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PCC ACADEMY PROVIDES YOU THE EXCELLENT COACHING FOR MEDICAL AND ENGG ENTRANCE EXAMS

CHEMISTRY- mT 7
Q 75 To distinguish between formic acid and acetic acid the suitable reagent is (1) acidified KMnO4 (2) Tollen s reagent (!) eth"l alcohol(4) sodium bicarbonate the correct answer is (#) 1 $2$!$4 (%) 2$!$4 (%) 1$2$! (&) 1$ 2 Q2 Mn ('(() and %r ('() are con)erted to *** and *** res+ecti)el" when acted u+on b" formic acid (#) Mn ((') and %r ((() (,) Mn (IV) and %r (((() (%) Mn (-() and %r (((() (&) Mn ((ll) and %r ((() Q7. Third member of dicarbo/"lic acid is

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(#) malonic acid (,) succinic acid (%) o/alic acid (&) 0one of these Q71 The unstable deri)ati)e of the acid obtained b" heating 2gl"cerol 3 cr"stal of o/alic acid4 to a tem+erature of 115o would be (#) acid chloride (,) anh"dride (%) both the abo)e (&) acid amide Q.5 6hich grou+ in an organic com+ound is identified with the hel+ of acet"l chloride (#) 7%8O (,) 9 % : 5 (%)7O8 (&) 0one of these Q;1 6hen sodium is heated with %O the +roduct would be

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(#) dimeth"l ether (,) meth"l acetate (%) sodium acetate Q.2 8ighest b*+* would be (#) formic acid (,) water (%) acetic acid Q.! %58(%0) is called (#) h"dro/" nitrile (,) h"dro/" c"anide (%) c"anoh"drin Q.84 #l<aline h"drol"sis of %48.%(2 gi)es a com+ound which on +reci+itate of %8(! The com+ound should be

(&) acetic anh"dride (&) ethanol (&) h"dro/" isoc"anide heating with 0aO8 and ( 2 +roduces a "ellow

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(#) %8!%82%82%8O (,) %8!%827%O7%8! (%) %8!7%827%87(O8)7%82(O8) (&)%8!7%8(O8)7%87%8(O8)7%8! Q.5 The +roduct of the h"dra=ine and urea on treatment with carbon"l com+ound results in the formation of a com+ound in which the following grou+ is essentiall" +resent (#) 9 %:07O8 (%) 9%:0*08*%;85 (,) 9%:0*08*%O082 (&) 0one of the abo)e Q.; %hoose the +air showing ma/imum and minimum reacti)it" towards nucleo+hilic addition reaction for the com+ounds (formaldeh"de$ acetaldeh"de$ acetone$ butanone and !7+entanone) (#) 8%8O$ %8!%8O (,) %8!%O%8!$ %8!%8O

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(%) %285%O%285$ %8!%O%285 (&) 8%8O$ %285%O%285 Q.7* %8!7%87%827%8O heat # ( O8 >eduction of # b" ?i#(84 gi)es (#) crotonic acid (,) crontonaldeh"de (%) crot"l alcohol Q.. ,utanone does not show an" reaction with the reagent (#) 708082 (,) %8!082 (%) 2#g(08!)24

(&) 0one of these (&) 082O8

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Q.1 %8!%O%( @dA,aBO4A2824 # The isomers of %8!%O%( and # will be res+ecti)el" (#) %82%(%8O$ O/irane (,) %hloral$ )in"l alcohol (%) a7chloroeth"l alcohol e+o/"7ethane(&) 0one Q15 %8!7%8:%87%8O 254) %8!7%8:%87%OO8 The abo)e reaction is com+leted b" the reagent (#) al<aline KMnO4 (,) Tollen s reagent (%) selenium dio/ide (&) Osmium tetrao/ide Q11 6hich of the following is not correctl" matched Bubstrate >eagent @roduct (#) #cetaldeh"de 7dilute base7acetaldol (,) %rotonaldeh"de 7 ?i#(84 7 %rot"l alcohol

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(%) Cormaldeh"de 7 )a+ourisation 7 +araldeh"de* (&) Cormaldeh"de7ammonia 7 aminoform Q12 6hich of the following c"anoh"drin on h"drol"sis gi)es a +roduct ca+able of gi)ing haloform reaction (#) formaldeh"de c"anoh"drin (,) acetone c"anoh"drin (%) +ro+ionaldeh"de c"anoh"drin (&) acetaldeh"dec"anoh"drin Q1! Drignard reagent does not react with the com+ounds (#) 825 (,) %O2 (%) BO2 (&) ether Q14 # +rimar" amine is formed when Drignard reagent reacts with the following com+ound

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(#) ammonia (,) meth"lamine (%) chloramine (&) acetonitrile Q15 Cor the s"nthesis of 17butene$ %8!Mg( should be treated with (#) +ro+ene (%) all"l chloride (,) 27chloro+ro+ene (&) eth"l chloride Q1; >eactions ( and (( res+ecti)el" are 1* %8!Mg( 3 %8!( +roduct 2* %8!Mg,r 3 %82:O +roduct reactions 1 and 2 are (#) addition and elimination (,) elimination and addition (%) substitution and addition (&) rearrangement and elimination

