, India
Corporate Office: Plot No:304,Kasetty Heights, Ayyappa Society, Madhapur  Hyd
Email:iconcohyd@srichaitanyacoll ege.net, Web: www.srichaitanya.net
JEEMAIN
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
2
IMPORTANT INSTRUCTIONS:
1. Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use of
pencil is strictly prohibited.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out
the Answer Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The test Booklet consists of 90 questions. The maximum marks are 360.
5. There are three parts in the question paper A, B, C consisting of Mathematics, Physics and Chemistry having
30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for each correct
response.
6. Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each question
1/4 (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from
the total score will be made if no response is indicated for an item in the answer sheet.
7. There is only one correct response for each question. Filling up more than one response in each question will
be treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6
above.
8. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side1 and Side 2 of the
Answer Sheet. Use of pencil is strictly prohibited.
9. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone,
any electronic device, etc., except the Admit Card inside the examination hall/room.
10. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is given
at the bottom of each page and in 3 pages (Pages 21 23) at the end of the booklet.
11. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
12. The CODE for this Booklet is G. Make sure that the CODE printed on Side2 of the Answer Sheet is the same
as that on this booklet. In case of discrepancy, the candidate should immediately report the matter to the
Invigilator for replacement of both the Test Booklet and the Answer Sheet.
13. Do not fold or make any stray mark on the Answer Sheet.
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
3
MATHEMATICS
1. The image of the line
x 1 y 3 z 4
3 1 5
= =
2)
x 3 y 5 z 2
3 1 5
= =
3)
x 3 y 5 z 2
3 1 5
= =
4)
x 3 y 5 z 2
3 1 5
= =
Key: 1
Sol :
x 1 y 3 z 4
is parallel to 2x y z 3 0
3 1 5
= = =
Image
h 1 k 3 l 4
2
2 1 1
= = =
( ) ( ) h, k, l 3, 5, 2 =
Required equation
x 3 y 5 z 2
3 1 5
= =
2. If the coefficients of
3 4
x andx in the expansion of
( )( )
18
2
1 ax bx 1 2x in powers
of x are both zero, then (a, b) is equal to:
1)
251
16,
3
1
( )
2)
251
14,
3
1
( )
3)
272
14,
3
1
( )
4)
272
16,
3
1
( )
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
4
Key : 4
Sol : Equating coefficients of
3 4
x and x is zero
32 17
17a b 0
3
=
16
15 32 a + 3b = 0
Solving (a, b) =
272
16,
3
1
( )
3. If a R and the equation [ [ ( ) [ [ ( )
2
2
3 x x 2 x x a 0 = (where [x] denotes the
greatest integer x _ ) has no integral solution, then all possible values of a lie in
the interval :
1) ( ) ( ) 1, 0 0, 1 '
2) (1, 2)
3) (2, 1)
4) ( ) ( ) , 2 2, '
Key : 1
Sol :
2 2
3f 2f a 0 = where [ [ ( )
x x
2
1 1 3a
f 1
3
= < 1 a 1; a 0 = < < =
( ) ( ) a 1, 0 0, 1 '
4. If
2
a bb c c a abc
l l
=X
l l
l l
then X is equal to:
1) 2
2) 3
3) 0
4) 1
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
5
Key : 4
Sol :
2
a bb c c a abc
l l
=
l l
l l
5. The variance of first 50 even natural numbers is :
1)
833
4
2) 833
3) 437
4)
437
4
Key : 2
Sol : Variance of first n even natural numbers is equal to
2
n 1
3
2
50 1
833
3
= =
6. A bird is sitting on the top of a vertical pole 20 m high and its elevation from a
point O on the ground is
0
45 . It flies off horizontally straight away from the
point O. After one second, the elevation of the bird from O is reduced to
0
30 .
Then the speed (in m/s) of the bird is:
1)
( )
40 2 1
2)
( )
40 3 2
3) 20 2
4)
( )
20 3 1
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
6
Key : 4
Sol :
P Q
A
B C
45
0
30
0
0
A 45 AB PB 20mtsandCQ 20 = = = = =
( )
0
20
Tan30 BC 20 3 1 PQ
20 BC
= = = =
( )
distance
speed 20 3 1 mts
time
= =
7. The integral
2
0
x x
1 4sin 4sin dx
2 2
t
]
equals:
1)
4 t
2)
2
4 4 3
3
t
3) 4 3 4
