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21 views5 pagesCrystal Structures

Sep 12, 2013

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Crystal Structures

Attribution Non-Commercial (BY-NC)

21 views

Crystal Structures

Attribution Non-Commercial (BY-NC)

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Outline:

Atomic Densities - Linear Density - Planar Density Single- vs poly- crystalline materials X-ray Diffraction Example Polymorphism and Allotropy

Linear Density

Number of atoms per length whose centers lie on the direction vector for a specific crystallographic direction.

Planar Density

Number of atoms per unit area that are centered on a particular crystallographic plane.

Dr. M. Medraj

Dr. M. Medraj

Linear Density

Calculate the linear density of the [100] direction for the FCC crystal

LD = n/LL n=1 LL = a linear density atoms line length

Planar Density

Calculate the planar density of the (110) plane for the FCC crystal

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

Dr. M. Medraj

Planar Density

Plane area AP = (AC)(AD) AC = . AD = .. AP =

Why do we care? Properties, in general, depend on linear and planar density. Examples:

Speed of sound along directions Slip (deformation in metals) depends on linear and planar density Slip occurs on planes that have the greatest density of atoms in direction with highest density

we would say along closest packed directions on the closest packed planes

Mech 221 lecture 6/5

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

Number of atoms = ..

PD =

Dr. M. Medraj

n = . AP

Mech. Eng. Dept. - Concordia University

Some engineering applications require single crystals:

Turbine blades Nickel alloy single crystal to improve high temp. mechanical properties

Single crystal

(Courtesy P.M. Anderson) Fig. 8.30(c), Callister 6e. ( courtesy of Pratt and Whitney)

Single Vs Polycrystals

Single Crystals

-Properties vary with direction: anisotropic. -Example: the modulus of elasticity (E) in BCC iron:

E (diagonal) = 273 GPa

(Courtesy GE Superabrasives)

Polycrystals

- Properties may/may not vary with direction. - If grains are randomly oriented: isotropic.

(Epoly iron = 210 GPa)

200 m Adapted from Fig. 4.12(b), Callister 6e.

- Each "grain" is a single crystal. - If crystals are randomly oriented, overall component properties are not directional. 1 mm - Crystal sizes typ. range from 1 nm to 2 cm (i.e., from a few to millions of atomic layers).

Nb-Hf-W plate with an electron beam weld

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

Mech 221 lecture 6/7

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

Textured grains

X-Ray Diffraction

Can be used to determine crystal structure

identify unknown materials measure lattice parameters

2D

Inter-planar spacing

The inter-planar spacing in a particular direction is the distance between equivalent planes of atoms

X-rays are a form of electromagnetic radiation that have high energies and short wavelengths. Diffraction occurs whenever a wave encounters a series of regularly spaced obstacles that;

Can scatter the wave Have a spacing comparable to the wavelength

The existence of, and distances between sets of of planes in a material is characteristic for each material Inter-planar spacings are measured by x-ray diffraction to identify unknown materials!

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

X-ray wavelength () ~ inter-atomic spacing. Other techniques such as neutron or electron diffraction, also, can be used.

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

X-ray Diffractometer

R

Detector Crystal

Specimen

Dr. M. Medraj

Dr. M. Medraj

Braggs Law

X-ray Source: Monochromatic and in-phase

Braggs Law

The law: For constructive interference, the additional path length SQ+QT must be an integer number of wavelengths (). n= SQ + QT = dhklsin+ dhklsin= 2 dhklsin n = 1,2,3order of reflection

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

we have a simple expression relating the x-ray wavelength and interatomic spacing to the angle of the diffracted beam. If Braggs law is not satisfied, then the interference will be nonconstructive in nature so as to yield a very lowintensity diffracted beam. Magnitude of difference between two adjacent and parallel planes of atoms is function of Miller Indices and the lattice parameter. For cubic symmetry:

Dr. M. Medraj

Diffractometer Technique

Use powder (or polycrystalline) sample to guarantee some particles will be oriented properly such that every possible set of crystallographic planes will be available for diffraction.

Example

For BCC Fe, compute (a) the interplanar spacing and, (b) the diffraction angle for (220) set of planes. The lattice parameter for Fe is 0.2866 nm

the wavelength used is 0.1790 nm First order reflection.

dhkl

a h2 + k2 + l2 n 2 dhkl = .

Mech. Eng. Dept. - Concordia University

Each material has a unique set of planar distances and extinctions, making X-ray diffraction useful in analysis of an unknown material.

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

sin

=

Dr. M. Medraj

X-Ray Diffraction

The results of a x-ray diffraction experiment using x-rays with = 0.7107 (a radiation obtained from molybdenum (Mo) target) show that diffracted peaks occur at the following 2 angles:

Determine 1) the crystal structure, 2) the indices of the plane producing each peak, and 3) the lattice parameter of the material.

Solution:

To identify the crystal structure of a material having cubic crystal system (SC, BCC or FCC). You need to look at the values of h2+k2+l2 for the different peaks. If these values form a pattern of 1,2,3,4,5,6,8,.. (note 7 is missing) the structure is SC. In BCC, diffraction only occurs from planes having an even h2+k2+l2 sum of 2, 4, 6, 8, 10, 12, 14,.....etc. For FCC metals, however, more destructive interference occurs, and planes having h2+k2+l2 sums of 3, 4, 8, 11, 12, 16, ...etc. will diffract.

Dr. M. Medraj Mech. Eng. Dept. - Concordia University

d 400

2 sin

2

2 2

a0 d 400 h k l

Dr. M. Medraj

(0.71699)(4) 2.868

Mech. Eng. Dept. - Concordia University

Some materials may have more than one crystal structure depending on temperature and pressure - called POLYMORPHISM Carbon

graphite diamond

Next time:

Imperfections in Solids

Dr. M. Medraj

Dr. M. Medraj

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