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Q17 (n the +re+aration of Drignard reagent iodine cr"stal is used as 7 * (#) it catal"ses the reaction (,) it e/changes with al<"l halide (%) it inhibits the reaction (&) 0one Q1. 6hich of the following com+ounds cannot be obtained from the +"ro acid (#) %$ (alcohol) (,) %2 (acid) (%) %1 (aldeh"de) (&) %! (<etone) Q11 @rimar" and secondar" alcoholic grou+s are +resent in the com+ound E (#) gl"col (,) 1$47butanediol (%) +ro+"lene gl"col (&) gl"cerine

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Q155 (n the o/idation of +rimar" alcohol (#) onl" 7h"drogen is remo)ed (,) h"drogen is not remo)ed (%) both the 7h"drogens are remo)ed (&) one or both the 7h"drogen can be remo)ed Q151 #ction of nitrous acid on eth"l amine gi)es (#) %28; (,) %285O8 (%) %285O8 and %284 (&) %285O8 and 08! Q152 %;85O8 %(%O%(8!A(0aO8) %;85O%O%8! The abo)e reaction is an e/am+le of (#) >eimer Tiemann reaction (,) Bcholten ,aumann reaction (%) #cet"lation (&) ,en=o"lation Q15! The general formula of +rimar" alcohol

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(a) 9%8O8 (b) 9%7O8 (c) E%82O8 (d) F%(O8)2 Q154 &eh"dration of gl"cerol gi)es (#) @ro+ane (,) @ro+ene (%) #crolein (&) ,en=ene Q155 #ldeh"des ha)ing no 7h"drogen atoms undergo (#) Criedel crafts reaction (,) >eimertiemann reaction (%) %anni==aro s reaction (&) >osenmund reaction Q15; ,en=ene he/a chloride is used as (#) &"e (,) #ntimalerial drug (%) #ntibiotic (&) (nsecticide

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Q157 Cormula of mesit"lene obtained b" treating acetone with conc 82BO4 is (#) (%8!)2%:%8%O%8! (,) (%8)2%(O8)%82%O%8! (%) 1$!$5 trimeth"l ben=ene Q15. (n %8!%OO8 and 8%OO8$ 8%OO8 will be (#) ?ess acidic (,) GHuall" acidic (%) More acidic

(&) none (&) 0one

Q151 6illiamsons s"nthesis is used to +re+are

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(#) #cetone (,) &ieth"l ether (%) @*'*% Q115 The general formula for mono7carbo/"lic acid is (#) %n8n%OO8 (b) %n82n31 %OO8 (c) %n82n%OO8 Q111 Cormic acid can reduce (#) Tollen s reagent (%) KMnO4 (,) Mercuric chloride Q112 The reaction of 8%OO8 with conc* 82BO4 gi)es (#) %O2 (,) %O (%) O/alic acid

(&) ,a<elite (d) %n82nO2 (&) #ll the abo)e (&) #cetic acid

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Q11 Gther is (#) #cidic (%) 0eutral (,) ,asic (&) #m+hoteric Q114 6hen dieth"l ether is heated with h"droiodic acid the com+ound obtained is (#) Gth"l alcohol (,) Gth"l iodide (%) Gth"l alcohol and eth"l iodide (&) 0one Q115 The b*+* of ethanol is higher than that of dimeth"l ether (#) &ue to intramolecular 87bonding (,) &ue to association of molecules (%) &ue to lewis base character (&) &ue to strong di+ole di+ole E attraction Q*11; &ecom+osition of dieth"l ether is done b"

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(#) 0aO8

(,) 82O

(%) %8!%O%(

(&) 8(

Q117 #n e/am+le of a com+ound with the functional grou+ is (#) #cetic acid Q11. G+o/ides are (#) %"clic ethers (,) 0ot ethers (%) #r"l7#l<"l ethers (&) Gthers with another functional grou+ (,) meth"l alcohol (%) &ieth"l ether (&) 0one

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Q111 @henol is less acidic than (#) #cetic acid (,) +70itro +henol Q125 Balol is +re+ared from (#) Balic"lic acid and +henol

(%) ,oth (#) and (,) (&) 0one (%) ,oth (&) 0one

(,) Balic"lic acid and meth"l alcohol

Q121 @henol is heated with %%l4 and al<aline KO8 when salic"lic acid is +roduced* The reaction is <nown as

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(#) Criedal craft reaction (,) >iemer7Tiemanns reaction (%) >osenmund s reduction (&) Bommelet Q122 @henol on treatment with conc*80O! gi)es (a) @icric acid (b) Bt"+hinic acid (c) ,oth (d) 0one Q12! @henol reacts with bromine in %B2 at low tem+erature to gi)e (#) m7+romo +henol (,) o7+7bromo +henol (%) +ara bromo+henol (&) 2$4$ ;7tribromo +henol Q124 Balic"laldeh"de can be +re+ared from (#) @henol and chloroform (,) @henol$ chloroform and sodium h"dro/ide (%) @henol$ carbon tetra chloride and 0aO8 (&) 0one