4) 4 3 4
3
t
Key : 4
Sol :
3
0 0
3
x x x
1 2sin dx 1 2sin dx 2sin 1 dx
2 2 2
t
t t
t
1 1
=
( ) ( )
] ] ]
3
0
3
x x
x 4cos 4cos x
2 2
t
t
t
l l
l l =
l l
l l
4 3 4
3
t
=
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
7
8. The statement ( ) ~ p ~q is :
1) equivalent to p q
2) equivalent to ~p q
3) a tautology
4) a fallacy
Key : 1
Sol : The statement ( ) ~ p ~q is
P q ~q
p ~q
( ) ~ p ~q
p q
T T F F T T
T F T T F F
F T F T F F
F F T F T T
( ) ~ p ~q is equivalent to p q
9. If A is an 3 3 nonsingular matrix such that
1
AA' A'A andB A A', then BB'
= =
equals :
1) I + B
2) I
3)
1
B
4)
( )
1
B
Key : 2
Sol :
( )( )
1
1 1 1 1
BB' A A A A
=
( )
1
1 1 1
A AA A I. I I
= = =
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
8
10. The integral
1
x
x
1
1 x e dx
x
1
( )
]
is equal to :
1) ( )
1
x
x
x 1 e c
2)
1
x
x
xe c
3) ( )
1
x
x
x 1 e c
4)
1
x
x
xe c
Key : 2
Sol :
1
x
x
1
1 x e dx
x
1
( )
]
1
x
x
2
1
1 x 1 e dx
x
l 1
l
( )
l
]
1 1
x x
x x
2
1
e dx x 1 e dx
x
1
=
( )
] ]
By parts =
1
x
x
xe c
11. If z is a complex number such that z 2, _ then the minimum value of
1
z
2
:
1) is equal to
5
2
2) lies in the interval (1, 2)
3) is strictly greater than
5
3
4) is strictly greater than
3
2
but less than
5
2
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
9
Key: 2
Sol : z rci s thenz r 2 = = _
2 2
2 2
1 1
z rcos r sin
2 2
1
=
( )
2
1
r rcos
4
=
17 9 25
2cos whichliesin ,
4 4 4
1 l
l _
l ( )
l
1 3 5
z ,
2 2 2
l
l
l
l
Minimum value
3
2
lies in (1, 2)
12. If g is the inverse of a function f and ( ) ( )
5
1
f ' x , theng' x
1 x
=
is equal to:
1)
5
1 x
2)
4
5x
3)
( )
5
1
1 g x
4) ( )
5
1 g x
Key : 4
Sol : If g is the inverse of a function f, then ( ) ( )
x f g x = ( ) ( ) ( ) f ' g x g' x 1 = =
( )
( )
( ) ( )
5 1
g' x 1 g x
f ' g x
= = =
l
l
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
10
13. If ( )
( ) ( )
( ) ( ) ( )
( ) ( ) ( )
n n
3 1 f 1 1 f 2
, 0, andf n and 1 f 1 1 f 2 1 f 3
1 f 2 1 f 3 1 f 4
o = =o
=
( ) ( ) ( )
2 2 2
K 1 1 , thenK o o is equal to :
1) o
2)
1
o
3) 1
4) 1
Key : 3
Sol : Given determinant =
2
2 2 2
1 1 1 1 1 1
1 . 1
1 1
o o o
o
K 1 =
14. Let ( ) ( )
k k
k
1
f x sin x cos x
k
= where x R and k 1 _ . Then ( ) ( )
4 6
f x f x equals:
1)
1
6
2)
1
3
3)
1
4
4)
1
12
Key : 4
Sol : ( ) ( )
4 6
f x f x =
2 2 2 2
1 1
[1 2sin xcos x] 1 3sin xcos x
4 6
l
l
l
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
11
15. Let and o be the roots of equation
2
px qx r 0, p 0 = = . If p, q, r are in A.P
and
1 1
4, =
o
then the value of   o is :
1)
61
9
2)
2 17
9
3)
34
9
4)
2 13
9
Key : 4
Sol :
q
p
o =
r
.
p
o =
2q p q =
By given condition
1 1
4 =
o
q
4
r
=
( )
2
4 o = o o
16. Let A and B be two events such that
( ) ( ) ( )
1 1 1
P A B , P A B and P A , whereA
6 4 4
' = = = stands for the complement of the
event A. Then the events A and B are :
1) mutually exclusive and independent
2) equally likely but not independent
3) independent but not equally likely
4) independent and equally likely
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
12
Key : 3
Sol : ( )
1 5
P A B 1
6 6
' = =
( ) ( )
1 5
P A P B
4 6
=
( )
3 1 5
P B
4 4 6
=
( )
5 1 5 3 1
P B
6 2 6 3
= = =
( ) ( ) ( )
3 1 1
P A .P B P A B
4 3 4
= = =
A, B are independent but not equally likely ( ) ( ) ( )
P A P B =
17. If f and g are differentiable functions in [0, 1] satisfying f(0) = 2 = g(1), g(0) = 0
and f(1) = 6, then for some c ]0, 1[ :
1) ( ) ( ) 2f ' c g' c =
2) ( ) ( ) 2f ' c 3g' c =
3) ( ) ( ) f ' c g' c =
4) ( ) ( ) f ' c 2g' c =
Key : 4
Sol :
( )
( )
( ) ( )
( ) ( )
( )
f ' c f 1 f 0
for c 0, 1
g' c g 1 g 0
18. Let the population of rabbits surviving at a time t be governed by the
differentiable equation
( )
( )
dp t 1
p t 200
dt 2
= . If p(0) = 100, then p(t) equals :
1)
t/2
400 300e
2)
t/2
300 200e
3)
t/2
600 500e
4)
t/2
400 300e
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
13
Key : 1
Sol : ( )
dp 1
p t 200
dt 2
=
This is linear d.e in p
1 1
t t
2 2
p.e 400e c
=
By given condition p(0) = 100, c = 300
1
t
2
p 400 300e =
19. Let C be the circle with centre at (1, 1) and radius = 1. If T is the circle
