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Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
A. General :
1. This booklet is your Questions Paper. Do not break the seals of this booklet before being instructed
to do so by the invigilators.
2. Blank spaces and blank pages are provided in this booklet for your rough work. No additional
sheets will be provided for rough work.
3. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers,
and electronic gadgets are NOT allowed inside the examination hall.
4. The answer sheet, a machine-readable Optical Response Sheet (ORS), is provided separately.
5. DO NOT TAMPER WITH/MUTILATE THE ORS OR THE BOOKLET.
6. On breaking the seals of the booklet check that it contains 28 pages and all the 20 questions
in each subject and corresponding answer choices are legible. Read carefully the instructions
printed at the beginning of each section.
B. Filling the ORS :
7. A candidate has to write his / her answers in the ORS sheet by darkening the appropriate bubble
with the help of Black ball point pen as the correct answer(s) of the question attempted.
8. Write your Name, FNO and sign with pen in the boxes provied on part of the ORS. Do not write
any of this information anywhere else.
C. Question Paper Format :
9. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists of
two sections.
10. SECTION I
(i) In this part of section I contains 6 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE is correct.
(ii) In this part of section I contains 4 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONE or MORE are correct
(iii) In this part of section I contains 1 paragraph each describing theory, experiment, data etc.
There are 3 multiple choice questions relating to one paragraphs with 3 questions on
paragraph. Each question of a particular paragraph has four choices (A), (B), (C) and (D) out
of which is ONLY ONE is correct
11. SECTION IV contains 7 questions. The answer to each question is a single digit integer,
ranging from 0 to 9.
D. Marking scheme :
12. For each question in Section I (i & iii), you will be awarded 3 marks if you darken the bubble
corresponding to the correct answer ONLY and zero marks if no bubbles are darkened. In all
other cases, minus one (1) mark will be awarded in this section.
13. For each question in Section I (ii), you will be awarded 4 marks if you darken the bubble
corresponding to the correct answer ONLY. In all other cases, zero(0) marks will be awarded.
No negative marks will be awarded for incorrect answers in this section.
14. For each question in Section IV, you will be awarded 4 marks if you darken ALL the bubble(s)
corresponding to the correct answer(s) ONLY. In all other cases zero (0) marks will be awarded.
No negative marks will be awarded for incorrect answers in this section.
15. Take g = 10 m/s
2
unless otherwise stated.
INSTRUCTIONS
PAPER 1 Time : 3 Hours Maximum Marks : 213
Write your Name, Form No. & Sign in the space provided on the back page of this booklet.
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Note: In case of any correction in the test paper, please mail to dlpcorrections@allen.ac.in within 2 days
along with Your Form No. & Complete Test Details.
DATE : 13 - 04 - 2013
SCORE : TEST # 01
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USEFULDATA
AtomicNo. H=1,B=5,C=6,N=7,O=8,F=9,Al=13,P=15,S=16,Cl=17,
Br=35,Xe=54,Ce=58,
Atomicmasses: H=1,Li=7,B=11,C=12,N=14,O=16,F=19,Na=23,Mg=24,
Al=27,P=31,S=32,Cl=35.5,Ca=40,Fe=56,Br=80,I=127,
Xe=131,Ba=137,Ce=140,
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PART-1 : PHYSICS
SECTIONI
(i) Single Correct Answer Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
1. An optical fibre of refractive index n is surrounded by air.A light ray enters the end of the fibre as shown
in figure. The largest value of | permitted, if the ray in the fibre is incident on the wall at critical angle for
the fibre-air interface is given by
Air
|
|/2
(A)
( )
1/ 2
2
sin n 1
2
| | |
=
|
\ .
(B) ( )
1/ 2
2
cos n 1
2
| | |
=
|
\ .
(C)
1/ 2
2
1
sin 1
2 n
| | | | |
=
| |
\ . \ .
(D)
1/ 2
2
1
cos 1
2 n
| | | | |
=
| |
\ . \ .
2. Two identical isosceles thin prisms of prism angle A and refractive index are placed with their bases
touching each other. This system acts as a converging lens. What is the focal length of this system for
