You are on page 1of 30

FIITJEE

Time: 3 Hours

Solutions to JEE(MAIN)-2013
Maximum Marks: 360

PAPER – 1 : CHEMISTRY, MATHEMATICS & PHYSICS

Test Booklet Code

Q
Important Instructions: 1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use of pencil is strictly prohibited. The test is of 3 hours duration. The Test Booklet consists of 90 questions. The maximum marks are 360. There are three parts in the question paper A, B, C consisting of Chemistry, Mathematics and Physics having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct response. Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each question. (1/4) (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. There is only one correct response for each question. Filling up more than one response in any question will be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6 above. 2. 3. 4.

5.

6.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.

JEE(MAIN)2013-CMP-2

PART - A: CHEMISTRY
1. An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism: (1) tertiary alcohol by SN1 (2) secondary alcohol by SN2 (3) tertiary alcohol by SN2 (4) secondary alcohol by SN1 The first ionization potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be: (1) – 5.1 eV (3) –10.2 eV (3) + 2.55 eV (4) – 2.55 eV
+ Stability of the species Li2, Li − 2 and Li 2 increases in the order of:
+ (1) Li − 2 < Li 2 < Li 2 + (3) Li − 2 < Li 2 < Li 2 − + < Li 2 (3) Li 2 < Li 2 + − (4) Li 2 < Li 2 < Li 2

2.

3.

4.

The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCl with 250 mL of 2(M)HCl will be: (1) 1.00 M (2) 1. 75 M (3) 0.975 M (4) 0.875 M Which of the following is the wrong statement? (1) O3 molecule is bent (3) Ozone is diamagnetic gas (2) Ozone is violet-black in solid state (4) ONCl and ONO– are not isoelectronic

5.

6.

Four successive members of the first row transition elements are listed below with atomic numbers. Which value? one of them is expected to have the highest E 0 M3+ /M 2+

(1) Mn(Z = 25) (3) Co(Z = 27) 7.

(2) Fe(Z = 26) (4) Cr(Z = 24)

A solution of (–) –1 – chloro –1 – phenylethane is toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of : (1) carbene (2) carbocation (3) free radical (4) carbanion The coagulating power of electrolytes having ions Na+, Al3+ and Ba2+ for arsenic sulphide sol increases in the order: (1) Na + < Ba 2+ < Al3+ (2) Ba 2+ < Na + < Al3+ (3) Al3+ < Na + < Ba 2+ (4) Al3+ < Ba 2+ < Na + How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pH of 1 to create an aqueous solution with pH of 2? (1) 0.9 L (2) 2.0 L (3) 9.0 L (4) 0.1 L Which one of the following molecules is expected to exhibit diamagnetic behaviour? (2) O2 (1) N2 (4) C2 (3) S2 Which of the following arrangements does not represent the correct order of the property stated against it ? (1) Ni2+ < Co2+ < Fe2+ < Mn2+ : ionic size (2) Co3+ < Fe3+ < Cr3+ < Sc3+ : stability in aqueous solution (3) Sc < Ti < Cr < Mn : number of oxidation states (4) V2+ < Cr2+ < Mn2+ < Fe2+ : paramagnetic behaviour
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.

8.

9.

10.

11.

JEE(MAIN)2013-CMP-3

12.

Experimentally it was found that a metal oxide has formula M0.98O. Metal M, is present as M2+ and M3+ in its oxide. Fraction of the metal which exists as M3+ would be: (1) 4.08% (2) 6.05% (3) 5.08% (4) 7.01% A compound with molecular mass 180 is acylated with CH3COCl to get a compound with molecular mass 390. The number of amino groups present per molecule of the former compound is: (1) 5 (2) 4 (3) 6 (4) 2 Given E0 = −0.74 V; E 0 = 1.51 V Cr3+ /Cr MnO− /Mn 2+
4

13.

14.

E

0 2− Cr2 O7 / Cr3+

= 1.33 V; E

0 Cl/ Cl−

= 1.36 V

Based on the data given above, strongest oxidising agent will be: (1) Cr3+ (2) Mn2+ − (3) MnO 4 (4) Cl− 15. Arrange the following compounds in order of decreasing acidity: OH OH OH OH

Cl CH3 (I) (II) (1) I > II > III > IV (3) IV > III > I > II
16.

NO2 (III)

OCH3 (IV)
(2) III > I > II > IV (4) II > IV > I > III

The rate of a reaction doubles when its temperature changes from 300K to 310K. Activation energy of such a reaction will be: (R = 8.314 JK–1 mol–1 and log 2 = 0.301) (2) 58.5 kJ mol–1 (1) 48.6 kJ mol–1 –1 (3) 60.5 kJ mol (4) 53.6 kJ mol–1 Synthesis of each molecule of glucose in photosynthesis involves: (1) 10 molecules of ATP (2) 8 molecules of ATP (3) 6 molecules of ATP (4) 18 molecules of ATP Which of the following complex species is not expected to exhibit optical isomerism? (1) ⎡ ⎣Co ( en )2 Cl2 ⎤ ⎦
+
+

17.

18.

⎤ (2) ⎡ ⎣ Co ( NH3 )3 Cl3 ⎦
⎤ (4) ⎡ ⎣ Co ( en )3 ⎦
3+

⎤ (3) ⎡ ⎣ Co ( en ) ( NH3 )2 Cl2 ⎦

19.

A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.00C. As it does so, it absorbs 208J of heat. The values of q and w for the process will be: (R = 8.314 J/mol K) ( n 7.5 = 2.01) (1) q = – 208 J, w = – 208 J (2) q = – 208 J, w = + 208 J (3) q = + 208 J, w = + 208 J (4) q = + 208 J, w = – 208 J A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO2. The empirical formula of the hydrocarbon is: (1) C3H4 (2) C6H5 (4) C2H4 (3) C7H8

20.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com.

then for a large number of molecules the ratios of these speeds are: (1) C* : C : C = 1. Identify the compound (A). 24.128 The gas leaked from a storage tank of the Union Carbide plant in Bhopal gas tragedy was: (1) Methylamine (2) Ammonia (3) Phosgene (4) Methylisocyanate Consider the following reaction: z 2− + xMnO− → xMn 2+ + 2yCO 2 + H 2 O 4 + yC 2 O 4 + zH ⎯⎯ 2 The values of x. 2 and 16 23. Ba. gives a white precipitate when warmed with alcoholic AgNO3. Ph 46106000. respectively: (1) 2. Wavelength of light required to excite an Energy of an electron is given by E = −2.62 × 10−34 Js and c = 3.178×10−18 J ⎜ ⎜ 2⎟ ⎟ ⎜ ⎝n ⎠ electron in an hydrogen atom from level n = 1 to n = 2 will be (h = 6. . CH2Br C2 H5 (2) (1) 27.0 × 108 ms−1) (2) 6. Se and Ar? (1) S < Se < Ca < Ba < Ar (2) Ba < Ca < Se < S < Ar (3) Ca < Ba < S < Se < Ar (4) Ca < S < Ba < Se < Ar For gaseous state.225 :1 (2) C* : C : C = 1:1. S. (B) easily forms anhydride on heating.125 :1. New Delhi -110016.com. C8H6O4. if most probable speed is denoated by C*.128 :1.JEE(MAIN)2013-CMP-4 21. Oxidation of (A) gives a acid (B).816 × 10−7 m (4) 1. 25. ⎛Z ⎞ ⎟ ⎟ . 5 and 8 (2) 2. Fax 26513942 website: www. Kalu Sarai. H3C I CH2 II CH2 .128 :1.128 :1 (3) C* : C : C = 1:1.500 × 10−7 m 2 FIITJEE Ltd. y and z in the reaction are. 29-A.. III is: (1) II > III > I (3) III > I > II 22. (2) I > II > III (4) III > II > I Which of the following represents the correct order of increasing first ionization enthalpy for Ca.214 × 10−7 m (3) 8.225 (4) C* : C : C = 1.500 × 10−7 m (1) 2. 5 and 16 (3) 5. FIITJEE House. 26. Br CH3 (3) CH2Br (4) CH2 Br CH3 CH3 28. Which of the following exists as covalent crystals in the solid state? (1) Silicon (2) Sulphur (3) Phosphorous (4) Iodine Compound (A). average speed by C and mean square speed by C. C8H9Br. Sarvapriya Vihar. 2 and 8 (4) 5.225 :1.fiitjee. 26569493. The order of stability of the following carbocations: CH2 H2C CH CH2 .

