2-1

Corrosion
Chemical ReactionElectrochemical Reaction
Rust
1.
H2O
H2OH2OH2O2HOH
HOHHOHHFe
Fe(OH)2
Fe2HOHH2Fe(OH)2
H2HOH
O2H2OHOH
2 H2O22 H2O
FeOH2O2
Fe(OH)3
2 Fe(OH)21/2 O2H2O2 Fe(OH)3Fe2O33H2O

2 Fe4 HOH2 H22 Fe(OH)2

2H2OH2O
2 H2O22 H2O
2 Fe(OH)21/2 O2m H2OFe2O3n H2O2 H2O
2 Fe3/2 O2m H2OFe2O3n H2Onm2

2.
2-1

Fe++Ferrous Ion
Cathode
AnodeeElectron

OH-Fe(OH)2
Fe(OH)3
2-2

3.
Mill Scale 900

2-3


FeOFe(OH)3
Fe(OH)3FeO 5

2-4

4. Uniform attackLocaal Corrosion

2-5

2-5

3-1 ( 3-1)
Sa 2 St 2
3-1

3-1

100
80
60

Sa 2 1/2

6.3

49.5

40

26.5

19.1

20
0

4.9

St 2

4.6
1.2

(Shop Primer)

3-1
1.

2.
4070

3.

4.
1015% 5065 1520% 0.10.5%
2030

6065
8090 2%
5.
1520%

6.
6mm

3-2
1.
1640mesh

2.
()

3.
()

4.

5.

6.

7.

SIS Swedish Corrosion Institute ASTM

American Society for Testing and Materials SSPCSteel Structures Paining Council

4-1.
SIS-05-5900
ABCD
A ( A)
B ( B)
C ( C)
D ( D)

4-2.
SIS
St--

Sa--

0-

2 -

1-

3-

2-

SIS 05 5900
A.
St 0-
St 1-
St 2-
SIS St 2

St 3-
SIS St 3

B --SIS St 2

B --SIS St 3

B.
Sa 0-

Sa 1-

SIS Sa 1

Sa 2-

SIS Sa 2

Sa 2 -

Near White Metal

SIS Sa2

Sa 3-

White Metal SIS Sa 3

B --SIS Sa 1

B --SIS Sa 2

B -- Sa 2

B -- Sa 3

4-3. SIS SSPC

SIS
SSPC
Swedish Standard
SIS 05 5900
A Sa 3

B Sa 3

C Sa 3

D Sa 3

A Sa 2 B Sa 2 C Sa 2 D Sa 2

SSPC-USA
Standard

British Standard
BS 4232

SSPC-SP-5
White Metal

First Quality

SSPC-SP-10
Near White

Second Quality

Entrostungsgrad 2

SSPC-SP-6
Commercial

Third Quality

Entrostungsgrad 3

B Sa 2

C Sa 2

D Sa 2

B Sa 1

C sa 1

D Sa 1

B St 3

C St 3

D St 3

SSPC-SP-3
Power Tool Cleaning

B St 2

C St 2

D St 2

SSPC-SP-2
Hand Tool Cleaning

German Standard
DIN 18364

SSPC-SP-7
Light Blast / Brush Off

SSPC 16 mesh

 51

Rmax

Grit G-50

25 mesh

80m

G-40

18 mesh

90m

G-25

16 mesh

100m

G-16

12 mesh

200m

Shot S-230

18 mesh

70m

S-330

16 mesh

80m

S-390

14 mesh

90m

Sand

40 mesh

50m

18 mesh

60m

12 mesh

70m

Disc Sander

15m

10m

Pickling

5m

80 psi

5/16

5-1.

1.

ASTM

B-64

BS

1134

DIN

4762

JIS

B-0651

2.

3.

6-1.

6-1

6-2

1952 Dr. M. Kronstein

Rmax
Rmax 3
6-1 125m 1971
Dr. T. R. Bullet
6-3
3550m
6-1 Rmax

 6-1 (Shot)

(Rmax)

mesh

mm

cm3/M2

85

0.24

22

119

20

52

0.33

25

124

23

44

0.39

30

128

24

36

0.46

35

133

27

30

0.55

45

140

31

25

0.65

50

144

33

22

0.78

55

153

36

18

0.93

70

160

51

16

1.10

80

163

54

6-2.

6-2-1

1.

6-2-2

1.
()

2.
3
4 34 M2

3.

90
10

1Volume Solids2Weiht Silids

7-1

7-1.

7-1

Volume Solids10

M2 / L / DFTm

D.F.T.m

L / M2 / DFTm

D.F.T.m
Volume Solids10

Wet Flim ThicknessDry Flim Thickness

Volume Solids

Volume Solids

W. F. T.m

D. F. T.m

D.F.T.m100
W. F. T.m

D.F.T.m100
Volume Solids
Volume Solids
W. F. T.m

100

 7-1
VOLUME
SOLIDS

(m)