parallel rays at a distance h from the base of the prism ?
A
h
h
(A)
( )
2h
1 A
(B)
( )
h
1 A
(C)
( )
h
2 1 A
(D) None of these
BEWARE OF NEGATIVE MARKING
HAVE CONTROL HAVE PATIENCE HAVE CONFIDENCE 100% SUCCESS
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3. The flow of charge through switch S when it is closed is :-
+
2F
+
6F
q
+
3F
q
q
(A) Zero (B) q/4 (C) 2q/3 (D) q/3
4. Consider the arrangement of three plates X, Y and Z each of the area A and separation d. The energy stored
when the plates are fully charged is :-
X
Y
Z
d
d
V
(A)
2
0
AV
2d
c
(B)
2
0
AV
d
c
(C)
2
0
2 AV
d
c
(D)
2
0
3 AV
2d
c
5. A ray of light makes normal incidence on the diagonal face of a right-angled prism as shown in figure such
that the ray strikes the surface AB of the prism after entering the prism. If u = 37 then the angle of de-
viation is (sin 37 = 3/5) :-
90
AIR
AIR
90
= 5/3
u
A
B C
(A) 53 (B) 127 (C) 106 (D) 90
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6. q number of identical equilateral prisms are kept in contact as shown in figure. If deviation through a single
prism is o then consider the following statements (m is an integer) :-
1
2
3
4
5 q
(i) if (q = 2m) deviation through q prisms is zero
(ii) if (q = 2m + 1) deviation through system of q prisms is o
(iii) if q = 2m deviation through system of q prisms is o
(iv) if q = 2m + 1 deviation through system of q prisms is zero
(A) Statements (i) & (iii) are true (B) Statements (i) and (ii) are true
(C) Statements (i) and (iv) are true (D) Statements (iii) and (iv) are true
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(ii) Multiple Correct Answer(s) Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct.
7. In the figure shown the radius of curvature of the left & right surface of the concave lens are
10 cm & 15 cm respectively. The radius of curvature of the mirror is 15 cm
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\
\ Glass
(n=3/2)
water
(n=4/3)
air
(A) modulus of equivalent focal length of the combination is 18 cm
(B) modulus of equivalent focal length of the combination is 36 cm
(C) the system behaves like a concave mirror
(D) the system behaves like a convex mirror
8. An equilateral prism ABC is placed in air with its base side BC lying horizontally along X-axis as
shown in the figure. A ray given by
3
z + x = 10 is incident at a point P on face AB of prism :-
60
P
A
C
B
(0,0,0,)
x
y
z
(A) For =
2
3
the ray grazes the face AC.
(B) For =
3
2
finally refracted ray is parallel to z-axis.
(C) For =
2
3
the ray emerges perpendicular to the face AC.
(D) For =
3
2
finally refracted ray is parallel to x-axis.
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9. An electrical circuit is shown in the given figure. The resistance of each voltmeter is infinite and each
ammeter is 100O. The charge on the capacitor of 100 F in steady state is 4 mC. Choose correct
statements (s) regarding above circuit :-
V
2
200O
[ideal
cell]
A
1
A
2
V
1 C
900O
100O
(A) Reading of voltmeter V
2
is 16 V
(B) Reading of Ammeter A
1
is 0A and A
2
is 1/25 A.
(C) Reading of voltmeter V
1
is 40V
(D) EMF of the ideal cell is 66 V.
10. Inside a parallel plate capacitor of capacitance C (without dielectrics) dielectrics are filled which have
dielectric constant k
1
and k
2
such that k
1
> k
2
. The capacitor is now connected to a battery of voltage V
then :-
K
1
K
2
A/2 A/2
(A) New capacitance of the capacitor will be
1 2
k k
C
2
+ | |
|
\ .
(B) Field in dielectric 1 will be more than the field in dielectric 2
(C) Surface charge density on the capacitor plates will be uniform
(D) Field in both the dielectric regions will be the same.
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(iii) Paragraph Type
This section contains 3 multiple choice questions relating to one paragraph with three questions
on paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
Paragraph for Questions 11 to 13
A ray of light travelling in air is incident at an angle of incidence i ~ 90 on a long rectangular slab of a
transparent medium of thickness y
0
. The medium has a variable refractive index of (x) =
+
2x / a
1 e
> x 0 , where 'a' is a positive constant.
y
y
0
i = 90
Air
Medium
( = 1)
Air ( = 1)
x
11. In the above situation if y
0
= a/2, the coordinates of the point where the ray intersects the upper surface
of the slab-air boundary are :-
(A)
(
(

