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Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

Appendix 1 LIST OF DANGEROUS GOODS WITH THEIR UNITED NATIONS NUMBER, DANGEROUS GOODS CLASS AND TOPS COMMODITY CODE Contents
Page Contents App 1.1 Latest issue June 06 June 06

List of Dangerous Goods with their App 1.2 United Nations Number, Dangerous Goods Class and TOPS Commodity Code

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

Page App1.1

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1.1

Classes 2 9 This list, applicable to freight train carriage, is for reference purposes only. It must not be used to allocate United Nations numbers, dangerous goods classifications, subsidiary risks or packing groups. More than one class or packing group is shown against some substances and in these instances the actual class or packing group, which should be declared by the consignor, will depend upon the properties of the actual substances consigned.
TOPS. Commodity Code 550 550 542 545 550 550 547 550 704 706 540 550 550 2.1 8 550 546 547 547 547 547 550 550 706 547 547 550 550 550 550 550 550 542 550 550 550 550
Page App1.2

Dangerous Goods Class

Subsidiary Risk(s) 5.1 8 8 5.1 2.1 2.1 2.1

Substance

1001 1002 1003 1005 1006 1008 1009 1010 1011 1012 1013 1014 1015 1016 1017 1018 1020 1021 1022 1023 1026 1027 1028 1029 1030 1032 1033 1035 1036 1037 1038 1039 1040 1041 1043

Acetylene, dissolved Air, compressed Air, refrigerated liquid Ammonia, anhydrous Argon, compressed Boron trifluoride Bromotrifluoromethane (R 13B1) Butadienes, stabilized Butane Butylene Carbon dioxide Carbon dioxide and oxygen mixture, compressed Carbon dioxide and nitrous oxide mixture Carbon monoxide, compressed Chlorine Chlorodifluoromethane (R 22) Chloropentafluoroethane (R 115) 1-Chloro-1,2,2,2-tetrafluoroethane (R 124) Chlorotrifluoromethane (R 13) Coal gas, compressed Cyanogen Cyclopropane Dichlorodifluoromethane (R 12) Dichloromonofluoromethane (R 21) 1,1-Difluoroethane (R 152a) Dimethylamine, anhydrous Dimethyl ether Ethane Ethylamine Ethyl chloride Ethylene, refrigerated liquid Ethyl methyl ether Ethylene oxide or ethylene oxide with nitrogen Ethylene oxide and carbon dioxide mixture Fertilizer ammoniating solution with free ammonia

2.1 2.2 2.2 2.3 2.2 2.3 2.2 2.1 2.1 2.1 2.2 2.2 2.2 2.3 2.3 2.2 2.2 2.2 2.2 2.3 2.3 2.1 2.2 2.2 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.1 2.3 2.1 2.2

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1044 1045 1046 1048 1049 1050 1051 1052 1053 1055 1056 1057 1058 1060 1061 1062 1063 1064 1065 1066 1067 1069 1070 1071 1072 1073 1075 1076 1077 1078 1079 1080 1081 1082 1083 1085 1086 1087 1088 1089 1090 1091 1092 1093 1098 1099 1100 1104 1105 1106 1107

Fire extinguishers with compressed or liquefied gas Fluorine, compressed Helium, compressed Hydrogen bromide, anhydrous Hydrogen, compressed Hydrogen chloride, anhydrous Hydrogen cyanide, stabilized Hydrogen fluoride, anhydrous Hydrogen sulphide Isobutylene Krypton Lighters or lighter refills (cigarettes), containing flammable gas Liquefied gases, non-flammable, charged with nitrogen, carbon dioxide or air Methylacetylene and propadiene mixture, stabilized Methylamine, anhydrous Methyl bromide with not more than 2% chloropicrin Methyl chloride (R 40) Methylmercaptan Neon, compressed Nitrogen, compressed Dinitrogen tetroxide (Nitrogen dioxide) Nitrosyl chloride Nitrous oxide Oil gas, compressed Oxygen, compressed Oxygen, refrigerated liquid Petroleum gases, liquefied Phosgene Propylene Refrigerant gas Sulphur dioxide Sulphur hexafluoride Tetrafluoroethylene, stabilized Trifluorochloroethylene, stabilized Trimethylamine, anhydrous Vinyl bromide, stabilized Vinyl chloride, stabilized Vinyl methyl ether, stabilized Acetal Acetaldehyde Acetone Acetone oils Acrolein, stabilized Acrylonitrile, stabilized Allyl alcohol Allyl bromide Allyl chloride Amyl acetates Pentanols Amylamine Amyl chloride

2.2 2.3 2.2 2.3 2.1 2.3 6.1 8 2.3 2.1 2.2 2.1 2.2 2.1 2.1 2.3 2.1 2.3 2.2 2.2 2.3 2.3 2.2 2.3 2.2 2.2 2.1 2.3 2.1 2.2 2.3 2.2 2.1 2.3 2.1 2.1 2.1 2.1 3 3 3 3 6.1 3 6.1 3 3 3 3 3 3 2.1 5.1, 8 8 5.1 2.1 5.1 5.1 8 8 2.1 5.1, 8 8 8 3 6.1 2.1 I I

550 550 550 550 550 550 553 550 550 706 550 550 550 550 550 550 550 550 550 550 550 550 550 550 550 539 706 550 549 547 550 550 550 547 550 550 548 550 529 529 529 529 522 517 528 576 576 530 526, 527 529, 530 576
Page App1.3

3 6.1 3 6.1 6.1 8

II I II II I I I I I III II, III II, III II

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1108 1109 1110 1111 1112 1113 1114 1120 1123 1125 1126 1127 1128 1129 1130 1131 1133 1134 1135 1136 1139 1143 1144 1145 1146 1147 1148 1149 1150 1152 1153 1154 1155 1156 1157 1158 1159 1160 1161 1162 1163 1164 1165 1166 1167 1169 1170 1171 1172 1173 1175 1176 1177 1178 1179 1180

1-Pentene (n-Amylene) Amyl formates n-Amyl methyl ketone Amyl mercaptan Amyl nitrate Amyl nitrite Benzene Butanols Butyl acetates Butylamine, normal 1-Bromobutane Chlorobutanes n-Butyl formate Butyraldehyde Camphor oil Carbon disulphide Adhesives containing flammable liquid Chlorobenzene Ethylene chlorohydrin Coal tar distillates Coating solution Crotonaldehyde, stabilized Crotonylene Cyclohexane Cyclopentane Decahydronaphthalene Diacetone alcohol Dibutyl ethers 1,2-Dichloroethylene Dichloropentanes Ethylene glycol diethyl ether Diethylamine Diethyl ether (Ethyl ether) Diethyl ketone Diisobutyl ketone Diisopropylamine Diisopropyl ether Dimethylamine, aqueous solution Dimethyl carbonate Dimethyldichlorosilane Dimethylhydrazine, unsymmetrical Dimethyl sulphide Dioxane Dioxolane Divinyl ether, stabilized Extracts, aromatic, liquid Ethanol (Ethyl alcohol or its solutions Ethylene glycol monoethyl ether Ethylene glycol monoethyl ether acetate Ethyl acetate Ethylbenzene Ethyl borate 2-Ethylbutyl acetate 2-Ethylbutyraldehyde Ethyl butyl ether Ethyl butyrate

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 6.1 3 3 6.1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 6.1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3

6.1 3 3

8 8 8 3

I III III II III II II II, III II, III II II II II II III I I, II, III III I II, III I, II, III I I II II III II, III III II III II, III II I II III II II II II II I II II II I I, II, III II, III III III II II II III II II III

596 530 530 596 597 596 529 526, 527 529, 530 520 576 576 529 520 597 529 596, 597 576 531 502, 503 505, 506 598 596 568 596 597 526, 527 530 576 576 529, 530 520 529 529 530 520 529 520 596 522 598 529 529 529 596 596, 597 526, 527 530 530 529 529 596 530 596 529 530
Page App1.4

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1181 1182 1183 1184 1185 1188 1189 1190 1191 1192 1193 1194 1195 1196 1197 1198 1199 1201 1202 1203 1204 1206 1207 1208 1210 1212 1213 1214 1216 1218 1219 1220 1221 1222 1223 1224 1228 1229 1230 1231 1233 1234 1235 1237 1238 1239 1242 1243 1244 1245 1246

Ethyl chloroacetate Ethyl chloroformate Ethyldichlorosilane Ethylene dichloride Ethyleneimine, stabilized Ethylene glycol monomethyl ether Ethylene glycol monomethyl ether acetate Ethyl formate Octyl aldehydes Ethyl lactate Ethyl methyl ketone (Methyl ethyl ketone) Ethyl nitrite solution Ethyl propionate Ethyltrichlorosilane Extracts, flavouring, liquid, flammable Formaldehyde solution, flammable Furaldehydes Fusel oil Diesel fuel or gas oil or heating oil (light) Motor spirit or gasoline or petrol Nitroglycerin solution in alcohol Heptanes Hexaldehyde Hexanes Printing ink or related material, flammable Isobutanol (Isobutyl alcohol) Isobutyl acetate Isobutylamine Iso-octene Isoprene, stabilized Isopropanol (Isopropyl alcohol) Isopropyl acetate Isopropylamine Isopropyl nitrate Kerosene Ketones, liquid Mercaptans or mercaptan mixture, liquid Mesityl oxide Methanol Methyl acetate Methylamyl acetate Methylal Methylamine, aqueous solution Methyl butyrate Methyl chloroformate Methyl chloromethyl ether Methyldichlorosilane Methyl formate Methylhydrazine Methyl isobutyl ketone Methyl isopropenyl ketone, stabilized

6.1 6.1 4.3 3 6.1 3 3 3 3 3 3 3 3 3 3 3 6.1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 6.1 6.1 4.3 3 6.1 3 3

3 3, 8 3, 8 6.1 3

II I I II I III III II III III II

531 598 522 576 598 530 530 529 597 530 529 596 529 520 596, 597 597 598 526, 527 721 or 724 716 or 719 596 529 521 529 596, 597 527 529 520 529 520 526 529 520 596 712, 713, 718 529, 530 596, 597 530 577 529 530 529 520 529 598 598 522 529 598 529 529
Page App1.5

6.1 8 8 3

I II II I, II, III III II II, III III II II II III II I, II, III III II II II I II II I II III II, III II, III III II II III II II II I I I I I II II

6.1 6.1

8 3, 8 3 3, 8 3, 8

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1247 1248 1249 1250 1251 1259 1261 1262 1263 1264 1265 1266 1267 1268 1272 1274 1275 1276 1277 1278 1279 1280 1281 1282 1286 1287 1288 1289 1292 1293 1294 1295 1296 1297 1298 1299 1300 1301 1302 1303 1304 1305 1306 1307 1308 1309 1310 1312 1313 1314 1318

Methyl methacrylate monomer, stabilized Methyl propionate Methyl propyl ketone Methyltrichlorosilane Methyl vinyl ketone, stabilized Nickel carbonyl Nitromethane Octanes Paint or Paint related material Paraldehyde Pentanes, liquid Perfumery products with flammable solvents Petroleum crude oil Petroleum distillates or petroleum products Pine oil n-Propanol (Propyl alcohol, normal) Propionaldehyde n-Propyl acetate Propylamine 1-Chloropropane 1,2-Dichloropropane Propylene oxide Propyl formates Pyridine Rosin oil Rubber solution Shale oil Sodium methylate solution in alcohol Tetraethyl silicate Tinctures, medicinal Toluene Trichlorosilane Triethylamine Trimethylamine, aqueous solution Trimethylchlorosilane Turpentine Turpentine substitute Vinyl acetate, stabilized Vinyl ethyl ether, stabilized Vinylidene chloride, stabilized Vinyl isobutyl ether, stabilized Vinyltrichlorosilane Wood preservatives, liquid, flammable Xylenes Zirconium suspended in a flammable liquid Aluminium powder, coated Ammonium picrate, wetted Borneol Calcium resinate Calcium resinate, fused Cobalt resinate, precipitated

3 3 3 3 6.1 6.1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4.3 3 3 3 3 3 3 3 3 3 3 3 3 3 4.1 4.1 4.1 4.1 4.1 4.1

II II II I I I II II I, II, III III I, II I, II, III I, II, III I, II, III III II, III II II II II II I II II I, II, III I, II, III II, III II, III III II, III II I II I, II, III II III II, III II I I II II II, III II, III I, II, III II, III I III III III III

520 529 529 520 531 598 530 529 505, 506 597 529 596 or 597 730, 731 708, 709, 735, 736 or 734 597 526, 527 520 529 520 576 576 578 529 529 520, 521 520, 521 730, 731 526, 527 597 514 529 598 520 520, 527 520 530 714 520 520 520 520 520 502, 503 529, 530, 735 or 736 596, 597 598 598 528 507 507 507
Page App1.6