15
20
25
30
40
50

15

20

25

30

35

40

45

50

MLiter
LiterM
26.7
30.0
33.3
(0.04) (0.03) (0.03)
20.0
22.5
25.0
(0.05) (0.05) (0.04)
16.0
18.0
20.0
(0.06) (0.06) (0.05)
13.3
15.0
16.7
(0.08) (0.07) (0.06)
10.0
11.2
12.5
(0.10) (0.09) (0.08)
8.0
9.0
10.0
(0.13) (0.11) (0.10)
6.7
7.5
8.3
(0.15) (0.13) (0.12)
5.7
6.4
7.1
(0.18) (0.16) (0.14)
5.0
5.6
6.2
(0.20) (0.18) (0.16)
4.0
4.5
5.0
(0.25) (0.22) (0.20)
3.2
3.6
4.0
(0.31) (0.28) (0.25)
2.7
3.0
3.3
(0.37) (0.33) (0.30)
2.5
(0.40)
2.0
(0.50)

60

70

80

40.0
(0.03)
30.0
(0.03)
24.0
(0.04)
20.0
(0.05)
15.0
(0.07)
12.0
(0.08)
10.0
(0.10)
8.6
(0.12)
7.5
(0.13)
6.0
(0.17)
4.8
(0.21)
4.0
(0.25)
3.0
(0.33)
2.4
(0.42)

46.7
(0.02)
35.0
(0.03)
28.0
(0.04)
23.3
(0.04)
17.5
(0.06)
14.0
(0.07)
11.7
(0.09)
10.0
(0.10)
8.7
(0.12)
7.0
(0.14)
5.6
(0.18)
4.7
(0.21)
3.5
(0.29)
2.8
(0.36)

53.3
(0.02)
40.0
(0.03)
32.0
(0.03)
26.7
(0.04)
20.0
(0.05)
16.0
(0.06)
13.3
(0.08)
11.4
(0.09)
10.0
(0.10)
8.0
(0.13)
6.4
(0.16)
5.3
(0.19)
4.0
(0.25)
3.2
(0.31)

10.0
(0.10)
7.5
(0.13)
6.0
(0.17)
5.0
(0.20)
3.8
(0.26)
3.0
(0.33)

60
70
80
100
125
150
200
250

13.3
(0.08)
10.0
(0.10)
8.0
0.13
6.7
(0.15)
5.0
(0.20)
4.0
(0.25)
3.3
(0.30)
2.9
(0.35)
2.5
(0.40)
2.0
(0.50)
1.6
(0.63)
1.3
(0.77)

16.7
(0.06)
12.5
(0.08)
10.0
(0.10)
8.3
(0.12)
6.2
(0.16)
5.0
(0.20)
4.2
(0.24)
3.6
(0.28)
3.1
(0.32)
2.5
(0.40)
2.0
(0.50)
1.7
(0.59)

20.0
(0.05)
15.0
(0.07)
12.0
(0.08)
10.0
(0.10)
7.5
(0.13)
6.0
(0.17)
5.0
(0.20)
4.3
(0.23)
3.8
(0.26)
3.0
(0.33)
2.4
(0.42)
2.0
(0.50)

23.3
(0.04)
17.5
(0.06)
14.0
(0.07)
11.7
(0.09)
8.7
(0.12)
7.0
(0.14)
5.8
(0.17)
5.0
(0.20)
4.4
(0.23)
3.5
(0.29)
2.8
(0.36)
2.3
(0.44)

7-2.

1.

A
BC

2.
(Airless Spray)

3.

4.

(Pot Life)

5.
90
90
90 80

90

120135

2035

80

105115

515

6.

7-3.

Q=

10AT
VS x100W
Q = Liters
T D.F.T.m
A M2

VS Volume Solids
W Wastage 3040

Pinhole

ABS PS
PP FRP

10

Boiled Oil
Varnish
Ready Mixed Paint
Enamel Paint

Shellac Varnish

Copal Varnish

Bituminous Solution

NC Lacquer

Acrylic Lacquer

Acetyl Cellulose Lacquer

Ethyl Cellulose Lacquer

Emulsion paint

Water Soluble Paint

Alkyd Coating

Phenolic Coating
Melamine
Coating

Urea Coating
Vinyl

FRP

Coating

Polyester
Coating

Epoxy Coating
Silicon Coating

CR Coating
Powder Coating
Inorganic Coating

Urushiol Coating

Cashew Coating

Polyurethane Coating

SIS
Sa2
SSPC
SP-6

SIS
Sa2
SSPC
SP-10

SIS
Sa3
SSPC
SP-5

SSPC
SP-8

SIS
St2
SSPC
SP-2

SIS
St3
SSPC
SP-3

SIS
St1
SSPC
SP-2

12-1.

X
12-2.

St2-St3

St2-St3

St3

St3

St3

Sa 2

SIS Sa 2SSPC-SP-10

12-3.

RH%

535

85

535

85

1035

80

1035

80

1035

80

535

80

1035

80

535

80

535

85

1035

85

535

80

535

80

1.

2.

3.

4.

5.

6.
5 85RH%

7.

8.

9.

10.

5%

Gelation

Thixtoropic

Settling

Skinning

()

Orange
Peeling

Cissing

Bubling

Cobwebbing

Sagging

()

Brush
Mark

Blushing

Bleeding

Lifting

W/P

Flocculation

()

Sandy

Delaying of
Drying Time

Aftertack

Pinholing

()

Yellowing

Discoloration

Cracking

Checking

Cracking

Blooming

Chalking

Wrinkling

()

Clouding

Gloss
Shitting

Blistering

Rusting

Lifting
(Scaling)

W/P