# MCAT Full-Length Tests

Albert Chen Executive Director, Pre-Health Research and Development Kaplan Test Prep

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1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. B A C C B C D C B B A D B D B A B D A D 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. B D C B B B C A C A D C D B C D A A C B 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. B C D A B C C A B C B D D C A C B B A D 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. A D C B D D A C C B C C B D A D D

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Passage I (Questions 1–6)
1. B

Since the two component forces are in serial in the Maxwell model, the elastic force is no longer applicable after time zero; and according to the equation for the viscous component, a given amount of force will continue to stretch the material as time progress. The Voight model, on the other hand, has a given length shared by both elasticity and viscosity, such that as the viscous component is stretched over time, it is also limited by the resistant elastic force that increases as the material is elongated. The correct answer is therefore choice (B).
2. A

This requires you to know the definition of Young’s modulus, which represents the stiffness of a material. It is a property of solids and therefore, does not involve viscosity. Eliminate choices (B) and (D). In order to increase stiffness, you need to increase the value of k. Based on the equation F = kx, a stiff material will require a large force to produce a small amount of deformation. Given a large F and a small x, k must be increased to increase Young’s modulus; choice (A) is correct.
3. C

According to the passage, the viscosity of the material can be attained from the equation F=␮v, where ␮ is the viscosity. Since the force F is given and is constant, the remaining information required is v, which is the speed of deformation—choice (C) is correct. Both choices (B) and (D) combined can allow one to evaluate the speed of elongation, but neither by itself is a sufficient.
4. C

First, work W = Fd. Given the constant force of 25 N, you need to calculate the total distance d that is stretched over the 1 second time period. First, calculate the instantaneous stretch of the elastic component, which is x = F/k after a little rearrangement of the equation provided in the passage. We then add the stretch of the viscous component in one second, which would be x=Ft/␩, if we substitute x/t for v (the definition for velocity). The total calculated elongation should equal 5 m for the elastic stretch plus 5 m for the viscous stretch; a total of 10 m. Substituting back to our equation for work, we get W=(25N)(10m) = 250 J. Choice (C) is correct.
5. B

At time t = 0, the viscous component has yet to come into play, since it is time-dependent. Hence, the initial elongation would simply be the elongation of the spring component, which is determined by the equation F = kx. To determine the elongation x, shuffle the equation, using F=F0 to get x=F0/k .
6. C

This model is a combination of both the Maxwell and Voight model. Though it may seem rather complex, it can be analyzed by its parts. First, it has an elastic spring in series with a Voight material. Since from the Maxwell model, you know that an elastic spring will deform instantaneously, you can narrow the answer choices to (A) and (C), where there is a short vertical component of the graph showing an instant displacement. After t = 0, the Voight material should take over with the asymptotic curve as shown in choice (C). Choice (A) is a simple spring, while choice (B) is a simple damper. Choice (D) is incorrect since it does not display an asymptotic limit , which we expect when no damper is present in series. Choice (D) represents a damper in series with a Voight material.
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Passage II (Questions 7–12)
7. D

In the passage, you learned that the color of a coordination complex is the result of a promotion of an electron from a low-energy d orbital to a higher energy orbital. Therefore, any transition metal complex that is colorless must not be able to effect this transition. This leaves you with two possibilities: either the complex has no electrons in d orbitals or all the d orbitals are filled so no electrons can be promoted. The first possibility makes no sense–the definition of a transition metal is that it has electrons in d orbitals. Therefore, the second option is your best bet. This matches what you already know about zinc ions; they are d10, meaning that there are 10 electrons in the d orbitals—all full. Now take a look at the answer choices. (D) matches this prediction; the eg orbitals are the higher-energy orbitals in a crystal field, so if they are full, all the d orbitals are filled. This will make a promotion impossible. The complex will be colorless. Choice (A) makes no sense—when a metal loses electrons, its properties change, so even a colorless metal could still have colored complexes once it lost electrons to become an ion. Choices (B) and (C) might seem tempting, but there is no evidence in the passage or the question stem that the crystal field splitting energy is either small or large, so there is no way to say what the frequency of light would be if an electron could be promoted. In any case, all orbitals are filled for this complex.
8. C

