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Chemwatch MSDS

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CITADEL DIAMOND WRAP STANDARD PRIMER RESIN
Chemwatch Material Safety Data Sheet Jun-2-2009 C!293TC CHEMWATCH 15-9237 Version No:2.0

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME CITADEL DIAMOND WRAP STANDARD PRIMER RESIN STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. NFPA

SUPPLIER Chemwatch Pty Ltd +61 3 9573 3112 or (where available) Toll Free +800 2436 2255 Email chemwatch@chemwatch.net Email: chemwatch@chemwatch.net PRODUCT USE » Used according to manufacturer's directions. SYNONYMS "Bisphenol A Epoxy Resin Compound"

Section 2 - HAZARDS IDENTIFICATION
CHEMWATCH HAZARD RATINGS Flammability 1 Toxicity 2 Body Contact 2 Reactivity 1 Chronic 2 SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4 CANADIAN WHMIS SYMBOLS

EMERGENCY OVERVIEW RISK May cause SENSITISATION by skin contact. Irritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED » Although ingestion is not thought to produce harmful effects, the material may still be damaging to the health of the individual following ingestion, especially where pre-existing organ (e.g. liver, kidney) damage is evident. <\p>. EYE » This material can cause eye irritation and damage in some persons. SKIN » Skin contact is not thought to have harmful health effects, however the material may still produce health damage following entry through wounds, lesions or abrasions. INHALED » The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. CHRONIC HEALTH EFFECTS » Skin contact with the material is more likely to cause a sensitization reaction in some persons compared to the general population. Sensitization may give severe responses to very low levels of exposure, i.e. hypersensitivity. <\p>.

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME bisphenol A/ epichlorohydrin resin, liquid (C12- 14)alkylglycidyl ether additives CAS RN 25068-38-6 68609-97-2 % >60 <16 <10

Section 4 - FIRST AID MEASURES
SWALLOWED

file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re... 2/26/2010

STORAGE REQUIREMENTS · Store in original containers. Personal Protective Equipment Gas tight chemical resistant suit. Combustion products include: carbon dioxide (CO2). · Clean up all spills immediately.. May emit poisonous fumes. · Chemical goggles. · Clear area of personnel and move upwind. · Remove all ignition sources. · Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re. · Keep containers securely sealed. lean patient forward or place on left side (head-down position. · If vomiting occurs. · Dry chemical powder.contain spillage. INHALED · If fumes or combustion products are inhaled remove from contaminated area.HANDLING AND STORAGE PROCEDURE FOR HANDLING · DO NOT allow clothing wet with material to stay in contact with skin. · Wear protective clothing when risk of exposure occurs. liquid: • (C12-14)alkylglycidyl ether: CAS:25068-38-6 CAS:25085-99-8 CAS:68609-97-2 PERSONAL PROTECTION RESPIRATOR Type A-P Filter of sufficient capacity Consult your EHS staff for recommendations EYE · Safety glasses with side shields. · No smoking. 2/26/2010 . including footwear · Flush skin and hair with running water (and soap if available). if possible) to maintain open airway and prevent aspiration. Section 8 . oxidizing acids. Moderate hazard. nitrates. SKIN » If skin contact occurs: · Immediately remove all contaminated clothing.ACCIDENTAL RELEASE MEASURES MINOR SPILLS » Environmental hazard . MAJOR SPILLS » Environmental hazard . Section 5 . naked lights or ignition sources.contain spillage. · Store away from incompatible materials and foodstuff containers. · Observe manufacturer's storing and handling recommendations. · Protect containers against physical damage and check regularly for leaks. dry.e. EYE » If this product comes in contact with the eyes: · Immediately hold eyelids apart and flush the eye continuously with running water. · Store in a cool. FIRE FIGHTING · Alert Emergency Responders and tell them location and nature of hazard.Chemwatch MSDS Page 2 of 5 · If swallowed do NOT induce vomiting. including inhalation. other pyrolysis products typical of burning organic material. · Lay patient down. · Wear breathing apparatus plus protective gloves.chlorine bleaches. RECOMMENDED STORAGE METHODS · Metal can or drum · Packing as recommended by manufacturer.FIRE FIGHTING MEASURES Flash Point (ºF): >199. · Alert Emergency Responders and tell them location and nature of hazard. · Avoid all personal contact.. · Slight fire hazard when exposed to heat or flame. NOTES TO PHYSICIAN » Treat symptomatically. GENERAL FIRE HAZARDS/HAZARDOUS COMBUSTIBLE PRODUCTS · Combustible. Section 6 .EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS • bisphenol A/ epichlorohydrin resin. FIRE INCOMPATIBILITY » Avoid contamination with oxidizing agents i. as ignition may result. well-ventilated area.4 Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available Autoignition Temp (ºF): Not Available EXTINGUISHING MEDIA · Foam. Section 7 . pool chlorine etc. Keep warm and rested.

