You are on page 1of 7


according to Regulation (EC) No. 1907/2006 Version 5.0 Revision Date 04.10.2012 Print Date 02.07.2013 GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA

1. 1.1

IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers Product name Product Number Brand CAS-No. : : : :

Sodium dodecylbenzenesulfonate
289957 Aldrich 25155-30-0


Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances


Details of the supplier of the safety data sheet Company : Sigma-Aldrich Chemicals Pvt Limited Plot No 12 Bommasandra - Jigani Link Road 560100 BANGALORE INDIA +91 80-6621 9400 +91 80-6621 9450

Telephone Fax 1.4

: :

Emergency telephone number Emergency Phone # : +91-9880711432

2. 2.1

HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP] Acute toxicity, Oral (Category 4) Skin irritation (Category 2) Serious eye damage (Category 1) Specific target organ toxicity - single exposure (Category 3) Classification according to EU Directives 67/548/EEC or 1999/45/EC Harmful if swallowed. Irritating to respiratory system and skin. Risk of serious damage to eyes.


Label elements Labelling according Regulation (EC) No 1272/2008 [CLP] Pictogram Signal word Hazard statement(s) H302 H315 H318 H335 Precautionary statement(s) P261 P280 P305 + P351 + P338 Supplemental Hazard Danger Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wear protective gloves/ eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. none
Page 1 of 7

Aldrich - 289957

Consult a physician. give artificial respiration. 246-680-4 : : : Dodecylbenzenesulfonic acid sodium salt C18H29NaO3S 348. 3. 5. If inhaled If breathed in.2 Most important symptoms and effects.Statements According to European Directive 67/548/EEC as amended. Consult a physician. Rinse mouth with water. and toxicological properties have not been thoroughly investigated.1 Other hazards . gloves and eye/face protection. If not breathing. In case of skin contact Wash off with soap and plenty of water. 4. Hazard symbol(s) R-phrase(s) R22 R37/38 R41 S-phrase(s) S26 S27 S36/37/39 2. rinse immediately with plenty of water and seek medical advice. Consult a physician. Risk of serious damage to eyes. 4. Show this safety data sheet to the doctor in attendance. dry chemical or carbon dioxide. 4. Wear suitable protective clothing. both acute and delayed To the best of our knowledge. 4. If swallowed Never give anything by mouth to an unconscious person. move person into fresh air. the chemical.3 5.none COMPOSITION/INFORMATION ON INGREDIENTS Substances Synonyms Formula Molecular Weight Component Sodium dodecylbenzenesulfonate CAS-No. Indication of any immediate medical attention and special treatment needed no data available FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media Use water spray. In case of contact with eyes.3 3. physical. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.1 Aldrich .1 FIRST AID MEASURES Description of first aid measures General advice Consult a physician. Take off immediately all contaminated clothing. Irritating to respiratory system and skin. alcohol-resistant foam. 25155-30-0 EC-No.48 g/mol Concentration - Harmful if swallowed.289957 Page 2 of 7 .

Wash hands before breaks and at the end of workday.2 7. Keep container tightly closed in a dry and well-ventilated place. Sodium oxides Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary.4 7. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Evacuate personnel to safe areas. Size M) Aldrich . Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Sweep up and shovel. 6.3 8. 7.3 5.3 6.4 Special hazards arising from the substance or mixture Carbon oxides. Ensure adequate ventilation. Reference to other sections For disposal see section 13.1 6.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. closed containers for disposal.5. Avoid breathing vapors.2 6. including any incompatibilities Store in cool place. Provide appropriate exhaust ventilation at places where dust is formed.2 5. Wash and dry hands. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Avoid formation of dust and aerosols. Keep in suitable. Avoid dust formation. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Further information no data available ACCIDENTAL RELEASE MEASURES Personal precautions. Environmental precautions Do not let product enter drains. mist or gas. Conditions for safe storage. Specific end uses no data available EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters 6. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0. Skin protection Handle with gloves. Gloves must be inspected prior to use. 8.1 8.1 7. Avoid breathing dust. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Sulphur oxides.11 mm Break through time: 480 min Material tested:Dermatril® (Aldrich Z677272.289957 Page 3 of 7 . protective equipment and emergency procedures Use personal protective equipment.