8 3, 8 3

3, 8 8 8 8

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1320 1321 1322 1323 1324 1325 1326 1327 1328 1330 1331 1332 1333 1334 1336 1337 1338 1339 1340 1341 1343 1344 1345 1346 1347 1348 1349 1350 1352 1353 1354 1355 1356 1357 1358 1360 1361 1362 1363 1364 1365 1366 1369 1370 1372 1373 1374 1376 1378 1379

Dinitrophenol, wetted Dinitrophenolates, wetted Dinitroresorcinol, wetted Ferrocerium Films, nitrocellulose base, gelatin coated (scrap excluded) Flammable solid, organic Hafnium powder, wetted Hay, straw or bhusa Hexamethylenetetramine Manganese resinate Matches, "strike anywhere" Metaldehyde Cerium Naphthalene, crude or refined Nitroguanidine (Picrite), wetted Nitrostarch, wetted Phosphorus, amorphous Phosphorus heptasulphide Phosphorus pentasulphide Phosphorus sesquisulphide Phosphorus trisulphide Trinitrophenol, wetted Rubber scrap or Rubber shoddy Silicon powder, amorphous Silver picrate, wetted Sodium dinitro-ortho-o-cresolate, wetted Sodium picramate, wetted Sulphur Titanium powder, wetted Fibres or fabrics impregnated with weakly nitrated nitrocellulose Trinitrobenzene, wetted Trinitrobenzoic acid, wetted Trinitrotoluene (TNT), wetted Urea nitrate, wetted Zirconium powders, wetted Calcium phosphide Carbon, animal or vegetable origin Carbon, activated Copra Cotton waste, oily Cotton, wet Diethylzinc p-Nitrosodimethylaniline Dimethylzinc Fibres, animal or fibres, vegetable burnt, wet or damp Fibres or fabrics, animal or vegetable or synthetic, with oil Fish meal (Fish scrap), unstabilized Iron oxide, spent, or iron sponge, spent Metal catalyst, wetted Paper, unsaturated oil treated, incompletely dried (includes carbon paper)

4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.3 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.3 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2

6.1 6.1

I I I II III II, III II III III III III II III I I III II II II II I II III I I I III II III I I I I II I II, III III III III III I II II III II III II III

598 598 598 598 598 598 598 595 598 507 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 594 587 587 598 598 598 594 598 594 595 598 598 598 598 598

4.1

6.1

6.1

4.3 4.3

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code


Page App1.7

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1380 1381 1382 1383 1384 1385 1386 1387 1389 1390 1391 1392 1393 1394 1395 1396 1397 1398 1400 1401 1402 1403 1404 1405 1407 1408 1409 1410 1411 1413 1414 1415 1417 1418 1419 1420 1421 1422 1423 1426 1427 1428 1431 1432 1433 1435 1436 1437 1438 1439 1442 1444 1445 1446

Pentaborane Phosphorus, white or yellow Potassium sulphide, anhydrous Pyrophoric metal or alloy Sodium dithionite (Sodium hydrosulphite) Sodium sulphide, anhydrous Seed cake Wool waste, wet Alkali metal amalgam, liquid Alkali metal amides Alkali metal or alkaline earth metal dispersion Alkaline earth metal amalgam, liquid Alkaline earth metal alloy Aluminium carbide Aluminium ferrosilicon powder Aluminium powder, uncoated Aluminium phosphide Aluminium silicon powder, uncoated Barium Calcium Calcium carbide Calcium cyanamide Calcium hydride Calcium silicide Caesium Ferrosilicon Metal hydrides, water-reactive Lithium aluminium hydride Lithium aluminium hydride, ethereal Lithium borohydride Lithium hydride Lithium Lithium silicon Magnesium or magnesium alloys, powder Magnesium aluminium phosphide Potassium metal alloys, liquid Alkali metal alloy, liquid Potassium sodium alloys, liquid Rubidium Sodium borohydride Sodium hydride Sodium Sodium methylate Sodium phosphide Stannic phosphides Zinc ashes Zinc, powder or dust Zirconium hydride Aluminium nitrate Ammonium dichromate Ammonium perchlorate Ammonium persulphate Barium chlorate, solid Barium nitrate

4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.2 4.3 4.3 4.3 4.3 4.1 5.1 5.1 5.1 5.1 5.1 5.1

6.1 6.1

I I II I II II III I II I I II II II II, III I III II II I, II III I II, III I III I, II I I I I I II I, II, III I I I I I I I I II I I III I, II, III II III II II III II II

598 583 594 598 594 594 598 595 598 594 598 598 598 594 594 598 594 594 598 598 594 594 594 594 598 598 594 594 594 594 594 598 594 598 594 598 598 598 598 594 594 598 594 594 594 598 598 594 594 598 598 598 594 594
Page App1.8

6.1 6.1

6.1 3

4.2 6.1

8 6.1 6.1 4.2

6.1 6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1447 1448 1449 1450 1451 1452 1453 1454 1455 1456 1457 1458 1459 1461 1462 1463 1465 1466 1467 1469 1470 1471 1472 1473 1474 1475 1476 1477 1479 1481 1482 1483 1484 1485 1486 1487 1488 1489 1490 1491 1492 1493 1494 1495 1496 1498 1499 1500 1502 1503 1504 1505 1506 1507

Barium perchlorate, solid Barium permanganate Barium peroxide Bromates, inorganic Caesium nitrate Calcium chlorate Calcium chlorite Calcium nitrate Calcium perchlorate Calcium permanganate Calcium peroxide Chlorate and borate mixture Chlorate and magnesium chloride mixture, solid Chlorates, inorganic Chlorites, inorganic Chromium trioxide, anhydrous Didymium nitrate Ferric nitrate Guanidine nitrate Lead nitrate Lead perchlorate, solid Lithium hypochlorite, dry or mixture Lithium peroxide Magnesium bromate Magnesium nitrate Magnesium perchlorate Magnesium peroxide Nitrates, inorganic Oxidizing solid Perchlorates, inorganic Permanganates, inorganic Peroxides, inorganic Potassium bromate Potassium chlorate Potassium nitrate Potassium nitrate and sodium nitrite mixture Potassium nitrite Potassium perchlorate Potassium permanganate Potassium peroxide Potassium persulphate Silver nitrate Sodium bromate Sodium chlorate Sodium chlorite Sodium nitrate Sodium nitrate and potassium nitrate mixture Sodium nitrite Sodium perchlorate Sodium permanganate Sodium peroxide Sodium persulphate Strontium chlorate Strontium nitrate

5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1

6.1 6.1 6.1

II II II II III II II III II II II II, III II, III II II II III III III II II II II II III II II II, III I, II, III II, III II, III II, III II II III II II II II I III II II II II III III

594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 598 594 594 594 594 594 594 594 594 594 594 594 594 594 594 579 594 594 594 594 594 594 594 594 594 594
Page App1.9

6.1 6.1

6.1

III II II I III II III

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1508 1509 1510 1511 1512 1513 1514 1515 1516 1517 1541 1544 1545 1546 1547 1548 1549 1550 1551 1553 1554 1555 1556 1557 1558 1559 1560 1561 1562 1564 1565 1566 1567 1569 1570 1571 1572 1573 1574 1575 1577 1578 1579 1580 1581 1582 1583 1585 1586 1587 1588 1589 1590

Strontium perchlorate Strontium peroxide Tetranitromethane Urea hydrogen peroxide Zinc ammonium nitrite Zinc chlorate Zinc nitrate Zinc permanganate Zinc peroxide Zirconium picramate, wetted Acetone cyanohydrin, stabilized Alkaloids, toxic, or their salts, solid Allyl isothiocyanate, stabilized Ammonium arsenate Aniline Aniline hydrochloride Antimony compound, inorganic, solid Antimony lactate Antimony potassium tartrate Arsenic acid, liquid Arsenic acid, solid Arsenic bromide Arsenic compound, liquid Arsenic compound, solid Arsenic Arsenic pentoxide Arsenic trichloride Arsenic trioxide Arsenical dust Barium compound Barium cyanide Beryllium compound Beryllium, metal powder Bromoacetone Brucine Barium azide, wetted Cacodylic acid Calcium arsenate Calcium arsenate and calcium arsenite mixture, solid Calcium cyanide Chlorodinitrobenzenes, liquid Chloronitrobenzenes, solid 4-Chloro-ortho-toluidine hydrochloride, solid Chloropicrin Chloropicrin and methyl bromide mixture with more than 2% chloropicrin Chloropicrin and methyl chloride mixture Chloropicrin mixture Copper acetoarsenite Copper arsenite Copper cyanide Cyanides, inorganic, solid Cyanogen chloride, stabilized Dichloroanilines, liquid

5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 4.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 4.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 2.3 2.3 6.1 6.1 6.1 6.1 6.1 2.3 6.1

6.1 8

4.1 3 6.1

II II I III II II II II II I I I, II, III II II II III III III III I II II I, II, III I, II, III II II I II II II, III I II, III II II I I II II II I II II III I

594 594 598 598 594 594 594 594 594 594 522 598 598 598 598 598 594 594 594 594 594 594 594 594 598 594 594 594 598 594 594 594 598 598 598 594 594 594 594 594 598 598 598 598 550 550

I, II, III II II II I, II, III II

598 594 594 594 594 550 598


Page App1.10

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1591 1593 1594 1595 1596 1597 1598 1599 1600 1601 1602 1603 1604 1605 1606 1607 1608 1611 1612 1613 1614 1616 1617 1618 1620 1621 1622 1623 1624 1625 1626 1627 1629 1630 1631 1634 1636 1637 1638 1639 1640 1641 1642 1643 1644 1645 1646 1647 1648 1649 1650 1651

o-Dichlorobenzene Dichloromethane Diethyl sulphate Dimethyl sulphate Dinitroanilines Dinitrobenzenes, liquid Dinitro-ortho-cresol Dinitrophenol solution Dinitrotoluenes, molten Disinfectant, solid, toxic Dye, liquid, toxic or dye intermediate, liquid, toxic Ethyl bromoacetate Ethylenediamine Ethylene dibromide (1,2Dibromoethane) Ferric arsenate Ferric arsenite Ferrous arsenate Hexaethyl tetraphosphate Hexaethyl tetraphosphate and compressed gas mixture Hydrocyanic acid, aqueous solution (Hydrogen cyanide, aqueous solution) Hydrogen cyanide, stabilized Lead acetate Lead arsenates Lead arsenites Lead cyanide London Purple Magnesium arsenate Mercuric arsenate Mercuric chloride Mercuric nitrate Mercuric potassium cyanide Mercurous nitrate Mercury acetate Mercury ammonium chloride Mercury benzoate Mercury bromides Mercury cyanide Mercury gluconate Mercury iodide Mercury nucleate Mercury oleate Mercury oxide Mercury oxycyanide, desensitized Mercury potassium iodide Mercury salicylate Mercury sulphate Mercury thiocyanate Methyl bromide and ethylene dibromide mixture, liquid Acetonitrile Motor fuel anti-knock mixture beta-Napthylamine, solid Naphthylthiourea

6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 6.1 6.1 6.1 6.1 6.1 2.3 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3 6.1 6.1 6.1

III III II I II II, III II II, III II I, II, III I, II, III II II I II II II II

531 531 598 598 598 598 598 598 598 515 598 576 531 576 594 594 594 579 550 553 553 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 594 576 596 566 598 579
Page App1.11

3 3

3 3

I I III II II II II II II II II I II II II II II II II II II II II II II II II II I II I II II

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1652 1653 1654 1655 1656 1657 1658 1659 1660 1661 1662 1663 1664 1665 1669 1670 1671 1672 1673 1674 1677 1678 1679 1680 1683 1684 1685 1686 1687 1688 1689 1690 1691 1692 1693 1694 1695 1697 1698 1699 1700 1701 1702 1704 1707 1708 1709 1710 1711 1712 1713 1714 1715 1716

Naphthylurea Nickel cyanide Nicotine Nicotine compounds or preparations thereof, solid Nicotine hydrochloride, liquid or solution Nicotine salicylate Nicotine sulphate solution Nicotine tartrate Nitric oxide, compressed Nitroanilines Nitrobenzene Nitrophenols Nitrotoluenes, liquid Nitroxylenes, liquid Pentachloroethane Perchloromethylmercaptan Phenol, solid Phenylcarbylamine chloride Phenylenediamines Phenylmercuric acetate Potassium arsenate Potassium arsenite Potassium cuprocyanide Potassium cyanide, solid Silver arsenite Silver cyanide Sodium arsenate Sodium arsenite, aqueous solution Sodium azide Sodium cacodylate Sodium cyanide, solid Sodium fluoride, solid Strontium arsenite Strychnine or salts thereof Tear gas substance, liquid Bromobenzyl cyanides, liquid Chloroacetone, stabilized Chloroacetophenone, solid Diphenylaminechloroarsine Diphenylchloroarsine, liquid Tear-gas candles Xylyl bromide, liquid 1,1,2,2-Tetrachloroethane Tetraethyl dithiopyrophosphate Thallium compounds Toluidines, liquid 2,4-Toluylenediamine, solid Trichloroethylene Xylidines, liquid Zinc arsenate and zinc arsenite or mixture thereof Zinc cyanide Zinc phosphide Acetic anhydride Acetyl bromide