centred at (0, y), passing through origin and touching the circle C externally,
then the radius of T is equal to :
1)
3
2
2)
3
2
3)
1
2
4)
1
4
Key : 4
Sol :
( ) ( )
1 2
c 1, 1 c 0, y = =
1 2
r 1, r y = =
1 2 1 2
cc r r =
( ) ( )
2 2
1 y 1 1 y =
1= 4y
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
14
20. The area of the region described by ( )
2 2 2
A x, y :x y 1and y 1 x = _ _ is
1)
4
2 3
t
2)
4
2 3
t
3)
2
2 3
t
4)
2
2 3
t
Key : 1
Sol.
Required area =
1
0
4
2 1 x dx
2 2 3
t t
=
]
21. Let a, b, c and d be nonzero numbers. If the point of intersection of the line
4ax + 2ay + c = 0 and 5bx + 2by + d = 0 lies in the fourth quadrant and is
equidistant from the two axes then :
1) 2bc 3ad = 0
2) 2bc + 3ad = 0
3) 3bc 2ad = 0
4) 3bc + 2ad = 0
Key : 3
Sol. Point of intersection
2ad 2bc 5bc 4ad
,
2ab 2ab
1
=
( )
Equidistance from the both axis in
fourth quadrant
3bc 2ad 0 =
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
15
22. Let PS be the median of the triangle with vertices P(2, 2), Q(6, 1) and R(7, 3).
The equation of the line passing through (1, 1) and parallel to PS is
1) 4x 7y 11 0 =
2) 2x 9y 7 0 =
3) 4x 7y 3 0 =
4) 2x 9y 11 0 =
Key : 2
Sol : Mid point
13
,1
2
1
=
( )
Slope PS
2
9
=
23.
( )
2
2
x 0
sin cos x
lim
x
t
is equal to :
1)
2
t
2) 1
3) t
4)
t
Key : 4
Sol :
( )
2
2
x 0
sin sin x
lim
x
tt
( )
2
2
2 2
x 0
sin sin x
sin x
lim 1 1
sin x x
t
t
= t =t
t
24. If
n
X 4 3n 1: n N = and ( )
Y 9 n 1 :n N , = where N is the set of natural
numbers, then X Y ' is equal to:
1) N
2) Y X
3) X
4) Y
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
16
Key : 4
Sol : X and Y are multiplies of 9 and X Y
X Y Y ' =
25. The locus of the foot of perpendicular drawn from the centre of the ellipse
2 2
x 3y 6 = on any tangent to it is :
1)
( )
2
2 2 2 2
x y 6x 2y =
2)
( )
2
2 2 2 2
x y 6x 2y =
3)
( )
2
2 2 2 2
x y 6x 2y =
4)
( )
2
2 2 2 2
x y 6x 2y =
Key : 3
Sol. Given that ellipse
2 2
x y
1
6 2
=
C
P
A
B
Slope CP =
1
1
y
x
Slope of AB =
1
1
x
y
= m
Equation of the tangent is
2
y mx 6m 2 =
By above equations we get
( )
2
2 2 2 2
x y 6x 2y =
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
17
26. Three positive numbers from an increasing G.P. If the middle term in this G.P is
doubled, the new numbers are in A.P. Then the common ratio of the G.P is :
1) 2 3
2) 3 2
3) 2 3
4) 2 3
Key : 4
Sol :
2
a,ar,ar G.P .
2
a ar
2ar
2
=
2
4ar a ar =
2
r 4r 1 0 =
4 16 4
r
2
=
r 2 3 =
r 2 3 = =
27. If ( ) ( ) ( ) ( ) ( ) ( ) ( )
9 1 8 2 7 9 9
10 211 10 311 10 ..... 1011 k 10 , = then k is equal to
1)
121
10
2)
441
100
3) 100
4) 110
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
18
Key : 3
Sol : ( ) ( ) ( ) ( ) ( ) ( )
9 1 8 2 7 9
S 10 211 10 311 10 .....1011 = (1)
( ) ( ) ( ) ( ) ( )
2 3 6 10
8 7
11
S 11.10 2 11 10 311 10 .....9 11 11
10
= (2)
(2) ... (1)
( )
( )
2
9 8 7 9 10
1
S 10 11.10 11 10 .... 11 11
10
=
( )
9
S 100 10 =
K 100 =
28. The angle between the lines whose direction cosines satisfy the equations
2 2 2
m n 0and m n l l = = is :
1)
3
t
2)
4
t
3)
6
t
4)
2
t
Key : 1
Sol :
2 2 2
l m n 0 =
( ) l m n =
( )
2
2 2
m n m n 0 =
2mn = 0
m = 0 (or) n = 0
If m = 0
l = (0 + n)
l = n
l : m : n = n : 0 : n = 1 : 0 : 1
similarly if n = 0 then
l : m : n = 1, : 1 : 0
1 0 0
cos
2 2
=
3
t
=
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19
29. The slope of the line touching both the parabolas
2 2
y 4x andx 32y = is :
1)
1
2
2)
3
2
3)
1
8
4)
2
3
Key : 1
Sol : Common tangent of ( )
2/3
2 2 1/3 1/3
y 4ax andx 4byisa x b y ab 0 = = =
Here 4a = 4 and 4b = 32
Slope of the common tangent = 1/2
30. If x = 1 and x = 2 are extreme points of ( )
2
f x logx x x =o then:
1)
1
6,
2
o = =
2)
1
6,
2
o = =
3)
1
2,
2
o = =
4)
1
2,
2
o = =
Key : 3
Sol : ( ) ( ) f ' 1 0andf ' 2 0 = =
Solving above equations we get
1
2,
2
o = =
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20
PHYSICS
31. When a rubberband is stretched by a distance x , it exerts a restoring force of
magnitude
2
F ax bx = + where a and b are constants. The work done in stretching
the unstretched rubberband by L is:
1)
2 3
1
2 2 3
aL bL  
+

