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Name

Magnesium Sulfate, Anhydrous Sodium Chloride Water Acetone Hydrochloric Acid Sodium Bicarbonate (Sodium hydrogen carbonate) Dichloromethane (Methylene chloride)

Formula
MgSO4 NaCl H2O C3H6O HCl NaHCO3

CH2Cl2

Sucrose

C12H22O11

Aspirin (Acetylsalicylic Acid, ASA)

C9H8O4 C8H9NO or CH3CONHC6H5 C10H13NO2 C8H9NO2

Acetanilide Phenacetin Acetaminophen

MW (g/mol)
120.37 (SA) 58.44 (SA) 18.02 (SA) 58.08 (SA) 36.46 (SA) 84.01 (SA)

MP (C)

BP (C)

801 (SA) 0.0 (SA) MP -94 (SA) MP -30 (SA) 300 (SA)

1413 (SA) 100 (SA) 56 (SA) >100 (SA) decmp

84.93 (SA); 84.9 (NB)

MP -97 (NB)

39.8-40 (SA); 40 (NB)

342.30 (SA)

185-187 (SA)

180.16 (SA)

134-136 (SA)

135.2 (NB) 179.2 (NB) 151.16 (SA)

114 (NB) 135 (NB) 168-172 (SA)

304-305 (NB) Decomposes (ScienceLab)

Density (g/ml)
2.66 2.165 (SA) 1.000 at 3.98C (SA) 0.791 at 25C (SA) 1.18 at 25C (SA) 2.160 (SA)

Flammability
Non-Flammable (SA) Non-Flammable (SA)

Highly Flammable (SA) Non-Flammable (SA) Non-Flammable (SA)

1.325 at 25C (SA); 1.327 (NB)

Non-Flammable (SA)

1.587 (ScienceLab)

1.35 (ScienceLab)

Non-Flammable (SA)

1.219 (NB)

1.293 (ScienceLab)

Non-Flammable (SA)

Solubility
26g/100L H2Oat 0C (http://fscimage.fishersci.com/msds/13510.h tm) Soluble in Water (SA)

Toxicity

LD50 3,550mg/kg (Oral Rat) (SA)

2.6g/100mL H2O (SA) Soluble in Water (SA) 50g/L H2O(SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 4220 mg/kg (Oral, Rat) (SA)

Slightly Soluble in Water (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

342g/L H2O at 20C - Completely Soluble (SA); Insoluble in Dichloromethane (NB) Soluble in Dichloromethane, Relatively Insoluble in Water (NB); Very slightly soluble in cold water (ScienceLab) 0.54g/100mL Cold H2O, 5.0g/100mL in Boiling H2O (NB) 0.076g/100mL Cold H2O, 1.22g/100mL in Boiling H2O (NB)

LD50 29,700mg/kg (Oral, Rat) (SA)

LD50 1500mg/kg (Oral, Rat) (SA)

LD50 800mg/kg (Oral, Rat) (ScienceLab) LD50 1650mg/kg (Oral, Rat) (SA) LD50 1944mg/kg (Oral, Rat) (SA)

Safety/Comments
Hygroscopic (SA) No Known OSHA Hazards (SA) No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood No Known OSHA Hazards (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. No Known OSHA Hazards (SA)

Notes on Source of Information

ACS Reagent 37% MSDS from SA

Irritant, Harmful on Ingestion (SA)

Irritant - Minimize Contact (NB) Irritant - Minimize Contact (NB); Carcinogen, Harmful by Ingestion (SA) Harmful by Ingestion, Irritant (SA)

Name
Water Acetone

Formula
H2O C3H6O

Dichloromethane (Methylene chloride)

CH2Cl2

Acetanilide Phenacetin

C8H9NO or CH3CONHC6H5 C10H13NO2

Sucrose

C12H22O11

Aspirin (Acetylsalicylic Acid, ASA)

C9H8O4

MW (g/mol)
18.02 (SA) 58.08 (SA)

MP (C)
0.0 (SA) MP -94 (SA)

BP (C)
100 (SA) 56 (SA)

84.93 (SA); 84.9 (NB)

MP -97 (NB)

39.8-40 (SA); 40 (NB)

135.2 (NB) 179.2 (NB)

114 (NB) 135 (NB)

304-305 (NB) Decomposes (ScienceLab)

342.30 (SA)

185-187 (SA)

180.16 (SA)

134-136 (SA)

Density (g/ml)
1.000 at 3.98C (SA) 0.791 at 25C (SA)

Flammability

Highly Flammable (SA)

1.325 at 25C (SA); 1.327 (NB)

Non-Flammable (SA)

1.219 (NB)

1.587 (ScienceLab)

1.35 (ScienceLab)

Non-Flammable (SA)

