Solutions Code – AC204

SECTION – I (1) (a) AgCl(s) +e- → (Ag(s) + ClΕ° = 0.22V Cl2 + e- → ClΕ° = 1.36V Wt get Ag(s) + Cl2(g) → AgCl(s) Ε° Cell = 1.44V ∴ by = = = Ε° F -(1) 96500 x 1.4 -110 kJ/mol.

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NOIDA.(2) (b) + OMe + O OMe + OH O MeO H⊕ O MeO MeO (3) Sol.+ 16N+ 2Cl. (a)s From salts of magnesium.204 .→ Mg at as ode :.Mg2+ + 2e.2Cl.→ 2 Mn2+ + Cl2 + 8N2O (a) Ph – c cn excess (5) (6) Ph—C CHCl2 || Trans Web Educational Services Pvt. UP-201301 Website:www.com Tel:0120-4616500 Ext .→ Cl2 + 2e- (4) (c) Based on theory (a) 2 M O4. Ltd B – 147. info@askiitians. magnesium cannot be extracted by other chemical methods as magnesium itself acts as a reducing agent and Mg obtained at cathode during electrotypes of its salt solution reacts with water forming Mg MgCl2 Mg2+ + 2Clat cathode :.askiitians.1st Floor.com Email. Sec-6.

askiitians. Sec-6.NOIDA.1st Floor. b. (a. (d) – tetrahedral. (a.1 x 10-11 = (1. UP-201301 Website:www. CO stronger legend so pairing of electrons occurs. (3) Sol. c. Ltd B – 147.4 x 10-4)x+y so we have. = = Hence. d) A(g) → t=0 400 2B(g) 0 + C(g) 0 Trans Web Educational Services Pvt.O ↓NaOH Ph–C–CH || || O O Internal cannizaro OH(-) H I Ph — C — CO– | || OH O (±) SECTION – II (1) Sol. c) a. info@askiitians. (by comparing values) so. b. (a. b) Ksp = 1.com Tel:0120-4616500 Ext . b and c are correctly method.204 .com Email. =4 (2) Sol.

t=20 400-P Given.0693 min-1 400 200 100 50 ← 10 min →← 10 min →← 10 min → After After After After (4) 30 30 30 30 min min min min partial pressure of A is 50 mm partial pressure of B is 700 mm partial pressure of C is 350 mm total pressure becomes 1150 mm (a.204 .askiitians. UP-201301 Website:www.NOIDA.com Tel:0120-4616500 Ext .com Email. Ltd B – 147. 2P P 400 – P + 2P + P = 1000 400 + 2P = 1000 P = 300mm k= k= min-1 = 4 T½ = 10 min Value of k = 0. Sec-6. d) SECTION – III (1) (2) (c) (a) Trans Web Educational Services Pvt.1st Floor. info@askiitians.

(a) pOH of the buffer = .602 → (3) NH4Cl + NaOH [Salt] = + + NaCl + OH- 0.04 M -log 1. info@askiitians.com Email.com Tel:0120-4616500 Ext . Potassium and cesium have low ionization energies and.log Kb + log = ∴ NH3 + HCl → NH4Cl [Salt] = [Base] = 0. UP-201301 Website:www.25 – 8. therefore.NOIDA.352 = 8.06 = 0.602 = 5. (b) (c) (3) (4) SECTION – IV Paragraph: (1) Sol.204 .1st Floor.16 M1 0. Ltd B – 147.75 + 0. Sec-6.1 – 0.1 + 0.8 x 10-5 + log (2) = log Kb + log = 4.askiitians.352 = 14 – 5.06 = 0.648 = 0.06 = 0.1 – 0.04M Trans Web Educational Services Pvt. their valence shell electrons can be easily eject off by the energy of light.Sol.648 = 9.

06 = 0.25 = 0.148 = 14 – 4.[Base]= 0. Sec-6.log Kb + log = 4.NOIDA. Both oxidation and reduction takes place in the same molecule. Ltd B – 147.com Email. (c) In Cannizaro reaction. UP-201301 Website:www. NaOH Ph —CH—COONa  OH Trans Web Educational Services Pvt.148 = 9.com Tel:0120-4616500 Ext .1st Floor.602 Paragraph: (1) Sol.852 = 9.askiitians.16M = .204 . —C—CHO  O Conc. info@askiitians.852 – 9. the best hydride donor is H C O– O – CH3 — This reaction is intermolecular Cannizaro reaction.1 + 0.75 + log ¼ = 4.

O O One equivalent CHO O—CH2  CH O—CH2 (X) CH3OH NaBH4 H OH H OH CHO (Z) Paragraph: (1) (2) (3) (b) (d) From the graph From the graph The slope of the line shown in graph.(3) (b) Aldehyde is more reactive than kete group.askiitians. Ltd B – 147. Sec-6. info@askiitians.1st Floor.com Tel:0120-4616500 Ext .com Email.204 . acetal formation takes place with aldehyde group only. Hence with one equivalent of glycol. UP-201301 Website:www.NOIDA. (Y) CH O—CH2  O—CH2 Trans Web Educational Services Pvt.

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