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Cells for Input

Cells for Auto calcs

Natural Gas Composition (mol%)
Methane
Ethane
Propane
Butane
Nitrogen
Carbondioxide
Total

92%
2%
2%
1%
2%
1%
100%

Pressure
Temperature
Basis
Desired Production Rate

250
1500

psig
°F
kgmol/hr Mixed Feed
Tonnes/day

Stream Factor
Operating hours

345
8280

days
hours

Max. Hydrocarbon conc. in Steam reformer outlet gas
Steam to hydrocarbon ratio in Primary Reformer

Natural gas Flow rate
Naphtha

0.50%
3.3

150
100

Naptha composition (mol%)
45.98
53.85
0.17

Carbon ©
Hydrogen(H2)
Sulphur

Total

Mixed Feed

Naphtha
40%

N.Gas
60%

0.17

100
0.17
C

H
45.98

53.85
1.17116

551.76

107.7

5.44

664.9

6.649

Pre Reformer
Naphtha

100

Temperature
Pressure
Pressure Drop
HC to Steam Ratio

727 °C
psig
psig
3

Reaction 1
Reaction 2
Reaction 3
Selectivity

1

2

CnHm + n H2O ---> nCO + (2n+m)/2 H2
CO + H2O --> CO2 + H2
CO + 3H2--> CH4 + H2O
0.7 mol CH4 / mol of CO2

100% Excess steam is used to ensure all naph
30% based on CO

Stream 1 (Naphtha)
Components

Carbon
Hydrogen(H2)
Hydrogen gas
Carbon monoxide
Carbon dioxide
Methane
Steam

Mol. Wt
12
2
2
28
44
16
18

Total

Steam Consumed
Steam un reacted
CO produced
Co consumed
CO 2 produced.
Ch4 Produced

60.13
82.06
45.98
18.392
27.588
14.14769
4.244308

Stream 2 (Steam)

Mol%
44.6148
52.2511
3.1341
-

Mole Flow
(kgmol/hr)
45.98
53.85
3.23000
-

Mass Flow
(kg/hr)
551.76
107.7
6.46
-

Mol%
-

Mole Flow
(mol/hr)
-

100

103.06

665.92

100
100

137.94
137.94

0.00

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3 am 2 (Steam) Mass Flow (kg/hr) 2482.08 1.92 2482.91 1477.83 35.24 82.00 .50 67.019077 3148.93 11.47 27.87 6.06 232.95 772.4 0.15 4.H2 for Hyderotreating (a) 3.84 0.17000 Pre reformer 3 team is used to ensure all naphtha converted 0.29 100 Mole Flow (kgmol/hr) 104.51 Mass Flow (kg/hr) 208.4 0.59 14.46 622.92 Stream 3 Mol% 44.

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Wt 16 30 44 58 28 44 28 2 32 18 40 Total 382.Gas 727 °C 900 psig 10 psig 3 150 Temperature Pressure Pressure Drop HC to Steam Ratio N.68 6 9 6 155.24 2275.Gas Flow rate Naphtha 60% 40.59 772.4984615 7.51 Total Primary Reformer Inlet 14643.784290382 3 84 4.1084923 kgmol/hr -2556758194 CO Consume Reaction 5 75% 100% 100% 100% 40% Stream 4 (Natural Gas) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 37.84 based CH4 based C2H6 based C3H8 based C4H10 based on CO Stream 5 (Steam) Mol% 100 100 .784290382 3 90 0.06 1477.18694748 142.9495385 21.27 5 5815.464 27.908923 0.31285223 104.212334354 27.Primary Reformer N.0% Natural Gas 4 Primary Reformer Steam Reaction 1 Reaction 2 Reaction 3 Reaction 4 Reaction 5 Components Methane Ethane Propane Butane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Oxygen Steam Argon Reactions in Primary Reformer CH4 + H2O = CO + 3H2 C2H6 + 2H2O = 2CO + 5H2 C3H8 + 3H2O = 3CO + 7H2 C4H10 + 4H2O = 4CO + 9H2 CO+H2O = CO2 + H2 Mol.64769231 688.090778193 15.392145191 1.47 208.76554 kg/hr CO Production Reaction 1 Reaction 2 Reaction 3 Reaction 4 Total kgmol/hr kgmol/hr kgmol/hr kgmol/hr Del H Rxn 21956795774 20784366000 4487031000 3905772000 62.784290382 3 132 0.5 87 0.45207141 82.019077 100 106.

