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Quantitative Analysis of Soda Ash by Double Indicator Titration

Kelvin L. Labarez
Department of Materials, Metallurgical and Mining Engineering College Engineering University of the Philippines, Diliman Quezon City, Philippines January 22, 2013 Prof. Gillian Macusi

INTRODUCTION The purpose of this experiment is to familiarize students with double indicator titration. Polyprotic acids and bases release or absorb more than one mole of H+ or OH- per mole of analyte. This means that a simple titration is not enough to determine the analyte composition. Using the relationship between the main component (Sodium Carbonate) with its dissociated components, the composition of Soda Ash can be determined. METHODOLOGY 500ml of 1.0M stoch HCl was prepared, and from there 500ml of 0.050M HCl was prepared. Into three Erlenmeyer Flasks, 0.1g of Na2CO3 was added to each. Each flask was filled with 50ml of boiled distilled water and mixed. These were then added with 3 drops of methyl orange then titrated. At the point when the solution turns from yellow to orange, titration is temporarily stopped and the solutions are boiled. If the solution turns red, it means it has been overtitrated. Since Na2CO3 reacts slowly, there may be a chance that the solution has already been added with too much HCl but the reaction has not yet manifested. There may also be CO2 gas developing within the reaction, and this leaves excess H+. To deal with this problem, the titration is stopped when the equivalence point is near, and the solution is boiled to catalize and complete the reaction. This ensures that the appropriate amount of titrant

was added. After boiling, the solution is further titrated to completion.[1] For the sample, 0.1g of soda ash is used and 50ml of boiled distilled water, all of these are added to Erlenmeyer flasks for three trials. Phenolphthalein is added then the solutions are titrated. After the titration of phenolphthalein is complete, Methyl Orange is used and titrated. It is stopped midway similar to what was done earlier. RESULTS AND DISCUSSION A. Standardization of HCl The exact concentration of stored titrant may not be completely accurate. It is necessary to know the exact concentration of the titrant to know the exact concentration of the analyte. A primary standard of Na2CO3 of known 99.9% purity is used. The reaction is as follows. Na2CO3 + 2HCl <-> 2NaCl + H2CO3 A solution with Methyl Orange indicator changes color when all CO3 2- has been converted to H2CO3. In the reaction, every two moles of HCl corresponds to a mole of Na2CO3. Using the known mass of the primary standard, it formula mass, the stoichiometric ratio of HCl and Na2CO3 and the volume of the titrant. The concentration of the titrant can be determined. B. Analysis of Soda Ash

it means that there is more HCO3than CO3 2. and the solution contains Na2CO3 and amounts of NaHCO3. the amount of HCl used indicates the amount of HCO3.to react with.remains.3 Trial 3 2. the pOH is given by√ .+ OHHCO3.The main component in this experiment is Na2CO3. There are two equations involved in this scenario.. some of the NaHCO3 comes from the Na2CO3. the amount of HCl used indicates the amount of CO32.+ H2O <-> H2CO3 + OHWhen the solution is titrated with HCl. Table 1: Titrant used in each trial Volume of HCl used 1st Titration 2nd Titration Trial 1 1. [HCl] 1st titration = [Na2CO3]total The volume of the second titration can be related to NaHCO3.has been “used up”.is the same as the total amount of HCO3.. If the amount of HCl used in the first titration (amount to reach the phenolphthalein indicated pH) is greater than the second titration (amount to reach the methyl orange indicated pH). The additional NaHCO3 is an impurity.366666667 3.+ H2O <-> HCO3. The results of the titrations are shown in table 1. Methyl orange changes the solution color also at the point when all the HCO3. there is no Na2CO3 present and it contains only NaHCO3.5 3.33 which is approximately the point when a solution with drops of phenolphthalein indicator changes from colorless to pink and vice versa. when all that remains is HCO3-. CO3 2. it means that the solution contains strong bases in addition to Na2CO3.to react with. If they are equal.. the volume of the first titration can be related to the concentration of Na2CO3. This indicates that all that any strong bases in addition to CO3 2.7 3 Trial 2 2.[Na2CO3]total = [NaHCO3]from impurities Therefore g Na2CO3 total x100% = g NaHCO3 total % g Na2CO3 . If the solution is immediately colorless at the addition of phenolphthalein. that means that there was no Na2CO3 and it only contains a strong base. it may contain small amounts of Na2CO3 or NaOH. If after the first titration. then only Na2CO3 is present. If the HCl used in the first is less than the second. [2] At this point only HCO3. The HCl has a 1:1 mole ratio with OH. Therefore.and CO3 2-(with respect to the first reaction only).6 Average 2. the moles of CO3 2. Its pH given by 14-pOH is 8.that can be generated as the solution is titrated.Therefore. C. [NaHCO3]total . the solution is already orange. The moles of of H+ from HCl is equal the moles of CO32.9 4. %Composition of Soda Ash Since Na2CO3 reacts first. If the solution contains just Na2CO3.is used up.[3] Soda Ash is an impure solution of Na2CO3.633333333 From this we can conclude that the solution contains Na2CO3 and NaHCO3. CO3 2is used up and transformed into HCO3. [HCl] 2nd titration = [NaHCO3]total However.

76% CONCLUSION While gravimetric methods can be used to measure moisture content.. Cengage Learning Asia Pte Ltd. are prone to mistaken calibration and positioning. Magnetic weight balances while accurate.J..25% (95%) to 20. Introduction to Analytical Chemistry. 1947 [2] Skoog D. REFERENCES   [1] Kolthoff I.51% range 7.41% mean 12..M. 8th ed.A. it is not precise.64% trail 3 13. M. Many external factors come into play as the sample is constantly being exposed to the air.67% RSD (ppt) 293. West D.47% trial 2 15. Holler F. Quantitative analysis with applications to agricultural and food products.R.71% standard deviation 3.. Crouch S. Pasig 2012 pp 124-186 [3] Howard Triebold.  . 1st Ed.. Minneapolis. Textbook of Quantitative Inorganic Analysis.The following summarizes important data: Table 2: Summary of Significant Data %Na2CO3 trial 1 8. It absorbs moisture as it is moved in and out of the dessicator. Show C...C.6ppt confidence limit from 4.