and under conditions which differ from EN 374. Size M) data source: KCL GmbH. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).45 no data available no data available no data available no data available Page 4 of 7 m) Relative density Aldrich .Splash protection Material: Nitrile rubber Minimum layer thickness: 0. D-36124 Eichenzell. It should not be construed as offering an approval for any specific use scenario. phone +49 (0)6659 873000. If the respirator is the sole means of protection. use a full-face supplied air respirator. Body Protection Complete suit protecting against chemicals. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. e-mail sales@kcl. gas) no data available k) l) n) o) p) q) r) s) no data available no data available no data available no data available log Pow: 0. contact the supplier of the CE approved gloves. 9. test method: EN374 If used in solution.289957 . This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers.1 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties a) b) c) d) e) f) g) h) i) j) Appearance Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Upper/lower flammability or explosive limits Vapour pressure Vapour density Water solubility Partition coefficient: noctanol/water Autoignition temperature Decomposition temperature Viscosity Explosive properties Form: powder Colour: light yellow no data available no data available no data available no data available no data available no data available no data available no data available Flammability (solid.11 mm Break through time: 480 min Material tested:Dermatril® (Aldrich Z677272. or mixed with other substances.

24 h Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1 Reproductive toxicity no data available Specific target organ toxicity . May be harmful if absorbed through skin. and Taste):Eye:Lacrimation. Diarrhoea Skin corrosion/irritation Skin .single exposure Inhalation .Severe eye irritation .rat .24 h Serious eye damage/eye irritation Eyes .6 11. Causes respiratory tract irritation. possible or confirmed human carcinogen by IARC.2 10. data available TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity LD50 Oral .repeated exposure no data available Aspiration hazard no data available Potential health effects Inhalation Ingestion Skin Eyes Aldrich .289957 May be harmful if inhaled.5 10. Specific target organ toxicity .rabbit . Eye. Harmful if swallowed.rabbit . Causes skin irritation.4 10. Causes eye burns.1 10. 10.438 mg/kg Remarks: Sense Organs and Special Senses (Nose.2 Oxidizing properties no data available Other safety information no data available STABILITY AND REACTIVITY Reactivity no data available Chemical stability no data available Possibility of hazardous reactions no data available Conditions to avoid no data available Incompatible materials Strong oxidizing agents Hazardous decomposition products Other decomposition products . Ear.1% is identified as probable.t) 9. Behavioral:Somnolence (general depressed activity).Skin irritation . 11.May cause respiratory irritation. Page 5 of 7 .3 10.

13.3.3 d mortality LOEC . 14.4 12.6 mg/l . physical. no data available DISPOSAL CONSIDERATIONS Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company.4 mg/l .6 13.5.4 14. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Daphnia .5 12. the chemical.3 d Toxicity to daphnia and other aquatic invertebrates 12.289957 . Contaminated packaging Dispose of as unused product.Oncorhynchus kisutch .1 mg/l .Oncorhynchus kisutch .3 14. 12. 12.6 IMDG: IMDG: IMDG Marine pollutant: no IATA: IATA: IATA: no Aldrich .1 14.1 ECOLOGICAL INFORMATION Toxicity Toxicity to fish mortality NOEC .5 14. Additional Information RTECS: DB6825000 12.2 TRANSPORT INFORMATION UN number ADR/RID: UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods Transport hazard class(es) ADR/RID: Packaging group ADR/RID: Environmental hazards ADR/RID: no Special precautions for user no data available Page 6 of 7 IMDG: - IATA: - 14.3 mortality NOEC .2 12. and toxicological properties have not been thoroughly investigated.7 d Persistence and degradability no data available Bioaccumulative potential Bioaccumulation Lepomis macrochirus .28 d -64 µg/l Bioconcentration factor (BCF): 220 Mobility in soil no data available Results of PBT and vPvB assessment no data available Other adverse effects Avoid release to the environment.1 14.Signs and Symptoms of Exposure To the best of our knowledge.

15. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide.1 15. See www. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. License granted to make unlimited paper copies for internal use and/or the reverse side of invoice or packing slip for additional terms and conditions of sale. It does not represent any guarantee of the properties of the product.2 Safety. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 16.sigmaaldrich. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions.289957 Page 7 of 7 . Aldrich . health and environmental regulations/legislation specific for the substance or mixture no data available Chemical Safety Assessment no data available OTHER INFORMATION Further information Copyright 2012 Sigma-Aldrich Co.15. LLC.