7 Components 417.9352213 -2911.049692 15 21 13.89203553 Methane Ethane Propane Butane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Oxygen Steam Argon Total CP /R CP J/mol.CO2 Produced Reaction 5 62.57720658 GJ Keq 0.50 Conv.683231 kgmol/hr Reaction 2 6 kgmol/hr Reaction 3 9 kgmol/hr Reaction 4 6 kgmol/hr Reaction 5 62.3 -860.7997 44.791723 kgmol/hr 48577206580 Fed mole dry base Energy Balance Feed moles Equilibrium Shift Conversion 134.98505 CO conc eqlib 1747.5 62.1084923 536.K Del H/mol .08 CO conc.27 48.43% CO H20 CO2 H2 134.02 a b c -0. Eq -26.13 kgmol/hr kgmol/hr kgmol/hr kgmol/hr kgmol/hr kgmol/hr Steam consumption Reaction 1 106.07 39214.27 417. 33.1084923 kgmol/hr Total 189.64769231 474.23 15.23 572.1084923 kgmol/hr H2 Produced Reaction 1 Reaction 2 Reaction 3 Reaction 4 Reaction 5 Total 320.

Del H Del H /mol Del H /mol .

.

15 0.00 0.4403077 8827.00 0.27 2608.92 Stream 6 Mole Flow (kgmol/hr) 35.89 8.00 0.71 Mass Flow (kg/hr) 568.00 77.925538 Reactions in Secondary Reformer CH4 + H2O = CO + 3H2 CH4 + 2O2 = CO2 + 2H2O 2CO + O2 = 2CO2 CH4 + 2CO + 4O2 +2H2= 3CO2 + 4H2O Reaction 1 Reaction 2 Reaction 3 Reaction 4 Mol% 3.23 .45 kgmol/hr CO Production Mol% 78 21 1 99 22823.56 0.04 kgmol/hr Reaction 1 17.00 0.13 382.6936 Stream 7 (Air) 100 1128.86 kgmol/hr CH4 Consumption Reaction 4 15.27 6888.925538 490.14 kgmol/hr Argon with Air 2.27 6.Secondary Reformer 1000 °C 890 psig 10 psig Exit Temperature Pressure Pressure Drop 6 Reformer 7 9 Secondary Reformer Air 205813 3464061 498559 650962 -41166 Stream 5 (Steam) Mole Flow Mass Flow (mol/hr) (kg/hr) 490.00 3.00 3421.00 84.39 kgmol/hr Total air 286.76 93.26 47.00 0.98 0.52 33.16 536.4403077 8827.00 0.56 1072.00 0.40 kgmol/hr O2 with Air 60.76554 Total Secondary Reformer Inlet Nitrogen in 223.318154 14643.

595530049 -1822.000011402 0 0 0 0 0 0 0 0 0 0 4000 -115700 -3100 8300 -22700 12100 -1.94857192 -31553.028785 0. Wt 16 30 44 58 28 44 28 2 32 18 40 5.376 0 3.22506E-06 -0.001045 0.249 0 3.355704698 0.38 Ref Temp 727 25 1000 Tau 298 3.72934 C D -0.009081 0.06209 B 0.000008824 -0.213 -125790 1.000002164 -0.000506 0.07 kgmol/hr Steam Consumption Reaction 1 17.388503339 -2378.45 kgmol/hr Steam Production Reaction 4 60.000593 0.51 Inlet Temp 382511.00145 B*(tau-1)/2 0.Reaction 1 17.036915 0.67528E-05 Inlet condition remaining steam .11 kgmol/hr H2 production Reaction 1 52.005221115 3.34 kgmol/hr H2 Consumed Reaction4 30.000005561 -0.019225 0.298 A Mol.270511 -0.000557 0.5463645 -3384.702 -83820 1.935 0 3.000422 0.07 kgmol/hr CO2 Production Reaction 4 45.28 -393509 5.566305363 397.457 -110525 3.131 -104680 1.595530049 2.45 kgmol/hr CO Consumption Reaction 4 30.14 kgmol/hr 382.011356612 2.47 A 2.406371412 44.639 -241818 3.8975 Heat of Formation A -74520 1.

1793 -1.0950786 GJ Inlet steam .207E+10 -12.2095E+10 -12.069725 GJ -31620.-1.

