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SCREENING EXAMINATION

Time : 3.00 Hrs. Max. Marks : 270

GENERAL INSTRUCTIONS

1. This question paper has 90 objective type questions. Each question has four choices (A), (B), (C) and (D) out of which only one is correct. For each question you will be awarded 3 Marks if you give the correct answer and zero Mark if no answer is given. In all other cases, minus one (1) Mark will be awarded.

2.

PART-I (PHYSICS)

Directions : Select the most appropriate alternative from A, B, C and D in questions.

1.

A simple pendulum is oscillating without damping. When the displacements of the bob is less than maximum, ! its acceleration vector a is correctly shown in

(A)

(B)

!

(C)

(D)

!

2 2.

A wooden block, with a coin placed on its top, floats in water as shown in figure. The distances " and h are shown there. After some time the coin falls into the water. Then (A) " decreases and h increases (C) both " and h increase (B) " increases and h decreases (D) both l and h decrease

Coin

" #

3.

A cylinder rolls up an inclined plane, reaches some height and then rolls down (without slipping throughout this motions). The directions of the frictional force acting on the cylinder are : (A) Up the incline while ascending and down the incline while descending (B) Up the incline while ascending as well as descending (C) Down the incline while ascending and up the incline while descending (D) Down the incline while ascending as well as descending.

4.

A circular platform is free to rotate in a horizontal plane about a vertical axis passing through its centre. A tortoise is sitting at the edge of the platform. Now the platform is given an angular velocity "0. When the tortoise moves along a chord of the platform with a constant velocity (with respect to the platform), the angular velocity of the platform "(t) will vary with time t as

(A)

(B)

(C)

(D)

5.

Two blocks of masses 10kg and 4kg are connected by a spring of negligible mass and placed on a frictionless horizontal surface. An impulse gives a velocity of 14 ms 1 to the heavier block in the direction of the lighter block. Then, the velocity of the centre of mass is (A) 30 ms 1 (C) 10 ms

1

(B) 20 ms 1 (D) 5 ms 1

6.

A particle, which is constrained to move along the x-axis, is subjected to a force in the same direction which varies with the distance x of the particle from the origin as F(x) = -kx + ax3. Here k and a are positive constant. For x # 0, the functional form of the potential energy U(x) of the particle is

(A)

(B)

(C)

(D)

3 7.

A siren placed at a railway platform is emitting sound of frequency 5 kHz. A passenger sitting in a moving train A records a frequency of 5.5 kHz, while the train approaches the siren. During his return journey in a different train B he records a frequency of 6.0 kHz while approaching the same siren. The ratio of the velocity of train B to that of train A is (A)

242 252

(B) 2

(C) 8.

5 6

(D)

11 6

A sonometer wire resonates with a given tuning fork forming standing waves with five antinodes between the two bridges when a mass of 9 kg is suspended from the wire . When this mass is replaced by a mass M, the wire resonates with the same tuning fork forming three antinodes for the same positions of the bridges. The value of M is (A) 25 kg (C) 12.5 kg (B) 5 kg (D) 1/25 kg

9.

An ideal spring with spring-constant k is hung from the ceiling and a block of mass M is attached to its lower end. The mass is released with the spring initially unstretched. Then the maximum extension in the spring is (A) 4 Mg/k (C) Mg/k (B) 2 Mg/k (D) Mg/2k

10.

A geostationary satellite orbits around the earth in a circular orbit of radius 36000 km. Then, the time period of a spy satellite orbiting a few hundred kilometers above the earths surface (REarth = 6400 km) will approximately be : (A) 1/2 hr (C) 2 hr (B) 1 hr (D) 4 hr

2R 2R

11.

The effective resistance between points P and Q of the electrical circuit shown in the figure is

2R

8R(R $ r ) (B) 3R $ r

r P 2R

r Q

(C) 2r + 4R 12.

5R (D) + 2r 2

2R

2R

A particle of mass m and charge q moves with a constant velocity v along the positive x direction. It enters a region containing a uniform magnetic field B directed along the negative z direction, extending from x = a to x = b. The minimum value of v required so that the particle can just enter the region x > b is : (A)

qbB m qaB m

(B)

(C)

(D)

4 13.