6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 2.3 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 4.3 8 8

II II II I, II, III II, III II II, III II II II III II II II I II I III II II II II I II II II II, III II II I III II I I, II I I II I I II II II II II II III III II II I I II II

579 594 579 579 579 579 579 579 550 598 598 598 598 598 531 598 504 598 598 579 594 594 594 594 594 594 594 594 594 594 594 594 594 579 598 598 598 598 598 598 598 576 531 579 594 598 598 531 598 594 594 594 557 557
Page App1.12

5.1, 8

3, 8

4.1

6.1 3

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1717 1718 1719 1722 1723 1724 1725 1726 1727 1728 1729 1730 1731 1732 1733 1736 1737 1738 1739 1740 1741 1742 1743 1744 1745 1746 1747 1748 1749 1750 1751 1752 1753 1754 1755 1756 1757 1758 1759 1760 1761 1762 1763 1764 1765 1766 1767 1768 1769 1770 1771 1773 1774

Acetyl chloride Butyl acid phosphate Caustic alkali liquids Allyl chloroformate Allyl iodide Allyl trichlorosilane, stabilized Aluminium bromide, anhydrous Aluminium chloride, anhydrous Ammonium hydrogendifluoride, solid Amyltrichlorosilane Anisoyl chloride Antimony pentachloride, liquid Antimony pentachloride, solution Antimony pentafluoride Antimony trichloride Benzoyl chloride Benzyl bromide Benzyl chloride Benzyl chloroformate Hydrogendifluorides Boron trichloride Boron trifluoride acetic acid complex, liquid Boron trifluoride propionic acid complex, liquid Bromine or bromine solution Bromine pentafluoride Bromine trifluoride Butyltrichlorosilane Calcium hypochlorite, dry or Calcium hypochlorite mixture, dry Chlorine trifluoride Chloroacetic acid, solution Chloroacetic acid, solid Chloroacetyl chloride Chlorophenyl trichlorosilane Chlorosulphonic acid Chromic acid solution Chromic fluoride, solid Chromic fluoride, solution Chromium oxychloride Corrosive solid Corrosive liquid Cupriethylenediamine solution Cyclohexenyltrichlorosilane Cyclohexyltrichlorosilane Dichloroacetic acid Dichloroacetyl chloride Dichlorophenyltrichlorosilane Diethyldichlorosilane Difluorophosphoric acid, anhydrous Diphenyldichlorosilane Diphenylmethyl bromide Dodecyltrichlorosilane Ferric chloride, anhydrous Fire extinguisher charges, corrosive liquid

3 8 8 6.1 3 8 8 8 8 8 8 8 8 8 8 8 6.1 6.1 8 8 2.3 8 8 8 5.1 5.1 8 5.1 2.3 6.1 6.1 6.1 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8

8 3, 8 8 3

6.1 8 8 8 8

II III II, III I II II II II II II II II II, III II II I II II I II, III II II

596 557 557 598 596 522 557 557 557 522 557 557 557 557 557 557 598 598 557 557 550 557 557 571 598 598 522 598 550 557 557 598 522 557 557 557 557 557 557 557 557 522 522 557 557 522 522 557 522 557 522 557 557
Page App1.13

6.1 6.1, 8 6.1, 8 3 5.1, 8 8 8 8

I I I II II, III II II I II I II, III II II, III I I, II, III I, II, III II, III II II II II II II II II II II III II

6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1775 1776 1777 1778 1779 1780 1781 1782 1783 1784 1786 1787 1788 1789 1790 1791 1792 1793 1794 1796 1796 1799 1800 1801 1802 1803 1804 1805 1806 1807 1808 1809 1810 1811 1812 1813 1814 1815 1816 1817 1818 1819 1823 1824 1825 1826 1827 1828 1829 1830 1831 1832 1833 1834 1835

Fluoroboric acid Fluorophosphoric acid, anhydrous Fluorosulphonic acid Fluorosilicic acid Formic acid Fumaryl chloride Hexadecyltrichlorosilane Hexafluorophosphoric acid Hexamethylenediamine solution Hexyltrichlorosilane Hydrofluoric acid and sulphuric acid mixture Hydriodic acid Hydrobromic acid Hydrochloric acid Hydrofluoric acid Hypochlorite solution Iodine monochloride Isopropyl acid phosphate Lead sulphate Nitrating acid mixture Nitrating acid mixture Nonyltrichlorosilane Octadecyltrichlorosilane Octyltrichlorosilane Perchloric acid, not more than 50% Phenolsulphonic acid, liquid Phenyltrichlorosilane Phosphoric acid solution Phosphorus pentachloride Phosphorus pentoxide Phosphorus tribromide Phosphorus trichloride Phosphorus oxychloride Potassium hydrogendifluoride solid Potassium fluoride, solid Potassium hydroxide, solid Potassium hydroxide solution Propionyl chloride Propyltrichlorosilane Pyrosulphuryl chloride Silicon tetrachloride Sodium aluminate solution Sodium hydroxide, solid Sodium hydroxide solution Sodium monoxide Nitrating acid mixture, spent Stannic chloride, anhydrous Sulphur chlorides Sulphur trioxide, stabilized Sulphuric acid with more than 51% acid Sulphuric acid, fuming Oleum Sulphuric acid, spent Sulphurous acid Sulphuryl chloride Tetramethylammonium hydroxide solution

8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6.1 8 8 6.1 8 8 3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8

6.1

II II I II II II II II III II I II, III III II, III I, II II, III II III II I II II II II II II II III II II II I II II III II II, III II II II II II, III II II, III II I II I I II I II II I II, III

557 557 557 557 557 557 522 557 522 522 557 557 557 552 557 557 557 557 557 557 557 522 522 522 557 557 522 555 557 557 557 598 557 557 594 557 557 596 522 557 557 557 561 560 557 557 557 557 557 556 556 556 557 557 557
Page App1.14

6.1

5.1

5.1

8 6.1

8 3

5.1

6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1836 1837 1838 1839 1840 1841 1843 1845 1846 1847 1848 1849 1851 1854 1855 1856 1857 1858 1859 1860 1862 1863 1865 1866 1868 1869 1870 1871 1872 1873 1884 1885 1886 1887 1888 1889 1891 1892 1894 1895 1897 1898 1902 1903 1905 1906 1907 1908 1910 1911 1912 1913 1914

Thionyl chloride Thiophosphoryl chloride Titanium tetrachloride Trichloroacetic acid Zinc chloride, solution Acetaldehyde ammonia Ammonium dinitro-ortho-creosolate, solid Carbon dioxide, solid (Dry Ice) Carbon tetrachloride Potassium sulphide, hydrated Propionic acid Sodium sulphide, hydrated Medicine, liquid, toxic Barium alloys, pyrophoric Calcium or calcium alloys, pyrophoric Rags, oily Textile waste, wet Hexafluoropropylene (R 1216) Silicon tetrafluoride Vinyl fluoride, stabilized Ethyl crotonate Fuel, aviation, turbine engine n-Propyl nitrate Resin solution Decaborane Magnesium or magnesium alloys Potassium borohydride Titanium hydride Lead dioxide Perchloric acid, more than 50% Barium oxide Benzidine Benzylidene chloride Bromochloromethane Chloroform Cyanogen bromide Ethyl bromide (Bromoethane) Ethyldichloroarsine Phenylmercuric hydroxide Phenylmercuric nitrate Tetrachloroethylene (Perchloroethylene) Acetyl iodide Diisooctyl acid phosphate Disinfectant, liquid, corrosive Selenic acid Sludge acid Soda lime with more than 4% sodium hydroxide Chlorite solution Calcium oxide Diborane Methyl chloride and methylene chloride mixture Neon, refrigerated liquid Butyl propionates

8 8 8 8 8 9 6.1 6.1 8 8 8 6.1 4.2 4.2 2.2 2.3 2.1 3 3 3 3 4.1 4.1 4.3 4.1 5.1 5.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 8 8 8 8 8 8 2.3 2.1 2.2 3

I II II II III III II II II III II II III I I 8 II I, II, III II I, II, III II III I II III I III II II III III I II I II II III II III I, II, III I II III II, III 2.1

557 557 557 557 557 598 598 595 531 557 557 557 514 598 598 595 595 550 550 550 529 717, 718 596 520, 521 598 598 594 594 594 598 594 598 598 576 531 598 576 598 579 579 531 557 557 515 557 556 557 557 595 550 550 542 530
Page App1.15

6.1

6.1 8

III

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1915 1916 1917 1918 1919 1920 1921 1922 1923 1928 1929 1931 1932 1935 1938 1939 1940 1941 1942 1944 1945 1950 1951 1952 1953 1954 1955 1956 1957 1958 1959 1961 1962 1963 1964 1965 1966 1967 1968 1969 1970 1971 1972 1973 1974 1975

Cyclohexanone 2,2-Dichlorodiethyl ether Ethyl acrylate, stabilized Cumene Methyl acrylate, stabilized Nonanes Propyleneimine, stabilized Pyrrolidine Calcium dithionite (Calcium hydrosulphite) Methyl magnesium bromide in ethyl ether Potassium hydrosulphite (Potassium hydrosulphite) Zinc dithionite (Zinc hydrosulphite) Zirconium scrap Cyanide solution Bromoacetic acid solution Phosphorus oxybromide Thioglycolic acid Dibromodifluoromethane Ammonium nitrate Matches, safety Matches, wax ''Vesta Aerosols Argon, refrigerated liquid Ethylene oxide and carbon dioxide mixture Compressed gas, toxic, flammable Compressed gas, flammable, Compressed gas, toxic Compressed gas, non-flammable, nontoxic Deuterium, compressed 1,2-Dichloro-1,1,2,2-tetrafluoroethane (R 114) 1,1-Difluoroethylene (R 1132a) Ethane, refrigerated liquid Ethylene Helium, refrigerated liquid Hydrocarbon gas mixture, compressed Hydrocarbon gas mixture, liquefied Hydrogen, refrigerated liquid Insecticide gas, toxic Insecticide gas, non-toxic Isobutane Krypton, refrigerated liquid Methane or natural gas, compressed Methane or natural gas, refrigerated liquid Chlorodifluoromethane and chloropentafluoroethane mixture (R 502) Chlorodifluorobromomethane (R12B1) Nitric oxide and nitrogen dioxide mixture

3 6.1 3 3 3 3 3 3 4.2 4.3 4.2 9 4.2 6.1 8 8 8 9 5.1 4.1 4.1 2.1, 2.2 2.2 2.2 2.3 2.1 2.3 2.2 2.1 2.2 2.1 2.1 2.1 2.2 2.1 2.1 2.1 2.3 2.2 2.1 2.2 2.1 2.1 2.2 2.2 2.3

6.1 8 3

III II II III II III I II II I II III III I, II, III II, III II II III III III III

521 598 520 567 520 597 596 596 594 594 594 594 598 598 557 557 557 576 591 598 598 543, 544 542 550 550 550 550 550 550 547 550 542 550 542 706 706 542 550 550 706 542 737 737 547 547 550
Page App1.16

5.1, 6.1, 8

2.1

5.1, 8

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1976 1977 1978 1979 1980 1981 1982 1983 1984 1986 1987 1988 1989 1990 1991 1992 1993 1994 1999 2000 2001 2002 2004 2005 2006 2008 2009 2010 2011 2012 2013 2014 2015

2016 2017 2018 2019 2020 2021 2022 2023 2024 2025 2026 2027

Octafluorocyclobutane (RC 318) Nitrogen, refrigerated liquid Propane Rare gases mixture, compressed Rare gases and oxygen mixture, compressed Rare gases and nitrogen mixture, compressed Tetrafluoromethane (R 14) 1-Chloro-2,2,2-trifluoroethane (R 133a) Trifluoromethane (R 23) Alcohols, flammable, toxic Alcohols Aldehydes, flammable, toxic Aldehydes Benzaldehyde Chloroprene, stabilized Flammable liquid, toxic Flammable liquid, non-toxic Iron pentacarbonyl Tars, liquid, including road asphalt and oils, bitumen and cut-backs Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap excluded) Cobalt naphthenates, powder Celluloid, scrap Magnesium diamide Magnesium diphenyl Plastics, nitrocellulose-based, selfheating Zirconium powder, dry Zirconium, dry, finished sheets, strip or coiled wire Magnesium hydride Magnesium phosphide Potassium phosphide Strontium phosphide Hydrogen peroxide, aqueous solution with not less than 20% but not more than 60% hydrogen peroxide Hydrogen peroxide, stabilized or hydrogen peroxide, aqueous solution, stabilized with more than 60% hydrogen peroxide Ammunition, toxic, non-explosive Ammunition, tear-producing, nonexplosive Chloroanilines, solid Chloroanilines, liquid Chlorophenols, solid Chlorophenols, liquid Cresylic acid Epichlorohydrin Mercury compound, liquid Mercury compound, solid Phenylmercuric compound Sodium arsenite, solid