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863958087 283.67 5.820790031 TPH 85% based on remaining CH4 after Reaction 4 100% based on O2 Stream 7 (Air) Mole Flow Mass Flow (kgmol/hr) (kg/hr) 223.98 8.03 Stream 8 Mole Flow (kgmol/hr) 3.42 0.80 0.26 6338.00 7657.22 15.00 .40 Mass Flow (kg/hr) 49.58 2.08 226.Ammonia Production 6.39 122.06 1116.884462 60.00 30.00 425.23 100 1416.46 Mol% 0.14 1924.23 kg/hr 0.40 0.39 6254.86 80.00 2255.53 8179.54 558.88 5406.67 22823.68 39.

34% 1.19% 0.31% 0.Energy Balance Feed moles 1128318.77 kj/kg 110.21% 9.00% 1.00% Mol.00% 0.18% 34.77 300454.00 3000.00 1500.00 0.00 300454.45% 0. Wt Methane Ethane Propane Butane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Oxygen Steam Argon 16 30 44 58 28 44 28 2 32 18 40 Total CP /R CP J/mol.00% 100.15 Mol% 37.77 0.00 104474.00 3000.00% Steam Stream 4 Mole Flow (mol/hr) 142244.00% 5.00 15647.00% 0.09% 7.00% 100.69 27588.K Del H/mol 2.39% 0.77% 0.678469167 22.26879266 21712.00% 0.21% 27.00% 21.00% 100.78% 4.00% 0.78% 0.50% 1.07284 .31 3000.5683 Components 47.78% 0.

3893.04991956 Del H 24498125945 Del H /mol Del H /mol 21803.669 10304.94 kg -3.417 24601191213 .2373 -3782.9801945 -51.898E+10 -38.

Inlet Temp
Ref Temp

25
1000

298 Tau
1273

0.234092694
4.271812081

Stream 4

A
Heat of Formation
A
-74520
-83820
-104680
-125790
0
-393509
-110525
0
0
-241818

B
1.702
1.131
1.213
1.935
3.28
5.457
3.376
3.249
3.639
3.47

C
0.009081
-2.164E-06
0.019225
-5.561E-06
0.028785
-8.824E-06
0.036915 -1.1402E-05
0.000593
0
0.001045
0
0.000557
0
0.000422
0
0.000506
0
0.00145
0

Mol%

D
0
0
0
0
4000
-115700
-3100
8300
-22700
12100

2.260970291 0.000606304 -6.8203E-08 -4274.76197
2.260970291 0.476251997 -0.04748459 -0.01126853
2204.446034 464.345697 -46.2974754 -2.8962E-05

3.15%
0.00%
0.00%
0.00%
0.27%
6.89%
8.26%
47.52%
0.00%
0.00%
0.00%
66.08%

803369574 .09666717 31.09666717 Consumption /ton NH3 7.2251454 GJ kj/kg 110.5683 3893.2373 4624.49812595 GJ Inlet condition remaining steam 24.69 kg 31096667168 31.1603 6888.5683 110.24.7286 4514.60119121 GJ Inlet steam 53.

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00 252770.40% 10.00% 0.00% 0.00 0.41 4.Stream 4 Mole Flow (kgmol/hr) mol% 12055.77% 0.00% .90% 0.49% 71.00 0.00% 0.14 31583.00% 100.43% 12.55 0.00 1017.57 0.03 26360.12 181754.00% 0.00 0.00 0.00% 0.

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376 271.68 39.5555556 588.2 Stream 10 (HTS out Mol% 0.43 kgmol/hr Energy Balance deg F T0 T A CO H2O CO2 deg c deg K 315.39 6338.23 1416.43 kgmol/hr 64.06 558.54 425.88 122.86 5406.144306 -0.000557 0.High Temperature Shift Converter 400 °C 880 psig 10 psig Temperature Pressure Pressure Drop 752 SR outlet stream HTS 9 Reactions in HTS CO+H2O = CO2 + H2 Reaction 1 Components Mol.14 43.86 . Wt Methane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Steam Mol% 0.5555556 tau 25 298 B 3.42 30.96 25.98 8.044859488 3.98 13.457 670.895211 0.80 425.22 1.40 1116.00145 -0.00 80.08 49.48 100 64.47 1476.7 22823.22 15.40 122.616832635 5.4662531 0.001045 0.26 226.40 7657.03 100 16 28 44 28 2 18 Total CO Consume Reaction 1 CO2 Produced Reaction 1 H2 Produced Reaction 1 Steam Consume Reaction 1 80% based on CO Stream 9 (SR outlet) Mole Flow Mass Flow (kgmol/hr) (kg/hr) 3.43 kgmol/hr 64.22 15.67 5.43 kgmol/hr 64.128392383 600 77 80.54 2255.