Solubility

Toxicity

2.6g/100mL H2O (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

Slightly Soluble in Water (SA) 0.54g/100mL Cold H2O, 5.0g/100mL in Boiling H2O (NB) 0.076g/100mL Cold H2O, 1.22g/100mL in Boiling H2O (NB) 342g/L H2O at 20C - Completely Soluble (SA); Insoluble in Dichloromethane (NB) Soluble in Dichloromethane, Relatively Insoluble in Water (NB); Very slightly soluble in cold water (ScienceLab)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 800mg/kg (Oral, Rat) (ScienceLab) LD50 1650mg/kg (Oral, Rat) (SA)

LD50 29,700mg/kg (Oral, Rat) (SA)

LD50 1500mg/kg (Oral, Rat) (SA)

Safety/Comments
No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant - Minimize Contact (NB) Irritant - Minimize Contact (NB); Carcinogen, Harmful by Ingestion (SA)

Notes on Source of Information

No Known OSHA Hazards (SA)

Irritant, Harmful on Ingestion (SA)

Name
Water Acetone

Formula
H2O C3H6O

MW (g/mol)
18.02 (SA) 58.08 (SA)

Dichloromethane (Methylene chloride) Ethyl acetate Hexanes Anthracene

CH2Cl2 C4H8O2 C6H14 C14H10

84.93 (SA); 84.9 (NB) 88.11 (SA) 86.18 (SA) 178.23 (SA)

Cholesterol

C27H46O

386.65 (SA)

1,4-napthoquinone para -nitroaniline Ferrocene Acetylferrocene 1,1'-Diacetylferrocene

C10H6O2 C6H6N2O2 C10H10Fe C12H12FeO C14H14FeO2

158.15 (SA) 138.12 (SA) 186.03 (SA) 228.07 (SA) 270.10 (SA)

Silica Gel

SiO2 X H2O

60.09 + xH2Og/mol (ScienceLab)

Iodine Sand

I2 SiO2

253.81 (SA)

MP (C)
0.0 (SA) MP -94 (SA)

BP (C)
100 (SA) 56 (SA)

Density (g/ml)
1.000 at 3.98C (SA) 0.791 at 25C (SA)

MP -97 (NB) MP -84 (SA) MP -95 (SA) 210-215 (SA)

39.8-40 (SA); 40 (NB) 76.5-77.5 (SA)


69 (SA)

1.325 at 25C (SA); 1.327 (NB) 0.902 at 25C (SA)


0.659 at 25C (SA)

340 (SA)

1.25-1.28 (Fisher http://fscimage.fishersci.com/msds/96670.htm)

147-149 (SA)

360 (SA)

1.067 at 25C (SA)

119-122 (SA) 146-149 (SA) 172-174 (SA) 81-83 (SA)


125-127 (SA)

1.422 (ScienceLab) 260 at 100mmHg (SA) 249 (SA) 1.44 (SA)

2.1 (ScienceLab)

113 (SA)

184 (SA)

4.930 (SA) 1.8 to 2.5 Depending on Mineral Composition (ScienceLab)

Flammability

Solubility

Highly Flammable (SA)

2.6g/100mL H2O (SA)

Non-Flammable (SA) Highly Flammable (SA) Highly Flammable (SA) Non-Flammable (SA)

Slightly Soluble in Water (SA) Water soluble (SA) Water Insoluble (SA) Insoluble in Cold Water (ScienceLab) Soluble in Diethyl ether and Acetone. Very slightly soluble in Alcohol and Cold Water. Solubility in Water 0.2mg/100mL H2O (ScienceLab) Water Soluble (SA)

Non-Flammable (SA)

Non-Flammable (SA) Flammable (SA) Non-Flammable (SA)

Slightly Soluble in Water (SA) Insoluble in Cold Water (ScienceLab) Insoluble in Water (http://fscimage.fishersci.com/msds/10307.h tm)

Non-Flammable (ScienceLab)

Insoluble in Cold Water. Soluble in Hot KOH and MaOH solutions. Insoluble in Ethanol and Acids, except Hydrofluoric Acid (ScienceLab) Easily Soluble in Diethyl ether. Soluble in Methanol. Very Slightly Soluble in Water. (ScienceLab)

Non-Flammable (SA) Non-Flammable (ScienceLab)

Insoluble in Water, Methanol, Diethyl Ether, and n-Octanol. (ScienceLab)

Toxicity

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA) LD50 5620mg/kg (Oral, Rat) (SA) LD50 25,000mg/kg (Oral Rat) (SA) LD50 4900mg/kg (Oral, Mouse) (Fisher http://fscimage.fishersci.com/msds/96670.htm)

LD50 190mg/kg (Oral, Rat) (SA) LD50 750mg/kg (Oral, Rat) (SA) LD50 1320mg/kg (Oral, Rat) (SA) LD50 50mg/kg (Oral, Mouse) (SA) LD50 1600mg/kg (Oral, Rat) (SA)

