f
H(H
3
PO
4
) =1290 kJ mol
1
,
f
H( )
2 4
H PO
=1302 kJ mol
1
,
S(H
3
PO
4
) =176 J mol
1
K
1
, S( )
2 4
H PO
= 89 J mol
1
K
1
.
A) It has a pK
a1
of 2.4
B) pK
a2
of phosphoric acid is less than pK
a1
.
C) First dissociation of phosphoric acid is endothermic.
D) First dissociation of phosphoric acid is entropy driven.
4) CuCN reacts with FeCl
3
to give
A) CuCl
2
B) Cu(CN)
2
C) (CN)
2
D) All of these
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SECTION2
SectionII contains 5 multiple correct answer(s) type questions. Each question has 4 choices (A) ,
(B) , (C) and (D) , out of which ONE OR MORE is/are correct. For each question in Section II ,
you will be awarded 4 marks s if you have darkened all the bubble(s) corresponding to the correct
answer and zero mark if no bubble is darkened. In all other cases , minus one (1) mark will be
awarded.
5) Which of the following statement/s is/are true?
A) Dimethyl ether is a better Lewis base than disilyl ether (SiH
3
OSiH
3
).
B) (CH
3
)
3
COH
is less acidic than (CH
3
)
3
SiOH
C)
4
4
SiO
undergoes polymerisation while
4
ClO
does not.
D)
Methyl isocyanate
( )
3
CH N C O = = is bent with respect to nitrogen but silyl
isocyanate
( )
3
SiH N C O = = is linear with respect to the same.
6) An organic compound of molecular formula
4 8 2
C H O reacts with excess MeMgBr to
give two products of which one reacts with NaOI to give yellow precipitate and the
other does not. The structure of the hydrocarbon may be
A) C H
3
O
O
CH
3
B) H
O
O
CH
3
CH
3
C) H
O
O
CH
3
D)
C H
3
O
CH
3
O
7) Sodium thiosulphate is prepared by
A) boiling Na
2
SO
3
solution with elemental sulphur in alkaline medium.
B) boiling Na
2
SO
3
solution with elemental sulphur in acidic medium.
C) oxidation of poly sulphides, Na
2
S
3
with air.
D) reduction of bisulphite solution plus SO
2
with zinc dust.
8) Alkene(s) which are more reactive than propene towards acid catalysed hydration is/are
A) Ethane B) but2ene
C) 2methylbut2ene D) but1ene
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9) Which of the following statements may explain the meta directing ability of nitro group
in electrophilic aromatic substitution?
A) nitro group decreases the electron density at ortho and para positions to a higher
extent than meta position
B) the arenium ion intermediates formed by the electrophilic attack at ortho and para
positions are more destabilised compared to the one formed by meta attack
C) nitro group increases the electron density at meta position and decreases the same at
ortho and para positions.
D) the arenium ion intermediate formed by meta attack in nitrobenzene is more stable
than the same formed in unsubstituted benzene
SECTION3
SectionIII contains 2 questions. Each question contains statements given in two columns , which have to be matched.
The statements in Column I are labeled A , B , C and D , while the statements in Column II are labeled p , q , r , s and t.
Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in Column II. For each
question in Section III , you will be awarded 2 for each row in which you have darkened the bubble(s) corresponding to
the correct answer. Thus , each question in this section carries a maximum of 8 marks. There is no negative marking
for incorrect answer(s) for this section.
10) Match the inorganic compounds in column A with the product(s) obtained on strong
heating given in column B Match the Following:
Column I Column II
(a) Pb(NO
3
)
2
(p) N
2
(b) NH
4
NO
3
(q) O
2
(c) (NH
4
)
2
Cr
2
O
7
(r) NO
2
(d) AgNO
3
(s) H
2
O
(t) Metal oxide
11) Match the Following:
Match the reactions in Column A with suitable thermodynamic parameters in column B
Column I Column II
(a)
HNO
2
(aq)
H
+
(aq) +
2
NO
(aq)
(p)
0 G A = ; 0 G A >
(b)
NaCl(s)+H
2
O Na
+
(aq) +Cl
(aq)
(q) 0 G A <
(c)
AgCl(s)+H
2
O
Ag
+
(aq) +Cl
(aq)
(r) 0 S A >
(d)
HNO
3
(l) +H
2
O H
3
O
+
(aq) +
3
NO
(aq)
(s) Addition of HCl solution
drives the reaction in the
backward direction.
(t) Addition of KCl solution
has no effect on the
direction of the reaction.
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SECTION4
SectionIV contains 8 questions. The answer to each of the question is a single digit integer ,
ranging from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS
have to be darkened. For each question in Section IV , you will be awarded 4 marks if you darken
the bubble corresponding to the correct answer , and zero mark if no bubble is darkened. In all
other cases , minus one (1) mark will be awarded.
12) The conductivity of 0.1 M solution of a weak monoprotic acid is 2.1910
4
S cm
1
. The
limiting molar conductivity of it is 400 S cm
2
mol
1
. If the dissociation constant of the