Two equal point charges are fixed at x = - a and x = + a on the x - axis. Another point charge Q is placed at the origin. The change in the electrical potential energy of Q, when it is displaced by a small distance x along the x - axis, is approximately proportional to : (A) x (C) x 3 (B) x 2 (D) 1/x

14.

A long straight wire along the z % axis carries a current I in the negative z direction. The magnetic vector ! field B at a point having coordinates (x, y) in the z = 0 plane is: (A) ' 0I 2&

' 0I 2&

( y i % x j ) (x2 $y2)

( x j % y i ) (x2 $y2 )

(B)

' 0I 2&

( x i $ y j ) (x2 $y2 )

(C) 15.

(D)

' 0I 2&

( x i % y j ) (x2 $y2 )

P Q E

As shown in the figure, P and Q are two coaxial conducting loops separated by some distance. When the switch S is closed, a clockwise current (P flows in P (as seen by E) and an induced current (Q1 flows in Q. The switch remains closed for a long time. When S is opened, a current (Q2 flows in Q. Then the direction (Q1 and (Q2 (as seen by E) are-

Battery

(A) respectively clockwise and anti-clockwise (B) both clockwise (C) both anti-clockwise 16. (D) respectively anti-clockwise and clockwise A 100 W bulb B1, and two 60 W bulbs B2 and B3,. are connected to a 250 V source, as shown in the figure. Now W 1, W 2 and W 3 are the output powers of the bulbs B1, B2 and B3, respectively. Then (A) W 1 > W 2 = W 3 17. (B) W 1 > W 2 > W 3 (C) W 1 < W 2 = W 3 (D) W 1 < W 2 < W 3 Two identical capacitors have the same capacitance C. One of them is charged to potential V1 and the other to V2. The negative ends of the capacitors are connected together. When the positive ends are also connected, the decrease in energy of the combined system is :

(A)

(B)

(C) 18.

(D)

A short-circuited coil is placed in a time-varying magnetic field. Electrical power is dissipated due to the current induced in the coil. If the number of turns were to be quadrupled and the wire radius halved, the electrical power dissipated would be (A) halved (C) doubled (B) the same (D) quadrupled

5 19.

The magnetic field lines due to a bar magnet are correctly shown in :

(A)

(B)

(C)

(D)

20.

An ideal gas is taken through the cycle A ! B ! C ! A as shown in the figure. If the net heat supplied to the gas in the cycle is 5 J,the work done by the gas in the process C ! A is : (A) 5 J (C) 15 J (B) 10 J (D) 20 J

21.

Which of the following graphs correctly represents the variation of ) = (dV/dP)/V with P for an ideal gas at constant temperature ?

(A)

(B)

(C)

(D)

22.

The potential difference applied to an X-ray tube is 5 kV and the current through it is 3.2 mA. Then the number of electrons striking the target per second is: (A) 2 * 1016 (B) 5 * 1016 (C) 1 * 1017 (D) 4 * 1015 An ideal black-body at room temperature is thrown into a furnace. It is observed that (A) initially it is the darkest body and at later times the brightest. (B) it is the darkest body at all times. (C) it cannot be distinguished at all times (D) initially it is the darkest body and at later times it cannot be distinguished. A hydrogen atom and a Li++ ion are both in the second excited state. If lH & lLi are their respective electronic angular momenta and EH & ELi their respective energies, then: (A) lH > lLi and +EH+ > +ELi+ (B) lH = lLi and +EH+ < +ELi+ (C) lH = lLi and +EH+ > +ELi+ (D) lH < lLi and +EH+ < +ELi+

23.

24.

6 25.

The half life of 215At is 100 's. The time taken for the radioactivity of a sample of of its initial value is: (A) 400 's (C) 40 's (B) 6.3 's (D) 300 's (B) AX Z + 1n0 -! A % 3X Z % 2 + c (D) AX Z + e%1 -! AX Z % 1 + g

215

At to decay to 1/16th

26.

Which of the following processes represents a gamma decay? (A) AX Z + , -! AX Z % 1 + a + b (C) AXZ -!.AXZ + f

27.

An observer can see through a pinhole the top end of a thin rod of height h, placed as shown in the figure. The beaker height is 3h and its radius h. When the beaker is filled with a liquid up to a height 2h, he can see the lower end of the rod. Then the refractive index of the liquid is:

(A)

5 2

(B)

5 2

3 2

(C) 28.

