Code No: RR212303

Set No. 1

II B.Tech I Semester Supplementary Examinations, February 2007 BIOORGANIC CHEMISTRY (Bio-Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1. What do you mean by antagonist and explain with different examples? 2. Write short notes (a) Clasien condensation (b) Benzoin condensation (c) Cannizaro reaction (d) Bayer-viller reaction. 3. (a) Define mutation. (b) What is chemical mutation. (c) Explain transition state analogue of chemical mutation. 4. Explain Copperian-Biomodels for photosynthesis and energy transfer. 5. Describe different proteins that are in association with metals. 6. (a) How many oxidation states cobalt has explain? (b) Explain in detail that coenzyme B12 involved in various reactions. [5] [5] [6] [16] [16] [8] [8] [8+8] [4x4=16]

7. Discuss in detail about the hydrolysis of ferrocyenylacrylate ester when complexed with β- cyclodextrin. [16] 8. Why meta anionic groups showa a large rate enhancement than a para anionic group. [16] ⋆⋆⋆⋆⋆

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Code No: RR212303

Set No. 2

II B.Tech I Semester Supplementary Examinations, February 2007 BIOORGANIC CHEMISTRY (Bio-Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1. (a) What is meant by molecular recognition? How can you explain this at supra molecular level? [4+4] (b) Explain the terms: i. Proximity effect ii. Molecular adaptation. 2. (a) What is a DNA? (b) Explain different bonds involved in the structure of DNA. 3. (a) Describe the basic aspects of molecular recognition. [8] [4+4] [8] [4+4]

(b) Explain about proo piomelancorten (POMC) precursor used in enkephalin molecules production. [4+4] 4. Describe various industrial applications of immobilized enzymes. 5. (a) What are metalloenzymes and metal activated enzymes? (b) Metal-bridge complexes. (c) Role of metal ions in the mechanism of action of enzymes. 6. Discuss in detail the role of copper ion in biological system. 7. (a) What are crown ethers? (b) Explain in detail about Host-guest relationship. 8. (a) Explain how stearic acid is converted to oleic acid. (b) Explain the strategies of Breslow’s. ⋆⋆⋆⋆⋆ [16] [6] [5] [5] [16] [8] [8] [8] [8]

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Code No: RR212303

Set No. 3

II B.Tech I Semester Supplementary Examinations, February 2007 BIOORGANIC CHEMISTRY (Bio-Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1. (a) What is a receptor? (b) Explain in detail how receptor binds with substrate. [8] [8]

2. Explain in detail that amide bond formed between two amino acids is a secondary amide. [8+8] 3. (a) Describe how the analgesic drugs suppress pain information with suitable examples. [4+4] (b) Explain whether morphine bind to the same receptor as enkephalin molecules. [4+4] 4. What is known as Biotransformation? Describe the different methods of Biotransformation. 5. (a) What are metalloenzymes and metal activated enzymes? (b) Metal-bridge complexes. (c) Role of metal ions in the mechanism of action of enzymes. [8+8] [6] [5] [5]

6. Discuss in detail the different in types of copper ion present in biological system. [16] 7. (a) What are crown ethers? (b) Explain in detail about Host-guest relationship. 8. Explain in detail about the boat chair tricyclic structure of squalene. ⋆⋆⋆⋆⋆ [8] [8] [16]

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Code No: RR212303

Set No. 4

II B.Tech I Semester Supplementary Examinations, February 2007 BIOORGANIC CHEMISTRY (Bio-Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ⋆⋆⋆⋆⋆ 1. Explain in detail about antimetabolite with different examples. 2. Discuss in detail that an anhydride structure is a high energy structure. 3. Explain molecular recognition with different examples. [8+8] [16] [12+4]

4. How are enzymes classified? How do they catalyze the reactions with examples? [8+8] 5. (a) What are metalloenzymes and metal activated enzymes? (b) Metal-bridge complexes. (c) Role of metal ions in the mechanism of action of enzymes. 6. Explain about Lindsys moores model. 7. (a) What are crown ethers? (b) Explain in detail about Host-guest relationship. 8. Explain in detail about the boat chair tricyclic structure of squalene. ⋆⋆⋆⋆⋆ [6] [5] [5] [16] [8] [8] [16]

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