acid is y10
6
, what is the value of y?
13) What is the total number of isomers (including stereoisomers) possible for the complex
[Fe(NO
2
)
2
(NH
3
)
4
]
14) K
p
for the dissociation of solid ammonium carbamate (NH
2
COONH
4
) into NH
3
(g) and
CO
2
(g) at 400 K is 32 bar
3
. What is the total pressure(in bar) of ammonia at
equilibrium?
15) How many of the following compounds are more basic than aniline?
(a) ethanamine (b) ptoluidine (c) pnitroaniline (d) pyrrole (e) otoluidine
16) How many of the following compounds turn into aromatic ions in strongly
acidic (HClO
4
) solutions?
a)
O
b)
O
c)
O
d)
O
O
e)
NH
17) An element with molar mass 2.710
2
kg mol
1
forms a cubic unit cell with edge length
405 pm. If its density is 2.710
3
kg m
3
, what is the rank (number of atoms per unit cell)
of the cubic unit cell?
18) What is the number of stereoisomers for the compound
CH
3
CH(OH)CH=CHCH=CHCH
3
?
19) What is the total number of beta particles emitted in the radioactive series
236 208
92 82
U Pb ?
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MATHEMATICS
SECTION1
SectionI contains 4 multiple choice questions. Each question has 4 choices (A) , (B) , (C)
and (D) , out of which ONLY ONE is correct. For each question in Section  I , you will
be awarded 3 marks if you have darkened only the bubble corresponding to the correct
answer and zero mark if no bubble is darkened. In case of bubbling of incorrect answer,
minus one (1) mark will be awarded.
20)
The greatest value of ( ) ( )
2 3
2sin 3cos 4 6 2sin 3cos u+ u+ u u as u ranges over all
real numbers is
A) 3456 B) 2345 C) 4567 D) 1234
21)
Let
4 1
9 2
A
(
=
(
then
100
A equals
A)
301 100
900 299
(
(
B)
301 100
900 301
(
(
C)
400 101
901 200
(
(
D)
400 99
901 200
(
(
22)
The number of integers ' ' m such that 3 m+ and
2
3 3 m m + + are both perfect cubes of
an integer, is
A) 1 B) 2 C) 3 D) 4
23)
The maximum value of
2 2
x y + such that the real numbers ' ' x and ' ' y satisfy
( )
2 2
4 1 x y x s s is
A)
24 16 2 +
B)
24 16 2
C)
12 8 2 +
D)
12 8 2
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SECTION2
SectionII contains 5 multiple correct answer(s) type questions. Each question has 4 choices (A) ,
(B) , (C) and (D) , out of which ONE OR MORE is/are correct. For each question in Section II ,
you will be awarded 4 marks s if you have darkened all the bubble(s) corresponding to the correct
answer and zero mark if no bubble is darkened. In all other cases , minus one (1) mark will be
awarded.
24) Which of the following statements is/are true?
A) In a triangle if the diameter of any escribed circle equals the perimeter of the triangle,
then the triangle is right angled.
B)
If the inradius of a triangle is 3cm and
1 2 3
, , r r r be the exradii of a triangle, then
1 2 3
1 1 1 1
3 r r r
+ + =
C)
In a triangle,
1
4
abc Rr s = where , , a b c are sides of a triangle, ' ' R the circum
radius, ' ' r the inradius and ' ' s the semi perimeter.
D) The inradius of a triangle having sides 16,63,65cm is 7 . cm
25)
If the matrix A and B are of 3 3 and ( ) I AB is invertible,
then which of the following statements is/are correct?
A) I BA is not invertible
B) I BA is invertible
C) I BA has for its inverse ( )
1
I B I AB A
+
D) I BA has for its inverse ( )
1
I A I BA B
+
26)
Let ( ) 0 z C z e = satisfy
1
2. z
z
+ = Which of the following statements is/are correct?
A) The product of the least and greatest value of z is 1
B) The sum of the least and greatest value of z is 2 2
C) The difference of the greatest and least value of z is 2
D) The least and greatest value occur when ' ' z is purely imaginary
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27)
A curve passes through the point ( ) 1,2 and has slope at any point ( ) , x y as
2
.
2 y
Then
A) The equation to the curve is ( ) ( )
2
2 4 1 y x =
B) The curve is a parabola with its directrix given by 1 x =
C) The curve is a parabola with its directrix given by
1
2
x =
D) The equation of the curve is ( ) ( )
2
2 2 1 y x =
28)
The co ordinates of a point on the line
1 1
2 3 1
x y z +
= =
=
(p) Family of straight lines passing through origin
(B) dy y
dx x
=
(q) Family of straight lines having slope 1
(C)
1
dy
dx
=
(r) Family of curves having slope at any point
( ) , x y equal to the negative of the slope of the
line joining origin and the point ( ) , x y
(D) dy y
dx x
=
(s) Family of curves orthogonal to the line joining
origin and the point ( ) , x y
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30) Match the following:
The matrix
2 2
2 2
2 1
i j
A a
(
(
= =
(
and
cos sin
sin cos
S
u u (
=
(
u u
are such that
T
S AS = diagonal matrix
2 2
i j
D d
(
= =
for some suitably chosen value of 0, .
4
t  
ue

