (C) 3ˆ i ˆ j 3k ˆ (D) ˆ i 3ˆ j 3k Sol. I = n 2 sin t sin (n6 t) b dt ..(1) 2 b apply a f ( x )dx = f (a b x)dx a 1 I= 2 n 3 n 2 sin(n6 t) sin t n 3 sin(n6 t ) dt . Let = a b ˆ i + ( ) ˆ j + ( )k = ( ) ˆ Now 1 ˆ = .MATHEMATICS n 3 sin t . is given by 3 ˆ (A) ˆ i 3ˆ j 3k Ans..bˆ ˆ and c Let a ˆ iˆ jk iˆ jk i j k be three vectors. A vector in the plane of a and b ... whose 1 projection on c is ... = 3ˆ l ˆ j 3k RESONANCE J10411Page # 32 ... ˆ ˆ ˆ ˆ.

Then b equals 4 1 3 (A) 3 4 (B) 1 2 (C) (D) 1 4 Ans.MATHEMATICS 50. Let P = { : sin – cos = (A) P Q and Q – P (C) P Q Ans. R1 = 0 ( x – 1)3 3 b = 0 (b – 1)3 1 3 1 1 also R2 = b ( x – 1)2 dx = ( x – 1)3 3 =– b (b – 1)3 3 R1 – R2 = 2(b – 1)3 1 3 3 1 8 1 2(b – 1)3 1 = 4 3 3 (b – 1)3 = – b= 1 2 J10411Page # 33 RESONANCE . b (B) ( x – 1)2 dx = Sol. n I 8 Let the straight line x = b divide the area enclosed by y = (1 – x)2. and x = 0 into two parts R1 (0 x b) and R2(b x 1) such that R1 – R2 = 1 . y = 0. P = {: sin – cos = sin = ( 2 + 1) cos tan = = n+ 2 +1 2 cos } 3 . = n + P=Q 3 . Then (B) Q P (D) P = Q Sol. (D) 2 cos } and Q = { : sin + cos = 2 sin } be two sets. n I 8 2 sin } Q = { : sin + cos = cos = ( 2 – 1) sin 1 tan = 2 –1 = 2 +1 51.

If an = n – n for n 1. then the value of is (A) 1 Ans.. (C) (B) 2 (C) 3 (D) 4 a10 2a 8 2a 9 x2 – 6x – 2 = 0 having roots and 2 – 6 – 2 = 0 10 – 69 – 28 = 0 10 – 28 = 69 similarly by (i) and (ii) (10 – 10) – 2(8 – 8) = 6 (9 – 9) a10 – 2a8 = 6a9 10 . Let and be the roots of x2 – 6x – 2 = 0. then the equation of L is (A) y + (C) Ans. If L also A straight line L through the point (3. 6 = =3 2 2 3 x y 1.. –2) is inclined at an angle 60º to the line intersects the x-axis.. m+ m=0 3 = 3 – 3m taking negative sign m+ m= As L cuts x-axis so L is y + 2 = m= 3 + 3 3 3 – 3m = 0 3 (x –3) J10411Page # 34 RESONANCE . (i) 8 9 – 2 = 6 .. 3x+2–3 3=0 (B) y – (D) 3x+2+3 3 =0 3y–x+3+2 3 =0 (B) 3y+x–3+2 3 =0 Sol. Let slope of line L = m m – (– 3 ) 1 m(– 3 ) = tan 60º = m 3 3 1 3m = 3 taking positive sign.MATHEMATICS 52. Sol. (ii) Aliter a10 – 2a8 =3 2a9 10 10 2( 8 8 ) 10 10 ( 8 8 ) 9 ( ) 9 ( ) = = 2( 9 9 ) 2( 9 9 ) 2( 9 9 ) = 53. with > ...

and perpendicular to the vector The vector(s) which is/are coplanar with vectors ˆ iˆ j 2k i 2ˆ jk ˆ ˆ is/are iˆ jk ˆ (A) ˆ j k Ans. then M2 N2 (MT N)–1 (MN–1)T is equal to (A) M2 Ans. we obtain correct answer.II (Total Marks : 16) (Multiple Correct Answers Type) The section contains 4 multiple choice questions. Data inconsistent A 3 × 3 non-singular matrix cannot be skew-symmetric However considering M. (B). ˆ and ˆ ˆ . (C) (B) – N2 (C) – M2 (D) MN Sol. (C) and (D) out of which ONE or MORE may be correct. a ) b ] ˆ ) – (1+1+2) ( ˆ ˆ)] [(1+2+1) – ( ˆ i+ˆ j +2 k j +k i +2 ˆ ˆ] j +4 k [–4 ˆ so our vector in parallel ˆ –ˆ j + k 55. If PT denotes the transpose of P. Each question has four choices (A). b ) a – ( c . Let M and N be two 3 × 3 non-singular skew-symmetric matrices such that MN = NM. N matrices as even order. ˆ j + 2k a =ˆ i+ˆ ˆ j+k i +2 ˆ b=ˆ ˆ j +k i+ˆ c = ˆ Required vector is c × ( a × b ) [( c .MATHEMATICS SECTION . M2 N2 (MT N)–1 (MN–1)T = M2N2 N–1 (MT)–1 (N–1)T MT – M2 N2 N–1 M–1 N–1 M – M2 NM–1 N–1 M – MNN–1 M –M2 (So the question is wrong) RESONANCE J10411Page # 35 . 54. (A. D) (B) ˆ iˆ j (C) ˆ iˆ j ˆ (D) ˆ jk Sol.

x. Let the eccentricity of the hyperbola hyperbola passes through a focus of the ellipse. 0 3 ( 3 )2 a2 =1 a= b = 1 & focus of hyperbola (±2. C) Sol. Sol. f(x) = kx Hence f(x) is continuous & differentiable at x R & f ’(x) = k (constant) RESONANCE J10411Page # 36 . (B. D) Eccentricity of ellipse = 1 1 3 = 4 2 1 b2 2 3 = a2 b = a 1 3 focus of ellipse 3 . If f(x) is differentiable at x = 0. then (A) (B) (C) (D) Ans. the equation of the hyperbola is a focus of the hyperbola is (2. 0) Hence equation of hyperbola x2 y2 =1 3 1 57. If the 2 – a b2 56. 0) the eccentricity of the hyperbola is 5 3 x2 y2 – =1 3 2 the equation of the hyperbola is x2 – 3y2 = 3 (B.MATHEMATICS x2 y2 = 1 be reciprocal to that of the ellipse x2 + 4y2 = 4. then (A) f(x) is differentiable only in a finite interval containing zero (B) f(x) is continuous x R (C) f(x) is constant x R (D) f(x) is differentiable except at finitely many points Ans. Let f : R R be a function such that f(x + y) = f(x) + f(y). y R.

No. If the point P(a. (B) (Q.. 58 to 60 Let a.. Let be a solution of x3 – 1 = 0 with m () > 0... b and c be three real numbers satisfying 1 9 7 [a b c] 8 2 7 = [0 0 0] 7 3 7 .... lies on the plane 2x + y + z = 1. then the value of 7a + b + c is (A) 0 Ans.(–1) – 8(6) + 7(7) = 0 1 1 1 RESONANCE J10411Page # 37 . 58 to 60) a + 8b + 7c = 0 9a + 2b + 3c = 0 a+b+c=0 . then n0 1 1 n is (A) 6 (B) 7 (C) 6 7 (D) Ans... (D) (B) 12 (C) 7 (D) 6 59.... c).. (iii) 1 8 7 = 9 2 3 = 1... with a and c satisfying (E)....... (i) . (C) and (D) out of which ONLY ONE is correct..III (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs... Based upon one of the paragraphs 3 multiple choice questions and based on the other paragraph 2 multiple choice questions have to be answered. (ii) ... Each of these questions has four choice (A).. with reference to (E). if a = 2 with b and c satisfying (E).MATHEMATICS SECTION ... (B).... then the value of 3 1 3 a + b + c is equal to (B) 2 (C) 3 (D) – 3 (A) – 2 Ans. Sol. If and are the roots of the quadratic equation ax2 + bx + c = 0. (A) Let b = 6. Paragraph for Questions Nos..(E) 58.... b. 60.....

if tail appears then 2 balls are drawn at random from U1 and put into U2. c) 7 7 58.MATHEMATICS Let C= a + 8b = –7 a + b = – b= 6 & a= 7 7 6 . Now 1 ball is drawn at random from U2. If head appears then 1 ball is drawn at random from U1 and put into U2...14 = 3 + 1 + 32 = 3( +2) + 1 = – 2 a 60.. However. . a=2 = –14 b = 12 & c = –14 Now 3 1 3 3 1 b c = 2 12 3.. = 1 1 6 7 =7 Paragraph for Question Nos. Sol. where R (a. 1 x2 + 6x – 7 = 0 1 1 6 = 7 n 0 n 0 n n = 1+ 6 6 + 7 7 2 + . b=6 now = –7 a=1 & c=–7 ax2 + bx + c = 0 x = –7 . P(a. c) lies on the plane 2x + y + z = 1 2 6 = 1 7 7 =1 7 = –7 7a + b +c = 7 + 6 – 7 = 6 59.. A fair coin is tossed. P(white) = P (H white) + P(T white) 2 C 1 3 2 1 1 3C 1 3 C ·2 C 2 · 1 · · 5 2 1 5 2 51 1 2 5 5 2 2 C2 3 C2 C2 3 = RESONANCE J10411Page # 38 . b. 61 and 62 Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls. b.. The probability of the drawn ball from U2 being white is (A) 13 30 (B*) (B) 23 30 (C) 19 30 (D) 11 30 Ans. 61. and U2 contains only 1 white ball.

MATHEMATICS = 1 8 1 3 1 12 2 10 2 10 30 30 4 1 22 10 2 30 23 30 = = 62. and 2 be the area of the triangle formed by drawing tangents at P 2 1 and at the end points of the latus rectum. 2 on the parabola. Let 1 be the area of the triangle formed by the end points of its latus rectum 1 and the point P . The answer to each of the questions is a single-digit integer.IV (Total Marks : 28) (Integer Answer Type) This section contains 7 questions. (2) 2 = 1 2 (by property) 1 2 = 2 RESONANCE J10411Page # 39 . Consider the parabola y2 = 8x. Then is 2 Ans. 63. P Head White = P(Head white) P( white) 1 3 2 1 4 1 12 2 5 5 2 10 = = = 23 23 23 30 30 SECTION . Sol. The boubble corresponding to the correct answer is to be darkened in the ORS. Sol. Given that the drawn ball from U2 is white. the probability that head appeared on the coin is (A) 17 23 (B) (D) 11 23 (C) 15 23 (D) 12 23 Ans. ranging from 0 to 9).

Let a1. but in principal. m = 0 n=7 7 = (2m + 1) n RESONANCE J10411Page # 40 . a2. not possible n If Ans. Sol. 1 sin n – (n = 7) 1 1 = 3 2 sin sin n n 2 cos 2 sin 1 n n 3 = sin 2 sin sin n n n 4 3 = sin n n sin 4 3 = (–1)k + k . k = 2m + 1 n = 7.MATHEMATICS p 64. The positive integer value of n > 3 satisfying the equation 1 1 1 is 2 3 sin sin sin n n n Ans.. a100 be an arithmetic progression with a1 = 3 and Sp = a . let m = 5n. question seems to have an error. a3. 65... k n n If k = 2m = 2m n 1 = 2m . (9) Sol.. If S does not depend on n. then a2 is n Ans. i i 1 Sm For any integer n with 1 n 20. 5n [6 (5n 1)d] 2 S 5n Sm 5[( 6 d) 5nd] = = = n Sn Sn [( 6 d) nd] [6 (n 1)d] 2 d = 6 or d = 0 a2 = 3 + 6 = 9 Now if d = 0 then a2 = 3 else a2 = 9 for single choice more appropriate choice is 9. 1 p 100...

a contradiction (given that f(1) = 2). (5) Sol. If z is any complex number satisfying |z – 3 – 2i| 2.MATHEMATICS 66. y = 2 y=x +x f(x) = x2 + x 2 f(2) = 4 + 2 = 6 67. (6) Data inconsistent. If x 6 f ( t ) dt 3 xf ( x ) x 3 1 for all x 1. ) be a differentiable function such that f(1) = 2. then the minimum value of |2z – 6 + 5i| is Ans. Let f : [1.F. Sol. x However if considering integral equation as 6 f ( t ) dt 3 xf ( x ) x 3 – 5 1 we obtain correct answer. in given integral equation f(1) = 1/3 . ) [2. = 1 x 1 =x+c x c=1 General solution is y Put x = 1. then the value of f(2) is Ans. 5i |2z – 6 + 5i| = 2 z 3 2 5 =5 2 for minimum = 2 × RESONANCE J10411Page # 41 . Putting x = 1 . Differentiating the integral equation 6f(x) = 3f(x) + 3xf(x) – 3x2 f(x) – put 1 f(x) = x x y = f(x) dy 1 – y=x dx x I.

a . Sol. 3 . sin sin = sin–1 tan 1 cos cos 2 f() = tan df =1 d tan RESONANCE J10411Page # 42 . at a = 1 5 a a a minimum value of 69. 3 . (1) Sol. d sin ( f ()) is tan 1 Let f() = sin cos 2 . 1. a–4. 1 1 1 1 1 1/ 8 4 3 3 3 1 a 8 a10 5 1 1 1 1 1 8 10 a a a a a 5 . where – 4 < < 4 .MATHEMATICS 68.a 8 a a a a a 1 1 3 1 a8 a10 8(1)1/ 8 a5 a 4 a 3 1 1 3 4 3 1 a 3 a10 = 8. Then the value of d (tan ) Ans. 3a–3. G. The minimum value of the sum of real numbers a–5.M. (8) A. 3 . a8 and a10 where a > 0 is Ans.1.M. 4 .

Name of the Candidate Roll Number I have read all the instructions and shall abide by them. -------------------------------Signature of the Candidate I have verified all the information filled in by the Candidate. -------------------------------Signature of the Invigilator RESONANCE J10411Page # 43 .

12. a machine-gradable Optical Response Sheet (ORS). and the name of centre and sign with pen in the boxes provided. 3. Write your Name. 6. In Section IV (Total Marks: 16). 7.2 Please read the instructions carefully. In Section II (Total Marks: 16). If the codes do not match. 11. You are allotted 5 minutes specifically for this purpose. for each question you will be awarded 3 marks it you darken ONLY the bubble corresponding to the correct answer and zero marks if no bubble is darkened. B. pagers and electronic gadgets are NOT allowed. In all other cases. ask for a change of the booklet. for each question you will be awarded 2 marks for each row in which you have darkened ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. clipboards. Filling the Right Part of the ORS: 10. Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators. cellular phones. Do not write them anywhere else. Write your Name registration number and sign in the space provided on the back page of this booklet. DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR . Write your name and registration number in the space provided on the back page of this booklet.QUESTIONS AND SOLUTIONS OF IIT-JEE 2011 Date : 11-04-2011 Duration : 3 Hours Max. calculators. each question in this section carries a maximum of 8 marks. INSTRUCTIONS A. In Section Ill (Total Marks: 24). Blank papers. slide rules. please check that all the questions are legible. 9. is provided separately. Marks : 240 PAPER . 2. Registration No. General : 1. There are no negative marks in this section. 4. Make sure the CODE on the ORS is the same as that on this booklet. C. DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET. The ORS also has a CODE printed on its Left and Right parts. On breaking the seals. 17. Physics and Mathematics). This Question Paper contains having 60 questions. The question paper consists of 3 parts (Chemistry. Each part consists of four sections. 15. There are no negative marks in this section. for each queshon you will be awarded 4 marks if you darken ALL the bubble(s) corresponding to the correct answer(s) ONLY and zero marks otherwise. 14. The question paper CODE is printed on the right hand top corner of this sheet and on the back page of this booklet. Thus. Question paper format and Marking Scheme: 13. The answer sheet. log tables. In Section I (Total Marks: 24). There are no negative marks in this section. 8. 5. Darken the appropriate bubble UNDER each digit of your Registration No. No additional sheets will be provided for rough work. minus one (-1) mark will be awarded. 16. with a good quality HB pencil. for each question you will be awarded 4 marks if you darken ONLY the bubble corresponding to the correct answer and zero marks otherwise.

0 × 108 m s–1 NA = 6.Useful Data : R = 8.626 × 10–34 Js 1 eV = 1.022 × 1023 RESONANCE J10411Page # 2 .206 × 10–2 L atm K–1 mol–1 1 F = 96500 C mol–1 h = 6.314 JK–1 mol–1 or 8.602 × 10–19 J c = 3.

N. M. K3[Fe(CN)6] (K).1 atm and pH = 3. O. with two unpared electrons . So only those sulphides are precipitated which have low solubility product (KSP) value.57 V RESONANCE J10411Page # 3 . ionisation of H2S is supressed so less number of S2– ions are produced. Consider the following cell reaction : 2Fe2+ (aq) + 2H2O (l) 2Fe (s) + O2 (g) + 4H+ (aq) 4. P (O2) = 0. Sol.67 V At [Fe2+] = 10–3 M. P (C) L. O–[Pt(CN)4]2– : 5d8 electron configuration. Na3[Co(oxalate)3] (M). Sol. d2sp3. III in haematite and III in magnetite (B) II.CHEMISTRY PART-II SECTION – I (Total Marks : 24) (Single Correct Answer Type) This section contains 8 multiple choice questions. Ni2+. P–[Zn(H2O)6]2+ : 3d10 electron configuration. Each question has four choices (A). III in magnetite (D) III in haematite and II. O 2. diamagnetic. respectively. K–[Fe(CN)6]3– : 3d5 electron configuration after pairing of electrons for d2sp3 hybridisation it contains one unapaired electrons. N–[Ni(H2O)6]2+ : 3d8 electron configuration. Oxidation states of the metal in the minerals haematite and magnetite.77 V (C) 1. (C) and (D) out of which ONLY ONE is correct. sp3d2 diamagnetic. M.87 V (D) 1. Sol. N Ans. sp3d2. L–[Co(NH3)6]3+ : 3d6 electron configuration. Cu2+ and Hg2+ ions in an acidified aqueous solution precipitates: (A) CuS and HgS (B) MnS and CuS (C) MnS and NiS (D) NiS and HgS Ans. the cell potential at 25ºC is : (A) 1. P (D) L. Passing H2S gas into a mixture of Mn2+. III in haematite and II in magnetite (C) II in haematite and II. 1. O. In presence of acidic medium. [Co(NH3)6]Cl3 (L). Among the following complexes (K–P). [Ni(H2O)6]Cl2 (N). Fe is present (III) oxidation state and in magnetite (Fe3O4) Fe is present in (II) and (III) oxidation state. M–[Co(ox)3]3– : 3d6 electron configuration. d2sp3. M. Eº = 1. paramagnetic. M. (D) (B) 1. dsp2 diamagnetic. diamagnetic.47 V Ans. III in magnetite Ans. are : (A) II. (C) (B) K. (B). (A) 3. (D) In haematite(Fe2O3). K2[Pt(CN)4] (O) and [Zn(H2O)6](NO3)2 (P) the diamagnetic complexes are : (A) K. L. For example CuS and HgS.

Wt.67 – 5.1 0.3 × 10–2 Ans. (A) (B) – 5.57 V. (B) (B) an acetal (C) an ether (D) an ester Sol.CHEMISTRY Sol.86 K kg mol–1) is : (A) – 2. .565 = 1. the one that would form a brilliant colored dye on treatment with NaNO2 in dilute HCl followed by addition to an alkaline solution of -naphthol is : (A) (B) (C) (D) Sol. 329) in 100 g of water (Kf = 1. 6. The freezing point (in ºC) of a solution containing 0.67 – 0.105 = 1. The major product of the following reaction is 2 H (anhydrous ) RCH OH (A) a hemiacetal Ans.67 – = 1. Tf = i × Kf × m = 4 × 1.03 × 7 = 1.2 × 10–2 Sol.1 g of K3[Fe(CN)6] (Mol. 7. 2 = 1.86 × 0. RESONANCE J10411Page # 4 .7 × 10–3 (D) – 1.3 × 10–2 ºC.059 E = Eº – log [H ]4 P 4 O2 (103 )2 0. Amongst the compounds given.06 0.3 × 10–2 = – 2.3 × 10–2 329 0.7 × 10–2 (C) – 5.1 Tf = 0 – 2.03 log = 1.67 – log107 4 2 (103 )4 0. [Fe2 ]2 0.1 = 2.

(B). (C) and (D) out of which ONE or MORE may be correct. It is a -pyranose hence it is an aldohexose.=1) RESONANCE J10411Page # 5 . In acidic medium. SECTION — II (Total Marks: 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions.=3) In strongly basic medium MnO42– MnO4– (v. The following carbohydrate is (A) a ketohexose (B) an aldohexose (C) an -furanose (D) an -pyranose Sol. 9.f. Each question has four choices (A). D) Sol.f.=5) In neutral / basic medium MnO2 MnO4– (v. Reduction of the metal centre in aqueous permanganate ion involves. C.CHEMISTRY 8. Mn2+ MnO4– (v. (A) 3 electrons in neutral medium (B) 5 electrons in neutral medium (C) 3 electrons in alkaline medium (D) 5 electrons in acidic medium Ans.f. D) / (A. (A.

After eight half lives. (A. C= Co 28 Co 28 100 = 99. D) Sol. (A) CH3OOC — (CH2)4 — COOCH3 (B) X = CONH2. B. Ct = C0e–Kt t1/2 1 . For the first order reaction 2N2O5 (g) 4NO2(g) + O2 (g) (A) The concentration of the reaction decreases exponentially with time (B) The half-life of the reaction decreases with increasing temperature (C) The half-life of the reaction depends on the initial concentration of the reactant (D) The reaction proceeds to 99. Sol. SCN– ions forms precipitate with Cu+.6% Co – 12.6% completion in eight half-life duration Ans. CN–.CHEMISTRY 10. C. Y = H2/NI/heat H2 / Ni HOOC— ( CH2 )4 — COOH HOCH2 — (CH2)4 — CH2 — OH (B) 2 4 HOOC— ( CH ) — COOH RESONANCE J10411Page # 6 . D) Cl–. (B. K K on increasing T. % completion = C0 The correct functional group X and the reagent/reaction conditions Y in the following scheme are condensation polymer : (A) X = COOCH3. Y = H2Ni/heat (D) X = CN. The equilibrium 2CuI Cu0 + CuII in aqueous medium at 25° C shifts towards the left in the presence of : (A) NO3 (B) Cl– (C) SCN– (D) CN– Ans. Y = H2/Ni/heat (C) X = CONH2. 11. Y = Br2/NaOH Sol.

01 × 30 = 0. Ans. 6 Sol. Sol. The bubble corresponding to the correct answer is to be darkened in the ORS.1 × V = 0. Among the following. RESONANCE J10411Page # 7 . SO2. mmole of Cl– = 0. 14. the number of compounds that can react with PCl5 to give POCl3 is O2. 4 PCl5 produces POCl3 on reaction with these compounds POCl3 + SOCl2 PCl5 + SO2 POCl3 + 2HCl PCl5 + H2O SO2Cl2 + 2POCl3 + 2HCl PCl5 + H2SO4 10POCl3 6PCl5 + P4O10 (Source : J. 13. Lee) (Source : Green wood).CHEMISTRY (C) HOOC— ( CH2 )4 — COOH Br2 NH — (CH ) — NH NH2OC — (CH2)4 — CONH2 2 2 4 2 NaOH / (D) 2 4 HOOC— ( CH ) — COOH Section Ill (Total Marks : 24) (Integer Answer Type) This section contains 6 questions.D.3 × 2 = 0.3.6 V = 6 mL.6 mmole of Ag+ = mmoles of Cl– 0. The answer to each of the questions is a single-digit integer. H2SO4.D. The volume (in mL) of 0..01 M solution of [Cr(H2O)5Cl]Cl2. P4O10.1 M AgNO3 required for complete precipitation of chloride ions present in 30 mL of 0. H2O. Ans. Lee) (Source :NCERT) (Source : J. as silver chloride is close to. CO2. m moles of [Cr(H2O)5Cl]Cl2 = 0. ranging from 0 to 9.

The resultant concentation of Ag+ in the solution is 1. 8 Cl / h 2 RESONANCE J10411Page # 8 . 8 Sol.6 × 10–10 Ksp(CuCl) = 10–6 Ag+ + Cl– Z Z+Y + CuCl (s) Cu + Cl– Y Z+Y –10 Z (Z + Y) = 1.0 × 10–6] is added. Sol.6 × 10–10].CHEMISTRY 15.6 × 10–10 + 10–6 (Z + Y)2 10–6 Z + Y = 10–3 Z (Z + Y) = 1. Sol.6 × 10 Y (Z + Y) = 10–6 (Z + Y)2 = 1.6 × 10–7 x=7 AgCl (s) 16.6 × 10–10 Z = 1. The number of hexagonal faces that are present in a truncated octahedron is Ans.6 × 10–x.6 × 10–10 Z × 10–3 = 1. The maximum number of isomers (including stereoisomers) that are possible on monochlorination of the following compound.1 mol of CuCl [Ksp(CuCl) = 1. The value of "x" is Ans.6 × 10–7 1.6 × 10–x = 1. 17. 0. is Ans. In 1 L saturated solution of AgCl [Ksp(AgCl) = 1. 7 Ksp(AgCl) = 1.

darken the bubbles corresponding to q and r in the ORS.CHEMISTRY + Total = 8 18. (D – p. B. (B – r. s) . SECTION — IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. (A – p. if for a given question. C and D) given in Column I and five statements (p. s) . solid) (p) phase transition (q) allotropic change (r) H is positive (s) S is positive (t) S is negative Ans. r. 19. (C – t) . t) CO2 (g) (A) CO2 (s) It is phase transition. against statement B. then for the particular question. so entropy increases. Sol. statement B matches with the statements given in q and r. Match the transformation in column I with appropriate options in column II Column I Column II CO2(g) (A) CO2(s) CaO(s) + CO2(g) (B) CaCO3(s) H2(g) (C) 2H P(red. RESONANCE J10411Page # 9 . r. s and t) in Column II. Gas is produced. q. For example. The total number of contributing structures showing hyperconjugation (involving C–H bonds) for the following carbocation is Ans. q. The process is endothermic (sublimation). 6 There are total 6 hyperconjugable H-atoms in this carbocation which are countributing in the hyperconjugation. Sol. Each question has four statements (A. solid) (D) P(white.

s. (C-r. 20. r) RESONANCE J10411Page # 10 . (D) It is phase transition. The entropy increases as gaseous product is formed. s) .CHEMISTRY (B) On heating CaCO3 decomposes. White and red P are allotopes. So H is – ve. (B-p. (A-r. Red P is more stable than white. (D-q. process is endothermic. s) . H2(g) (C) 2H Entropy decreases as number of gaseous particles decreases. t) . Match the reactions in column I with appropriate type of steps/reactive intermediate involved in these reactions as given in column II Column I Column II (A) aq NaOH (p) Nucleophilic substitution (B) 3 CH MgI (q) Electrophilic substitution (C) 2 4 H SO (r) Dehydration (D) 2 4 H SO (s) Nucleophilic addition (t) Carbanion Ans. So.

(A) aq / NaOH dehydration OH / (B) (C) 2 4 H SO 2 4 H SO de hydration (D) 2 4 H SO substituti on Electrophi lic dehydration RESONANCE J10411Page # 11 .CHEMISTRY Sol.

So transmitted intensity = 0 So correct answer is (C) RESONANCE J10411Page # 12 . Sol.I (Total Marks . 21. all the light rays will be total internal reflected.PHYSICS PART-II SECTION . both as function of . (C) and (D) out of which ONLY ONE is correct. Each question has four choices (A). (C) (C) Initially most of part will be transmitted. The correct sketch is 100% 100% (A) (B) 100% (C) (D) Ans.24) (Single Correct Answer Type) This section contains 8 multiple choice questions. A light ray traveling in glass medium is incident on glass-air interface at an angle of incidence . are plotted. When > iC . The reflected (R ) and transmitted (T) intensities. (B).

The values of B and are (A) 2 A. (A) Sol. B 0 dNi 2x N 0 dx i ba 2x = 0Ni b n 2(b a) a A point mass is subjected to two simultaneous sinusoidal displacements in x-direction. the kinetic energy of the object is (A) 1 mV 2 2 (B) (B) mV2 (C) 3 mV 2 2 (D) 2mV2 Sol. 5 6 (D) A. (B) Ve = KE = 2v 0 1 1 mv 2 m 2v 0 e = 2 2 2 = mv02 23. Adding a third sinusoidal displacement x (t) = B sin (t + ) brings the mass to a x2 (t) = A sin t 3 3 complete rest. A long insulated copper wire is closely wound as a spiral of ‘N’ turns. The spiral has inner radius ‘a’ and outer radius ‘b’. x1 (t) = A sin t and 2 . 3 4 (B) A. An object of mass ‘m’ is ejected from the satellite such that it just escapes from the gravitational pull of the earth. A satellite is moving with a constant speed 'V’ in a circular orbit about the earth.PHYSICS 22. 24. The Zcomponent of the magnetic field at the center of the spiral is (A) 0N b n 2(b a) a (B) 0N ba n 2(b a) b a (B) 0N b n 2b a (D) 0N b a n 2b ba Ans. (B) RESONANCE J10411Page # 13 . Ans. 4 3 (C) 3 A. 3 Ans. At the time of its ejection. The spiral lies in the X-Y plane and a steady current flows through the wire.

