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Revision Date: 05/04/2004 000000006467/Version: 1.4 Print Date: 10/13/2005 Page: 1/7
1. Identification of the substance/preparation and the company/undertaking
Product name: KODAK FLEXICOLOR Ra Fixer and Replenisher, Process C-41/RA Product code: 10069598 Supplier: EASTMAN KODAK COMPANY, 343 State Street, Rochester, New York 14650; KODAK CANADA INC., 3500 Eglinton Avenue W., Toronto, Ontario, M6M 1V3 For Emergency Health, Safety & Environmental Information, call (585) 722-5151 (USA) For other information or to request an MSDS, call (800) 242-2424. Synonyms: PCD 6546
2. Hazards identification
CONTAINS: Ammonium thiosulphate (7783-18-8), Ammonium thiocyanate (1762-95-4), Ammonium sulphite (10196-04-0), Sodium sulphite (7757-83-7) WARNING! CAUSES SKIN AND EYE IRRITATION HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWED CAN CAUSE THYROID DAMAGE MAY LIBERATE SULFUR DIOXIDE CONTACT WITH STRONG OXIDIZER OR ACID LIBERATES POISONOUS AND FLAMMABLE GAS DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT. HMIS Hazard Ratings: Health - 2*, Flammability - 1, Reactivity (Stability) - 0 NFPA Hazard Ratings: Health - 2, Flammability - 1, Instability - 0 NOTE: HMIS and NFPA hazard indexes involve data review and interpretation that may vary among companies. They are intended only for rapid, general identification of the magnitude of the potential hazards. An asterisk (*), in the HMIS health field, designates potential chronic or target organ hazards. To adequately address safe handling, ALL information in this MSDS must be considered.
3. Composition/information on ingredients
Weight % 65 - 70 25 3 2 1- 5 Components (CAS-No.) Water (7732-18-5) Ammonium thiosulphate (7783-18-8) Ammonium thiocyanate (1762-95-4) Ammonium sulphite (10196-04-0) Sodium sulphite (7757-83-7)
sulfur oxides (see also Hazardous Decomposition Products section). First aid measures Inhalation: If symptomatic. Get medical attention if symptoms occur.4 Print Date: 10/13/2005 Page: 2/7 4. Wash thoroughly after handling.MATERIAL SAFETY DATA SHEET Revision Date: 05/04/2004 000000006467/Version: 1. rags. 5. 6. the local emergency ambulance/resuscitation service or physician should be informed that the patient may have been exposed to hydrogen cyanide gas. sawdust. Get medical attention if symptoms occur. Clean surface thoroughly to remove residual contamination. Handling and storage Personal precautions: If accidentally mixed with a strong oxidizer or acid. Fire or excessive heat may produce hazardous decomposition products. For Large Spills: Flush with plenty of water. move to fresh air. and clothing. 7. Get medical attention if symptoms occur. nitrogen oxides (NOx). Use with adequate ventilation. Fire-fighting measures Extinguishing Media: Use water spray. Flush with plenty of water. dry chemical or carbon dioxide. Eyes: Immediately flush with plenty of water for at least 15 minutes. In the event that hydrogen cyanide gas is released. Avoid breathing mist or vapour. Notes to physician: Hazards: WARNING! Contact with a strong oxidizer or acid may liberate hydrogen cyanide gas. Never give anything by mouth to an unconscious person. alcohol-resistant foam. Treat symptomatically. paper. cotton. porous material (e. Call a physician or poison control center immediately. Destroy or thoroughly clean contaminated shoes. Reacts violently with oxidizing materials. May cause spontaneous heating and ignition when absorbed on combustible. Accidental release measures Methods for cleaning up: Collect in a noncombustible container for prompt disposal. clothing). Wash contaminated clothing before re-use. Hazardous Combustion Products: Carbon oxides. Ingestion: Only induce vomiting at the instruction of medical personnel.g. Unusual Fire and Explosion Hazards: Dried product residue can act as a reducing agent. Skin: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Avoid contact with eyes. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing. skin. do not breathe gas. .