2
a
ae ,
2
(B)
(
(

a
a n2,
2
(C)
(
(

a a
n2,
2 2
(D)
(
(

a
2a,
2
12. In the previous question, the angle made by light ray with +ve x-axis at the upper surface of slab air
boundary, inside the medium is :-
(A) t/4 (B) t/3 (C) tan
1
(2) (D) tan
1
| |
|
\ .
1
2
13. If y
0
= a, the light ray will :-
(A) Emerge out from the upper surface of slab-air boundary
(B) Emerge out from the lower surface of slab-air boundary
(C) Never emerge out of the slab
(D) Move in a close loop inside the slab
SECTION II & SECTION III
Matrix Match Type Integer Answer Type
No question will be asked in section II and III
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SECTIONIV
Integer Answer Type
This section contains 7 questions. The answer to each question is a single digit Integer, ranging from
0 to 9.
1. Two identical conducting spheres of radius r separated far apart are joined through resistor R & a switch
S. Initially switch is open and one of the spheres is provided with a charge +Q
0
. If switch S is closed at
t = 0 then. If charge on sphere B at time
65rR
t
26k
=
is given by
n
Q a 1 e

(
=

(where a & n are constant),
find the value of n.
+
+
+
+
+
+
+
+
+
+
+
++
+
+
+
+
+
+
+
+
+
+
r
S
R
A B
2. An equi-convex lens of focal length 10 cm (at t = 0) and refractive index (
g
= 1.5) is placed in a liquid
whose refractive index varies with time as (t) = 1.0 +
1
10
t. If the lens was placed in the liquid at
t = 0 after what time (in sec) lens will act as concave lens of focal length 20 cm.
3. For the circuit shown in the figure. Find the emf (in V) of the unknown battery E. The ammeter repre-
sented by the symbol A can be considered perfect (i.e. no resistance) and it reads the current in the wire
to be
7
A
11
in the direction shown.
4V
6O 4O
12V
2O
E
A
7
11
A
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4. In the figure shown, O is a point object placed above the lens L of focal length 10 cm. The distance
between the object O and its image formed in the plane mirror is n 20 cm find n.
O
15cm
1m
Water n=4/3
Plane mirror
L
15cm
5. Four wire of equal length 2m are arranged as shown in the figure. Wires 2, 3 and 4 are of equal cross
sectional area and wire 1 is of half the cross section of these wires. The distance (in m) pointer at point
5 must be moved to get null point is given by o. Fill 12o in OMR sheet.
G
5
3
1
6
2 4
7
8
x
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6. Find out the net emf of the three batteries between A & B when the point P is the null point, measured
by the potentiometer arrangement shown in the figure.
r
1
c
a b
A
4V 6.5O
2V
6V
1O
1O
B
G
P
r
2
7. A thin bi-convex lens of refractive index 3/2 and radius of curvature 50 cm is placed on a reflecting convex
surface of radius of curvature 100 cm. A point object is placed on the principle axis of the system such
that its final image coincides with itself. Now few drops of a transparent liquid is placed between the mirror
and lens such that final image of the object is at infinity. The refractive index of the liquid used is given
by . Fi l l 6 i n OMR sheet.
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PART-2 : CHEMISTRY
SECTIONI
(i) Single Correct Answer Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
1. Which of the graph is correct representation for the elementary reaction of type A + 2B C
(A) c
o
n
c
.