2.2 2.2 2.1 2.2 2.2 2.2 2.2 2.2 2.2 3 3 3 3 9 3 3 3 6.1 3 4.1 4.1 4.2 4.2 4.2 4.2 4.2 4.2 4.3 4.3 4.3 4.3 5.1 5.1 6.1 6.1 6.1 8 8

547 541 702 550 550 550 547 547 547 526, 527 526, 527 529, 530 529, 530 598 520 596, 597 596, 597 598 500, 733, 735 or 736 598 507 598 594 594 598 598 598 594 594 594 594 574 574

6.1 6.1 6.1 6.1 3

I, II, III II, III I, II, III I, II, III III I I, II, III I, II, III I II, III III III III II I III I, II, III III I I I I II I

4.3

6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1

II II II II III III II II I, II, III I, II, III I, II, III II

598 598 598 598 598 598 504 531 594 594 594 594
Page App1.17

8 3

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2028 2029 2030 2031 2031 2032 2033 2034 2035 2036 2037 2038 2044 2045 2046 2047 2048 2049 2050 2051 2052 2053 2054 2055 2056 2057 2058 2059 2067 2071 2073 2074 2075 2076 2077 2078 2079 2187 2188 2189 2190 2191 2192 2193 2194 2195 2196 2197 2198 2199 2200 2201

Bombs, smoke, non-explosive with corrosive liquid Hydrazine, anhydrous Hydrazine aqueous solution, with more than 37% hydrazine Nitric acid Nitric acid Nitric acid, red fuming Potassium monoxide Hydrogen and methane mixture, compressed 1,1,1-Trifluoroethane (R 143a) Xenon Receptacles, small, containing gas (gas cartridges) Dinitrotoluenes, liquid 2,2-Dimethylpropane Isobutyraldehyde (Isobutyl aldehyde) Cymenes Dichloropropenes Dicyclopentadiene Diethylbenzene Di-isobutylene, isomeric compounds 2-Dimethylaminoethanol Dipentene Methyl isobutyl carbinol Morpholine Styrene monomer, stabilized Tetrahydrofuran Tripropylene Valeraldehyde Nitrocellulose solution, flammable Ammonium nitrate based fertilizer Ammonium nitrate based fertilizer Ammonia solution with more than 35% ammonia Acrylamide, solid Chloral, anhydrous, stabilized Cresols, liquid alpha-Naphthylamine Toluene diisocyanate Diethylenetriamine Carbon dioxide, refrigerated liquid Arsine Dichlorosilane Oxygen difluoride, compressed Sulphuryl fluoride Germane Hexafluoroethane (R 116) Selenium hexafluoride Tellurium hexafluoride Tungsten hexafluoride Hydrogen iodide, anhydrous Phosphorus pentafluoride Phosphine Propadiene, stabilized Nitrous oxide, refrigerated liquid

8 8 8 8 8 8 8 2.1 2.1 2.2 2.1, 2.2 2.3 6.1 2.1 3 3 3 3 3 3 8 3 3 8 3 3 3 3 3 5.1 2.2 6.1 6.1 6.1 6.1 6.1 8 2.2 2.3 2.3 2.3 2.3 2.3 2.2 2.3 2.3 2.3 2.3 2.3 2.3 2.1 2.2 3, 6.1 6.1 5.1 5.1, 6.1

II I I, II, III I II I II

557 557 557 554 554 554 557 550 547 550 543, 544 550 598 550 520 530 576 521 597 596 598 530 527 557 569 529 596, 597 596 505, 506 509 508 573 522 598 504 598 522 531 540 550 550 550 550 550 550 550 550 550 550 550 550 550 542
Page App1.18

5.1, 8 II II III II, III III III II II II III I III II II, III II I, II, III III

3 3

III II II III II II

2.1 2.1, 8 5.1, 8 2.1 8 8 8 8 8 2.1 5.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2202 2203 2204 2205 2206 2208 2209 2210 2211 2213 2214 2215 2216 2217 2218 2219 2222 2224 2225 2226 2227 2232 2233 2234 2235 2236 2237 2238 2239 2240 2241 2242 2243 2244 2245 2246 2247 2248 2250 2251 2252 2253 2254 2256 2257 2258 2259 2260 2261 2262 2263

Hydrogen selenide, anhydrous Silane Carbonyl sulphide Adiponitrile Isocyanates, toxic or isocyanate solution, toxic Calcium hypochlorite mixture, dry Formaldehyde solution Maneb or maneb preparation Polymeric beads, expandable Paraformaldehyde Phthalic anhydride with more than 005% maleic anhydride Maleic anhydride or maleic anhydride, molten Fish meal (fish scrap), stabilized Seed cake Acrylic acid, stabilized Allyl glycidyl ether Anisole Benzonitrile Benzenesulphonyl chloride Benzotrichloride n-Butyl methacrylate, stabilized 2-Chloroethanal Chloroanisidines Chlorobenzotrifluorides Chlorobenzyl chlorides, liquid 3-Chloro-4-methylphenyl isocyanate, liquid Chloronitroanilines Chlorotoluenes Chlorotoluidines, solid Chromosulphuric acid Cycloheptane Cycloheptene Cyclohexyl acetate Cyclopentanol Cyclopentanone Cyclopentene n-Decane Di-n-butylamine Dichlorophenyl isocyanates Bicyclo[2,2,1]hepta-2,5-diene, stabilized (2,5-Norbornadiene, stabilized) 1,2-Dimethoxyethane N,N-Dimethylaniline Matches, fusee Cyclohexene Potassium 1, 2-Propylenediamine Triethylenetetramine Tripropylamine Xylenols, solid Dimethylcarbamoyl chloride Dimethylcyclohexanes

2.3 2.1 2.3 6.1 6.1 5.1 8 4.2 9 4.1 8 8 4.2 8 3 3 6.1 8 8 3 6.1 6.1 3 6.1 6.1 6.1 3 6.1 8 3 3 3 3 3 3 3 8 6.1 3 3 6.1 4.1 3 4.3 8 8 3 6.1 8 3

2.1 2.1 III II, III III III III III III III III III II III III II III II III I III III III II III III III I II II III III III II III II II II II II III II I II II III II II II

550 550 550 522 522 594 515 579 522 598 522 522 595 598 522 597 530 598 557 557 521 598 598 597 598 522 598 530 598 557 596 596 530 530 597 596 530 557 522 596 529 598 598 596 598 557 557 597 504 557 596
Page App1.19

4.3

3 8

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2264 2265 2266 2267 2269 2270 2271 2272 2273 2274 2275 2276 2277 2278 2279 2280 2281 2282 2283 2284 2285 2286 2287 2288 2289 2290 2291 2293 2294 2295 2296 2297 2298 2299 2300 2301 2302 2303 2304 2305 2306 2307 2308 2309 2310 2311 2312 2313 2315 2316 2317 2318 2319 2320 2321 2322 2323

N,N-Dimethylcyclohexylamine N,N-Dimethylformamide Dimethyl-N-propylamine Dimethyl thiophosphoryl chloride 3,3'-Iminodipropylamine Ethylamine, 50-70% aqueous solution Ethyl amyl ketone N-Ethylaniline 2-Ethylaniline N-Ethyl-N-benzylaniline 2-Ethylbutanol 2-Ethylhexylamine Ethyl methacrylate, stabilized n-Heptene Hexachlorobutadiene Hexamethylenediamine, solid Hexamethylene diisocyanate Hexanols Isobutyl methacrylate, stabilized Isobutyronitrile Isocyanatobenzotrifluorides Pentamethylheptane Isoheptene Isohexene Isophoronediamine Isophorone diisocyanate Lead compound, soluble 4-Methoxy-4-methylpentan-2-one N-Methylaniline Methyl chloroacetate Methylcyclohexane Methylcyclohexanone Methylcyclopentane Methyl dichloroacetate 2-Methyl-5-ethylpyridine 2-Methylfuran 5-Methylhexan-2-one Isopropenylbenzene Naphthalene, molten Nitrobenzenesulphonic acid Nitrobenzotrifluorides, liquid 3-Nitro-4-chlorobenzotrifluoride Nitrosylsulphuric acid, liquid Octadienes Pentane-2,4-dione Phenetidines Phenol, molten Picolines Polychlorinated biphenyls, liquid Sodium cuprocyanide, solid Sodium cuprocyanide solution Sodium hydrosulphide Terpene hydrocarbons Tetraethylenepentamine Trichlorobenzenes, liquid Trichlorobutene Triethyl phosphite

8 3 3 6.1 8 3 3 6.1 6.1 6.1 3 3 3 3 6.1 8 6.1 3 3 3 6.1 3 3 3 8 6.1 6.1 3 6.1 6.1 3 3 3 6.1 6.1 3 3 3 4.1 8 6.1 6.1 8 3 3 6.1 6.1 3 9 6.1 6.1 4.2 3 8 6.1 6.1 3

3 8 8 8

6.1 3

6.1

II III II II III II III III III III III III II II III III II III III II II III II II III III III III III I II III II III III II III III III II II II II II III III II III II I I II III III III II III

557 530 596 598 557 596 530 598 598 598 527 557 520 596 576 522 522 527 521 596 598 597 596 596 557 522 594 530 598 531 529 530 529 598 598 596 530 521 598 557 598 598 557 596 530 598 504 597 576 594 594 594 530 531 576 576 597
Page App1.20

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2324 2325 2326 2327 2328 2329 2330 2331 2332 2333 2334 2335 2336 2337 2338 2339 2340 2341 2342 2343 2344 2345 2346 2347 2348 2350 2351 2352 2353 2354 2356 2357 2358 2359 2360 2361 2362 2363 2364 2366 2367 2368 2370 2371 2372 2373 2374 2375 2376 2377 2378 2379 2380 2381 2382 2383 2384

Triisobutylene 1,3,5-Trimethylbenzene Trimethylcyclohexylamine Trimethylhexamethylenediamines Trimethylhexamethylene diisocyanate Trimethyl phosphite Undecane Zinc chloride, anhydrous Acetaldehyde oxime Allyl acetate Allylamine Allyl ethyl ether Allyl formate Phenyl mercaptan Benzotrifluoride 2-Bromobutane 2-Bromoethyl ethyl ether 1-Bromo-3-methylbutane Bromomethylpropanes 2-Bromopentane Bromopropanes 3-Bromopropyne Butanedione Butyl mercaptan Butyl acrylates, stabilized Butyl methyl ether Butyl nitrites Butyl vinyl ether, stabilized Butyryl chloride Chloromethyl ethyl ether 2-Chloropropane Cyclohexylamine Cyclooctatetraene Diallylamine Diallylether Diisobutylamine 1, 1-Dichloroethane Ethyl mercaptan n-Propylbenzene Diethyl carbonate alpha-Methyl valeraldehyde alpha-Pinene 1-Hexene Isopentenes 1,2-Di-(dimethylamino) ethane Diethoxymethane 3,3-Diethoxypropene Diethyl sulphide 2,3-Dihydropyran 1,1-Dimethoxyethane 2-Dimethylaminoacetonitrile 1,3-Dimethylbutylamine Dimethyldiethoxysilane Dimethyl disulphide Dimethylhydrazine, symmetrical Dipropylamine Di-n-propyl ether

3 3 8 8 6.1 3 3 8 3 3 6.1 3 3 6.1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 8 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 6.1 3 3

6.1 3 6.1 6.1 3

8 6.1 3 6.1, 8 6.1 8

6.1 8 3 8

III III III III III III III III III II I II I I II II II III II II II, III II II II III II II, III II II II I II II II II III II I III III II III II I II II II II II II II II II II I II II

736 597 557 522 522 597 597 557 597 596 598 596 596 598 576 576 576 576 576 576 576 576 596 596 521 529 596, 597 529 596 529 576 557 596 596 596 597 596 596 597 530 596 530 596 596 596 596 596 596 596 596 597 596 520 596 598 596 596
Page App1.21

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2385 2386 2387 2388 2389 2390 2391 2392 2393 2394 2395 2396 2397 2398 2399 2400 2401 2402 2403 2404 2405 2406 2407 2409 2410 2411 2412 2413 2414 2416 2417 2418 2419 2420 2422 2424 2426 2427 2428 2429 2430 2431 2432 2433 2434 2435 2436 2437 2438 2439 2440 2441 2442 2443 2444