Keep away from incompatible substances (see Incompatibility section. extension 60. request a copy of the KODAK Publication CIS-3. Remove and wash contaminated clothing promptly. Biocides for Photographic Solution Tanks and Wash Water. Skin and body protection: Wear impervious gloves and protective clothing appropriate for the risk of exposure. Respiratory protection: None should be needed. chlorine containing bleaches. 9. The addition of concentrated cleaning agents. highly oxygenated or halogenated solvents. e. Ventilation rates should be matched to conditions. For information on the recommended methods for cleaning processing tanks. Storage: Store in original container. In the United States: If respirators are used.) 8. Keep container tightly closed to prevent the loss of water.134. Eye protection: Wear safety glasses with side shields (or goggles). closed systems. a program should be instituted to assure compliance with OSHA Standard 29CFR 1910.g. However in the unlikely event that hazardous decomposition products are released.18 .4 Print Date: 10/13/2005 Page: 3/7 Cleaning Precautions: DO NOT add cleaning agents to processor tanks unless the tank and recirculation lines have been completely drained and thoroughly rinsed with water. eye wash. Recommended Decontamination Facilities: Safety shower. contact the Kodak Customer Assistance Center at (800) 242-2424. See Stability and Reactivity Section. or respiratory protection may be needed in special circumstances. For information on controlling biological growth. Exposure controls / personal protection Occupational exposure controls Chemical Name Sulphur dioxide Regulatory List ACGIH ACGIH OSHA Z1 Value Type Time Weighted Average (TWA): Short Term Exposure Limit (STEL): PEL: Value 2 ppm 5 ppm 5 ppm 13 mg/m3 Ventilation: Good general ventilation (typically 10 air changes per hour) should be used. emergency response personnel must wear a full-face positivepressure air supplied respirator. Supplementary local exhaust ventilation. washing facilities as appropriate to condition of use.MATERIAL SAFETY DATA SHEET Revision Date: 05/04/2004 000000006467/Version: 1. organic compounds containing reducible functional groups. Prevention of Fire and Explosion: Keep from contact with oxidizing materials. to control biological growth or clean tanks may liberate hazardous gases. Keep away from acids. Physical and Chemical Properties Physical form: liquid Colour: clear Odour: ammonia Specific gravity: 1.
6 Volatile fraction by weight: 65 . Contact with strong acids liberates sulphur dioxide. chloramine.70 % Boiling point/range: > 100. rapid pulse. Contact with base liberates ammonia. Contact with strong oxidizing agents or acids liberates toxic and flammable gas. sulphites may liberate sulphur dioxide gas.MATERIAL SAFETY DATA SHEET Revision Date: 05/04/2004 000000006467/Version: 1. Toxicological information Effects of Exposure General advice: Contains: Ammonium thiocyanate. unconsciousness. sodium hypochlorite (bleach) or strong acids may liberate cyanides or carbonyl sulphide.0 °C (68.0 °C (> 212. sodium hypochlorite (bleach). Some asthmatics or hypersensitive individuals may experience difficult breathing. carbonyl sulfide.5 Flash point: None 10.0 mm Hg) Relative vapour density: 0. Eyes: Causes irritation. halogenated compounds. Hazardous decomposition products: ammonia. convulsions and death. Sulphur dioxide gas is irritating to the respiratory tract. sulphur oxides. If hydrogen cyanide gas is liberated due to contact with a strong oxidizer or acid. Skin: Causes irritation.0 °F) Water solubility: complete pH: 7. and symptoms of hypothyroidism in humans and animals. oxidizing agents. Hazardous Polymerization: Hazardous polymerisation does not occur. however. Inhalation: Expected to be a low hazard for recommended handling. This material has a low potential to cause allergic skin reactions. cyanides.g. it may cause dizziness. Harmful if absorbed through skin. . Stability and reactivity Stability: Stable Incompatibility: Acids. Contact with sodium hypochlorite (bleach) may form chloramine (toxic gas).0 °F)) : 24 mbar (18. headache. rapid respiration. Overexposure to thiocyanates has been shown to cause thyroid enlargement. strong bases. cases of human skin sensitization have been reported.4 Print Date: 10/13/2005 Page: 4/7 Vapour pressure (at 20. Contact with strong oxidizing agents e. decrease in metabolic rate. Contact with base liberates flammable material. In contact with strong acids or if heated. 11.