com. Kalu Sarai. New Delhi -110016. FIITJEE House.fiitjee.JEE(MAIN)2013-CMP-5 29. Fax 26513942 website: www. 26569493. An organic compound A upon reacting with NH3 gives B. . A is (2) H3C CH COOH (1) CH3CH2CH2COOH (3) CH3CH2COOH (4) CH3 CH3COOH 30. He 2 2− (4) H + 2 .. Sarvapriya Vihar. He 2 2+ (3) H− 2 . C in presence of KOH reacts with Br2 to give CH3CH2NH2. In which of the following pairs of molecules/ions. On heating B gives C. 29-A. He 2 FIITJEE Ltd. Ph 46106000. both the species are not likely to exist? 2− + (1) H− (2) H 2 2 . He 2 2 .

Statement -II is False.B: MATHEMATICS 31.P. Statement -II is True Statement -I is True. Statement − I : An equation of a common tangent to these curves is y = x + 5 ..fiitjee. tan−1y and tan−1z are also in A.. Statement-II is a correct explanation for Statement-I A ray of light along x + 3y = 3 gets reflected upon reaching x-axis. BC = p and CD = q. Statement -I is False. y = mx + 5 (m ≠ 0) is their common tangent. Kalu Sarai. y2 = 4 5 x.I is True. then AB is equal to p 2 + q 2 cos θ p2 + q 2 (1) (2) 2 p cos θ + q sin θ p cos θ + q 2 sin θ (3) 32. and tan−1x. then m satisfies m4 − 3m2 + 2 = m 0. Statement . 2x2 + 2y2 = 5 and a parabola. 29-A. then ∫ x f ( x ) dx 5 3 is equal to 1 3 x Ψ ( x 3 ) − ∫ x 2 Ψ ( x 3 ) dx + C 3 1⎡ 3 (4) x Ψ ( x 3 ) − ∫ x 2 Ψ ( x 3 ) dx ⎤ ⎦+C 3⎣ 1 3 x Ψ ( x 3 ) − 3∫ x 3 Ψ ( x 3 ) dx + C 3 1⎡ 3 (3) x Ψ ( x 3 ) − ∫ x 3 Ψ ( x 3 ) dx ⎤ ⎦+C 3⎣ (1) (2) FIITJEE Ltd. ∫ f ( x ) dx = Ψ ( x ) . 37. 0) also passes through the point (1) (2. Which of the following statistical measures will not change even after the grace marks were given ? (1) median (2) mode (3) variance (4) mean If x. 26569493. FIITJEE House. Ph 46106000. Statement -II is true. (1) (2) (3) (4) 34.P. 2) ABCD is a trapezium such that AB and CD are parallel and BC⊥CD. (p 2 + q 2 ) sin θ ( p cos θ + q sin θ ) 2 (4) (p 2 + q 2 ) sin θ p cos θ + q sin θ 33. . Statement -II is True. −2) (3) (−2.com. Fax 26513942 website: www.JEE(MAIN)2013-CMP-6 PART . All the students of a class performed poorly in Mathematics. 5) (4) (−5. Given : A circle. the equation of the reflected rays is (1) (3) 3y = x − 3 3y = x − 1 (2) y = 3x − 3 (4) y = x + 3 35. New Delhi -110016. Statement-II is not a correct explanation for Statement-I Statement -I is True. −5) (2) (5. The circle passing through (1. Statement − II : If the line. y. Sarvapriya Vihar. z are in A. then (1) 2x = 3y = 6z (2) 6x = 3y = 2z (3) 6x = 4y = 3z (4) x = y = z If 36. If ∠ADB = θ. The teacher decided to give grace marks of 10 to each of the students. −2) and touching the axis of x at (3.

JEE(MAIN)2013-CMP-7 38. 3) is 16 9 (2) x 2 + y 2 − 6y − 5 = 0 (4) x 2 + y 2 − 6y − 7 = 0 39. .. . (1 − cos 2x )( 3 + cos x ) x tan 4x 1 2 is equal to (2) 1 (4) − 1 4 (1) (3) 2 FIITJEE Ltd. x ∈ R. Fax 26513942 website: www.777.fiitjee. Statement-II is a correct explanation for Statement-I The area (in square units) bounded by the curves y = x. The x-coordinate of the incentre of the triangle that has the coordinates of mid points of its sides as (0. 45. 0.. Statement -II is True (4) Statement -I is True. 1) and (1.7. The equation of the circle passing through the foci of the ellipse (1) x 2 + y 2 − 6y + 7 = 0 (3) x 2 + y 2 − 6y + 5 = 0 x 2 y2 + = 1 . 0. 29-A.I is True. (2) ± 3 (4) ± 1 The sum of first 20 terms of the sequence 0. 1) (1. Statement -II is True. Kalu Sarai. 43. 2x3 + 3x + k = 0 has two distinct real roots in [0. Statement-II is not a correct explanation for Statement-I (2) Statement -I is True. Ph 46106000. 2y − x + 3 = 0 . Statement -II is False. (1) Statement .com. Sarvapriya Vihar. 2x. Statement − II : (p → q) ↔ (~ q → ~ p) is a tautology. 1] (1) lies between 2 and 3 (2) lies between −1 and 0 (3) does not exist (4) lies between 1 and 2 lim x →0 46. Statement -II is true. 44.77. and having centre at (0. 0) is (2) 1 + 2 (1) 2 − 2 (3) 1 − 2 (4) 2 + 2 The intercepts on x-axis made by tangents to the curve. which are parallel to the line y = 0 x 40. (3) Statement -I is False. are equal to (1) ± 2 (3) ± 4 41. x-axis. New Delhi -110016. …. 26569493. y = ∫ t dt . The real number k for which the equation. FIITJEE House. is 7 7 (2) (1) ( 99 − 10−20 ) (179 + 10−20 ) 9 81 7 7 (3) ( 99 + 10−20 ) (4) (179 − 10−20 ) 9 81 Consider : Statement − I : (p ∧ ~ q) ∧ (~ p ∧ q) is a fallacy. and lying in the first quadrant is (1) 36 (2) 18 27 (4) 9 (3) 4 The expression tan A cot A can be written as + 1 − cot A 1 − tan A (1) secA cosecA + 1 (2) tanA + cotA (3) secA + cosecA (4) sinA cosA + 1 42.