This question might seem daunting when you first read the stem—there are so many possibilities! Don’t panic; just keep the passage information in mind as you read the answer choices. The answer choices are limited to information about color, so you know that the question is asking you to say something about the color of two solutions: a solution of K3[CrBr6] and a solution of K3[Cr(CN)6]. Now things are a lot simpler. What is the difference between these two solutions? This, too, might seem complicated, but as is often the case on the MCAT, you really only need one piece of information to answer this question correctly. That piece of information is going to come from the spectrochemical series given at the end of the passage. Take a look, and you will see that bromide and cyanide ions lie at opposite ends of that spectrum. Whatever difference there is between these two solutions, it will be related to high and low spins. As cyanide ions replace bromide ions, the solution will be changing from high spin to low spin. According to the passage, this is going to mean a larger crystal field splitting energy—a larger transition for an electron to make. In addition to the enlargement of the splitting, you also need to consider the fact that as the complex changes from high spin to low spin, there will be more opportunities for promotion. This is because there will be more electrons in the lower energy levels and more available orbitals into which these electrons can be promoted. There will be more promotions, so the intensity of the color will increase. Therefore, the answer is (C). (A) makes a false comparison between bromide and cyanide—in CFT, most of the ligands will be negatively charged, so a negative charge will not be enough to draw parallels between pairs of ligands. (B) assumes that the ions are all in solution together—you know this isn’t true because a complex is one unit. (D) tells you that the ⌬0 decreases, but you know that it increases, so (D) is incorrect.

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9. B

10. B

The first thing to do here is to take a look at the electron configuration of the Fe2+ ion. Iron(II) has six electrons. This means that when it is high spin, it will have four unpaired electrons. When it is low spin, it will have no unpaired electrons, because all the electrons will be in the three t2g orbitals. Once all the electrons are paired, the complex will be diamagnetic; it will have lost its paramagnetic properties, so (B) is correct.
11. A

Beware of extraneous information in question stems when you’re taking the MCAT! It doesn’t matter whether a complex is low spin or high spin when it comes to the total number of electrons that can fill all the d orbitals. Every transition metal has five d orbitals, each of which can hold two electrons, so ten electrons would fill the d orbitals of a coordination complex. Therefore, (A) is correct.
12. D

At first, it might seem that this question makes no sense because the first compound, Mn(NO3)2, isn’t a coordination complex. Don’t be fooled, though; the question stem tells you that you’re dealing with an aqueous solution. Therefore, it is a coordination complex with Mn(NO3)2 as the central “ion” and water molecules as ligands. Now your job is to compare H2O and CN– with Cl–. Don’t fall into the next trap, either—just because cyanide and chloride are both negatively charged doesn’t mean they’re the most similar. What you need to do is consult the spectrochemical series. Water is high spin, while cyanide is low spin. Where does chloride fall on the spectrum? It is even more high spin than water, so the complex will be high spin. Therefore, choice (D) is correct.
Passage III (Questions 13–18)
13. B

The question gives a speed, a distance, and wants you to find time. Here the rate is Mach 3, which equals the ratio of the speed of the jet to the speed of sound. Since the jet is going 3 times as fast as the speed of sound, the speed of the jet is 900 m/s. The question asks the time required to fly around the circumference of the Earth.

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If speed decreases. Therefore. B The figure indicates that the waves are building up in front of the jet. Mach number is the speed of the jet over the speed of sound. then the sound waves have to travel through air and then through water to reach them. wavelength must also change: choice (D) is incorrect. it travels faster in water than in air. As one jet speeds up.0 × 102 m/s ϭ 0. choice (B). we do not know how deep the people are underwater. choice (C) is never implied. A Remember that beat frequency is the difference between frequencies of a combined sound wave. Initially. B If the two people are underwater. 17. and the speed of the jet is constant. the frequencies of sound emitted by the two jets are now different. and a beat will be detected. Finally. the beat frequency increases from zero to some larger frequency. if frequency is constant. without increasing its velocity. Finally. density must have decreased: choice (D) is correct. the swimmers could be so deep underwater that the wave has so much longer to travel before it can reach them. the waves would be ahead of the jet. However.28 ϫ 107 m) Ϸ 4 ϫ 107 m (4 × 107 m) ᎏᎏ → t = 9. Therefore. = ␲d Ϸ (3)(1.5 ϫ 105 s Ϸ 13 hours. since the speed of sound in air does change as you change altitude. 14. In other words. The passage states this is exactly what happens when the jet flies at the speed of sound. Remember that the speed of sound is inversely proportional to the density of the medium through which it is propagated. the larger Mach number must mean a smaller speed of sound. 5 . you would expect the two people swimming to hear it first. 15. If choice (A) were true. Choice (A) is wrong. so there are no beats. The speed of sound is decreasing as the altitude increases. The only thing we can be sure of is that the frequency of sound is constant as it passes from one medium to another: choice (B). D The passage mentions that the Mach number of a jet can increase as it ascends.Circum. but speed changes between two media. 16. since the intensity of the sound wave may be different depending on whether the nose or the back is emitting the wave. Choice (B) is incorrect since the frequency of a wave passing from one medium to another is constant. thus even though it travels faster it may take more time to reach them then their friend. Choice (C) is illustrated in the passage and choice (D) would involve a change in the jet’s speed that is not illustrated by the figure. So. the Doppler effect indicates that the detector will record a smaller frequency for the sound emitted by that jet. Since. the jets start at the same place and emit identical sound waves. Since sound travels faster in denser substances.

