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Test paper

Chapters included General principle and Processes of Isolation of Elements. Solution Electrochemistry Chemical kinetics Surface Chemistry Solid State

hpXIIC7

Full marks -70, Time 3 h

Q.1.A compound forms hexagonal close packed structure .What is the total number of voids in one mole of it? How many of these are tetrahedral voids. (1) Q.2.Give the difference between ferromagnetism and antiferromagnetism. (1) Q.3.Define F-center. Q.4.Can 1m FeSO4 solution be stored in a zinc vessel? Explain. (1) (1)

Q.5.How many coulombs are required to deposit 40.5 g of Aluminum from molten Al2O3. (1) Q.6.For a reaction N2O5 (g) 2NO2(g) +1/2O2(g).The rate of -3 disappearance of N2O5 is 6.25 x10 mol L-1 s-1.Calculate the rate of reaction. (1) Q.7.Why is chemisorptions referred as activated adsorption. (1)

Q.8.A reddish brown colloidal sol is formed when a small amount of FeCl3 is added to freshly prepared Fe(OH)3 ppt.Explain. (1) Q.9.With the help of neat diagram explain froth floatation process.
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Q.10.Complete the following sequence of reactions and identify A,B,C,D.

(2) Q.11.Analysis shows that Nickel oxide has the formula Ni0.98O.What fraction of nickel exists as Ni2+ and Ni3+ ions. (2) Q.12.Conc HNO3 is used in laboratory is 69% by mass. Density of HNO3 is HNO3 is 1.41g cm-3.Find molarity and molality of the acid. (2) Q.13.Two liquids X and Y on mixing form an ideal solution. Vapour pressure of the solution containing 3:1 mole ratio of X and Y is 550 mm Hg.When the molar ratio is 4:1 the vapour pressure is 550 mm of Hg Determine the vapour pressure of pure X and pure Y. (2) Q.14. Pt(s) |H2(g)1 bar) | H+(aq)(5x10-4M) II H+(aq)(M1)|H2(g) I Pt 1 bar.The observed emf of the cell at 298 K is 0.15V.Calculate the value of M1. (2) Q.15.Calculate the equilibrium constant for the reaction Zn +Cd 2+(1M) =Zn 2+ (1M)+Cd. E0 Zn2+/Zn= -0.76V. E0 Cd2+/Cd = -0.40V. Q.16.Draw the following graphs for a zero order reaction. (i)Variation of concentration. with time. (ii)Variation of rate with concentration. Q.17.Give any 4 characteristics of enzyme catalysed reactions. (2) (2) (2)

Q.18.The adsorption of acetic acid vapour by 1g charcoal ,the following data was obtained. X cm3 P(atm) 0.726 0.570 0.478 0.210 (2)

Determine Freundlich constants K and 1/n. Q.19.Explain the following terms. (i)Electrophoresis. (ii)Electro Kinetic potential. (iii)Tyndall effect.

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Q.20.In a reaction between A and B the initial rate of reaction was measured at different initial concentration of A and B . Rate :MolL-1s-1 1 0.2 0.3 5.07x10-5 2 0.2 0.05 5.04x10-5 3 0.4 0.05 7.56x10-5 Calculate the order and rate constant for the reaction. What is the rate of above reaction when [A]=[B]=0.05. (3) Q.21.From the following data show that the decomposition of H2O2 is a first order reaction .Calculate the rate constant and t1/2 for the reaction. (3) Time on mins. Volume in KMnO4(cm3) 0 22.8 10 13.8 20 8.3 30 5.0 [A] [B]

Q.22.The rate constant of a reaction at 500 K and 600 K are 2x10-2 s-1 and 5x10-2 s-1 respectively. Calculate +the values of Ea and A . (3)

Q.23.Silver is deposited on a metallic vessel of surface area 900 cm2. by


passing 0.2 amp of current for 2 hrs. Calculate the thickness of silver deposited given that density of Ag is 10.5 g cm-3 and its atomic mass =108 amu. (3) Q.24.With the help of a neat graph explain the type of deviation exhibited by mixing acetone and chloroform. What type of azeotrope is formed. (3)

Q.25.Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 is 2 liters of water at 2500C assuming it to be 80% dissociated. (3) Q.26.The metal of calcium crystalises of fcc pattern.The radius of Ca is 196 pm.Calculate the density of the metal if it contains 0.1% Schottky defect.(3) Q.27.Distinguish between the following pairs. a. Face centered and end centered unit cells. b. Cubic close packing and hexagonal close packing c. Octahedral voids and tetrahedral voids.

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Q.28.With the help of neat diagram and redox reactions at the electrodes a. Explain the working of hydrogen oxygen fuel cell. b. Mention two advantages of fuel cell. c. Calculate the maximum efficiency of the above fuel cell

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Q.29.Briefly discuss collision theory to explain rate of reactions. Mention also a. The draw backs of above theory. b. Draw a graph between kinetic energy and progress of an endothermic reaction A +B P+Q a. Indicate Activation energy b. Threshold energy and c. Enthalpy of reaction. (5)

Q.30.Draw the blast furnace and explain the step involved in the extraction of iron Hematite ore. Give all relevant equations. (5)