\ .
2)
2 3
aL bL +
3)
( )
2 3
1
2
aL bL +
4)
2 3
2 3
aL bL
+
Key: 4
Sol:
( )
2 3
2
0
2 3
L
aL bL
w Fdx ax bx dx = = + = +
} }
32. The coercivity of a small magnet where the ferromagnet gets demagnetized is
3 1
3 10 Am
 
=

\ .
has focal length f . When it is
measured in two different liquids having refractive indices
4
3
and
5
3
, it has the
focal lengths
1
f and
2
f respectively. The correct relation between the focal lengths
is:
1)
1
f and
2
f both become negative
2)
1 2
f f f = <
3)
1
f f > and
2
f becomes negative
4)
2
f f > and
1
f becomes negative
Key: 3
Sol: From
( )
1 2
1
f R
(
=
(
1 1
f R
=   3 2 / =
f R =
For medium 4 3 / =
3
1 2 1
2
1
4 3 4 f / R R
 

= =


\ .
1
4 f R =
for medium
2
1 3 2 2
5 3 1
5 3
/
M /
f / R
 
= =

\ .
1
5R
=
2
5 f R =
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25
39. A parallel plate capacitor is made of two circular plates separated by a distance
of 5 mm and with a dielectric of dielectric constant 2.2 between them. When the
electric field in the dielectric is
4
3 10 / V m , the charge density of the positive plate
will be close to:
1)
4 2
6 10 / C m
2)
7 2
6 10 / C m
3)
7 2
3 10 / C m
4)
4 2
3 10 / C m
Key: 2
Sol:
4
0
3 10
K
o
=
e
12 4
2.2 8.8 10 3 10 o
=
7
6 10 o
=
40. In the circuit shown here, the point C is kept connected to point A till the
current flowing through the circuit becomes constant. Afterward, suddenly, point
C is disconnected from point A and connected to point Bat time t=0. Ratio of
the voltage across resistance and the inductor at t = L/R will be equal to:
L
R
B
A
C
1)
1 e
e
2)
1
e
e
3) 1
4)
1
Key: 4
Sol: 0
R L
V V + = always for 0 t >
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26
41. Two beams, A and B, of plane polarized light with mutually perpendicular planes
of polarization are seen through a polaroid. From the position when the beam A
has maximum intensity (and beam B has zero intensity), a rotation of polaroid
through 30 makes the two beams appear equally bright. If the initial intensities
of two beams are
A
I and
B
I respectively, then
A
B
I
I
equals:
1)
1
3
2) 3
3)
3
2
4)
1
Key: 1
Sol:
1 1 2 2
30 60
A B A B
I I I cos I cos = =
2
2
cos 60 1
cos 30 3
A
B
I
I
= =
42. There is a circular tube in a vertical plane. Two liquids which do not mix and of
densities
1
d and
2
d are filled in the tube. Each liquid subtends 90 angle at centre.
Radius joining their interface makes an angle
o
with vertical. Ratio
1
2
d
d
is:
o
1
d
2
d
1)
1 sin
1 cos
o
o
+
2)
1 sin
1 sin
o
o
+
3)
1 cos
1 cos
o
o
+
4)
1 tan
1 tan
o
o
+
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27
Key: 4
Sol:
A B
P P =
1 1 2 2
h d g h d g =
( ) ( )
1 2
cos sin cos sin R d R d o o o o = +
1
2
cos sin 1 tan
cos sin 1 tan
d
d
o o o
o o o
+ +
= =
A
B
R
2
h
2
d
1
d
1
h
R
o
o
43. The pressure that has to be applied to the ends of a steel wire of length 10 cm to
keep its length constant when its temperature is raised by 100 C is: (For steel
Youngs modulus is
11 2
2 10 N m
= + , ( )
096 026 012
100
46 13 12
. . .
T T T = +
200 5T =
40 T C =
Heat flow per sec through copper
( ) 100 KA T
l
=
( ) 096 4 60
46
.
= 48 . = cal/sec
0 C
0 C
100 C
B
r
a
s
s
C
o
p
p
e
r
S
t
e
e
l
l
=
1
3
c
m
k
=
0
.
2
6
l
=
1
2
c
m
k
=
0
.
1
2
l
=
4
6
k
=
0
.
9
6
T
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30
46. A mass m is supported by a massless string wound around a uniform hollow
cylinder of mass m and radius R. If the string does not slip on the cylinder, with
what acceleration will the mass fall on release?
m
R
m
1) g
2)
2
3
g
3)
2
g
4)
5
6
g
Key: 3
Sol: mg T ma =
2 2
.
a
TR mR mR T ma
R
o = = =
2ma mg = or / 2 a g =
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31
47. Match ListI (Electromagnetic wave type) with List II (Its
association/application) and select the correct option from the choices given
below the lists:
ListI ListII
(a) Infrared waves (i) To treat muscular strain
(b) Radio waves (ii) For broadcasting
(c) Xrays (iii) To detect fracture of bones
(d) Ultra violet rays (iv) Absorbed by the ozone layer
of the atmosphere
(a) (b) (c) (d)
1) (i) (ii) (iii) (iv)
2) (iv) (iii) (ii) (i)
3) (i) (ii) (iv) (iii)
4) (iii) (ii) (i) (iv)
Key: 1
Sol: Conceptual
48. The radiation corresponding to 3 2 transition of hydrogen atom falls on a
metal surface to produce photoelectrons. These electrons are made to enter a
magnetic field of
4
3 10 T
.
Assume parallel motion along the x axis.
x
y B
I
2.0
1.5
1.5
1) 29.7 W
2) 1.57 W
3) 2.97 W
4) 14.85 W
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35
Key: 3
Sol:
4 0.2
Instant 3
2
3 10 3
5 10
x
P B V e
= =
1 0.2
12
10
5
x
P e
=
2.97
range
pdx
P W
dx
= ~
}
}
54. The forward biased diode connection is:
1)
2V
2V +
2)
2V 2V +
3)
3V 3V
4)
2V
4V
Key: 2
Sol: Conceptual
55. Hydrogen
( )
1
1
H , Deuterium
( )
2
1
H , singly ionized Helium
( )
4
2
He
+
and doubly
ionized lithium
( )
6
3
Li
++
all have one electron around the nucleus. Consider an
electron transition from 2 n = to 1 n = . If the wavelengths of emitted radiation are
1 2 3
, , and
4
respectively then approximately which one of the following is
correct?
1)
1 2 3 4
2 3 4 = = =
2)
1 2 3 4
4 2 2 = = =
3)
1 2 3 4
2 2 = = =
4)
1 2 3 4
4 9 = = =
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36
Key: 4
Sol:
2
2
1 1 1
1
4
Rz
z
o
 