LD50 >31600mg/kg (Oral, Rat) (ScienceLab)

LD50 14,000mg/kg (Oral, Rat)

Safety/Comments
No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood
Irritant, Teratogen, May be Fatal if Swallowed or Inhaled, Do not breath dust/fume/gas/mist/vapors/spray (SA); Work in Hood

Notes on Source of Information

Anhydrous Hexanes MSDS from SA

Carcinogen, Irritant (SA)

Irritant and Permeator (ScienceLab)

Highly Toxic by Inhalation, Toxic by Ingestion, Irritant. (SA) Work in Hood. Toxic by Inhalation, Toxic by Ingestion, and by Skin Absorption (SA) Harmful by Ingestion (SA) Highly Toxic by Ingestion - Fatal if Swallowed (SA) Hamful by Ingestion. Hamful on contact with skin. (SA) Carcinogen, Harmful to Respiratory Tract due to its Super Fine Nature. Do not stir silica gel excessively or breath in dust. Work in Hood. (Ghurbanyan Supplement)
Toxic by Inhalation. Harmful by Skin Absorption. Skin Sensitiser. Corrosive. (SA) Slight Irritant (ScienceLab)

D
Water Acetone Diethyl Ether (ethyl ether, ether) Methanol (methyl alcohol) -Phellandrene (5-isopropyl-2-methyl-1,3cyclohexadiene) Maleic Anhydride

Formula
H2O C3H6O C4H10O CH3OH C10H16 C4H2O3

MW (g/mol)
18.02 (SA) 58.08 (SA) 74.1 (NB) 32.0 (NB) 136.23 (SA) 98.1 (NB)

MP (C)
0.0 (SA) MP -94 (SA) MP -116 (NB) MP -94 (NB) 127 (NB) 53 (NB)

BP (C)
100 (SA) 56 (SA) 34.5 (NB) 65 (NB) 175 (MerckMillpore) 202 (NB)

Density (g/ml)
1.000 at 3.98C (SA) 0.791 at 25C (SA) 0.714 (NB) 0.791 (NB) 0.85 at 25C (SA)

Flammability

Highly Flammable (SA) Flammable (SA), Extremely Flammable (NB) Highly Flammable (SA) Flammable and Combustible (SA) Non-Flammable (SA)

Solubility

Toxicity

2.6g/100mL H2O (SA) 65g/L H2O at 20C (SA)

LD50 5,800mg/kg (Oral, Rat) (SA) LD50 1215mg/kg (Oral, Rat) (SA)

Completely Miscible with Water LD50 1187-2769mg/kg (Oral, Rat) (SA) (SA) 2.86mg/L H2O at 25C (Merck LD50 5700mg/kg (Oral, Rat) (Merck Millpore) Millpore) Soluble in Cold and Hot Water. Very slightly soluble in LD50 400mg/kg (Oral, Rat) Methanol. (ScienceLab)

Safety/Comments
No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood. Toxic by Inhalation, Toxic by Ingestion, Toxic by Skin Absorption (SA) Harmful by Ingestion. Respiratory Sensitiser. Irritant. (SA) Work in Hood. Corrosive. Can cause severe damage to eyes, skin, and upper respiratory tract. Avoid contact. Do not breath dust. Work in Hood (NB)

Notes on Source of Information

Name
Water Dichloromethane (Methylene chloride)

Formula
H2O CH2Cl2

MW (g/mol)
18.02 (SA) 84.93 (SA); 84.9 (NB)

MP (C)
0.0 (SA) MP -97 (NB)

Acetic Anhydride

C4H6O3

102.1 (NB)

MP -73 (NB)

Aluminum chloride Sodium Hydroxide Magnesium Sulfate, Anhydrous Sodium Chloride Hydrochloric Acid

AlCl3 NaOH MgSO4 NaCl HCl

133.3 (NB) 40.00 (SA) 120.37 (SA) 58.44 (SA) 36.46 (SA)

193 (NB) 318 (SA)

801 (SA) MP -30 (SA)

Anisole 4'-Methoxyacetophenone Acetone

C7H8O C9H10O2 C3H6O

108.2 (NB) 150.2 (NB) 58.08 (SA)

MP -38 (NB) 39 (NB) MP -94 (SA)

BP (C)
100 (SA) 39.8-40 (SA); 40 (NB)

Density (g/ml)
1.000 at 3.98C (SA)

Flammability

1.325 at 25C (SA); 1.327 (NB)

Non-Flammable (SA)

140 (NB)

1.082 (NB)

Flammable (SA)

Sublimes (NB) 1390 (SA)

2.4400 (SA) 2.1300 (SA) 2.66

Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Flammable and Combustible (SA) Non-Flammable (SA) Highly Flammable (SA)

