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MOCK TEST PAPER 2

CHEMISTRY
Time : 3 Hours
General Instructions: Same as in Mock Test Paper 1. Q.1. Q.2. Q.3. Q.4. Q.5. Q.6. Q.7. Q.8 What do you understand by dislocation with respect to crystals? (1) Write the units of the rate constant for second order reaction? (1) Why does phenol has higher boiling point than toluene? (1) Name the products when anisole is treated with HI. (1) (1) Which of the two Fe2+ or Zn2+ is coloured? Complete the reaction : XeF6 + H2O Out of C and CO, which is better reducing agent at 673 K? (1) What is oxidation state of P in: (1) (i) H3PO3 (ii) PH3 Crystalline CsBr has a bcc structure. Calculate the unit cell edge length if the density of CsBr crystal is 4.24 cm3. (2) Define the molar conductance. How does molar conductance of a weak electrolyte vary with dilution ? (2) 2+ Calculate the standard reduction potential of Ni /Ni if the cell potential of the cell: (2) Ni | Ni2+ (0.01)M || Cu2+(0.1 M) | Cu is 0.59 V. [Given that E 2 + = +0.34 V] Cu / Cu(s) Or A cell is set up between copper and silver electrode as : Cu | Cu2+ (aq) || Ag+(aq) | Ag. If the two half cells were under standard conditions, calculate e.m.f. of the cell. [Given ECu 2 + / Cu = +0.34 V
EAg + / Ag = + 0.80 V]

Max. Marks: 70

Q.9. Q.10. Q.11.

Q.12. Give the IUPAC names of the following compounds.

(2)

O || (i) (CH3 )2 C = CH C CH = C(CH3 ) 2 (ii) CH3OCH2CH2OC2H5 Q.13. Discuss the mechanism of dehydration when butan2-ol is heated with conc. H2SO4 at 443 K. Name the product formed. (2) Q.14. With the help of a suitable example, explain (2) (i) Aldol condensation

CBSE CHEMISTRY XII

(ii) Carbylamine reaction Q.15. (a) Give the resonating structures of NO2 and N2O5. (b) How can you prepare Cl2 from HCl ? Write reaction. Q.16. Complete and name the following reactions: (i) RCONH2 + Br2 + KOH

(2) (2)

(ii) RNH2 + CHCl3 + KOH Q.17. Name two components of starch. How do they differ from each other structurally. Q.18. Show how would you synthesise the following alcohols from suitable alkenes:
(i ) (ii) Q.19. Explain the following: (i) Antihistamines (ii) Artificial sweetening agents (iii) Anionic detergents Q.20. (a) What is the role of depressant in froth floatation process? (b) State the role of silica in the metallurgy of copper. (c) Copper can be extracted by hydrometallurgy but not zinc. Q.21. Give structure of A, B and C in the following reactions: (a) C6H5NO2
2 Fe/HCl A 273 K

(2) (2)

OH
OH

(3)

(3)

(3)

HNO

C6 H5OH B C
HNO 2 B 0C NH

KCN (b) CH3CH2Br

LiAIH 4 A
+

C C

(c) C6H5N2Cl

Q.22. An element with molar mass 2.7 10 kg mol forms a cubic unit cell with edge length 405 pm. If its density is 2.7 103 kg3, what is the nature of the cubic unit cell ? (3) Q.23. Mention what is required in case of the following polymers ? (3) (i) Nylon-66 : (Constituent units) (ii) Terylene : (Nature of linkage) (iii) Orlon (Monower) Q.24. (a) What are proteins ? Discuss denaturation of proteins. (b) What are amino acids ? Give two examples. (3) Q.25. (a) How will you prepare the colloidal solution of gold ? (3) (b) What happens when a small amount of FeCl3 is added to the precipitate of Fe (OH)3? (c) What is the difference between multi-molecular and macro-molecular colloids ? Q.26. How will you account for the following? (3) (i) Transition metals show variable oxidation states. (ii) It is not proper to regard Zn, Cd and Hg as the transition metals.

CuCN H 2O/H 3 A B
2 1

MOCK TEST PAPER 2

(iii) The ions of the transition metal atoms are generally coloured. Q.27. A reaction which is of first order with respect to the reactant, A has rate constant of 6 min1. If we start with [A] = 5.0 mol L1, when would value of [A] reach a value of 0.05 mol L1? (3) Or 0.05 M NaOH solution offered a resistance of 31.6 in a conductivity cell at 298 K. If the cell constant for the cell is 0.367 cm1, calculate the molar conductance of NaOH solution. Q.28. (a) Explain why the molecular mass of acetic acid when dissolved in benzene is more than the normal molecular mass. (5) (b) Osmotic pressure of a 100 cm3 of a solution containing 3.002 g of an unidentified solute is 2.55 atmospheres at 298 K. What is the molar mass of the solute ? Or (a) Why is the freezing point of a liquid depressed when a non-volatile solute is dissolved in it ? (b) Find the molarity of 15% H2SO4 (by mass). Density of H2SO4 is 1.1 g/cc. Q.29. (a) Discuss two tests with equations to distinguish between acetaldehyde and acetone ? (5) (b) What happens (write chemical equations) when: (i) HCl gas is passed through solution of acetone? (ii) Acetaldehyde is treated with HCN and the product is hydrolysed? (iii) Acetone is warmed with Zn and concentrated HCl ? Or (a) How will you distinguish between : (i) CH3CHO and CH3COCH3 (ii) CH3CHO and C6H5CHO (iii) CH3COC6H5 and C6H5COC6H5 (b) What is the decreasing order of reactivity of halogen acid (HCl, HBr, HI) towards primary alcohols ? Q.30. (a) What happens when : (5) (i) Conc. H2SO4 added to calcium fluoride. (ii) SO3 is passed through water. (b) Assign reasons for the following: (i) K a 2 << K a1 for H2SO4 in water. (ii) NO2 dimerizes.

Or (a) Describe the following about halogen family : (i) Relative oxidising power. (ii) Relative strengths of oxoacids. (iii) Order of boiling points of their hydrides. (b) Explain why does O3 act as a powerful oxidising agent.