LDEQ-EDMS Document 40169977, Page 17 of 435

"Optional·· Fee Explanation: Use the space provided to give an explanation of the fee determination displayed above.
In accordance with LAC 33:1II.211.B.l3.c the minimum minor modification fee is assessed, since there is no increase in
the capacity at the facility. Per LAC 33:1Il.211.A, the 25% NSPS surcharge is applied as the new BenFree Reboiler is
subject to NSPS Ja and the fugitives associated with the new BenFree Unit are subject to NSPS GGGa and NSPS VVa.
Additionally. the 10% Air Tories surcbarge is applied since some emission rates will increase by an amount greater than
the Minimum Emission Rate listed in Chapter 51.

Electronic Fund Transfer (EFT): If paying the permit application fee using an Electronic Fund Transfer (EFT), please
include the EFT Transaction Number, the Date that the EFT was made. and the total dollar amount submitted in the EFT.
If not paying the permit application fee using EFT, leave blank.
EFT Transaction Number Date of Submittal· Total Dollar Amount
N/A __ N_!A~ _ $ N/A

6. Key Dates
Estimated date construction will commence: 08/2009 Estimated date operation will commence: 112010

7. Pending Permit Applications - For Process Unit-Specific Permits Only

[LAC 33:III.517.D.18)
List all other process units at this facility for which Part 70 permit applications have been submitted, but have not been
acted upon by LDEQ as of the date of submittal of this application. If none, state Hnone" in the table. **It is not necessary
to update this table durine the permit relliew Mocess, unless requested by WE 'J. **
Process Unit Name Permit Number Date Submitted

'. 8. LAC 33:1.1701 Requirements - Answer all below for n~w sources and permit renewals -
DYes [8INo I
Does the company or owner have ftderal or state environmental permits identical to, or of a similar nature to. the permit
, for which you are applying in Louisiana or other states? (This requirement applies to aU individuals, partnerships,
corporations, or other entities who own a controlling interest of 50% or more in your company, or who participate in the
environmental management of the facility for an entity applying for the permit or an ownership interest in the permit.)
DYes t81No

If yes, list States: Nt A

Do you owe any outstandingfees or final penalties to the Department? Dyes 0 No

If yes. explain below. Add rows if necessary.

is your company a corporation or limited liability company? DYes 0 No

If yes, attach a copy of your company's Certificate of Registration and/or Certificate of Good Standing from the
Secretary of State. The appropriate certificate(s) should be attached to the end of this application as an appendix.

Note: *Please refer to Appendix F for the Certificate of Good Standing .

• form _7195 _rOO

06/06/07
LDEQ-EDMS Document 40169977, Page 21 of 435

12. Proposed Project Emissions [LAC 33:111.517.0.3)

List the total emissions following the proposed project for this facility or process unit (for process unit-specific
permits). Speciate all criteria pollutants, TAP, and HAP for the proposed project
Pollutant 45.64
1.63
0.15
8.37
2035.51
9.23
Proposed Emission 6.22
0.038
8.50
729.34
638.64 10.042
0.03
0.50
1230.77
2.95 0.124
211.001
08.40
8.J1
Rate 0.87
(tonslyear)

'.

•
 LDEQ-EDMS Document 40169977, Page 26 of 435

i.
,
19. Air Quality Dispersion Modeling (LAC 33:III.517.D.15)
Was Air Quality Dispersion Modeling as required by LAC 33:/U performed in support of this permit application?
Dispersion Modeling is only required when applyingfor PSD permits and as requested by LDEQ.)
DYes l8lNo
•
(Air Quality

Has Air Quality Dispersion Modeling completed in accordance with LAC JJ:III ever been performed for this facility in
support of a air permit application previously submitted for this facility or process unit (for process unit-specific permits) or
as required by other regulations AND approved by LDEQ?
18lYes 0 No

If yes, enter the date the most recent Air Quality Dispersion Modeling results as required by ~AC 33:11I were submitted:
May 31,2007

If the answer to either question above is "yes," enter a summary of the most recent results in the following table. If the answer
to both questions is "no," enter "none" in the table. Add rows to table as necessary.
Ambient
Louisiana
(National Air Toxic
AmbientStandard
AirQuality
Air or
Pollutant
0.5 Adv
Time 8-hr061.90
0.442
Annual
Best
8-hr
Annual
8-hr
8-hr
8-hr .2
199.7
Annual
Period
Ground
Annual
24-hr Mv
Available
0.92
0.35
330 .
0.03
0.004
7.69
640
136.00
0.06
9.6
759.3
485.6
1211.6
50.5
12
1,190
4,190
10,300
8,900 LevelRetrofit
Technology Threshold
(BART)
Standard
Hydrocarbons Exemption
fNAAQS}) Calculated Maximum
ration Toluene
Hydrogen
Xylene

••

Note: The toxies modeling results listed above were submitted in March 2002 and are the only
facility-wide modeling submitted sinee the issuance of Title V Permit No. 2500-0000] -VO.

fOffi"L7195_rOO
06/06/07
 Section 5111
Title 33, Part III

HISTORICAL NOTE: Promulgated by the Department of amended by the Office of the Secretary, Legal Affairs Division, LR
Environmental Quality, Office of Air Quality and Radiation 31:2447 (October 2005), LR 33:2093 (October 2007), LR 33:2623
Protection, Air Quality Division, LR 17:1204 (December 1991), (December 2007).
amended LR 18:1363 (December 1992), LR 19:891 (July 1993),
§5112. Tables-51.1, 51.2, and 51.3
repromulgated LR 19:1314 (October 1993), amended LR 23:59
(January 1997), amended by the Office of the Secretary, LR 25:661
(April 1999), amended by the Office of Enviromnental Assessment,
Enviromnental Planning Division, LR 26:2461 (November 2000),

