vol in 10 ml vol

10
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90

EXPERIMENTAL
mass % MeOH n

mass

1
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9

0.9264
1.8528
2.316
2.7792
3.2424
3.7056
4.1688
4.632
5.0952
5.5584
6.0216
6.4848
6.948
7.4112
7.8744
8.3376

10
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90

1.3345
1.337
1.3381
1.3397
1.3408
1.3421
1.343
1.3435
1.3435
1.3435
1.3435
1.3425
1.342
1.3412
1.3391
1.3381

8.128592
14.21698
17.15411
21.80295
25.33483
30

1.348
1.346
1.344
1.342
1.34
n

Vol % MeOH

1.338
1.336
1.334

1.332
1.33
1.328

10
REAL VALUES
wt% MeOH

n
0
1
2
3
4
5
6
7
8
9
10
12
14
16
18
20
24
28
32
36
40
44
48
52
56
60
64

1.333
1.3332
1.3334
1.3336
1.3339
1.3341
1.3344
1.3346
1.3349
1.3351
1.3354
1.3359
1.3365
1.337
1.3376
1.3381
1.3392
1.3402
1.3411
1.3419
1.3425
1.3429
1.3431
1.3431
1.3429
1.3426
1.3422

1.3397 30.26153
1.339452

68
72
76
80
84
88
92
96
98
100

1.3415
1.3407
1.3397
1.3385
1.3372
1.3357
1.3339
1.3316
1.3304
1.329

y = -5E-06x2 + 0.0005x + 1.3289

Calibration Curve
R = 0.9736
1.348
1.346
1.344
1.342
EXPERIMENTAL

1.34

REAL VALUES

1.338

Poly. (EXPERIMENTAL)

1.336

Poly. (REAL VALUES)

1.334

1.332
1.33
1.328
0

50

100

150

y = -5E-06x2 + 0.0005x + 1.3317

R = 0.9776

wt % MeOH
The Density used to get the Mass percents was the density for a 50/50 solution
Density g/cm3 50/50 sln
0.9264
total mass of 10 ml sln
9.264

XPERIMENTAL)

EAL VALUES)

0.0005x + 1.3317

nsity for a 50/50 solution

stage

c*

root1

1.00
1.337
2.00
1.3385
3.00
1.3412
4.00
1.34
5.00
1.3348
6.00 1.331275

-0.01
-0.01
-0.01
-0.01
-0.01
0.00

20.34
25.92
43.68
33.27
13.67
5.00

1.00
2.00
3.00
4.00
5.00
6.00

-0.01
-0.01
-0.01
-0.01
-0.01
-0.01

41.06
41.06
20.00
44.90
25.92
22.07

1.341
1.341
1.3369
1.34127
1.3385
1.3375

Experimental
wt% MeOH exp
Chosen One
79.66
74.08
56.32
66.73
86.33
95.00
Vapor Experimental
58.94
58.94
80.00
55.10
74.08
77.93

20.34
25.92
43.68
66.73
86.33
95

Total Mass MeOH

0.2034
0.2592
0.4368
0.6673
0.8633
0.95

41.06
58.94
80
55.1
74.08
77.93

0.4106
0.5894
0.8
0.551
0.7408
0.7793

Stages 3 and 4 for liquid and 1 2 and 4 for liquid gave refractive index that were unreal
for the data fit

Distillate concentration of .91 used since our real vapor concentration is only 66.51

stage

n
1.00
2.00
3.00
4.00
5.00
6.00
1.00
2.00
3.00
4.00

c*
1.337
1.3385
1.34
1.34
1.3348
1.3374
1.344
1.344
1.3369
1.3417

root1
-0.01
-0.01
-0.01
-0.01
0.00
-0.01
-0.01
-0.01
-0.01
-0.01

Theoretical using n values given in the charts

wt% MeOH theor chosen
12.05
87.95
12.05
16.24
83.76
16.24
21.02
78.98
21.02
21.02
78.98
21.02
6.64
93.36
93.36
13.12
86.88
86.88
43.68
56.32
43.68
43.68
56.32
43.68
11.79
88.21
88.21
27.64
72.36
72.36

0.120526681
0.16236114
0.210172465
0.210172465
0.933589668
0.868781778
0.436754289
0.436754447
0.882099463
0.723606798

5.00
6.00

1.3385
1.3375

-0.01
-0.01

16.24
13.39

83.76
86.61

83.76
86.61

0.83763886
0.866060104

1.00
Mol Percent
12.56
16.44
30.37
53.01
78.03
91.44

a
b
c

28.15
44.67
69.23
40.84
61.65
66.51

stage
1
2
3
4
5
6

stage
1
2
3
4
5
6

7.16
9.83
13.02
13.02
88.77
78.83
30.37
30.37
80.80
59.56

Xn

Yn

For vapor Efficiencies

Yn*
Yn
12.55882878
0.45
16.44484548
0.54
30.37458277
0.66
53.01220772
0.78
78.03332362
0.91
91.44385027
0.95

EMV

Yn+1
0.28
0.44
0.69
0.40
0.61
0.66

For Liquid Efficiency

Xn*
Xn
28.15371254
0.05 12.55883
44.67332536
0.12 16.44485
69.23076923
0.34 30.37458
40.83834308
0.09 53.01221
61.65113182
0.24 78.03332
66.51272179
0.28 91.44385

0.44
0.69
0.40
0.61
0.66

EMV
Xn+1
16.44485
30.37458
53.01221
78.03332
91.44385

-16.00
1.61
1.12
-1.24
-0.20

0.24
0.46
0.43
0.32
0.15

74.37
78.44

y = -5E-06x2 + 0.0005x + 1.3289

y = -5E-06x2 + 0.0005x + 1.3317
exp
theory
0.00
0.00
0.00
0.00
1.33
1.33

exp
theory

y
0
0.02
0.04
0.06
0.08
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

0
0.134
0.23
0.304
0.365
0.418
0.517
0.579
0.665
0.729
0.779
0.825
0.87
0.915
0.958
0.979
1
0.979

0.9

0.8

0.7

0.6

Feed Line
0.5

0.4
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1

0.3

0.2

0.1

0
0

TOP OP LINE

y=0.5723x+.39112
m=
x
y
0 0.39112
0.1 0.44835
0.2 0.50558
0.3 0.56281
0.4 0.62004
0.5 0.67727

0.1

0.5723 b=

0.2

0.3

0.39112

Using distillate concentration from liq

0.6
0.7
0.8
0.9
1
Bottom Op line

0.7345
0.79173
0.84896
0.90619
0.96342

Top Operating line

EXPERIMENTAL DATA

0.4

0.5

0.6

0.7

Using distillate concentration from liquid stage 6 since vapor is too low

0.8

0.9

Experimental Values
of the column
x
y
0.125588 0.281537
0.164448 0.446733
0.303746 0.692308
0.530122 0.408383
0.780333 0.616511
0.914439 0.665127