=

\ .
1 2
= as 1 z = for both
1
1
H and
2
1
H
2
3 1
1 3 2
3 1
4 4
z
z
= = =
2
1 4
1 4 2
4 1
9 9
z
z
= = =
1 2 3 4
4 9 = = =
56. On heating water, bubbles being formed at the bottom of the vessel detach and
rise. Take the bubbles to be spheres of radius R and making a circular contact of
radius r with the bottom of the vessel. If , r R << and the surface tension of water
is T, value of r just before bubbles detach is: (density of water is
w
)
R
2r
1)
2
3
w
g
R
T
2)
2
3
w
g
R
T
3)
2
6
w
g
R
T
4)
2 w
g
R
T
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37
Key: 3(This is an ambigious Question, so expected key is 3)
Sol: sin Tdl u =
}
buoyancy force on bubble
R
u
r r
( ) 2
r
T r
R
t
3
4
3
w
R g t =
4
2
2
3
w
R g
r
T
=
2
2
3
w
g
r R
T
=
57. A pipe of length 85 cm is closed from one end. Find the number of possible
natural oscillations of air column in the pipe whose frequencies lie below 1250
Hz. The velocity of sound in air is 340 m/s.
1) 4
2) 12
3) 8
4) 6
Key: 4
Sol: From
2
340
100
4 4 85 10
V
n HZ
l
= = =
Possible frequencies in closed pipe is odd harmonics only So
100 300 500 700 900 HZ, HZ, HZ, HZ, HZ and 1100 1300 1500 HZ, HZ, HZ..... etc below
1250HZ , 6 natural oscillations are possible
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38
58. Assume that an electric field
2
30 E x i =
2
H
AC O
B C
+
ONa
The major product C would be:
1)
3
OCOCH
COOH
2)
3
OCOCH
COOH
3) OH
3
COCH
3
COCH
4) OH
3
COOCH
Key: 2
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42
Sol:
ONa
0
125 C
5atm 2
CO +
OH
COOH
H
AC O
2
+
COOH
3
OCOCH
(B)
(C)
Aspirin
64. Given below are the halfcell reactions:
2 0
2 ; 1.18 Mn e Mn E V
+
+ =
( )
3 2 0
2 ; 1.51 Mn e Mn E V
+ +
+ = +
The
0
E for
2 3
3 2 Mn Mn Mn
+ +
+ will be:
1)  0.33 V; the reaction will occur
2) 2.69 V; the reaction will not occur
3) 2.69 V; the reaction will occur
4) 0.33 V; the reaction will not occur
Key: 2
Sol:
0
1.18 1.51 E =
= 2.69 V
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65. For complete combustion of ethanol. ( ) ( ) ( ) ( )
2 5 2 2 2
3 2 3 C H OH l O g CO g H O l + + , the
amount of heat produced as measured in bomb calorimeter, is 1364.47
1
kJmol
at
0
25 C . Assuming ideally the Enthalpy of combustion,
c
H A , for the reaction will be:
( )
1
8.314 R kJmol
=
1)
1
1350.50kJmol
2)
1
1366.95kJmol
3)
1
1361.95kJmol
4)
1
1460.50kJmol
Key: 2
Sol: H U nRT A A A = +
( )
3
1364 1 8.314 298 10
=
66. For the estimation of nitrogen, 1.4 g of an organic compound was digested by
Kjeldahl method and the evolved ammonia was absorbed in 60 mL of
10
M
sulphuric acid. The unreacted acid required 20 mL of
10
M
sodium hydroxide for
complete neutralization. The percentage of nitrogen in the compound is:
1) 5%
2) 6%
3) 10%
4) 3%
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Key: 3
Sol: Meq of
2 4
1
H SO 60 2 12
10
= =
Meq of base used for back titration
1
20 2
10
= =
= Meq of acid left
Meq of acid reacted with liberated