Wt 16 30 44 58 28 44 28 2 32 18 Heat of Formation A -74520 -83820 -104680 -125790 0 -393509 -110525 0 0 -241818 B 1.089 A CO H2O CO2 H2 N2 CH4 B 54.009081 0.061553 0.001045 0.5555556 473.244528 0.000422 0.824E-06 0.249 3.47 C 0.000593 0 0.28 5.000422 0 0.000593 0.000506 0 0.23564518 742.262834701 742.385513 0.1402E-05 0.000557 0.03450175 -5.009081 0.000422 0.000593 0.027958533 4980.027958533 5100.702 1814.089 298 tau 661.240108316 0.5602 deg K 25 388.089 661.457 3.H2 N2 CH4 558.134248517 5.008971898 1252.83 226.000557 0 0.036915 -1.106326609 H2 H3 H4 Cp/R 5100.195721884 2023.08 H1 3.29 622.5550369 0.7116191 4841.935 3.089 Tau 200.639 3.009081 -2.289439427 -5.523408925 1022.40 226.134248517 5.00145 0 .521270877 4929.028785 -8.331784 16.004353061 3.001045 0 0.702 Heat Coservation for steam generation Fed mole dry base Energy Balance Feed moles Components Methane Ethane Propane Butane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Oxygen Steam #REF! Inlet Temp 1416671.5555556 A Mol.11 360.326193928 -281.240108316 0.164E-06 0.5550369 0.00145 -0.019225 -5.045728533 H2 H3 H4 Cp/R 4980.39 3.47 5.249 3.45 Out let temp 388.545444 -0.066081 Del H total -0.702 1.376 3.571704 -0.249 3.385513 22.457 3.97 187.700232 deg F T0 T deg c 77 730.578068 0.28 1.08 H1 H rxn -2706.37904219 0.39 3.561E-06 0.213 1.376 3.98408452 -0.131 1.28 1.545444 -40.

00152744 -675.4309334 GJ Del H /mol Del H /mol -8108.4873839 -11487383.169153 -300.7029E-09 3.K Del H/mol Del H 5.866948 -11430933435 -11.9 .002823536 -4.849 GJ -11.511269 -11487096411 -11.286446762 CP /R CP J/mol.175160265 43.02628244 -8068.600259972 0.601854648 -0.4870964 GJ Del H total stream Hrxn -205813 Del H rxn total -287511.40132 0.Argon 40 Total 3.600259972 1.

57 348.08 49.89 kgmol/hr 1.97 6497.23 3.88 187.26 15.20 44.13 200.22 90.87 635.72 1271.975018643 C D 0 0 0 0 0 0 -3100 -249666.23 CO Consume Reaction 1 CO2 Produced Reaction 1 H2 Produced Reaction 1 Steam Consume Reaction 1 80% based on CO Stream 11(LTS outlet) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 0.89 kgmol/hr 12.991 -115700 -14215309.67 22823.09 6265.43 24.39 6338.98 226.541586 100 1416.88 14.49 1416.78 CO H2O CO2 .39 6338.29 8240.89 kgmol/hr 12.67 22823.18 8807.83 1245.92 16.01 622.91 0.66 360.811 12100 5147361.08 49.26 226.23 12.22 3.89 kgmol/hr 12.11 451.Low Temperature Shift converter 200 °C 870 psig 10 psig Exit Temperature Pressure Pressure Drop 10 11 LTS Reactions in LTS Reaction 1 CO+H2O = CO2 + H2 Stream 10 (HTS outlet) Mole Flow Mass Flow (kgmol/hr) (kg/hr) 3.

66251E-06 -6.0 0 -0.63451 kj 0 0 0 0 0 -0.00% 15.22% 0.25083246 14614.96% 54.53 8300 5169497.40 1.98% 19.239 -115700 -21669877.48% .396011497 0.24 13.66251E-06 -6.00% 25.716326479 D 0 0 0 0 4000 -115700 -3100 8300 -22700 12100 Outlet temp Ref Stream 10 (HTS outlet) Mole Flow Mol% (mol/hr) 0.57278 kj 8300 4000 0 4634727.63 15.27 0.14% 43.00% 0.98% 13.22% 0.00 0.02 43.00% 0.31 25.96% 0.9231 0 0 -11277001.22% 1.00% 0.000002164 H rxn Del H total 1.3622 12100 4367757.48% 31.22% 16.14% 1.00 0.00% 0.05 CO H2O CO2 H2 N2 CH4 0.66251E-06 CP del H 40.48 905554.00% 0.9231 0 -3777332.450771379 C D 0 0 0 0 0 -6.00 0.00% 0.00 0.66251E-06 CP del H 40.98552773 -11908.000002164 0 0 -6.682 4000 905554.2 H2 N2 CH4 -3100 -49933.