Glucinum
Methyl
Benzol, ethylene
MethyleneCoal
2-Chloropropylene
Ethylene oxide
naphtha
bromide,
oxide
Dichloroethyl
Chloroethene, ether RateCAS
Ethylene
oxide
Monochloride Number
Synonyms
dibromide
(pounds/year)
ethylene 106-93-4
106-89-8
50-00-0
75-01-4
TableSl.l 35.0
7440-38-2
107-13-1
71-43-2
25.0
75-56-9
75-21-8
240.0
700.0
260.0
111-44-4
7440-02-0
1332-21-4
7440-47-3
7440-43-9
7440-41-7
3,400.0
2,180.0 25.0
25.0
35.0
Minimum Emission
ClassRates1Toxic and
Known Air Probable
Pollutants Hnman Carcin~ens Minimum Emission

DBP
Benzene
Carbon
Acetic chloride
Tetrachloromethane
bisulfide
aldehyde
Trichloromethane
p-Dichlorobenzene
Methyl
Propylene
2,4-DNT
Acrylic
Ethylene
Methylene chloride
3-chloropropene
1,I-biphenyl,
Cyanomethane,
Acrylic
EthylChlorine dichloride
amide
Biethylene Xenene
dichloride,
chloride,
aldehyde
chloride
Aminobenzene, peroxide
1,3-dichloropropene, EDC
DCM
Methyl Synonyms
(Pounds/year)
cyanide
Phenylamine
OCP 75-07-0
79-06-1
7440-36-0
92-52-4
126-99-8
107-02-8
75-05-8
10049-04-4
542-75-6
106-46-7
108-90-7
78-87-5
67-66-3
75-00-3
106-99-0
56-23-5
75-15-0
62-53-3
7440-39-3
CAS Number
25376-45-8
7440-50-8
107-06-2700.0
380.0
75-09-2
84-74-2
51207-31-9
3268-87-9540.0
74-87-3
107-05-1
606-20-2
121-14-297.5
83.5
48.5
69.5
600.0
25.0
100.0
340.0 0.0001
37.5
25.0
250.0
0.0001
1000
TableSl.l 2,700.0
5,000.0
2,400.0
7,750.0
20,000.0
20,000.0
Minimum
ll. SuspectedEmission
Emission
Human Rates Rate
Toxic Airand
Carcinoeens Pollutauts
Known or Suspected Human Reproductive Toxins Minimum

December 2008 Environmental Regulatory Code 272

 Title 33, Part III Section 5112

Nitrobenzol
Hexachlorobutadiene
Perchloroethane
Perchlorobenzene
PARs
Vinylbenzene
Vinyl
Camphor
Ethyl trichloride
I,Antisoll,
I-dichloroethylene
Phenyl
Benzeno1,
Diethylene
Acetylene tar
propenoate
Dimethylnitromethane
Carbon
Tetrachloride
ethane
ortho-xylene,Carbolicdichloride,
dioxide,
trichloride acid
p-dioxane
meta-xylene, Synonyms
Perchloroethylene
(Pounds/vear)
para-xylene 100-41-4
CAS Number
123-91-1
140-88-5
67-72-1
79-46-9
584-84-9
7439-97-6
7439-96-5
1330-20-7
302-01-2
109-86-4
127-18-4
118-74-1
79-00-5
75-35-4
91-08-7
900.0
870.0
700.0
98-95-3
108-95-2
79-34-5
91-20-3
79-01-6
87-68-3
206-44-0
7782-49-2
100-42-525.0
400.0
300.0
1,500.0
1,990.0
1,040.0 25.0
25.0
75.0
25.0
TableS!.! 1,200.0
20,000.0
1,500.0
1,400.0
2,700.0
2,800.0
2,000.0
4,000.0
Minimum
II. SuspectedEmission
Human Rates
Emission Toxic Airand
Rate
CarcinOl!:ens Pollutants
Known or Suspected Human Reproductive Toxins Minimum

MIBK
n-butanol
MEK
Chloroethene
Cyclon
Azine
Carbonyl
Methyl
Hydrogen
Isopropyl
Acroleic chloride
alcohol
Methylbenzene
Carbon chloride
oxvsulfide
cis-Butenedioic
Fluoric acid,
benzene
acid, anhydride
Hydrogen
Propene CAS
Emissiou
Number
acidfluoride Rate
Synonyms 7664-39-3
7697-37-2
80-62-6
108-31-6
67-56-1
7647-01-0
110-54-3
74-90-8
7782-50-5500.0
71-36-3
110-86-1
108-10-1
123-38-6
75-44-5
85-44-9
78-93-3
7440-66-6
108-05-4
7783-06-4
98-82-8
7664-41-7
79-10-7
463-58-1
71-55-6
7664-93-9
108-88-3
107-21-1
1319-77-3 63.0
30.0
800.0
400.0
70.0
18,000.0
11,000.0
1,000.0
15,000.0
20,000.0
1,200.0 400.0
300.0
1000
700.0
200.0
75.0
13,000.0
9,000.0
1,600.0
1,200.0
20,000.0
TableS!.! 1,000.0
2,600.0
Minimum Emission Rates Toxic
andAir
Class (pounds/year)
IIL Acute Pollutants
Chronic (Non-earcinOl!enie1 Toxins Minimum

Explanatory Notes:

273 Environmental Regulatory Code December 2008