Ethyl isobutyrate 1-Ethylpiperidine Fluorobenzene Fluorotoluenes Furan 2-Iodobutane Iodomethylpropanes Iodopropanes Isobutyl formate Isobutyl propionate Isobutyryl chloride Methacrylaldehyde, stabilized 3-Methylbutan-2-one Methyl tert-butyl ether 1-Methylpiperidine Methyl isovalerate Piperidine Propanethiols Isopropenyl acetate Propionitrile Isopropyl butyrate Isopropyl isobutyrate Isopropyl chloroformate Isopropyl propionate 1,2,3,6-Tetrahydropyridine Butyronitrile Tetrahydrothiophene Tetrapropyl orthotitanate Thiophene Trimethyl borate Carbonyl fluoride Sulphur tetrafluoride Bromotrifluorethylene Hexafluoroacetone Octafluorobut-2-ene (R 1318) Octafluoropropane (R 218) Ammonium nitrate, liquid (hot concentrated solution) Potassium chlorate, aqueous solution Sodium chlorate, aqueous solution Calcium chlorate, aqueous solution Alkylphenols, solid Anisidines N, N-Diethylaniline Chloronitrotoluenes, liquid Dibenzyldichlorosilane Ethyl phenyl dichlorosilane Thioacetic acid Methylphenyldichlorosilane Trimethylacetyl chloride Sodium hydrogendifluoride Stannic chloride pentahydrate Titanium trichloride, pyrophoric or titanium trichloride mixture, pyrophoric Trichloroacetyl chloride Vanadium oxytrichloride Vanadium tetrachloride

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 8 3 3 3 3 3 6.1 3 3 3 3 3 3 3 2.3 2.3 2.1 2.3 2.2 2.2 5.1 5.1 5.1 5.1 8 6.1 6.1 6.1 8 8 3 8 6.1 8 8 4.2 8 8 8

8 6.1 8 3 6.1 3, 8 6.1

8 8 8

II II II II I II II III II III II II II II II II I II II II III II I II II II II III II II

596 596 576 576 596 576 576 576 596 530 596 520 529 596 596 596 598 596 596 529 530 529 598 596 596 596 529 597 596 529 550 550 547 550 550 550 565 594 594 594 504 598 598 598 522 522 596 522 598 557 557 598 557 557 557
Page App1.22

3, 8 8

II, III II, III II, III I, II, III III III III II II II II I II III I II II I

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2445 2446 2447 2448 2451 2452 2453 2454 2456 2457 2458 2459 2460 2461 2463 2464 2465 2466 2468 2469 2470 2471 2473 2474 2475 2477 2478 2480 2481 2482 2483 2484 2485 2486 2487 2488 2490 2491 2493 2495 2496 2498 2501 2502 2503 2504 2505 2506 2507 2508 2509 2511 2512 2513 2514

Lithium alkyls, liquid Nitrocresols, solid Phosphorus, white, molten Sulphur, molten Nitrogen trifluoride Ethylacetylene, stabilized Ethyl fluoride (R 161) Methyl fluoride (R 41) 2-Chloropropene 2,3-Dimethylbutane Hexadienes 2-Methyl-1-butene 2-Methyl-2-butene Methylpentadiene Aluminium hydride Beryllium nitrate Dichloroisocyanuric acid dry or its salts Potassium superoxide Trichloroisocyanuric acid, dry Zinc bromate Phenylacetonitrile, liquid Osmium tetroxide Sodium arsanilate Thiophosgene Vanadium trichloride Methyl isothiocyanate Isocyanates, flammable, toxic or isocyanate solution, flammable, toxic Methyl isocyanate Ethyl isocyanate n-Propyl isocyanate Isopropyl isocyanate tert-Butyl isocyanate n-Butyl isocyanate Isobutyl isocyanate Phenyl isocyanate Cyclohexyl isocyanate Dichloroisopropyl ether Ethanolamine or ethanolamine solution Hexamethyleneimine Iodine pentafluoride Propionic anhydride 1,2,3,6-Tetrahydrobenzaldehyde Tris-(1-aziridinyl) phosphine oxide solution Valeryl chloride Zirconium tetrachloride Tetrabromoethane Ammonium fluoride Ammonium hydrogen sulphate Chloroplatinic acid, solid Molybdenum pentachloride Potassium hydrogen sulphate 2-Chloropropionic acid Aminophenols Bromoacetyl bromide Bromobenzene

4.2 6.1 4.2 4.1 2.2 2.1 2.1 2.1 3 3 3 3 3 3 4.3 5.1 5.1 5.1 5.1 5.1 6.1 6.1 6.1 6.1 8 6.1 3 6.1 3 6.1 3 6.1 6.1 3 6.1 6.1 6.1 8 3 5.1 8 3 6.1 8 8 6.1 6.1 8 8 8 8 8 6.1 8 3

4.3 6.1 5.1

I III I III

6.1

3 6.1 3 6.1 3 6.1 3 3 6.1 3 3 8 6.1, 8

I II II I II II I II II I II III III I III II III I II, III I I I I I I II I I II III II I III III II, III II III III III II III III II III III II III

594 598 583 586 550 550 550 550 576 596 596 596 596 520 594 594 598 594 598 594 598 594 594 598 557 598 520, 521 522 520 522 520 522 522 520 522 522 531 557 596 598 557 597 598 557 557 576 594 557 557 557 557 557 598 557 530
Page App1.23

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2515 2516 2517 2518 2520 2521 2522 2524 2525 2526 2527 2528 2529 2531 2533 2534 2535 2536 2538 2541 2542 2545 2546 2547 2548 2552 2554 2555 2556 2557 2558 2560 2561 2564 2565 2567 2570 2571 2572 2573 2574 2576 2577 2578 2579 2580 2581 2582 2583 2584 2585

Bromoform Carbon tetrabromide 1-Chloro-1,1-difluoroethane (R 142b) 1,5,9-Cyclododecatriene Cyclooctadienes Diketene, stabilized 2-Dimethylaminoethyl methacrylate Ethyl orthoformate Ethyl oxalate Furfurylamine Isobutyl acrylate, stabilized Isobutyl isobutyrate Isobutyric acid Methacrylic acid, stabilized Methyl trichloroacetate Methylchlorosilane 4-Methylmorpholine (NMethylmorpholine) Methyltetrahydrofuran Nitronaphthalene Terpinolene Tributylamine Hafnium powder, dry Titanium powder, dry Sodium superoxide Chlorine pentafluoride Hexafluoroacetone hydrate, liquid Methylallyl chloride Nitrocellulose with water Nitrocellulose with alcohol Nitrocellulose mixture with or without plasticizer or pigment Epibromohydrin 2-Methylpentan-2-ol 3-Methyl-1-butene Trichloroacetic acid solution Dicyclohexylamine Sodium pentachlorophenate Cadmium compound Alkylsulphuric acids Phenylhydrazine Thallium chlorate Tricresyl phosphate Phosphorus oxybromide, molten Phenylacetyl chloride Phosphorus trioxide Piperazine Aluminium bromide solution Aluminium chloride solution Ferric chloride solution Alkyl or aryl sulphonic acids, solid, with more than 5% free sulphuric acid Alkyl or aryl sulphonic acids, liquid, with more than 5% free sulphuric acid Alkyl or aryl sulphonic acids, solid, with not more than 5% free sulphuric acid

6.1 6.1 2.1 6.1 3 6.1 6.1 3 6.1 3 3 3 3 8 6.1 2.3 3 3 4.1 3 6.1 4.2 4.2 5.1 2.3 6.1 3 4.1 4.1 4.1 6.1 3 3 8 8 6.1 6.1 8 6.1 5.1 6.1 8 8 8 8 8 8 8 8 8 8

III III III III I II III III III III III III II III II II III III II I, II, III I, II, III I II II II II II I III I II, III III II I, II, III II II II II II II III III III III III II II III

8 8 2.1, 8 8

576 576 547 557 597 598 598 597 531 597 521 597 597 522 598 550 596 529 598 530 598 598 598 594 550 598 576 507 507 507 598 527 596 557 557 579 594 557 598 594 522 557 557 557 557 557 557 557 557 557 557

5.1, 8

6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code


Page App1.24

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2586 2587 2588 2589 2590 2591 2599 2600 2601 2602 2603 2604 2605 2606 2607 2608 2609 2610 2611 2612 2614 2615 2616 2617 2618 2619 2620 2621 2622 2623 2624 2626 2627 2628 2629 2630 2642 2643 2644 2645 2646 2647 2648 2649 2650 2651 2653 2655 2656 2657 2659

Alkyl or aryl sulphonic acids, liquid, with not more than 5% free sulphuric acid Benzoquinone Pesticide, solid, toxic Vinyl chloroacetate White asbestos Xenon, refrigerated liquid Chlorotrifluoromethane and trifluoromethane azeotropic mixture (R 503) Carbon monoxide and hydrogen mixture, compressed Cyclobutane Dichlorodifluoromethane and 1,1difluoroethane azeotropic mixture (R 500) Cycloheptatriene Boron trifluoride diethyl etherate Methoxymethyl isocyanate Methyl orthosilicate Acrolein dimer, stabilized Nitropropanes Triallyl borate Triallylamine Propylene chlorohydrin Methyl propyl ether Methallyl alcohol Ethyl propyl ether Triisopropyl borate Methylcyclohexanols, flammable Vinyltoluenes, stabilized Benzyldimethylamine Amyl butyrates Acetyl methyl carbinol Glycidaldehyde Firelighters, solid with flammable liquid Magnesium silicide Chloric acid, aqueous solution Nitrites, inorganic Potassium fluoroacetate Sodium fluoroacetate Selenates or selenites Fluoroacetic acid Methyl bromoacetate Methyl iodide Phenacyl bromide Hexachlorocyclopentadiene Malononitrile 1,2-Dibromobutan-3-one 1,3-Dichloroacetone 1,1-Dichloro-1-nitroethane 4,4'-Diaminodiphenylmethane Benzyl iodide Potassium fluorosilicate Quinoline Selenium disulphide Sodium chloroacetate

8 6.1 6.1 6.1 9 2.2 2.2 2.3 2.1 2.2 3 8 3 6.1 3 3 6.1 3 6.1 3 3 3 3 3 3 8 3 3 3 4.1 4.3 5.1 5.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3 6.1 3

III II I, II, III II III

557 598 579 598 598 542 547 550 706 547

2.1

8 3

3 6.1

II I I I III III III III II II III II II, III III III II III III II III II II II I I I I II I II I II II II II III II III III II III

596 557 520 598 521 597 598 597 598 596 527 596 596, 597 527 597 557 530 527 597 598 594 598 594 594 594 594 598 598 598 598 576 598 598 598 598 522 598 594 598 594 594
Page App1.25

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2660 2661 2662 2664 2667 2668 2669 2670 2671 2672 2673 2674 2676 2677 2678 2679 2680 2681 2682 2683 2684 2685 2686 2687 2688 2689 2690 2691 2692 2693 2698 2699 2705 2707 2709 2710 2713 2714 2715 2716 2717 2719 2720 2721 2722 2723 2724 2725 2726 2727 2728 2729 2730 2732

Nitrotoluidines (mono) Hexachloroacetone Hydroquinone, solid Dibromomethane Butyltoluenes Chloroacetonitrile Chlorocresols solution Cyanuric chloride Aminopyridines Ammonia solution with more than 10% and not more than 35% ammonia 2-Amino-4-chlorophenol Sodium fluorosilicate Stibine Rubidium hydroxide solution Rubidium hydroxide Lithium hydroxide solution Lithium hydroxide Caesium hydroxide solution Caesium hydroxide Ammonium sulphide solution 3-Diethylaminopropylamine N,N-Diethylethylene diamine 2-Diethylaminoethanol Dicyclohexylammonium nitrite 1-Bromo-3-chloropropane Glycerol alpha-monochlorohydrin N-n-Butylimidazole Phosphorus pentabromide Boron tribromide Bisulphites, aqueous solution Tetrahydrophthalic anhydrides with more than 005% of maleic anhydride Trifluoroacetic acid 1-Pentol Dimethyldioxanes Butylbenzenes Dipropyl ketone Acridine Zinc resinate Aluminium resinate 1,4-Butynediol Camphor, synthetic Barium bromate Chromium nitrate Copper chlorate Lithium nitrate Magnesium chlorate Manganese nitrate Nickel nitrate Nickel nitrite Thallium nitrate Zirconium nitrate Hexachlorobenzene Nitroanisoles, liquid Nitrobromobenzenes, liquid

6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 6.1 8 6.1 6.1 2.3 8 8 8 8 8 8 8 3 8 8 4.1 6.1 6.1 6.1 8 8 8 8 8 8 3 3 3 6.1 4.1 4.1 6.1 4.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 6.1 5.1 6.1 6.1 6.1