Ammonia = 122 = 10 meq
= meq of
3
NH
Millimoles of
3
NH liberated = 10 [
nfactor = 1]
Moles of
3
3
NH 10 10
=
Moles N
3
10 10
=
Wt of N
3
10 10 14
=
% of N in the organic compound
3
10 10 14
100 10%
1.4
= =
67. The major organic compound formed by the reaction of 1, 1, 1 trichloroethane
with silver powder is:
1) 2 Butene
2) Acetylene
3) Ethene
4) 2 Butyne
Key: 4
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Sol:
3
2CH C Cl
Cl
Cl
3 3
6Ag CH C C CH +
2Butyne
+6 AgCl
68. The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 :
4. The ratio of number of their molecule is:
1) 3 : 16
2) 1 : 4
3) 7 : 32
4) 1 : 8
Key: 3
Sol: Ratio of the molecules =
1 4
:
32 28
= 7: 32
69. The metal that cannot be obtained by electrolysis of an aqueous solution of its salt
is:
1) Cr
2) Ag
3) Ca
4) Cu
Key: 3
Sol: Ca cannot be obtained by the electrolysis of aqueous solution of its salt.
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70. The equivalent conductance of NaCl at concentration C and at infinite dilution
are
C
and
is given as
(where the constant B is positive)
1) ( )
C
B C
= +
2) ( )
C
B C
= +
3) ( )
C
B C
=
4) ( )
C
B C
=
Key: 4
Sol: ( )
C
B C
=
71. The correct set of four quantum numbers for the valence electrons of rubidium
atom (Z=37) is:
1)
1
5,0,1,
2
+
2)
1
5,0,0,
2
+
3)
1
5,1,0,
2
+
4)
1
5,1,1,
2
+
Key: 2
Sol:
1
5s
72. Consider separate solutions of 0.500 M ( )
2 5
, C H OH aq ( ) ( )
3 4
2
0.100 , M Mg PO aq
( ) 0.250M KBr aq and ( )
3 4
0.125M Na PO aq at
0
25 C . Which statement is true about these
solutions, assuming all salts to be strong electrolytes?
1) ( )
2 5
0.500M C H OH aq has the highest osmotic pressure
2) They all have the same osmotic pressure
3) ( ) ( )
3 4
2
0.100M Mg PO aq has the highest osmotic pressure
4) ( )
3 4
0.125M Na PO aq has the highest osmotic pressure
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Key: 2
Sol: iCST t =
73. The most suitable reagent for the conversion of
2
R CH OH R CHO is:
1) PCC (Pyridinium Chlorochromate)
2)
4
KMnO
3)
2 2 7
K Cr O
4)
3
CrO
Key: 1
Sol: Most suitable reagent for the conversion of
0
1 alcohol to aldehyde is PCC
74. CsCl crystallises in body centred cubic lattice. If a is its edge length then which
of the following expressions is correct?
1) 3
Cs Cl
r r a
+
+ =
2) 3
Cs Cl
r r a
+
+ =
3)
3
2
Cs Cl
a
r r
+
+ =
4)
3
2
Cs Cl
r r a
+
+ =
Key: 4
Sol:
c a
3a 2(r r ) = +
c a
3a
r r
2
+ =
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
48
75. In which of the following reactions
2 2
H O acts as reducing agent?
(a)
2 2 2
2 2 2 H O H e H O
+
+ +
(b)
2 2 2
2 2 H O e O H
+
+
(c)
2 2
2 2 H O e OH
+
(d)
2 2 2 2
2 2 2 H O OH e O H O
+ +
1) (b), (d)
2) (a), (b)
3) (c), (d)
4) (a), (c)
Key: 1
Sol: While acting as reducing agent it gives up electrons and release oxygen gas.
76. For which of the following molecule significant 0 = ?
a)
Cl
Cl
b)
CN
CN
c)
OH
OH
d)
SH
SH
1) (c) and (d)
2) Only (a)
3) (a) and (b)
