MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer

10/31/12

Material Safety Data Sheet
Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SCOTCHKOTE 345 Liquid Phenolic Primer MANUFACTURER: 3M DIVISION: Infrastructure Protection Division ADDRESS: 3M Center, St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 10/31/12 Supercedes Date: 02/16/12 Document Group: 11-1235-8 Product Use: Specific Use: Intended Use:

Primer for Metal Primer

SECTION 2: INGREDIENTS
Ingredient
ETHANOL PHENOL-FORMALDEHYDE RESIN IRON OXIDE BUTANOL 2-BUTOXYETHANOL METHANOL PHENOL ETHYL ACETATE FORMALDEHYDE METHYL ISOBUTYL KETONE

C.A.S. No.
64-17-5 9003-35-4 1332-37-2 71-36-3 111-76-2 67-56-1 108-95-2 141-78-6 50-00-0 108-10-1

% by Wt
30 - 40 20 - 30 10 - 20 3- 7 3- 7 1- 3 1- 2 <2 < 0.25 < 0.25

SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Red, Solvent Odor General Physical Form: Liquid

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and environmental hazards: Flammable liquid and vapor. Central Nervous System (CNS) Depression: Signs/symptoms may include headache. Blood Effects: Signs/symptoms may include generalized weakness and fatigue. cloudy appearance of the cornea. sneezing. Hematopoietic Effects: Signs/symptoms may include generalized weakness. and tightness of chest. chest tightness. swelling. incoordination. blistering. tearing. 3. nausea. cough. changes in heart rate. and may be fatal. sputum production. Inhalation: May be harmful if inhaled. swelling. May be absorbed following ingestion and cause target organ effects. and/or hemoglobinemia. drowsiness. changes in blood clotting time. wheezing.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 Immediate health. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. stomach upset. and dryness. May cause severe eye irritation. and impaired vision. headache. giddiness. Respiratory Effects: Signs/symptoms may include cough. May cause allergic skin reaction. nausea. Moderate Skin Irritation: Signs/symptoms may include localized redness. May cause target organ effects. Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia). changes in lung function tests. and unconsciousness. dizziness. skin pallor. bluish colored skin (cyanosis). Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness. wheezing. _________________________________________________________________________________________________ Page 2 of 10 . fatigue and alterations in numbers of circulating blood cells. damage to heart muscle. pain. internal bleeding. Closed containers exposed to heat from fire may build pressure and explode. Allergic Respiratory Reaction in sensitive people: Signs/symptoms may include difficulty breathing. Skin Contact: May be harmful if absorbed through skin. slowed reaction time. slurred speech. Target Organ Effects: May cause blindness. May be absorbed through skin and cause target organ effects. physical. hoarseness. shortness of breath. Contains a chemical or chemicals which can cause cancer. itching. Vapors may travel long distances along the ground or floor to an ignition source and flash back. and nose and throat pain. Ingestion: May be harmful if swallowed. May be absorbed following inhalation and cause target organ effects. increased heart rate. heart attack. vomiting and diarrhea. and/or respiratory failure.2 POTENTIAL HEALTH EFFECTS Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness. swelling. Respiratory Tract Irritation: Signs/symptoms may include cough. nasal discharge. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain. and itching.