86 0.-7960.00 122.20916 -0.00% .52315E-05 J/mol -0.00028751 0.00% Steam 0.02542691 1.00% 100.

000557 0.47 1252.37904219 0.523408925 0 5.5555556 tau 1.deg F T0 T deg c deg K 200.376 54.457 1022.00145 -0.008971898 0 3.571704 -0.5555556 473.195721884 0 393 77 A 16.11 360.97 187.29 0 0 0 .061553 0.001045 0.589112603 25 298 B C 3.

412 298 tau 494.08 -541.857184 -0.622.380613 0.28 1.702 2023.88751899 8030.000422 0.39 3.011893219 3.249 3.60273618 B C 10.00145 -0.249 3.268272606 0 0 742.39 3.5550369 0.7079539 4917.387738329 -238.87580844 0.08 3.136737637 -6.027958533 -0.5550369 0.911834 40.64441542 5131.66251E-06 H1 H2 H3 H4 Cp/R CP del H 5124.262834701 0 0 742.83 226.66251E-06 5124.72 226.65399935 -0.240108316 0.134248517 0 0 5.444776 0.376 3.209187785 0 0 2065.353527 32.5416 A deg K 25 221.000593 0.66226741 -7489.09 200.000422 0.009081 0.457 3.009081 0.00179438 0 0 1207.353527 0.134248517 0 0 5.385513 0.240108316 0.66251E-06 H1 H2 H3 H4 Cp/R CP del H 5100.702 .504724183 0 0 1092.376884 42.000557 0.001045 0.578068 0.027958533 -0.66251E-06 5100.18 635.28 1.799379 3.106326609 -6.412 0.2132161 -0.598056 deg F T0 T deg c 77 430.22 348.547138433 -31.18292446 -2.385513 65.000002164 -6.000593 0.000002164 -6.47 5.

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239 -115700 -21669877.D -3100 -49933.53 .3622 12100 4367757.

82 kj .9231 0 -11277001.05 kj D -3100 -9986.288 -115700 -23160791.722 4000 905554.9231 0 0 -12776934.672441 12100 4211836.08 8300 5276451.8300 4000 0 5169497.682 905554.

43 348.18 8807.91 28 0.13 0.88 200.30 3.23 44.26 226.39 6338.00 100.72 1271.7 22823.18 8807.6 16557.43 119.72 1271.20 2 59.22 90.91 3.88 44 18.00 1068.39 6338.20 635.26 28 21.08 49.54 kg/hr .22 15.7 0.00 0.08 49.29 3.00 0.54 1416.Cooler Separator 120 °C 860 psig 10 psig Temperature Pressure Pressure Drop Assumptions: Water Condensed CO2 Solubility in Water Components LTS outlet stream 11 100% 0% Mol.57 100 Stream 11 (LTS outlet) Mole Flow (kgmol/hr) Mass Flow (kg/hr) 3.00 18 0.7 157705.49 635.00 0.87 24.73 200.00 0. Wt Mol% (kgmol/hr) Mass Flow (kg/hr) 16 0.22 90.19 226.09 6265.2 CO2 Removal 120 °C 850 psig 10 psig Temperature Pressure Pressure Drop Stream from Cooler Separator Lean Solvent Assumptions: Solvent Used Rich Solvent Loading Lean Solvent Loading Solution Strength Components Methane Nitrogen Carbon dioxide Carbon monoxide Hydrogen MDEA Water Total Total Mass in 13 14 MDEA 0 mol of Acid gas /mol of pure solvent 0 mol of Acid gas /mol of pure solvent 50% by weight Stream 13 (Feed Gas) Mole Flow Mol. Wt Methane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Steam 16 28 44 28 2 18 Total Mol% 0.98 14.