(C) True for induced electric field and magnetic field. RESONANCE J10411Page # 14 . = 240° = 4 3 Which of the field patterns given below is valid for electric field as well as for magnetic field? (A) (B) (C) (D) Sol. Ans. B = A.PHYSICS So 25.

V2 = 100 m/sec. A bullet of mass 0. If the measured mass of the ball has a relative error of 2%. the relative percentage error in the density is (A) 0. After the collision.01 kg. Sol.5 mm + (20)(0. The reading on the main scale is 2.2% Ans. The ball hits the ground at a distance of 20 m and the bullet at a distance of 100 m from the foot of the post.5 mm and there are 50 divisions on the circular scale.01) D = 2. A ball of mass 0.2 kg rests on a vertical post of height 5 m.5 mm and that on the circular scale is 20 divisions.1% (D) 4.7 mm M 3 M D = = 4 vol 3 2 RESONANCE J10411Page # 15 .2)(20) + (0. traveling with a velocity V m/s in a horizontal direction.01)(100) V = 500 m/s 27.PHYSICS 26. The density of a solid ball is to be determined in an experiment. whose pitch is 0. The diameter of the ball is measured with a screw gauge. Applying momentum conservation just before and just after the collision (0. (D) R= u (B) 250 2 m/s (C) 400 m/s (D) 500 m/s 2h g 25 25 and 100 = V2 10 10 20 = V1 V1 = 20 m/s . Least count = 0 .9% (B) 2. (C) Sol.4% (C) 3.01) (V) = (0. hits the centre of the ball. The initial velocity V of the bullet is (A) 250 m/s Ans.5 = 0. the ball and bullet travel independently.01 mm 50 Diameter of ball D = 2.

They get arranged into an equilibrium state as shown in the figure with a tension in the string. Each question has four choices (A). If now a uniform electric field E is switched-on as shown. (B).PHYSICS m D 3 m D . then the SHM of the block will be (A) of the same frequency and with shifted mean position. the equilibrium position gets shifted by will be (A) SECTION — II (Total Marks: 16) (Multiple Correct Answer(s) Type) This section contains 4 multiple choice questions. (D) of changed frequency and with the same mean position. (C) and (D) out of which ONE or MORE may be correct. (D) (B) dB > dF (C) dA > dF (D) dA + dB = 2dF RESONANCE J10411Page # 16 . K but due to the constant qE force. (A) The frequency will be same f = 1 k 2 m qE in forward direction.1% 28. Ans. A wooden block performs SHM on a frictionless surface with frequency. 0. (A). The block carries a charge +Q on its surface. Two solid spheres A and B of equal volumes but of different densities dA and dB are connected by a string.01 100% = 2% + 3 2 . Sol. (C) of changed frequency and with shifted mean position. (B) of the same frequency and with the same mean position. 29. max 0.7 max = 3. (B). So Ans. They are fully immersed in a fluid of density dF. The arrangement is possible only if (A) dA < dF Ans.

(C) Sol. (B). Case I Z= 1 R2 C 2 Case II A R V Z V Z´ Z´ < Z B R A R B R A B VR VR So. For equilibrium dAvg + dBvg = dFvg + dFvg dF = d A dB 2 Option (D) is correct to keep the string tight dB > dF and dA < dF 30.PHYSICS Sol. (A) when C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. Consider two cases. Which of the following is/are true? A (A) R B R A (B) R B R A B (C) VC VC A B (D) VC VC Ans. A series R-C circuit is connected to AC voltage source. The current IR through the resistor and voltage VC across the capacitor are compared in the two cases. A B VC VC 2 2 2 VR VC V0 RESONANCE J10411Page # 17 .

hits the ring at a height of 0.1 kg. in m/s2. 33. 5 RESONANCE J10411Page # 18 . then the Gauss law will still be valid. Sol. = Eds = Kq r 2 4 r 2 = q 0 W ext = q(VB – VA) Comment : (D) is not crrect answer because it is not given that charge is moving slowly.75 m and goes vertically up with velocity 10 m/s. Which of the following statement(s) is/are correct? (A) If the electric field due to a point charge varies as r –2. The bubble corresponding to the correct answer is to be darkened in the ORS. (C) Sol. The answer to each of the questions is a single-digit integer. is Ans.15 m inside the train to catch the ball back at the initial height. A thin ring of mass 2 kg and radius 0. then the sign of the two charges is the same. (D) The work done by the external force in moving a unit positive charge from point A at potential VA to point B at potential VB is (VB — VA). A train is moving along a straight line with a constant acceleration ‘a’. 32. A small ball of mass 0. Ans. The acceleration of the train. Section — Ill (Total Marks : 24) (Integer Answer Type) This section contains 6 questions. (C) If the electric field between two point charges is zero somewhere. (C) Friction between the ring and the ground is to the left. ranging from 0 to 9. (C) Friction force on the ring.5 m is rolling without slipping on a horizontal plane with velocity 1 m/ s. at an angle of 60º to the horizontal. Immediately after the collision (A) The ring has pure rotation about its stationary CM (B) The ring comes to a complete stop. The boy has to move forward by 1. A boy standing in the train throws a ball forward with a speed of 10 m/s. (D) There is no friction between the ring and the ground.5 instead of r –2. moving with velocity 20 m/s in the opposite direction. Ans. (B) The Gauss law can be used to calculate the field distribution around an electric dipole.PHYSICS 31.

18 u2 = 0.18 × 10 × 0.15 2 3a = 8. The coefficient of friction between the block and the floor is 0.18 kg is attached to a spring of force-constant 2 N/m.5 2 a = 7. An impulse is given to the block as shown in the figure.06 2 0.06 m and comes to rest for the first time. T 2u sin g 2 10 3 3 sec 10 2 1 2 aT 2 T= R = ucos.06 + kx2 2 2 1 × 0.15 = 10 × 1 1 3 – a( 3 )2 2 2 3 a = 5 3 – 1.1 1 1 mu 2 = mg × 0.PHYSICS Sol.1.4 = N 10 N = 4 Ans. The initial velocity of the block in m/s is V= N/10. Sol.65 – 1.5 × 2 5 m/sec2 3 a = 5 m/sec2 34. A block of mass 0. 4 = 0. Initially the block is at rest and the spring is un-stretched.15 = 7. The block slides a distance of 0.1 × 0. T – 1. Then N is Ans. RESONANCE J10411Page # 19 .

Oil of refractive index lies on water making a 3 4 convex surface of radius of curvature ‘R = 6 cm’ as shown. E1 E 2 6 3 r1 r2 1 2 1 1 1 1 r1 r2 1 2 15 = 5 volt 3 = Ans. The voltage across AB in volts is Ans. Consider oil to act as a thin lens. The location of its image is at ‘x’ cm above the bottom of the tank. 5 Sol. Water (with refractive index = 4 7 ) in a tank is 18 cm deep. An object ‘S’ is placed 24 cm above water surface. 36. Then ‘x’ is Ans. Two batteries of different emfs and different internal resistances are connected as shown. 2 RESONANCE J10411Page # 20 .PHYSICS 35.

25 L 2 Z= RESONANCE J10411Page # 21 . W = 500 rad/s 1 2 R = R 1. 2 1 2 1 v u R 7 1 7 1 4 4v 24 6 7 3 1 2 1 4v 24 24 24 12 7 12 V = 21 cm 4 21 7/4 OS" 4 / 3 21 7 3 OS" 4 4 OS" = 16 BS" = 2cm 37. A series R-C combination is connected to an AC voltage of angular frequency = 500 radian/s.25 . the time constant (in millisecond) of the circuit is Ans.PHYSICS Sol. 4 Sol. If the impedance of the R-C circuit is R 1.

5 9 10 1.2 – 4.25) L 1 R2 + R2 = R2 + L 4 1 R L 2 2 2 CR = 2 2 = sec. R = 1cm f = 4. 500 2 × 103 ms 500 2 1000 ms 500 = = = 4 ms 38. It is under continuous illumination of 200 nm wavelength light. A silver sphere of radius 1 cm and work function 4.5 Ne 1. the sphere gets charged and acquires a potential.5 volt 1 Q 4 0 R = 1.7 = V V = 1.7 eV is suspended from an insulating thread in freespace.6 10 19 11 = 15 1 10 8 16 9 = 5 50 10 8 = 10 7 3 16 48 Z=7 J10411Page # 22 RESONANCE .5 (9 × 10 ) 1 100 9 9 × 1011 Ne = 1. The value of ‘Z’ is Ans. Sol.7 (eV) + eV 200(nm) 1240 e = 4. The maximum number of photoelectrons emitted from the sphere is A × 10Z (where 1 < A < 10).7 e + eV 200 6.PHYSICS 1 + R2 = R2 (1.5 . N= 1.7 cm hc = + eV 7 1240(ev )(nm) = 4. As photoelectrons are emitted.

r. Match them with each of the processes given in Column I. darken the bubbles corresponding to q and r in the ORS. q.s. (r) CD DA (q). Column II (p) Internal energy decreases (q) Internal energy increases (r) Heat is lost (s) Heat is gained (t) Work is done on the gas. Each question has four statements (A. (s) (r).PHYSICS SECTION — IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. s and t) in Column II. C and D) given in Column I and five statements (p. Sol. against statement B. Any given statement in Column I can have correct matching with ONE or MORE statement(s) given in Column II. One mole of a monatomic ideal gas is taken through a cycle ABCDA as shown in the P-V diagram.r (C) – q. statement B matches with the statements given in q and r. Column II gives the characteristics involved in the cycle. (D) – r. Column I (A) Process A B (B) Process B C (C) Process C D (D) Process D A Ans. then for the particular question. if for a given question. 39. r. (t) RESONANCE J10411Page # 23 . For example. (A) – p.t . (B) – p. (r). (t) AB BC (p). t V P const d 0 PT d = du +d V T du +ve d = +ve dw –ve dq –ve du = 0 T U (p). B.

Column I (A) Pipe closed at one end Column II (p) Longitudinal waves (B) Pipe open at both ends (q) Transverse waves (C) Stretched wire clamped at both ends (r) f = L (D) Stretched wire clamped at both ends and at mid-point (s) f = 2L (t) f = 4L Ans.s. Column I shows four systems. (A) (A) – p. = 2L 2 String waves are =L String waves are transverse waves transverse waves (D) RESONANCE J10411Page # 24 . (B) – p. whose wavelength is denoted as f. for producing standing waves. = 4L.s. 4 Sound waves are longitudinal waves (B) = L . Sol. (D) – q. each of the same length L. = 2L 2 Sound waves are longitudinal waves (C) = L. ‘ The lowest possible natural frequency of a system is called its fundamental frequency.t .PHYSICS 40. (C) – q. r = L . Match each system with statements given in Column II describing the nature and wavelength of the standing waves.

3 i RESONANCE J10411Page # 25 . 0). 3) be a point on the hyperbola 1 .I (Total Marks : 24) (Single Correct Answer Type) This section contains 8 multiple choice questions. Sol. x2 a2 y2 b2 41. If the normal at the point P intersects the x-axis at (9. (B) (B) – i 3 (C) i 5 (D) 2 x 2 bx 1 0 x2 x b 0 Sol. (B). then the eccentricity of the hyperbola is (A) Ans. (C) and (D) out of which ONLY ONE is correct. Each question has four choices (A). 5 2 (B) (B) 3 2 (C) 2 (D) 3 Equation of normal at P(6. b2 = –3 b = 0. x x 1 b2 1 1 b 1 b x= b2 1 (b 1) (b 1) 1 b 2 (b2+1)(1–b) =(b+1)2 b2 –b3 + 1– b = b2 + 2b +1 b3 + 3b = 0 b = 0 .III SECTION . 1 b2 = a2 A value of b for which the equations x2 + bx – 1 = 0 x2 + x + b = 0 have one root in common is (A) – 2 Ans. 0) 3 2 a = a2 + b2 2 e= a2 b2 b2 3 = =1+ 2 2 2 a a 3 2 42.MATHEMATICS PART . Let P(6. 3) a2 x b2 y – = a2 + b2 6 3 It passes through (9.

then the value of is x 0 1 (A) ± Ans. 1 where each of a. Sol. g = 45. ].0) & (0. lim x 0 4 (D) (B) ± 3 (C) ± 6 (D) ± 2 xn(1 b2 ) e x = 1 + b2 = 2b sin2 sin2 = 1 b 1 b 2 RESONANCE J10411Page # 26 . ) number of non singular matrices = 2 44. 2 2 3 5 (C) . (A) a. c= 4 . Let 1 be a cube root of unity and S be the set of all non-singular matrices of the form 1 2 a b 1 c . b > 0 and (–. b. 2) also passes through the point 3 (A) . 2 2 (D) (–4. The circle passing through the point (–1. c {. b and c is either or 2. 2 . Sol. Then the number of distinct matrices in the set S is (A) 2 (B) 6 (C) 4 (D) 8 Ans. (D) Let equation of circle is x2 + y2 + 2gx + 2 fy + c = 0 as it passes through (-1. If lim 1 x ln(1 b 2 ) x = 2b sin2 .2) 1 – 2g + c = 0 and 4 + 4 f+ c =0 also f2 = c 5 2 equation of circle is x2 + y2 + 5x – 4y + 4 =0 which passes through (–4. 0) and touching the y-axis at (0. b. 0) f = –2. .MATHEMATICS 43. c) ( . 0) Ans. Sol. 2} 1 Let A = 2 a b 1 c 1 |A| = 1 – (a + c) + ac2 Now |A| will be non-zero only when a = c = (a. 0 2 5 (B) . ) or ( .

2]. where (f o g) (x) = f(g(x)).. n {0...} (D) 2n.. 0.MATHEMATICS We know b + 1 2 b but sin2 1 = ± sin2 1 sin2 =1 2 46. R2 = f ( x ) dx –1 2 and R1 = –1 xf ( x ) dx = –1 (1 – x)f (1 – x) dx 2 –1 = (1 – x )f ( x ) dx 47.. Then (A) R1 = 2R2 Ans. n {. x = 2. x = –1. ) be a continuous function such that f(x) = f(1 – x) for all x [–1. 2 Let R1 = 1 x f ( x) dx . (4n+1) sin x2 = 0 x2 = n x = n . Sol. 2... 1... 2. 1. n {. Let f : [–1. n W .} 2 (A) Ans. 2. R1 = R2 – R1 2R1 = R2 Let f(x) = x2 and g(x) = sin x for all x R. Then the set of all x satisfying (f o g o g o f) (x) = (g o g o f) (x)..} (C) (B) ± n . 1. and the x-axis. 2 (B) R1 = 3R2 (C) 2R1 = R2 (D) 3R1 = R2 (C) 2 Sol. g (x) = sin x gof (x) = sin x2 gogof (x) = sin (sin x2) (fogogof) (x) = (sin (sin x2 ))2 = sin2 (sin x2) Now sin2 (sin x2) = sin (sin x2) sin (sin x2) = 0.... is (A) ± n .... and R 2 be the area of the region bounded by y = f(x). –1..... 2 I RESONANCE J10411Page # 27 .} + 2n. –2. 2. 1 sin x2 = n. –1. f(x) = x2 .... 0. 2] [0.. n {1.–2.

4 then locus of P is x = y2 SECTION . . x 2 x 0 . (C) and (D) out of which ONE or MORE may be correct. 0) to (x. (B).II (Total Marks : 16) (Multiple Correct Answers Type) The section contains 4 multiple choice questions. C. y) in the ratio 1 : 3. (A) (A. x 2 If f(x) = cos x x 1 n x . D) at x = – 3 2 2 Lf – = 0 2 = f– 2 Rf – = 0 2 (B) (C) continuous at x = 0 Rf(0) = 1 Lf(0) = 0 not differentiable at x = 1 Rf(1) = 1 Lf(1) = 1 differentiable at x = 1 RESONANCE J10411Page # 28 .MATHEMATICS 48. Each question has four choices (A). y2 y P 16 . 49. Sol. y) be any point on the parabola y2 = 4x. . B. . Then the locus of P is (A) x2 = y (B) y2 = 2x (C) y2 = x (D) x2 = 2y Ans. Let P be the point that divides the line segment from (0. then 2 0 x 1 x 1 (A) f(x) is continuous at x = – 2 (B) f(x) is not differentiable at x = 0 (D) f(x) is differentiable at x = – (C) f(x) is differentiable at x = 1 Ans. Let (x. (C) Sol.

MATHEMATICS (D) at x = – 3 > – 2 2 f(x) = – cos x differentiable at x = – 3 2 50. Let E and F be two independent events. 25 1 2 . P(F) = 5 5 11 and the 25 2 . 4 3 ... (A.... P(F) = 5 5 3 4 .(3) P( E F ) by (2) 2 25 11 25 2 25 P(F) + P (E) – 2P (E F) = by (3) . 6).(4) 1 – [P(E) + P (F) – P (E F)] = [P(E) + P (F) – P (E F)] = by (4) & (5) and 23 25 12 25 .. P(F) = or P(E) = .... P(F) = 5 5 5 5 Let L be a normal to the parabola y2 = 4x. then L is given by (A) y – x + 3 = 0 (B) y + 3x – 33 = 0 (C) y + x – 15 = 0 (D) y – 2x + 12 = 0 Ans. B.(7) P (E) P (F) = P (E) + P (F) = 7 5 By (6) and (7) P(E) = 51.(5) .. P(F) = 5 5 (B) P(E) = (D) P(E) = (A. The probability that exactly one of them occurs is probability of none of them occurring is then (A) P(E) = (C) P(E) = Ans.(6) . D) RESONANCE J10411Page # 29 .. If P(T) denotes the probability of occurrence of the event T. P(F) P(E F ) + P( E F) = 11 25 . P(F) = 5 5 2 1 ... D) ... P(E F) = P(E) ... .... 4 3 3 4 .(2) . If L passes through the point (9..(1) Sol.

where b is a constant such that 0 < b < 1. then the solution is following a+b+c=x a + b + c2 = y a + b2 + c = z | x |2 | y |2 | z |2 |a| |b| |c | 2 2 2 i2 / 3 = xx yy zz | a | | b |2 | c |2 2 RESONANCE J10411Page # 30 . b. B) Sol. f(x) < 0 x (0. 1) R be defined by f(x) = (A) f is not invertible on (0. 3 | x | 2 | y |2 | z |2 is | a | 2 | b |2 | c |2 Sol. The answer to each of the questions is a single-digit integer. i 53. The bubble corresponding to the correct answer is to be darkened in the ORS. 1) and f(b) = f (0) (D) f–1 is differentiable on (0. b. 2. x. Let = e 3 . Then the value of Ans. 1) f(x) = 2 (bx 1) Range of f(x) is (–1. Let f : (0. Equation of normal is y = mx – 2m – m3 (9. c so lets assume = e . – 3 y=x–3 y = 2x – 12 y = – 3x + 33 bx . 1 b x b 1 b f(x) = = + bx 1 b (bx 1) 1 b b b. 1) 1 (B) f f–1 on (0. z be non-zero complex numbers such that a+b+c=x a + b + c2 = y a + b2 + c = z. 1) and f(b) = f (0) Ans. 6) satisfies it 6 = 9m – 2m – m3 m3 – 7m + 6 = 0 m=1 m=2 m=–3 m = 1. Then 1 bx 52. ranging from 0 to 9). c. 1) 1 (C) f = f–1 on (0. On taking = e i / 3 expression is in terms of a.MATHEMATICS Sol. and a. y. b) so range co-domain so f is not invertible SECTION . (A.III (Total Marks : 24) (Integer Answer Type) This section contains 6 questions.

y (0) = 0 x R d (y(x)) + y (x) g (x) = g(x) g(x).I. 0 y(x) + y (x) g(x) = g(x) g(x). f(x) = x4 – 4x3 + 12x2 + x – 1 f(x) = 4x3 – 12x2 + 24x + 1 f(x) = 12x2 – 24x + 24 = 12 (x2 – 2x + 2) > 0 xR f(x) is S. function Let is a real root of the eqution f(x) = 0 f(x) is MD for x (– . 2 Sol. y(0) = 0. Sol. for x (. The number of distinct real roots of x4 – 4x3 + 12x2 + x – 1 = 0 is Ans. df ( x ) and g(x) is a given nondx constant differentiable function on R with g(0) = g(2) = 0. ) where < 0 f(0) = – 1 and < 0 f() is also negative f(x) = 0 has two real & distinct roots. Let y(x) + y(x) g(x) = g(x) g(x). x R .MATHEMATICS = (a b c ) ( a b c ) (a b c2 ) ( a b 2 c ) (a b 2 c) ( a b c2 ) | a |2 | b |2 | c |2 = 3 ( | a |2 | b |2 | c |2 ) | a |2 | b |2 | c |2 =3 54. Then the value of y(2) is 55. dx g (0) = g(2) = 0. where f(x) denotes Ans.I.. ) and M. I·F = e g( x )dx = eg(x) y (x) eg(x) = Let g(x) = t g(x) dx = dt y(x) eg(x) = e te t g( x ) g( x )g( x ) dx + c t dt = te – et + c y(x) = (g(x)–1) + c e–g(x) Let x =0 y(0) = (g(0)–1) + c e–g(0) 0 = (0–1) + c c =1 y (x) = (g(x) –1) + e–g(x) y(2) = (g(2)–1) + e–g(2) y (2) = (0 –1) + e–(0) = –1 + 1 = 0 RESONANCE J10411Page # 31 .

9 a13 a 23 a 33 1 1 1 = 1 . 2x – 3y = 1. III. The straight line 2x – 3y = 1 divides the circular region x2 + y2 6 into two parts. . IV) will lie on the P region if (0. then the number of point(s) in S lying inside the smaller part is Sol. a 0 . a11 a12 Let M = a 21 a 22 a 31 a 32 then a12 = –1. 8 . a32 = 3 . . and M 0 1 1 0 1 = 0 . 4 . IV will lie inside the circle and point (I. a =0 ( c + b ) . then the value of r . a = 0 R ˆ ˆ ˆ ˆ (( ˆ i + 2 j +3 k ) + (– ˆ i + j )) . Then the sum of the diagonal entries of M is 1 12 Sol. x2 + y2 6 3 5 3 1 1 1 1 S 2.MATHEMATICS 56. ˆ be three given vectors. 4 . 0) and the given point will lie opposite to the line 2x – 3y – 1 = 0 RESONANCE J10411Page # 32 . a31 = 2. . b is Ans. . . If r is a vector such that ˆ . . a11 – a12 = 1 a21 – a22 = 1 a31 – a32 = 1 a11 = 0. 4 . 4 . (– ˆ i –k ) = 0 –1–3=0 =4 ˆ ˆ ˆ so r . 2 . (r c ) b = 0 r – c = b r = c + b r.M 0 3 Ans. 3 5 3 1 1 1 1 If S = 2. b = ( – 3 ˆ i +6 j +3 k ) . a22 = 2 . a11 + a12 + a13 = 0 a13 = 1 a21 + a22 + a23 = 0 a23 = –5 a31 + a32 + a33 = 12 a33 = 7 Hence sum of diagonal of M is = a11 + a22 + a33 = 0 + 2 + 7 = 9 57.(– ˆ i –k ) = 0 ˆ ˆ ˆ ((1 – ) ˆ i +(2+) j + 3 k ) . III. (– ˆ i+j ) =3+6=9 58. b ˆ Let a ˆ iˆ j and c ˆ i 2ˆ j 3k i k r b c b and r . Let M be a 3 × 3 matrix satisfying 0 1 1 2 M = . 9 Sol. a21 = 3. 4 2 4 4 4 8 4 ( ) ( ) ( ) ( V ) Plot the two curves I. 4 .

P 2. = positive. q. 1 3 (C) (s). then the value of f is 6 5/6 (q) 2 3 3 (C) 2 The value of ln 3 7/6 sec (x) dx is (r) (D) 1 The maximum value of Arg 1 z for |z| = 1. r. and . but it will not lie in the given circle 2 4 1 3 1 so point 2. If a ˆ j 3k j 3k 2 3k then the internal angle of the triangle between a and b is b (p) 6 (B) If (f ( x ) 3x ) dx a = a2 – b2. against statement B. P . 0) = negative.IV (Total Marks : 16) (Matrix-Match Type) This section contains 2 questions. Any given statement in Column-I can have correct matching with ONE or MORE statement(s) given in Column-II. then for the particular question. b ˆ ˆ and c ˆ form a triangle. 59. (D) (t) Sol. = negative 8 4 1 3 1 so two point 2. (B) (p). (A) a . Each question has four statements (A. C and D) given in Column-I and five statements (p. satisfy S1 < 0 4 4 4 SECTION . B. statement B matches with the statements given in q and r. = positive . For example.MATHEMATICS 1 1 3 P(0. 4 4 4 1 3 1 Further 2. Match the statements given in Column-I with the values given in Column-II Column-I Column-II (A) ˆ . if for a given question. s and t) in Column-II. (A) (q). z 1 is given by (s) (t) 2 Ans. and . darken the bubbles corresponding to q and r in the ORS. will lie on the opp side of the line 4 4 4 1 1 . = positive P 4 4 4 5 3 P . and .b cos( – ) = = | a| | b | – cos = = 2 3 1 3 1 3 = 2 4 1 2 RESONANCE J10411Page # 33 .

z lies on circle – z lies on circle 1 – z lies on circle max |arg (1 – z)| = 2 RESONANCE J10411Page # 34 . radius 1 1 = Arg 1 – Arg (1 – z) = angle between OA and BA Arg 1 z Absolute value of angle between OA and BA tends to Alter # 1 as B tends to A.e. 2 1 arg = |arg 1 – arg (1 – z)| = |arg (1 – z)| 1 z as |z| = 1 i.MATHEMATICS (B) Using Leibeintz Theorem f(b) – 3b = – 2b f(b) = b 2 n | sec x tan x | 2 (sec x ) dx = n3 7 / 6 n3 7 / 6 5/6 5/6 (C) n 2 = n3 (D) 2 1 2 1 n 3 3 3 3 3 3 n 1 3 2 = = n3 z (z 1) lies on circle with center 0.

| z | 1. ) RESONANCE J10411Page # 35 . 0) (0. ) 1 (C) If f() = tan 1 tan 1 tan 1 . ) 2iz The set Re : z is a complex number . ) tan 1 (D) then the set f ( ) : 0 is 2 If f(x) = x3/2 (3x – 10). (r) [2. ) Ans. Match the statements given in Column-I with the intervals/union of intervals given in Column-II Column-I (A) Column-II (p) (–. (B) (t). then f(x) is increasing in (s) (t) (–. (C) (r). ) (–. –1) (1. –1] [1. 0] [2. z 1 is 2 1 z The domain of the function f(x) = sin–1 (B) 8(3) x 2 1 3 2( x 1) is (q) (–. x 0. (D) (r) Sol. (A) 2y 2ix 2i ( x iy ) = Re Re 1 x 2 y 2 2xyi) 1 ( x 2 y 2 2xyi) 1 1 = –1 y 1 = y 1 or y – 1 Alternate 2ie i 2i(cos i sin ) Re 2i = Re 1 (cos 2 i sin 2 ) 1 e 2y 2ix 1 = Re 2y ( y ix ) = Re (–1/y) = y i (cos i sin ) 2i(cos i sin ) = Re = Re sin (sin i cos ) = Re 2 sin2 2i sin cos ) 1 = Re sin (cos i sin ) sin (cos i sin ) as –1 sin 1 (– . 0 ) (0.MATHEMATICS Alter # 2 z = ei 1 1 1 1 1 = = +i cot sin i cos = 2 2 2 2 1 z 2 2 2 sin i sin 2 sin 2 2 Locus is 1 1 is x = 1 z 2 2 Maximum value of tends to 60. (A) (s).

) f() = 2 sec2 f() 2 f() [2. 3 x 2 –1 (B) 1 3 2x 2 1 8t 8t –1 9 t2 1 8t –1 1 9 t2 t 2 8t 9 t 9 2 8t 9 t 2 9t 2 0 9 t 2 8t 9t 2 9 t2 – 1 0 0 0 ( t 9) ( t 1) ( t 9) ( t 1) 0 ( t 3) ( t 3) ( t 3) ( t 3) 0 (C) t (– . 1] [9. ) x (– . ) RESONANCE J10411Page # 36 . –9] [–1 . 0) [2 . ) f(x) = x3/2 (3x – 10) f ’(x) = x3/2 3 + (D) 3 1/2 x (3x –10) 2 asf ’(x) 0 3 x1/ 2 3 x (3 x 10 ) 0 2 3x + 9x – 15 0 2 15 x – 15 0 2 x 2 x [2.MATHEMATICS 8.