Molecular Weight: Not Applicable Melting Range (ºF): Not Available Solubility in water (g/L): Immiscible pH (1% solution): Not Applicable Volatile Component (%vol): <0. · Eye wash unit. Care must be taken. Refer to individual constituents.CHEMICAL STABILITY AND REACTIVITY INFORMATION CONDITIONS CONTRIBUTING TO INSTABILITY · Presence of incompatible materials. eg. when removing gloves and other protective equipment. Section 11 . This material and its container must be disposed of as hazardous waste.4 Upper Explosive Limit (%): Not Available Decomposition Temp (ºF): Not Available Viscosity: Not Available APPEARANCE Dark translucent viscous liquid with mild acrylate odour. Refer to individual constituents. LIQUID: » None assigned. OTHER · Overalls.g nitrile or nitrile-butatoluene rubber).. to avoid all possible skin contact. Sinks in water. BISPHENOL A/ EPICHLOROHYDRIN RESIN. Section 10 .sensitiser Eye (rabbit): Mild [Ciba] Skin : Moderate » Contact allergies quickly manifest themselves as contact eczema.ECOLOGICAL INFORMATION Toxic to aquatic organisms. Avoid reaction with amines. · Barrier cream. <\p>. apron. 2/26/2010 . may cause long-term adverse effects in the aquatic environment. rubber or polyethylene gloves (which absorb the resin). STORAGE INCOMPATIBILITY » Avoid cross contamination between the two liquid parts of product (kit). does not mix with water. data presented he for 1. (C12-14)ALKYLGLYCIDYL ETHER: » unless otherwise specified data extracted from RTECS . polymerization with gelation and evolution of heat (exotherm) may occur. strong acids and oxidizing agents. ENGINEERING CONTROLS » General exhaust is adequate under normal operating conditions. Oxiranes (including glycidyl ethers and alkyl oxides. silicone-based barrier creams should be reviewed prior to use.20 pH (as supplied): Not Applicable Vapour Pressure (mmHG): Negligible Evaporation Rate: <1 BuAC = 1 Flash Point (ºF): >199.TOXICOLOGICAL INFORMATION Citadel Diamond Wrap Standard Primer Resin TOXICITY AND IRRITATION » Not available. polyvinyl chloride. Does not mix with water.Register of Toxic Effects of Chemical Substances. If two part products are mixed or allowed to mix in proportions other than manufacturer's recommendation. Significant increases in nasal papillary adenomas and combined alve Section 12 . <\p>. Wear chemical protective gloves. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes <\p>. and epoxides) exhibit many common characteristics with respect to animal toxicology. NOTE: The material may produce skin sensitization in predisposed individuals.. Section 9 . mercaptans. For incompatible materials . Avoid release to the environment.C. · Product is considered stable. boots and aprons. One such oxirane is ethyloxirane. Refer to special instructions/ safety data sheets.PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL PROPERTIES Liquid. · DO NOT use barrier creams containing emulsified fats and oils as these may absorb the resin. · Skin cleansing cream. store and attach MSDS together. Ecotoxicity Ingredient Citadel Diamond Wrap Standard Primer Resin bisphenol A/ Persistence: Water/Soil Persistence: Air No data Bioaccumulation Mobility file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re. more rarely as urticaria or Quincke's edema.2-butylene oxide (ethyloxirane): Ethyloxirane increased the incidence of tumours of the respiratory system in male and female rats exposed via inhalation. · DO NOT use cotton or leather (which absorb and concentrate the resin). TOXICITY Oral (rat) LD50: 17000 mg/kg Oral (rat) LD50: >10000 mg/kg IRRITATION Skin (rabbit): Moderate Skin (human): Irritant Skin (guinea pig): sensitiser Skin (human): non.5 Relative Vapor Density (air=1): >1 Lower Explosive Limit (%): Not Available Autoignition Temp (ºF): Not Available State: Liquid Boiling Range (ºF): Not Available Specific Gravity (water=1): 1.Chemwatch MSDS Page 3 of 5 HANDS/FEET · When handling liquid-grade epoxy resins wear chemically protective gloves (e. Local exhaust ventilation may be required in specific circumstances.V. Refer also to protective measures for the other component used with the product.refer to Section 7 . PVC. · P. Read both MSDS before using.Handling and Storage.