5555556 298 #REF! Inlet Temp 1416671.8 -4.009081 0.639 3.131 1.000557 0.28 5.028785 0.34198E+11 .529 -306491809.K Del H/mol Del H 126876.702 1.00145 3.617178513 -1050.249 3.935 3.Total Mass out Fed mole dry base Energy Balance Feed moles 157705.000593 0.036915 0. Wt 16 30 44 58 28 44 28 2 32 18 40 Heat of Formation A -74520 -83820 -104680 -125790 0 -393509 -110525 0 0 -241818 Total CP /R CP J/mol.991312 286.45 Ref Temp A Components Methane Ethane Propane Butane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Oxygen Steam Argon Mol.47 0.000506 0.5555556 25 588.0559 1054847.019225 0.457 3.000422 0.213 1.376 3.196 GJ Del H /mol Del H /mol -306491934 -4.14 Hrxn Del H rxn total -434198.5555556 315.4461 -4.2144178 126872.54 kg/hr 600 315.34198E+14 -434198.617178513 3.34198E+14 -434198.001045 0.372 GJ Del H total stream B 1.4911 -36863507.

00 0.37 73.13 Cooler Condenser 12 Mol% 0.22 90.69 Stream 13 (Condensed Water) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 0.wt 119.00 0.00 100 Stream 12 Mole Flow (kgmol/hr) 3.07 0.09 6265.88 8807.09 6265.08 226.00 0.72 0.00 0.00 0.00 0.541586 100 348.45 4507.97 141147.51 70444.58 70444.00 0.49 7753.00 0.18 3.88 0.00 16557.59 Mass Flow (kg/hr) 49.54 22823.00 0.08 49.91 90.01 0.00 0.85 Mol% 0.00 13.29 21.00 0.19 18.43 0.00 0.00 348.26 226.23 15 Treated Gas CO2 Removal Stripper 16 Rich Solvent MDEA M.82 3.39 6338.00 100.73 0.26 6338.94 0.60 .7 H20 18 CO2 44 Stream 14 (Lean Solvent) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 0.89 258.30 59.00 1068.00 0.00 0.00 0.35 26.00 0.81 3913.20 1271.20 0.00 0.05 588.13 5.00 0.43 0.00 0.00 0.72 1271.22 635.39 200.49 0.00 0.00 0.00 100 Stream 15 (Treated Gas) Mole Flow Mass Flow (kgmol/hr) (kg/hr) 3.00 0.00 0.45 86.00 0.00 0.00 0.00 0.09 3.20 635.00 0 868.

824E-06 -1.00% 0.23% 44.30 0.54 0 0 0 -205813 J/mol -73809067.164E-06 -5.13% 0.87% 0.22% 0.22% 0.00 0.00% 0.24 358.00 157705.00% Steam Mole Flow (mol/hr) 342.0.57% 0.98% 14.54 0.98% 14.975018643 0.00095719 -0.07380907 CP /R CP J/mol.13% 0.561E-06 -8.00% 24.3 -0.05142257 0.7029E-09 -9018.00% 15.00 25201.00 38749.00% 0.51882E-05 Mol% 0.87% 0.278116843 8.98237 -0.62 70768.00 0.00% 157705.57% 0.506324335 Stream 12 (CO2 Removal outlet) C D -2.00% 0.00% 24.86 22284.00% 15.1402E-05 0 0 0 0 0 0 0 0 0 0 4000 -115700 -3100 8300 -22700 12100 -4.00% 100.K Del H/mol Del H .00 Tau Outlet temp Ref 1.23% 44.78 0.74 0.

03 0.00 4708.94 50% Rich 13.00 0.01 6.375 Co2 stripped 83.5 0.00 12.00 0.58 70444.81462141 100 1 0.9575 4.45 83.125 200.65 8 50% L/R 12.00 0.66 Stream 16 (Rich Solvent) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 0.05483029 0.35 6.Lean 1 0.00 0.51 70444.00 0.00 0.130548303 86.00 4.09 100 .13 3913.00 0.00 0.98 9063.38 205.00 0.50 588.00 0.65 7.07 149951.45 100.

.

0.0425 .

63 0.66 kgmol/hr 3.Methanator 400 °C 840 psig 10 psig Temperature Pressure Pressure Drop From CO2 Removal Unit Methanator 12 Reaction 1 Components Methane Nitrogen Carbon monoxide Hydrogen Steam Reactions in Methanator CO+3H2 = CH4 +H2O Mol.26 0.35 3.00 72.73 26.5555556 Fed mole dry base Energy Balance Feed moles Components #REF! Inlet Temp 868406. Wt 315.11 Ref Temp Mol.26 26.07 226.37 3.22 90.8 3.00 0.4 7749.21 635.72 1271.5555556 588.22 kgmol/hr 600 315.00 100 868.88 0.22 kgmol/hr 9.22 kgmol/hr 3.20 73.43 0.5555556 Tau 25 298 A Stream 14 (Methanator outl Mol% 0. Wt 16 28 28 2 18 Total CO Consume Reaction 1 H2 Consume Reaction 1 CH4 Produced Reaction 1 Steam Produced Reaction 1 100% based on CO Stream 12 (CO2 Removal outlet) Mole Flow Mass Flow Mol% (mol/hr) (kg/hr) 0.37 100 .08 49.00 0.39 6338.