1413 (SA) >100 (SA)

2.165 (SA) 1.18 at 25C (SA)

155 (NB) 258 (NB) 56 (SA)

0.996 (NB) 1.082 (NB) 0.791 at 25C (SA)

Solubility

Toxicity

Slightly Soluble in Water (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 1780mg/kg (Oral, Rat) (SA)

LD50 3450mg/kg (Oral, Rat) (SA)

26g/100L H2Oat 0C (http://fscimage.fishersci.com/ msds/13510.htm) Soluble in Water (SA) Soluble in Water (SA) Insoluble in Water. Soluble in Ethanol, Diethyl ether, and Acetone-Like Solvents. (SA) 2.474g/L H2O at 20C (SA) 2.6g/100mL H2O (SA)

LD50 3,550mg/kg (Oral Rat) (SA)

LD50 3700mg/kg (Oral, Rat) (SA) LD50 1720mg/kg (Oral, Rat) (SA) LD50 5,800mg/kg (Oral, Rat) (SA)

Safety/Comments
No Known OSHA Hazards (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant - Can Cause Severe Damage to Skin and Eyes. Use Gloves and Avoid Contact. Vapors are Harmful if Inhaled. Do Not Breath Vapors. Reacts Violently with Water. Keep away from Water. (NB) Work in Hood Reacts with Atmospheric Moisture and Violently with Water to Generate HCl Vapors - Keep away from Water. Can cause painful burns on moist skin and eyes - Avoid Contact. Do not inhale dust or vapors, which can damage respiratory tract. (NB) Work in Hood Corrosive (SA) Hygroscopic (SA) No Known OSHA Hazards (SA) Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood Irritant. (SA) Harmful by Ingestion. Irritant. (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)

Notes on Source of Information

ACS Reagent 37% MSDS from SA

Name
2-methylcyclohexanol and Trans Isomers) (Cis

Formula

MW (g/mol)

MP (C)

C7H14O

114.2 (NB)

MP -38 (Acros)

85% Phosphoric Acid Sodium Bicarbonate (Sodium hydrogen carbonate) Calcium Chloride, Anhydrous (Beads) Bromine Carbon Tetrachloride Potassium Permanganate, Aqueous 1% Ethanol Water

H3PO4

98.0 (NB for Pure Acid); 85% Phosphoric Acid is ~14.7M (NB) 84.01 (SA) 110.98 (SA) 159.81 (SA) 153.82 (SA) 158.03 (SA) 46.07 (SA) 18.02 (SA)

40 (SA)

NaHCO3 CaCl2 Br2 CCl4 KMnO4 C2H6O H2O

300 (SA) 772 (SA) 7.2 (SA) MP -23 (SA) 240 (SA) MP -114 (SA) 0.0 (SA)

Acetone 1-Methylcyclohexene 3-Methylcyclohexene Methylenecyclohexane

C3H6O C7H12 C7H12 C7H12

58.08 (SA) 96.2 (NB) 96.2 (NB) 96.17 (SA)

MP -94 (SA)

Dichloromethane (Methylene chloride)

CH2Cl2

84.93 (SA); 84.9 (NB)

MP -97 (NB)

BP (C)

Density (g/ml)

Flammability
Flammable and Combustible (SA)

Solubility
Slighlty Soluble in Water (Acros)

166 (NB)

0.930 (NB)

158 (SA)

1.70 (NB); 1.685 (SA)

Non-Flammable (SA)

Easily Soluble in Hot and Cold Water (ScienceLab) 50g/L H2O(SA)

decmp 1670 (SA) 58.8 (SA) 76-77 (SA)

2.160 (SA) 2.150 (SA) 3.119 (SA) 1.594 (SA) 2.710 (SA)

Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Flammable (SA)

36.5g/L H2O at 20C 0.8461g/L H2O at 20C (SA)

78.3 (SA) 100 (SA)

0.789 (SA) 1.000 at 3.98C (SA)

Completely Water Soluble (SA)

56 (SA) 110 (NB) 104 (NB) 102-103 (SA)

0.791 at 25C (SA) 0.813 (NB) 0.801 (NB) 0.8 at 25C (SA)

Highly Flammable (SA) Flammable (NB) Flammable (NB) Flammable (SA)

2.6g/100mL H2O (SA)

39.8-40 (SA); 40 (NB) 1.325 at 25C (SA); 1.327 (NB)

Non-Flammable (SA)

Slightly Soluble in Water (SA)

Toxicity

Safety/Comments
Inhalation, Ingestion, or Skin Absorption May be Harmful. Avoid Contact. Do Not Breath Vapors. Keep away from Flames and Hot Surfaces (NB); Work in Hood

LD50 1530mg/kg (Oral, Rat) (ScienceLab)