Name of the Candidate Roll Number I have read all the instructions and shall abide by them. -------------------------------Signature of the Invigilator RESONANCE J10411Page # 37 . -------------------------------Signature of the Candidate I have verified all the information filled in by the Candidate.

K3[Fe(CN)6] (K). (C) and (D). : Among the following complexes (K – P). O (C) K3Fe(CN)6 is paramagnetic [Ni(H2O)6]Cl2 is paramagnetic too. 1. O.67 V Ecell = E cell 2. M.57 Volt. Key.0591 106 log 13 4 10 0. N (B) K.0591 log 4 n O2 H 2 2 103 0. The major product of the following reaction is RCH 2 OH H anhydrous Key.67 – 7 = 1. Each question has four choices (A). : Sol. N. : Sol. P (C) L. O. : Sol.67 V At [Fe2+] = 10-3M.67 – 4 1 4 10 103 0. 4 = 1.0591 log = 1. Key.1 atm and pH = 3. M. Na3[Co(oxalate)3] (M). Consider the following cell reaction : 2Fe (s) + O2(g) + 4H+ (aq) 2Fe2+ (aq) + 2H2O (l) E° = 1. M. out of which ONLY ONE is correct.57 V (D) 2Fe(s) O 2 g 4H 2Fe 2 aq 2H 2 O E° = 1.IIT – JEE (2011) PAPER II QUESTION & SOLUTIONS PART I : CHEMISTRY PAPER – II SECTION – I(TOTAL MARKS: 24) (Single Correct Answer Type) CODE 0 This section contains 8 multiple choice questions. K2[Pt(CN)4] (O) and [Zn(H2O)6](NO3)2 (P) the diamagnetic complexes are (A) K.77 V (C) 1.566 1. P (D) L. L.87 V (D) 1. the cell potential at 25°C is (A) 1. [Co(NH3)6]Cl3 (L). [Ni(H2O)3]Cl2 (N).0591 = 1. : Fe2 0. (B).67 – 3. P(O2) = 0. : O (A) a hemiacetal (C) an ether (B) (B) an acetal (D) an ester H RCH 2 OH O O O Acetal NARAYANA IIT ACADEMY OCH2 R 3 .47 V (B) 1. M.

86 0. 329) in 100 g of water (Kf = 1.0226 = 2. : Sol.2 × 10-2 (A) Tf = i × kf × m W 1000 = i kf B M B WA = 4 1. : (C) Azo dye test is given by Aromatic 1° amine NH2 NaNO2 HCl 0 5 C N NCl OH H3C N N OH napthol H3C H3C Red azo dye 7. Wt. respectively are (A) II. Key. (A) NH2 (B) CH2 NH2 (C) H3C (D) Key. : Sol.3 × 10-2.1 g of K3[Fe(CN)6] (Mol. III in magnetite (D) III in haematite and II.86 K kg mol-1) is (A) – 2. III in magnetite (C) Formula Oxidation state of Fe Haematite Fe2O3 +3 Magnetile Fe3O4 (FeO + Fe2O3) +2. Key: Sol. HCl followed by addition to an alkaline solution of -naphthol is N(CH3 )2 NHCH3 5.26 × 10-2 2.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 4. Ni2+. Key. +3 Amongst the compounds given. 8.: The freezing point (in °C) of a solution containing 0. Hence CuS and HgS will be precipitated out even in acidic medium by passing H2S gas.7 × 10-2 -2 (C) – 5.3 × 10-2 (B) – 5. Oxidation states of the metal in the minerals haematite and magnetite. the one that would from a brilliant colored dye on treatment with NaNO2 in dil.1 1000 329 100 = 0.3 × 10-2 Freezing point = – 2. Cu2+ and Hg2+ ions in an acidified aqueous solution precipitates (A) CuS and HgS (B) MnS and CuS (C) MnS and NiS (D) NiS and HgS (A) Cu2+ & Hg2+ ions belong to Group – II of salt analysis & their sulphides are very less soluble.: Sol. III in haematite and II in magnetite (C) II in haematite and II. The following carbohydrate is H HO HO H 4 OH H H O OH OH H NARAYANA IIT ACADEMY . III and haematite and III in magnetite (B) II. : Passing H2S gas into a mixture of Mn2+. : 6.7 × 10 (D) – 1.

The correct functional group X and the reagent / reaction condition Y in the following scheme are X CH 2 4 X condensation polymer O i Y ii O C HO (CH 2) 4 heat C OH Key. Y = H2/ Ni / heat (D) X = CN. NARAYANA IIT ACADEMY 5 . B. SECTION – II (TOTAL MARKS: 16) (Multiple Correct Answer(s) Type) 9. C. 10. : (A) X = COOCH3. : Sol. Y = Br2 / NaOH (A. D) The equilibrium constant for the reaction Cu Cu 2 is high enough to keep it largely towards right. (C) and (D). Y = H2 / Ni/ heat H3C (B) O O C (CH2 )4 O C C H 2 / Ni OCH3 CH 3 OH HO CH 2 CH 2 4 CH 2 OH H2 N (C) C (CH2 )4 NH2 H 2 / Ni NH 2 CH 2 6 NH 2 O H2 N C (CH2 )4 O C NH2 Br2 / NaOH NH 2 CH 2 4 NH 2 (D) NC (CH 2 ) 4 CN H 2 / Ni NH 2 CH 2 6 NH 2 Diamines give polyamides with dicarboxylic acids Similarly di-ols give polyester with dicarboxylic acid. out of which ONE OR MORE may be correct. (A) a ketohexose (C) an -furanose (B) OH H (B) an aldohexose (D) an . This section contains 4 multiple choice questions. Y = H2 / Ni / heat (C) X = CONH2. D) O O (A) (B) X = CONH2.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Key. The equilibrium Cu Cu|| 2Cu| In aqueous medium at 25°C shifts towards the left in the presence of (A) NO3 (B) Cl (D) CN Key. Each question has four choices (A). : (C) SCN (B. : Sol. C. (B). CuCn and CuSCN are insoluble cuprous salt. The Cu+ will exist in water with 2Cu stability when either present as complexes or as insoluble salt CuCl.pyransose H HO HO H O OH OH H H is an aldohexose. : Sol.

(C) the half-life of the reaction depends on the initial concentration of the reactant. SECTION – III (TOTAL MARKS: 24) (Integer Answer Type) 13. D) (B) 5 electrons in neutral medium (D) 5 electrons in acidic medium 8H 5e MnO Mn 2 4H 2 O 4 2H 2 O 3e MnO MnO2 4OH 4 2H 2 O 3e MnO MnO2 4OH 4 This Section contains 6 questions. (D) the reaction proceeds to 99. Key. : The number of hexagonal faces that are present in a truncated octahedron is 6 The truncated octahedron is an Archimedean solid with 14 faces out of which 8 faces are hexagonal and rest 6 faces are square shaped. 12.39 28 256 % reacted = 100 – 0.39 = 99. (B) the half-life of the reaction decreases with increasing temperature. ranging from 0 to 9. : (A. : Sol. N 2 O5 n2 K With temperature ‘K’ increases and therefore t 1/2 decreases At the completion of 8 half lives Remaining % = 1 1 100 100 = 0. For the first order reaction 2N2O2 (g) 4NO2 (g) + O2 (g) (A) the concentration of the reactant decreases exponentially with time. Key. 6 NARAYANA IIT ACADEMY . Reduction of the metal centre in aqueous permagnate ion involves (A) 3 electrons in neutral medium (C) 3 electrons in alkaline medium Key. : Sol. B. C. The answer to each question is a Single-digit integer.6% completion in eight half-life diration.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 11. : (A.61 %. : Sol. The bubble corresponding to the correct answer is to darkened in the ORS. D) First order reaction : Half life period : t1/2 = d N 2 O5 dt K.

0 10-6 = y (x + y) from equation (i) and (ii) . : Ag+ + Cl AgCl(s) x x Cu+ + Cl CuCl(s) y y Net Cl in solution = (x + y) ksp AgCl = 1. .(i) .6 1010 1. Key. 0. the reaction is more gentle and yields POCl3) PCl5 + SO2 POCl3 + SOCl2 PCl5 + P4O10 10 POCl3 PCl5 + H2SO4 POCl3 + HSO2Cl + HCl chlorosulphonic acid 2PCl5 + H2SO4 SO2 Cl2 + 2POCl3 + 2HCl sulphuryl chloride 16. : Sol. .6 putting the value of y in eq. . : 6 H3 C + C CH2 CH3 H = 6 contributing hyper conjugating structure = 6 15. P4O10 5 CO2 + PCl5 POCl3 + COCl2 PCl5 + H2O POCl3 + 2 HCl (if equi molar amounts are used.6 NARAYANA IIT ACADEMY 7 .6 × 10-10]. In 1 L saturated solution of AgCl [Ksp (AgCl) = 1. . the number of compounds than can react with PCl5 to give POCl3 is O2. H2O.6 104 y y 104 x 1.6 × 10-x. : Sol. The resultant concentration of Ag+ in the solution is 1. The total number of contributing structures showing hyperconjugation (involving C – H bonds) for the following carbocation is CH2 CH3 Key. . x x 1.0 × 10-6] is added. H2SO4.1 mole of CuCl [Ksp (CuCl) = 1. : Sol.0 10-6 = [Cu+][Cl] 1. The value of “x” is 7 Key. (i) 104 x.6 10-10 = [Ag+] [Cl] = x (x + y) x(x + y) = 1. : Among the following.6 10-10 ksp of CuCl = 1. . CO2. SO2.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II H3C 14. . (ii) x 1.

q.1 1 V = 0. of AgNO3 reacted = milli equivalent of [Cr(H2O)5Cl]Cl2 reacted thus (M n V) AgNO3 (M n V)[Cr(H2O)5 Cl]Cl2 0. if for a given question.6 10-7 17. : 104 1.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II x2 x2 = (1. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. The maximum number of isomers (including stereoisomers) that are possible on mono-chlorination of the following compound.1 M AgNO3 required for complete precipitation of chloride ions present in 30 mL of 0. : Sol. 8 Match the reactions in Column I with appropriate types of steps / reactive intermediate involved in these reactions as given in Column II NARAYANA IIT ACADEMY . and ‘D’ has one therefore total product will be 8 This section contains 2 questions. Key.6 The volume (in mL) of 0. then for that particular question. B.6)2 10-14 x = 1. ‘B’ has 4. ‘C’ has 1. darken the bubbles corresponding to q and r in the ORS. Each question four statements (A. 8 H: 3C CH2 CH CH3 CH2 CH3 + Cl2 Monochlorination CH2 Cl CH2 CH CH3 (1 chiral) (A) H CH2 CH3 * CH2 CH3 Cl H3C CH Cl * CH * CH2 CH3 H3C CH2 C CH2 CH3 CH3 (2 chiral carbon) (B) CH3 (no chiral carbon) (C) H3C CH2 CH CH2 CH3 CH2 Cl (no chiral carbon) (D) Thus ‘A’ has two structures. SECTION – IV (TOTAL MARKS: 16) (Matrix-Match Type) 19. is CH3 C CH3 CH2 Key.01 M solution of [Cr(H2O)5Cl]Cl2. s and t) in Column II.6 1010 1. against statement B. For example. as silver chloride is close to 6 2AgNO3 + [Cr(H2O)5Cl] Cl2 2AgCl + [Cr(H2O)5Cl](NO3)2 milli equivalent . statement B matches with the statements given in q and r. C and D) given in Column I and five statements (p. : Sol. r.01 2 30 V=6 18.

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

Column I (A)

H3C O

O

O

(p)

Column II Nucleophilic substitution

aq. NaOH

(B)

**O O CH2 CH2 CH2 Cl
**

CH3 MgI

(q)

Electrophilic substitution

CH3

18

(C)

O

18

(r)

Dehydration

**O CH2 CH2 CH2 OH
**

H 2 SO 4

(D)

CH2 CH2 CH2

C (CH3 )2 OH

H 2SO4

(s)

Nucleophilic

H3C

CH3

**(t) Key: Sol. (A –r,s,t); (B–p,s,t); (C–r,s); (D–q,r) :
**

C O H2 C O NuAddition O OH

Carbanion

O

-H2O

O CH2 CH2 CH2 Cl Nu- addition CH3 MgI (source of carbanion)

O CH2 CH2 CH2 CH3 Cl

SNi

O

CH3

NARAYANA IIT ACADEMY

9

**IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II
**

+

H H CH2

18

O C

HO C CH2

+ 18 O

+O

H CH2

18

C IMPE

: O:

H

O

H

18

+

O

C

H2O H+,

CH2

18

O

CH2 CH2 CH2 C(CH3 )2

H2SO4

**CH2 CH2 CH2 C(CH3 )2
**

+

OH H

OH -H2O

EAS

+

H3C

CH3

H3C

CH3

20.

Match the transformations in Column I with appropriate options in column II Column I (A) CO2 (s) CO2 (g) (B) CaCO3 (s) CaO (s) + CO2 (g) (C) 2H H2 (g) (D) P(white, solid) P(red, solid) (p) (q) (r) (s) (t) Column II Phase transition Allotropic change H is positive S is positive S is negative

Key: Sol.:

(A –p,r,s); (B–r,s); (C–t); (D–q,r,t) (A) CO2(s) + Q CO2 (g)

(B) (C)

(D)

H = +ve , phase transition and S = +ve CaCO3(s) + Q CaO (s) + CO2(g) H = +ve, S = +ve 2H0 H2 (g) two particle give one gaseous particle S = -ve Pwhite , solid Pred, solid H = +ve, S = +ve, allotropic change

10

NARAYANA IIT ACADEMY

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

**PART II : PHYSICS SECTION – I(TOTAL MARKS: 24) (Single Correct Answer Type)
**

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of which ONLY ONE is correct.

21.

Key: Sol.:

A satellite is moving with a constant speed V in a circular orbit about the earth. An object of mass m is ejected from the satellite such that it just escapes from the gravitational pull of the earth. At the time of its ejection, the kinetic energy of the object is 1 (A) (B) mV2 mV 2 2 3 (C) (D) 2mV2. mV 2 2 (B) At the time of ejection ETotal = 0 GMm Total Kinetic Energy = ETotal – P.E. = r = mV2 A point mass is subjected to two simultaneous sinusoidal displacements in x–direction, x1 (t) A sin t and

22.

Key: Sol.:

2 x 2 (t) A sin t . Adding a third sinusoidal displacement x 3 (t) Bsin(t ) brings the mass to a 3 complete rest. The value of B and are 3 4 2A, (A) (B) A, 4 3 5 (C) (D) A, . 3A, 6 3 (B) x1+x2 x2 x1 + x2 = Asin(t + /3) 4 x1 + x2 + x3 = 0 x3 = A sin t 2/3 3 4/3 x1

x3

23. The density of a solid ball is to be determined in an experiment. The diameter of the ball is measured with a screw gauge, whose pitch is 0.5 mm and there are 50 divisions on the circular scale. The reading on the main scale is 2.5 mm and that on the circular scale is 20 divisions. If the measured mass of the ball has a relative error of 2%, the relative percentage error in the density is (A) 0.9% (B) 2.4% (C) 3.1% (D) 4.2%. (C) 0.5mm 1 Least count of screw gauge = = mm. 50 100 1 Diameter D = 2.5 + 20 = 2.7 mm 100 m Now, density 3 4 D 3 2

Key: Sol.:

NARAYANA IIT ACADEMY

11

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

24.

% error in density =

m D 100 3 100 = 3.1%. m D

Key: Sol.:

A long insulated copper wire is closely wound as a spiral of N turns. The spiral has inner radius a and outer radius b. The spiral lies in the X–Y plane and a steady current I flows through the wire. The Z–component of the magnetic field at the centre of the spiral is 0 NI 0 NI b ba (A) (B) n n 2(b a) a 2(b a) b a NI NI b ba (C) 0 n (D) 0 n . 2b a 2b ba (A) N dN = dr ba N 0 Idr b N 0 I b ba B= ln a 2r 2b a a

Y

I b

a X

25.

A light ray traveling in glass medium is incident on glass air interface at an angle of incidence . The reflected (R) and transmitted (T) intensities, both as function of , are plotted. The correct sketch is

100%

100%

Intensity

Intensity

(A)

T R 90º

T R 90º

(B)

0

100%

0

100%

Intensity

T

(D)

Intensity

0

T R 90º

(C)

R

Key: Sol.:

90º (C) For 0 c there will be little reflection For c there will be no transmission.

0

26.

Key: Sol.:

A ball of mass 0.2 kg rests on a vertical post of height 5 m. A bullet of mass 0.01 kg traveling with a velocity V m/s in a horizontal direction, hits the centre of the ball. After the collision, the ball and bullet travel independently. The ball hits the ground at a distance 20 m and the bullet at a distance of 100 m from the foot of the post. The initial velocity of the bullet is (A) 250 m/s (B) 250 2 m/s (C) 400 m/s (D) 500 m/s. (D)

V m/s

0 20

100

25 = 1s 10 COM v 0.01 0.2 20 0.01 100 v = 500 m/s t

12

NARAYANA IIT ACADEMY

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

27.

Which of the field patterns given below is valid for electric field as well as for magnetic field ?

(A)

(B)

(C)

(D)

Key: Sol.:

(C) In case of non-conservative electric field, lines as shown in (C) are possible. Also, in case of toroid, magnetic field lines are circular A wooden block performs SHM on a frictionless surface with frequency, E v0. The block carries a charge +Q on its surface. If now a uniform electrical +Q field E is switched on as shown, then the SHM of the block will be (A) of the same frequency and with shifted mean position (B) of the same frequency and with the same mean position (C) of changed frequency and with shifted mean position (D) of changed frequency and with the same mean position. (A) An additional constant force will not change the frequency but will shift the mean position.

28.

Key: Sol.:

This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D), out of which ONE OR MORE may be correct.

SECTION – II (TOTAL MARKS: 16) (Multiple Correct Answer(s) Type)

29.

A series R–C circuit is connected to AC voltage source. Consider two cases; (A) when C is without a dielectric medium and (B) when C is filled with dielectric of constant 4. The current IR through the resistor and voltage VC across the capacitor are compared in the two cases. Which of the following is/are true ? B B (A) I A (B) I A R IR R IR

A B (C) VC VC (B, C) A B (D) VC . VC

Key: Sol.:

Z R2

1 c B A B zA > z B I A R I R and v C v C

2 2

30.

Key:

A thin ring of mass 2 kg and radius 0.5 m is rolling without slipping on a horizontal plane with velocity 1 m/s. A small ball of mass 0.1 kg, moving with velocity 20 m/s in the opposite direction, hits the ring at a height of 0.75 m and goes vertically up with velocity 10 m/s. Immediately after the collision (A) the ring has pure rotation about its stationary CM (B) the ring comes to a complete stop (C) friction between the ring and the ground is to the left (D) there is no friction between the ring and the ground. (C)

NARAYANA IIT ACADEMY

10m/s 20 m/s 0.75 m

1m/s

13

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

Sol.:

Assuming friction to be absent at point of contact (to check the tendency of sliding), we find that under the impulsive forces shown in figure, the point of contact moves to the right hence friction will act towards left.

F dt

Jx= 2 Ns

Jy= 1 Ns

31. Which of the following statement(s) is/are correct ? (A) if the electric field due to a point charge varies as r–2/5 instead of r–2, then the Gauss law will still be valid (B) the Gauss law can be used to calculate the field distribution around an electric dipole (C) if the electric field between two point charges is zero somewhere, then the sign of the two charges is the same (D) the work done by the external force in moving a unit positive charge from point A at potential VA to point B at the potential VB (VB – VA). (C, D) Q E ds f r enc If E r–2.5 then 0 sphere (A) is incorrect. As field of an electric dipole is not symmetric,

Key: Sol.:

E ds

is incalculable

(B) is incorrect. In case of similar charges, null point is between the two charges. (C) is correct. Wext = q(VB – VA) (D) is incorrect. 32. Two solid spheres A and B of equal volumes but of different densities dA and dB are connected by a string. They are fully immersed in a fluid of density dF. They get arranged into an equilibrium state as shown in the figure with a tension in the string. The arrangement is possible only if (A) dA < dF (B) dB > dF (C) dA > dF (D) dA + dB = 2 dF. (A, B, D) For equilibrium of system V(dA + dB)g = 2V dF g

A B

Key: Sol.:

A

B

This Section contains 6 questions. The answer to each question is a Single-digit integer, ranging from 0 to 9. The bubble corresponding to the correct answer is to darkened in the ORS.

SECTION – III (TOTAL MARKS: 24) (Integer Answer Type)

14

NARAYANA IIT ACADEMY

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

33.

Water (with refractive index

4 ) in a tank is 18 cm deep. Oil of 3

S =1.0 R=6 cm

Key: Sol.:

7 refractive index lies on water making a convex surface of radius of 4 curvature R = 6 cm as shown. Consider oil to act as a thin lens. An object S is placed 24 cm above water surface. The location of its image is at x cm above the bottom of the tank. Then x is 2 Refraction at air-oil boundary

=4/3

7 / 4 1 7/4 1 V1 24 6

7 1 1 1 3 1 4V1 24 8 24 12 7 12 V1 21cm 4

Refraction at oil-water boundary

**4/3 7/4 4 1 0 V 21 3V 12 4 1 4 12 V 16cm 3V 12 3
**

x = 2 cm 34. A silver sphere of radius 1 cm and work function 4.7 eV is suspended from an insulating thread in free– space. It is under continuous illumination of 200 nm wavelength light. As photoelectrons are emitted, the sphere gets charged and acquires a potential. The maximum number of photoelectrons emitted from the shphere is A × 10Z (where 1 < A < 10). The value of Z is 7

Key: Sol.:

E

**hc 1242 6.21eV 200 1 ne V 4 0 r
**

E eV

When emission will stop then

** 1.51 1.6 1019 102 1.5 102 1.51 15.1 n 108 107 10 1.6 9 10 1.6 9 16 9 z= 7
**

35. A train is moving along a straight line with a constant acceleration a. A boy standing in the train throws a ball forward with a speed of 10 m/s, at an angle of 60º to the horizontal. The boy has to move forward by 1.15 m inside the train to catch the ball back at the initial height. The acceleration of the train, in m/s2 is 5

n 1.6 1019

2

9 109

Key: Sol.:

u y 10sin 60 5 3 m/s

t

2u y g

25 3 3s 10

NARAYANA IIT ACADEMY

15

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II

1 Sx u x t a x t 2 2 1 1.15 5 t a t 2 2 3 1.15 5 3 a 2 3a 5 1.73 1.15 8.65 1.15 2 3a 7.5 2 15 a 5 m/s2 3

36. Two batteries of different emfs and different internal resistances are connected as shown. The voltage across AB in volts is

A

6V 3V

1 2

B

Key: Sol.:

5

I

63 1A 3

+

I 6V A

+

1 B 2

VA 3 2 1 VB VAB 5 V

37. A block of mass 0.18 kg is attached to a spring of force–constant 2 N/m. The coefficient of friction between the block and the floor is 0.1. Initially the block is at rest and the spring is un–stretched. An impulse is given to the block as shown in the figure. The block slides a distance of 0.06 m and comes to rest for the first time. The initial velocity of the block in m/s is V = N/10. Then N is 4 Work done by friction

3V

Key: Sol.:

mgx 0.1 0.18 10 0.06 108 10 4

= 36×10–4

1 2 1 1 2 mv 108 104 kx 2 2 0.06 2 2 2

**0.09v 2 144 104 12 4 v 101 3 10
**

N=4 38. Key:

16

A series R–C combination is connected to an AC voltage of angular frequency = 500 radian/s. If the impedance of the R–C circuit is R 1.25 , the time constant (in millisecond) of the circuit is 4

NARAYANA IIT ACADEMY

Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. Each question four statements (A. r. t NARAYANA IIT ACADEMY 17 . Column I Pipe closed at one end (A) (B) Column II Longitudinal waves (p) 0 Pipe open at both ends L (q) Transverse waves (C) 0 L Stretched wire clamped at both ends 0 L Stretched wire clamped at both ends and at mid–point (r) f = L (D) (s) f = 2L 0 L/2 L (t) Key: Sol. (C–q. Match each system with statements given in Column II describing the nature and wavelength of the standing waves. Column I shows four systems. for producing standing waves. The lowest possible natural frequency of a system is called its fundamental frequency whose wavelength is denoted as 1. B. q.: 5 4 R C ~ 5 2 R 2 XC R2 4 R 2 XC 2 R 2 C R 2 2 RC R R 2 4 103 4ms 500 This section contains 2 questions. against statement B. s and t) in Column II.r) (A) f = 4L 1 L 1 4L 4 Longitudinal wave A – p. C and D) given in Column I and five statements (p. (B–p. SECTION – IV (TOTAL MARKS: 16) (Matrix-Match Type) 39. each of the same length L. statement B matches with the statements given in q and r.s).IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 2 Z R 2 XC R Sol.s). then for that particular question. if for a given question.t). darken the bubbles corresponding to q and r in the ORS. (D–q.: (A –p. For example.

Key: Sol. s (D) 1 1 L 1 L 2 2 Transverse wave D. Each question has four choices (A). (D–r. Match them with each of the processes given in Column I. r C.: 18 A value of b for which the equations x2 + bx .. 41. (B–p.i 3 (D) 2 NARAYANA IIT ACADEMY .r. t B. out of which ONLY ONE is correct. r. One mole of a monatomic ideal gas is taken through a cycle ABCDA as shown in the P–V diagram. (ii) (B) .t) (A) Volume decreases Temperature decreases (B) Pressure decreases Temperature decreases (C) Volume increases Temperature increases (D) A. s PV P 9V 9PV TD nR nR nR 3P 3V 9PV TA nR nR D – r.1 = 0 x2 + x + b = 0 have one root in common is (A) 2 (C) i 5 (B) x2 + bx . s (C) 1 L 1 2L 2 Transverse wave C. t PART I : MATHEMATICS SECTION – I(TOTAL MARKS: 24) (Single Correct Answer Type) This section contains 8 multiple choice questions. Column II gives the characteristics involved in the cycle. P 3P B A 1P C 0 1V 3V D 9V V (A) (B) (C) (D) Key: Sol. (C) and (D)... r 40.t).q.q. (B). (i) x2 + x + b = 0 ..1 = 0 .s).p.p.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II (B) 1 L 1 2L 2 Longitudinal wave B – p.: Column I Process A – B Process B – C Process C – D Process D – A (p) (q) (r) (s) (t) Column II Internal energy decreases Internal energy increases Heat is lost Heat is gained Work is done on the gas. (C–q. (A –p.q.r).

0) and touching the y-axis at (0. -1. 1. .(g(f(x)))) = g. 2) will be (x .(ii) gives x = Putting x in (ii) 2 b 1 which is the common root b 1 b 1 b 1 +b=0 b 1 b 1 b3 + 3b = 0 b(b2 + 3) = 0 b = 0.. Key: Sol. 3 i. 2.. } (B) n .. . n {1. is (A) n . -1.4y + 4 = 0 Also passes through (-4. (–1. b2 = -3 b= 3i b=42. 0) 2 2 (D) Equation of family of circle touching y-axis at (0. Key: 1 Let 1 be a cube root of unity and S be the set of all non-singular matrices of the form 2 where each of a. -2. 0). 2. (g. 2.} 2 (A) f(x) = x2. 0) 1+4-=0 =5 Equation of circle is x2 + y2 + 5x . n {0.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II (i) . 2) also passes through the point 3 5 (A) . } 43.. 1.. and c is either or 2. Let f(x) = x2 and g(x) = sinx for all xR.(g.(g. 2. 1 NARAYANA IIT ACADEMY 19 . } (C) 2n ..(g...1] = 0 sin (sin (x2)) = 0 [or.. 2 2 2 3 5 (C) .0 (B) .(f(x)) (sin (sin (x2)))2 = sin (sin (x2)) (sin (sin (x2))) [sin..} (D) 2n.. g(x) = sinx g(f(x)) = g(x2) = sinx2 g(g(f(x)) = sin(sin(x2)) f. n {. .. . . 1...2)2 + x = 0 Since this passes through. 1. Then the number of distinct matrices in the set S is (A) 2 (B) 6 (C) 4 (D) 8 (A) a b 1 c ..: 44.(f(x)))) = (sin (sin (x2)))2 f. 0. where (f o g) (x) = f(g(x)).: The circle passing through the point (-1. Then the set of all x satisfying (f o g o g o f) (x) = (g o g o f) (x). n {. 0. 2.. (D) (-4..0)2 + (y . -2. sin (sin(x2)) 1) sin(x2) ] 2 sin (x2) = 0 x = n {n = 0.sin (x2) . Key: Sol. b.