4) Only (c)
Key: 1
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
49
Sol:
Cl
Cl
0 =
CN
CN
0 =
;
0 =
0 =
;
O
H
O
H
S H
S
H
But dipole moment of
"SH"
SH
is less than dipolemoment of
OH
OH
, but is significant
77. On heating an aliphatic primary amine with chloroform and ethanolic potassium
hydroxide, the organic compound formed is:
1) an alkyl isocyanide
2) an alkanol
3) an alkanediol
4) an alkyl cyanide
Key: 1
Sol:
2 3
R NH CHCl KOH R NC + + alkylisocyanide
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
50
78. In 2
N
S reactions, the correct order of reactivity for the following compounds:
( )
3 3 2 3
2
, , CH Cl CH CH Cl CH CHCl and ( )
3
3
CH CCl is
1) ( ) ( )
3 3 2 3 3
2 3
CH CHCl CH CH Cl CH Cl CH CCl > > >
2) ( ) ( )
3 3 3 2 3
2 3
CH Cl CH CHCl CH CH Cl CH CCl > > >
3) ( ) ( )
3 3 2 3 3
2 3
CH Cl CH CH Cl CH CHCl CH CCl > > >
4) ( ) ( )
3 2 3 3 3
2 3
CH CH Cl CH Cl CH CHCl CH CCl > > >
Key: 3
Sol: ( ) ( )
3 3 2 3 3
2 3
CH Cl CH CH Cl CH CHCl CH CCl > > >
79. The octahedral complex of a metal ion
3
M
+
with four monodentate ligands
1 2 3
, , L L L and
4
L absorb wavelengths in the region of red, green, yellow and blue,
respectively. The increasing order of ligand strength of the four ligands is:
1)
1 2 4 3
L L L L < < <
2)
4 3 2 1
L L L L < < <
3)
1 3 2 4
L L L L < < <
4)
3 2 4 1
L L L L < < <
Key: 3
Sol: Order of wavelength of colours
Red >Yellow > Green > Blue
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
51
80. The equation which is balanced and represents the correct product(s) is:
1) ( )
4 2 2 4
4
4 CuSO KCN K Cu CN K SO ( + +
2)
2 2
2 2 Li O KCl LiCl K O + +
3) ( )
2
3 4
5
5 5 CoCl NH H Co NH Cl
+
+ + +
( + + +
4) ( ) ( ) ( )
2 2
4
2 2
6
6
excess NaOH
Mg H O EDTA Mg EDTA H O
+ +
( + ( +
Key: 3
Sol: ( )
2
3 4
5
CoCl NH 5H Co 5NH Cl
+
+ + +
( + + +
81. In the reaction,
5 4
.
3
,
PCl LiAlH Alc KOH
CH COOH A B C the product C is:
1) Acetyl chloride
2) Acetaldehyde
3) Acetylene
4) Ethylene
Key: 4
Sol:
5 4
3 3 2 3 2 2 2
PCl LiAlH Alc.KOH
CH C OH CH CH OH CH CH Cl CH CH =
O
82. The correct statement for the molecule,
3
CsI , is:
1) it contains , Cs I
+
and lattice
2
I molecule
2) it is a covalent molecule
3) it contains Cs
+
and
3
I
ions
4) it contains
3
Cs
+
and I
ions
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
52
Key: 3
Sol:
3
CsI contains Cs
+
and
3
I
ions
83. For the reaction
( ) ( ) ( )
2 2 3
1
2
g g g
SO O SO +
, if ( )
x
p c
K K RT = where the symbols have
usual meaning then the value of x is: (assuming ideality)
1) 1
2) 1
3)
1
2
4)
1
2
Key: 3
Sol:
n
P C
K K (RT)
A
=
3 1
n 1
2 2
= =
84. For the nonstoichiometre reaction 2 , A B C D + + the following kinetic data
were obtained in three separate experiments, all at 298 K.
Initial
Concentration
(A)
Initial Concentration
(B)
Initial rate of formation
of C
( )
mol L S
0.1M
0.1 M
0.2 M
0.1 M
0.2 M
0.1 M
3
1.2 10
3
1.2 10
3
2.4 10
The rate law for the formation of C is?
1)
 