then k can have 1 1 k 2 1 −k (1) exactly one value (2) exactly two values (3) exactly three values (4) any value 51. 52. Ph 46106000. then the value of n is (1) 5 (2) 10 (3) 8 (4) 7 At present. a firm is manufacturing 2000 items. If the lines 54. Statement -II is true. Kalu Sarai. Statement-II is not a correct explanation for Statement-I Statement -I is True. Sarvapriya Vihar. dP additional number of workers x is given by = 100 − 12 x . Statement-II is a correct explanation for Statement-I 50.t. Let A and B be two sets containing 2 elements and 4 elements respectively.fiitjee. The number of subsets of A × B having 3 or more elements is (1) 220 (2) 219 (3) 211 (4) 256 FIITJEE Ltd. 6 ∫ f ( x ) dx = ∫ f ( a + b − x ) dx . FIITJEE House. Statement -II is True. Let Tn be the number of all possible triangles formed by joining vertices of an n-sided regular polygon. then at x = 1 is equal to dx 1 (2) 1 (1) 2 1 (3) 2 (4) 2 x −2 y−3 z−4 x −1 y − 4 z − 5 = = = = and are coplanar. 26569493. Fax 26513942 website: www. . If the firm employs 25 more workers. Statement -I is False. a a (1) (2) (3) (4) Statement . If Tn+1 − Tn = 10. π/6 ∫ 1+ dx tan x is equal to π . 53. Statement -II is True Statement -I is True. then α is equal to ⎢ ⎣ 2 4 4⎥ ⎦ (1) 11 (2) 5 (3) 0 (4) 4 The number of values of k.I is True.. is (1) 1 (2) 2 (3) 3 (4) infinite dy If y = sec(tan−1x). 49. It is estimated that the rate of change of production P w. ⎡1 α 3⎤ ⎥ If P = ⎢ ⎢1 3 3 ⎥ is the adjoint of a 3 × 3 matrix A and |A| = 4.com.r. 29-A. Statement -II is False. for which the system of equations (k + 1)x + 8y = 4k kx + (k + 3)y = 3k − 1 has no solution.JEE(MAIN)2013-CMP-8 47. then dx the new level of production of items is (1) 3000 (2) 3500 (3) 4500 (4) 2500 Statement − I : The value of the integral Statement − II : b b π /3 48. New Delhi -110016.

The probability that a student will get 4 or more correct answers just by guessing is 13 11 (1) 5 (2) 5 3 3 10 17 (3) 5 (4) 5 3 3 ⎛ 1+ z ⎞ If z is a complex number of unit modulus and argument θ. 60. a. then a : b : c is (1) 3 : 2 : 1 (2) 1 : 3 : 2 (3) 3 : 1 : 2 (4) 1 : 2 : 3 Distance between two parallel planes 2x + y + 2z = 8 and 4x + 2y + 4z + 5 = 0 is 5 7 (1) (2) 2 2 9 3 (3) (4) 2 2 x +1 x −1 ⎞ ⎛ The term independent of x in expansion of ⎜ 2/3 − 1/3 1/ 2 ⎟ ⎝ x − x +1 x − x ⎠ (1) 120 (2) 210 (3) 310 (4) 4 10 56. b. then arg ⎜ ⎟ equals ⎝1+ z ⎠ π (1) − θ (2) θ 2 (3) π − θ (4) − θ If the equations x2 + 2x + 3 = 0 and ax2 + bx + c = 0. Sarvapriya Vihar. Kalu Sarai.com. then the length of the ˆ + 4k ˆ and AC = 5i If the vectors AB = 3i median through A is (2) 33 (1) 72 (3) 45 (4) 18 A multiple choice examination has 5 questions. is FIITJEE Ltd. FIITJEE House. Ph 46106000. 29-A. 59. c ∈ R.fiitjee. Each question has three alternative answers of which exactly one is correct. 57. 58..JEE(MAIN)2013-CMP-9 55. New Delhi -110016. Fax 26513942 website: www. . 26569493. ˆ − 2j ˆ + 4k ˆ are the sides of a triangle ABC. have a common root.

Ph 46106000. Which of the following statement is correct? V R S1 C S2 L (1) At t = τ.04 Volt (4) zero volt A uniform cylinder of length L and mass M having cross-sectional area A is suspended. The extension x0 of the spring when it is in equilibrium is: Mg ⎛ LAσ ⎞ Mg ⎛ LAσ ⎞ (1) (2) ⎜1 − ⎟ ⎜1 − ⎟ k ⎝ M ⎠ k ⎝ 2M ⎠ Mg ⎛ LAσ ⎞ Mg (4) (3) ⎜1 + ⎟ k ⎝ M ⎠ k (Here k is spring constant) Two charges.62 kHz (2) 5.com. A 60 W bulb is already switched on.C: PHYSICS 61. from a fixed point by a massless spring.fiitjee. S2 kept open. The resistance of the lead wires is 6 Ω. such that it is half submerged in a liquid of density σ at equilibrium position. If charge q0 is given a small displacement (y a) along the y-axis. (4) y FIITJEE Ltd. Now switch S1 is closed.9 Volt (2) 13.3 Volt (3) 10. FIITJEE House.. What is the decrease of voltage across the bulb. 65. 62. A diode detector is used to detect an amplitude modulated wave of 60% modulation by using a condenser of capacity 250 pico farad in parallel with a load resistance 100 kilo ohm. (1) 10. In an LCR circuit as shown below both switches are open initially. A particle of mass m and charge q q 0 = is placed at the origin. q = CV/2 (2) At t = 2τ. the net 2 force acting on the particle is proportional to: 1 (1) −y (2) y (3) − 1 y 63. (q is charge on the capacitor and τ = RC is capacitive time constant). Kalu Sarai. Fax 26513942 website: www. 64. each equal to q. New Delhi -110016.JEE(MAIN)2013-CMP-10 PART . 29-A. q = CV(1 − e−1 ) 2 (4) Work done by the battery is half of the energy dissipated in the resistor. 26569493. when a 240 W heater is switched on in parallel to the bulb? (1) 2. are kept at x = −a and x = a on the x-axis.31 kHz (4) 10.62 MHz The supply voltage to a room is 120 V. Find the maximum modulated frequency which could be detected by it. .31 MHz (3) 5. q = CV(1 − e−2) τ (3) At t = . with its length vertical. Sarvapriya Vihar.