3 2

(D)

Which one of the following spherical lenses does not exhibit dispersion? The radii of curvature of the surface of the lenses are as given in the diagrams.

(A)

R1

R2

(B)

R1 R2

(C)

(D)

29.

In the ideal double-slit experiment, when a glass-plate (refractive index 1.5) of thickness t is introduced in the path of one of the interfering beams (wavelength / ), the intensity at the position where the central maximum occurred previously remains unchanged. The minimum thickness of the glass-plate is : (A) 2 / (B) 2 / /3 (C) / /3 (D) / Two plane mirrors A and B are aligned parallel to each other, as shown in the figure. A light ray is incident at an angle of 30 to a point just inside one end of A. The plane of incidence coincides with the plane of the figure. The maximum number of times the ray undergoes reflections (including the first one) before it emerges out is: (A) 28 (B) 30 (C) 32 (D) 34

30.

PART-II (CHEMISTRY)

IMPORTANT INFORMATION Logarithmic table can be used. Use of Calculator is not allowed. Useful data Gas constant : R = 0.082 L atm K1 mol1 = 8.314 J K1 mol1 Atomic number : Be = 4; Relative atomic mass ; H = 1.008; O = 16.00; S = 32.07 ; Se = 78.96 ; Te = 127.6 31. Standard electrode potential data are useful for understanding the suitability of an oxidant in a redox titration. Some half cell reactions and their standard potentials are given below : MnO4 (aq.) + 8H+ (aq.) + 5e ! Mn2+ (aq.) + 4H2O(") Cr2O72 (aq.) + 14H+ (aq.) + 6e ! 2Cr3+ (aq.) + 7H2O(") Fe3+ (aq.) + e ! Fe2+ (aq.) Cl2(g) + 2e ! 2Cl (aq.) (A) MnO4 can be used in aqueous HCl (C) MnO4 can be used in aqueous H2SO4 32. How many moles of electron weigh one kilogram ? (A) 6.023 1023

6.023 1054 9.108

B = 5; C = 6; N = 7;

O = 8; S = 16; Xe = 54

E0 = 1.51 V E0 = 1.38 V E0 = 0.77 V E0 = 1.40 V (B) Cr2O72 can be used in aqueous HCl (D) Cr2O72 can be used in aqueous H2SO4

Identify the only incorrect statement regarding the quantitative estimation of aqueous Fe(NO3)2.

1

(C) 33.

One mole of a non-ideal gas undergoes a change of state (2.0 atm, 3.0 L, 95 K) ! (4.0 atm, 5.0 L, 245 K) with a change in internal energy, 0U = 30.0 L atm. The change in enthalpy (0H) of the process in L atm is : (A) 40.0 (C) 44.0 (B) 42.3 (D) not defined, because pressure is not constant

34.

A substance Ax By crystallizes in a face centered cubic lattice in which atoms A occupy each corner of the cube and atoms B occupy the centres of each face of the cube. Identify the correct composition of the substance Ax By. (A) AB3 (C) A3 B (B) A4 B3 (D) composition cannot be specified N2 O4 (g) 2NO2 (g)

35.

Consider the following equilibrium in a closed container At a fixed temperature, the volume of the reaction container is halved. For this change, which of the following statements holds true regarding the equilibrium constant (KP) and degree of dissociation (1) ? (A) neither KP nor 1 changes (C) KP changes, but 1 does not change (B) both KP and 1 change (D) KP does not change but 1 changes

8 36.

Which of the following volume (v)-temperature (T) plots represent the behaviour of one mole of an ideal gas at one atmospheric pressure ?

(A)

(B)

(C)

(D)

37.

If nitrogen atom had electronic configuration 1s7, it would have energy lower than that of the normal ground state configuration 1s2 2s2 2p3, because the electrons would be close to nucleus, yet 1s7 is not observed because it violates : (A) Heisenberg uncertainty principle (C) Paulis exclusion principle (B) Hunds rule (D) Bohrs postulate of stationary orbits.

38.

Rutherfords experiment, which established the nuclear model of the atom, used a beam of : (A) ) -particles, which impinged on a metal foil & got absorbed. (B) ,-rays, which impinged on a metal foil & ejected electrons. (C).helium atoms, which impinged on a metal foil & got scattered. (D) helium nuclei, which impinged on a metal foil & got scattered.