and painful urination.S.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 Kidney/Bladder Effects: Signs/symptoms may include changes in urine production. 50-00-0 50-00-0 50-00-0 108-10-1 Class Description Grp. Immediately flush skin with large amounts of water. the U. Prolonged or repeated exposure may cause: Liver Effects: Signs/symptoms may include loss of appetite. abdominal tenderness and jaundice. Respiratory Effects: Signs/symptoms may include cough.A. 1: Carcinogenic to humans Known human carcinogen Cancer hazard Grp. lack of coordination.S. sensory loss. 2B: Possible human carc. blindness. Inhalation: Remove person to fresh air. weakness. blood in urine. and/or respiratory failure. Additional pharmacologic and supportive care should be based on the treating physician’s judgement. bluish colored skin (cyanosis). weakness. National Toxicology Program. and/or changes in blood pressure and heart rate. If signs/symptoms develop. Alcoholic beverages and ethanol in alcoholic beverages have been classified as human carcinogens by the International Agency for Research on Cancer. Regulation International Agency for Research on Cancer National Toxicology Program Carcinogens OSHA Carcinogens International Agency for Research on Cancer SECTION 4: FIRST AID MEASURES 4. weight loss. sputum production.2 NOTE TO PHYSICIANS This product contains methanol.1 FLAMMABLE PROPERTIES _________________________________________________________________________________________________ Page 3 of 10 . Get immediate medical attention. Get medical attention. and the California Environmental Protection Agency (for purposes of Proposition 65). Never give anything by mouth to an unconscious person. chest tightness. fatigue. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Neurological Effects: Signs/symptoms may include personality changes.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. SECTION 5: FIRE FIGHTING MEASURES 5. Carcinogenicity: NOTE: This product contains ethanol. wheezing. get medical attention. Skin Contact: Remove contaminated clothing and shoes. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. increased heart rate. Give victim two glasses of water. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. increased protein in urine. and death. tingling or numbness of the extremities. 4. Wash contaminated clothing and clean shoes before reuse. Methanol poisoning can cause metabolic acidosis. If methanol poisoning is confirmed. Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer. changes in lung function tests. increased blood urea nitrogen (BUN). No. tremors. abdominal or lower back pain. Ingredient FORMALDEHYDE FORMALDEHYDE FORMALDEHYDE METHYL ISOBUTYL KETONE C. Get medical attention. Onset of signs or symptoms may be delayed for 18 to 24 hours. Contains a chemical or chemicals which can cause cancer. shortness of breath. intravenous (IV) administration of ethanol should be considered.

An AR . state. however.0 % volume 36. 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e. or spills in confined spaces.. Dispose of collected material as soon as possible. Place in a metal container approved for use in transportation by appropriate authorities.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. The spill should be cleaned up by qualified personnel.2. Read and follow safety precautions on the solvent label and MSDS. Seal the container. adding an absorbent material does not remove a toxic. dry chemical. such as alcohols and acetone. cover drains and build dikes to prevent entry into sewer systems or bodies of water. Use only non-sparking tools. in accordance with good industrial hygiene practice. Vapors may travel long distances along the ground or floor to an ignition source and flash back. it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Ventilate the area with fresh air.g. smoking materials. provide mechanical ventilation to disperse or exhaust vapors. vermiculite. or commercially available inorganic absorbent material. Water may be used to blanket the fire. Contain spill.1. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Personal precautions. Mix in sufficient absorbent until it appears dry. For large spill. Ventilate the area with fresh air.1 HANDLING For industrial or professional use only. cover with bentonite.5 % volume Class IB Flammable Liquid 5. SECTION 7: HANDLING AND STORAGE 7. Avoid skin contact. Do not breathe vapors. the user should determine if the release qualifies as reportable according to local. Unusual Fire and Explosion Hazards: Flammable liquid and vapor. and federal regulations. Avoid eye _________________________________________________________________________________________________ Page 4 of 10 . protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. Remove all ignition sources such as flames. Remember. Environmental precautions For larger spills. that can dissolve in water. Closed containers exposed to heat from fire may build pressure and explode. 6. Collect as much of the spilled material as possible using non-sparking tools.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 Autoignition temperature Flash Point Flammable Limits(LEL) Flammable Limits(UEL) OSHA Flammability Classification: No Data Available 55 ºF [Test Method: Tagliabue Closed Cup] 1. and personal protective equipment. Keep out of the reach of children. In the event of a release of this material. and electrical spark sources. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. Cover spill area with a fire-extinguishing foam designed for use on solvents. carbon dioxide). Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).AFFF type foam is recommended. Working from around the edges of the spill inward. respiratory protection. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. ventilation. corrosivity or flammability hazard. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. or spray. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist. If ventilation is not adequate. Keep container in well-ventilated area. Wear low static or properly grounded shoes. _________________________________________________________________________________________________ Page 5 of 10 . Do not spray near flames or sources of ignition. grinding or machining. Ground containers securely when transferring contents. 8. drink or smoke when using this product. Avoid breathing of vapors created during cure cycle.1 ENGINEERING CONTROLS Provide appropriate local exhaust ventilation on open containers. 8. Avoid static discharge. Keep away from heat. Store away from acids.2 STORAGE Store away from areas where product may come into contact with food or pharmaceuticals. Avoid contact with oxidizing agents. mists. Provide ventilated enclosure for heat curing. or spray. Avoid breathing of dust created by cutting. or spray. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Do not use in a confined area or areas with little or no air movement.2.2 Skin Protection Avoid skin contact. use respiratory protection equipment. If a respirator is needed. Wash exposed areas thoroughly with soap and water. Keep container tightly closed.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 contact with vapors. consult with your respirator manufacturer.2. sanding.4 Prevention of Swallowing Do not eat. laminate Apron . open flame. Avoid breathing of dust created by cutting.2. grinding or machining. drink or smoke when using this product. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.3 Respiratory Protection Do not breathe vapors. 8. 8.polymer laminate . sparks. sanding. Store out of direct sunlight. Store away from heat.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8. Provide local exhaust ventilation at transfer points.Disposable. select from the following respirator type(s) to reduce inhalation exposure: Full facepiece supplied-air respirator Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application. Based on the results of the exposure assessment. use respirators as part of a full respiratory protection program. grinding. Gloves made from the following material(s) are recommended: Butyl Rubber Fluoroelastomer Polymer laminate . Store away from oxidizing agents. sanding or machining. vapor. The following eye protection(s) are recommended: Indirect Vented Goggles . Provide appropriate local exhaust for cutting. Wash exposed areas thoroughly with soap and water.Neoprene Coveralls .2. Avoid breathing of vapors created during cure cycle. 7. pilot lights and other sources of ignition. An exposure assessment may be needed to decide if a respirator is required.1 Eye/Face Protection Avoid eye contact with vapors. mists. The following protective clothing material(s) are recommended: Boots . Do not eat.