faintness. 12. and 5 p. 14.m.m. (Eastern Standard Time). May cause irritation of the gastrointestinal tract.) . weakness and diarrhea. hives. Ammonium sulphite: 3 (not classifiable as to carcinogenicity to humans). Transport information Not regulated for all modes of transportation.MATERIAL SAFETY DATA SHEET Revision Date: 05/04/2004 000000006467/Version: 1. state. or disposal may be subject to national.4 Print Date: 10/13/2005 Page: 5/7 Ingestion: Harmful if swallowed.S. or local laws. In Canada: General Shipping Information. Regulatory information U. California Prop. chest tightness. Disposal considerations Consult state or local regulatory authorities before flushing to sewer with large amounts of water. Since emptied containers retain product residue. treatment. Sulphur dioxide: 3 (not classifiable as to carcinogenicity to humans) American Conference of Governmental Industrial Hygienists (ACGIH): Sodium bisulphite: Group A4 (Not classifiable as a human carcinogen. call: (416) 766-8233. Monday through Friday. Discharge. Some asthmatics or sulfite-sensitive individuals may experience wheezing. Potential Toxicity: Fish LC50: Daphnid EC50: Algal IC50: Waste treatment organisms EC50: Organics Readily Degradable: Potential Bioaccumulation: COD (approximate): BOD (approximate): > 100 mg/l > 100 mg/l 100 mg/l > 100 mg/l Readily biodegradable log Pow < 1 75 g/l 61 g/l 13. 15. Ecological information The following properties are ESTIMATED from the components of the preparations. For transportation information regarding this product call the Kodak Worldwide Transportation Hazmat Hot Line: (585) 722-2400 between 8 a. 65: none Carcinogenicity Classification (components present at 0. follow label warnings even after container is emptied.1% or more): International Agency for Research on Cancer (IARC): Sodium sulphite: 3 (not classifiable as to carcinogenicity to humans). stomach upset.
do not breathe gas. and clothing. follow label warnings even after container is emptied. Avoid contact with eyes.S. Sodium sulphite (7757-83-7) WARNING! CAUSES SKIN AND EYE IRRITATION HARMFUL IF ABSORBED THROUGH SKIN OR SWALLOWED CAN CAUSE THYROID DAMAGE MAY LIBERATE SULFUR DIOXIDE CONTACT WITH STRONG OXIDIZER OR ACID LIBERATES POISONOUS AND FLAMMABLE GAS DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT. alcohol-resistant foam. only induce vomiting as directed by medical personnel. immediately flush eyes and skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. National Toxicology Program (NTP): none U. Remove and wash contaminated clothing promptly. Additional hazard precautions for containers greater than 1 gallon of liquid or 5 pounds of solid: IN CASE OF FIRE: Use water spray. Destroy or thoroughly clean contaminated shoes. . Keep out of reach of children. Ammonium thiosulphate (as a source of aqueous ammonia). FIRST AID: If swallowed. Since emptied containers retain product residue. Ammonium thiocyanate (1762-95-4). Occupational Safety and Health Administration (OSHA): none Chemical(s) subject to the reporting requirements of U. Ammonium sulphite (10196-04-0). Wash contaminated clothing before reuse. Other information US/Canadian Label Statements: CONTAINS: Ammonium thiosulphate (7783-18-8). Call a physician or poison control center immediately.4 Print Date: 10/13/2005 Page: 6/7 U.S. If accidentally mixed with a strong oxidizer or acid. Wash thoroughly after handling. Do not handle or use until safety precautions in Material Safety Data Sheet (MSDS) have been read and understood. Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372: Ammonium sulphite (as a source of aqueous ammonia). Keep container tightly closed to prevent the loss of water. Avoid breathing mist or vapour. Ammonium thiocyanate 16. Use with adequate ventilation. dry chemical or carbon dioxide. Never give anything by mouth to an unconscious person. skin. Keep from contact with clothing and other materials.S. Get medical attention if symptoms occur.MATERIAL SAFETY DATA SHEET Revision Date: 05/04/2004 000000006467/Version: 1. In case of contact.
S-2. The information relating to the working solution is for guidance purposes only. and is based on correct mixing and use of the product according to instructions. C-1 . Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials and the safety and health of employees and customers and the protection of the environment. F-1. R-1. The information contained herein is furnished without warranty of any kind.MATERIAL SAFETY DATA SHEET Revision Date: 05/04/2004 000000006467/Version: 1.4 Print Date: 10/13/2005 Page: 7/7 IN CASE OF SPILL: Flush with plenty of water.