III III III III III II II, III II II III II III II, III II II, III II II, III II II III II II III III III II II I III III I II II, III III III III III III III III II III II III II III III III II III III III III

598 598 598 576 598 598 598 557 598 573 598 594 550 557 557 557 557 557 557 557 597 557 557 598 576 598 598 557 557 557 557 557 557 596, 597 597 530 598 507 507 528 598 594 594 594 594 594 594 594 594 594 594 576 598 598
Page App1.26

2.1

3, 6.1 8 3 3

6.1

5.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2733 2734 2735 2738 2739 2740 2741 2742 2743 2744 2745 2746 2747 2748 2749 2750 2751 2752 2753 2754 2757 2758 2759 2760 2761 2762 2763 2764 2771 2772 2775 2776 2777 2778 2779 2780 2781

Amines or polyamines, flammable, corrosive Amines or polyamines, liquid, corrosive, flammable Amines or polyamines, liquid, corrosive N-Butylaniline Butyric anhydride n-Propyl chloroformate Barium hypochlorite with more than 22% available chlorine Chloroformates, toxic, corrosive, flammable n-Butyl chloroformate Cyclobutyl chloroformate Chloromethyl chloroformate Phenyl chloroformate tert-Butylcyclohexyl chloroformate 2-Ethylhexyl chloroformate Tetramethylsilane 1,3-Dichloropropanol-2 Diethylthiophosphoryl chloride 1,2-Epoxy-3-ethoxypropane N-Ethylbenzyltoluidines, liquid N-Ethyltoluidines Carbamate pesticide, solid, toxic Carbamate pesticide, liquid, flammable, toxic, flash point below 23C Arsenical pesticide, solid, toxic Arsenical pesticide, liquid, flammable, toxic, flash point below 23C Organochlorine pesticide, solid, toxic Organochlorine pesticide, liquid, flammable, toxic, flash point below 23C Triazine pesticide, solid, toxic Triazine pesticide, liquid, flammable, toxic, flash point below 23C Thiocarbamate pesticide, solid, toxic Thiocarbamate pesticide, liquid, flammable, toxic, flash point below 23C Copper based pesticide, solid, toxic Copper based pesticide, liquid, flammable, toxic, flash point below 23C Mercury based pesticide, solid, toxic Mercury based pesticide, liquid, flammable, toxic, flash point below 23C Substituted nitrophenol pesticide, solid, toxic Substituted nitrophenol pesticide, liquid, flammable, toxic, flash point below 23C Bipyridilium pesticide, solid, toxic

3 8 8 6.1 8 6.1 5.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3 6.1 8 3 6.1 6.1 6.1 3 6.1 3 6.1 3 6.1 3 6.1 3 6.1 3 6.1 3 6.1 3 6.1

8 3

I, II, III I, II I, II, III II III I II II II II II II III II I II II III III II I, II, III I, II I, II, III I, II I, II, III I, II I, II, III I, II I, II, III I, II I, II, III I, II I, II, III I, II I, II, III

520, 521 522 522 598 557 598 598 598 598 598 598 598 598 598 596 528 557 597 598 598 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579

3, 8 6.1 3, 8 3, 8 3, 8 8 8 8

6.1 6.1 6.1

6.1 6.1

6.1

6.1

6.1

I, II I, II, III

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code


Page App1.27

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2782 2783 2784 2785 2786 2787 2788 2789 2790 2793 2794 2795 2796 2797 2798 2799 2800 2801 2802 2803 2805 2806 2807 2809 2810 2811 2812 2813 2814 2815 2817 2818 2819 2820 2821 2822 2823 2826 2829 2830 2831 2834 2835 2837 2838 2839 2840 2841

Bipyridilium pesticide, liquid, flammable, toxic, flash point below 23C Organophosphorus pesticide, solid, toxic Organophosphorus pesticide, liquid, flammable, toxic, flash point below 23C 4-Thiapentanal Organotin pesticide, solid, toxic Organotin pesticide, liquid, flammable, toxic, flash point below 23C Organotin compound, liquid Acetic acid, glacial or solution Acetic acid solution Ferrous metal borings, shavings, turnings or cuttings Batteries, wet, filled with acid Batteries, wet, filled with alkali Sulphuric acid with not more than 51% acid or battery fluid, acid Battery fluid, alkali Phenylphosphorus dichloride Phenylphosphorus thiodichloride Batteries, wet, non-spillable type Dye or dye intermediate, liquid, corrosive Copper chloride Gallium Lithium hydride, fused solid Lithium nitride Magnetized material Mercury Toxic liquid, organic Toxic solid, organic Sodium aluminate, solid Water-reactive solid Infectious substance affecting humans N-Aminoethylpiperazine Ammonium hydrogendifluoride solution Ammonium polysulphide solution Amyl acid phosphate Butyric acid Phenol solution 2-Chloropyridine Crotonic acid Ethyl chlorothioformate Caproic acid Lithium ferrosilicon 1,1,1-Trichloroethane Phosphorous acid Sodium aluminium hydride Bisulphates, aqueous solution Vinyl butyrate, stabilized Aldol Butyraldoxime Di-n-amylamine

3 6.1 3 6.1 6.1 3 6.1 8 8 4.2 8 8 8 8 8 8 8 8 8 8 4.3 4.3 8 6.1 6.1 4.3 6.2 8 8 8 8 8 6.1 6.1 8 8 8 4.3 6.1 8 4.3 8 3 6.1 3 3

6.1

I, II I, II, III

579 579 579 598 579 579 594 551 551 598 557 557 557 557 557 557 557 557 598 598 594 594 595 598 598 598 595 598 598 557 557 557 557 557 504 598 557 557 557 594 576 557 594 557 520 598 597 597
Page App1.28

6.1

I, II III I, II, III I, II I, II, III II II, III III

6.1 3

II II II II I, II, III III III II I III I, II, III I, II, III I, II, III 6.1 6.1 III II, III II, III III III II, III II III II III II III III II II, III II II III III

6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2842 2844 2845 2846 2849 2850 2851 2852 2853 2854 2855 2856 2857 2858 2859 2861 2862 2863 2864 2865 2869 2870 2871 2872 2873 2874 2875 2876 2878 2879 2880 2881 2900 2901 2902 2903 2904 2905 2907 2908 2909

2910 2911 2912

Nitroethane Calcium manganese silicon Pyrophoric liquid, organic Pyrophoric solid, organic 3-Chloropropanol-1 Propylene tetramer Boron trifluoride dihydrate Dipicryl sulphide, wetted Magnesium fluorosilicate Ammonium fluorosilicate Zinc fluorosilicate Fluorosilicates Refrigerating machines Zirconium, dry, coiled wire, finished metal sheets, strip Ammonium metavanadate Ammonium polyvanadate Vanadium pentoxide Sodium ammonium vanadate Potassium metavanadate Hydroxylamine sulphate Titanium trichloride mixture Aluminium borohydride or aluminium borohydride in devices Antimony powder Dibromochloropropanes Dibutylaminoethanol Furfuryl alcohol Hexachlorophene Resorcinol Titanium sponge granules or sponge powders Selenium oxychloride Calcium hypochlorite, hydrated or Calcium hypochlorite hydrated mixture Metal catalyst, dry Infectious substance affecting animals only Bromine chloride Pesticide, liquid, toxic Pesticide, liquid, toxic, flammable Chlorophenolates or phenolates, liquid Chlorophenolates or phenolates, solid Isosorbide dinitrate mixture Radioactive material, excepted package, empty packaging Radioactive material, excepted package, articles manufactured from natural uranium or depleted uranium or natural thorium Radioactive material, excepted package, limited quantity of material Radioactive material, excepted package, instruments or articles Radioactive material, low specific activity (LSA-I)

3 4.3 4.2 4.2 6.1 3 8 4.1 6.1 6.1 6.1 6.1 2.2 4.1 6.1 6.1 6.1 6.1 6.1 8 8 4.2 6.1 6.1 6.1 6.1 6.1 6.1 4.1 8 5.1 4.2 6.2 2.3 6.1 6.1 8 8 4.1 7 7 5.1, 8 3 6.1

III III I I III III II I III III III III III II II III II II III II, III I III II, III III III III III III I II, III I, II, III

530 594 598 598 528 597 557 598 594 594 594 594 550 598 594 594 594 594 598 557 557 594 598 579 528 528 515 504 598 557 594 598 598 550 579 579 557 557 598 097 097

4.3

I, II, III I, II, III III III II

7 7 7

097 097 097

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code


Page App1.29

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2913 2915 2916 2917 2919 2920 2921 2922 2923 2924 2925 2926 2927 2928 2929 2930 2931 2933 2934 2935 2936 2937 2940 2941 2942 2943 2945 2946 2947 2948 2949 2950 2956 2965 2966 2967 2968 2969 2977 2978 2983 2984 2985 2986

Radioactive material, surface contaminated objects (SCO-I or SCOII) Radioactive material, Type A package Radioactive material, Type B(U) package Radioactive material, Type B(M) package Radioactive material, transported under special arrangement Corrosive liquid, flammable Corrosive solid, flammable Corrosive liquid, toxic Corrosive solid, toxic Flammable liquid, corrosive Flammable solid, corrosive, organic Flammable solid, toxic, organic Toxic liquid, corrosive, organic Toxic solid, corrosive, organic Toxic liquid, flammable, organic Toxic solid, flammable, organic Vanadyl sulphate Methyl-2-chloropropionate Isopropyl-2-chloropropionate Ethyl-2-chloropropionate Thiolactic acid alpha-Methylbenzyl alcohol, liquid 9-Phosphabicyclononanes (Cyclooctadiene phosphines) Fluoroanilines 2-Trifluoromethylaniline Tetrahydrofurfurylamine N-Methylbutylamine 2-Amino-5-diethylaminopentane Isopropyl chloroacetate 3-Trifluoromethylaniline Sodium hydrosulphide Magnesium granules, coated 5-tert-Butyl-2,4,6-trinitro-m-xylene (musk xylene) Boron trifluoride dimethyl etherate Thioglycol Sulphamic acid Maneb, stabilized or maneb preparation, stabilized Castor beans, meal, pomace or flake Radioactive material, uranium hexafluoride, fissile Radioactive material, uranium hexafluoride Ethylene oxide and propylene oxide mixture Hydrogen peroxide, aqueous solution, with not less than 8% but less than 20% hydrogen peroxide Chlorosilanes, flammable, corrosive Chlorosilanes, corrosive, flammable

7 7 7 7 7 8 8 8 8 3 4.1 4.1 6.1 6.1 6.1 6.1 6.1 3 3 3 6.1 6.1 4.2 6.1 6.1 3 3 6.1 3 6.1 8 4.3 4.1 4.3 6.1 8 4.3 9 7 7 3 5.1 3 8 8 3 3 4.1 6.1 6.1 8 8 6.1 8 8 3 4.1 I, II I, II I, II, III I, II, III I, II, III II, III II, III I, II I, II I, II I, II II III III III II III II III III III II III III II II III III I II III III II

097 097 095, 096, 097 or 098 095, 096, 097 or 098 095, 096, 097 or 098 557 557 557 557 596, 597 598 598 598 598 598 598 594 597 597 597 598 528 598 598 598 597 596 598 597 598 594 598 598 598 598 557 579 598 097 097 I III II II 596 574 520 522
Page App1.30

3, 8

8 8 6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

2987 2988

Chlorosilanes, corrosive Chlorosilanes, water reactive, flammable, corrosive. 2989 Lead phosphate dibasic 2990 Life saving appliances, self-inflating 2991 Carbamate pesticide, liquid, toxic, flammable, flash point not less than 23C 2992 Carbamate pesticide, liquid, toxic 2993 Arsenical pesticide, liquid, toxic, flammable, flash point not less than 23C 2994 Arsenical pesticide, liquid, toxic, 2995 Organochlorine pesticide, liquid, toxic, flammable, flash point not less than 23C 2996 Organochlorine pesticide, liquid, toxic 2997 Triazine pesticide, liquid, toxic, flammable, flash point not less than 23C 2998 Triazine pesticide, liquid, toxic 3005 Thiocarbamate pesticide, liquid, toxic, flammable, flash point not less than 23C 3006 Thiocarbamate pesticide, liquid, toxic 3009 Copper based pesticide, liquid, toxic, flammable, flash point not less than 23C 3010 Copper based pesticide, liquid, toxic 3011 Mercury based pesticide, liquid, toxic, flammable, flash point not less than 23C 3012 Mercury based pesticide, liquid, toxic 3013 Substituted nitrophenol pesticide, liquid, toxic, flammable, flash point not less than 23C 3014 Substituted nitrophenol pesticide, liquid, toxic 3015 Bipyridilium pesticide, liquid, toxic, flammable, flash point not less than 23C 3016 Bipyridilium pesticide, liquid, toxic 3017 Organophosphorus pesticide, liquid, toxic, flammable, flash point not less than 23C 3018 Organophosphorus pesticide, liquid, toxic 3019 Organotin pesticide, liquid, toxic, flammable, flash point not less than 23C 3020 Organotin pesticide, liquid, toxic 3021 Pesticide, liquid, flammable, toxic, flash point less than 23C 3022 1,2-Butylene oxide, stabilized 3023 2-Methyl-2-heptanethiol