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PCC ACADEMY PROVIDES YOU THE EXCELLENT COACHING FOR MEDICAL AND ENGG ENTRANCE EXAMS

Q125 #mongst the following +henols which is most acidic (#) +icric acid (,) 27nitro+henol (%) 2$ 47di nitro +henol (&) m7nitro +henol Q12; Cehling s solution consists of two se+arate solutions* One solution contains %uBO4 The other contains (#) 0a8%O! (,) 82%2O4 (%) K2%O! (&) K0a%484O; Q127 The characteristic grou+ of secondar" alcohol is (#)7%82O8 (,) 9%7O8 (C) 9%8O8 (&) 9%(O8)2

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PCC ACADEMY PROVIDES YOU THE EXCELLENT COACHING FOR MEDICAL AND ENGG ENTRANCE EXAMS

Q12. ?indlar s catal"st is (#) @d 3 ,aBO4 (%) #l2 O! 3 '2O5 ,) @d 3 %a%O! (&) #(@! 3 #(%(! Q*121 Cormaldeh"de +ol"merises from ; to 5 molecules to form (#) Cormalin (,) Meta formaldeh"de (%) @araformaldeh"de (&) 0one Q 1!5 Gth"l alcohol is heated with conc* 82BO4 The +roduct formed is (#) %8!7%7OO%285 (%) %284 (,) %28; (&) %282 Q1!1 8"bridisation of carbon in 7 %8O grou+ is (#) s+ (,) B+2 (%) B+! (&) 0one

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Q1!2 6hich of the following reagent can not be used for +re+aring alll"l chloride from alcohol (#) 8%( 3 anh"drous In%(2 (,) 0a%( (%) @%l5 (&) BO%(2 Q1!! 6hich of the following <etone will not gi)e iodoform test (#) 27@entanone (,) #cetone (%) ,en=o+henone (&)27he/anone Q1!4 The )a+our densit" of a com+ound is 21$ which react with iodine and 0aO8 to form a "ellow com+ound* The com+ound is (#) %8!%OO8 (,) %8!%O%8! (%) %8!%8O8%8! (&) %8!O8

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Q1!5 Gth"l alcohol is industriall" +re+ared from eth"lene b" (#) @ermanganate o/idation (,) %atal"tic reduction (%) #bsorbing in 82BO4 followed b" h"drol"sis Q1!; 6hich one is +rimar" alcohol (#) ,utane 727ol (,) @ro+ane727ol (%),utane717ol Q1!7 The reaction between al<"l halide and sodium metal is called (#) 6urt= reaction (,) Kolbe s reaction (%) %lemmensen s reaction Q1!. #lcohols of low melecular weight are (&) Cermentation (&) 2$! dimeth"l he/ane747ol (&) Cin<elstein reaction

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(#) Boluble in water (,) Boluble in water on heating(%) (nsoluble in water (&) (nsoluble in all sol)ents ( Q1!1 6hich of the following can not be +roduced b" deh"dration of alcohols E (#) Gthers (,) aldeh"des (%) #l<"l h"drogen sul+hate (&) #l<ene

Q145 Tollen s reagent is (#) #mmonical cu+rous chloride (,) #mmonical cu+rous o/ide (%) #mmonical sil)er nitrate (&) #mmonical

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sil)er nitrite Q141 @hosgene is a common name of (#) Mi/ture of %O2 and %l2 (,) @O%(! Q142 Damme/ane is the name gi)en to (#) %;8;%l! (,) %;84%l2 Q14! &&T is (#) #n insecticide (%) 8"+notic

(%) %O%l2

(&) %%(4

(%) %;8;%l; (&) &i+hen"ln" trichloroethane (,) ,leaching agent (&) O/idising agent

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PCC ACADEMY PROVIDES YOU THE EXCELLENT COACHING FOR MEDICAL AND ENGG ENTRANCE EXAMS

Q144 %arbon"l grou+ undergoes* (#) Glectro+hilic addition reaction (,) 0ucleo+hilic addition reaction (%) ,oth Q145 # mi/ture of calcium acetate and calcium formate on heating gi)es (#) %8!%O%8! (,) %8!%OO8 (%) %8!O8 Q14; Monomer of orlon is (#) 'in"l chloride (%) #crielonitrile (,) %hloro+rene Q147 6hich of the following re+resents westrosol

(&) 0one (&) %8!%8O (&) #cetonitrile

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(#) %8%(!

(,) %82%l2

(%) %8%l2%82%(

(&) %%l2:%8%(

Q14. 6hich of the following order of reacti)it" is correct (#) 8%8O 9%8!%O%8! 9%8!%8O (%) %8!%O%8!98%8O9%8!%8O Q149 'in"l +ol"mers are (,) 8%8O9%8!%8O9%8!%O%8! (&) Jn+redictable

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(#) Thermo+lastics (%) @lastici=ers (,) Thermosetting +lastics Q155 6hich of the following is used as general anaesthetic in +lace of dieth"l ether (#) %8%(! (,) %C!7%8%(,r (%)%C!7%8,r

(&) ,oth (#) and (%) (&) 0one

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