D Carbonate. you know that the three oxygen atoms will repel each other as much as possible. Therefore. Once this transfer has occurred. the final velocity is zero. you can eliminate choices (C) and (D). so one can say that the force on the spring is proportional to the change in speed of the chair: since. this will result in atoms that are in a plane with 120º separations. These forces are equal. 21. Passage IV (Questions 19–24) 19. Choice (C) is incorrect because the molecular geometry of bicarbonate ion is not changed by losing a hydrogen ion. it will combine with water to form carbonic acid. so the solution starts out with a blue color. B In the section on Experiment 2.18. D The key to answering this question correctly is to write equilibrium expressions for Reactions 1 and 2. the concentration of bicarbonate ion increases. 20. a proton is transferred from a carbonic acid molecule to a water molecule. The answer is (B). A In Reaction 1. Choice (D) is incorrect because. Since bromothymol blue is colorless in acidic solution. while hydrogen bonds form. any positively charged species will be difficult to remove. CO32–. the solution will lose its blue color to become clear. This will neutralize the hydroxide ions and cause the solution to become acidic. Choice (B) is incorrect because as protons are lost from carbonic acid. 6 from each of the three oxygen atoms (18) and 2 from the negative charge on the whole ion. So. has 24 valence electrons: 4 from carbon. the bicarbonate ion has a charge of –1. the chair experiences a force equal to its mass times acceleration. Start out by writing: -] [H3O+][HCO3 [H3O+][CO23] ᎏᎏ Ka ϭ and Ka ϭ ᎏᎏ -] [H2CO3] 1 2 [HCO3 6 . These will be arranged according to the following Lewis structure: O C 2- O O Using VSEPR Theory. choice (D). Then. D As the jet decelerates. the spring will elongate under that force according to Hooke’s law: F = kx. the passage states that a dilute solution of potassium hydroxide is used. recognize that as solid carbon dioxide dissolves in the aqueous solution. From this. This is a trigonal planar geometry. 22. This will be basic. the force is proportional to the original velocity of the jet. charge separation is not favored by Coulomb’s Law. they do not have a significant effect on the Ka values.

2ϫ10–4 M. set up a table of values: H2CO3(aq) Initial concentration (M) Change in concentration (M) Equilibrium concentration (M) 0. Each oxygen atom should be identical. this gives x = 1.3ϫ10–7 All the other answer choices are traps: (A) is simply the Ka2 value. B Take a look at the Lewis structure you drew for question 2.034 –x 0.034 – x The next step is to solve for x.034 – x +H2O(l) H3O+(aq) Ϸ0 +x +x + HCO3–(aq) 0 +x +x Now set up the following equation: Ka -] [H3O+][HCO3 ϭ ᎏᎏ [H2CO3] 1 x2 ϭᎏ 0. while one of them is double-bonded. 23. (B) is the Ka1 value and (D) is the initial concentration of carbonic acid. The following three resonance structures are relevant: O C C O 2- O C O 2- O C O O 2- O 7 . two of the oxygen atoms have single bonds to carbon.Then. C To calculate the equilibrium concentration of the bicarbonate ion. 4. Any of these could have been eliminated with a little thinking! 24. so there must be enough resonance structures to account for that. solve for hydronium ion concentration in each equation to get: -] Ka2[HCO3 Ka1[H2CO3] [H3O+] ϭ ᎏᎏ and [H3O+] ϭ ᎏᎏ -] [CO2[HCO3 3] Now it is clear that only choice (D) makes sense. Each of the oxygen atoms is equivalent. but in the one shown.