f. 26569493. The wavelength λ of the light falling on the cathode is gradually changed. New Delhi -110016. Ph 46106000. If n >> 1. O λ O λ (3) I (4) I O λ O λ d S1 S2 D Screen 68. Kalu Sarai.m. Sarvapriya Vihar.fiitjee. Two coherent point sources S1 and S2 are separated by a small distance ‘d’ as shown. . The fringes obtained on the screen will be: (1) straight lines (2) semi-circles (3) concentric circles (4) points A metallic rod of length ‘ ’ is tied to a string of length 2 and made to rotate with angular speed ω on a horizontal table with one end of the string fixed. density of liquid is ρ and L is its latent heat of vaporization. FIITJEE House. so that its temperature remains unchanged. FIITJEE Ltd. The intensity of the emergent light is: (2) I0/4 (1) I0/2 (3) I0/8 (4) I0 The anode voltage of a photocell is kept fixed. In a hydrogen like atom electron makes transition from an energy level with quantum number n to another with quantum number (n – 1). A beam of unpolarised light of intensity I0 is passed through a polaroid A and then through another polaroid B which is oriented so that its principal plane makes an angle of 45° relative to that of A. The plate current I of the photocell varies as follows: (1) (2) I I 67. the e. 70. induced across the ends of the rod is: 3Bω 2 4Bω 2 (2) (1) 2 2 2 5Bω 2Bω 2 (3) (4) 2 2 69. If there is a vertical magnetic field ‘B’ in the region.JEE(MAIN)2013-CMP-11 66. Fax 26513942 website: www. (1) T / ρL (2) T/ρL (3) 2T/ρL (4) ρL/T 71. What should be the minimum radius of the drop for this to be possible? The surface tension is T. 29-A..com. the frequency of radiation emitted is proportional to 1 1 (1) 2 (2) 3/ 2 n n 1 1 (4) (3) 3 n n Assume that a drop of liquid evaporates by decrease in its surface energy.

Statement – II is the correct explanation of statement.com. The graph between angle of deviation (δ) and angle of incidence (i) for a triangular prism is represented by: δ δ (1) (2) O i O i (3) δ (4) δ O i O i 73.5 Hz This question has statement I and statement II. L = length. New Delhi -110016. additional shunt needs to be used across it. .fiitjee. Ph 46106000. 29-A. Statement.JEE(MAIN)2013-CMP-12 72. then: (1) [ε0] = [M-1L-3T4A2] (2) [ε0] = [M-1L2T-1A-2] -1 2 -1 (4) [ε0] = [M-1L-3T2A] (3) [ε0] = [M L T A] A B C 2v0 v 74. 26569493. A sonometer wire of length 1. The amount of heat extracted from the source in a single cycle is ⎛ 13 ⎞ ⎛ 11 ⎞ (1) ⎜ ⎟ p0 v0 (2) ⎜ ⎟ p0 v0 ⎝2⎠ ⎝2⎠ (4) p0v0 (3) 4p0v0 75. 76.2 Hz (2) 200. Fax 26513942 website: www. 2p0 p p0 O D v0 The above p-v diagram represents the thermodynamic cycle of an engine. Statement. (3) Statement – I is false.7 × 103 kg/m3 and 2. statement – II is false.. Statement – II is not the correct explanation of Statement–I.5 m is made of steel. greater is the resistance of ammeter. FIITJEE House. choose the one that best describes the two statements. operating with an ideal monoatomic gas. Statement – II is true. Let [ε0] denote the dimensional formula of the permittivity of vacuum. Of the four choices given after the statements.II: To increase the range of ammeter. Sarvapriya Vihar. (2) Statement – I is true. Statement – II is true (4) Statement – I is true. Statement – II is true. T = time and A = electric current. Kalu Sarai.5 Hz (3) 770 Hz (4) 188.I .I: Higher the range.2 × 1011N/m2 respectively? (1) 178. FIITJEE Ltd. If M = mass. What is the fundamental frequency of steel if density and elasticity of steel are 7. (1) Statement – I is true. The tension in it produces an elastic strain of 1 %.

A charge Q is uniformly distributed over a long rod AB of length L as shown in the figure. (4) y = x − 5 x 2 2 Two capacitors C1 and C2 are charged to 120 V and 200 V respectively. What will be the velocity of the centre of the hoop when it ceases to slip? rω0 rω0 (1) (2) 3 2 rω0 (4) (3) rω0 4 An ideal gas enclosed in a vertical cylindrical container supports a freely moving piston of mass M. the piston executes a simple harmonic motion with frequency: (1) (3) 1 V0 MP0 2π A2γ 1 2π MV0 Aγ P0 80. the equation of its trajectory is: (1) y = 2 x − 5 x 2 (2) 4 y = 2 x − 5 x 2 (3) 4 y = 2 x − 25 x 2 79. Assuming that the system is completely isolated from its surrounding. FIITJEE House. the volume of the gas is V0 and its pressure is P0.JEE(MAIN)2013-CMP-13 77. Fax 26513942 website: www. Sarvapriya Vihar. 29-A. It is found that by connecting them together the potential on each one can be made zero. The piston and cylinder have equal cross sectional area A. where iˆ is along the ground and ˆ A projectile is given an initial velocity of i 78.. What is the minimum energy required to launch a satellite of mass m from the surface of a planet of mass M and radius R in a circular orbit at an altitude of 2R? GmM 2GmM (1) (2) 3R 2R GmM 5GmM (4) (3) 3R 6R ˆ+2ˆ j is along the j m/s. 81. (2) (4) 1 2π A2γ P0 MV0 1 Aγ P0 2π V0 M 82. The initial velocity of the centre of the hoop is zero. Then : (2) 3C1 + 5C2 = 0 (1) 3C1 = 5C2 (3) 9C1 = 4C2 (4) 5C1 = 3C2 A hoop of radius r and mass m rotating with an angular velocity ω0 is placed on a rough horizontal surface. If g = 10 m/s . New Delhi -110016. Ph 46106000. The piston is slightly displaced from the equilibrium position and released. 26569493. When the piston is in equilibrium.fiitjee.com. ( ) vertical. Kalu Sarai. . The electric potential at the point O lying at a distance L from the end A is: O L A L B (1) (3) 3Q 4πε 0 L Q ln 2 4πε 0 L (2) (4) Q 4πε 0 L ln 2 Q 8πε 0 L FIITJEE Ltd.

(1) 0.6 (4) 0.1 × 10–11 weber If a piece of metal is heated to temperature θ and then allowed to cool in a room which is at temperature θ 0 the graph between the temperature T of the metal and time t will be closest to : (1) (2) T T θ0 O t θ0 O t 84. Red Yellow Green Blue V (3) V (4) . 26569493. The distance between their centres is 15 cm.3 cm lies parallel to a much bigger circular loop of radius 20 cm. In another 10s it will decrease to α times its original magnitude.fiitjee.. then the flux linked with bigger loop is (1) 6 × 10–11 weber (2) 3. Statement – II is not a correct explanation of Statement – I.81 (2) 0. Fax 26513942 website: www.7 FIITJEE Ltd. The centre of the small loop is on the axis of the bigger loop. (3) Statement – I is false.9 times its original magnitude is 5s. The amplitude of a damped oscillator decreases to 0. This question has Statement I and Statement II.729 (3) 0. Statement – II is true. 29-A. where α equals. choose the one that best describes the two Statements. 87. 2 ⎝M +m⎠ ⎝ ⎠ Statement – II : Maximum energy loss occurs when the particles get stuck together as a result of the collision.0 A flows through the smaller loop. (2) Statement – I is true. If the maximum energy loss possible is given as f ⎜ mv 2 ⎟ then f = ⎜ ⎟. A circular loop of radius 0.6 × 10 weber (4) 9. If a current of 2.JEE(MAIN)2013-CMP-14 83. FIITJEE House. Kalu Sarai.com. New Delhi -110016. Statement – I : A point particle of mass m moving with speed v collides with stationary point particle of ⎛ m ⎞ ⎛1 ⎞ mass M.3 × 10–11 weber –9 (3) 6. Sarvapriya Vihar. Statement – II is true (4) Statement – I is true. Statement – II is false. Statement – II is a correct explanation of Statement – I. Ph 46106000. Of the four choices given after the Statements. (1) Statement – I is true. The I – V characteristic of an LED is (1) B G Y R O V O (2) I O V R Y G B (R)(Y)(G)(B) I I O 86. Statement – II is true. (3) T θ0 O t (4) T O t 85.