39.

When the temperature is increased, surface tension of water : (A) increases (C) remains constant (B) decreases (D) shows irregular behaviour

40.

Consider the chemical reaction, N2(g) + 3H2(g) -! 2NH3(g) The rate of this reaction can be expressed in terms of time derivatives of conc. of N2(g) , H2(g) or NH3(g). Identify the correct relationship amongst rate expressions : (A) Rate = %

d [N2 ] 1 d [H2 ] 1 d [NH3 ] 2% 2 dt 3 dt 2 dt

(B) Rate =

(D) Rate = %

Specify the coordination geometry around and hybridisation of N and B atoms in a 1 : 1 complex of BCl3 & NH3. (A) N : tetrahedral sp3, B : tetrahedral sp3 (C) N : pyramidal sp3, B : planar sp2 (B) N : pyramidal sp3, B : pyramidal sp3 (D) N : pyramidal sp3, B : tetrahedral sp3

42.

Polyphosphates are used as water softening agents because they : (A) form soluble complexes with anionic species (B) precipitate anionic species (C) form soluble complexes with cationic species (D) precipitate cationic species

9 43.

Identify the correct order of acidic strengths of CO2, CuO, CaO, H2O. (A) CaO < CuO < H2O < CO2 (C) CaO < H2O < CuO < CO2 (B) H2O < CuO < CaO < CO2 (D) H2O < CO2 < CaO < CuO (B) Be (D) C (B) F2 (D) O22

44.

Identify the least stable ion amongst the following. (A) Li (C) B

45.

Which of the following molecular species has unpaired electron(s) ? (A) N2 (C) O

2

46.

A gas X is passed through water to form a saturated solution. The aqueous solution on treatment with silver nitrate gives a white precipitate. The saturated aqueous solution also dissolves magnesium ribbon with evolution of a colourless gas Y. Identify X and Y. (A) X = CO2 , Y = Cl2 (C) X = Cl2 , Y = H2 (B) X = Cl2, Y = CO2 (D) X = H2 , Y = Cl2

47.

An aqueous solution of a substance gives a white precipitate on treatment with dilute hydrochloric acid, which dissolves on heating. When hydrogen sulfide is passed through the hot acidic solution, a black precipitate is obtained. The substance is a : (A) Hg22+ salt (C) Ag+ salt (B) Cu2+ salt (D) Pb2+ salt (B) Self reduction (D) Thermite reduction (B) ZnS > Na2S < CuS (D) Na2S > ZnS > CuS

48.

Which of the following processes is used in the extractive metallurgy of magnesium ? (A) Fused salt electrolysis (C) Aqueous solution electrolysis

49.

Identify the correct order of solubility of Na2S, CuS and ZnS in aqueous medium. (A) CuS > ZnS > Na2S (C) Na2S > CuS > ZnS

50.

Anhydrous ferric chloride is prepared by : (A) heating hydrated ferric chloride at a high temperature in a stream of air. (B) heating metallic iron in a stream of dry chlorine. (C) reaction of metallic iron with hydrochloric acid. (D) reactrion of metallic iron with nitric acid.

51.

Identify the correct order of reactivity in electrophilic substitution reactions of the following compounds.

10 52.

(C)

(D)

53.

Which of the following acids has the smallest dissociation constant? (A) CH3CHFCOOH (C) BrCH2CH2COOH (B) FCH2CH2COOH (D) CH3CHBrCOOH

54.

The nodal plane in the p-bond of ethene is located in : (A) the molecular plane (B) a plane parallel to the molecular plane (C) a plane parallel to the molecular plane which bisects the carbon-carbon 3 bond at right angle (D) a plane perpendicular to the molecular plane which contains the carbon-carbon 3 bond

55.

CH3 CH2CH2CH2OH 1

(A) 1 > 2 > 3 (C) 1 > 3 > 2 56.

CH3 CH2CH2CHO 2

CH3 CH2CH2COOH 3

Which of the following hydrocarbons has the lowest dipole moment ? (A) (C) CH3CH2C 4 CH (B) CH3C 4 CCH3 (D) CH2 = CH C 4 CH (B) H2, Lindlar catalyst (D) Ammonical Cu2Cl2 solution

X Y

57.