25ϫ108 m/s. Since they operate spontaneously. C When a substance sublimes. 26. The change in internal energy is therefore 900 – 600 = 300 J. 27. The question is asking about which forces do work. its speed is reduced to: 3ϫ108 m/s c v ϭ ᎏᎏ ϭ ᎏᎏ ϭ 2. Since the CO2 molecules are absorbing heat. We should test the most popular statement first. Carbon dioxide sublimes at room temperature because the energy of the air surrounding it is sufficient to effect a phase transformation. entropy increases. C The first things we should take notice of upon reading the question are: This is a Roman numeral question. Whenever an ideal gas undergoes a change in internal energy. the oxidation and reduction reactions are carried out in separate compartments. B In a galvanic or voltaic cell. its temperature changes as well: 2⌬U 2(300) 3 ⌬U ϭ ᎏᎏnR⌬T→⌬T ϭ ᎏ ϭ ᎏ ϭ 100/R K. The answer is (C). ⌬G must be negative. eliminating answer choices as we go along. so the entropy change for sublimation must be positive. it is converted from solid to gas using the heat of its surroundings. Gases have greater entropy than solids. Passage V (Questions 29–33) 29. which means we need to understand what it means for forces to do work. 8 . 3nR 3(2)R 2 answer choice (A). so the answer is (B). B When light enters a medium with an index of refraction n. 4/3 n answer choice (B). So the gas in this case absorbs 900 J of heat energy. Notice that answer choice (D) is impossible. as nothing can travel faster than the speed of light in a vacuum. so their reactions must be spontaneous. 28.Discrete Questions 25. These cells are used to do work. A A gas absorbs heat and does work—this should remind you of the First Law of Thermodynamics: ⌬U ϭ Q –W. and does 600 J of work.

As the contact force is now smaller. the force F is applied only to the box with mass m1. The acceleration of the upper box decreases. which is 4/3 times the old acceleration. The top box begins to slide when the contact force between the boxes switches over from static friction to kinetic friction. so you can trust your gut. This problem can be analyzed in great detail. but that is not necessary to answer this question correctly. 10 . while simultaneously. answer choice (C). it should fall off the back.32. C Now that the top box is sliding. Choice (D) is correct. a’. is F/m1. Since the coefficient of kinetic friction is generally less than the coefficient of static friction. Note that you could have eliminated answer choices (A) and (B) right away by realizing that removing mass from the system while keeping the force constant was going to increase the acceleration by some amount. After the top box is removed. Let’s start with the motion of the system of boxes. and then asked to compare the current acceleration of the system to the acceleration of the lower box if the top box were removed. so the top box must be slowing down.” Go with that instinct—the physical scenario in this passage is in line with everday experiences. and the acceleration of the lower box increases. 33. Thinking physically about the scenario in this problem will back up our gut reaction. the force of kinetic friction is less than the maximum force due to static friction. The structure of the answer choices indicates to us that we need to figure out two things: Does the acceleration of the bottom box increase or decrease? Does the acceleration of the top box increase of decrease? Your gut instinct may be to think “well. D We are told in the problem that the mass of the lower box is three times the mass of the upper box. The new acceleration of the system. the force that pushes the upper box forward with respect to the ground is lessened as well. the impediment to the forward motion of the lower box is lessened. 3 F a = ᎏᎏ ᎏ 4 m1 . so the acceleration a must satisfy F = (m1+m2)a. once the top box starts sliding. Since m1 = 3m2. The only external force on the system of boxes is F. the motion of both boxes is no longer identical.