So. x = -1. a = c = While b can take value or 2 So. 2 x 1 x ln (1 b 2 ) If lim = 2bsin .a) (1 . Let f : [-1. Let R1 = 1 xf (x) dx.: 45.[x ln (1 b2 )] = 2bsin2 NARAYANA IIT ACADEMY . and the x-axis.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol. 47. and R2 be the area of the region bounded by y = f(x).: (C) 2 (B) Let P be (a sec. x 2 y2 Let P (6. b tan = 3 The equation of normal at P is ax cos + bycot = a2 + b2 a 2 b2 a 2 b2 9 Put y = 0. x = =9 a a cos a. If the normal at the point P intersects the x-axis at a b (9.R1 2R1 = R2. then the eccentricity of the hyperbola is (A) 5 2 (B) (D) 3 2 3 Key: Sol. 6 1+ b2 3 e= a2 2 3 2 46. 1 a b Let A = 1 c 2 1 |A| = (1 .x)) 2 2 1 = 1 (1 x) f (x)dx = 1 f (x) dx xf (x) dx 1 R1 = R2 . 0). R2 = (1 x) f (1 x)dx 2 2 1 f (x) dx (replace x by (-1 + 2 . 2]. ) be a continuous function such that f(x) = f(1-x) for all x [-1. the number of distinct matrices in the set S is 2. b > 0 and (-. x = 2.: e x 0 x 20 1 lim . btan) a sec = 6. 3) be a point on the hyperbola 2 2 1 .c) For A to be non-singular matrix. Then (B) R1 = 3R2 (D) 3R1 = R2 2 Key: Sol.: (A) R1 = 2R2 (C) 2R1 = R2 (C) R1 = R1 = 2 1 2 xf (x) dx . ]. none of a and c should be 2. then the value of is x 0 (A) (B) 4 3 (C) (D) 2 6 (D) lim[1 x ln (1 b 2 )]1/ x = 2bsin2 (b > 0) x 0 1 Key: Sol. 2] [0.

P(F) = 5 25 25 3 4 4 3 P(E) = .: Let (x. D) 3 5 1 5 11 25 11 and the 25 2 .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 1 + b2 = 2b sin2 1 1 sin2 = (b + ) 1 2 b sin2 = 1 (when b = 1) = 48. 2 Key: Sol. (B). If L passes through the point (9.15 = 0 (D) y . y) in the ratio 1 : 3. y2 = 4x 16k2 = 16h k2 = h So. 0) to (x. y) be any point on the parabola y2 = 4x. The probability that exactly one of them occurs is probability of none of them occurring is then 4 . P(F) = 5 2 (C) P(E) = . P(F) = 5 5 5 5 1 .: P(E) + P(F) . 1) Key: Sol. P(F) = 5 (A. 1) (C) f = f -1 on (0. Let f : (0. out of which ONE OR MORE may be correct. So. k). If P(T) denotes the probability of occurrence of the event T.[P(E) + P(F) . (A) As range of f(x) R f(x) is not invertible.2P(EF) = 2 25 7 12 12 P(E) + P(F) = . Then 1 b x (B) f f -1 on (0.x + 3 = 0 (B) y + 3x . 1) and f (b) = bx .2x + 12 = 0 NARAYANA IIT ACADEMY 21 . P(F) = 5 5 3 4 (D) P(E) = .P(E F)] = 50. P(F) 5 5 (A) P(E) = (B) P(E) = Key: Sol. Let P be the point that divides the line segment from (0.33 = 0 (C) y + x . Let E and F be two independent events. 25 1 2 . P(E F) = P(E) . P(F) = or P(E) = . Let L be a normal to the parabola y2 = 4x. 1) R be defined by f(x) = (A) f is not invertible on (0.: 51. (C) and (D). then L is given by (A) y . locus of P is y2 = x This section contains 4 multiple choice questions. Each question has four choices (A). where b is a constant such that 0 < b < 1. Then the locus of P is (A) x2 = y (B) y2 = 2x (C) y2 = x (D) x2 = 2y (C) x y Let P be (h. SECTION – II (TOTAL MARKS: 16) (Multiple Correct Answer(s) Type) 49. 1) and f (b) = 1 f (0) 1 f (0) (D) f -1 is differentiable on (0. h = and k = 4 4 As. 6).

: (A. 2 cos x. B. at x = 1 f(x) is diff. Key: 0 1 1 1 1 0 Let M be a 3 × 3 matrix satisfying M 1 2 .x + 3 = 0.3) (t + 2) = 0 t = -1. D) Equation of normal is y + tx = 2t + t3 As it passes through (9. (t + 1) (t2 . then (A) f(x) is continuous at x = 2 (C) f(x) is differentiable at x = 1 (B) f(x) is not differentiable at x = 0 (D) f(x) is differentiable at x = - 3 2 Key: Sol. x 0 If f(x) = 2 0 x 1 x 1. SECTION – III (TOTAL MARKS: 24) (Integer Answer Type) 53. 1 x 1 2 sin x x 0 f (x) = 2 1 0 x 1 1 x 1 x f(x) is not diff. D) f f (x) 0 lim f (x) lim 2 x x 2 2 f(x) is continuous at x = -/2 f(x) is also continuous at x = 0. y . Then the sum of the 0 3 0 1 1 12 diagonal entries of M is (9) 22 NARAYANA IIT ACADEMY .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Key: Sol. and M 1 0 .6 = 0 or. x 1.6) = 0 or. t3 . The answer to each question is a Single-digit integer. (t + 1) (t .33 = 0 52. M 1 1 . -2. 3 equation of normals are y . B. ln x. at x = -3/2 This Section contains 6 questions.2x + 12 = 0 y + 3x . The bubble corresponding to the correct answer is to darkened in the ORS.7t . ranging from 0 to 9. 6) 6 + 9t = t3 + 2t or.: (A. x x 2 . C. at x = 0 f(x) is diff.t .

F. where f (x) denotes y(x) eg(x) = e g(x) . Then the value of is | a |2 | b |2 | C |2 Value is not fixed.g(x) g (x)dx = eg(x) (g(x) . . Then the value of y(2) is (0) g ( x ) dx I. satisfies above two inequality 4 4 4 Key: Sol.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol. then the number of point(s) in S lying inside the smaller part is 4 2 4 4 4 8 4 (2) x2 + y2 6 L 2x – 3y – 1 > 0 S x2 + y2 – 6 < 0 3 1 1 Clearly 2.1) + c NARAYANA IIT ACADEMY 23 .: Let = ei/3 . b. and a. c.3y = 1 divides the circular region x2 + y2 6 into two parts. df (x) and g(x) is a given nondx constant differentiable function on R with g(0) = g(2) = 0. Key: Sol. y(0) = 0. y. z be non-zero complex numbers such that a+b+c=x a + b + c2 = y | x |2 | y | 2 | z | 2 a + b2 + c = z .: 55. . = e eg ( x ) Let y(x) + y(x) g(x) = g(x) g(x). xR. . . x. . Sol. . The straight line 2x .: a M b c d = 1 e=2 f=3 a d b e c f d l 0 1 e m 1 2 f n 33 0 33 3 l 1 1 m 1 1 0 1 n a–d=1a=0 b–e=1b=3 c–f=1c=2 a d l 1 0 b e m 1 0 c f n 1 12 a + d + l = 0 l= 1 b + e + m = 0 m = 5 c + f + n = 12 n = 7 0 1 1 M 3 2 5 2 3 7 Sum of diagonal entries = 9 54. .: 56. and . If 3 5 3 1 1 1 1 S 2.

For example. If Let a = ˆ i k. r. The number of distinct real roots of x4 . |z| = 1.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 57. statement B matches with the statements given in q and r.b)r (a. ) (q) (-. ) 24 NARAYANA IIT ACADEMY . 0 = (-1) + c c = 1 y(2) = (-1) + 1. darken the bubbles corresponding to q and r in the ORS. iˆ j and c = ˆ i 2j r is a vector such that r b c b and r. z 1} The domain of the function f(x) = sin-1 8(3) x 2 is 2(x 1) 1 3 (-.r)b a (c b) r 0 a (c b) r a (c b) ˆ ˆ i ˆ j k ˆ 3j ˆ 3k ˆ ˆ 2) 3i cb 1 2 3 ˆ i(0 3) ˆ j(3 0) k(1 1 1 0 ˆ ˆ ˆ i j k ˆ 0) r a (c b) 1 0 1 ˆ i(0 3) ˆ j(3 3) k(3 3 3 3 ˆ 6j ˆ 3k ˆ r 3i ˆ 6j ˆ 3k). SECTION – IV (TOTAL MARKS: 16) (Matrix-Match Type) 59. 0) (0. Key: Sol. q.a 0 .1) + ce-g(x) Put x = 0. So.4x3 + 12x2 + x . Key: Sol. f(0) = 1 Hence f(x) = 0 has two distinct real roots.( ˆ ˆ r. against statement B. B. f(x) will have only one point of extrema. -1) (1. s and t) in Column II.e-0 y(2) = 0.b (3i iˆ j) = 3 + 6 = 9 This section contains 2 questions.: 58. then for that particular question. Each question four statements (A. C and D) given in Column I and five statements (p.1 = 0 is (2) Let f(x) = x4 – 4x3 + 12x2+ x – 1 f (x) = 4x3 – 12x2 + 24x + 1 O f(x) = 12x2 – 24x + 24 Hence f(x) > 0 x R f (x) is strictly increasing function. Match the statement given in Column I with the intervals/union of intervals given in Column II (A) Column I (p) Column II (B) 2iz The set {Re : z is a complex 2 1 z number.: y(x) = (g(x) . if for a given question. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II.b is (9) r b cb a (r b) a (c b) (a. ˆ bˆ ˆ 3k ˆ be three given vectors. then the value of r.

0] [2.10). ) (-. 1] [1. -1] [1. ) Key: Sol. then f(x) is increasing in the set {f() : 0 < (r) (-. 0] [2. (D–r) (A) z = ei 2iei 2iei Re Re i2 1 e 1 cos 2 i sin 2 1 2iei (2iei )i Re Re Re = (. (B–t). (C–r).: (A–s).IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II (C) 1 tan 1 1 tan . then If f() = tan 1 tan 1 } is 2 3/2 If f(x) = x (3x . ) 2 sin 2sin (sin i cos )i 2sin i2sin cos (B) 3x = t 8t 1 1 9 t2 t 2 8t 9 0 t2 9 (t 9)(t 1) 0 (t 3)(t 3) t<39t x < 1 2 x …(i) 8t where 1 9 t2 t 2 8t 9 0 (9 t 2 ) (t 9)(t 1) 0 (3 t)(3 t) t13<t x 0 1 < x …(ii) from (i) & (ii) x02x 1 (C) f () tan 1 2 tan 1 1 tan tan 1 1(1 tan ) tan ( tan tan ) 1(tan 2 1) = 2 sec2 f() 2 (D) f(x) = x3/2(3x – 10) 3 f (x) = x3/2 × 3 + (3x – 10) x1/ 2 2 3x 10 3 x x 2 NARAYANA IIT ACADEMY 25 . ) (D) (s) (t) (-. x 0.

Match the statement given in Column I with the values given in Column II (A) Column I (p) 6 Column II ˆ bˆ ˆ and c If a ˆ = j 3k. (B-p.q. j 3 k ˆ 2 3 k form a triangle.r.s. (D-) (A) a b c 2 b c a a.b 1 3 1 cos | a || b | 2 2 2 3 Required angle b 2 3 3 (B) f (x)dx a 5/ 6 b2 a 2 f can take many values 2 6 5/ 6 (C) 2 2 ln | sec x tan x |7 / 6 (sec x)dx ln 3 7 / 6 ln 3 26 NARAYANA IIT ACADEMY .b2. then the (q) 2 3 (C) (D) value of f is 6 5/ 6 2 The value of 6 sec x) dx is ln 3 7/ 1 The maximum value of Arg for 1 z |z| = 1.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 3 x (5x 10) 2 (– ve) (+ ve) 2 0 x2 60. then the internal angle of the triangle between a and b is If (B) (f (x) 3x) dx = a a b 2 .: (A-q). (C-s). z 1 is given by (r) (s) 3 (t) Key: Sol.t).

NARAYANA IIT ACADEMY 27 .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 3 1 ln ln = ln 3 3 3 1 (D) Arg 1 z 2 Hence maxima does not exist.

AgNO3(aq. positron. (A) proton. Each question has four choices (A). The major product of the following reaction is 3. (C) and (D). neutron.INDIA IIT – JEE (2011) PAPER I QUESTION & SOLUTIONS (CODE PART I : CHEMISTRY PAPER – I SECTION – I (TOTAL MARKS: 21) (Single Correct Answer Type) This section contains 7 multiple choice questions.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. Bombardment of aluminum by α–particle leads to its artificial disintegration in two ways. proton (C) proton. positron (B) neutron. (i) and (ii) as shown. (B). The plot of conductance (Λ) versus the volume of AgNO3 is X X X volume (P) volume (Q) (A) (P) (C) (R) Key: Sol.p. neutron (D) positron. out of which ONLY ONE is correct. neutron. 0) 1.: (D) Ag+ + NO3− + K+ + Cl− ⎯⎯ → AgCl↓ + K+ + NO3− AgNO3(aq) + K+Cl−(aq) ⎯⎯ → AgCl(s) + K+NO3− On adding AgNO3 p. NARAYANA IIT ACADEMY X X Λ Λ X X X X X X X X X X Λ XX X X Λ X X X X X X X X volume (R) volume (S) (B) (Q) (D) (S) 3 . Products X. (A) 27 13 4 (ii) Al + 2 He ⎯⎯→ 15 P + 30 27 13 ( ii ) Al 30 15 P + Y (i) 30 14 Si + X 30 14 Si + Z Key: Sol. neutron. Y and Z respectively are. “Y’ and ‘Z’ is proton neutron and positron respectively n (Y) 1 0 2.t will not started immediately until ionic product of AgCl > Ksp after it Cl– − will be precipited in the form of AgCl but at the same time NO3 will be added to the solution hence the number ion remain same therefore the conductance will remain same when the precipitation completed on further adding AgNO3 the number of ions in the solution increases hence the conductance increases.: 30 14 ↓ (i) ↓ (i) 1 30 0 Si + 1H 14 Si + +1e (X) (Z) Thus ‘X’ .NARAYANA IIT ACADEMY . proton. positron.

square planar and octahedral (C) square planer.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II O C NH C O O C (i) KOH (ii) Br CH2 Cl O C (A) C N CH2 Br (B) C N CH2 Cl O O C O O C (C) N C O CH2 Br (D) N C O CH2Cl Key: Sol.: (A) This is an example of Gabriel Pthalamide type of reaction O (i) KOH N O H acidic hydrogen absttracted N K+ O salt formation Benzylic 'C' (SN2) Br phenylic 'C' CH2 Cl Better site for SN2 reaction O O C N H2 C C O Br 4. respectively. are (A) octahedral. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl–. tetrahedral and octahedral (D) octahedral. tetrahedral and square planar (B) tetrahedral. Key: (B) 4 NARAYANA IIT ACADEMY . square planar and octahedral. CN– and H2O.

05 M (D) 2.: (C) Volume of solution = mass of solution density of solution 1000 + 120 = 973.98 4.78 M (B) 2. (D) Δ Ba(N3)2 ⎯⎯ → Ba + 3N2 (g) Dissolving 120 g of urea (mol.: Ni(28) = [Ar] 3d8. the most acidic is (A) p-nitrophenol (B) p-hydroxybenzoic acid (C) o-hydroxybenzoic acid (D) p-toluic acid.05 m V 973. Key: Sol.91 × 60 7. wt. The molarity of the solution is (A) 1. Extra pure N2 can be obtained by heating (A) NH3 with CuO (C) (NH4)2Cr2O7 (B) NH4NO3 (D) Ba(N3)2.15 4. Among the following compounds. 4s0 [NiCl4]24s sp3 4p 3d [Ni(CN)4]2- 4s 4p dsp2 due to strong field ligand CN− [Ni(H2O)6 ]+2 3d [Ni(H2O)6]2+ sp3d2 4s 4p 4d 5. 60) in 1000 g of water gave a solution of density 1.15 ω 1000 1000 × 120 = Molarity = × = 2. Key: Sol. 4s2 and Ni2+ = [Ar] 3d8.37 NARAYANA IIT ACADEMY 5 .58 2.15 g/mL.22 M.: (C) Compound p-nitrophenol p-hydroxybenzoic acid o-hydroxybenzoic acid p-toluic acid pka 7.00 M (C) 2.91 = 1. Key: Sol.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol.: 6.

Key: Sol. Each question has four choices (A).: 9. D) Amongst the given options. (A. out of which ONE OR MORE may be correct. Key: 11. however it is very slow due to higher energy of activation. C. the molecules move in straight lines with constant velocities. D) According to kinetic theory of gases. B. (D) Chemisorption is more exothermic than physisorption. (B) Physisorption may transform into chemisorption at high temperature. B. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is(are) (A) Adsorption is always exothermic. (B). (A. (A.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Hence COOH OH is the most acidic one due to ortho effect. (B) heavier molecules transfer more momentum to the wall of the container. is (are) H H H (A) C H2C H2C C CH2 (B) (D) H C C C CH2 (C) Key: Sol. (C) and (D). (C) Physisorption increases with increasing temperature but chemisorption decreases with increasing temperature. where as other conformer in different plane. H H C sp C 2 sp CH2 sp sp2 C (B) (C) 6 CH2 = C = O sp2 sp (absence of any atom at oxygen) NARAYANA IIT ACADEMY . (D) The terminal H of allene will be in perpendicular to each other plane. C) (A) Only two conformer cisoid and transoid have all the atom in same plane. Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore (C) removal of copper impurity (D) removal of iron impurity. Key: Sol.: 10. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any). (C) only a small number of molecules have very high velocity. SECTION – II (TOTAL MARKS: 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. 8.: C O H2C C CH2 (B. (D) between collisions. D) According to adsorption theory According to kinetic theory of gases (A) collisions are always elastic.

(B). Addition of aqueous NaCl to the blue solution gives a white precipitate O. gave acetone as the only organic product through the following sequence of reactions. NARAYANA IIT ACADEMY 7 . having molecular formula C6H10.H 2SO4 ( catalytic amount ) ( − H2O ) ⎯⎯⎯⎯⎯⎯⎯ → 2 H3C ( ii ) O3 ( iii ) Zn / H 2 O C CH3 12. (C) and (D) out of which ONLY ONE is correct. in which Q is an intermediate organic compound. 12 to 13 An acyclic hydrocarbon P. 14 to 16 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N. Sol. Paragraph for Question Nos. O ( i ) dil. Each of these questions has four choices (A). H SO 4 ( C6 H10 ) P 2 4 4 ⎯⎯⎯⎯⎯⎯⎯⎯ → Q ( ii ) NaBH /ethanol /HgSO ( iii ) dil. H 2SO 4 ( cathytic amount ) H3C ←⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ −H O 2 OH C H CH3 C CH3 ( rearrangement ) CH3 H3C C CH3 C H CH3 CH3 H3C C CH3 C CH3 CH 3 shift (Q) O ⎯⎯⎯ → −H + ( i ) O3 ⎯⎯⎯⎯⎯ → 2 H3C ( ii ) Zn/H 2 O C CH3 Paragraph for Question Nos. H H3C C C C CH3 (D) The structure of the compound Q is H3C OH C C H CH2 CH3 H3C OH C C H CH3 (A) H H3C (B) H3C H3C H3C OH HO (C) Key.: H H3C C CH2 CHCH3 (D) CH3 CH2 O C CH2 CH CH2 CH3 (B) CH3 H3C C CH3 C C CH3 → H ⎯⎯⎯⎯⎯⎯⎯ dil. The structure of compound P is (A) CH3CH2CH2CH2 – C ≡ C – H H3C (B) (D) H3CH2C – C ≡ C – CH2CH3 H3C H3C H3C C C C H (C) Key: 13. H 2SO 4 /HgSO 4 H3C C CH3 CH3 (P) (i) NaBH 4 /Ethanol (ii) dilute acid CH3 H3C C CH3 − CH3 C H CH3 conc. Addition of aqueous NH3 dissolves O and gives an intense blue solution. the solution turns light blue. Based upon one of the paragraph 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II SECTION – III (TOTAL MARKS: 15) (Paragraph Type) This section contains 2 paragraphs. acid ( i ) conc.

17. is 9 n = 3. Key: 15. Total number of orbitals = n2 = 9 1 ∴ No. The answer to each question is a Single Integer.: ⎡ Ag ( NH3 ) ⎤ and ⎡ Cu ( NH3 ) ⎤ ⎣ ⎣ 2⎦ 4⎦ ⎡ ⎤ ⎤ (D) ⎡ ⎣ Ag ( NH3 )2 ⎦ and ⎣ Ni ( NH3 )6 ⎦ 2+ (C) Cu + 2AgNO3 ⎯⎯ → Cu ( NO3 )2 + 2Ag ↓ (M) ( N) blue Blue solution contains Cu(NO3)2 and unreacted AgNO3 AgNO3 + NaCl ⎯→ AgCl ↓ + NaNO3 ⎤ AgCl + 2NH4OH ⎯→ ⎡ ⎣ Ag ( NH3 )2 ⎦ Cl + 2H 2 O ⎤ Cu(NO3)2 + 4NH4OH ⎯→ ⎡ ⎣Cu ( NH3 )4 ⎦ ( NO3 )2 + 4H 2 O int ense blue solution SECTION – IV (TOTAL MARKS: 28) (Integer Answer Type) This Section contains 7 questions. Key: Sol.: The maximum number of electrons that can have principal quantum number. Key: Sol. The number of sodium bromide molecules involve in the balanced chemical equation is 5 2− − 3Br2 + 3 CO3 ⎯→ 5Br − + BrO3 + 3CO2 18. The metal rod M is (A) Fe (C) Ni (B) The compound N is (A) AgNO3 (C) Al(NO3)3 (A) The final solution contains ⎤ (A) ⎡ ⎣ Pb ( NH3 )4 ⎦ 2+ + (B) Cu (D) Co (B) Zn(NO3)2 (D) Pb(NO3)2 Key: 16. n = 3. ranging from 0 to 9. and [ CoCl2 ] 2− (B) 2+ ⎡ Al ( NH3 ) ⎤ 4⎦ ⎣ 3+ + ⎤ and ⎡ ⎣ Cu ( NH3 )4 ⎦ 2+ (C) Key: Sol. 2 Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with evolution of CO2 gas. The bubble corresponding to the correct answer is to darkened in the ORS. a spin quantum number. The following products will be formed 8 NARAYANA IIT ACADEMY . ms = – ½ .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 14. of electrons having ms = − = 9. Key: Sol.: The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is 5 The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentyl hexane using alcoholic KOH is 5.: 19.

1 eV = 4. alanine and phenylalanine.4 2. Glycine contributes 47. The number of glycine units present in the decapeptide is 6 O O NH 2 ⎯⎯⎯ → Sol.: C HO C OH + NH 2 − Let there are n glycine unit in the compound because it is decapeptide hence 9 water molecule will be added during hydrolysis therefore total weight of the product will be 796 + 9 × 18 = 958 % Wt. Cu 4.6 × 10−19 E in eV = = 4.7 φ (eV) 4 λ = 300 nm = 300 × 10-9 m = 3 × 10-7 m c 6.0% to the total weight of the hydrolysed products.: 21. Wt.3 W 4.6 × 10 −34 × 3 × 108 = 6.2 3.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II H3C CH2 CH2 C C H CH3 H3C CH2 CH2 C C CH3 H CH3 CH2 C H H C C C CH2 CH3 CH2 CH3 CH3 CH2 H3C CH2 CH2 C CH2 CH3 20. The work function (φ) of some metals is listed below. of glycine in the given weight of product NARAYANA IIT ACADEMY 9 .6 × 10 −19 J E= h = 3 × 10−7 λ 6.3 2. Key.6 × 10−19 Number of metals having φ less than 4.1 eV 1.75 Key: Sol. 796) on complete hydrolysis gives glycine (mol. A decapeptide (mol.7 Pt 6. The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metal is Metal Li Na K Mg 2. Wt. 75).8 Ag 4.3 Fe 4.

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II = 75n × 100 = 47 958 47 × 958 ≈ 6. 23. Key: Sol. . (i) = RT RT Hence total mole of gas in vessel will be 0.: The difference in the oxidation number of the two types of sulphur atoms in Na2S4O6 is 5 O S O S S S O O O O Two sulphur are in zero oxidation state and two sulphur are in +5 oxidation state.68V RT ⎠ ⎝ or 0. a) (a. Considering the ideal gas behaviour the total volume (in litre) of the gaes at 0°C is close to 7 Let the volume of gas is V Mole of the vapour of compound PV 0.1RT + 0.68V ⎞ ⎛ 1 × V = ⎜ 0. Each question has four choices (A). a) E0a 2 2 x (0..: To an evacuated vessel with movable piston under external pressure of 1 atm.689V ⎞ ⎛ = ⎜ 0. (C) and (D). (C) 10 NARAYANA IIT ACADEMY . r ˆ where E0 is a constant. Key: Sol. 0) y Key. 24.082 × 273 V= ≈7 0. .1 + ⎟ RT ⎠ ⎝ There for applying gas equation PV = nRT 0.1 + ⎟ RT = 0.32 PART II : PHYSICS SECTION – I (TOTAL MARKS: 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. n= 75 × 100 22.68 atm. The flux Consider an electric field E = E0 x. a.1 mol of He and 1.0 mol of an unknown compound (vapour pressure 0.1 RT 0.68 × V PV = nRT → n = . 0) (0. 0. at 0°C) are introduced. The difference in the oxidation number of the two types of sulphur atoms in Na2S4O6 is 5. 0.32 V = 0. 0. a.1× 0. out of which ONLY ONE is correct. through the shaded area (as shown in the figure) due to this field is (A) 2E0a2 (C) E0a2 (B) (D) 2E 0 a 2 z (a. (B).

IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol. Taking the initial temperature to be T1. Sol.5 1 2 s V A 2μF capacitor is charged as shown in figure. 5. The maximum possible value of angular velocity of ball (in radian/s) is (A) 9 (B) 18 (C) 27 (D) 36 (D) …(1) T cos q= mg L m Tsin q= m ( Lsin q) w2 from (2) …(2) m L θ Þ Þ 26.5 ´ 0. Key. A ball of mass (m) 0. Sol.6 liter of helium gas at STP is adiabatically compressed to 0. Key. The maximum tension the string can bear is 324N. the work done in the process is 3 9 (A) (B) RT1 RT1 8 2 9 15 (D) (C) RT1 RT1 8 2 (A) NARAYANA IIT ACADEMY 11 . T = mLw2 324 = 0.7 liter. The ball is rotated on a horizontal circular path about vertical axis.5 ´ w2 324 18 w= = = 36 0.5 m. The percentage of its stored energy dissipated after the switch S is turned to position 2 is (A) 0% (B) 20% (C) 75% (D) 80% 2μF 8μF Key. (D) ui = 1 ´ 2´ V2 = V2 2 ( 2´ V)2 V2 uf = = 2 ´ 10 5 V 2 4V 2 = 5 5 Loss of energy = V 2 - 4V 2 4 % loss = 52 ´ 100 = ´ 100 = 80% V 5 27.5 kg is attached to the end of a string having length (L) 0.5 0. φ = EAcos 45o = E0 Z ( 2a 2 ) 1 2 = E0a 2 a 2a Y X 25.

f '' 8.52 310 320 31 So. Þ é C ù f ' = fê ë C.6) 2/3 = T2 ( 0.1 T1 ( 5.6 (1) ê 2 ë2 l1 hc 2é 1 = 13.5kHz Þ ¢= f¢ 29. The speed of sound in air is 320 m/s.T2 ) r. W= nR ( T1 .V ú û é 320 ù f ' = 8ê ë 310 ú û é C+ V ù ¢= f ê f¢ ' ë C ú û V Now wall becomes source so frequency heard by driven is 8´ 320 330 8 ´ 33 ´ = = 8. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/h towards a tall building which reflects the sound waves. The frequency of the siren heard by the car driver is (A) 8. Sol.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol.6 ( 2) ê 2 ë2 l2 Dividing 1ù û 32 ú 1ù û 42 ú l 2 1´ ( 5 / 36) = l 1 4 ´ ( 3 / 16) l ´ 5´ 16 5 l2= 1 = l = 1215 Å Þ 36 ´ 4 ´ 3 27 1 12 NARAYANA IIT ACADEMY .25 kHz (C) 7.50 kHz (B) 8.75 kHz (D) 7. The wavelength of the second spectral line in the Balmer series of singly–ionized helium atom is (A) 1215 Å (B) 1640 Å (C) 2430 Å (D) 4687 Å.7 ) 2/3 T2 = T1 ( 8) = T1 ´ 4 nR ´ 3T1 9 W= = nRT1 2/3 2 1 But n = 4 9 Þ W = RT1 8 Þ 28. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561Å. Key.50 kHz (A) Frequency received by total bulting 2/3 Key. (A) hc 2é 1 = 13. Sol.

