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Mathematical formulation of quantum mechanics

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of a quantum mechanical syste m are represented by unit vectors (called "state vectors") residing in a complex separable Hilbert space (variously called the "state space" or the "associated Hilbert space" of the system.) The exact nature of this Hilbert space is depende nt on the system; for example, the state space for position and momentum states is the space of square-integrable functions, while the state space for the spin of a single electron is just the product of two complex planes. Each observable is represented by a densely-defined Hermitian (or self-adjoint) linear operator acting on the state space. Each eigenstate of an observable corresponds to an ei genvector of the operator, and the associated eigenvalue corresponds to the valu e of the observable in that eigenstate. If the operator's spectrum is discrete, the observable can only attain those discrete eigenvalues. The time evolution of a quantum state is described by the Schrdinger equation, in which the Hamiltonian, the operator corresponding to the total energy of the sy stem, generates time evolution. The inner product between two state vectors is a complex number known as a proba bility amplitude. During a measurement, the probability that a system collapses from a given initial state to a particular eigenstate is given by the square of the absolute value of the probability amplitudes between the initial and final s tates. The possible results of a measurement are the eigenvalues of the operator - which explains the choice of Hermitian operators, for which all the eigenvalu es are real. We can find the probability distribution of an observable in a give n state by computing the spectral decomposition of the corresponding operator. H eisenberg's uncertainty principle is represented by the statement that the opera tors corresponding to certain observables do not commute. The Schrdinger equation acts on the entire probability amplitude, not merely its absolute value. Whereas the absolute value of the probability amplitude encodes information about probabilities, its phase encodes information about the interfe rence between quantum states. This gives rise to the wave-like behavior of quant um states. It turns out that analytic solutions of Schrdinger's equation are only available for a small number of model Hamiltonians, of which the quantum harmonic oscillat or and the hydrogen atom are the most important representatives. Even the helium atom, which contains just one more electron than hydrogen, defies all attempts at a fully analytic treatment. There exist several techniques for generating app roximate solutions. For instance, in the method known as perturbation theory one uses the analytic results for a simple quantum mechanical model to generate res ults for a more complicated model related to the simple model by, for example, t he addition of a weak potential energy. Another method is the "semi-classical eq uation of motion" approach, which applies to systems for which quantum mechanics produces weak deviations from classical behavior. The deviations can be calcula ted based on the classical motion. This approach is important for the field of q uantum chaos. An alternative formulation of quantum mechanics is Feynman's path integral formu lation, in which a quantum-mechanical amplitude is considered as a sum over hist ories between initial and final states; this is the quantum-mechanical counterpa rt of action principles in classical mechanics.

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