Will performing the reaction in the presence of hydrogen gas affect the production of titanium dioxide? A side reaction similar to Reaction 2 is very likely to occur here: TiCl4(g) ϩ 2H2(g)→Ti(s) ϩ 4HCl(g) 11 . it will not inhibit the reaction. but (D) is a better choice. as shown in the Lewis dot structure above. however. substituting bromine for chlorine. Therefore. Choices (A) and (B) both involve redox chemistry. consider statement (III). it is a hydrolysis reaction. This leaves you with (C) and (D). so it is not unlikely. Any choice that contains statement (I) should be eliminated. D You are asked to characterize the type of reaction you are given. Whenever a substance reacts with water. Will performing the reaction in the presence of a base affect the reaction? Since acid is produced. the presence of a base will drive the equilibrium to the right. it will not inhibit production of titanium dioxide. A Once titanium has lost all four of its valence electrons.) Now examine statement (II). The reaction in (D) is very similar to Reaction 1. which will drive the reaction because of the stability of titanium. Each oxygen has a charge of –2. (Notice that just by doing this. C O Ti O Titanium is bonded to two oxygen atoms in TiO2. A Titanium dioxide forms spontaneously according to Reaction 1. you should immediately think of the Gibbs free energy. you are already done because only choice (C) does not contain statement (I). Finally. just substitute chlorine for bromine. [Ar]. You know these can’t be correct because the oxidation state of Ti does not change from reactants to products. The reaction in (C) forms solid titanium. You know that a reaction with a negative Gibbs free energy is spontaneous. 38. so titanium must have a charge of +4. The fundamental aspect of this process is the reaction between liquid water and titanium tetrachloride.Passage VI (Questions 34–39) 34. (C) or (D) would apply if titanium had not yet lost its electrons by ionization. 39. Is humidity going to affect Reaction 1? Most certainly—the reaction is between titanium tetrachloride and water. 36. The transfer of chloride ions from titanium ion to the aqueous acid form might lead you to label this an exchange reaction. so humid conditions will make this reaction more favorable. 35. DG. Therefore. This eliminates choices (A) and (D). all involve the formation of one of two stable substances: solid titanium or titanium dioxide. 37. The reaction in choice (B) is extremely similar to Reaction 2 as shown in the passage. The other three reactions. B When you’re asked about the spontaneity of a reaction. it is +4 in both cases. so the answer is (B). It is very unlikely that this stable compound would undergo a corrosion reaction to form a gaseous “tetraoxide”. it has the electronic configuration of argon. C Consider statement (I) first since it appears most often in the answer choices.

n1 sin␪1 ϭ n2 sin␪2. because the phaseshift that wave undergo on reaching a boundary with a higher index of refraction doesn’t depend on the angle of incidence. Passage VII (Questions 40–44) 40. we’ve already stated the correct answer: choice (C). which integer pair m1. 12 . m␭ d ϭ ᎏᎏ → 2 d ϭ m1ϭ (400)/2 ϭ 200m1. 800/3 d ϭ m2ϭ ( ᎏ 2 ) ϭ 400/3 m2 The question is. Are all the conditions for the soap bubble the same as those for the thin film? No. the path length through the film would no longer be 2d. 42. and so the equation no longer applies to constructive interference. D C 43. In fact. What determines the degree to which light is refracted? Snell’s Law. as nothing prevents light from entering a medium with a higher index of refraction at any angle. 1. Choice (B) is correct. If they were coming in shallow. The thin film is layered between a medium of lower index of refraction. we need to know what the wavelengths of those two sources are inside the film: 400 nm 600 nm ␭ ϭ ᎏ ϭ 233 nm. you can see that m1 = 2 and m2 = 3 yields a depth of 400 nm. so statement (III) is the only one that applies.5 1. 41. Answer choice (D) is correct—it’s ray 2 that meets the second soap-air boundary. The formula assumes that the rays are coming in close to the vertical. so choices (A) and (B) are incorrect. To employ the formula given in the passage. inside the film. ␭ ϭ ᎏ ϭ 400 nm.5 So. at 400 nm and 600 nm. A soap bubble is surrounded on air on both sides. choice (B). The angle of refraction has no dependence at all upon the wavelength of the light. choice (C) is wrong.This will reduce the amount of titanium dioxide produced. m2 yield the same d? By trial and error. One of the rays isn’t going to undergo a phase shift. but something much longer. B Answer choice (D) is certainly wrong. Choice (D) is incorrect: it’s because the indices of refraction are different that refraction occurs at all. B There are two bright maxima. and a layer with a higher index of refraction. Similarly.