Identify a reagent from the following list which can easily distinguish between 1-Butyne and 2-Butyne. (A) Bromine, CCl4 (C) Dilute H2SO4, HgSO4

58.

Identify the set of reagents/reaction conditions X and Y in the following set of transformations. CH3 CH2 CH2Br --! product --! CH3 % CH % CH3

| Br

(A) X = concentrated alcoholic NaOH, 80C ; Y = HBr acetic acid, 20C (B) X = dil. aq. NaOH, 20C, Y = HBr / acetic acid, 20C (C) X = dil. aq. NaOH, 20C, Y = Br2 / CHCl3 , 0C (D) X = conc. alc. NaOH, 80C, Y = Br2 / CHCl3 , 0C

11 59.

Which of the following compounds exhibits stereoisomerism ? (A) 2-Methylbutene-1 (C) 3-Methylbutanoic acid (B) 3-Methylbutyne-1 (D) 2-Methylbutanoic acid

60.

Compound 'A (molecular formula C3H8O) is treated with acidified potassium dichromate to form a product 'B' (mol. Formula C3H6O). 'B' forms a shining silver mirror on warming with ammonical AgNO3 . 'B' when treated with an aqueous solution of H2NCONHNH2, HCl & sodium acetate gives a product 'C'. Identify the structure of 'C.

CH3 | (B) CH3 % C 2 N % CONHNH2

PART-III (MATHEMATICS)

61. The area bounded by the curves y = | x | 1 and y = | x | + 1 is (A) 1 (C) 2 2

; 10 8 9 9 6 6 i20 : i 7

(B) 2 (D) 4

m

; 20 9 9m % : ;p8 8 , (where 9 6 9 q6 6 = 0, if p < q), is maximum when ' m ' is: 6 i7 : 7

62.

The sum

2

(B) 10 (D) 20

2

If the tangent at the point P on the circle x + y + 6x + 6y = 2 meets the straight line 5x 2y + 6 = 0 at a point Q on the y-axis, then the length of PQ is (A) 4 (C) 5 (B) 2 5 (D) 3 5

64.

2 If a > 2b > 0, then the positive value of m for which y = mx b 1 $ m is a common tangent to

2b a % 2b

(B)

a 2 % 4b 2 2b

b a % 2b

(C) 65.

(D)

For all complex numbers z 1, z 2 satisfying |z 1| = 12 and |z 2 3 4i| = 5, the minimum value of |z1 z2| is (A) 0 (C) 7 (B) 2 (D) 17

12

66.

(A) 3 " (C) 3 "2 (B) 3 " (".% 1) (D) 3 " (1 %.")

67.

A tan %1 x , if | x | C 1 > The domain of the derivative of the function f(x) = @ 1 <| x | %1= , if | x | B 1 is > ?2

1

68.

f (1 $ x ) 8 x lim ; 9 6 equals Let f : R ! R be such that f(1) = 3 and f D (1) = 6. Then x !0 9 f (1) 6 : 7

1

(B) e 2 (D) e3

Let T > 0 be a fixed real number. Suppose f is a continuous function such that for all x E R,

T

3 $3T

f(x + T) = f(x). If ( =

F

0

F f (2x ) dx is

3

(A)

3 ( 2

(B) 2( (D) 6(

(C) 3(

x

70. Let f (x) = (A) 1

1

(B)

1 2

1 (C) 2

71. The integral

(D) 0 & 1

1/ 2

13 72.

Let function f : R

(B) one to one but not onto (D) neither one to one nor onto (B) y = 2x + 1 (D) y = x + 2

(A) one to one and onto (C) onto but not one to one 73. (A) 3y = 9x + 2 (C) 2y = x + 8 74. The integer ' n ' for which Limit x !0 (A) 1 (C) 3 75.

(B) 2 (D) 4

The length of a longest interval in which the function 3 sin x 4 sin3x is increasing is (A)

& 3

(B)

& 2

(C) 76.

3& 2

(D) &

The number of arrangements of the letters of the word BANANA in which the two Ns do not appear adjacently is (A) 40 (C) 80 (B) 60 (D) 100

77.

The locus of the mid point of the line segment joining the focus to a moving point on the parabola y2 = 4ax is another parabola with directrix (A) x = a (C) x = 0 (B) x = % (D) x 2

a 2

78.