29-A. Sarvapriya Vihar. If speed of light in material of lens is 2 × 108 m/s. The peak value of electric field strength is : (1) 6 V/m (2) 9 V/m (3) 12 V/m (4) 3 V/m Two short bar magnets of length 1 cm each have magnetic moments 1.point O of the line joining their centres is close to (Horizontal component of earth’s magnetic induction is 3.50 × 10–4 Wb/m2 –4 2 (4) 3. 90. FIITJEE Ltd.0 cm.00 Am2 respectively..80 × 10 Wb/m 89.6 × 10–5 Wb/m2) (1) 2. Fax 26513942 website: www.20 Am2 and 1. FIITJEE House.fiitjee.56 × 10–4 Wb/m2 (2) 3.com. The value of the resultant horizontal magnetic induction at the mid . 26569493.6 × 10–5 Wb/m2 (3) 5. Kalu Sarai.JEE(MAIN)2013-CMP-15 88. New Delhi -110016. Ph 46106000. Diameter of plano-convex lens is 6 cm and thickness at the centre is 3 mm. the focal length of the lens is : (1) 20 cm (2) 30 cm (3) 10 cm (4) 15 cm The magnetic field in a travelling electromagnetic wave has a peak value of 20 nT. . They have a common magnetic equator and are separated by a distance of 20. They are placed on a horizontal table parallel to each other with their N poles pointing towards the South.

18. 30. 11. 24. 76. 36. 81. 1 3 1 4 3 2 3 3. 42. 56. 79. 3 21. 50. New Delhi -110016. 8.A: CHEMISTRY 1. 39. 52. 4 25. 85. 83. 72. 86. 43. 1 2 2 3 3 2 2 34. 4 4 4 1 2 4 2 2 33. 16. 90. 80. 75. 20. 3 2 3 2 1 3 3 1 63. 51. 35. 57. 74. 46. 71. Kalu Sarai. 68. 44. 1 2. 65. 4 29. 45. 55. 6. 15. 2 3 2 3 2 2 2 FIITJEE Ltd. 84. 78. 1 3 1 or 4 3 2 2 1 2 4. 58. 14. 7. 5. 2 4 3 1 4 2 4 1 62.fiitjee. Ph 46106000. 88. 12. 3 3 3 1 1 4 2 64. 4 17. 27. 23. Sarvapriya Vihar. 2 3 1 4 1 1 2 2 32. 26569493. 54. 37. 66. 87. 22. 67.com. FIITJEE House. 1 4 1 3 1 2 4 PART . 60. 47. 70. 82. Incorrect question 1 9. 73. Fax 26513942 website: www. 69. 1 13. 48. 4 2 2 or 4 2 4 2 3 PART . 38. 29-A. 26. 28. 53. 19.C: PHYSICS 61. 89. 77. 49. . 40.B: MATHEMATICS 31. 41. 10. 59.JEE(MAIN)2013-CMP-16 [Code – Q] JEE(MAIN) 2013 ANSWERS PART ..

O. * 2 Li 2 ( 6 ) = σ1s 2 σ 1s σ2s 2 B.97 V Co+3 / Co+2 E0 = −0.57 V Mn +3 / Mn +2 E0 = 0. 7.5 2 − − Li + 2 is more stable than Li 2 because Li 2 has more numbers of antibonding electrons. Sarvapriya Vihar. = 4−2 =1 2 3− 2 = 0. ⎯⎯⎯⎯⎯ → Na + + e − . 4. = * 2 * − Li 2 1s σ2s 2 σ 2s1 ( 7 ) = σ1s2 σ B.5 2 * 2 + Li 2 1s σ2s1 ( 5) = σ1s2 σ B. (3) Correct. New Delhi -110016.77 V Fe +3 / Fe+2 E0 = 1. (1) Correct.1eV ∆H =+5. = 4−3 = 0. SbCl5 CH3 ⎯⎯⎯ → [ Ph − CH − CH 3 ] [SbCl6 ] + Planer structure − . Fax 26513942 website: www. Electron gain enthalpy. which is directly proportional to the valency of cation (Hardy-Schulze rule). as O (2) Correct. as ONCl = 32 electrons and ONO− = 24 electron hence are not isoelectronic.com. FIITJEE House. here the backward reaction releases same amount of energy and known as Na ←⎯⎯⎯⎯ ⎯ ∆H =−5. E0 = 1.fiitjee. As2S3 is an anionic sol (negative sol) hence coagulation will depend upon coagulating power of cation.1eV 2.O. FIITJEE Ltd. Reaction proceeds through carbocation formation as 30 carbocation is highly stable. hence reaction proceeds through SN1 with 30 alcohol.5 × 750 + 2 × 250 M= 1 1 = V 1000 M = 0. 875 5. M1V1 + M2V2 = MV M V + M 2 V2 0. as ozone is violet-black solid.JEE(MAIN)2013-CMP-17 HINTS AND SOLUTIONS PART . All options are correct statements. Kalu Sarai. 3. O O is bent. as ozone is diamagnetic..A: CHEMISTRY 1.41 V Cr +3 / Cr +2 6.O. 26569493. (4) Correct. 29-A. CH Cl 8. Ph 46106000.

Metal oxide = M0.98O If ‘x’ ions of M are in +3 state. Correct order of acidic strength is III > I > II > IV As per Arrhenius equation: E ⎛1 k 1⎞ ⎟ ln 2 = − a ⎜ − ⎟ ⎜ ⎟ ⎜ ⎟ k1 R⎜ ⎝ T2 T1 ⎠ ⎞ Ea ⎛ ⎟ ⎜ 1 − 1 ⎟ ⎜ ⎟ ⎜ 8.1 mole/litre New pH = 2.1 ×1 =0.e. As per data mentioned MnO − 4 is strongest oxidising agent as it has maximum SRP value. so least stable (not most stable) Fe+2 contains 4 unpaired electrons where as Mn+2 contains 5 unpaired electrons hence (4) is incorrect.303 log 2 = − || 17. i. [H+] = 0. Sarvapriya Vihar. 12. Light reaction 12H 2 O + 12NADP + 18ADP ⎯⎯⎯⎯⎯ → 6O 2 + 18ATP + 12NADPH Dark reaction 6CO 2 + 12NADPH + 18ATP ⎯⎯⎯⎯⎯ → C6 H12 O6 + 12NADP + 18ADP + 6H 2 O → C6 H12 O6 + 6O2 Net reaction: 6CO2 + 6H 2 O ⎯⎯ FIITJEE Ltd. Volume of water added = 9 litre.com. R − NH 2 + CH 3 − C − Cl ⎯⎯ → R − NH − C− CH 3 + HCl O Each CH 3 − C addition increases the molecular wt.08% 0. N2 → Diamagnetic O2 → Paramagnetic S2 → Paramagnetic C2 → Diamagnetic The exothermic hydration enthalpies of the given trivalent cations are: Sc+3 = 3960 kJ/mole Fe+3 = 4429 kJ/mole Co+3 = 4653 kJ/mole Cr+3 = 4563 kJ/mole Hence Sc+3 is least hydrated.98 O || 13.JEE(MAIN)2013-CMP-18 9.04 × 100 = 4.01 mole/litre In case of dilution: M1V1 = M2V2 0. 15. = 390 – 180 = 210 210 =5 Then number of NH2 groups = 42 14.04 So the percentage of metal in +3 state would be O || 10. Fax 26513942 website: www.wt. FIITJEE House. [H+] = 0. 0.314 ⎝ 310 300 ⎠ ⇒ Ea = 53.e. Initial pH = 1. 16. Ph 46106000.98 – x) × 2 = 2 x = 0. then 3x + (0. Kalu Sarai.01 × V2 V2 = 10 litre. Total increase in m. New Delhi -110016. 29-A.. i. 26569493. . by 42. 11.fiitjee.6 kJ/mole 2.