more particularly.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 8.75 ppm 2 ppm 200 ppm 250 ppm 260 mg/m3 20 ppm 75 ppm 410 mg/m3 5 ppm 19 mg/m3 Additional Information Skin Notation* Sensitizer 29 CFR 1910. Color. Vehicles can alter skin absorption.1 [Ref Std: WATER=1] No Data Available Not Applicable Negligible > 1 [Ref Std: BUOAC=1] 614 g/l _________________________________________________________________________________________________ Page 6 of 10 . Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits(LEL) Flammable Limits(UEL) Boiling Point Density Vapor Density Vapor Pressure Specific Gravity pH Melting point Solubility in Water Evaporation rate Volatile Organic Compounds Red.336 F] 1. by direct contact with the substance.3 EXPOSURE GUIDELINES Ingredient 2-BUTOXYETHANOL 2-BUTOXYETHANOL BUTANOL BUTANOL ETHYL ACETATE ETHYL ACETATE ETHANOL ETHANOL FORMALDEHYDE FORMALDEHYDE FORMALDEHYDE FORMALDEHYDE METHANOL METHANOL METHANOL METHYL ISOBUTYL KETONE METHYL ISOBUTYL KETONE METHYL ISOBUTYL KETONE PHENOL PHENOL Authority ACGIH OSHA ACGIH OSHA ACGIH OSHA ACGIH OSHA ACGIH CMRG OSHA OSHA ACGIH ACGIH OSHA ACGIH ACGIH OSHA ACGIH OSHA Type TWA TWA TWA TWA TWA TWA STEL TWA CEIL TWA TWA STEL TWA STEL TWA TWA STEL TWA TWA TWA Limit 20 ppm 240 mg/m3 20 ppm 300 mg/m3 400 ppm 1400 mg/m3 1000 ppm 1900 mg/m3 0.5 ppm 0.1 g/ml > 1 [Ref Std: AIR=1] 63. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor.3 ppm 0.1048 29 CFR 1910.5 % volume 148 ºF [Details: Boiling Range 148 F . either by airborne or.1048 Skin Notation* Skin Notation* Skin Notation* Skin Notation* * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye.0 % volume 36.11 mmHg [Test Method: Calculated] [Details: @25C] 1. Solvent Odor Liquid No Data Available 55 ºF [Test Method: Tagliabue Closed Cup] 1.