liquid. liquid (CAS: 25085-99-8) is found on the following regulatory lists. state and federal regulations. LIQUID. 146. liquid (C1214) alkylglycidyl ether HIGH No data No data LOW HIGH Section 13 . Canada Toxicological Index Service .DISPOSAL CONSIDERATIONS Disposal Instructions All waste must be handled in accordance with local.Workplace Hazardous Materials Information System .. · Consult Waste Management Authority for disposal. IB3. *(CONTAINS BISPHENOL A/ EPICHLOROHYDRIN RESIN.Minnesota Hazardous Substance List US EPA High Production Volume Program Chemical List US EPA Master Testing List .Substances for Use Only as Components of Adhesives .Workplace Hazardous Materials Information System . * (limited evidence). » Possible respiratory sensitizer*. LIQUID.Minnesota Hazardous Substance List US DOE Temporary Emergency Exposure Limits (TEELs) US FDA Indirect Food Additives: Adhesives and Components of Coatings .Sunset Date/Status US TSCA Section 8 (d) .Chemicals Subject to Testing Consent Orders US TSCA Section 4/12 (b) . N.Inventory US TSCA Section 8 (d) . Canada Domestic Substances List (DSL) OECD Representative List of High Production Volume (HPV) Chemicals US . N. · Recycle wherever possible or consult manufacturer for recycling options.REGULATORY INFORMATION REGULATIONS Citadel Diamond Wrap Standard Primer Resin (CAS: None): No regulations applicable Regulations for ingredients bisphenol A/ epichlorohydrin resin.Minnesota Hazardous Substance List US Toxic Substances Control Act (TSCA) .Index I Chemicals Listed US Toxic Substances Control Act (TSCA) .OTHER INFORMATION LIMITED EVIDENCE » Ingestion may produce health damage*. liquid (CAS: 25068-38-6) is found on the following regulatory lists. » Cumulative effects may result following exposure*. OECD Representative List of High Production Volume (HPV) Chemicals US . T4. liquid (C12-14)alkylglycidyl ether) ICAO/IATA Subrisk: Packing Group: None III IMDG Subrisk: Packing Group: Special provisions: Marine Pollutant: None III 274 909 944 Not Determined Section 15 . TP29 241 No limit A Air Transport IATA: ICAO/IATA Class: 9 UN/ID Number: 3082 A97 Special provisions: Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE.Chemwatch MSDS Page 4 of 5 epichlorohydrin resin.S.S-F Limited Quantities: 5L Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE.S. TP1. » May possibly affect fertility*.Health and Safety Data Reporting Section 16 . LIQUID (C12-14)ALKYLGLYCIDYL ETHER) Maritime Transport IMDG: IMDG Class: 9 UN Number: 3082 EMS Number: F-A.WHMIS (French) OECD Representative List of High Production Volume (HPV) Chemicals US . » May produce discomfort of the respiratory system*.WHMIS Canada Toxicological Index Service . INGREDIENTS WITH MULTIPLE CAS NUMBERS Ingredient Name CAS file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re.TRANSPORTATION INFORMATION DOT: Symbols: G Identification Numbers: UN3082 Label Codes: 9 Packaging: Exceptions: 203 Packaging: Exceptions: 203 Quantity Limitations: Cargo aircraft only: No limit Vessel stowage: Other: None Hazardous materials descriptions and proper shipping names: Environmentally hazardous substance.Inventory bisphenol A/ epichlorohydrin resin.Adhesives US Toxic Substances Control Act (TSCA) ..O.O. Section 14 .Health and Safety Data Reporting (C12-14)alkylglycidyl ether (CAS: 68609-97-2) is found on the following regulatory lists. n. 335.s Hazard class or Division: PG: Special provisions: Packaging: Non-bulk: Quantity limitations: Passenger aircraft/rail: Vessel stowage: Location: 9 III 8.o. 2/26/2010 .(contains bisphenol A/ epichlorohydrin resin.Inventory US TSCA Section 4 . » Limited evidence of a carcinogenic effect*.

Regulations and Standards: OSHA Standards . This document is copyright.138 .Personal Protective Equipment .29 CFR: 1910.Eye and face protection 1910.133 . » For detailed advice on Personal Protective Equipment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings.ANSI Z87.ANSI Z41 Respirators must be NIOSH approved.132 . research. frequency of use and current or available engineering controls must be considered.General requirements 1910. Apart from any fair dealing for the purposes of private study. Scale of use. review or criticism.net/references.134 . TEL (+61 3) 9572 4700. » The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.1 Foot protection . refer to the following U.. no part may be reproduced by any process without written permission from CHEMWATCH. Issue Date: Jun-2-2009 Print Date: Feb-26-2010 file://C:\Users\Matt Green\Documents\CHEM\Citadel Diamond Wrap Standard Primer Re. A list of reference resources used to assist the committee may be found at: www.Respiratory Protection 1910.Occupational foot protection 1910.Chemwatch MSDS Page 5 of 5 bisphenol A/ epichlorohydrin resin.S.Hand Protection Eye and face protection . Risks may be determined by reference to Exposures Scenarios. 25085-99-8 » Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. 2/26/2010 . liquid 25068-38-6.chemwatch. as permitted under the Copyright Act..136 .