Can Cause Serious Burns, Particularly to Eyes. Avoid Skin and Eye Contact. (NB) Work in Hood. No Known OSHA Hazards (SA) Irritant (SA) Highly Corrosive. Do Not Remove Bromine Reagent Bottle from Fume Hood. (Ghurbanyan Supplement) Carcinogen; Work in Hood. (Ghurbanyan Supplement) Oxidizaing Agent; Work in Hood (Ghurbanyan Supplement) Irritant - Avoid Contant with Skin and Eyes. Avoid Inhalation of Vapor or Mist. (SA) No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) Irritant - Avoid Contact with Skin and Eyes. Avoid Inhalation of Vapors or Mist. (SA) Work in Hood

LD50 4220 mg/kg (Oral, Rat) (SA) LD50 2301 (Oral, Rat) (SA) LD50 2600mg/kg (Oral, Rat) (SA) LD50 2350mg/kg (Oral, Rat) (SA) LD50 1090mg/kg (Oral, Rat) (SA) LD50 7060mg/kg (Oral, Rat) (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

Avoid Contact with Skin and Eyes. Avoid Inhalation of Vapors or Mist. (SA) Work in Hood May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Notes on Source of Information

All MSDS Sources for 85%

ACS Reagent 99.0% MSDS from SA ACS Reagent 99.5%, 200 Proof MSDS from SA

Name
Isopentyl Alcohol (3-methyl-1-butanol)

Formula
C5H12O

MW (g/mol)
88.1 (NB)

MP (C)
MP -117 (SA)

Acetic Acid, Glacial

C2H4O2

60.1 (NB)

16.2 (SA)

Sulfuric Acid (100%, Concentrated) Water Sodium Bicarbonate (Sodium hydrogen carbonate) Magnesium Sulfate, Anhydrous Sodium Sulfate, Anhydrous Granular Sodium Acetate

H2SO4 H2O NaHCO3 MgSO4 Na2O4S C2H3NaO2

98.1 (NB) 18.02 (SA) 84.01 (SA) 120.37 (SA) 142.04 (SA) 82.03 (SA)

3 (SA for 99%) 0.0 (SA) 300 (SA)

884 (SA) >300 (SA)

Dichloromethane (Methylene chloride)

CH2Cl2

84.93 (SA); 84.9 (NB)

MP -97 (NB)

Acetone

C3H6O

58.08 (SA)

MP -94 (SA)

Isopentyl Acetate (3-methylbutyl ester)(Isoamyl Acetate)

C7H14O2

130.2 (NB)

MP -78 (SA)

BP (C)
130 (NB)

Density (g/ml)
0.815 (NB)

Flammability
Flammable and Combustible (SA) Flammable and Combustible (SA)

118 (NB)

1.049 (NB)

290 (NB) 100 (SA) decmp

1.84 (NB) 1.000 at 3.98C (SA) 2.160 (SA) 2.66 2.68 at 25C (SA) 1.528 (SA)

Non-Flammable (SA)

Non-Flammable (SA) Non-Flammable (SA)

Non-Flammable (SA)

39.8-40 (SA); 40 (NB)

1.325 at 25C (SA); 1.327 (NB)

Non-Flammable (SA)

56 (SA)

0.791 at 25C (SA)

Highly Flammable (SA)

142 (NB)

0.876 (NB)

Flammable (SA)

Solubility
2.7g/100mL H2O (NB)

Toxicity
LD50 5000mg/kg (Oral, Rat)

Completely Miscible with Water (SA)

LD50 3310mg/kg (Oral, Rat) (SA)

Miscible with Water (NB)

LD50 2140mg/kg (Oral, Rat) (SA for 99%)

50g/L H2O(SA) 26g/100L H2Oat 0C (http://fscimage.fishersci.com/msds/13510.htm) Water Soluble (SA) 246g/L H2O at 20C - Completely Water Soluble (SA)

LD50 4220 mg/kg (Oral, Rat) (SA)

LD50 5989mg/kg (Oral, Mouse) (SA) LD50 3530mg/kg (Oral, Rat) (SA)

Slightly Soluble in Water (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

2.6g/100mL H2O (SA) 0.25g/100mL H2O (NB); Completely miscible with alcohol and ether (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 7422 (Oral, Rabbit) (SA)

Safety/Comments
Irritant - skin, eyes, and respiratory tract (NB) Causes Chemical Burns that can Seriously Damage Skin & Eyes. Avoid Contact and Wear Gloves. Vapors Irritate Eyes and Respiratory Tract. Do not inhale vapors. Work in Hood (NB) Causes Chemical Burns that can Seriously Damage Skin & Eyes. Avoid Contact and Wear Gloves. (NB) No Known OSHA Hazards (SA) No Known OSHA Hazards (SA) Hygroscopic (SA) No Known OSHA Hazards (SA) No Known OSHA Hazards (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) Irritant - skin, eyes, and respiratory tract (NB)