Sol.6 ohm (C) 10. D) 32. The galvanometer shows null point when tapping key is a 52 cm mark. The end–corrections are 1 cm and 2 cm respectively for the ends A and B. (B).2 ohm (B) 10. (C) and (D). Key. Sol. Heat Q flows only from left to right 2K through the blocks. A meter bridge is set–up as shown. (B. 31. Key.6 W 50 5 SECTION – II (TOTAL MARKS: 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. out of which ONE OR MORE may be correct. D) dQ B ⎛ A ⎞ ΔT = 3K ⎜ ⎟ 2 = i B dt ⎝ 4 ⎠ 4L dQ C ⎛ 2A ⎞ ΔT2 = 4K ⎜ = iC ⎟ dt ⎝ 4 ⎠ 4L dQ D ⎛ A ⎞ ΔT = 5K ⎜ ⎟ 2 = i D dt ⎝ 4 ⎠ 4L i B + i D = iC 5L 6L B 3K C D 4K 5K E 6K NARAYANA IIT ACADEMY 13 . B. D and E of heat different thermal conductivities (given in terms of a constant K) 1L A and sizes (given in terms of length. L) as shown in the figure. Then in steady state 3L (A) heat flow through A and E slabs are same 4L (B) heat flow through slab E is maximum (C) temperature difference across slab E is smallest (D) heat flow through C = heat flow through B + heat flow through D. B.8 ohm (D) 11. Each question has four choices (A). C.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 30. The determined value of ‘X’ is (A) 10. (A. 0 1L A composite block is made of slabs A.1 ohm (B) X A 10Ω B X 10 = 53 50 53 53 X= ´ 10 = = 10. Sol. Which of the following statement(s) is/are true ? (A) they will never come out of the magnetic field region (B) they will come out traveling along parallel paths (C) they will come out at the same time (D) they will come out at different times. C. Key. They enter a semi– infinite region of uniform magnetic field perpendicular to the velocity. All slabs are of same width. An electron and a proton are moving on straight parallel paths with same velocity. to determine an unknown resistance X using standard 10 ohm resistor.

To sustain the oscillations. Ne 2 Key. D all are correct RA QA RB QB 34.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 33. Let N be the number density of free electrons. Paragraph for Question Nos. which is called the plasma frequency. Based upon one of the paragraph 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. (C) and (D) out of which ONLY ONE is correct. Which of the following statement(s) is/are true ? (A) restoring torque in case A = restoring torque in case B (B) restoring torque in case A < restoring torque in case B (C) angular frequency for case A > angular frequency for case B (D) angular frequency for case A < angular frequency for case B. B. When the electrons are subjected to an electric field. Consider two ways the disc is attached: (case A) The disc is not free to rotate about its centre and (case B) the disc is free to rotate about its centre. Q A + Q B = 2Q QA QB = Þ s A R A = s BR B RA RB So. use dimensional analysis to determine the correct expression for ωp. C. Now they are connected by a thin metal wire. Key. A metal rod of length L and mass m is pivoted at one end. they are displaced relatively away from the heavy positive ions. The rod–disc system performs SHM in vertical plane after being released from the same displaced position. B. the electrons begin to oscillate about the positive ions with a natural angular frequency ωp.w2 q I In case A the moment of inertia is more as compared to B. This is the explanation of high reflectivity of metals. If the electric field becomes zero. where a part of the energy is absorbed and a part of it is reflected. 35. mε 0 Ne (B) (A) Ne mε 0 (C) Ne 2 mε 0 (D) mε 0 . C. all the free electrons are set to resonance together and all the energy is reflected. a time varying electric field needs to be applied that has an angular frequency ω. each of mass m. < E on A B Key. 35 to 36 A dense collection of equal number of electrons and positive ions is called neutral plasma. As ω approaches ωp. Sol. 14 (C) NARAYANA IIT ACADEMY . Sol. A. so wB > wA SECTION – III (TOTAL MARKS: 15) (Paragraph Type) This section contains 2 paragraphs. (B). Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma. D) surface surface (D) E on . Each of these questions has four choices (A). A thin disc of mass M and radius R (< L) is attached at its centre to the free end of the rod. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB (< RA) are kept far apart and each is given charge +Q. Taking the electronic charge as ‘e’ and the permittivity as ‘ε0’. Then (B) QA > QB (A) E inside =0 A (C) σA R B = σB R A (A. (A. D) Resorting torque is same in both cases a= t = .

For such system.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol. We use the sign convention in which position or momentum upwards (or to right) is positive and downwards (or to left) is negative. For example.30 = 1. (B) wp = Ne 2 = me0 4 ´ 1027 ´ 1.7 = 600 nm 0.14 c= f l Þ ∴ l= 3´ 108 = 6 ´ 10.5 ´ 1015 Answer is (B) Paragraph for Question Nos.19 ´ 2 ´ 1034 = ´ 1. Momentum Position 37.19 (from previous question) 10 ´ 10. They are especially useful in studying the changes in motion as initial position and momentum are changed. Here we consider some simple dynamical systems in one–dimension.6 ´ 2 ´ 1015 wp 1. Take ε0 ≈ 10–11 and m ≈ 10–30.11 . (A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm. mε 0 b Answer is (C) Key. 37 to 39 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. The phase space diagram is x (t) vs p(t) curve in this plane. The arrow on the curve indicates the time flow. where these quantities are in proper SI units.5 ´ 1015 f= 2p 2 ´ 3. phase space is a plane is which position is plotted along horizontal axis and momentum is plotted along vertical axis. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons N ≈ 4 × 1027 m–3.6 ´ 2 ´ 1015 = = 0. Sol. the phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure.6 ´ 10. Ne 2 . The phase space diagram for a bal thrown vertically up from ground is Momentum Momentum (A) Position (B) Position NARAYANA IIT ACADEMY 15 .6 ´ 10. b Let ωP ∝ e a ε 0 NC md Putting dimensions ⎡ Q 2 ⎤ −3 c [T −1 ] ∝ [Q]a ⎢ [L ] [M]d 3 −2 ⎥ ⎣ ML T ⎦ Solving ωP ∝ ∴ 36.

The phase space diagram for one cycle of this system is 39. (C) From diagram (amplitude of oscillator)1 = 2 × (amplitude of oscillator)2 ⇒ E1 = 4E 2 ∴ Answer is (C) Consider the spring mass system. Sol.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Momentum Momentum (C) (D) Position Position Key. ∴ Answer is (D) The phase space diagram for simple harmonic motion is a circle centered at the origin. Momentum E2 2a a Position E1 Key. with the mass submerged in water. Sol. In the figure. as shown in the figure. the two circles represent the same oscillator but for different initial conditions. Momentum Momentum (A) (B) position position Momentum Momentum (C) (D) position position Key. 38. and E1 and E2 are the total mechanical energies respectively. Then (B) E1 = 2 E2 (A) E1 = 2 E 2 (C) E1 = 4 E2 (D) E1 = 16 E2. 16 (B) NARAYANA IIT ACADEMY . (D) The momentum is initially positive and then negative.

then N is 5. For equilibrium of a charge 1 q2 ⎛ 1 ⎞ ⎜ + 2 ⎟ = C γa 4πε 0 a 2 ⎝ 2 ⎠ Where C is a constant q2 ⇒ a3 ∝ γ ∴ N = 3. The force required to just push it up the inclined plane is 3 times the force required to just prevent it from sliding down. NARAYANA IIT ACADEMY 17 . From Ampere’s Law μI Bin = 0 L μ dφ dI ∴ εind = − = − 0 ⋅ π(r) 2 dt L dt εind ∴ Iind = R r ∴ | M |= Iind ⋅ πr 2 = 6μ0 I0 sin(300t) ⇒ N = 6.3 m carries a current I along its curved surface as shown. The bubble corresponding to the correct answer is to darkened in the ORS. If the magnetic moment of the loop is N μ0 I0 sin (300 t). The current varies as I = I0 cos (300 t) where I0 is constant. initial position is positive meaning thereby that the block starts from above the mean position. A long circular tube of length 10 m and radius 0. each of +q.5 ⇒ N = 5. then N is 42. momentum first increases and then decreases (in negative direction). and Key. ⎡ q2 ⎤ N a = k ⎢ ⎥ . The surface tension of the soap film is γ. Then N is ⎣γ⎦ 3. If we define N = 10 μ. A block is moving on an inclined plane making an angle 45º with the horizontal and the coefficient of friction is μ. Sol. are rigidly fixed at the four corners of a square planar soap film of side a. 6. where k is a constant. The answer to each question is a Single Integer. (mg sin θ + μ mg cos θ) = 3 (mg sin θ – μ mg cos θ) ⇒ 1 + μ = 3 (1 – μ) ⇒ μ = 0.1 m is placed inside the tube with its axis coinciding with the axis of the tube. Sol. Key. ∴ Answer is (B) SECTION – IV (TOTAL MARKS: 28) (Integer Answer Type) This Section contains 7 questions. As it comes down. 1 q q q q 41. I Key. Sol.005 ohm and of radius 0. 40. A wire–loop of resistance 0. ranging from 0 to 9. From diagram. The system of charges and planer film are in equilibrium.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Sol. Four point charges.

4. Sol. The mass (in mg) of the radioactive sample is 1. then N is 9 2 ⎡2 ⎤ I = 2 × mR 2 + 2 ⎢ mR 2 + md 2 ⎥ 5 ⎣5 ⎦ = 9 × 10 −4 kg m 2 ⇒ N = 9. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second. Sol. ∴ P = 4. l mg = YA A and l = LαΔt γAαΔt ⇒ m= g 1011 × π(1×10−3 ) 2 × 10−5 × 10 10 ≅ 3kg . Steel wire of length L at 40ºC is suspended from the ceiling and then a mass m is hung from its free end. The mass of an atom of this radioisotope is 10–25 kg.8 N ⇒ μ = 0. Sol.5 m with a stick as shown in the figure.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 43.3 m/s2. Assume that L >> diameter of the wire. The coefficient of linear thermal expansion of the steel is 10–5/ºC. Stick Ground Key. = 44. A boy is pushing a ring of mass 2 kg and radius 0. Key. Four solid spheres each of diameter 5 cm and mass 0. Sol. …(i) 0. The stick applied a force of 2 N on the ring and rolls it without slipping with an acceleration of 0. dN M = λN = λ dt M0 M0 = Mass of an atom ⇒ M = 1 mg.3 N’ 2N f2 f1 mg 46. The momentum of inertia of the system about the diagonal of the square is N × 10–4 kg–m2. whose mean life is 109 s.4.3 and …(ii) (f1 − f 2 )0. The value of P is 45. Key. Equations of motion are 2 – f1 = 2 × 0. For equilibrium.5 = 2(0. Young’s modulus of steel is 1011 N/m2 and radius of the wire is 1 mm. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficient of friction between the stick and the ring is (P/10).5) 2 ⋅ 0.8/2 = 0. The wire is cooled down from 40ºC to 30ºC to regain its original length L. Key.5 solving f2 = 0. 18 NARAYANA IIT ACADEMY .5 kg are placed with their centers at the corners of a square of side 4 cm. Then the value of m in kg is nearly 3.

A vector v in the plane of a and b .c 1 r = |c| 3 x + y − (x − y) − (x + y) 1 = 3 3 −x + y = 1 x – y = −1 y=x+1 r ˆ−ˆ ˆ v = (x + 1 + x)i j + (x + x + 1)k r ˆ−ˆ ˆ v = (2x + 1)i j + (2x + 1)k 2x + 1 = 3 x=1 r Put x = 1 in v ˆ − 3j ˆ−k ˆ (B) −3i ˆ − 3k ˆ i + 3j (D) ˆ 48. is given by 3 ˆ + 3k ˆ i − 3j (A) ˆ Key: Sol. y = 0 and x = 0 into two parts 1 R1 (0 ≤ x ≤ b) and R2 (b ≤ x ≤ 1) such that R1 . 0) X ⎡ (x − 1) ⎤ ⎡ (x − 1)3 ⎤ 1 ⎢ ⎥ −2⎢ ⎥ = ⎣ 3 ⎦0 ⎣ 3 ⎦b 4 1 2 1 1 1 ⎡(x − 1)3 ⎤ ⎦ b = 3 − 4 = 12 3⎣ 3 1 1 x=b NARAYANA IIT ACADEMY 19 . Each question has four choices (A).R2 = . whose Let a = ˆ r 1 projection on c is .: Let the straight line x = b divide the area enclosed by y = (1 . Then b equals 4 3 1 (B) (A) 4 2 1 1 (D) (C) 3 4 (B) Y b 1 1 (1 − x) 2 dx − ∫ (1 − x) 2 dx = ∫ 4 0 b 2 2 ∫ (1 − x) dx − 2∫ (1 − x) dx = 0 b 1 1 1 4 R1 R2 (1.x)2. out of which ONLY ONE is correct. Key: Sol.: ˆ−ˆ ˆ j + 3k (C) 3i (C) r r r v = xa + yb ˆ+ˆ ˆ + y(i ˆ−ˆ ˆ = x(i j + k) j + k) r ˆ + (x − y)ˆ ˆ v = (x + y)i j + (x + y)k rr v. b=ˆ ˆ and c i+ˆ j+ k i −ˆ j+ k = i − j − k be three vectors. r r r r ˆ ˆ ˆ r r ˆ . (B).IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II PART III : MATHEMATICS SECTION – I (TOTAL MARKS: 21) (Single Correct Answer Type) This section contains 7 multiple choice questions. 47. (C) and (D).

y0) be the solution of the following equations (2x)ln2 = (3y)ln3 3 lnx = 2ln y The x0 is 20 NARAYANA IIT ACADEMY .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II = −(b − 1)3 = 1 8 1 (b − 1)3 = − 8 1 b −1 = − 2 1 b= 2 49. 1) and 120º – 60º = 60º 120º As line L intersects x-axis So m = 60º 3. Key: Sol. 0 And line will be 3x + y = 1 y + 2 = 3 (x – 3) ( ) ⇒ y − 3x + 2 + 3 3 = 0 50. The value of 1 3 ln 4 2 3 (C) ln 2 (A) Put x2 = t x sin x 2 dx is sin x + sin(ln 6 − x 2 ) ln 2 ln 3 ∫ 2 (A) 1 3 ln 2 2 1 3 (D) ln 6 2 (B) Key: Sol. Let (x0.: ∴ dt 2 ln 3 1 sin t I= ∫ dt 2 ln 2 sin t + sin(ln 6 − t) x dx = I= 1 sin(ln 6 − t) dt ∫ 2 ln 2 sin(ln 6 − t) + sin(t) ln 3 2I = ln 3 1 3 1 ∫2 dt = 2 ln 2 2 ln I= 1 3 ln 4 2 51. If L also intersects the x-axis.3 + 2 3 = 0 (C) 3 y .3 x + 2 + 3 3 = 0 (D) 3 y + x .3 3 = 0 (B) y . then the equation of L is (A) y + 3 x + 2 . -2) is inclined at an angle 60° to the line 3 x + y = 1.: A straight line L through the point (3. 120º + 60º = 180º (0.x + 3 + 2 3 = 0 (B) Two line can be drawn at an angle 60º with 3x + y = 1 and their slope will be.

Then (B) Q ⊄ P (D) P = Q ( ( 2 + 1 cos θ = sin θ ) tan θ = 2 + 1 sin θ + cos θ = 2 sin θ 2 − 1 sin θ = cos θ ) tan θ = 1 2 −1 = 2 +1 Hence P = Q 53.: 1 6 1 (C) 2 (C) (2x)ln2 = (3y)ln3 ln 2 ln 3y = (ln 2x) ln 3 ln2 ln2x = ln3 ln3 y lnx ln3 = lny ln2 ln 3 + ln y = ln 3y = (B) 1 3 (D) 6 … (i) … (ii) ln 2 ln 2x ln 3 ln 2(ln 2x) − (ln 3) 2 ln y = ln 3 (ln 2) 2 + ln x × ln 2 − (ln 3) 2 = ln 3 ln 3 from (ii) ln y = × ln x ln 2 ln 3 (ln 2) 2 + ln 2 × ln x − (ln 3) 2 ln x = ln 2 ln 3 ln 3 ln 2 (ln 2) 2 − (ln 3) 2 ⎛ ⎞ ln x ⎜ − = ⎟ ln 3 ⎝ ln 2 ln 3 ⎠ … (iii) ⎛ (ln 3)2 − (ln 2) 2 ln x ⎜ ln 2 ln 3 ⎝ 1 ln x = ln 2 1 x= 2 ⎞ ⎛ (ln 2)2 − (ln 3) 2 ⎟=⎜ ln 3 ⎠ ⎝ ⎞ ⎟ ( −1) ⎠ 52.cosθ = (A) P ⊂ Q and Q -P ≠ ∅ (C) P ⊄ Q (D) sin θ − cos θ = 2 cos θ 2 cosθ} and Q = {θ : sinθ + cosθ = 2 sinθ} be two sets. Key: Sol.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II (A) Key: Sol. Let α and β be the roots of x2 .: Let P = {θ : sinθ . If an = αn .βn for n ≥ 1.6x . with α > β. then the value of (A) 1 (C) 3 (B) 2 (D) 4 NARAYANA IIT ACADEMY a10 − 2a 8 is 2a 9 21 .2 = 0.

3y2 = 3 (B. out of which ONE OR MORE may be correct. 3 ⎠ ⎝ (±2.: x 2 y2 − = 1 be reciprocal to that of the ellipse x2 + 4y2 = 4.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Key: Sol. 54. Key: Sol.: (C) α2 −6α − 2 = 0 β2 − 6β − 2 = 0 8 2 8 2 a10 − 2a 8 α10 − β10 − 2(α8 − β8 ) α ( α − 2 ) − β ( β − 2 ) = = 2a 9 2(α 9 − β9 ) 2 ( α 9 − β9 ) α 8 × 6α − β8 × 6β =3. (C) and (D). D) 1 3 Eccentricity of the ellipse e = 1 − = 4 2 Focus (±ae. If the a 2 b2 hyperbola passes through a focus of the ellipse. 0) Let the eccentricity of the hyperbola x 2 y2 − 2 = 1 will pass through the points (± 3. 2(α 9 − β9 ) SECTION – II (TOTAL MARKS: 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions.: 55. 0) 2 ⎛ ⎞ . Key: Sol. 0) 5 (C) the eccentricity of the hyperbola is 3 (D) the equation of the hyperbola is x2 . 0) eH = 2 . 0) Focus (± 3. then M2N2 (MT N)-1 (MN-1)T is equal to (B) -N2 (A) M2 (C) . If PT denotes the transpose of P. then x 2 y2 − =1 (A) the equation of the hyperbola 3 2 (B) a focus of the hyperbola is (2. Let M and N be two 3 × 3 non-singular skew-symmetric matrices such that MN = NM. (B).M2 (D) MN Wrong Statement is wrong. 22 NARAYANA IIT ACADEMY . 0) 2 b 3 a 3 −1 = 0 a2 2 ⇒ a =3 ⎛4 ⎞ b 2 = 3 ⎜ − 1⎟ = 1 ⎝3 ⎠ Hence hyperbola is x2 − y2 = 1 3 x2 – 3y2 = 3 its focus is (±ae. 0⎟ ⎜ ± 3. Each question has four choices (A).

∀x. Key: Sol. y∈R If f(x) is differentiable at x = 0. ˆ and ˆ ˆ . (C) and (D) out of which ONLY ONE is correct.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 56. D) r ˆ a=ˆ i+ˆ j + 2k Let r ˆ b=ˆ i + 2ˆ j+ k r r r Let vector c is coplanar with a & b r r r c = λa + μ b r ˆ + (λ + 2μ)ˆ ˆ c = (λ + μ)i j + (2λ + μ)k r ˆ i+ˆ j+ k c ⊥ to the ˆ λ + μ + λ + 2μ + 2 λ + μ = 0 4λ + 4 μ = 0 λ+μ=0 r r r Hence c = λ(a − b) ˆ = λ ( −ˆ j + k) if λ = ± 1 r ˆ &ˆ ˆ j+ k j− k then c = −ˆ 57. Paragraph for Question Nos. Each of these questions has four choices (A). ⇒ f(x) = kx Hence clearly f(x) is continuous & has constant derivative ∀ x ∈ R. (B.: (A. then (A) f(x) is differentiable only in a finite interval containing zero (B) f(x) is continuous ∀x∈R (C) f ′(x) is constant ∀x∈R (D) f(x) is differentiable except at finitely many points. (B). and perpendicular to the vector i+ˆ j + 2k i + 2ˆ j+ k The vector(s) which is/are coplanar with vectors ˆ ˆ ˆ is/are i+ˆ j+ k ˆ j− k (A) ˆ i −ˆ j (C) ˆ i +ˆ j (B) −ˆ ˆ j+ k (D) −ˆ Key: Sol. 58 to 59 NARAYANA IIT ACADEMY 23 . Based upon one of the paragraph 2 multiple choice questions and based on the other paragraph 3 multiple choice questions have to be answered. SECTION – III (TOTAL MARKS: 15) (Paragraph Type) This section contains 2 paragraphs.: Let f : R → R be a function such that f(x + y) = f(x) + f(y). C) x=y=0 ⇒ f(0) = 0 f (x + h) − f (x) f (x + h) − f (x + 0) f '(x) = lim = lim h →0 h →0 h h f (x) + f (h) − f (x) − f (0) = lim h →0 h f (h) − f (0) = lim = f '(0) = k h →0 h (Given f(x) is differentiable x = 0 ⇒ f ′(0) = k(let) f(x) = kx + c f(0) = 0 c = 0.

c). then (A) 6 Key: 62. with a and c satisfying (E).. lies on the plane 2x + y + z = 1. the probability that head appeared on the coin is 17 11 (B) (A) 23 23 15 12 (C) (D) 23 23 (D) Required probability 4 12 10 = = 23 23 30 Paragraph for Question Nos. However. ∑⎜ α + β ⎟ n =0 ∞ ⎛1 ⎝ 1⎞ ⎠ n is (B) 7 24 NARAYANA IIT ACADEMY . Now 1 ball is drawn at random from U2. Key: Sol.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls.: Given that the drawn ball from U2 is white. with reference to (E). If the point P(a. Key: 61. Key: Sol. If head appears. b and c be three real numbers satisfying ⎡1 9 7 ⎤ ⎥ [a b c] ⎢ ⎢8 2 7 ⎥ = [0 0 0] . 58. (E) ⎢ ⎣7 3 7 ⎥ ⎦ 60. then 1 ball is drawn at random from U1 and put into U2.. then the value of 3 1 3 + b + c is equal to a ω ω ω (A) -2 (B) 2 (C) 3 (D) -3 (A) Let b = 6. then 2 balls are drawn at random from U1 and put into U2. A fair coin is tossed. and U2 contains only 1 white ball. If α and β are the roots of the quadratic equation ax2 + bx + c = 0. b.1 = 0 with Im (ω) > 0. if tail appears.: The probability of the drawn ball from U2 being white is 13 (A) (B) 30 19 (C) (D) 30 (B) Required probability 1 ⎡3 2 1⎤ 1 ⎡ 3 1 1 6 2⎤ = ⎢ ×1 + × ⎥ + ⎢ ×1 + × + × ⎥ 2 ⎣5 5 2 ⎦ 2 ⎣10 10 3 10 3 ⎦ 23 = 30 23 30 11 30 59. If a = 2 with b and c satisfying (E). 60 to 62 Let a. then the value of 7a + b + c is (A) 0 (B) 12 (C) 7 (D) 6 (D) Let ω be a solution of x3 .

The bubble corresponding to the correct answer is to darkened in the ORS. NARAYANA IIT ACADEMY 25 . = 1 1− 6 7 62. If we put a = 2 in (*). b = 6.1) = 0 So. if we put c = λ 6λ λ We get a = − . b = − 7 7 Now 2a + b + c = 1 ⇒ λ = -7 So a = 1. 61. P(a.7 = 0 ⇒ (x + 7) (x .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II (C) Key: 60-62. ∑⎜ α + β ⎟ =∑⎜ ⎟ ⎝7⎠ n =0 ∞ ⎛1 ⎝ 1⎞ n ∞ ⎛6⎞ n ⎠ n =0 = 7. c = -7 Hence 7a + b + c = 6. c) lies on the plane 2x + y + z = 1 ⇒ 2a + b + c = 1 Now in (*). SECTION – IV (TOTAL MARKS: 28) (Integer Answer Type) This Section contains 7 questions. c = -14 3 1 3 So a + b + c ω ω ω 3 1 3 = 2 + 12 + −14 ω ω ω 3 1 3 = 2+ + ω 1 ω ⎡ 1 1⎤ = 1 + 3 ⎢ 2 + ⎥ = 1 + 3 (ω + ω2) ⎣ ω ω⎦ = 1 + 3 [-1] = -2 . ranging from 0 to 9. α = -7. (*) 7a + 7b + 7c = 0 ⎪ ⎭ 60. c = -7 So quadratic equation becomes x2 + 6x . 6 7 (D) ∞ (B) ⎡1 9 7 ⎤ ⎥ [a b c] ⎢ ⎢8 2 7 ⎥ = [0 0 0] ⎢ ⎣7 3 7 ⎥ ⎦ a + 8b + 7c = 0 ⎫ ⎪ ⇒ 9a + 2b + 3c = 0 ⎬ .. The answer to each question is a Single Integer. If we put b = 6. we get b = 12.. we get a = 1. b. β = 1 1 1 6 + = ⇒ α β 7 Now.

1≤ p ≤ 100 .sin n ⎢ n n⎦ n n ⎣ π 4π π 3π − sin sin sin .k) d = 0 k = 25 (here we have neglected d = 0) then d = 6 so.1) d) 2 i =1 5n 2a + (5n − 1)d ] Sm S5n 2 [ 1 = = n Sn Sn [ 2a1 + (n − 1)d ] 2 5(6 + (5n − 1)d) = k (constant) = (6 + (n − 1)d) ∑a p i = ⇒ 30 + 25nd .k) dn + (k . 1.: 7 1 1 1 = + ⎛ π ⎞ sin 2π ⎛ 3π ⎞ sin ⎜ ⎟ sin ⎜ ⎟ n ⎝n⎠ ⎝ n ⎠ π 3π π 2π ⎛ 2π ⎞ ⎛ 3π ⎞ sin ⎜ ⎟ sin ⎜ ⎟ = sin . .6) = 0 ∀ 1 ≤ n ≤ 20 ⇒ (25 .sin ⎥ = sin .sin + sin ..sin n n n n n n ⎝ ⎠ ⎝ ⎠ 2π ⎡ 3π π⎤ π 3π sin − sin ⎥ = sin . NARAYANA IIT ACADEMY 26 . a2 = a1 + d = 9 65. For any integr n i =1 i p Key: Sol..5d = 6k + knd . Let a1 .kd ⇒ (25 . the required minimum value is 8. then a2 is Sn ∑ a . The positive integer value of n > 3 satisfying the equation 1 1 1 is = + ⎛π⎞ ⎛ 2π ⎞ ⎛ 3π ⎞ sin ⎜ ⎟ sin ⎜ ⎟ sin ⎜ ⎟ ⎝n⎠ ⎝ n ⎠ ⎝ n ⎠ Key: Sol.sin sin n ⎢ n n⎦ n n ⎣ 2π ⎡ 2π π⎤ π 3π 2 cos .: (9) Sp = p (2a1 + (p .sin =0 n 2n 2n π 7π π 2sin cos sin =0 n 2n 2n π ⎛ ⎞ ⎜ As sin n ≠ 0 ⎟ 7π ⇒ cos =0⇒n=7 ⎜ ⎟ 2n ⎜ sin π ≠ 0 ⎟ ⎜ ⎟ ⎝ ⎠ 2n sin 64.sin =0 n n n n π 7π π sin . a3 .IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 63. a-4. Key: Sol. a2 . let m = 5n.. If Sm does not depend on n.cos . 3a-3. a8 and a10 with a > 0 is (8) a −5 + a −4 + a −3 + a −3 + a −3 + 1 + a 8 + a10 a > 0.2. a100 be an arithmetic progression with a1 = 3 and Sp = with 1 ≤ n ≤ 20.: The minimum value of the sum of real numbers a-5 . ≥ 1 (Applying AM ≥ GM) 8 -5 -4 -3 8 10 ⇒ a + a + 3a + 1 + a + a ≥ 8 So.5) (d .