time
A
B
C
(B) c
o
n
c
.

time
A
B
C
(C) c
o
n
c
.

time
A
B
C
(D) c
o
n
c
.

time
A
B
C
2. 50 ml of 0.1 M KI solution is completely oxidized by atmospheric oxygen according to the following
equation-
4H
+
+ 4I

+ O
2
2l
2
+ 2H
2
O
I
2
formed then quickly reacts with I

to form I
3

I
2
+ I

I
3

What will be the final concentration of I


3

in the solution -
(A) 0.025 (B) 0.033 (C) 0.01 M (D) 0.066 M
3. Degree of hardness for aqueous 10
4
M Ca(HCO
3
)
2
solution will be -
(A) 10 ppm (B) 20 ppm (C) 16.2 ppm (D) 8.1 ppm
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4. Find the element having highest 1
st
ionisation energy -
(A) Tl (B) Al (C) In (D) Ga
5. Choose the correct option regarding the

HNN bond angle in HN


3
molecule -
(A) less than 10928' (B) In between 10928' and 120
(C) Approximately 150 (D) Just greater than 120
6.
HBr(1eq)
HBr(1eq)
80C
80C
(A)
(B)
(A) Both A and B are
Br
(B) A is
Br
& B is
Br
(C) A is
Br
& B is
Br
(D) A is
Br
& B is
Br
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(ii) Multiple Correct Answer(s) Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct.
7. Based on the following graph mark the correct option for the reaction : A P
(A) III order reaction
(B) Rate constant is 0.5 (mol/L)
1n
sec
1
time (min)
1
[A]
2
45
(C) [A]
0
= 0.5 M
(D) Reaction complete in finite time
8. In which of the following compound 2 2
x y
d

orbital is not involved for the hybridisation of their central
atom -
(A) I
3
+
(B) [BrF
4
]

(C) I
3

(D) [AsF
4
]

9. Which of the following properties are showing the correct order in the given option -
(A) SiH
4
< GeH
4
< PbH
4
: Boiling point order
(B) Li
2
CO
3
< K
2
CO
3
< Cs
2
CO
3
: Solubility order in water
(C) He > Ar > Xe : Solubility order in water
(D) SiCl
4
35
< SiCl
4
37
: Boiling point order
10. Find out incorrect stability order in the following carbocations-
(I)

(II)

(III)

(IV)

OH
(A) IV > I > III > II (B) IV > III > I > II (C) I > IV > III > II (D) I > III > IV > II
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(iii) Paragraph Type
This section contains 3 multiple choice questions relating to one paragraphs with three questions
on paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
Paragraph for Questions 11 to 13
From the following data answer the question :
Reaction A + B P
[A] M [B] M
at 300 K at 400 K
2.5 10
4
3.0 10
5
5.0 10
4
2.0 10
3
5.0 10
4
6.0 10
5
4.0 10
3
1.0 10
3
6.0 10
5
1.6 10
2
Initial rate (M sec
1
)
11. The order with respect to A is -
(A) 1 (B) 2 (C) 3 (D) 0
12. The value of rate constant at 300 K is (M
2
sec
1
)
(A) 2.667 10
8
(B) 2.667 10
5
(C) 2.667 10
4
(D) 2.667 10
9
13. The energy of activation for reaction (kcal/mol) is (log 2 = 0.3)-
(A) 1.68 (B) 3.36 (C) 6.72 (D) 1.12
SECTION II & SECTION III
Matrix Match Type Integer Answer Type
No question will be asked in section II and III
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SECTIONIV
Integer Answer Type
This section contains 7 questions. The answer to each question is a single digit Integer, ranging from
0 to 9.
1. A gaseous mixture of N
2
& O
2
containing 60% by mole N
2
is allowed to react with each other according
to the following equaion.
N
2
+ O
2
NO
2
If 92 gm of NO
2
is formed, find the mole of N
2
present in the mixture.
2. Find the number of d-block elements from the following
La, Th, Ac, Pd, Pb, Pm , Pt
3. Find the number of S-S linkage in hexathionate ion.
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4.
14
14
Na
Na

D O
2
Product(s)
+
1
2
H
2

How many organic product(s) are obtained.


