You are on page 1of 4

This Question Paper contains 4 printed pages


Time allowed : 3 hours ] General Instructions:

(i) (ii) (iii) (iv) (v) (vi) (vii)

[Maximum marks : 70

All questions are compulsory. Marks for each question are indicated against it. Question numbers 1 to 8 are very short-answer questions and carry 1 mark each. Question numbers 9 to 18 are short-answer questions and carry 2 marks each. Question numbers 19 to 27 are also short-answer questions and carry 3 marks each. Question numbers 28 to 30 are very long-answer questions and carry 5 marks each. Use Log Tables,if necessary. Use of calculators is not allowed.


1. 2. 3. 4. 5. 6.

What do you mean y shape selective catalysis ?1 What is a reducing sugar ? How will you cone chloroenzene into diphenyl ? Is (NH-CHR-CO)n a homopolymer or copolymer Write the structural formula of 1-phenylpentan-2-one. Write the IUPAC name of the following. CH3 | CH = CHCH3 | | CH3 Cl

1 1 1 1

7. Arrange the following in the increasing order of their basic strength. C6H5NH2 C2H5NH2 (C2H5)2NH NH3

8. What is meant by a flux ? Give an example for basic flux. 1 9. In an ionic crystal the anions (B ) form cubic close type of packing and the cations (A+) occupy one-third of the tetrahedral voids. Deduce the formula of the compound. Also find the coordination number of (A +) ion. 2 10. (i) State Kohlrauschs Law of independent migration of ions. (ii) Calculate The number of coulombs of electricity required for the oxidation of 1 mole 1

11. 12. 13. 14.










ofwater to oxygen as per the equation. 2 H2O 4H+ +O2 + 4e2 A first orderreaction takes 240 seconds for 75% completion. Find the rate constant for the reaction. 2 Write the mechanism of acid catalysed hydration of alkenes. (i) What do you mean by a copolymer ? Give one example. (ii) Draw he structures of the monomers of Nylon-6,6. 2 Explain the principles used in the following processes. 2 (i) Zone refining. (ii) Froth floatation process. Write the equations involved in the following reacions. 2 (i) Riemer-Tiemannreacion. (ii) Williamsons ether synthesis. Complete the following chemical equations. 2 (i) XeF4 + H2O (ii) H3PO3 2 heat 2 Explain the following with suitable examples. 2 (i) n-type semiconductor. (ii) Schottkydefect. Give reasons for the followings: 2 (i) Chloroform is stored in dark coloured bottles and completely filled. (ii) The dipole moment of chloroenzene is less than that of cyclohexyl chloride. What are the characteristics of the following colloids ? Give one example each. 3 (i) Micromolecular colloids. (ii) Lyophobic sol. (iii) Emulsion. Account for the following: 3 (i) NH3 is more basic than PH3 (ii) ICl is more reactive than I2 (iii) H2O is a liquid but H2S is a gas. (i) What is the basic structural difference between starch and cellulose ? (ii) What do you understand by glycosidiclinkage ? (iii) What is meant by essential amino acids ? Give an example. 3 Complete the following chemical equations. 3 (i) C6H5NH2 + Br2(aq) (ii) CH3NH2 + CHCl3 + KOH (iii) C6H5N2Cl + C6H5OH OHA person used morphine to get relief from rheumatic pain on his knee for a couple of months. When he consulted a doctor, he was advised to discontinue morphine and prescribed some other medicine for him. How will you convince him tomake use o he 2

medicine prescribed y he physician. What massage will you give to the society. What is he value associated with your work. 3 24. Drawthe structures of: 3 (i) PCl5 (ii) (HPO3)3 (iii) XeF4 25. A first order reaction takes 40 minutes for 30% completion. Calculate is half life period. 3 OR The rate of a reaction quadruples when he temperate is changedfrom 293 to 313 Calculate the energy of activation. 26. The resistance of a conductivity cell when filled with 0.05 M solution of an electrolyte X is 100 Ohms at 40oC. The same conductivity cell is filled with 0.01 M solution of electrolyte Y has a resistance of 50 Ohms. The conductivity of 0.05 M solution of electrolyte X is 1 x 10 4 S cm 1. Calculate: (i) Cell constant (ii) Conductivity of 0.01 M solution of Y (iii) Molar conductivity of the solution of Y OR Calculate the emf of the following cell at 298 K. Mg(s) /Mg2+(aq)(0.001 M) //Cu2+(aq)(0.0001 M) /Cu(s) Eo Mg2+/Mg = -2.36 V Eo Cu2+/Cu = 0.34 V Predict whether the reaction is reactant favoured or product favoured. 3 3+ 27. For the complex [CoF6] , write (i) IUPAC name (ii) Hybridisation (iii) Magnetic property [ At. No. of Co is 27] 28. (a) Define thefollowing: 5 (i) Isotonic solutions. (ii) Reverse osmosis (b) A solution containing 11 g of diethyl ether boils at 38 oC. Whereas pure ether boils at 35.6 oC. Calculate the molecular mass of the solute. [Forether Kb = 2.02 K kg mol-1] OR (a) State Henrys Law. (b) What is an azeotrope. (c) Calculate the temperature at which a solution containing 45 g of glucose (C 6H12O6) in 250 g of water will freeze.[ForwaterKf= 1.86 K kg mol-1] 29. (a) How would you Account for the following: 3

Cu+ is not stable in aqueous solution. Actinoid contraction is greater from element to element than Lanthanoid contraction. (iii) Transition metals and their compounds generally exhibit paramagnetic behaviour. (b) Complete the following equations: (i) MnO4-(aq) + S2O32-(aq) + H2O(l) (ii) Cr2O72-(aq) + Fe2+ (aq) + H+(aq) OR (i) (ii) (a) Complete following chemical equations: (i) Cr2O72-(aq) + H2S(g) + H+(aq) (ii) Cu2+(aq) + I-(aq) (b) How would you account for the following: (i) The oxidizing oxoanions are in the order VO2+< Cr2O72-< MnO4(ii) The third ionisation enthalpy of manganese (Z=25) is exceptionally high. (iii) Cr2+ is a stronger reducing agent than Fe2+ . 30.(a) Illustrate the following reactions by giving one example each. 5 (i) Cannizzaros reaction (ii) Decarboxylation (b) Complete the following reaction equations by giving the indicated missing substance.


CH3CHO (?)




(i) O3 (ii) Zn H2O (?) =CH2


OR (a) Bring out the following conversitions: (i) 4-Nitrotoluene to 2-bromobenzoic acid (ii) Ethyl cyanide to 1-phenylpentanone (b) Give a reason for the following: (i) Chloroacetic acid is more acidic than acetic acid. (ii) Carboxylic acid have higher boiling point than alcohol. (iii) 4-Nitrobenzoic acid is more acidic than 4-methoxybenzoic acid.