\ .
Let
50
2 2
i j
M A m
(
= =
Column I Column II
(A)
If u is the angle that makes
T
S AS a diagonal matrix
then 3tan2u is
(p) 0
(B)
The value of
11 22
51
4
3
m m
is
(q) 4
(C)
The value of
11 22
d d is
(r) 1
(D)
The value of
12 21
50
3
m m
is
(s) 5
SECTION4
SectionIV contains 8 questions. The answer to each of the question is a single digit integer ,
ranging from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS
have to be darkened. For each question in Section IV , you will be awarded 4 marks if you darken
the bubble corresponding to the correct answer , and zero mark if no bubble is darkened. In all
other cases , minus one (1) mark will be awarded.
31)
Suppose a solution of the differential equation
( )
2 7 3
1
dy
x y x y
dx
+ = satisfies the initial
condition
1
1.
4
y
 
=

\ .
Then the value of
5
4
.
dy
dx
when 1, y = is
32)
The number of integers ' ' k such that the equation
3
3 0 x x k + = has the integer roots,
not necessarily distinct, is
33)
Let
2 2 , , a i j k b i j c = + = +
is a vector such that , 2 2 . a c c c a = =
and angle
between a b
and c
is .
3
t
If
( )
a b c
is
6 3
,
The value of
11
11
+
equals
37)
Let ' ' be the number of divisors of the form ( ) 4 1, 0 n n n Z + > e of the number
13 10 11
10 11 13 then
800
124
equals
38)
The area bounded by the curves
2
4 , 2 y x x y
2
= = and x y = can be expressed
in the form of ,
t+
and
1
2 hr
O I
h h =
I
h
O
h
(r) Concave mirror
(d)

O
I
(s) Convex mirror
49) A block is executing SHM on a rough horizontal surface under the action of an
external variable force. The force is plotted against the position x of the particle
from the mean position. (v =velocity of block, for both v and x positive direction is
towards right)
Column I Column II
(a) x positive, v positive (p) I
(b) x positive, v negative (q) II
(c) x negative, v positive (r) III
(d) x negative, v negative (s) IV
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SECTION4
SectionIV contains 8 questions. The answer to each of the question is a single digit integer ,
ranging from 0 to 9. The appropriate bubbles below the respective question numbers in the ORS
have to be darkened. For each question in Section IV , you will be awarded 4 marks if you darken
the bubble corresponding to the correct answer , and zero mark if no bubble is darkened. In all
other cases , minus one (1) mark will be awarded.
50) A student of height h jumps vertically up from the squat position. At the top point of the
jump, the students center of mass is at a height 3h/4 from the ground. The average force
acting on the floor during the jump prior to the moment when the student loses contact
with the floor is F. It is known that when the student stands on the floor, the center of
mass is at a height h/2 from the floor; in the squat position, the center of mass is at a
height h/4 from the floor. The mass of the student is m. If,
mg
F n
3
1
=
( )
. Find n.
51) O is the point object kept on the principal axis of a concave mirror M of radius of
curvature 20 cm. P is a prism of angle
0
1.8 = . Light first falls on the prism and then
falls on the mirror. The distance between the images formed by the concave mirror due
to
this light is ( )
mm
n
. Find n. Take
2
8
= for prism.
O
52) A metal rod of length 1 m is clamped at two points as shown in figure. Distance of
the clamp from the two ends are 5 cm and 15 cm respectively. The minimum and
next higher frequency of natural longitudinal oscillation of the rod are
1
f and
2
f
respectively. If
2 1
4
10 , f f n Hz = Find n. Given that Youngs modulus of
elasticity and density of aluminum are
11 2 3
1.6 10 2500 Y Nm and kgm
= =
respectively.
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53) What is current i (in amperes) in figure, where all resistances are 4.0O and all batteries
have an emf of 10 V?
54) A battery of e.m.f. 10 V and internal resistance 2O is connected in primary circuit
with a 100 cm long uniform potentiometer wire and a rheostat whose resistance is
fixed at 998O. A battery of unknown e.m.f. E is being balanced on this
potentiometer wire and balancing length is found to be 50 cm. When area of cross
section of potentiometer wire is doubled, then balancing length is found to be 75
cm . Area of crosssection (initially) is
2
100cm . If the e.m.f of the battery
2
n
E Volts = ,
Find n
55)
A current of 2 I A = flows in a circuit having the shape of an isosceles trapezium.
The ratio of the parallel sides of the trapezium is 2. Find the magnetic induction B
( ) in T at symmetric point O in the plane of the trapezium. The length of the smaller
base of the trapezium is 100 , l mm = the distance 50 . h mm =
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56) An A.C. source of angular frequency is fed across a resistor R and a capacitor C in
series. The current registered is I. If now the frequency of source is changed to
3
(but
maintaining the same voltage), the current in the circuit is found to be halved. If the ratio
of reactance to resistance at the original frequency is r, Find the value of
2
5r .
57) The potential energy of a 200 gm particle free to move along the X axis is given
by ( )
2
2
x
V x x J
 
=

\ .
. The total mechanical energy of the particle is 2 J. Find the
maximum speed of the particle. (in m/s).
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