07 = y / 2 0. Hence. ∴ q = −W As q = +208 J Hence W = −208 J 20. C= . hence ∆U = 0.07 0. FIITJEE House.JEE(MAIN)2013-CMP-19 18. Kalu Sarai. y = 5. z = 16 26. [Co(NH3)3Cl3] exists in two forms (facial and meridonial) NH3 H3 N Cl H3 N NH3 Cl Co Co H3 N Cl Cl NH3 Cl facial Cl meridonial 19.72 g 0. (Stability ∝ extent of delocalization) Increasing order of first ionization enthalpy is Ba < Ca < Se < S < Ar C* = 2RT 8RT 3RT . 29-A.fiitjee. . [Co(NH3)3Cl3] does not show optical isomerism. It was methyl isocyanate (CH3NCO) −2 + 2MnO− → 2Mn +2 + 10CO2 + 8H 2O 4 + 5C2 O 4 + 16H ⎯⎯ x = 2. New Delhi -110016. Silicon (Si) – covalent solid Sulphur (S8) – molecular solid Phosphorous (P4) – Molecular solid Iodine (I2) – Molecular solid FIITJEE Ltd. Both of these forms are achiral. Sarvapriya Vihar. Ph 46106000.. ⎛ ⎞ y ⎟ ⎜x + y ⎟ → xCO 2 + H 2 O Cx H y + ⎜ ⎟ O 2 ⎯⎯ ⎜ ⎝ 4⎠ 2 Weight (g ) moles x 0.04 ⇒ 3. 23.com. C= M πM M 22. Process is isothermal reversible expansion. 25.04 x 7 = y 8 21. 24. Order of stability is III > I > II.08 g 0. Fax 26513942 website: www. 26569493.

fiitjee. Ph 46106000. CH2Br (A) CH3 [O] ) 3( ⎯⎯⎯⎯⎯ → AgNO alc. E= ⇒ λ = 1.com. . 29-A.JEE(MAIN)2013-CMP-20 27. New Delhi -110016. Kalu Sarai.214 ×10−7 m 29. CH2 CH3 + + AgBr ↓ ( pale yellow ) O COOH COOH (B) hc ⎡1 1 ⎤ = 2. FIITJEE Ltd. O C (B) ONH4 ∆ / (−H 2 O) O CH3CH2 C NH2 (C) Br2 / KOH CH3 CH2 NH2 30. thus their existence is not possible. Fax 26513942 website: www. FIITJEE House. 26569493.. Sarvapriya Vihar. + Bond order of H 2 2 and He2 is zero.178 ×10−18 × Z2 ⎢ 2 − 2 ⎥ λ ⎣1 2 ⎦ O CH3CH2 C (A) OH ⎯⎯⎯ → CH3CH2 NH3 ∆ ⎯⎯⎯ → −H O 2 O O pthalic anhydride 28.

y. So. Variance is not changed by the change of origin. . its distance from the centre of the circle must be equal to the radius of the circle. Kalu Sarai.. Slope of the incident ray is − 1 3 . m Now. 5 (m ≠ 0). the common tangents are y = x + 5 and y = − x − 5. 1 3 So. New Delhi -110016. . Note: If y = 0. (x − 3)2 + y2 + λy = 0 The circle passes through (1. 2 tan−1y = tan−1x + tan−1z ⇒ x = y = z. the equation of reflected ray is y = ) (x − 3) . FIITJEE House. Ph 46106000. 36. tan−1y.B: MATHEMATICS 31. = m 2 Let the tangent to the parabola be y = mx + ⇒ (m2 − 1) (m2 + 2) = 0 ⇒ m = ± 1 So.P. Alternate Solution: σ= σ1 = ∑ x−x n 2 for y = x + 10 ⇒ y = x + 10 2 ∑ y + 10 − y − 10 n = ∑ y−y n 2 =σ. Fax 26513942 website: www. − 2) satisfies. 34. ( p cos θ + q sin θ ) (p 2 +q 2 ) sin θ . − 2) ⇒ 4 + 4 − 2λ = 0 ⇒ λ = 4 (x − 3)2 + y2 + 4y = 0 ⇒ Clearly (5. tan−1z are in A. Sarvapriya Vihar. 0 . If x. ⇒ AB = p 2 + q 2 sin θ sin θ cos α + cos θ sin α = p 2 + q 2 sin θ sin θ ⋅ q cos θ ⋅ p + 2 2 p +q p2 + q 2 p2 + q 2 θ D α q C p ⇒ AB = 33. 1 + m 2 ⇒ (1 + m2) m2 = 2 ⇒ m4 + m2 − 2 = 0. 29-A.P. 5 5 So. 1 3 ( 3. FIITJEE Ltd.JEE(MAIN)2013-CMP-21 PART . the slope of the reflected ray must be The point of incidence is 35. 26569493. Using sine rule in triangle ABD AB BD = sin θ sin ( θ + α ) A π −(θ + α) α B 32. then none of the options is appropriate.fiitjee. 2y = x + z and tan−1x. z are in A.com.