∞) be a differentiable function such that f(1) = 2. Key: Sol. 67.t. 6[f(x)] = 3 f(x) + 3x f′(x) . ⎟ ⎟ .: ⎛ π π d ⎛ sin θ ⎞ ⎞ Let f(θ) = sin ⎜ tan −1 ⎜ (f (θ)) is. x we get. Key: Sol.R2 both in numerator and denominator) 2 | (t 2 − t1 ) (t 3 − t 2 ) (t1 − t 3 ) | = 2.: Consider the parabola y2 = 8x.− <θ < 4 4 cos 2 θ ⎝ ⎠⎠ ⎝ sin θ sin θ Let tan-1 = α ⇒ tanα = cos 2θ cos 2θ sin θ sin θ ⇒ f(θ) = sinα = = = tan θ cos 2θ + sin 2 θ cos θ ⇒ d d (f (θ)) = (tan θ) = 1.x2 xf ′(x) − f (x) ⇒ =1 x2 d ⎛ f (x) ⎞ f (x) ⇒ = x+c ⎜ ⎟ =1 ⇒ dx ⎝ x ⎠ x ⇒ f(x) = x2 + cx Now as f(1) = 2 ⇒ c = 1 (however by putting x = 1 in the given relation. ∞) . and Δ2 be the area of the triangle formed by drawing tangnets at P ⎝2 ⎠ Δ and at the end points of the latus rectum. If 6 ∫ f (t) dt = 3x f(x) . 1 x Key: Sol. Let Δ1 be the area of the triangle formed by the end points of its latus rectum ⎛1 ⎞ and the point P ⎜ . . f(1) can’t be 2) So. where . f(x) = x2 + x ⇒ f(2) = 6.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 66. Let f : [1. Then 1 is Δ2 (2) 2 2 at1 2at1 1 t1 t1 1 1 2 2 2 | at 2 2at 2 1 | 2 | t 2 − t 1 t 2 − t1 0 | 2 2 2 − t2 at 2at 1 t3 t3 − t2 0 Δ1 3 3 2 = = at 2 t 3 a(t 2 + t 3 ) 1 t2 t3 t2 + t3 1 Δ2 1 | at 3 t1 a(t 3 + t1 ) 1 | | t 3 (t1 − t 2 ) t1 − t 2 0 | 2 at1 t 2 a(t1 + t 2 ) 1 t1 (t 2 − t 3 ) t 2 − t 3 0 (Applying R2 → R2 . NARAYANA IIT ACADEMY 27 . ∞) → [2. = | (t1 − t 2 ) (t 2 − t 3 )(t 3 − t1 ) | (The result is true for any three points lying on the parabola). d(tan θ) d(tan θ) 68. 2 ⎟ on the parabola. Then the value of d(tan θ) 4 4 ⎝ cos 2θ ⎠ ⎠ ⎝ (1) ⎛ π ⎛ sin θ ⎞ ⎞ π f(θ) = sin ⎜ tan −1 ⎜ ⎟⎟.x3 for all x ≥ 1.R1 and R3 → R3 . ∞) → [2.: then the value of f(2) is (6) f : [1.3x2 ⇒ f(x) = xf′ (x) .f (x) − x 3 ∀ x ≥ 1 1 x Differentiating w.< θ < .r. given f(1) = 2 6 ∫ f (t) dt = 3x.

3 + 2 So. the minimum value of |2z .3 .2i| ≤ 2. Key: Sol. 2) and radius 2 units. 5i | will be minimum when z = 3.3-2i| ≤ 2 ⇒ z will be lie on boundary or inside the circle having centre at (3.IIT-JEE2011-Code-0-Questions and Solutions-Paper-I and II 69. The value of |z . y 2 O 1 • 3 5 x 5⎞ ⎛ ⎜ 3.6 + 5i| will be 5. then the minimum value of |2z . − ⎟ 2⎠ •⎝ 28 NARAYANA IIT ACADEMY .6 + 5i| is (5) |z .: If z is any complex number satisfying |z .

PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Part – I : (CHEMISTRY) CODE . (C) and (D). of ions increases in solution.1. Road No. [Ni(H2O)6]+2 : It will formed octahedral complex since C. CN– is a strong legand so pairing of electron will take place & geometry is square planar.careerpointgroup.: 0744-3040000 Website : www. CN– and H2O. tetrahedral and square planar (B) tetrahedral. Each question has 4 choices (A). CP Tower. CAREER POINT. square planar and octahedral (C) square planar. out of which ONLY ONE is correct. Cl– is a weak legand so no pairing of electron take place and geometry is tetrahedral [Ni(CN)4]–2 : Since. IPIA.com. So conductivity increases. 1. Sol. respectively. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl–. (B). tetrahedral and octahedral (D) octahedral. square planar and octahedral Ans.9 SECTION – I (Total Marks : 21) (Single Correct Answer Type) 10/04/2011 This section contains 7 multiple choice questions. = 6 2.) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured.com 1 / 33 . Sol. [D] volume (Q) (B) (Q) (C) (R) volume (R) (D) (S) volume (S) Because in the beginning of the reaction no of ions remain constant so conductivity remains constant but after complete precipitation of Cl– the no.) Ph. are (A) octahedral. Email: info@careerpointgroup. Kota (Raj. [Ni(CN)4]–2 & [Ni(H2O)6]+2 Ni+2 = 3d84s0 [NiCl4]–2 : Now Since.N. AgNO3 (aq. [B] Complexes are : [NiCl4]–2. The plot of conductance ( Λ ) versus the volume of AgNO3 is - Λ Λ Λ Λ volume (P) (A) (P) Ans.

PAPER-1 3. the most acidic is (A) p-nitrophenol (C) o-hydroxybenzoic acid (B) p-hydroxybenzoic acid (D) p-toluic acid Ans. Email: info@careerpointgroup.com 2 / 33 . 5. IPIA. Extra pure N2 can be obtained by heating (A) NH3 with CuO (B) NH4NO3 (C) (NH4)2Cr2O7 (D) Ba(N3)2 [D] ∆ Ba(N3)2 Ba + 3N2 ↑ → Among the following compounds. positron.1. [A] 4 27 30 2 He → 15 P 13 Al Z (B) neutron. neutron 30 14 Si + + 1 0n 4 2 He 30 14 Si +1 1H 30 14 Si + 0 +1 e 4.) Ph. proton (D) positron.careerpointgroup. Kota (Raj. neutron. Sol. Ans. CP Tower. positron. Y and Z respectively are 27 13 Al (ii) 30 15 P + Y (i) 30 14 Si + X (A) proton. neutron Ans. Road No. The major product of the following reaction is O C NH C O O C (A) C O O C (i) KOH (ii) Br CH2Cl O C N–CH2 Br (B) C N O O C CH2Cl (C) N O–CH2 Br (D) N O CH2Cl CAREER POINT. Sol.: 0744-3040000 Website : www. Sol. (i) and (ii) as shown. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Bombardment of aluminum by α-particle leads to its artificial disintegration in two ways. 6. [C] o-hydroxy benzoic acid is stronger acid due to ortho effect. positron (C) proton. Products X. proton.com.

Kota (Raj. The molarity of the solution is (A) 1.15 × 10 = = 2.D] Cassiterite is SnO2. Sol. Sol. [B. CP Tower. out of which ONE OR MORE is/are correct. the compound(s) in which all the atoms are in one plane in all the possible conformations (if any). 60) in 1000 g of water gave a solution of density 1. IPIA. Each questions has 4 choices (A). Sol.78 M (B) 2. Sol. Road No. is (are) H H C–C (A) (B) H–C≡C–C H H2 C CH2 CH2 (D) H2C=C=CH2 (C) H2C=C=O Ans.com.00 M (C) 2.C] Factual. carbon reduction process is used.1.7 × 1. Dissolving 120 g of urea (mol. Email: info@careerpointgroup.15 g/mL. To reduce SnO2 into Sn.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.05 M mol wt 60 x = percentage by weight x= 120 × 100 120 + 1000 SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions.: 0744-3040000 Website : www. wt. [C] M= x × d × 10 10. [A.) Ph. [A] O C NH C O KOH O C C O NK Θ⊕ Cl–CH2– – Br O C N – CH2– C O –Br 7. (C) and (D).careerpointgroup.C. CAREER POINT. Amongst the given options. Sn has iron impurity. Extraction of metal from the ore cassiterite involves (A) carbon reduction of an oxide ore (C) removal of copper impurity (B) self-reduction of a sulphide ore (D) removal of iron impurity Ans. (B).05 M (D) 2. SnO2 + C → Sn + CO2 9. 8.com 3 / 33 .22 M Ans.

According to kinetic theory of gases (A) collisions are always elastic (B) heavier molecules transfer more momentum to the wall of the container (C) only a small number of molecules have very high velocity (D) between collisions.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 10. Paragraph for questions Nos. D] Factual. SECTION – III (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs. (C) and (D) out of which ONLY ONE is correct.com 4 / 33 . Sol. 11. 12 to 14 When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N. Each of these questions has four choices (A).: 0744-3040000 Website : www. 13. the solution turns light blue. Based upon the first paragraph 3 multiple choice questions and based upon the second paragraph 2 multiple choice questions have to be answered. Sol. NH3 dissolves O and gives an intense blue solution. CP Tower. Ans. Addition of aq. (B).careerpointgroup.) Ph.1. Email: info@careerpointgroup. Addition of aqueous NaCl to the blue solution gives a white precipitate O. B. Sol. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are) (A) Adsorption is always exothermic (B) Physiosorption may transform into chemisorption at high temperature (C) Physiosorption increases with increasing temperature but chemisorption decreases with increasing temperature (D) Chemisorption is more exothermic than physiosorption.) —→ Cu(NO3)2 + Ag light blue (B) Cu (C) Ni (D) Co (B) Zn(NO3)2 (C) Al(NO3)3 (D) Pb(NO3)2 CAREER POINT. IPIA.com. The metal rod M is (A) Fe [B] Metal rod M is Cu The compounds N is (A) AgNO3 [A] Cu + AgNO3(conc. Road No. 12. Kota (Raj. the molecules move in straight lines with constant velocities [A. Ans. Ans. Sol. Ans. however it is very slow due to higher energy of activation [A. D] Factual.

HCl H3C OH CH3–C–CH–CH3 CH3 (Q) –H2O (i) conc.1. acid (i) conc. H2SO4/HgSO4 (ii) NaBH4 (iii) dil. (i) dil.careerpointgroup. having molecular formula C6H10.com.: 0744-3040000 Website : www. Sol. The structure of compound P is (A) CH3CH2CH2CH2–C≡C–H (B) H3CH2C–C≡C–CH2CH3 H3C (C) H–C–C≡C–CH3 H3C Ans.) Ph. H2SO4/HgSO4 (ii) NaBH4/ethanol (iii) dil. The final solution contains (A) [Pb(NH3)4]2+ and [CoCl4]2– (C) [Ag(NH3)2]+ and [Cu(NH3)4]2+ [C] AgCl + NH2(aq) → [Ag(NH3)2]+ Cu+2 + NH3(aq) → [Cu(NH3)4]+2 Intense blue (B) [Al(NH3)4]3+ and [Cu(NH3)4]2+ (D) [Ag(NH3)2]+ and [Ni(NH3)6]2+ Ans. in which Q is an intermediate organic compound. Paragraph for Questions Nos. [B] Factual. CH3 CH3 C=O The structure of compound Q is H3C OH (A) H–C–C–CH2CH3 H3C H H3C OH (B) H3C–C–C–CH3 H3 C H OH OH H3 C (C) H–C–CH2CHCH3 H3 C (D) CH3CH2CH2CHCH2CH3 Ans.com 5 / 33 . CP Tower.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 14. Email: info@careerpointgroup. [D] H3C (D) H3C–C–C ≡C–H H3C CH3 CH3–C–C≡C–H CH3 (P) (i) dil. gave acetone as the only organic product through the following sequence of reactions. CAREER POINT. 15 to 16 An acyclic hydrocarbon P. Road No. IPIA. Sol. Kota (Raj. H2SO4 (catalytic amount) (–H2O) (ii) O3 (iii) Zn/H2O O P (C6H10) Q 2 H3C C CH3 15. H2SO4 H3 C CH3–C=C CH3 CH3 (ii) O3 (iii) Zn/H2O 2 16. Sol.

[6] molecule Decapeptide 9 → (x) glycine + (y) alanine + (z) phenylalanine water Mass of hydrolysed product = 796 + 18 × 9 mass of glycine = 958 × No.) Ph. n = 3 and spin quantum number.: 0744-3040000 Website : www.1. alanine and phenylalanine. 75). Sol. The number of sodium bromide molecules involved in the balanced chemical equation is. wt. Ans. Ans. 17.N. 18. 796) on complete hydrolysis gives glycine (mol. Sol. Ans. Glycine contributes 47. max e– = 2n2 = 18 Half of them can have ms = – 1/2 20. The answer to each questions is a single digit integer ranging from 0 to 9. IPIA. The number of glycine units present in the decapeptide is. Email: info@careerpointgroup.N. wt. ms = – 1/2. Road No. Sol. is. Kota (Raj.com 6 / 33 . O. [5] 3 Na2CO3 + 3Br2 → 5NaBr + NaBrO3 + 3CO2 The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is. The bubble corresponding to the correct answer is to be darkened in the ORS.26 100 450. [5] # NaO–S–S–S–S–ONa ⊕ Θ O # ∗ ∗ O O Θ⊕ O O.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – IV (Total Marks : 28) (Integer Answer Type) This section contains. [9] For n = 3.26 =6 75 CAREER POINT. The maximum number of electrons that can have principal quantum number. * S =0 S# = + 5 ∴ Difference = 5 19. Ans.careerpointgroup. solution gives sodium bromide and sodium bromate with evolution of CO2 gas. A decapeptide (mol.0% to the total weight of the hydrolysed products. of glycine unit = 47 = 450.com. CP Tower. Sol. 7 questions. Reaction of Br2 with Na2CO3 in aq.

CP Tower. Kota (Raj. Email: info@careerpointgroup. Mg Efalling = Part –II (PHYSICS) CAREER POINT. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using alcoholic KOH is.68 = 0.PAPER-1 21.7 6.) Ph. [7] Pext = 1 atm He + compounds Vapour pressure of compound = 0. the total volume (in litre) of the gases at 0ºC is close to. The number of metals which will show photoelectric effect when light of 300 nm wavelength falls on the metal is. C–C–C–C–C–C 1 2 3 4 5 6 Br alc.8 4.. at 0ºC) are introduced.1× 0. K.137 eV = λ 300 × 10−9 × 1.: 0744-3040000 Website : www.careerpointgroup.7 4.1.3 4.com Code : 9 7 / 33 .75 Ans.I C–C–C–C= C– C + G. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Sol. [5] Sol. Sol. for He n RT 0.3 2.68 ∴ PHe = 1 – 0.0 mol of an unknown compound (vapour pressure 0.62 × 10−34 × 3 × 108 = 4.2 3.6 × 10−19 The metals having less work function will show photoelectric effect Hence Li.32 ∴ By PV = nRT.68 atm.32 V ~ 7L 22. Considering the ideal gas behaviour. To an evacuated vessel with movable piston under external pressure of 1 atm.4 2. IPIA.I + C–C–C=C– C– C C–C–C–C– C– C 23.com.0821× 273 V = He = PHe 0. [4] hc 6. W Metal Li Na K Mg Cu Ag Fe Pt φ (eV) 2. The work function (φ) of some metals is listed below. Ans. Road No. Na. 0.1 mol of He and 1.KOH + G.3 4.

IPIA.com. (C) and (D) out of which ONLY ONE is correct.7 liter.5 m. [D] L θ T θ mg T cos θ = mg CAREER POINT.1. (B). Email: info@careerpointgroup.6 liter of helium gas at STP is adiabatically compressed to 0. A ball of mass (m) 0.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – I Single correct answer type This section contains 7 multiple choice questions. Road No.7 3 = T1 0. 24. of mole = 5 −1 = T1(8)2/3 = 4T1 1 4 1 × R ( 4T1 − T1 ) nR (T1 − T2 ) 9 = 4 W= = RT1 γ −1 2/3 8 25. the work done in the process is(A) Ans. Kota (Raj. 5. Each question has four choices (A).com 8 / 33 . The maximum tension that the string can bear is 324 N. Taking the initial temperature to be T1.) Ph.careerpointgroup. The maximum possible value of angular velocity of ball (in radian/s) is- L m (A) 9 (B) 18 (C) 27 (D) 36 Ans.: 0744-3040000 Website : www.7 no. Sol. CP Tower. The ball is rotated on a horizontal circular path about vertical axis. Sol. [A] T1V1γ–1 = T2V2γ–1 9 RT1 8 (B) 3 RT1 2 (C) 15 RT1 8 (D) 9 RT1 2 V1 T 2 = T1 V 2 γ −1 5.5 kg is attached to the end of a string having length (L) 0.

0) x flux through EHBA = flux through EHDC = E0a2 C (a.a. Email: info@careerpointgroup.com.0. [C] z (a.0. IPIA.a.PAPER-1 T sin θ = mω2L sin θ T = mω2L ω2max = ωmax = Tmax mL Tmax = mL 324 = 0.1.0) y z F(0.) Ph.a) (0.0.0.5 × 0.: 0744-3040000 Website : www.a.a.0) x (0.a) B (0.a.a. Road No.5 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 324 × 4 = 36 rad/s 26.0.0) y D(a.0) CAREER POINT.a) (0.a) E (a.0) y (C) E0a2 (D) E 0a 2 2 Ans.0.a) (a.a) G (0.a) A H(a. CP Tower. where E0 is a constant.a.0) x (A) 2E0a2 (B) 2E 0a 2 (0.careerpointgroup. r ˆ .a. The flux through the shaded area (as shown in Consider an electric field E = E 0 x the figure) due to this field is- z (a.a) (a.com 9 / 33 . Kota (Raj. Sol.0.

The end-corrections are 1 cm and 2 cm respectively for the ends A and B. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall building which reflects the sound waves. x 52 + 1 = 10 48 + 2 = 53 × 10 = 10.75 kHz (D) 7.50 kHz [A] Vs = 36 × 103 m/s = 10 m/s.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 27.com.51 KHz 310 28.com 10 / 33 . The galvanometer show null point when tapping-key is at 52 cm mark. V0 = 320 m/s V0 = Vs = 10 m/s Vs Observer V + V0 ν′ = V−V ′ ν s 320 + 10 = 8 KHz 320 − 10 = 330 × 8 = 8.6 50 CAREER POINT. IPIA.6 ohm (C) 10. to determine an unknown resistance 'X' using a standard 10 ohm resistor.2 ohm (B) 10. ν = 8 KHz 3600 Ans.1 ohm Ans. [B] Sol.) Ph. Sol. The frequency of the siren heard by the car driver is(A) 8.1. CP Tower.25 kHz (C) 7. The determine value of 'X' is- X 10Ω A (A) 10. A meter bridge is set-up as shown.8 ohm B (D) 11. Kota (Raj.: 0744-3040000 Website : www. Road No.careerpointgroup.50 kHz (B) 8. Email: info@careerpointgroup. The speed of sound in air is 320 m/s.

Sol. CP Tower. Sol.1. [D] 2µF 8µF ∆U = = 1 2×8 × [V – 0]2 2 2+8 8V 2 1 16 × × V2 = 2 10 10 Ui′ = 1 × 2 × V2 2 = V2 ∆U 8 × 100 = Ui 10 % dissipated = = 80% 30. Kota (Raj. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 Å. The percentage of its stored energy dissipated after the switch S is turned to position 2 is1 S V 2µF 8µF 2 (A) 0 % (B) 20 % (C) 75 % (D) 80 % Ans. Road No.6 × 4 × 16 λ CAREER POINT. The wavelength of the second spectral line in the Balmer series of singly-ionized helium atom is(A) 1215 Å (B) 1640 Å (C) 2430 Å (D) 4687 Å Ans. IPIA.6 × 6561 36 hc 3 = 13.: 0744-3040000 Website : www.6 2 − 2 6561 3 2 1 hc 1 = 13. Email: info@careerpointgroup.com.) Ph.careerpointgroup. [A] hc 1 1 = 13. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT A 2 µF capacitor is charged as shown in figure.6 × 4 2 − 2 λ 2 4 hc 5 = 13.com 11 / 33 .PAPER-1 29.

Q S RA RB Q Ans.com. Email: info@careerpointgroup.: 0744-3040000 Website : www.PAPER-1 hc 5 4 = × 6561 36 3 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT λ= λ= 5 27 6561× 5 = 243 × 5 27 = 1215 Å SECTION – II Multiple Correct Answers Type This section contains 4 multiple choice questions. Road No. Then(A) E inside =0 A (B) QA > QB (C) σA R = B σB RA surface surface (D) E on < E on B A Ans. Now they are connected by a thin metal wire. (C) and (D) out of which ONE or More may be correct.com 12 / 33 . IPIA. Each question has four choices (A). 31. [A. (B). A spherical metal shall A of radius RA and a solid metal sphere B of radius RB(<RA) are kept far apart and each is given charge '+Q'. D] Sol. [D] CAREER POINT. B.careerpointgroup.1. [B] QA RA 2 4πR A R2 σ R = A = A = B Ans [C] QB RB σB RA 2 R 4πR 2 B B as RA > RB ∴ ∴ σB > σA EB > EA Ans. CP Tower. Kota (Raj.(A) kQ A kQ B = RA RB QA R = A QB RB as RA > RB ∴ Q A > QB [Final potential will be same] Ans.) Ph. C.

[B. The rod-disc system performs SHM in vertical plane after being released from the same displaced position.: 0744-3040000 Website : www. CP Tower. Kota (Raj.careerpointgroup. IPIA. Email: info@careerpointgroup. Consider two ways the disc is attached :(case A) The disc is not free to rotate about its center and (case B) the disc is free to rotate about its center. 33.PAPER-1 32. Which of the following statement(s) is/are true ? (A) They will never come out of the magnetic field region (B) They will come out traveling along parallel paths (C) They will come out at the same time (D) They will come out at different times Ans.1. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT A metal rod of length 'L' and mass 'm' is pivoted at one end.D] An electron and a proton are moving on straight parallel paths with same velocity. Sol.com. Which of the following statement(s) is (are) true ? Ans. D] × × × × e– p v v × × × × R × p× × × × × × × ×Re× × × × × × × mp v2 me v 2 evB = evB = Rp Re m V mpv Re = e Rp = eB eB Rp > Re Te = Tp = π Re πm e = v eB πm p eB ⇒ Tp > Te CAREER POINT. Road No. A thin disk of mass 'M' and radius 'R' (<L) is attached at its centre to the free end of the rod. (A) Restoring torque in case A = Restoring torque in case B (B) Restoring torque in case A < Restoring torque in case B (C) Angular frequency for case A > Angular frequency for case B (D) Angular frequency for case A < Angular frequency for case B [A. They enter a semi-infinite region of uniform magnetic field perpendicular to the velocity.) Ph.com 13 / 33 .

Email: info@careerpointgroup.com. Road No. ∆θ A = HR A = ∆θ B = ∆θ C = ∆θ D = HL 8KA 3H 3H 4L HL RB = = 16 16 3KA 4KA H 4L HL (R C ) = H = 2 2 8KA 4KA 5H 4L HL = 16 5KA 4KA HL L ∆θ E = H = 24KA 24KA CAREER POINT. C. 8KA RD = 4L . IPIA. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT A composite book is made of slabs A. CP Tower. 5KA RE = L 24KA Using parallel combination rate of heat flow across C = rate of heat flow through B+ rate of heat flow through D. RA = L .com 14 / 33 . L) as shown in the figure. Sol.careerpointgroup.1. 3KA RC = 4L . [A. D and E of different thermal conductivities (given in terms of a constant K) and sizes (given in terms of length.: 0744-3040000 Website : www.) Ph. C. 8(KA ) RB = 4L . Then in steady stateheat 1L 0 A 1L B C 3L 5L 6L 3K E 4K 6K D 5K 4L (A) heat flow through A and E slabs are same (B) heat flow through slab E is maximum (C) temperature difference across slab E is smallest (D) heat flow through C = heat flow through B + heat flow through D Ans. Kota (Raj. Heat 'Q' flow only from left to right through the blocks. All slabs are of same width. D] 3H 16 H A 4A H 2K L A B 3K 4K 5K 4A E H 6K L 2A C A D 2 5H 16 4L All the three system shown are in series hence rate of heat flow will be same through both A & E. B.PAPER-1 34.

Email: info@careerpointgroup.: 0744-3040000 Website : www. The arrow on the curve indicates the time flow. Here we consider some simple dynamical systems in one-dimension. the phase space diagram for a particle moving with constant velocity is a straight line as shown in the figure.careerpointgroup. For example.com. Sol. Paragraph for Questions 35 to 37 Phase space diagrams are useful tools in analyzing all kinds of dynamical problems. IPIA.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – III (Paragraph type) This section contains 2 paragraphs. [D] From conservation of mechanical energy 1 1 mv 2 + mgx = mu 2 2 2 CAREER POINT. The phase space diagram for a ball thrown vertically up from ground is- Momentum Momentum (A) Position (B) Position Momentum Momentum (C) Position (D) Position Ans.. They are especially useful in studying the changes in motion as initial position and momentum are changed. (C) and (D) out of which ONLY ONE is correct. Based upon the first paragraph 3 multiple choice question and based upon on the other paragraph 2 multiple choice questions have to be answered. Kota (Raj. phase space is a plane in which position is plotted along horizontal axis and momentum is plotted along vertical axis. Road No.com 15 / 33 .1. Each of these questions has four choices (A). Momentum Position 35. (B). The phase space diagram is x(t) vs p(t) curve in this plane. CP Tower.) Ph. For such systems. We use the sign convention in which position or momentum upwards (or to right) is positive and downwards (or to left) is negative.

careerpointgroup. [C] 2 E2 (B) E1 = 2E2 (C) E1 = 4E2 (D) E1 = 16 E2 K' EMax 1 K' Emax 2 maximal position K. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT The phase space diagram for simple harmonic motion is a circle centered at the origin.E1= 0 maximal position K.) Ph. CP Tower. Consider the spring-mass system. with the mass submerged in water. Kota (Raj.: 0744-3040000 Website : www. the two circles represent the same oscillator but for different initial conditions.PAPER-1 m 2 v 2 − m 2 u 2 = 2m 2 gx p2 – p02 = 2m2gx p2 = p02 + 2m2gx 36. IPIA. Email: info@careerpointgroup. In the figure. ThenMomentum E2 2a a E1 Position (A) E1 = Ans. as shown in figure. The phase space diagram for one cycle of this system is- CAREER POINT. and E1 and E2 are the total mechanical energies respectively.E2 = 0 1 k ( 2a ) 2 E1 2 = =4 1 E2 k (a ) 2 2 E1 = 4E2 37. Road No.1. Sol.com 16 / 33 .com.

Let 'N' be the number density of free electrons. each of mass 'm'. (A) Ne mε0 (B) mε0 Ne (C) Ne 2 mε0 (D) mε0 Ne 2 Ans.com 17 / 33 . This is the explanation of high reflectivity of metals.PAPER-1 Momentum IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Momentum (A) (B) Position Position Momentum Momentum (C) Position (D) Position Ans. IPIA. they are displaced relatively away from the heavy positive ions. a time varying electric field needs to be applied that has an angular frequency ω. use dimensional analysis to determine the correct expression for ωp. When the electrons are subjected to an electric field.1. Certain solids containing fixed positive ions surrounded by free electrons can be treated as neutral plasma.com. 38. Taking the electronic charge as 'e' and the permittivity as 'ε0'. Email: info@careerpointgroup. the electrons begin to oscillate about the positive ions with a natural angular frequency 'ωp'. [B] Paragraph for Questions 38 to 39 A dense collection of equal number of electrons and positive ions is called neutral plasma.careerpointgroup. As ω approaches ωp. all the free electrons are set to resonance together and all the energy is reflected. CP Tower. [C] F = mω2l ≡ ω2 ≡ e2 4πε 0 l 2 Nl 3 l3 e2 e2 ≡ 3 mε 4πε 0 l 0 Ne 2 mε 0 ω= CAREER POINT. If the electric field becomes zero.: 0744-3040000 Website : www. where a part of the energy is absorbed and a part of it is reflected. Road No. Kota (Raj. Sol. which is called the plasma frequency. To sustain the oscillations.) Ph.

