Event Tree Outcomes

6/27/2013

Large LPG Leakage A

Immediate Ignition B

Wind To Pop'd Area C

Delayed Ignition D

Congested Area E

Ignited Jet Points @ Tank F Yes 0.1

Yes 0.9 0.9 No Yes 0.1

BLEVE

Local Thermal Hazard

VCE Yes 0.9 Yes 0.125 Large Leak 1.00E-04 0.1 Safe Dispersal No 0.1 No Yes 0.9 Yes 0.1 VCE Yes 0.1 0.9 0.875 No No No 0.1 Safe Dispersal No Total = 0.9 Flash Fire 0.9 No 0.9 Flash Fire No Yes 0.1

Flash Fir & BLEVE

Flash Fir & BLEVE

Event

Large Leak

Freq or Prob

Source

A B

Large Leak Of Pressurized Flammable Immediate Ignition at Tank

1.00E-04 0.9

Fault Tree Analysis Expert Opinion

R.A. Hawrelak

1:10 AM

154364146.xls.ms_office

ms_office .xls. Hawrelak 1:10 AM 154364146.9 0.125 0.1 Wind Rose data Expert Opinion Historical Data Layout & Piping Geometry R.Event Tree Outcomes 6/27/2013 C D E F Wind Blowing Toward Populated Area Delayed Ignition Near Populated Area Congested Area w Vertical Confinement Jet Flame Strikes Pressurized Vessel 0.1 0.A.

Event Tree Outcomes 6/27/2013 Frequency Per Year 9.00E-04 R.1E-07 1.xls. Hawrelak 1:10 AM 154364146.00E-06 8.1E-07 1.4E-06 8.A.8E-07 1.1E-07 6.1E-05 1.3E-07 7.ms_office .9E-07 7.0E-07 9.

xls. Hawrelak 1:10 AM 154364146.ms_office .A.Event Tree Outcomes 6/27/2013 R.

x13 yo 2y1 2y2 2y3 2y4 2y5 2y6 2y7 2y8 2y9 2y10 2y11 2y12 y13 Ttl yo .. R1.7 18.4 34.50 kgm/cu.9 23.0 0 13 2.1 15.03390 kgm/cu. Clancey. Ta = Atmospheric Pressure.5 Line failure 2085.56% Trapazoidal Rule to Solve Integral in Eq 27 Radius at R1 = b Radius at 0 = a Divide (a to b) into n = parts h = (b . R1. La Propane Goto List_Of_Chemicals For Some Phys Prop Data 8.36 533.68 266.844 US Gal 220. std dev'n of conc'n by Eq 25 Cloud Radius.90 feet 19.791. Eq 4 Flammable Conc'n.35 0.36 56.60 491.1 28. cf = Vessel Surface Area Vessel Shell Thickness = Wt Of Vessel = Vessel Design Pressure..5 13.99 5.a) / n = dr = xo x1 x2 x3 x4 x5 x6 x7 x8 x9 x10 x11 x12 Cloud Radius.7 kPa 138 °F 59 °C 44 19. m.00 deg K 0. at UEL Sig m.89 R.04 537.54 52.1771 kJ/kgmK 183. 63.00% 138 deg F 332.80 277.8 10. at LEL by Eq 26 Mass of Vapor in Flam Cloud.2 7.6 0. T = Atmospheric Boiling Pt.000 lbs 99. Frankfurt 1978 34.38 189.02 268. 0.2 BTU/lb 426.. psig = Liquid Temp at Failure Pressure = Molecular Weight Quantity Material = Liquid Density = Ambient Temperature.085. Eq 27 Depropanizer 27-Jun-13 Rapid Depressurization 1:10 AM Norco.3 20.37 tonnes 27 lb/cf 432.69 355.04 4. Heidelberg. C1.64 430. m.xls.0 2.95 252. 2nd Int.5 50.7 psia 101.689.98 meters 12.52 BTU/lb/F 2.48 meters 111.15334 kgm/cu..97 252.000 lbs 9. Hawrelak 1:10 AM 154364146.19 556. = Relative Humidity = Flow Temperature.5 psig 302. m.000 Tower 226.25 272.0 yo y1 y2 y3 y4 y5 y6 y7 y8 y9 y10 y11 y12 y13 Integral Eqn 27 0.00957 lb/cf 0.3125 inches 59.Vessel Hazards and Consequence Analyses 6/27/2013 Vessel = Case Chemical Stored Vessel Volume. 1877. m3.63 136. Tb = Avg Liq Cp Between Amb & Stg Temp Latent Heat at Atm Boiling Point = Lower Flammable Limit Upper Flammable Limit Heat Of Combustion = Mols O2/Mols HC On Combustion = Mass of Liq Flashing to Atm.00 6.82 215.y13 A = h/2(yo+2y1+2y2+. in Hemisphere = kgm in flam=(2p)(C2)(m3.095 19. Symp.29 Mj/Kgm 5 = (n+m/4) in CnHm Hydrocarbon.5 26.)= Basis: V.35 350 PSV Fire Flow Pressure = 423.418 % Full = 17.69 94.481.353 N/sq m 101.34 177.59 278.12 kJ/kgm 0.900 BTU/lb 46.61 555.+yn) Cu..6 5.00212 lb/cf 0.71 113.353.7 31..37 Tonnes 3.04 0 13.A.47 feet 33.73% 17.89 kgms 31. psig = Vessel Failure Pressure.30 245. cf = Liquid Storage Volume.54 cu.15 Tons 17. eg in C2H4 =(2+4/4) = 3 20. m 1.69 m2 1.850 sf 357. Dechema. at LEL Flammable Conc'n.ms_office .33 deg K 14.23% 0. meter 86 °F 303. p-323.22 deg K -46 deg F 230.38 lbs 5.481. Presented In Lihou Course Promotion in the Process Industries.021 0. on Loss Prevention and Safety.77 26.07 tonnes 52.69 5.J. C2.

000 Distance From Vessel.000 .00 Clancey Gugan P S O i n p s i g Flix Pts. Feet 10.10.00 0.10 100 1. Edge Of Cloud 1.

0 T i 10. p 100.1 1 10 100 1000 Incident Thermal Flux. 1984).33: Serious Injury/Fatality Levels For Thermal Radiation (Mudan. CPQRA.0 0.Fig 2. kW/sq m .0 m e S e c 1.

p-161 Near 100% Fatal Mean 50% Fatal 2nd Deg Burns 1st Deg Burns Pain Threshold Mudan LC50 Pt. Case Eisenberg LC50 1000 . CPQRA. Single Pt.1984).