dc
k A
dt
=
2)
  
dc
k A B
dt
=
3)
   
2 dc
k A B
dt
=
4)
   
2 dc
k A B
dt
=
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
53
Key: 1
Sol:
m m
r K(A) (B) =
85. Resistance of 0.2 M solution of an electrolyte is 50O. The specific conductance of
the solution is
1
1.4S m
is:
1)
2
5 10
2)
4
5 10
3)
3
5 10
4)
3
5 10
Key: 2
Sol:
l
R
a
=
1 l
50
1.4a
= 70
a
l
=
280 (70) = 4 =
K = 0.25
3
4
10 0.25
5 10
0.5
= =
86. Among the following oxoacids, the correct decreasing order of acid strength is:
1)
2 4 3
HClO HClO HClO HOCl > > >
2)
2 3 4
HOCl HClO HClO HClO > > >
3)
4 2 3
HClO HOCl HClO HClO > > >
4)
4 3 2
HClO HClO HClO HOCl > > >
Key: 4
Sol: With increase in unprotonated oxygen atoms acidic strength increases
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
54
87. Which one of the following bases is not present in DNA?
1) Thymine
2) Quinoline
3) Adenine
4) Cytosine
Key: 2
Sol: Qunoline is the base which is not present in DNA
88. Considering the basic strength of amines in aqueous solution, which one has the
smallest
b
pK value?
1)
6 5 2
C H NH
2) ( )
3
2
CH NH
3)
3 2
CH NH
4) ( )
3
3
CH N
Key: 2
Sol: ( )
3
2
CH NHStronger base in aqueous medium than
3
MeN. So its pKb value is
smallest
89. If Z is a compressibility factor, vander Waals equation at low pressure can be
written as:
1) 1
Pb
Z
RT
= +
2) 1
RT
Z
Pb
= +
3) 1
a
Z
VRT
=
4) 1
Pb
Z
RT
=
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2014 JEEMAIN Q. PAPER WITH SOLUTIONS
#CORPORATE OFFI CE: PLOT NO: 304,KASETTY HEIGHTS, AYYAPPA SOCIETY, MADHAPUR HYD
EMAIL: ICONCOHYD@SRICHAITANYACOLLEGE.NET, WEB: WWW.SRICHAITANYA.NET
55
Key: 3
Sol:
2
a
P V RT
V
 
+ =

\ .
a
PV RT
V
=
a
Z 1
RTV
=
90. Which series of reactions correctly represents chemical relations related to iron
and its compound?
1)
0 0
2
, ,600 ,700
3 4
O heat CO C CO C
Fe Fe O FeO Fe
2) ( )
2 4 2 4 2
dil ,
4 2 4
3
H SO H SO O heat
Fe FeSO Fe SO Fe
3)
2 2 4
, dil
4
O heat H SO heat
Fe FeO FeSO Fe
4)
2
, ,
3 2
Cl heat heat air Zn
Fe FeCl FeCl Fe
Key: 1
Sol:
O heat CO CO
2
600 700 3 4
Fe FeO FeO Fe
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