000557 0 0.25206802 0.213 1.001045 0 0.00156151 -944.00145 0 3.036915 -1.028785 -8.000506 0 0.019225 -5.249 3.1961379 -8483.90643 -64.282E+09 Hrxn -205813 Del H rxn total -663028069 -7.47 C 0.000593 0 0.51168365 29.11231 0.K Del H/mol Del H 3.6721E-09 3.2817678 GJ Del H total stream -0.000497779 -7.36677591 GJ Del H /mol Del H /mol -8385.824E-06 0.2103 -7.2729774 .702 1.1402E-05 0.935 3.000010 -10.639 3.376 3.Components Methane Ethane Propane Butane Nitrogen Carbon dioxide Carbon monoxide Hydrogen Oxygen Steam Argon Mol.457 3.220654222 -0.131 1.25206802 0.164E-06 0.1001 -7.000422 0 0.009081 -2.453704998 CP /R CP J/mol.367E+09 -7.28 5. Wt 16 30 44 58 28 44 28 2 32 18 40 Heat of Formation A -74520 -83820 -104680 -125790 0 -393509 -110525 0 0 -241818 Total B 1.561E-06 0.

00 0.96 7749.88 0.00 626.30 100.00 0.05 1252.00 626.975018643 0.99 861.506324335 Mol% 0.39 6338.00 858.14 Methanator Cooler and Separator 16 Knock out water 15 Stream 14 (Methanator outlet) Mole Flow Mass Flow (mol/hr) (kg/hr) 6.15 612.80 6338.00 0.00 1252.73 26.74 Mass Flow (kg/hr) 100.00 0.36 0.00 0.09 Outlet temp Ref Stream 12 (CO2 Removal outlet) Stream 15 (Knock out Water) Mole Flow Mol% (mol/hr) 0.79 861963.90 0.00 0.00 0.00 100.05 0.00 3.88 0.00 100 Stream 16 Mole Flow (mol/hr) 6.39 0.11 0 7691.80 226.00 72.78 1.15 298 Tau Stream 14 (Methanator outlet) .22 100 3.22 339.00 0.11 3.30 226.22 57.

26% 0.246660499 0.00 0.00% 0.00 0.07% 0.00% 0.000534045 -1.5817E-08 3.7131E-05 Mol% 0.00% 26.00% 72.00% 0.00% 0.00% 100.00 626052.30 0.00 0.73% 0.1669046 -9.00 226388.00% 0.00 868406.33975255 9217.63% 0.083264 7944785599 7.00% 0.944785599 .118309356 -0.00% 26.00 0.00% 100.00% 0.35% 0.11 0.00% 0.00 0.00 0.00 3221.00 861963.21% 0.00% Steam Mole Flow (mol/hr) 3078.11 868406.00% 0.00% Mol% 0.00% 26.00 226388.73 0.528957488 29.09 3.00% 0.296827 0.27408305 J/mol -0.21% 0.07 0.09 861963.040522919 -6.246660499 0.35% 0.37% 0.00% 0.55 0.66302807 CP /R CP J/mol.79 0.K Del H/mol Del H 3.D 0 0 0 0 4000 -115700 -3100 8300 -22700 12100 7107.00% 0.51 0.51 635717.00 0.07% 0.00% 0.37% 73.00% 0.151977 322.0008071 2095.00 3221.73 0.37% 73.00% Steam Mole Flow (mol/hr) 6300.

15 612.486808789 2.55555556 861963.99 57.00 0.09 Ti T out 339.054194631 Methanator outlet) Heat Recovery via Boiler Feed water 0F 105 73 40.511312587 1.99 0.00 57.Knock out Water) Mass Flow (kg/hr) 0.955750799 .00 0.00 0.15 313 Tau Stream 15 & 16 0.