Notes on Source of Information

Name
Dimethyl malonate Sodium methoxide Methanol (methyl alcohol) 25% Solution of Sodium Methoxide in Methanol

Formula
C5H8O4 CH3ONa CH3OH

Mesityl Oxide (4-methyl-3-penten-2-one) Sodium Hydroxide Hydrochloric Acid Diethyl Ether (ethyl ether, ether) Ethyl acetate Water Acetone

C6H10O NaOH HCl C4H10O C4H8O2 H2O C3H6O

Dichloromethane (Methylene chloride)

CH2Cl2

Dimedone (5,5-dimethyl-1,3-cyclohexanedione) (Methone) Calcium Chloride, Anhydrous (Beads)

C8H12O2 CaCl2

MW (g/mol)
132.1 (NB) 54.0 (NB) 32.0 (NB)

MP (C)
MP -62 (NB) 126 (Fisher) MP -94 (NB)

BP (C)
181 (NB) Decomposes (Fisher) 65 (NB)

98.2 (NB) 40.00 (SA) 36.46 (SA) 74.1 (NB) 88.11 (SA) 18.02 (SA) 58.08 (SA)

MP -52 (NB) 318 (SA) MP -30 (SA) MP -116 (NB) MP -84 (SA) 0.0 (SA) MP -94 (SA)

129 (NB) 1390 (SA) >100 (SA) 34.5 (NB) 76.5-77.5 (SA) 100 (SA) 56 (SA)

84.93 (SA); 84.9 (NB)

MP -97 (NB)

39.8-40 (SA); 40 (NB)

140.2 (NB) 110.98 (SA)

151 (NB), 146-148 (SA) 772 (SA)

164-166 (SA) 1670 (SA)

Density (g/ml)
1.154 (NB) 0.970 (SA) 0.791 (NB) For 25% Sodium Methoxide Solution in Methanol 0.945 (NB)

Flammability
Combustible (SA) Non-Flammable (SA); Flammable (Fisher) Highly Flammable (SA) Flammable (NB)

0.858 (NB) 2.1300 (SA) 1.18 at 25C (SA) 0.714 (NB) 0.902 at 25C (SA) 1.000 at 3.98C (SA) 0.791 at 25C (SA)

Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Flammable (SA), Extremely Flammable (NB) Highly Flammable (SA)

Highly Flammable (SA)

1.325 at 25C (SA); 1.327 (NB)

Non-Flammable (SA)

Non-Flammable (SA) 2.150 (SA) Non-Flammable (SA)

Solubility
Partially soluble in cold water (ScienceLab)

Completely Miscible with Water (SA)

Soluble in Diethyl ether, Acetone, and Alcohol. Partially Soluble in Cold Water. Soluble in ~30 parts water. Slightly soluble in Propylene Glycol. (SpectrumChemical)

Soluble in Water (SA) 65g/L Water at 20C (SA) Water soluble (SA)

2.6g/100mL H2O (SA)

Slightly Soluble in Water (SA)

Very slightly soluble in cold water. Solubility in Water is 0.416g/100mL H2O at 25C (ScienceLab)

Toxicity
LD50 5331mg/kg (Oral, Rat) (SA) LD50 800mg/kg (Oral, Rat) (SA) LD50 1187-2769mg/kg (Oral, Rat) (SA)

LD50 1120mg/kg (Oral, Rat) (SA)

LD50 1215mg/kg (Oral, Rat) (SA) LD50 5620mg/kg (Oral, Rat) (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 5000mg/kg (Oral, Rat) (SA) LD50 2301mg/kg (Oral, Rat) (SA)

Safety/Comments
Irritant (SA) Unstable Reactive, Harmful by Ingestion, Corrosive (SA); Work in Hood Toxic by Inhalation, Toxic by Ingestion, Toxic by Skin Absorption (SA) Corrosive and Toxic. Contact or Inhalation can Cause Severe Damage to Skin, Eyes, and Respiratory Tract. Wear Gloves, Avoid Contact, Do Not Inhale its Vapors, and Keep Away from Flames. (NB); Work in Hood Lachrymator and Strong Irritant, Inhalation and Skin Absorption are Harmful. Avoid Contact and Do Not Breath its Vapors. Forms Explosive Peroxides on Standing so, Never Distill to Dryness. (NB); Work in Hood Corrosive (SA) Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood. Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. No Known OSHA Hazards (SA) Irritant (SA)