0) A(0. 0) We have a2e2 = a2 − b2 = 7 Equation of circle (x − 0)2 + (y − 3)2 = ⇒ x2 + y2 − 6y − 7 = 0. 0) 2× 2 + 2 2 × 0 + 2× 0 2+2+2 2 4 2 = = 2− 2 . 26569493. 0) (1. 1) C(0. Kalu Sarai.JEE(MAIN)2013-CMP-22 37.. we get x = 1 and − 1. 29-A.com. S1: p T T F F q T F T F ~p F F T T ~q F T F T p^~q F T F F ~p^q F F T F (p^~q)^(~p^q) F F F F Fallacy FIITJEE Ltd.. ⎦ 3⎣ 3 { } 38. tr = 0. Ph 46106000.fiitjee. 41. 2 ⎝ ⎠ 40. . ( 7 −0 ) 2 + ( 0 − 3) 2 39. ∫ f ( x ) dx = ψ ( x ) Let x3 = t 3x2dx = dt then = ∫ x f ( x ) dx 5 3 = 1 tf ( t ) dt 3∫ 1⎡ 1 t ∫ f ( t )dt − ∫ 1 ⋅ ∫ f ( t ) dt dt ⎤ = x 3 ψ ( x 3 ) − ∫ x 2 ψ ( x 3 ) dx + C . dy = x =2 ⇒x=±2⇒y= dx −2 ∫ t dt = 2 for x = 2 0 2 and y = ∫ 0 t dt = −2 for x = − 2 ∴ tangents are y − 2 = 2 (x − 2) ⇒ y = 2x − 2 and y + 2 = 2 (x + 2) ⇒ y = 2x + 2 Putting y = 0. = 4+2 2 2+ 2 Alternate Solution: x-coordinate = r = (s − a) tan A/2 ⎛ 4+2 2 ⎞ π =⎜ −2 2⎟ ⎜ ⎟ tan 4 = 2 − 2 . Fax 26513942 website: www. r times = 7 (10–1 + 10–2 + 10–3 + …. FIITJEE House. foci ≡ (± ae. New Delhi -110016. Sarvapriya Vihar. + 10–r) 7 = (1 − 10− r ) 9 20 20 ⎞ 7⎛ 7⎛ 1 7( ⎞ S20 = t r = ⎜ 20 − 10− r ⎟ = ⎜ 20 − (1 − 10 −20 ) ⎟ = 179 + 10−20 ) ⎜ ⎟ 9 9 9 81 ⎝ ⎠ r =1 r =1 ⎝ ⎠ ∑ ∑ 42. 1) B(2. x-coordinate = = ax1 + bx 2 + cx 3 a+b+c (0.. 2) (1.777 ….

Kalu Sarai. Sarvapriya Vihar.JEE(MAIN)2013-CMP-23 S2: p T T F F q T F T F ~p F F T T ~q F T F T p⇒q T F T T ~q⇒~p T F T T (p ⇒ q) ⇔ (~ q ⇒ ~ p) T T T T Tautology S2 is not an explanation of S1 43.com. 12 2I = FIITJEE Ltd. . 1 cot 2 A 1 − cot 3 A cos ec 2 A + cot A − = = = 1 + sec A cosec A cot A (1 − cot A ) (1 − cot A ) cot A (1 − cot A ) cot A If 2x3 + 3x + k = 0 has 2 distinct real roots in [0. π/3 12 × 2 ( 25 )3/ 2 3 49. 2000 ∫ P dP = ∫ (100 − 12 0 x ) dx (P – 2000) = 25 × 100 – P = 3500.. 1]. 29-A. 0) 3⎞ ⎛ ⎜ −0. 2 x = x −3 4x = x2 – 6x + 9 x2 – 10x + 9 x = 9. 25 48. lim 45. x →0 (1 − cos 2x ) ( 3 + cos x ) x ( tan 4x ) 2 1 ⎛ sin x ⎞ 1 ⎛ 4x ⎞ lim 2 ⎜ ⎟ ⋅ ⎜ ⎟ ( 3 + cos x ) = 2 × 1× × 1× ( 3 + 1) = 2 . FIITJEE House. ⎟ ⎝ x⎠ 9 ⎡ 2 y ⎢ y + 3y − ⎥ = 9 + 9 – 9 = 9 3 ⎦0 ⎣ 3 ⎤3 44. then f′ (x) will change sign but f′(x) = 6x2 + 3 > 0 So no value of k exists.fiitjee. n +1 C3 − n C3 = 10 ⇒ nC2 = 10 ⇒ n = 5. x = 1 3 ∫ ( 2y + 3) − y 0 3 2⎤ ⎦ dy (3. I= π/6 π/3 ∫ 1+ dx tan x I= π/6 ∫ 1+ tan x tan x dx π 6 π I= . Ph 46106000. New Delhi -110016. Fax 26513942 website: www. 26569493. 46. x →0 4 ⎝ x ⎠ 4 ⎝ tan 4x ⎠ 47.

1 k 1 2 −k = 0 1 1 (1 + 2k) + 1 (1 + k2) − 1 (2 − k) = 0 k2 + 1 + 2k + 1 − 2 + k = 0 k2 + 3k = 0 (k) (k + 3) = 0 2 values of k. FIITJEE House.com. AM = AB + AC 2 ˆ ˆ AM = 4i − ˆ j + 4k AM = 16 + 16 + 1 = 33 A C M B 56. 29-A.. . 5 ( 3) ( 3) 3 FIITJEE Ltd. New Delhi -110016.fiitjee. 26569493. 28 − 8C0 − 8C1 − 8C2 = 256 − 1 − 8 − 28 = 219. P (correct answer) = 1/3 4 1 5 ⎛1⎞ ⎛ 2⎞ ⎛1⎞ 5 C 4 ⎜ ⎟ ⎜ ⎟ + 5 C5 ⎜ ⎟ ⎝ 3⎠ ⎝ 3⎠ ⎝ 3⎠ 5× 2 1 11 + 5 = 5 . 55. α = 11. For no solution k +1 8 4k … (1) = ≠ k k + 3 3k − 1 ⇒ (k + 1) (k + 3) − 8k = 0 or k2 − 4k + 3 = 0 ⇒ k = 1. y = sec (tan−1x) dy 1 = sec ( tan −1 x ) tan ( tan −1 x ) ⋅ dx 1+ x2 dy 1 1 = 2 × 1× = . A × B will have 8 elements. 54. equation (1) is not satisfied Hence k = 3. Sarvapriya Vihar. dx x =1 2 2 1 −1 − 1 51. 52. ⎡1 α 3⎤ ⎥ P= ⎢ ⎢1 3 3⎥ ⎢2 4 4⎥ ⎣ ⎦ 2 |Adj A| = |A| |Adj A| = 16 1 (12 − 12) − α (4 − 6) + 3 (4 − 6) = 16. 2α = 22. Fax 26513942 website: www.JEE(MAIN)2013-CMP-24 50. 3 But for k = 1. 53. Kalu Sarai. 2α − 6 = 16. Ph 46106000.

Kalu Sarai.com. . 26569493. 36 6 2 ⎛ ( x1/3 + 1)( x 2/3 − x1/3 + 1) 1 ⎜ − ⋅ 2/3 1/3 ⎜ x − x +1 x ⎜ ⎝ 59. Fax 26513942 website: www.. c ∈ R. = = 1 2 3 a : b : c = 1 : 2 : 3. FIITJEE House. ( x +1 ( x −1 ⎞ ⎟ ⎟ ⎟ x −1 ⎠ )( ) ) 10 = (x1/3 − x−1/2)10 Tr+1 = (− 1) 10 C4 = 210. r 10 Cr x 20 − 5r 6 ⇒r=4 FIITJEE Ltd. Sarvapriya Vihar. If one root is common then both roots are common a b c Hence. b. New Delhi -110016. Ph 46106000. 1 1+ z 1+ z 58. Since a. 60. |z| = 1 ⇒ zz = 1 1+ z 1+ z = =z. 29-A. 4x + 2y + 4z = 16 4x + 2y + 4z = − 5 21 21 7 dmin = = = .JEE(MAIN)2013-CMP-25 57.fiitjee. For equation x2 + 2x + 3 = 0 both roots are imaginary.

