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Introduction to Crystallography (This material has been slightly modified from a narrative by Dr John Grace, WMU faculty emeritus) Since most naturally occurring solid substances have an orderly array of atoms they will often display (given enough time and space) planar faces typically grouped together in a shape referred to as a crystal. Since a given crystal shape is a reasonable diagnostic feature for any given mineral it will be worth our while to understand the science of crystallography. It is one of natures' most amazing intrigues that no matter what sort of permutations, or numbers of atoms you put together as a regularly bonded aggregate you will have only six possible basic arrays! These are referred to as the six crystal systems. For convenience we illustrate the six systems below by using a notation called the crystallographic axes to illustrate the dimensionality of each system.

There are literally thousands of possible crystal shapes and combinations of shapes so the process of understanding crystallography is a little more complicated than just knowing the six systems. You should carefully study pages 16 through 21 in you field guide to understand some of the possible forms found within each of the six systems. A more extensive Introduction to Crystallography and Mineral Crystal Systems by Mike and Darcy Howard is provided as Appendix A of your M&RCP

Symmetry One technique that can be useful in determining what system a particular crystal might belong to is the property of symmetry. Symmetry elements include planes of symmetry (2-D or mirror plane symmetry), axes of symmetry (1D, linear or rotational symmetry), and points of inversion (dimension-less or roto-inversion symmetry) that, in combination, can help distinguish one crystal from another. An axis of symmetry is an imaginary axis about which an object is rotated and if it appears symmetrical or the same at some point in one full rotation then it is said to have an axis of symmetry. The number of times it may repeat during one rotation gives the "foldedness" of a particular symmetry axis. In the crystalline world axis of symmetry of 2, 3, 4, or 6 fold are the only types of axis found

Figure 2

We can illustrate the concept by observing the figures shown above in Figure 2. The cube can be seen to have three 4 fold axes or symmetry corresponding to the crystallographic axes. In addition there are 3-fold axis of symmetry and many 2-fold axis of symmetry that do not correspond to the crystallographic axes. The cube represents one of natures most symmetrical crystalline shapes. If we observe the hexagonal prism in Figure 2b we see that it has a six fold symmetry axis corresponding to the C crystallographic axis and many two fold axis that are normal to the C axis and lie in the plane of the a1 a2 a3 crystallographic axis. The orthorhombic crystal in Figure 2c has only 3 axis of 2 fold symmetry which correspond to the a, b, and c crystallographic axes. It can be shown that the amount of symmetry is greatest for the cubic systems and is sequentially less as we consider each succeeding system until we reach the triclinic system that have very little symmetry. The following table lists the "characteristic" symmetry for each system and in our first laboratory we will use these concepts to develop our skills at placing unknown crystal into the appropriate crystal system. TABLE 1 Crystal System Cubic (isometric) Tetragonal Hexagonal Orthorhombic Monoclinic Triclinic Characteristic Symmetry 3 axes of 4 fold 1 axis of 4 fold 1 axis of 6 fold 3 axes of 2 fold* 1 axis of 2 fold 1 fold symmetry only Symbology (3A4) (1A4) (1A6) (3A2) (1A2)

Book references: Simon and Schusters Guide to Rocks and Minerals; pp8-2 Darby; Hands on Mineral Identification: Ch7, slides 145 to 186 WWW sites for reference: Mike and Darcy Howard: Crystallography and Mineral Crystal Systems http://www.rockhounds.com/rockshop/xtal/ David Barthelmy: Mineralogy Database; Crystallography http://webmineral.com/crystall.shtml L.S. Fichter: Crystal/Cleavage Models http://csmres.jmu.edu/geollab/Fichter/Minerals/cleavage.PDF

Name ____________________

I. Determine the crystal system for each of the large wood models in the grey plastic trays. Sym. System Sym. System 1 ___________________________ 4____________________________ 2 ___________________________ 5____________________________ 3 ___________________________ 6____________________________ II. Do the same for the small models in the wood box set. Sym. System Sym. System 1___________________________ 7*__________________________ 2___________________________ 8__________________________ 3___________________________ 9__________________________ 4*__________________________ 10__________________________ 5___________________________ 11 __________________________ 6___________________________ *Nos. 4 and 7 are difficult and may have more symmetry than you might think initially. III. Real crystals (in plastic tray) Real crystals are often distorted by accidents of growth so you must make allowances and assume the crystal is complete and perfect. Quartz ______________________ Halite _____________________ Garnet ______________________ Feldspar _____________________ Apatite _____________________ Pyrite _____________________

IV. Museum Tour - do the best you can do observing the following from a distance. Calcite _________________ Fluorite _____________________ Tourmaline _________________ Gypsum _____________________

Name________________

1. List the axes and planes of symmetry for the following objects. (These are not mineral crystals so there is no limitation on the amount of symmetry they might possess) a. b. c. d. e. f. An egg ___________________________________ A pair of scissors ___________________________________ The human body ___________________________________ Everett Tower ___________________________________ A star fish ___________________________________ A car ___________________________________

Construct the crystal/cleavage models and determine the symmetry elements for the first four models. Include mirror plane symmetry, rotational symmetry and try to determine roto-inversion symmetry. See : L.S. Fichter: Crystal/Cleavage Models http://csmres.jmu.edu/geollab/Fichter/Minerals/cleavage.PDF

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