A There are two fringes between 400 nm and 700 nm—the visible spectrum. Consequently. The electrons are excited from the s to the d orbital (level 5 in strontium. sodium perchlorate would not be a good oxidizer. and m=4. Passage VIII (Questions 45–50) 45. indigo. indicating that at least two atoms are going to change oxidation states. B Red is a longer wavelength (ROYGBIV) and therefore less energetic form of light than green light. 48. orange. C The passage states that the yellow produced by sodium generally washes out all other colors in the firework. not keep them in separate compartments. m m Only two values of m yield wavelengths in the visible spectrum: m=3. when white light is shone upon a film with d = 900 nm. not from s to s. which emits violet light. shorter wavelength of light than does sodium (yellow light). blue. Using the equation from the passage. Choice (A) is true—solid reactants do not mix and therefore cannot react. leaving only (C). ␭ ϭ 600 nm and 400 nm can be seen. 2d 1800 nm ␭ ϭ ᎏᎏ = ᎏᎏ.44. Red is the lowest energy and violet is the highest energy. the wavelength gets shorter. Consequently. indicating that either (A) or (C) is correct (oxygen is a 2– ion). So the act of melting from a solid to a liquid allows the reaction to begin. When the reactants are melted. the reaction is between the perchlorate and the fuel. dextrin is not used as an inhibitor. which allows them to react. So potassium. B Remember ROYGBIV (red. So the presence of sodium (in the form of sodium perchlorate) will eliminate the desired red color. (D) is the exact opposite of what is stated in the passage. So the difference between energy levels in the strontium atom is less than in the barium atom. As energy increases. 49. We also know from common sense that (B) is false—you can go to the store and buy fireworks. (A) and (B) are wrong because the reactivity of sodium and potassium are not at issue. 47. emits a higher energy. (D) is completely false. (B) and (D) have Al with a +4 charge and can therefore be eliminated. they mix and begin to react. Al produces a 3+ ion (see periodic table). right? (C) is tempting. green. C The reaction is a redox reaction. 46. but we are told that dextrin is used to bind the reactants together. not the cation and the fuel. So the correct answer is (B). level 6 in barium). A The passage states that the composition melts upon ignition. yellow. 13 . violet). The correct answer is choice (A). (A) is not balanced (too many Al atoms. not enough O atoms).

C The passage states that ignition melts the reactants. choice (C). Each has a charge of +6. Discrete Questions 51. leaving +12 for the two chromium atoms. 53. Now you can use the right-hand rule to determine the direction of the force: your fingers point with the moving charges. or once every one-third of a second: 0. A 14 . 55. So the beats occur three times per second. The number of valence electrons about a nucleus and the number of protons in the nucleus are determined by the location of the element on the periodic table. The radial size of an electron cloud is determined by the principal quantum number (A). up the page. that is the beat frequency (fb ϭf1 – f2).5 T)ϭ1. We can eliminate choices (C) and (D). As the two sounds are 3 Hz apart. Choice (B) is correct. This should immediately point you to (D). The correct answer is choice (A). out of the page. The shape of the electron cloud is determined by the magnetic quantum number. The difference between +6 and +3 is 3. then: mg (2 kg)(10 m/s2) ᎏ ᎏᎏ kx ϭ mg → k ϭ ᎏ ϭ ϭ 333 N/m. (D) is false because the redox reaction between the oxidizer and fuel causes the oxidizer to release its oxygen. There are seven oxygen atoms. not the heat from the fuse. Curl your fingers in the direction of the field. C The oxidation number of chromium in Cr2O72– is 3. This may be calculated as follows: the oxidation number of oxygen in Cr2O72– is –2. x 0. 52.06 m choice (D).5 N. (B) is false because we know that the reaction generates heat and is therefore exothermic.50. B The magnetic force on a current-carrying wire is: FϭILBϭ(1 A)(3 m)(0. (A) is false because the dextrin is not used to separate the oxidizer and fuel. D The magnetic quantum number indicates how an orbital behaves in an electric field. resulting in a charge of –14. The overall charge of the ion is –2.33 s. D When the weight of the mass is in balance with the restoring force from the spring. 54. So (C) makes sense: melting the oxidizer and fuel allows them to mix and begin reacting. Your thumb now points to the right—that is the direction of the force.