5.
OH
major product
conc.H SO
2 4

Number of 1, 2 shifts involved in above reaction.


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6. HO CCH CHCNHCHCOMe
2 2
NH
2
O CH
2
Number of functional group = x excluding (C = C)
Number of amino acids formed on hydrolysis = y
Then find out the value of (x + y).
7. How many of the following compounds will show Tautomerism.
(a) Ph CH = NH (b) C
O
(c)
Me C C CMe
3 3
O
(d) C
O
CHMe
2
(e) Me
3
C N = O (f)
Ph
O
(g) Ph C Me
O
(h)
NO
2
(i)
Ph
O
(j) O
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PART-3 : MATHEMATICS
SECTIONI
(i) Single Correct Answer Type
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
1. If y = cos
1
(cos (|2x| (x)), where
2 x 0
(x) 0 x 0
2 x 0
>

= =

<

, then
5
8
dy
dx
t

is -
(A) 2 (B) 0 (C) 2 (D) Not defined
2. If ( )( ) (x) x 1 2 x = + , then the domain of ([x] x
2
+ 4), is
(where [.] denotes the greatest integer function) -
(A) 5, 1 3, 7
( (


(B) 3, 1 3, 7
( (


(C) 3, 1 3, 5
( (


(D) 5, 1 5, 7
( (


3. If (x) is differentiable and '(x) is continuous with '(2) = 14, then
x 0
(2 sin x) (2 x cos x)
lim
x sin x

+ +

is
equal to-
(A) 14 (B) 7 (C) 28 (D) 56
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(DATE : 13-04-2013)
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4.
4 4
dx
x 1
}
is equal to-
(A)
2 4
1
log x x 1 C
2
+
(B)
4 4 4
1
4
1 x x 1 1 x 1
n tan C
4 2 x
x x 1

| |

+ + |
|
+
\ .

(C)
2 4
1
log x x 1 C
2
+
(D)
4 4 4
1
4
1 x x 1 1 x 1
n tan C
4 2 x
x x 1

| |
+
+ |
|

\ .

5. Possible value of a
2
, for which equation
2 2 2
2
a sin x a 2
1 tan x cos 2x
+
=

has no solution, is (tan x = 1)


(A) 4 (B) 2 (C)
3
(D) 1
6. If x and y are independent variables and ( )
x
x y 2 x
0
(x) e '(y)dy x x 1 e

| |
= +
|
\ .
}
, where (x) is a
differentiable function, then (x) is-
(A) (x
2
+ x 1)e
x
(B) (2x + 1)e
x
(C) (2x 1)e
x
(D) (x
2
+ x 1)e
x
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(ii) Multiple Correct Answer(s) Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct.
7. If
2
1
(x)
x 1
=

, then identify the correct option(s) (where


n
(x) represent
n
d (x)
dx
)
(A)
2013
(x) is an odd function (B)
2014
(x) is an even function
(C)
n
(x) is always an odd function (D)
( ) ( ) ( )
( )
n n 1 n 1
n
n 1
2
1 n! x 1 x 1
(x)
2
x 1
+ +
+
(
+
(
=
(


8. If x and y are independent variables and ( )
1
2 2
0
(x) 1 x y x (y)dy = + +
}
be a continuous and differentiable
function, then identify the correct option(s)-
(A) ( )
164
' 0
57
=
(B) ( )
25
' 0
19
=
(C)
1
0
164
(x)dx
57
=
} (D)
1
0
25
(x)dx
19
=
}
MATHEMATICS
TARGET : JEE 2013
(DATE : 13-04-2013)
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9. Let
( )
/ 3
sin x
/ 3
I cos x dx
t
t
=
}
, then I is greater than -
(A)
2
t
(B)
2
3
t
(C)
4
3
t
(D) 2t
10. Let
: , a ( , b]
2
t | (