Oct/Water partition coef Percent volatile Percent volatile Viscosity 5.12 lb/gal No Data Available 56 % weight 74 % volume 38 . Materials and Conditions to Avoid: 10. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition Not Specified Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 Volatile Organic Compounds Kow . dispose of waste product in a permitted hazardous waste facility. As a disposal alternative.40 centipoise [Test Method: Estimated] SECTION 10: STABILITY AND REACTIVITY Stability: Stable.2 Materials to avoid Strong oxidizing agents Reducing agents Hazardous Polymerization: Hazardous polymerization will not occur. Combustion products will include HCl.1 Conditions to avoid Sparks and/or flames 10. _________________________________________________________________________________________________ Page 7 of 10 . Facility must be capable of handling halogenated materials. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Test Organism . Test Type Result NA CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator.

_________________________________________________________________________________________________ Page 8 of 10 .No Immediate Hazard .7 3.2 < 0. All components of this product are listed on the Inventory of Existing Chemical Substances in China or are exempt. consult applicable regulations or authorities before disposal. This MSDS has been prepared to meet the U.S.3 1. 50-00-0 67-56-1 108-10-1 Classification **Carcinogen *Developmental Toxin **Carcinogen * WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.1200. 80-6300-0109-9 For Transport Information. please visit http://3M. CALIFORNIA PROPOSITION 65 Ingredient FORMALDEHYDE METHANOL METHYL ISOBUTYL KETONE C.No Reactivity Hazard .Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient BUTANOL 2-BUTOXYETHANOL (GLYCOL ETHERS) METHANOL PHENOL FORMALDEHYDE C.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.S.Yes Pressure Hazard . Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. OSHA Hazard Communication Standard. SECTION 14:TRANSPORT INFORMATION ID Number(s): 80-6109-1539-1.A.7 1.A. No 71-36-3 111-76-2 67-56-1 108-95-2 50-00-0 % by Wt 3. 311/312 Hazard Categories: Fire Hazard .Yes Delayed Hazard .MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary.25 STATE REGULATIONS Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. 29 CFR 1910. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. ** WARNING: contains a chemical which can cause cancer.S. No.

We encourage you to reread the MSDS and review the information. Section 3: Potential effects from ingestion information was modified. 3M MAKES NO WARRANTIES. Section 15: California proposition 65 ingredient information was modified. acute exposure to a material under conditions of fire.decontamination . Section 8: Respiratory protection . BUT NOT LIMITED TO.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term. Section 2: Ingredient table was modified. HMIS Hazard Classification Health: 2 Flammability: 3 Reactivity: 0 Protection: X . HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). EXPRESSED OR IMPLIED. HMIS® ratings are to be used with a fully implemented HMIS® program. ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.was modified. Section 8: Engineering controls information was modified. Revision Changes: Section 4: First aid for eye contact . Section 3: Immediate other hazard(s) was modified.protective clothing information was modified.was modified. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Section 7: Handling information was modified. Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. Section 3: Carcinogenicity phrase was modified. Section 6: Methods for cleaning up information was modified. Section 8: Skin protection .recommended respirators guide was modified. Section 8: Respiratory protection . Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format.recommended respirators punctuation was deleted.medical assistance . Section 15: California proposition 65 reproductive harm warning was added. Section 3: Potential effects from eye contact was modified. or similar emergencies. Section 3: Immediate eye hazard(s) was added. Section 8: Exposure guidelines ingredient information was modified. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. spill. Section 3: Other health effects information was modified.See PPE section. Section 8: Respiratory protection .recommended respirators information was modified. Section 6: Environmental procedures information was modified. INCLUDING. The potential hazards of the product have not changed. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of _________________________________________________________________________________________________ Page 9 of 10 .recommended respirators was modified. Section 4: Note to physicians heading was added. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. Section 4: Note to physicians was added. Section 8: Respiratory protection . Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Carcinogenicity table was modified. Section 4: First aid for eye contact . Section 12: Ecotoxicological phrase was deleted. Section 8: Respiratory protection information was modified.

Due to the remote possibility that electronic transfer may have resulted in errors. Given the variety of factors that can affect the use and application of a 3M product. it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers.com _________________________________________________________________________________________________ Page 10 of 10 . 3M makes no representations as to its completeness or accuracy. In addition.MATERIAL SAFETY DATA SHEET SCOTCHKOTE 345 Liquid Phenolic Primer 10/31/12 use or application. omissions or alterations in this information. information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M. some of which are uniquely within the user's knowledge and control.

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