8 4.3 4.1 9 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3 3 6.1

3, 8

II I II, III

522 522 594 598 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 579 520 598

I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III

I, II, III I, II, III I, II, III I, II, III

I, II, III I, II, III I, II II I

6.1 3

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code


Page App1.31

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3024 3025 3026 3027 3028 3048 3051 3052 3053 3054 3055 3056 3057 3064 3065 3066 3070 3071 3072 3073 3076 3077 3078 3079 3080 3082 3083 3084 3085 3086 3087 3088 3089 3090 3091 3092 3093 3094 3095 3096 3098 3099 3101

Coumarin derivative pesticide, liquid, flammable, toxic, flash point less than 23OC Coumarin derivative pesticide, liquid, toxic, flammable, flash point not less than 23C Coumarin derivative pesticide, liquid, toxic Coumarin derivative pesticide, solid, toxic Batteries, dry, containing potassium hydroxide, solid Aluminium phosphide pesticide Aluminium alkyls Aluminium alkyl halides, liquid Magnesium alkyls Cyclohexyl mercaptan 2-(2-Aminoethoxy) ethanol n-Heptaldehyde Trifluoroacetyl chloride Nitroglycerin, solution in alcohol Alcoholic beverages Paint or Paint related material Ethylene oxide and dichlorodifluoromethane mixture Mercaptans, liquid, toxic, flammable or mercaptan mixture, liquid, toxic, flammable Life-saving appliances not self-inflating Vinylpyridines, stabilized Aluminium alkyl hydrides Environmentally hazardous substance, solid Cerium, turnings or gritty powder Methacrylonitrile, stabilized Isocyanates, toxic, flammable or isocyanate solution, toxic, flammable Environmentally hazardous substance, liquid Perchloryl fluoride Corrosive solid, oxidizing Oxidizing solid, corrosive Toxic solid, oxidizing Oxidizing solid, toxic Self-heating solid, organic Metal powder, flammable Lithium batteries Lithium batteries contained in equipment or packed with equipment 1-Methoxy-2-propanol Corrosive liquid, oxidizing Corrosive liquid, water-reactive Corrosive solid, self-heating Corrosive solid, water-reactive Oxidizing liquid, corrosive Oxidizing liquid, toxic Organic peroxide type B, liquid

3 6.1 6.1 6.1 8 6.1 4.2 4.2 4.2 3 8 3 2.3 3 3 8 2.2 6.1 9 6.1 4.2 9 4.3 3 6.1 9 2.3 8 5.1 6.1 5.1 4.2 4.1 9 9 3 8 8 8 8 5.1 5.1 5.2

6.1 3

I, II I, II, III I, II, III I, II, III

579 579 579 579 557

4.3 4.3 4.3

I I I I III III III II II, III II, III II

579 594 594 594 597 557 530 550 596 340, 341 557 550 598 598 598 594 595 598 520 522 595 550 557 598 598 598 598 598 598 598 527 557 557 557 557 598 598 522
Page App1.32

3, 8 4.3

II I III II I II III

6.1 3

5.1 5.1 8 5.1 6.1

I, II I, II, III I, II I, II, III II, III II, III II II III I, II I, II I, II I, II I, II, III I, II, III

5.1 4.3 4.2 4.3 8 6.1 1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3102 3103 3104 3105 3106 3107 3108 3109 3110 3122 3123 3124 3125 3126 3128 3129 3130 3131 3134 3136 3138 3139 3140 3141 3142 3143 3144 3145 3146 3147 3148 3149 3150 3151 3152 3153 3154 3155 3156 3157 3158 3159 3160 3161 3162 3163 3164 3165

Organic peroxide type B, solid Organic peroxide type C, liquid Organic peroxide type C, solid Organic peroxide type D, liquid Organic peroxide type D, solid Organic peroxide type E, liquid Organic peroxide type E, solid Organic peroxide type F, liquid Organic peroxide type F, solid Toxic liquid, oxidizing Toxic liquid, water-reactive Toxic solid, self-heating Toxic solid, water-reactive Self-heating solid, corrosive, organic Self-heating solid, toxic, organic Water-reactive liquid, corrosive Water-reactive liquid, toxic Water-reactive solid, corrosive Water-reactive solid, toxic Trifluoromethane, refrigerated liquid Ethylene, acetylene and propylene mixture, refrigerated liquid Oxidizing liquid Alkaloids, liquid or alkaloid salts, liquid Antimony compound, inorganic, liquid Disinfectant, liquid, toxic Dyes or dye intermediate, solid, toxic Nicotine compounds or preparations, liquid Alkylphenols, liquid Organotin compounds, solid Dye, solid, corrosive or dye intermediate, solid, corrosive Water-reactive liquid Hydrogen peroxide and peroxyacetic acid mixture Devices, small, or refills, hydrocarbon gas powered Polyhalogenated biphenyls or terphenyls, liquid Polyhalogenated biphenyls or terphenyls, solid Perfluoro(methyl vinyl ether) Perfluoro(ethyl vinyl ether) Pentachlorophenol Compressed gas, oxidizing Liquefied gas, oxidizing Gas, refrigerated liquid 1,1,1,2-Tetrafluoroethane (R 134a) Liquefied gas, toxic, flammable Liquefied gas, flammable Liquefied gas, toxic Liquefied gas Articles, pressurized pneumatic or hydraulic Aircraft hydraulic power unit fuel tank

5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 5.2 6.1 6.1 6.1 6.1 4.2 4.2 4.3 4.3 4.3 4.3 2.2 2.1 5.1 6.1 6.1 6.1 6.1 6.1 8 6.1 8 4.3 5.1 2.1 9 9 2.1 2.1 6.1 2.2 2.2 2.2 2.2 2.3 2.1 2.3 2.2 2.2 3

5.1 4.3 4.2 4.3 8 6.1 8 6.1 8 6.1

I, II I, II I, II I, II II, III II, III I, II, III I, II, III I, II, III I, II, III

522 522 522 522 522 522 522 522 522 598 598 598 598 598 598 598 598 598 598 542 542 598 598 594 515 598 579 504 594 557 598 522 550

I, II, III I, II, III III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III 8 I, II, III II

II II

576 576 550 550 598 550 550 542 550 550 550 550 550 550 596
Page App1.33

5.1 5.1 2.1

II

6.1, 8

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3166 3167 3168 3169 3170 3171 3172 3174 3175 3176 3178 3179 3180 3181 3182 3183 3184 3185 3186 3187 3188 3189 3190 3191 3192 3194 3200 3205 3206 3208 3209 3210 3211 3212 3213 3214 3215 3216 3218 3219 3220 3221 3222 3223 3224

Engines, internal combustion or vehicle, flammable gas powered or vehicle, flammable liquid powered Gas sample, non-pressurized, flammable Gas sample, non-pressurized, toxic, flammable Gas sample, non-pressurized, toxic Aluminium smelting by-products or aluminium remelting by-products Battery powered vehicle or equipment Toxins, extracted from living sources, liquid Titanium disulphide Solids containing flammable liquid Flammable solid, organic, molten Flammable solid, inorganic Flammable solid, toxic, inorganic Flammable solid, corrosive, inorganic Metal salts of organic compounds, flammable Metal hydrides, flammable Self-heating liquid, organic Self-heating liquid, toxic, organic Self-heating liquid, corrosive, organic Self-heating liquid, inorganic Self-heating liquid, toxic, inorganic Self-heating liquid, corrosive, inorganic Metal powders, self-heating Self-heating solid, inorganic Self-heating solid, toxic, inorganic Self-heating solid, corrosive, inorganic Pyrophoric liquid, inorganic Pyrophoric solid, inorganic Alkaline earth metal alcoholates Alkali metal alcoholates, self-heating, corrosive Metallic substance, water-reactive Metallic substance, water-reactive, self heating Chlorates, inorganic, aqueous solution Perchlorates, inorganic, aqueous solution Hypochlorites, inorganic Bromates, inorganic, aqueous solution Permanganates, inorganic, aqueous solution Persulphates, inorganic Persulphates, inorganic, aqueous solution Nitrates, inorganic, aqueous solution Nitrites, inorganic, aqueous solution Pentafluoroethane (R 125) Self-reactive liquid type B Self-reactive solid type B Self-reactive liquid type C Self-reactive solid type C

2.1 2.3 2.3 4.3 6.1 4.2 4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.2 4.3 4.3 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 2.2 4.1 4.1 4.1 4.1 2.1 II, III I, II, III III II II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III II, III I I II, III II, III I, II, III I, II, III II, III II, III II II, III II III III II, III II, III 1 1

802 550 550 550 598 809 598 594 598 598 598 598 598 598 594 598 598 557 598 598 557 598 598 598 557 598 598 594 594 598 598 598 598 598 598 598 598 598 598 598 550 598 598 598 598
Page App1.34

6.1 8

6.1 8 6.1 8 6.1 8

8 4.2

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3225 3226 3227 3228 3229 3230 3241 3242 3243 3244 3245 3246 3247 3248 3249 3250 3251 3252 3253 3254 3256 3257 3258 3259 3260 3261 3262 3263 3264 3265 3266 3267 3268 3269 3270 3271 3272 3273 3274 3275 3276 3277 3278 3279 3280 3281 3282 3283 3284 3285 3286 3287 3288 3289

Self-reactive liquid type D Self-reactive solid type D Self-reactive liquid type E Self-reactive solid type E Self-reactive liquid type F Self-reactive solid type F 2-Bromo-2-nitropropane-1,3-diol Azodicarbonamide Solids containing toxic liquid Solids containing corrosive liquid Genetically modified micro-organisms Methanesulphonyl chloride Sodium peroxoborate, anhydrous Medicine, liquid, flammable, toxic Medicine, solid, toxic Chloroacetic acid, molten Isosorbide-5-mononitrate Difluoromethane (R32) Disodium trioxosilicate Tributylphosphane Elevated temperature liquid, flammable Elevated temperature liquid Elevated temperature solid Amines or polyamines, solid, corrosive Corrosive solid, acidic, inorganic Corrosive solid, acidic, organic Corrosive solid, basic, inorganic Corrosive solid, basic, organic Corrosive liquid, acidic, inorganic Corrosive liquid, acidic, organic Corrosive liquid. basic, inorganic Corrosive liquid, basic, organic Air bag inflators or modules or seat belt pretensioners Polyester resin kit Nitrocellulose membrane filters Ethers Esters Nitriles, flammable, toxic Alcoholates solution, in alcohol Nitriles, toxic, flammable Nitriles, toxic, liquid Chloroformates, toxic, corrosive Organophosphorus compound, toxic, liquid Organophosphorus compound, toxic, flammable Organoarsenic compound, liquid Metal carbonyls, liquid Organometallic compound, toxic, liquid Selenium compound, solid Tellurium compound Vanadium compound Flammable liquid, toxic, corrosive Toxic liquid, inorganic Toxic solid, inorganic Toxic liquid, corrosive, inorganic

4.1 4.1 4.1 4.1 4.1 4.1 4.1 4.1 6.1 8 9 6.1 5.1 3 6.1 6.1 4.1 2.1 8 4.2 3 9 9 8 8 8 8 8 8 8 8 8 9 3 4.1 3 3 3 3 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3 6.1 6.1 6.1

III II II II 8 6.1 8 I II II, III II, III II III III I III III III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III III II, III II II, III II, III I, II II I, II I, II, III II I, II, III I, II I, II, III I, II, III I, II, III I, II, III I, II, III I, II, III I, II I, II, III I, II, III I, II

598 598 598 598 598 598 598 598 598 557 598 557 598 514 514 557 598 550 594 598 597 598 or 733 598 522 557 557 557 557 557 557 557 557 598 521 598 529, 530 529, 530 596 596 598 598 598 598 598 598 598 598 594 594 594 596 598 598 598
Page App1.35

6.1 8 3 8 3

6.1, 8 8

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3290 3291 3292 3293 3294 3295 3296 3297 3298 3299 3300 3301 3302 3303 3304 3305 3306 3307 3308 3309 3310 3311 3312 3313 3314 3315 3316 3317 3318 3319 3320 3321 3322 3323 3324 3325 3326 3327