1. If we define N = 10 µ. [5] N=mgcosθ 45º mgsinθ + µmgcosθ = 3(mgsinθ – µmgcosθ) ⇒ ⇒ µ= 1 2 4µ 2 1 2 + = µ 2 2 2 = 3 2 − 3µ 2 1 N = 10µ = 10 = 5 2 41. Ans. The stick applies a force of 2 N on the ring and rolls it without slipping with an acceleration of 0. The value of P is.14 × 3 × 108 2πc mε 0 = e N Ne 2 1. A boy is pushing a ring of mass 2 kg and radius 0. The coefficient of friction between the ground and the ring is large enough that rolling always occurs and the coefficient of friction between the stick and the ring is (P/10).PAPER-1 39. The bubble corresponding to the correct answer is to be darkened in the ORS. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Estimate the wavelength at which plasma reflection will occur for metal having the density of electrons N ≈ 4 × 1027 m–3. CP Tower.com. Take ε0 = 10–11 and m ≈ 10–30.6 × 10−19 –9 = 589 × 10 m ≈ 600 nm = mε 0 (10−30 )(10−11) 4 × 1027 SECTION – IV Integer Type This section contains 7 questions. IPIA.careerpointgroup. The answer to each question is a single-digit integer. Sol. 40. Kota (Raj.3 m/s2. Email: info@careerpointgroup. then N is. CAREER POINT.) Ph. The force required to just push it up the inclined plane is 3 times the force required to just prevent it from sliding down. Road No. where these quantities are in proper SI unit(A) 800 nm (B) 600 nm (C) 300 nm (D) 200 nm Ans. A block is moving on an inclined plane making an angle 45º with the horizontal and the coefficient of friction is µ. [B] c = λf ωp = ω = λ = 2πc 2π c = λ Ne 2 mε 0 2 × 3. ranging from 0 to 9.com 18 / 33 .5 m with a stick as shown in the figure.: 0744-3040000 Website : www.

Sol.careerpointgroup.3 = 1 .8 N P 0. where 'k' is a constant. Ans. The surface tension of the soap film is γ. [3] FAC FAB +q FAD +q A D B +q C +q CAREER POINT.(1) f2 = 2 – 2 × 0. IPIA.3 = 0.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION Stick CAREER POINT Ground Ans. each of +q.1.com.) Ph. and q2 a = k γ 1/N .4 N (f2 – f1) R = Icm α a (f2 – f1) R = MR 2 × cm R f2 – f1 = Macm f1 = f2 – macm = 1. Four point charge. Then N is.8 = ⇒ P = 4 5 Note : It has been assumed that the stick applies horizontal force of 2N (only normal reaction) 42. Road No. Kota (Raj. CP Tower.4 – 2 × 0. The system of charges and planar film are in equilibrium.com 19 / 33 . Sol.: 0744-3040000 Website : www. Email: info@careerpointgroup. are rigidly fixed at the four corners of a square planar soap film of side 'a'. [4] 2N f1= µ×2 = f2 P×2 P = 10 5 mg 2 – f2 = Macm …….

1. [9] m m m l m r= m= 5 5 cm = × 10–2 m 2 2 1 kg 2 l = 4 × 10–2 m Using parallel axis theorem 2 1 5 1 Itotal = 4 × × × × 10 − 4 + 2 × × 8 × 10 − 4 5 2 4 2 ⇒ 10–4 + 8 × 10–4 ⇒ 9 × 10–4 kg m2 CAREER POINT.com. CP Tower. The momentum of inertia of the system about the diagonal of the square is N × 10–4kg-m2.5 kg are placed with their centers at the corners of a square of side 4 cm.PAPER-1 FAC = q2 8πε 0 a 2 q2 4πε 0 a 2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT FAD = FAB = FR = q2 1 2 cos 45º + 2 2 4πε 0 a = r (2) (BD) = 2 r( 2 a) 1 q2 2 + 2 ⇒ a3 = 8 2πε 0 r q2 a = k r 1/ 3 ⇒N=3 1/ 3 1 2+ 2 where k = 8 2π 43.com 20 / 33 . Email: info@careerpointgroup. Kota (Raj.) Ph.: 0744-3040000 Website : www. then N is. IPIA. Sol.careerpointgroup. Road No. Ans. Four solid spheres each of diameter 5 cm and mass 0.

1. Then the value of 'm' in kg is nearly.01 × µ 0I0 sin 300 t 100 i = 3.3 carries a current I along its curved surface as shown. A long circular tube of length 10 m and radius 0.14 × 300 µ 0I0 sin 300t × 10–3 dt φ= φ = 3. Young's modulus of steel is 1011 N/m2 and radius of the wire is 1 mm.1 m is placed inside the tube with its axis coinciding with the axis of the tube. The coefficient of linear thermal expansion of the steel is 10–5/ºC.careerpointgroup. then 'N' is. The current varies as I = I0cos(300 t) where I0 is constant. CP Tower.14 × 0. IPIA. [3] CAREER POINT. Email: info@careerpointgroup.com 21 / 33 . Sol. Kota (Raj.14 × 60 × 3. Assume that L >> diameter of the wire.14 × 300 µ 0 I 0 sin 300t × 10 −3 e = R 0.: 0744-3040000 Website : www. The mass (in mg) of the radioactive sample is. A wire-loop of resistance 0.005 ohm and of radius 0. I Ans. [6] B= µ 0 I 0 cos 300 t 10 µ 0I0 × 3. whose mean life is 109 s. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second.14 × = 5.com. If the magnetic moment of the loop is N µ 0 I0 sin(300 t).01 cos 300 t 10 dφ = 3. Ans.9 µ 0I0sin 300 t = 6 µ 0 I0 sin 300 t 46.005 0.) Ph.14 × 60 µ 0I0 sin 300 t Magnetic moment = 3. Sol. [1] A = λN 1010 = 1 ×N 109 N = 1019 mass of sample = 1019 × 10–25 × 1 × 106 = 1 mg 45. Steel wire of length 'L' at 40ºC is suspended from the ceiling and then a mass 'm' is hung from its free end. The mass of an atom of this radioisotope is 10–25 kg.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 44.14 × µ 0I0 cos 300 t × 10–3 e= − i= 3. Road No. The wire is cooled down from 40ºC to 30ºC to region its original length 'L'. Ans.

com.1. IPIA.com 22 / 33 . IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT m ∆L = mgL = Lα(∆θ) AY AYα(∆θ) π × 10 −6 × 1011 × 10 −5 × 10 = g 10 ⇒m= m = 3. (B). Let the straight line x = b divide the area enclosed by y = (1 – x)2.14 kg ⇒ 3 kg Part – III : (MATHEMATICS) SECTION – I (Total Marks : 21) Code-9 (Single Correct Answer Type) 10/04/2011 This section contains 7 multiple choice questions.) Ph. [A] Let x2 = t xdx = ln 3 dt 2 sin t 1 I= dt 2 ln 2 sin t + sin(ln6 − t ) ∫ ∫ …… (1) I= sin (ln6 − t ) 1 dt 2 ln 2 sin t + sin(ln6 − t ) 1 dt 2 ln 2 ln 3 ln 3 …… (2) Add (1) & (2) 2I = I= ∫ 1 1 3 (ln3 – ln2) = ln 4 4 2 48. y = 0.PAPER-1 Sol. CP Tower. Each question has four choices (A). and x = 0 into two parts R1(0 ≤ x ≤ b) and CAREER POINT.careerpointgroup. Email: info@careerpointgroup. The value of (A) 1 3 ln 4 2 ∫ x sin x 2 ln 2 sin x 2 + sin(ln 6 – x 2 ) (B) 1 3 ln 2 2 dx is (C) ln 3 2 (D) 1 3 ln 6 2 Ans. ln 3 47. out of which ONLY ONE is correct. Road No. Sol. (C) and (D).: 0744-3040000 Website : www. Kota (Raj.

PAPER-1 R2(b ≤ x ≤ 1) such that R1 – R2 = (A) 3 4 (B) 1 2 IITIIT-JEE 2011 2011 EXAMINATION 1 . CP Tower. Email: info@careerpointgroup. Then b equals 4 (C) 1 3 (D) 1 4 CAREER POINT Ans. whose projection on c is ˆ (A) iˆ – 3 ˆ j + 3k → → → → → → → 1 3 . A vector v in the plane of a ˆ – ˆ Let a = iˆ + ˆ j + k j + k j – k and b . Road No. Kota (Raj.careerpointgroup. IPIA.) Ph. Sol. b = iˆ – ˆ ˆ and c = i ˆ be three vectors.(1) Q projection CAREER POINT.1. is given by ˆ (C) 3 iˆ – ˆ j + 3k ˆ (D) iˆ + 3 ˆ j – 3k ˆ (B) – 3 iˆ – 3 ˆ j – k Ans.com.com 23 / 33 . Sol. [C] → ˆ Let ν = x iˆ + y ˆ j + zk Q [a 1 1 → → b → ν]=0 1 1 −1 1 = 0 x y z On solving x = z ….: 0744-3040000 Website : www. [B] R1 0 b R2 1 R 1 – R2 = 1 4 ∫ 0 b ( x − 1) 2 dx – b ∫ ( x − 1) b 1 2 dx = 1 4 ( x − 1) 3 ( x − 1) 3 1 – = 4 3 0 3 b (b − 1) 3 1 (b − 1) 3 1 + –0+ = 3 3 3 4 2(b − 1) 3 1 1 −1 – = = 4 3 3 12 1 (b – 1)3 = – 8 1 1 b–1= − ⇒ b= 2 2 1 49. ˆ .

Kota (Raj. If L also 3y–x+3+2 3 =0 (D) 3y+x–3+2 3 =0 Ans. Road No. CP Tower. If an = αn – βn for n ≥ 1.. (2x)ln 2 = (3y)ln 3 3ln x = 2ln y Then x0 is 1 (A) 6 [C] (2x)ln 2 = ( 3y)ln 3 Let (x0.com. Sol. a10 − 2a8 (α 10 − β10 ) − 2(α 8 − β 8 ) α 8 (6α) − β 8 (6β) α 8 (α 2 − 2) − β 8 (β 2 − 2) = = = = 3. –2) is inclined at an angle 60° to the line intersects the x-axis.(2) ln x = – ln 2 ⇒ x = 51. = ν. α2 – 2 = 6α & β2 – 2 = 6β an = αn – βn So. ln 2 ln y = ln x ln3 ln 2 Solving (1) & (2) 1 2 a10 – 2a8 is 2a 9 . Let α and β be the roots of x2 – 6x – 2 = 0. (C) 3 (D) 4 Ans. Email: info@careerpointgroup. [B] CAREER POINT. ln x – ln 3 ln y = (ln 3)2 – (ln 2)2 3 ln x ..careerpointgroup. IPIA. ln 3 = lny .PAPER-1 of ν on c is 1 3 → → IITIIT-JEE 2011 2011 EXAMINATION 1 3 → → CAREER POINT So...com 24 / 33 . β So..: 0744-3040000 Website : www.1.(1) =2 ln y ln x . y0) be the solution of the following equations (B) 1 3 (C) 1 2 (D) 6 Ans. with α > β... then the equation of L is (A) y + (C) 3x+2–3 3 =0 (B) y – 3x+2+3 3 =0 3 x + y = 1.c |c| → ⇒ x− y−z = 1 3 …. Sol. A straight line L through the point (3..(2) 3 ⇒ x–y–z=1 So solving (1) & (2) y = –1 & x = z 50.) Ph. then the value of (A) 1 (B) 2 [C] ∴ x2 – 6x – 2 = 0 has roots α. 2a 9 2(α 9 − β 9 ) 2(α 9 − β 9 ) 2(α 9 − β 9 ) 52. ln 2 (ln 2 + ln x) = ln 3 (ln 3 + ln y) ln 2 .

PAPER-1 Sol. CP Tower.com 25 / 33 .: 0744-3040000 Website : www.1. 3x+2+ 3 3 =0 2 cos θ} and Q = {θ : sin θ + cos θ = (B) Q ⊄ P (D) P = Q 2 sin θ} be two sets. y – 53. Let P = {θ : sin θ – cos θ = (A) P ⊂ Q and Q – P ≠ ∅ (C) P ⊄ Q [D] P : sin θ – cos θ = tan θ = 2 cos θ sin θ = ( 2 + 1) cos θ 2+1 tan θ = tan 67 1 ° 2 θ = nπ + 3π . Road No.) Ph. Then Ans.n∈I 8 ……(2) CAREER POINT. Kota (Raj.careerpointgroup. Sol.n∈I 8 2 sin θ ……(1) Q : sin θ + cos θ = 1 2 −1 cos θ = ( 2 – 1) sin θ tanθ = θ = nπ + ∴ P=Q = 2 +1 3π . m + m+ m=0 3 = 3 – 3m 3 = – 3 + 3m 3 3 (x – 3) hence line y=–2 hence line y+2= y– 3x+2+ 3 3 =0 as line intersects x-axis So line will be. Email: info@careerpointgroup. IPIA. Let the slope of the line is m tan 60º = m+ 3 1 − 3m IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 3 = m+ 3 1 − 3m 3 =± 3 (1 – 3 m) m+ m= So.com.

(B). r .D] ˆ is coplanar with the given vector so ˆ + yˆ r = xi j + zk x y z ∴ 1 1 2 =0 1 2 1 So.careerpointgroup.) Ph. IPIA. (i j+k So.. y ∈ R If f(x) is differentiable at x = 0. Kota (Raj. CP Tower.com.1. Each question has four choices (A).com 26 / 33 . [A. Sol.. (C) and (D). ˆ and iˆ + 2 ˆ ˆ . and perpendicular to the The vector(s) which is/are coplanar with vectors iˆ + ˆ j + 2k j + k ˆ is /are ˆ + ˆ vector i j + k ˆ (A) ˆ j – k (B) – iˆ + ˆ j (C) iˆ – ˆ j ˆ (D) – ˆ j + k Ans.. out of which ONE OR MORE may be correct. 54. x = 0 ∴ y+z=0 . Road No. then (A) f(x) is differentiable only in a finite interval containing zero (B) f(x) is continuous ∀ x ∈ R (C) f '(x) is constant ∀ x ∈ R (D) f(x) is differentiable except at finitely many points [B...C] f(x + y) = f(x) + f(y) By Partial differentiation with respect to x f ' (x + y) = f ' (x) f ' (y) = f '(0) f(y) = (f '(0))y + c f(y) = ky +c ∴ f(y) = ky as f(0) = 0 ∴ f(x) = kx Alternate f ( x + h) − f ( x ) f '(x) = lim h →0 h f ( x ) + f ( h) − f ( x ) f ( h) = lim = lim h →0 h → 0 h h CAREER POINT.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions.(2) ∴ (A) & (D) Satisfy → 55.. x + y + z = 0 On solving (1) & (2) So. ∀x.. Email: info@careerpointgroup. Ans. Let f : R → R be a function such that f(x + y) = f(x) + f(y). 3x = y + z ˆ ∴ r ⊥ iˆ + ˆ j+k → .(1) ˆ) = 0 ˆ+ ˆ So.: 0744-3040000 Website : www.. Sol.

com. Email: info@careerpointgroup. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. y2 = 1 be reciprocal to that of the ellipse x2 + 4y2 = 4. 0) Hyperbola passes through it So. 0) ≡ (± 3 . the most suitable answer is (C). 0) CAREER POINT. Road No. Let M and N be two 3 × 3 non-singular skew-symmetric matrices such that MN = NM. Sol.com 27 / 33 . CP Tower.PAPER-1 = λ (let) f(x) = λx + c As f(0) = 0 ⇒ c = 0 f(x) = λx 56.D] Let e1 = eccentricity of hyperbola e2 = eccentricity of ellipse 1 ∴ e1 = e2 so eccentricity of ellipse = 3 = e2 2 2 eccentricity of ellipse = = e1 3 Now focus of ellipse is (± ae2. 0) ≡ (± 2.: 0744-3040000 Website : www. then Let the eccentricity of the hyperbola x2 – (A) the equation of the hyperbola is x2 y2 – = 1 (B) a focus of the hyperbola is (2. Kota (Raj. – 0 = 1 ⇒ a2 = 3 a2 also b2 = a2 (e12 – 1) ( 3) 2 4 b2 = 3 – 1 = 1 3 and hyperbola x2 y2 − =1 3 1 also focus (± ae1.careerpointgroup.) Ph. 0) 3 2 5 3 (C) the eccentricity of the hyperbola is (D) the equation of the hyperbola is x2 – 3y2 = 3 Ans. (MN–1)T = – MN MN N–1 M–1 N–1 M M I = –M NN–1 M = – M2 Although. M2N2(MTN)–1.1. Sol. [B. If the 2 2 b a hyperbola passes through a focus of the ellipse. If PT denotes the transpose of P. then M2N2 (MTN)–1(MN–1)T is equal to (A) M2 (B) –N2 (C) –M2 (D) MN [C] Q MN = NM M2 N2 = MN MN Q (MT)–1 = (–M)–1 = –M–1 Given. IPIA. But given information is contradictory as Skew symmetric matrix of odd order cannot be non singular 57.

then the value of Ans. CP Tower. Kota (Raj. λ 7 7 ∴ a = 2 is given so λ = – 14 So (a. Sol. Ans. with reference to (E). b. 1 3 + c is equal to b ω ω ω (A) –2 (B) 2 [A] a 3 + (C) 3 (D) –3 λ 6λ ∴ (a.PAPER-1 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – III (Total Marks : 15) (Paragraph Type) This section contains 2 paragraphs.: 0744-3040000 Website : www. b. – 14) So 3 ω a + 1 ω b + 3 ωc = –2 CAREER POINT. c).− . 58 to 60 Let a. c) ≡ − . c) ≡ (2.com 28 / 33 .− . c) ≡ − . Each of these questions has four choices (A). c) lies on the plane 2x + y + z = 1 2λ 6λ – +λ=0 7 7 on solving λ = – 7 So 7a + b + c = 6 So − 59. then the value of 7a + b + c is (A) 0 (B) 12 (C) 7 (D) 6 [D] 1 9 7 [a b c] 8 2 7 = [0 0 0] 7 3 7 a + 8b + 7c = 0 9a + 2b + 3c = 0 7a + 7b + 7c = 0 On solving above equation λ 6λ (a. (B). Road No.(E) 58. lies on the plane 2x + y + z = 1. λ 7 7 ∴ (a.1. Paragraph for Question Nos.) Ph. 12. Based upon one of the paragraphs 3 multiple choice questions and based on the other paragraph 2 multiple choice questions have to be answered. If a = 2 with b and c satisfying (E). If the point P(a. b.careerpointgroup.com. b. (C) and (D) out of which ONLY ONE is correct. Email: info@careerpointgroup. Let ω be a solution of x3 – 1 = 0 with Im(ω) > 0. b. b and c be three real numbers satisfying 1 9 7 [a b c] 8 2 7 = [0 0 0] 7 3 7 ……. IPIA. Sol.

1.com 29 / 33 . However. U1 U2 both W both R Required probability = P(H)[P(W/H) × P(W2) + P(R/H)P(W2)] + P(T) [P P(W2) + P T T R & W1 P(W2) + P 1 P(W2)] T = = 2 1 3 2 1 1 3 C2 C2 1 3 C1 × 2C1 2 × 1 + × + × 1 + × + 5 × 5 5 2 5 2 3 C2 3 C2 5 2 C2 1 3 1 1 3 1 2 2 11 23 + + + + = + = 2 5 5 2 10 30 5 5 30 30 CAREER POINT. B = – 7 S= ∑ 1 1 α + β n=0 n ∞ n = ∑ 1 1 − 1 7 2 n = ∑ 1 6 6 6 + + . A fair coin is tossed. c) ≡ − . Sol. So (a. Now 1 ball is drawn at random from U2. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Let b = 6.. The probability of the drawn ball from U2 being white is 13 23 19 (A) (B) (C) 30 30 30 [B] 3W 1W 2R 11 30 (D) Ans..: 0744-3040000 Website : www. Kota (Raj. then ∑ Ans.PAPER-1 60.com. with a and c satisfying (E). IPIA. 61.. CP Tower. b. and U2 contains only 1 white ball. ∞ =1+ 7 7 7 = 6 1− 7 = 7 Paragraph for Question Nos. Sol. If α and β are the roots of the quadratic equation ax2 + bx + c = 0.λ ∴ (a. –7) So the equation ax2 + bx + c = 0 x2 + 6x – 7 = 0 So α = 1. If head appears then 1 ball is drawn at random from U1 and put into U2. 6.) Ph. Email: info@careerpointgroup. [B] 1 1 α + β is n=0 (B) 7 (C) 6 7 (D) ∞ ∞ n (A) 6 λ 6λ .− 7 7 ∴ b=6 so λ = – 7. Road No.careerpointgroup. c) ≡ (1. b. if tail appears then 2 balls are drawn at random from U1 and put into U2. 61 and 62 Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls.

: 0744-3040000 Website : www. The bubble corresponding to the correct answer is to be darkened in the ORS. 1 ≤ p ≤ 100. IPIA. Sol. [9] a1 = 3 5n [2a1 + (5n − 1) d ] Sm S5n = = 2 n Sn Sn [2a1 + (n − 1) d ] 2 5[(6 − d ) + 5nd ] = (6 − d ) + nd Q S5 n is independent of n so d = 6 Sn So a2 = a1 + d = 3 + 6 = 9 64. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Kota (Raj.careerpointgroup. …. a3. CP Tower. then a2 is Sn ∑a i =1 p i . For any integer Ans.PAPER-1 62. Then ∆1 is ∆2 Ans. Let a1. If Sm does not depend on n. Sol. Given that the drawn ball from U2 is white. 63.) Ph. Road No. and ∆2 be the area of the triangle formed by drawing tangents at P 2 and at the end points of the latus rectum. ranging from 0 to 9.. Consider the parabola y2 = 8x. let m = 5n.. Sol. a2. Email: info@careerpointgroup. Let ∆1 be the area of the triangle formed by the end points of its latus rectum 1 and the point P .com 30 / 33 . The answer to each of the questions is a single-digit integer. 2 on the parabola. [2] It is a property that area of triangle formed by joining three points lying on parabola is twice the area of triangle formed by tangents at these points Alternate : y2 = 8x CAREER POINT.1. a100 be an arithmetic progression with a1 = 3 and Sp = n with 1 ≤ n ≤ 20. the probability that head appeared on the coin is 17 11 15 12 (B) (C) (D) (A) 23 23 23 23 [D] Required probability W R P ( H ) P 1 P(W2 ) + P 1 P(W2 ) H H = W1 R R & W1 both W both R P ( H ) P P(W2 ) + P 1 P(W2 ) + P(T ) P P(W2 ) P (W2 ) + P P (W2 ) + P 1 T H T H T 1 3 2 1 ×1 + × 2 5 5 2 12 = = 23 13 30 SECTION – IV(Total marks : 28) (Integer Answer Type) This section contains 7 questions.com.

4)A • P • 3/2 • B(2. The positive integer value of n > 3 satisfying the equation 1 1 1 = + is π 2π 3π sin sin sin n n n Ans. 3). 0). IPIA.com 31 / 33 .PAPER-1 1 P .1. M (1. [7] CAREER POINT.: 0744-3040000 Website : www. –1) −2 0 1 1 ∆2 = 1 3 1 2 −1 −1 1 =| = So. –4) 1 |Base × Height| 2 1 3 = × ×8 =6 2 2 Also ∆1 = 1 Equation of tangent at P . 2 2 • •P • • 1 y (2) = 4. N (–1. Kota (Raj.com. Email: info@careerpointgroup.(1) Tangent at A : y = x + 2 Tangent at B : – y = + x + 2 ⇒ y = – x – 2 Point of intersection L(–2.careerpointgroup. x + 2 y = 2x + 1 …. 1 [–2(4) + (–1 + 3)]| 2 1 [−8 + 3 − 1] = 3 2 ∆1 6 = =2 ∆2 3 65.) Ph. Road No. 2 2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT (2. CP Tower.

1. a–4. a–4. Email: info@careerpointgroup. If z is any complex number satisfying | z – 3 – 2i| ≤ 2. 1.M.com. Sol. Min of |2z – 6 + 5i| = PA 5i 5 = Min 2 z – 3 + =2× =5 2 2 68. then the minimum value of | 2z – 6 + 5i| is [5] (3. where – 4 < θ < 4 .com 32 / 33 . a–3. 1. a–3. Ans. a–3. a –5 + a –4 + a –3 + a –3 + a –3 + 1 + a 8 + a10 ≥ (a–5. Ans.PAPER-1 Sol. Let π =θ n IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 1 1 1 = + sin θ sin 2θ sin 3θ 1 1 1 – = sin θ sin 3θ sin 2θ [sin 3θ – sin θ] sin 2θ = sin θ sin 3θ 2 sin θ cos 2θ sin 2θ = sin θ sin 3θ Q sin θ ≠ 0 2 cos 2θ sin 2θ = sin 3θ sin 4θ = sin 3θ so either 4θ = 3θ or 4θ = π – 3θ π so θ = 0 or θ = so n = 7 7 66. Sol. Road No.: 0744-3040000 Website : www. IPIA. –1 sin θ d π π Let f(θ) = sin tan cos 2θ . 3a–3. Ans.) Ph. ≥ G. Kota (Raj. CP Tower. Then the value of d (tan θ) (f (θ)) is [1] sin θ –1 Q tan–1 = sin tan θ cos 2θ so f (θ) = sin (sin–1 tan θ) = tan θ d ( f (θ)) d (tan θ) Q = =1 d (tan θ) d (tan θ) 67.– 2 So. a8 . The minimum value of the sum of real numbers a–5.M.a10)1/8 8 a–5 + a–4 + a–3 + a–3 + a–3 + 1 + a8 + a10 ≥ 8 so minimum value is 8 CAREER POINT. a8 and a10 with a > 0 is [8] A. 2) B Min value A 5 P 3.careerpointgroup. Sol.

careerpointgroup.com. ∞) be a differentiable function such that f(1) = 2. = e ∫ –1 dx x = e–ln x = 1 x y.PAPER-1 69. Road No. Kota (Raj. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Let f : [1. Email: info@careerpointgroup.F. If 6 f (t ) dt = 3x f(x) – x3 for all x ≥ 1.com 33 / 33 . x dx ⇒ 1 y = x + c ⇒ y = x2 + cx x Q f(1) = 2 ⇒ c = 1 y = x2 + x f(2) = 4 + 2 = 6 CAREER POINT. ∞) → [2. CP Tower.) Ph.1. 1 ∫ x Ans.: 0744-3040000 Website : www. IPIA. then the value of f (2) is [6] 6 ∫ f (t ) dt 1 x = 3xf(x) – x3 6 f(x) = 3f(x) + 3xf '(x) –3x2 3f(x) = 3x f '(x) – 3x2 dy 3y = 3x – 3 x2 dx dy x – y = x2 dx y dy – =x dx x I. Sol. 1 = x ∫ x.

IPIA. (B).com. Kota (Raj.1. F e2 O 3 Ans. Each question has 4 choices (A).: 0744-3040000 Website : www. Road No. Ans. out of which ONLY ONE is correct.careerpointgroup. [D] +3 Haematite is F e 2 O 3 +2 +3 Magnetite is Fe3O4 or F eO .) Ph. Email: info@careerpointgroup. [B] Aldohexose CAREER POINT. Sol. CP Tower. (C) and (D).9 Part – I : (CHEMISTRY) SECTION – I (Total Marks : 24) (Single Correct Answer Type) 10/04/2011 This section contains 8 multiple choice questions. Sol.com 1 / 38 .PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT CODE .

Email: info@careerpointgroup.: 0744-3040000 Website : www. Kota (Raj. O R. CP Tower.) 0–5° C CH3 N2 Cl OH Alkaline solution OH CH3 H=N Coloured dye CAREER POINT.com. [B] Sol.CH2 –OH ⊕ H (anhydrous) O OCH2–R Acetal Ans.com 2 / 38 . IPIA.careerpointgroup.1.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Road No. Sol. [C] CH3 NH2 NaNO2 + HCl (dil.) Ph.

Email: info@careerpointgroup.67 − .careerpointgroup. CP Tower. [D] Ecell = E°cell − . Sol.: 0744-3040000 Website : www.3 × 10 –2 Ans. Hg +2 +2 are group II basic radicals CAREER POINT.com.1][10 −3 ] 4 = 1.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.26 × 10 ≈ 2. Kota (Raj.1 × 4 × 1000 329 × 100 –2 = 2. [A] ∆T = kf × m × i × 1000 = 1.0591 [Fe +2 ] log 4 [PO ][H + ] 4 2 = 1.) Ph.591 [10 −3 ] 2 log 4 [. Road No.57 V Ans. Sol.1.com 3 / 38 . [A] Cu .86 × 0 . IPIA.

IPIA.) Ph. [A. D] CAREER POINT.careerpointgroup. (B).com. CP Tower. [C] (L) : [Co(NH3)6]Cl3 (M) : Na3[Co(Ox)3] (O) : K2[Pt(CN)4] (P) : [Zn(H2O)6] (NO3)2 SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. C. out of which ONE OR MORE is/are correct.1. Kota (Raj. B. KMnO4 is first reduced to mangnate and then to insoluble MnO2 +7 +4 → Neutral 2KMnO 4 + H2O → 2MnO 4 + 2KOH + 3[O] acidic − MnO 4 + 8H + + 5e − → Mn +2 + 4H2 O →I Ans.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Email: info@careerpointgroup. Road No. (C) and (D). Each questions has 4 choices (A).: 0744-3040000 Website : www. D] → In alkaline solution. Ans. Sol. [A.com 4 / 38 .