Notes on Source of Information

ACS Reagent 37% MSDS from SA

Name
Magnesium Turnings Bromobeneze Diethyl Ether (ethyl ether, ether) Benzophenone (Diphenyl Ketone) Water Hydrochloric Acid Sodium Bicarbonate (Sodium hydrogen carbonate) Sodium Chloride Magnesium Sulfate, Anhydrous Hexanes Acetone Dichloromethane (Methylene chloride) Triphenylmethanol (Trityl alcohol, Triphenylcarbinol) Sodium Sulfate, Anhydrous Granular Ethyl acetate Calcium Chloride, Anhydrous (Beads) Biphenyl

Formula
Mg C6H5Br C4H10O (C6H5)2CO C13H10O (SA) H2O HCl NaHCO3 NaCl MgSO4 C6H14 C3H6O CH2Cl2 C19H16O Na2O4S C4H8O2 CaCl2 C12H10

Benzene

C6H6

MW (g/mol)
24.3 (NB); 24.31 (SA) 157.01 (SA) 74.1 (NB) 182.2 (NB) 18.02 (SA) 36.46 (SA) 84.01 (SA) 58.44 (SA) 120.37 (SA) 86.18 (SA) 58.08 (SA) 84.93 (SA); 84.9 (NB) 260.3 (NB) 142.04 (SA) 88.11 (SA) 110.98 (SA) 154.21 (SA)

MP (C)
648 (SA) MP -31 (NB and SA) MP -116 (NB) 48 (NB) 0.0 (SA) MP -30 (SA) 300 (SA) 801 (SA) MP -95 (SA) MP -94 (SA) MP -97 (NB) 164 (NB) 884 (SA) MP -84 (SA) 772 (SA) 68-70 (SA)

BP (C)
1090 (SA) 156 (NB and SA) 34.5 (NB) 306 (NB) 100 (SA) >100 (SA) decmp 1413 (SA)
69 (SA)

56 (SA) 39.8-40 (SA); 40 (NB) 380 (NB) 76.5-77.5 (SA) 1670 (SA) 255 (SA)

78.11 (SA)

5.5 (SA)

80 (SA)

Density (g/ml)
1.74 (SA) 1.495 (NB) 0.714 (NB)

1.000 at 3.98C (SA) 1.18 at 25C (SA) 2.160 (SA) 2.165 (SA) 2.66
0.659 at 25C (SA)

0.791 at 25C (SA) 1.325 at 25C (SA); 1.327 (NB) 1.199 (Fischer http://fscimage.fishersci.com/msds/45870.htm) 2.68 at 25C (SA) 0.902 at 25C (SA) 2.150 (SA) 0.992 (SA)

0.874 at 25C (SA)

Flammability
Flammable Flammable (SA) Flammable (SA), Extremely Flammable (NB) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Highly Flammable (SA) Highly Flammable (SA) Non-Flammable (SA)

Highly Flammable (SA) Non-Flammable (SA) Non-Flammable (SA)

Flammable (SA)

Solubility
Insoluble in Water (Acros) insoluble in Water (https://fscimage.fishersci.com/msds/03420.htm) 65g/L H2O at 20C (SA) Easily Soluble in Acetone, Soluble in Methanol, Diethyl Ether. Insoluble in Cold Water (ScienceLab) Soluble in Water (SA) 50g/L H2O(SA) Soluble in Water (SA) 26g/100L H2Oat 0C (http://fscimage.fishersci.com/msds/13510.htm) Water Insoluble (SA) 2.6g/100mL H2O (SA) Slightly Soluble in Water (SA) Water Insoluble (http://fscimage.fishersci.com/msds/45870.htm) Water Soluble (SA) Water soluble (SA) 0.0075g/L H2O at 15C (SA); Soluble in Diethyl ether. Very slightly soluble in n-octanol. Insoluble in Cold Water and Hot Water. (ScienceLab) Miscible in Alcohol, Chloroform, Carbon Disulfide Oils, Carbon Tetrachloride, Glacial Acetic Acid, Diethyl Ether, and Acetone. Very slightly soluble in cold water. Water/Oil Dist. Coeff: More Soluble in Oil; Log Oil/Water=2.1 (ScienceLab)

Toxicity
LD50 300mg/kg (Oral, Mouse) (Clearsynth) LD50 2,383mg/kg (Oral, Rat) (SA) LD50 1215mg/kg (Oral, Rat) (SA) LD50 Greater than 10,000mg/kg (Oral, Rat) (SA)

LD50 4220 mg/kg (Oral, Rat) (SA) LD50 3,550mg/kg (Oral Rat) (SA) LD50 25,000mg/kg (Oral Rat) (SA) LD50 5,800mg/kg (Oral, Rat) (SA) LD50 1600mg/kg (Oral, Rat) (SA)

LD50 5989mg/kg (Oral, Mouse) (SA) LD50 5620mg/kg (Oral, Rat) (SA) LD50 2301mg/kg (Oral, Rat) (SA) LD50 2140mg/kg (Oral, Rat) (SA)

LD50 2990mg/kg (Oral, Rat) (SA)

Safety/Comments

Keep Away from Flames and Hot Surfaces (NB) Eye and Skin Irritation; Inhalation, Ingestion, or Skin Absorptions May be Harmful. Avoid Contract with Liquid and Do Not Brea May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.