(
\
be an invertible function with longest domain defined as
(x) = tanx + cotx2 then -
(A) Ordered pair (a,b) is
( )
4 2 3
,
3 3
| |
+
t
|

|
\ .
(B) Ordered pair (a,b) is
, 4
4
t | |

|
\ .
(C)
2
1 1
x 2 x 4x
(x) tan
2

| |
+ + +
= |
|
\ .
(D)
2
1 1
x 2 x 4x
(x) tan
2

| |
+ +
= |
|
\ .
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(iii) Paragraph Type
This section contains 3 multiple choice questions relating to one paragraph with three questions
on paragraph. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is
correct.
Paragraph for Questions 11 to 13
Let
{ }
n 2
2n
n
| x 1| x
lim 6 x 0
| x | x (x)
sin x 0 x 6

+ +
s <

+ =

s <

, where {.} denotes fractional part function.


On the basis of above information, answer the following questions :
11. Number of points at which (x) is not differentiable in [6,6] -
(A) 6 (B) 5 (C) 4 (D) 3
12. Number of solutions of the equation
x
(x)
6
=
in [6,6]
(A) 2 (B) 3 (C) 4 (D) 5
13. Value of
/ 2
/ 2
(x)dx
t
t
}
is-
(A)
7
2
(B)
5
2
(C)
3
2
(D)
1
2
SECTION II & SECTION III
Matrix Match Type Integer Answer Type
No question will be asked in section II and III
MATHEMATICS
TARGET : JEE 2013
(DATE : 13-04-2013)
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SECTIONIV
Integer Answer Type
This section contains 7 questions. The answer to each question is a single digit Integer, ranging from
0 to 9.
1. If the period of
( ) ( ) ( ) ( ) ( )
x x x x x x
(x) sin cos tan cot sec cosec
n 2 ! n 1 ! n! n 1 ! n 2 ! n 3 !
| | | | | | | |
t t t t t t | |
= + + + + +
| | | |
|
| | | |
+ + +
\ .
\ . \ . \ . \ .
is
10080, then the value of n is
2. If 'o' is a solution of
1 1
1
tan x cot
x 4

t
+ =
, then
1 (
(
o

is equal to (where [.] denotes greatest integer
function)
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3. If x sinu y cosu = 0 & x sin
3
u + y cos
3
u = sinu. cosu (x,y = 0), then the value of (x
2
+ y
2
) is
equal to
4. If
1
1 4
tan tan
3 3

| |
o =
|
\ .
&
1
1 4 2
sin sin
2 9

| |
| =
|
|
\ .
, then the value of
3 2
1
4 3 o o o +|
is
MATHEMATICS
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(DATE : 13-04-2013)
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5. If ( ) ( )
xy 2 2 2
n e 1 e x x y + = + , then
( ) 1,0
dy
dx
| |
|
\ .
is equal to
6. Let (x) = min(tan
1
x, cot
1
x) & h(x) = (x + 2) t/3. Let x
1
,x
2
(where x
1
< x
2
) be the integers in the
range of h(x), then the value of (cos
1
(cosx
1
) + sin
1
(sin x
2
)) is equal to
7. Let : A
1
, 0
2
(

(

is such that
3
(x) 3x(x) + x
3
+ 1 = 0 and (x) is an invertible function, then
number of solution(s) of the equation (((x)))
2
=
3
2

1
(x) + 1 is
JEE 2013
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Name of the Candidate
I have read all the instructions and shall
abide by them.
Signature of the Candidate
Form Number
I have verified all the information filled
in by the Candidate.
Signature of the Invigilator
JEE 2013
LEADER & ENTHUSIAST COURSE
(DATE : 13-04-2013)
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Corporate Office : ALLEN CAREER INSTITUTE, SANKALP, CP-6, INDRA VIHAR, KOTA-324005
PHONE : +91 - 744 - 2436001, Fax : +91-744-2435003, E-mail: info@allen.ac.in Website: www.allen.ac.in
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