(A) ( G,

2 ) H (2, G)

(B) ( G,

2 ) H ( 2 , G)

(D) ( 2 , G) If a1, a2, a3, ........., an are positive real numbers whose product is a fixed number c, then the minimum value of a1 + a2 + a3 + .... + an 1 + 2an is (A) n(2c)1/n (C) 2nc1/n (B) (n + 1) c 1/n (D) (n + 1)(2c)1/n

80.

Suppose a, b, c are in A.P. and a2, b2, c2 are in G.P. if a < b < c and a + b + c =

1

(A)

1

(B)

2 2 1 1 3 2

2 3 1 1 2 2

(C)

(D)

14 81.

Which of the following pieces of data does NOT uniquely determine an acute - angled triangle ABC (R being the radius of the circumcircle )? (A) a , sin A, sin B (C) a, sin B, R (B) a, b, c (D) a, sin A, R

82.

& be fixed angle. If P = (cosI, sin I) and Q = (cos(1 I), sin (1 I)), then Q is obtained from P by 2

(A) clockwise rotation around origin through an angle 1 (B) anticlockwise rotation around origin through an angle 1 (C) reflection in the line through origin with slope tan 1 (D) reflection in the line through origin with slope tan (1/2) 83. Let P = (1, 0), Q = (0, 0) and R = (3, 3 3 ) be three points. Then the equation of the bisector of the angle PQR is (A)

3 x+y=0 2

(B) x +

3y = 0

(C) 84.

3x + y = 0

(D) x +

3 y=0 2

A straight line through the origin O meets the parallel lines 4x + 2y = 9 and 2x + y + 6 = 0 at points P and Q respectively. Then the point O divides the segement PQ in the ratio (A) 1 : 2 (C) 2 : 1 (B) 3 : 4 (D) 4 : 3 y3 + 3x 2 = 12y where the tangent is vertical, is (are)

85.

; 4 8 , % 26 (A) 9 9J 6 3 : 7

; 11 8 9 6 (B) 9 J 3 , 16 : 7

; 4 8 , 26 (D) 9 9J 6 3 7 :

The number of integral values of ' k ' for which the equation, 7 cos x + 5 sin x = 2 k + 1 has a solution is: (A) 4 (C) 10 (B) 8 (D) 12

87.

! ! ! ! ! ! If a & b are two unit vectors such that a + 2 b & 5 a % 4 b are perpendicular to each other, then the ! ! angle between a & b is:

(A) 45 (C) cos

%1

15

88.

$ . If U is a unit vector, then the maximum value of the scalar triple product &W =$ Let V = 2 i$ j %k i $ 3k

!! ! KU V W L is:

(A) % 1 (C) (B) (D)

10 $ 6

59

60

89.

The number of values of k, for which the system of equations (k + 1) x + 8y = 4k, kx + (k + 3) y = 3k 1 has infinitely many solutions, is (A) 0 (C) 2 (B) 1 (D) infinite

2

90.

Suppose f(x) = (x + 1) for x # 1. If g(x) is the function whose graph is reflection of the graph of f(x) with respect to the line y = x, then g(x) equals

1

(A) x 1, x # 0 (C)

x $1, x # 1

(B) (D)

( x $ 1)2

, x > 1

x 1, x # 0

SCREENING EXAMINATION

1. 6. 11. 16. 21. 26. 31. 36. 44. 46. 51. 56. 61. 66. 71. 76. 81. 86. C D A D A C A C A C C B B B A A D B 2. 7. 12. 17. 22. 27. 32. 37. 42. 47. 52. 57. 65. 67. 72. 77. 82. 87. D B B C A B D C C D B D C D A C D B 3. 8. 13. 18. 23. 28. 33. 38. 43. 48. 53. 58. 63. 68. 73. 78. 83. 88. B A B B A C C D A A C A C C D B C C 4. 9. 14. 19. 24. 29. 34. 39. 44. 49. 54. 59. 64. 69. 74. 79. 84. 89. C B A D B A A B B D A D A C C A B B 5. 10. 15. 20. 25. 30. 35. 40. 45. 50. 55. 60. 65. 70. 75. 80. 85. 90. C C D A A B D A C B B A B A A D D D

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