No Known OSHA Hazards (SA) Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood No Known OSHA Hazards (SA) No Known OSHA Hazards (SA) Hygroscopic (SA)
Irritant, Teratogen, May be Fatal if Swallowed or Inhaled, Do not breath dust/fume/gas/mist/vapors/spray (SA); Work in Hood

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant (SA) No Known OSHA Hazards (SA) Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood Irritant (SA) Irritant, Mutagen (SA)

Irritant, Carcinogen, Mutagen (SA)

Notes on Source of Information Liquid and Do Not Breath Vapors (NB)

ACS Reagent 37% MSDS from SA

Anhydrous Hexanes MSDS from SA

r Liver and Kidneys (SA)

Name
Sodium Hydroxide Water Acetone

Formula
NaOH H2O C3H6O

Dichloromethane (Methylene chloride) Magnesium Sulfate, Anhydrous Sodium Chloride Benzyltriphenylphosphonium Chloride trans -Cinnamaldehyde Ethanol

CH2Cl2 MgSO4 NaCl C25H22ClP C9H8O C2H6O

Triphenylphosphine Oxide

C18H15OP

Ph3PO

(E, E)-1,4-diphenyl-1,3-butadiene (E, Z)-1,4-diphenyl-1,3-butadiene

C16H14 C16H14

MW (g/mol)
40.00 (SA) 18.02 (SA) 58.08 (SA)

MP (C)
318 (SA) 0.0 (SA) MP -94 (SA)

BP (C)
1390 (SA) 100 (SA) 56 (SA)

84.93 (SA); 84.9 (NB) 120.37 (SA) 58.44 (SA) 388.9 (NB) 132.2 (NB) 46.07 (SA)

MP -97 (NB)

39.8-40 (SA); 40 (NB)

801 (SA) 300 (SA) MP -7.5 (NB) MP -114 (SA)

1413 (SA)

246 (NB) 78.3 (SA)

278.28 (SA)

150-157 (SA)

206.3 (NB) 206.3 (NB)

153 (NB); 150-152 (SA) or 151-154 (SA) 88 (NB)

350 (SA)

Density (g/ml)
2.1300 (SA) 1.000 at 3.98C (SA) 0.791 at 25C (SA)

Flammability
Non-Flammable (SA)

Highly Flammable (SA)

1.325 at 25C (SA); 1.327 (NB) 2.66 2.165 (SA)

Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Non-Flammable (SA) Combustible (SA and ScienceLab) Flammable (SA)

1.050 (NB) 0.789 (SA)

Solubility

2.6g/100mL H2O (SA)

Slightly Soluble in Water (SA) 26g/100L H2Oat 0C (http://fscimage.fishersci.com/msds/13510.htm) Soluble in Water (SA) Soluble in Methanol and Diethyl Ether. Very slightly soluble in Cold Water (ScienceLab) Completely Water Soluble (SA) Almost insoluble in deionized water, cyclohexane, petroleum ether, and hexane. Readily soluble in ethanol, formic acid, acetic acid, and dichloromethane. (Article Hu, F.H.; Wang, L.S.; Cal, S.F. Solubilities of Triphenylphosphine Oxide in Selected Solvents. J. Chem. Eng. Data 2009, 54, 1382-1384.) Soluble in Alcohol, Sparingly Soluble in Ether (TCI)

Toxicity

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 3,550mg/kg (Oral Rat) (SA) LD50 43mg/kg (Oral, Rat) (SA) LD50 2220mg/kg (Oral, Rat) (ScienceLab) LD50 7060mg/kg (Oral, Rat) (SA)

LD50 1380mg/kg (Oral, Mouse) (SA)

Safety/Comments
Corrosive (SA). Toxic and Corrosive - Causing Severe Damage to Skin, Eyes, and Mucous Membranes. Wear Gloves and Avoid Contact with the NaoH Solution. (NB) No Known OSHA Hazards (SA) Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA) May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Hygroscopic (SA) No Known OSHA Hazards (SA) Highly Toxic by Ingestion - Fatal if Swallowed (SA). Skin Irritant - Avoid Contact (NB) Irritant - Avoid Contant with Skin and Eyes. Avoid Inhalation of Vapor or Mist. (SA)

Notes on Source of Information

ACS Reagent 99.5%, 200 Proof MSDS from SA

Harmful by Ingestion, Irritant (SA)

Aldrich Reagent 98% MSDS from SA

Irritant (SA); Work in Hood

Fluka HPLC Reagent 99.0% from SA