Toxic solid, corrosive, inorganic Clinical waste, unspecified Batteries or cells, containing sodium Hydrazine, aqueous solution with not more than 37% hydrazine Hydrogen cyanide, solution in alcohol Hydrocarbons, liquid Heptafluoropropane (R 227) Ethylene oxide and chlorotetrafluoroethane mixture Ethylene oxide and pentafluoroethane mixture Ethylene oxide and tetrafluoroethane mixture Ethylene oxide and carbon dioxide mixture Corrosive liquid, self-heating 2-Dimethylaminoethyl acrylate Compressed gas, toxic, oxidizing Compressed gas, toxic, corrosive Compressed gas, toxic, flammable,corrosive Compressed gas, toxic, oxidizing, corrosive Liquefied gas, toxic, oxidizing Liquefied gas, toxic, corrosive Liquefied gas, toxic, flammable, corrosive Liquefied gas, toxic, oxidizing, corrosive Gas, refrigerated liquid, oxidizing Gas, refrigerated liquid, flammable Organic pigments, self-heating Plastics moulding compound Chemical sample, toxic Chemical kit or First aid kit 2-Amino-4,6-dinitrophenol, wetted Ammonia solution, with more than 50% ammonia Nitroglycerin mixture, desensitized, solid Sodium borohydride and sodium hydroxide solution Radioactive material, low specific activity (LSA-II) Radioactive material, low specific activity (LSA-III) Radioactive material, type C package Radioactive material, low specific activity (LSA-II), fissile Radioactive material, low specific activity (LSA-III), fissile Radioactive material, surface contaminated objects (SCO-I or SCOII), fissile Radioactive material, Type A package, fissile

6.1 6.2 4.3 6.1 6.1 3 2.2 2.2 2.2 2.2 2.3 8 6.1 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.3 2.2 2.1 4.2 9 6.1 9 4.1 2.3 4.1 8 7 7 7 7 7 7 7

I, II II II III I I, II, III

598 598 598 557 553 596, 597 547 550 550 550

2.1 4.2 5.1 8 2.1, 8 5.1, 8 5.1 8 2.1, 8 5.1, 8 5.1 II, III III I II, III I II II, III I, II II

550 557 522 550 550 550 550 550 550 550 550 542 542 522 522 598 598 598 550 598 598 097 097 097 097 097 097 097
Page App1.36

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3328 3329 3330 3331 3332 3333 3334 3335 3336 3337 3338 3339 3340 3341 3342 3343 3344 3345 3346 3347 3348 3349 3350 3351 3352 3354 3355 3356 3357 3358 +3359 3360 3361 3362 3363

Radioactive material, Type B(U) package, fissile Radioactive material, Type B(M) package, fissile Radioactive material, type C package, fissile Radioactive material, transported under special arrangement, fissile Radioactive material, Type A package, special form Radioactive material, Type A package, special form, fissile Aviation regulated liquid Aviation regulated solid Mercaptans, liquid, flammable or mercaptan mixture, liquid, flammable Refrigerant gas R404A Refrigerant gas R407A Refrigerant gas R407B Refrigerant gas R407C Thiourea dioxide Xanthates Nitroglycerin mixture, desensitized, liquid, flammable Pentaerythrite tetranitrate mixture, desensitized, solid Phenoxyacetic acid derivative pesticide, solid, toxic Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic, flash point below 23C Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flash point not less than 23C Phenoxyacetic acid derivative pesticide, liquid, toxic Pyrethroid pesticide, solid, toxic Pyrethroid pesticide, liquid, flammable, toxic, flash point below 23C Pyrethroid pesticide, liquid, toxic, flammable, flash point not less than 23C Pyrethroid pesticide, liquid, toxic Insecticide gas, flammable Insecticide gas, toxic, flammable Oxygen generator, chemical Nitroglycerin mixture, desensitized, liquid Refrigerating machines, containing flammable, non-toxic, liquefied gas Fumigated unit Fibres, vegetable, dry Chlorosilanes, toxic, corrosive, Chlorosilanes, toxic, corrosive, flammable Dangerous goods in machinery or apparatus

7 7 7 7 7 7 3 2.2 2.2 2.2 2.2 4.2 4.2 3 4.1 6.1 3 6.1 6.1 6.1 3 6.1 6.1 2.1 2.3 5.1 3 2.1 9 6.1 6.1 6.1 3 6.1 3

095, 096, 097 or 098 095, 096, 097 or 098 097 095, 096, 097 or 098 097 097 595 595 596, 597 547 547 547 547 598 598 596, 597 598 579 579 579 579 579 579 579 579 550 550 598 596 550 598 595 598 598 801 or 802
Page App1.37

I, II, III

II, III II, III II I, II, III I, II I, II, III I, II, III I, II, III I, II I, II, III I, II, III 2.1 II II

8 3, 8

II II

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3364 3365 3366 3367 3368 3369 3370 3371 3373 3374 3375 3376 3377 3378 3379 3380 3381 3382 3383 3384 3385 3386 3387 3388 3389 3390 3391 3392 3393 3394 3395 3396 3397 3398 3399 3400 3401 3402 3403 3404 3405 3406

Trinitrophenol (Picric acid), wetted Trinitrochlorobenzene (Picryl chloride), wetted Trinitrotoluene (TNT), wetted Trinitrobenzene, wetted Trinitrobenzoic acid, wetted Sodium dinitro-o-cresolate, wetted Urea nitrate, wetted 2-Methylbutanal Diagnostic specimens or clinical specimens Acetylene, solvent free Ammonium nitrate emulsion, suspension or gel 4-Nitrophenylhydrazine Sodium perborate monohydrate Sodium carbonate peroxyhydrate Desensitized explosive, liquid Desensitized explosive, solid Toxic by inhalation liquid Toxic by inhalation liquid Toxic by inhalation liquid, flammable Toxic by inhalation liquid, flammable Toxic by inhalation liquid, waterreactive Toxic by inhalation liquid, waterreactive Toxic by inhalation liquid, oxidizing Toxic by inhalation liquid, oxidizing Toxic by inhalation liquid, corrosive Toxic by inhalation liquid, corrosive Organometallic substance, solid, pyrophoric Organometallic substance, liquid, pyrophoric Organometallic substance, solid, pyrophoric, water-reactive Organometallic substance, liquid, pyrophoric, water-reactive Organometallic substance, solid, waterreactive Organometallic substance, solid, waterreactive, flammable Organometallic substance, solid, waterreactive, self-heating Organometallic substance, liquid, water-reactive Organometallic substance, liquid, water-reactive, flammable Organometallic substance, solid, selfheating Alkali metal amalgam, solid Alkaline earth metal amalgam, solid Potassium metal alloys, solid Potassium sodium alloys, solid Barium chlorate solution Barium perchlorate solution

4.1 4.1 4.1 4.1 4.1 4.1 4.1 3 6.2 2.1 5.1 4.1 5.1 5.1 3 4.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 4.2 4.2 4.2 4.2 4.3 4.3 4.3 4.3 4.3 4.2 4.3 4.3 4.3 4.3 5.1 5.1 3 4.1 4.2 4.3 4.3

I I I I I I I II

598 598 598 598 598 598 598 596 598 550 598 598 594 594 596 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 598 594 594 594
Page App1.38

6.1

II I III II, III I I I I I I I I I I I I I I I I I, II, III I, II, III I, II, III I, II, III I, II, III II, III I I I I II, III II, III

3 3 4.3 4.3 5.1 5.1 8 8

6.1 6.1

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3407 3408 3409 3410 3411 3413 3414 3415 3416 3417 3418 3419 3420 3421 3422 3423 3424 3425 3426 3427 3428 3429 3430 3431 3432 3433 3434 3435 3436 3437 3438 3439 3440 3441 3442 3443 3444 3445 3446 3447 3448 3449 3450 3451 3452 3453 3454 3455 3456 3457 3458 3459

Chlorate and magnesium chloride mixture solution Lead perchlorate solution Chloronitrobenzenes, liquid 4-Chloro-o-toluidine hydrochloride solution beta-Napthylamine solution Potassium cyanide solution Sodium cyanide solution Sodium fluoride solution Chloroaceto-phenone, liquid Xylyl bromide, solid 2,4-Toluylenediamine solution Boron trifluoride acetic acid complex, solid Boron trifluoride propionic acid complex, solid Potassium hydrogendifluoride solution Potassium fluoride solution Tetramethylammonium hydroxide, solid Ammonium dinitro-o-cresolate solution Bromoacetic acid, solid Acrylamide solution Chlorobenzyl chlorides, solid 3-Chloro-4-methylphenyl isocyanate, solid Chlorotoluidines, liquid Xylenols, liquid Nitrobenzotrifluorides, solid Polychlorinated biphenyls, solid Lithium alkyls, solid Nitrocresols, liquid Hydroquinone solution Hexafluoroacetone hydrate, solid Chlorocresols, solid alpha-Methylbenzyl alcohol, solid Nitriles, toxic, solid Selenium compound, liquid Chlorodinitrobenzenes, solid Dichloroanilines, solid Dinitrobenzenes, solid Nicotine hydrochloride, solid Nicotine sulphate, solid Nitrotoluenes, solid Nitroxylenes, solid Tear gas substance, solid Bromobenzyl cyanides, solid Diphenylchloroarsine, solid Toluidines, solid Xylidines, solid Phosphoric acid, solid Dinitrotoluenes, solid Cresols, solid Nitrosylsulphuric acid, solid Chloronitrotoluenes, solid Nitroanisoles, solid Nitrobromobenzenes, solid

5.1 5.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 8 8 6.1 8 6.1 8 6.1 6.1 6.1 6.1 6.1 6.1 9 4.2 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 6.1 6.1 8 6.1 6.1 6.1 6.1 6.1

II, III II, III II III II, III I, II, III I, II, III III II II III II II II, III III II II, III II III III II III II II II I III III II II III I, II, III I, II, III II II II II II II II I, II I I II II III II II II III III III

579 594 598 598 598 594 594 594 598 576 598 557 557 557 598 557 598 557 522 598 522 598 504 598 576 594 598 598 598 598 528 598 594 598 598 598 579 579 598 598 598 598 598 598 598 555 598 504 557 598 598 598
Page App1.39

4.3

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

3460 3461 3462 3464 3465 3466 3467 3468

N-Ethylbenzyltoluidines, solid Aluminium alkyl halides, solid Toxins, extracted from living sources, solid Organophosphorus compound, toxic, solid Organoarsenic compound, solid Metal carbonyls, solid Organometallic compound, toxic, solid Hydrogen in a metal hydride storage system

6.1 4.2 6.1 6.1 6.1 6.1 6.1 2.1

4.3

III I I, II, III I, II, III I, II, III I, II, III I, II, III

598 594 598 598 598 598 598 550

734 to be used for Gas condensate Class 3. Packages, containers and wagons are not required to bear a hazard warning label or placard There are no dangerous goods requirements that apply to rail transport but there may be for other modes of transport

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

TOPS. Commodity Code


Page App1.40

Dangerous Goods Class

Subsidiary Risk(s)

Substance

Packing Group

UN No

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

1.2

UN8989
Dangerous Goods Class Subsidiary Risk(s) Packing Group TOPS. Commodity Code 598, 873, 882, 950

UN No 8989

Substance Mixed loads of differing dangerous goods classes and groupage (various) traffic

1.3

D.G. Class 1 Explosive Emergency and Commodity Codes


Dangerous Goods Class Subsidiary Risk(s) Packing Group TOPS. Commodity Code 889 888 890

UN No

Substance

1.3.1

Military
011 012, 014, 016 013, 015

1.3.2

Commercial
011 012, 014, 016 013, 015

532 533 534

1.4

Containerised Traffic Dangerous Goods Class and TOPS Commodity Code When dangerous goods are permitted to be carried in full container loads TOPS Commodity Code 950 will apply except as shown below. Exceptions to using Code 950 (a) Traffics which are allocated United Nations numbers which could be identified with more than one of the dangerous goods Classes 2.1, 2.2 or 3 must be allocated the following: Traffic TOPS Commodity Code Flammable liquids Class 3 Packing groups I & II 951 Flammable liquids Class 3 Packing group III 952 Aerosols Class 2.1 953 Aerosols Class 2.2 954

1.4.1 Full loads Code 950

1.4.2

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

Page App1.41

Appendix

Document Withdrawn as of April 2009 Unontrolled When Printed

GO/RT3053/1 Issue 3 June 2006

(b) When more than one of these D.G. classes or packing groups are carried on the same wagon, the following to be used: Dangerous goods Class 3 Packing groups I & II with Class 3 Packing group III Dangerous goods Classes 2.2 & 3 Packing group III 1.4.3 Class 1 traffic, explosives Division 1.1 Division 1.2, 1.4 or 1.6 Division 1.3 or 1.5 951 952

955 956 957

Working Manual for Rail Staff

Handling and Carriage of Dangerous Goods

Page App1.42