00% 7124.00% 0.00% Steam Mole Flow (mol/hr) 6300.00% 0.09% 0.31 3.142219484 0.00% 26.37% 0.09% 0.51 3.00% 26.00% 0.000138154 GJ Mol% 0.00% 72.37% 0.00% 100.00% 0.00% 0.00 626052.47416 -7533966141 -7.00% 72.00% 0.73% 0.K Del H/mol Del H 3.07% 0.6675146 -7.169703 0.00% 0.246660499 0.500449 282.37% 0.26% 0.00% 0.00 0.73% 0.00% 0.164794729 0.31 0.00% 861966.83794501 CP /R CP J/mol.22 861966.55 0.126312504 -0.63% 0.00 0.21769734 -8740.00 3221.73% 0.514276803 29.5817E-08 3.00% 0.000113536 .00 226388.00% 0.00% 0.73 0.07% 0.30 0.0.00 0.00091568 1899.00% 72.53396614 GJ 7124.000534045 -1.246660499 0.17 0.00% 26.

06% 54.90% 626.8 H2 Consume Reaction 1 N2 Consume Reaction 1 NH3 Produced Reaction 1 Stream 17 (Converter outle Mol% 11.78 449.Ammonia Conversion Loop 400 °C 840 psig 10 psig Temperature Pressure Pressure Drop 21 From Methanator Ammonia Converter 16 Reaction 1 Reactions in Ammonia Converter N2+3H2 = 2NH3 25% based onN2 Iteration No.05 1252.7 7691.33 224. recycle is required after that all the stream s Scale up Factor Calculations NH3 production based on 100 kgmol/hr ofNaphthas Feed Scale up Factor All the stream flow should be multiplied by this factor to get the desired production rate.36% 226.97 3323.78 kgmol/hr 224. 1 Components Methane Nitrogen Hydrogen Ammonia Mol.80 26.63 449.00% Calculations for Purge stream 20 Rate 674.88 72. Wt 16 28 2 17 Total Stream 16 (Methanator Outlet) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 0.20% 18.55 R /F 3.00 0.33 kgmol/hr 674.01 10% 7.54% 100. until the system get stabilized.11 0.870351356 Note: This indicates that at the start-up.73% 6.55 kgmol/hr Feed Stream Flow Feed Stream Inert Required Inert Conc.00 1 858.19% 16. .7 0. Purge Stream 20 flow Recycle Stream 21 Flow 858.00% 0.30 100.39 6338.

ammonia price dollar Total Input .

80 674.99 4045.00 0.72% 2018.51 kgmol/hr mol% mol% Methane Nitrogen Hydrogen NH3 kgmol/hr kgmol/hr N2 :H2 3 Stream 18 (Mixed feed) Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 10.72% 4.80 21.03 Recycle Stream 21 Mole Flow Mol% (kgmol/hr) 12.20 Recycle Stream Ammonia Converter 17 Cooler and Ammonia Separator 18 Liquid Ammonia 19 Sep.00% 4182.00% 0.50% 899.22 2022.00% 401.52 3732. Purge Stream 6.01% 167.24 6691.24% 1.33 18881.97 197.00% quired after that all the stream should be purged.820790031 TPH 7.72 60.00% 0.15 6.49% 2697.27 10493.96 64.24 6691.53 3323.00% 418.14 60.48% 0.61 . 6820.52 1.7 Tonnes/day 9.00% 0.24% 672.11 25174.98 617.22 100.71 2851.00 100.79 kg/hr 163.00% 401.84 135.55% 417.63 100.48% 215.124902 100.82 40112.51 Stream 19 (Liquid Ammonia) Mole Flow Mol% (kgmol/hr) 0.00% 3323.00 16.32 5394.2 e desired production rate.55% 1.63 4.24 20.22 Purge Stream 20 Mole Flow Mass Flow Mol% (kgmol/hr) (kg/hr) 12.43 6. Efficiency65% Stream 17 (Converter outlet) Mole Flow Mass Flow (kgmol/hr) (kg/hr) 418.00 0.63 100.37 40112.61 45.00 20.

1236761 -2053.708657 2233.44780919 15.44780919 2.970289 -4586.5551613 0.23146505 Nh3/ton naphtha Put Basis 2265.233093965 179.Required 2290.790353 15231.2595 365.093965 .46505 0.

00 6820.15 .31 le Stream 21 Mass Flow (kg/hr) 6675.(Liquid Ammonia) Mass Flow (kg/hr) 0.07 56508.79 46933.76 82451.00 0.79 6820.22 431.00 0.05 82648.80 18836.