) Ph.PAPER-2 Sol. IPIA. B. C. Cu2(CN)2 and Cu2 (SCN)2 are stable Ans. [A.careerpointgroup. Road No.: 0744-3040000 Website : www. Sol. Kota (Raj.4 1 4 100 = 8 [D] = = =n= 100 2 100 1 log 2 Ans. [B. CP Tower.693 Ea / RT = = e [B] − E / RT a K A0 A 0e 4 4 log 0 . Email: info@careerpointgroup. D] Factual CAREER POINT. C. D] Cu2 Cl2.1.com. Sol.693 0. IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT C A = C A 0 e −kt [ A ] t1 = 2 0.693 0.com 5 / 38 .

Road No. Sol.com. The total bubble corresponding answer it to be darkened in the ORS.careerpointgroup.) Ph.6 × 10 −10 1.0 × 10 −6 = 1.com 6 / 38 . The answer to each of the question is a single-digit integer.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – III (Total Marks : 24) (Integer Answer Type) This section contains 6 Question. Ans. [7] [ Ag + ] = K1 K1 + K 2 Q K1 < < K2 ∴ K 1 + K 2 ≅ K 2 ∴ [ Ag + ] = 1. Email: info@careerpointgroup. [4] PCl5 + H2O → POCl3 + 2HCl PCl5 + H2SO → POCl3 + H2O + SO2Cl2 6PCl5 + P4O10 → 10POCl3 PCl5 + SO2 → POCl3 + SO2Cl2 CAREER POINT. Sol. Sol. IPIA. Kota (Raj. [8] CH3–CH2 –CH –CH3–CH3 CH3 Cl or CH3 –CH2 –C–CH2– CH3 (1) CH3 Cl2 / hν * Cl–CH2 –CH2 –CH–CH2– CH3 or (2) CH3 CH3 –CH2 –CH–CH2– CH3 (1) CH2Cl * * CH3 –CH –CH–CH2– CH3 (4) Cl CH3 or Ans. CP Tower.1.: 0744-3040000 Website : www. ranging from 0 to 9.6 × 10 –7 x=7 Ans.

careerpointgroup. Road No.1 V = 30 × 0. Email: info@careerpointgroup. IPIA.com. [6] 0. Sol.01 × 2 V= 0. [6] 6 (α – H → 6) CAREER POINT. Kota (Raj.3 × 2 = 6 ml 0. Sol. Sol.1 Ans. CP Tower. [8] 8 Hexagonal faces Ans.1.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.com 7 / 38 .: 0744-3040000 Website : www.) Ph.

PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – IV (Total Marks : 16) (Matrix-Match Type) This section contain 2 questions. Sol. q. r. C and D) given in column I and five statements (p.careerpointgroup.com 8 / 38 . D → p.1. [A → p. Any given statement in column I can have correct matching with ONE or MORE statement (s) given in Column II.com. darken the bubbles corresponding to q and r in the ORS Ans. For example. t] [A] CO2(s) → CO2(g) p. q. s [C] [D] 2H → H2 (g) t Pwhite → Pred p. Kota (Raj. s. t CAREER POINT. s. Road No. IPIA.: 0744-3040000 Website : www. statement B matches with the statements given in q and r. B → r. then for the particular question. q. Each question has four statements (A. s and t) in column II. if for a given question. r. C → t . against statement B. r.) Ph. s [B] CaCO3 (s) → CaO (s) + CO2(g) r. CP Tower. Email: info@careerpointgroup. B.

q] Factual CAREER POINT.com. Kota (Raj. Sol. [A → r. s. s . IPIA. t. C → r. B → p. CP Tower.) Ph.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.com 9 / 38 . s.: 0744-3040000 Website : www. t. D → r.careerpointgroup. Email: info@careerpointgroup.1. Road No.

careerpointgroup.1. [8] CH3–CH2 –CH –CH3–CH3 CH3 Cl or CH3 –CH2 –C–CH2– CH3 (1) CH3 Cl2 / hν * Cl–CH2 –CH2 –CH–CH2– CH3 or (2) CH3 CH3 –CH2 –CH–CH2– CH3 (1) CH2Cl * * CH3 –CH –CH–CH2– CH3 (4) Cl CH3 or Ans.0 × 10 −6 = 1. IPIA.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – III (Total Marks : 24) (Integer Answer Type) This section contains 6 Question. [4] PCl5 + H2O → POCl3 + 2HCl PCl5 + H2SO → POCl3 + H2O + SO2Cl2 6PCl5 + P4O10 → 10POCl3 PCl5 + SO2 → POCl3 + SO2Cl2 CAREER POINT. Email: info@careerpointgroup.: 0744-3040000 Website : www. CP Tower. Sol. Kota (Raj.6 × 10 −10 1. ranging from 0 to 9.6 × 10 –7 x=7 Ans. The answer to each of the question is a single-digit integer. Sol. The total bubble corresponding answer it to be darkened in the ORS. Ans.) Ph.com 10 / 38 . Road No.com. [7] [ Ag + ] = K1 K1 + K 2 Q K1 < < K2 ∴ K 1 + K 2 ≅ K 2 ∴ [ Ag + ] = 1. Sol.

[6] 0.3 × 2 = 6 ml 0.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.1 Ans. IPIA.01 × 2 V= 0. [6] 6 (α – H → 6) CAREER POINT. Sol. Sol. [8] 8 Hexagonal faces Ans. Kota (Raj.com 11 / 38 .: 0744-3040000 Website : www. CP Tower.careerpointgroup.1 V = 30 × 0. Email: info@careerpointgroup. Sol. Road No.1.com.) Ph.

r.careerpointgroup.: 0744-3040000 Website : www. r. s [C] [D] 2H → H2 (g) t Pwhite → Pred p. statement B matches with the statements given in q and r. s [B] CaCO3 (s) → CaO (s) + CO2(g) r. s. Sol. B → r. darken the bubbles corresponding to q and r in the ORS Ans. B. r. Each question has four statements (A. t] [A] CO2(s) → CO2(g) p. C and D) given in column I and five statements (p. Road No. Email: info@careerpointgroup.com.com 12 / 38 . Kota (Raj. [A → p. q. IPIA. D → p. For example. CP Tower. q. C → t . s and t) in column II. against statement B. q. then for the particular question.1.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – IV (Total Marks : 16) (Matrix-Match Type) This section contain 2 questions. s. if for a given question. t CAREER POINT.) Ph. Any given statement in column I can have correct matching with ONE or MORE statement (s) given in Column II.

Road No.: 0744-3040000 Website : www.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. t. s.careerpointgroup. IPIA. s. t. s . CP Tower.1. [A → r.) Ph. B → p. C → r. Sol.com. q] Factual CAREER POINT.com 13 / 38 . Kota (Raj. D → r. Email: info@careerpointgroup.

careerpointgroup.: 0744-3040000 Website : www. Email: info@careerpointgroup.1. T + R = 100 % and R > 0 T θc CAREER POINT.com 14 / 38 .PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Code : 9 10/04/2011 Ans. Kota (Raj.) Ph. no ray will transmit ⇒ T = 0. IPIA. CP Tower.[C] θ θ e When θ > θC. Road No.com.

7 CAREER POINT.: 0744-3040000 Website : www. the mean position will be shifted towards right but the time period will remain unaffected.5 = 0.5 mm + (20 × 0.com 15 / 38 . Road No.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.01) mm = 2. IPIA.[A] In order to have net force zero. Kota (Raj.com.1. Email: info@careerpointgroup.01 × 100 = 2 % + 3 × 100 = 3.2 mm = 2.7 mm ρ= m 4π D 3 2 3 ∆ρ ∆m ∆D = +3 ρ m D %error = ∆ρ 0.5 mm + 0.[C] Pitch = 0.) Ph.careerpointgroup. Ans.01 50 main scale.5 mm divisions on the = 50 circular scale ⇒ least count of screw gauge = 0.5 mm circular scale reading = 20 ⇒ reading = 2. reading = 2.1. CP Tower. ρ 2 .

2 × 20) 0.: 0744-3040000 Website : www.01 kg m2 = 0.01 × v = (0. CAREER POINT.com 16 / 38 . v2 × 1 = 20 ⇒ & v1 = 100 From conservation of momentum 0. Email: info@careerpointgroup.[D] m1 = 0. IPIA.1.01 × 100) + (0. CP Tower.01 v = 1 + 4 = 5 v= 5 10 − 2 v2 = 20 = 500 m/sec.2 kg v H = 5m Ball 20 m 100 m Bullet T= 2H = 1 sec g Let v1 & v2 be velocity of bullet & ball respectively just after collision.com. Kota (Raj.careerpointgroup.) Ph.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Road No.

careerpointgroup.[B] A 30º 120º θ A Here φ = π + θ A cos 30º = B sin θ ⇒ B sin θ = 3A A and A sin 30º + B cosθ = A ⇒ B cos θ = 2 2 π 4π Solving above. Kota (Raj. Email: info@careerpointgroup. B = A and θ = 60º = .1. Ans.com. IPIA.) Ph. CP Tower.com 17 / 38 .[C] Electric lines of force for induced electric field is closed loop.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Hence φ = 240º = 3 3 B CAREER POINT.: 0744-3040000 Website : www. Road No.

Road No.com 18 / 38 . of turns per unit thickness = N b−a magnetic field at centre due to element = dB = B= = µ 0i N dr 2r b − a µ 0 (dN)i 2r µ 0iN 2(b − a) ∫r a b dr µ 0iN b ln 2(b − a) a CAREER POINT.: 0744-3040000 Website : www. Kota (Raj. CP Tower. Email: info@careerpointgroup.1.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. IPIA.) Ph.careerpointgroup.com.[A] y dr a r x b No.

1. of mass m = was k then from E=K– GmM e GMe 2 = 0 ⇒K = m = mv r r CAREER POINT.(1) If K.. Road No.. Kota (Raj. IPIA..careerpointgroup.com.) Ph.com 19 / 38 .PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. CP Tower.E. Email: info@careerpointgroup.[B] V M • r ⇒ GmM e mv 2 = r r2 ⇒ r= GMe V2 .: 0744-3040000 Website : www.

1.D] Ans. CP Tower.C] R C 1 Z1 = R 2 + ωC 2 ~ R 4C 1 Z2 = R2 + 4 ωC 2 ~ z1 > z2 A VC = A IK ωC ∴ A B IR < IR B VC = .com 20 / 38 . Road No.D] IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Vdfg A VdAg Vdfg B VdBg system will be in equilibrium with tension in string only if df > dA and dB > df. Kota (Raj.[B.PAPER-2 Ans.[A. IPIA. IB K .com.: 0744-3040000 Website : www. If both A & B are considered as a system then ⇒ dA + dB = 2df 2Vdfg = V (dA + db)g Ans. 4ωC B A VC < VC CAREER POINT.) Ph. Email: info@careerpointgroup.B.[C.careerpointgroup.

com 21 / 38 . Email: info@careerpointgroup.C] CAREER POINT.) Ph.: 0744-3040000 Website : www. CP Tower.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. IPIA. Road No. Kota (Raj.careerpointgroup.com.1.[A.

[5] IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT VA – VB 6 3 + 6 + 1 . IPIA.careerpointgroup. Ans.PAPER-2 Ans.15 2 (a : acceleration of train) a = 5 m/sec2 CAREER POINT. Email: info@careerpointgroup.25 R 500 C ⇒ 1 = 0.: 0744-3040000 Website : www.5R 500C 1 = RC 2500 1 = RC 250 0.25 1 2 =Z 500C 1 2 = R × 1.1.004 sec = RC RC = 4 mill second. Road No. 25 500C 2 2 2 R2 + 1 2 = 0. Kota (Raj.[4] Z = R τ = RC R2 + 1. 5 3= 1 × a × ( 3 )2 + 1. CP Tower. 5 7.com 22 / 38 .5 1.5 + 1 2 Ans.com. 5 = 1 2 = = = 5V 1 1 1 .[5] T = 2 × 10 × 3 = 2 × 10 3 sec x = 10 cos 60° (T) = 5 3 m In frame of train.) Ph.

com.1. = (18 –16) cm = 2 cm µ 3 µ1 µ 2 − µ1 µ 3 − µ 2 = + − R1 R2 v u 4 7 7 − −1 1 4 – = 4 + 3 4 − 24 ∞ 3V 6 ⇒ 1 4 1 + = ⇒ 24 8 3V 1 4 = ⇒ V = 16 cm 3 V 12 Ans.18 × 10 × 0.1 × 0.18) u = × 2 × 36 × 10–4 + 0. CP Tower.[2] ∴ Ans.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.careerpointgroup.) Ph.[4] k = 2N/m m = 0.4 m/sec. Kota (Raj. 10 CAREER POINT.com 23 / 38 . Road No. IPIA. Email: info@careerpointgroup.18 kg µ = 0. ⇒ 4 m/sec.: 0744-3040000 Website : www.06 2 2 ⇒ u = 0.1 Using W – E theorem 1 1 × m(u)2 = K (x)2 + µmg (x) 2 2 1 1 2 × (0.

) Ph. Kota (Raj.com. of photoelectron emitted n = = 1.5V q = 1.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.com 24 / 38 .[7] Energy of photon ≈ 1240 ev = 6.1.6 × 10 −19 No.2 eV 200 Maximum KE of a electron = 6. IPIA. Email: info@careerpointgroup.5 × ( 4πε0 )r 1.7 eV When potential on surface of sphere becomes equal to 1.careerpointgroup. 04 × 107 CAREER POINT. CP Tower. Road No.: 0744-3040000 Website : www.5 × (4π ε0) × r 1.5 V 4π ∈0 r ⇒ q = 1.2 eV – 4.

Email: info@careerpointgroup.: 0744-3040000 Website : www.com 25 / 38 .com.s.t. (B) → p.) Ph.r. CP Tower. (C) → q.t Process AB : (Pressure is constant) If TA = T ⇒ TB = T 3 So ∆U = Negative [Q ∆U = nCv∆T] ∆W = nR∆T = Negative ∆Q = ∆U + ∆W = Negative Process BC : (Volume is constant) If TB = T T then TC = 3 9 ∆U = nCv∆T = Negative ∆W = Zero ∆Q = Negative Process C → D : (Pressure is constant) If TC = T then TD = T 9 ∆U = nCv∆T = positive ∆W = positive ∆Q = positive Process D → A : TD = T andTA = T Hence process is isothermal ∆U = 0 ∆W = negative ∆Q = negative CAREER POINT.r.1. (D) → r.careerpointgroup. Road No. Kota (Raj. (A) → p. IPIA.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.

PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans.) Ph. IPIA.r (A) λf =L 4 ⇒ λf = 4L (B) Longitudinal waves λf =L 2 (C) Stretched wire clamped at both ends (D) λf = L ⇒ λf = 2L 2 λf λ + f =L 2 2 ⇒ λf = L CAREER POINT.careerpointgroup. (B) → p. Road No.com. (A) → p.s.t. (C) → q. Kota (Raj. CP Tower.1. Email: info@careerpointgroup.s.: 0744-3040000 Website : www.com 26 / 38 . (D) → q.

Sol.careerpointgroup. Email: info@careerpointgroup. (C) and (D). Each question has four choices (A). CP Tower. 2t) 3 1 • P(h.) Ph. Kota (Raj. (B).com 27 / 38 .: 0744-3040000 Website : www. [C] h= t2 2t . k) (0.com. 0) t2 = 4h.1. Sol. IPIA. 3) is a2 x b2 y + = a2 + b2 6 3 it passes through (9.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Part – III : (MATHEMATICS) SECTION – I (Total Marks : 24) Code-9 (Single Correct Answer Type) 10/04/2011 This section contains 8 multiple choice questions. Road No.k= 4 4 (t2. out of which ONLY ONE is correct. [B] Equation of the normal at (6. Ans. 0) so 9a 2 = a2 + b2 6 a2 2 ⇒ b2 = Now b2 = a2 (e2 –1) ∴ e2 –1 = e = 2 1 2 3 2 ⇒e= 3 2 Ans. t = 2k so 4k2 = 4h CAREER POINT.

Road No.1. Kota (Raj.careerpointgroup.} Ans. …. 1. [A] gof(x) = gf(x) = g(x2) = sin x2 go (gof(x)) = g(sin x2) = sin (sin x2) fo(gogof(x)) = f(sin (sin x2)) = (sin(sin x2))2 ∴ (sin (sin x2))2 = sin (sin x2) sin (sin x2) (sin (sin x2) –1) = 0 sin (sin x2) = 0 sin x2 = nπ At n = 0 sin x2 = 0 x2 = nπ x=± nπ .) Ph. IPIA.PAPER-2 ∴ k2 = h hence required locus is y2 = x IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Sol.: 0744-3040000 Website : www. CP Tower. or sin (sin x2) = 1 sin x2 = 2nπ + π 2 At n = 0 sin x2 = π 2 Not possible n ∈ {0. [C] R1 = R1 = 2 −1 2 −1 ∫ x f (x ) dx ∫ (1 − x ) f (1 − x) dx 2 … (i) = −1 ∫ (1 − x ) f ( x) dx 2 … (ii) (i) + (ii) 2R1 = −1 ∫ f ( x) dx = R2 ∴ 2R1 = R2 CAREER POINT. Email: info@careerpointgroup. Sol.com.com 28 / 38 . 2.

com 29 / 38 .) Ph. 2) (–1.com.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. [D] ∴ (h – 0)2 + (2 –2)2 = (h + 1)2 + (2 – 0)2 h2 = h2 + 1 + 2h + 4 (h. θ ∈ (–π. CP Tower.1. Road No. Email: info@careerpointgroup.: 0744-3040000 Website : www. Kota (Raj. Sol. 2) (0. π) = 2b sin θ 2 e ln(1+ b ) = 2b sin θ 2 2 1 + b2 = 2b sin2 θ 2 sin2θ = b + RHS = b + 1 b 1 ≥2 b as b > 0 But LHS = 2 sin2 θ ≤ 2 Only possibility 2 sin2 θ = 2 sin2θ = 1 θ=± π 2 Ans. 0) h= − 5 2 2 2 Equation of circle is 5 5 2 x + + (y –2) = – − 0 2 2 CAREER POINT. Sol.careerpointgroup. IPIA. [D] 2 1/x 2 lim (1 + x ln(1 + b )] = 2b sin θ x →0 1 2 x ln(1+ b2 ) lim [1 + xln (1 + b )] x →0 ln(1+ b2 ) b > 0.

ω) Ans.com 30 / 38 . ω) or (ω.PAPER-2 x2 + 25 25 + 5x + y2 + 4 – 4y = 4 4 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT x2 + y2 + 5x – 4y + 4 = 0 from given points only point (–4. IPIA.careerpointgroup. [A] 1 ω ω2 a b 1 c ≠0 ω 1 2 2 2 2 (1 – ωc) – a (ω – ω c) + b(ω – ω ) ≠ 0 1 – ωc – aω + acω ≠ 0 (1 – ωc) – aω (1 – ωc) ≠ 0 (1 – ωc) (1 – aω) ≠ 0 c ≠ ω & a ≠ ω & b = ω or ω 2 2 2 (a . Road No. Email: info@careerpointgroup. ω. c) ≡ (ω. Kota (Raj. Sol. 0) satisfies this equation.1. b.com.: 0744-3040000 Website : www. ω2.) Ph. Ans. CP Tower. [B] x + bx –1 = 0 x +x+b=0 (i) – (ii) we get x = Put this value in (i) 2 2 … (i) … (ii) b +1 b–1 b + 1 +b b – 1 2 b + 1 –1 = 0 b – 1 ⇒ b3 + 3b = 0 ⇒ b(b2 + 3) = 0 ⇒ b = 0 or b = ± i 3 CAREER POINT. Sol.

B.com. C. f − = 0 So f(x) is continuous at x = − π 2 At x = 0 LHD = 0. (B). RHD = 1 So f(x) is differentiable at x = 1 in − . Ans.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT SECTION – II (Total Marks : 16) (Multiple Correct Answers Type) This section contains 4 multiple choice questions. out of which ONE OR MORE may be correct. f(x) = – cos x 2 π so f(x) is differentiable at x = − 3 2 CAREER POINT. (C) and (D). RHL = 0.com 31 / 38 . Road No. Kota (Raj. IPIA. Each question has four choices (A). D] At x = − π 2 π 2 LHL = 0.careerpointgroup. RHD = 1 So f(x) is not differentiable at x = 0 At x = 1 LHD = 1.1. Email: info@careerpointgroup. [A. Sol. 0 .: 0744-3040000 Website : www. CP Tower.) Ph.

1. Sol. [A. P(F) = 5 5 5 5 CAREER POINT.com. IPIA.: 0744-3040000 Website : www. 1. CP Tower. P(F) = and P(E) = . 6) 6 = 9m –2m – m3 m3 – 7m + 6 = 0 (m –1) (m –2) (m + 3) = 0 ∴ m = –3.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. Email: info@careerpointgroup. [A. Kota (Raj. y = 2x –12 and y = –3x + 33 Ans. D] y = mx – 2m – m 3 It passes through (9. Sol. D] P(E) (1 – P(F)) + (1 – P(E)) P(F) = P(E) + P(F) –2P (E) P(F) = (1 – P(E)) (1 – P(F)) = 2 25 2 25 11 25 11 25 … (1) 1 – P(E) – P(F) + P(E) P(F) = P(E) + P(F) – P(E) P(F) = From (1) & (2) P(E) P(F) = 12 25 7 5 23 25 … (2) and P(E) + P(F) = so either P(E) = 4 3 3 4 .) Ph.careerpointgroup. Road No. 2 Hence equations will be y = x –3.com 32 / 38 . B.

careerpointgroup.dg = g ∫ CAREER POINT. so f(x) is not invertible function.com. Kota (Raj. F. Sol.: 0744-3040000 Website : www.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. 1) f(x) ∈ (f(1). [0] dy +y=g dg I. The answer to each of the questions is a single-digit integer. CP Tower. B] f : (0. b) so f(x) is not onto. IPIA. 1) = (–) ve f ′(x) = b2 − 1 (1 − bx )2 So f(x) is monotonically decreasing for x ∈ (0. Email: info@careerpointgroup. Sol. The bubble corresponding to the correct answer is to be darkened in the ORS Ans. 1) so for x ∈ (0.) Ph. f(0)) f(x) ∈ (–1. SECTION – III (Total Marks : 15) (Integer Answer Type) This section contains 6 questions. Road No. [A. 1) → R f(x) = b−x 1 − bx ∀ b ∈ (0. = 1. ranging from 0 to 9.com 33 / 38 .1.

: 0744-3040000 Website : www. Kota (Raj. Sol.e = g g IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT ∫ ge g g . If ω = e i π / 3 then no integral solution is possible.) Ph.careerpointgroup. Road No.dg = ge – g g ∫e g .PAPER-2 y. CP Tower.c ⇒ λ=− r r =4 b. b= –ˆ ˆ j. IPIA.a r rr rr ⇒ r .a = 0 rr a. Sol. [9] r r r ˆ .dg ye = ge – e + c –g y = g –1 + ce Q y(0) = 0 & g(0) = 0 at x = 0 –0 0 = 0 –1 + Ce C=1 –g y = g –1 + e at x = 2 –0 y(2) = 0 – 1 + e = 0 Ans.1.c + λb. [*] wrong question if ω = e i 2π / 3 then ans is 3.b = c. Email: info@careerpointgroup. c =ˆ j + 3k a= –ˆ i– k i+ ˆ i + 2ˆ r r r r r r r r r ( r − c ) × b = 0 ⇒ r − c = λb ⇒ r = c + λb r r Q r ⋅a = 0 rr rr ⇒ a.com.b + λ | b |2 = 9 Ans.com 34 / 38 . CAREER POINT.

Sol. δ are the root of equation. Road No. ….careerpointgroup. Kota (Raj. γ.(ii) Ans.com. i = 7 0 12 So a + e + i = 0 + 2 + 7 = 9 Ans. f = –5.. β.) Ph. CP Tower. IPIA. [9] a b c Let M = d e f g h i 0 QM 1 = 0 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT − 1 2 ⇒ b = –1.(i) 3 2 f'(x) = 4x – 12x + 24x + 1 f"(x) = 12x2 – 24x + 24 = 12((x + 1)2 + 1) so f"(x) > 0 so f'(x) = 0 has only one real roots so f(x) = 0 has at most two real roots.: 0744-3040000 Website : www. from (i) & (ii) f(x) = 0 has exactly two real roots. ∴ αβγδ = –1 so the equation has at least two real roots. 3) CAREER POINT. e = 2.PAPER-2 Ans. h = 3 3 1 1 ⇒ a = 0. Email: info@careerpointgroup. [2] Let f(x) = x4 – 4x3 + 12x2 + x – 1 Let α.0 2 (2. g = 2 − 1 1 ∴M − 1 = 0 1 M 1 = 1 0 ⇒ c = 1. Sol. ….com 35 / 38 . Sol. d = 3. [2] 1 .1.

Each question has four statements (A. CAREER POINT. 3 P1 ≡ 2. IPIA. For example. Road No. s and t) in Column II. Any given statement Column I can have correct matching with ONE or MORE statement(s) given in Column II.com 36 / 38 . q. y1) lies inside the region if x1 + y1 − 6 ≤ 0 & 2x1 – 3y1 – 1 ≤ 0. Kota (Raj. 4 4+ 5 P2 ≡ .PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT 2 2 Pont (x1.) Ph. B. C and D) given in Column I and five statements (p.1. against statement B.com. darken the bubbles corresponds to q and r in the ORS. if for a given question. 4 3 4 − 1 4 9 True −6≤0 16 9 True 4 − −1> 0 4 25 9 + − 6 ≤ 0 False 4 16 1 1 P4 ≡ . r. CP Tower. Email: info@careerpointgroup. statement B matches with the statements given in q and r.: 0744-3040000 Website : www. then for the particular question. 8 4 1 1 + − 6 ≤ 0 True 16 16 2 3 + − 1 > 0 True 4 4 1 1 + − 6 ≤ 0 True 64 16 2 3 − − 1 > 0 False 8 4 So P1 & P3 lies in the interval SECTION – IV(Total marks : 28) (Integer Answer Type) This section contains 2 questions.careerpointgroup. 2 1 P3 ≡ .

i cot 2 2 θ = z-θ 2 CAREER POINT.1. IPIA. CP Tower. C → s. Kota (Raj. Road No.: 0744-3040000 Website : www. [A → q. B → p. f(b) – 3b = – 2b f (b ) = b So f = π 6 π 6 (C) I = π2 ln 3 5/6 ∫ sec πx dx 7/6 I= π2 5/6 ln | sec πx + tan πx | 7 / 6 π ln 3 I= (D) ∴ π ⋅ ln 3 = π ln3 |z| = 1 z = cos θ + i sin θ.PAPER-2 Ans. 1 1 1 Arg = Arg = Arg + (1 − z ) 2 1 − cos θ − i sin θ so maximum values is π.com 37 / 38 .t (b).com. Email: info@careerpointgroup.) Ph.careerpointgroup. ∀ θ∈ (– π.r. D → s] (A) IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT r c r b θ r a r r −a ⋅b 1 2π ⇒ θ= cos θ = r r = − 3 2 | −a || b | b (B) ∫ (f ( x ) − 3( x ))dx = a a 2 − b2 differentiating w. Sol. π] and θ ≠ 0.

careerpointgroup.PAPER-2 IITIIT-JEE 2011 2011 EXAMINATION CAREER POINT Ans. [A → p. s . ∞) (D) f(x) = 3x5/2 – 10x3/2 f'(x) = −1≤ 8t 15 x (x − 2) 2 So f(x) is increasing for f'(x) ≥ 0 x ∈ [2. ∞) CAREER POINT.1. D → r] (A) Let z = cos θ + i sin θ so 2iz 1− z 2 = 2i (cos+ i sin θ) = − cos ecθ 1 − cos 2θ − i sin 2θ ∀ θ ≠ (2n + 1) π 2 so Re 2iz = − cos ec θ ∈ ( −∞.com. r. ∞ ) 1− z2 = 8 × 3x 9 − 32 x (B) 8 × 3 x −2 1 − 32 x −2 x Let 3 = t 8 × 3x 8t –1 = sin−1 So f(x) = sin 9 − 32 x 9 − t2 ≤ 1 on solving 9 − t2 x ∈ (– ∞. Sol. CP Tower. Kota (Raj. t .: 0744-3040000 Website : www.com 38 / 38 . Road No. Email: info@careerpointgroup. B → r. − 1] ∪ [1.) Ph. 0] ∪ [2. ∞) ∪ {1} (C) f(θ) = 2 sec2θ so f(θ) ∈[2. C → r . IPIA.