29-A.37 kHz 2πRC 2 × 3. 120 × 120 = 240Ω 60 120 × 120 Resistance of Heater = = 60Ω 240 Heater Resistance of bulb = 6Ω Bulb 120 Voltage across bulb before heater is switched on.04 (approximately) Note: Here supply voltage is taken as rated voltage..com. New Delhi -110016. 26569493.fiitjee.14 × 100 × 103 × 250 × 10−12 fC = cut off frequency As we know that fm fC ∴ (3) is correct Note: The maximum frequency of modulation must be less than fm. At equilibrium ΣF = 0 ⎛ AL ⎞ kx 0 + ⎜ σg ⎟ − Mg = 0 ⎝ 2 ⎠ LA σ⎤ ⎡ x 0 = Mg ⎢1 − 2M ⎥ ⎣ ⎦ Fnet = 2F cos θ kx0 Buoyant force Mg F F θ θ q/2 y q a a q 65. V1 = × 240 246 120 Voltage across bulb after heater is switched on. Fax 26513942 website: www. V2 = × 48 54 Decrease in the voltage is V1 − V2 = 10. de = B(ωx) ⋅ dx 2L x L ω FIITJEE Ltd. 120 V 64. FIITJEE House. where 1 − m2 m m ⇒ modulation index f m = fC 63. Ph 46106000. =2 ( k ⋅q ⋅q / 2 a 2 + y2 (y ) 2 ⋅ y a 2 + y2 = kq 2 y a3 a) 69. Kalu Sarai. 1 1 = = 6. .C: PHYSICS 61. Charge on the capacitor at any time ‘t’ is q = CV 1 − e− t / τ ( ) at t = 2τ q = CV 1 − e−2 fC = ( ) 62.JEE(MAIN)2013-CMP-26 PART . Sarvapriya Vihar.

1 2 1 2 T Aρ stress 1 2.2 × 1011 × 10−2 . R= ρL R 73. x=t y = 2t − 5t 2 Equation of trajectory is y = 2 x − 5 x 2 FIITJEE Ltd.7 × 103 Ig G For Ammeter. S = I − Ig So for I to increase. FIITJEE House. 1 q2 =F 4πε0 r 2 ε0= [A 2 T 2 ] [MLT −2 L2 ] = [M −1L−3 A 2 T 4 ] 74. Ph 46106000. S should decrease. ρ4πR2∆RL = T 4π[R2 – (R .JEE(MAIN)2013-CMP-27 e = Bω ∫ xdx 2L 3L 70.fiitjee. Ef = − GMm 6R GMm T.5 7.. Fundamental frequency f = 1 2 T µ = = 76. 29-A. Heat is extracted from the source in path DA and AB is 3 ⎛ P V ⎞ 5 ⎛ 2P V ⎞ 13 P0 V0 ∆Q = R ⎜ 0 0 ⎟ + R ⎜ 0 0 ⎟ = 2 ⎝ R ⎠ 2 ⎝ R ⎠ 2 75. Ei = − R 5GMm 6R ∆W = T.Ef – T. New Delhi -110016.com. Fax 26513942 website: www. Kalu Sarai. 26569493. so additional S can be connected across it. .Ei = 78. 5BωL2 2 ⎡ 1 1⎤ ν∝⎢ − 2⎥ 2 n ⎦ ⎣ (n − 1) (2n − 1) ∝ 2 n (n − 1) 2 = ∝ 1 n3 (since n 1) 71. = ρ 2 × 1. Sarvapriya Vihar. 77 T.∆R)2] ρR2∆RL = T[R2 – R2 + 2R∆R .∆R2] ρR2∆RL = T2R∆R (∆R is very small) 2T .

Patm A P0 A mg FBD of piston at equilibrium ⇒ Patm A + mg = P0 A Patm A .com.... 3 me get f = 1 2π A2γ P0 MV0 82. Fax 26513942 website: www.(1) (P0 + dP) A mg FBD of piston when piston is pushed down a distance x d2x Patm + mg – (P0 +dP) A = m 2 . Sarvapriya Vihar. O x dx V =∫ x=2 L x= L k ⎛Q⎞ Q ln 2 ⎜ ⎟ dx = x⎝ L⎠ 4πε 0 L 83. 2 1 r R d Let M12 be the coefficient of mutual induction between loops φ1 = M 12 i2 ⇒ µ0 i2 R 2 2(d 2 + R 2 )3/2 π r 2 = M12 i2 FIITJEE Ltd... 120C1 = 200C2 6C1 = 10C2 3C1 = 5C2 From conservation of angular momentum about any fix point on the surface mr 2ω0 = 2mr 2ω ∴ ω= 80. 2. 29-A.JEE(MAIN)2013-CMP-28 79. New Delhi -110016.(2) dt γ PdV Process is adiabatic ⇒ PV γ = C ⇒ − dP = V Using 1. Ph 46106000. . Kalu Sarai. 26569493. ω0 2 ∴ VCM = ω0 r 2 81. FIITJEE House.fiitjee.

29-A. 86.9 A0 = A0 e−5k and α A0 = A0 e−15k solving ⇒ α = 0.JEE(MAIN)2013-CMP-29 ⇒ M12 = µ 0 R 2π r 2 2(d 2 + R 2 )3/2 φ2 = M 12 i1 ⇒ φ2 = 9. Ph 46106000. New Delhi -110016. 87. Kalu Sarai. intensity increases with voltage. The temperature goes on decreasing with time (non-linearly) The rate of decrease will be more initially which is depicted in the second graph. Fax 26513942 website: www. R d t R-t R 2 = d 2 + ( R − t )2 ⎧ t⎫ R 2 − d 2 = R 2 ⎨1 − ⎬ ⎩ R⎭ 2 d 2t 1− 2 = 1− R R (3) 2 90 R= = = 15 cm 2 × (0 ⋅ 3) 6 ⎛ 1 1 1 ⎞ = ( µ − 1) ⎜ − ⎟ f ⎝ R1 R2 ⎠ 1 ⎛ 3 ⎞⎛ 1 ⎞ = ⎜ − 1⎟ ⎜ ⎟ f ⎝ 2 ⎠ ⎝ 15 ⎠ f = 30 cm FIITJEE Ltd. 1 ⎛ Mm ⎞ 2 KE in COM frame is ⎜ ⎟ Vrel 2⎝ M +m⎠ 1 ⎛ Mm ⎞ 2 KEi = ⎜ KE f = 0 (∵ Vrel = 0 ) ⎟V 2⎝ M +m⎠ 1 ⎛ Mm ⎞ 2 Hence loss in energy is ⎜ ⎟V 2⎝ M +m⎠ M ⇒ f = M +m 85. A = A0 e− kt ⇒ 0. Loss of energy is maximum when collision is inelastic as in an inelastic collision there will be maximum deformation. FIITJEE House..com.729 88.1×10−11 weber 84. 26569493. For LED. in forward bias. Sarvapriya Vihar. 2 .fiitjee.

New Delhi -110016. Fax 26513942 website: www. Kalu Sarai.6 × 10−5 10 = 2. Ph 46106000. . 29-A.JEE(MAIN)2013-CMP-30 89. 26569493. Sarvapriya Vihar.. FIITJEE House. Ε0 = CB0 = 3 × 108 × 20 × 10–9 = 6 V/m 90. Bnet = BM1 + BM 2 + BH = µ0 M 1 µ0 M 2 + + BH 4π x3 4π x 3 µ = 0 3 ( M 1 + M 2 ) + BH 4π x 10−7 = −3 × 2.56 × 10−4 Wb/m2 ***** FIITJEE Ltd.com.fiitjee.2 + 3.