sodium is the limiting reagent.63 by 0. The molar mass of nitrogen is approximately 28 grams per mole. At a high altitude such as that of Mt. so choice (B) is correct.63 mol Na Now you’re ready to take a look at the iron oxide present in the reaction chamber: mol Fe2O3 35 g Fe2O3ϫᎏᎏ 159 g Fe2O3 ϭ 0. the meaning of root mean square speed is not important.4 This is greater than 6. If the quotient is greater than 6 (the molar ratio of sodium to iron oxide in Reaction 2) then iron oxide is the limiting reagent. 65. so you have to take that into account as well. and M is the molar mass of the gas in kilograms per mole. and the reaction will go to completion.2 molFe2O3 The next step is to compare the stoichiometry of Reaction 2 with the molar amounts you just calculated.63 mol Na ᎏᎏ 0. To calculate the root-mean-square speed. If the quotient is equal to 6. this is a pure calculation question. Do this by dividing 1.22. 64. you only need to determine the molar mass of nitrogen to answer this question correctly. T is the temperature of the system in Kelvins. designed to test your knowledge of the ideal gas law and its applications. However. Therefore.Now that you know the number of moles of sodium azide. 1. the pressure will be lower than it is at sea level. excess sodium is present.63 mol NaN3ϫᎏᎏ 2 mol NaN3 ϭ 1. B In this case. the temperature is slightly lower at high altitudes. urms ϭ ᎏ M where R is the ideal gas constant. If the quotient is less than 6. Since the answer choices are conveniently given in terms of RT. Take a look at the Ideal Gas Law to see how these two factors will affect the volume of the experimental balloon: PVϭnRT Manipulate the equation to examine the effects of pressure and temperature: nRT ᎏ Vϭᎏ P Notice that a decrease in pressure and a decrease in temperature will cause competing effects—lowering the pressure causes an increase in volume. then stoichiometric amounts of reactant are present. while lowering the temperature causes a decrease in volume. However. you should know that root-mean-square speed is a measure of the typical speed of molecules in a gas at thermal equilibrium. Shasta. you’ll want to calculate the resulting number of moles of elemental sodium: 2 mol Na 1. D Ί๶๶๶ This is a conceptual question. choice (C) is correct.22 mol Fe2O3 ϭ 7. Only (D) conveys this appropriately. use the following formula: 3RT ᎏ. 17 .

so products are lower in energy than reactants. the reaction is spontaneous. because the activation energy will be lower with a catalyst. How does a catalyst speed up a reaction? It does this by lowering the activation energy of the reaction. answer choice (C). Passage XI (Questions 68–72) 68. choice (D) is correct. the total work done by friction is choice (C). The amount of work done by friction is equal to the change in kinetic energy of the object: 1 ᎏ (0. you just need to determine the oxidation number of iron in iron oxide. In this case. D This question indirectly tests your knowledge of reaction mechanisms. Therefore. There are two iron atoms in iron oxide. A catalyst is a substance that takes part in a chemical reaction and speeds it up. you can apply the work-energy theorem to this problem. Choice (A) is wrong because the energy of the products will not be higher than that of the reactants. Therefore.2 seconds. not higher. 0– 4 vf –v0 2 ᎏ aϭᎏ ϭ t 1. 67. Therefore. 18 . however. according to the table in experiment 1.2 ϭ – 3. there are no forces or distances available. the iron atoms must balance the charge with +6. The key to answering it correctly is knowing how a catalyst works. 69. but undergoes no permanent change itself. C The amount of work done by a force over a distance is W = Fd. elemental iron (Fe) will have an oxidation number of zero. This allows you to eliminate choices (C) and (D). A The MCAT expects you to know that substances in their elemental states have oxidation numbers equal to zero. But since you have both the starting (10 m/s) and ending (0 m/s) speed. C The disk that started at 4 m/s decelerated to 0 m/s in 1.5)(10)2 ϭ 25 J KEi ϭ ᎏ 2 KEf ϭ 0 J. This will be manifest in the height of the peak between products and reactants in the energy profile. Choice (B) is also wrong. Choice (C) is wrong because the final potential energy of the products is not equal to the potential energy of the reactants.66. 25 J. Since oxygen has a charge of –2 and there are three of them. the product.3 m/s . so each must have a charge of +3. Using kinematics. Now.

Hence. If you used a different solvent with a lower polarity than water. eliminate (C). pressure. During the phase transition. more salt will dissolve. 76. adding more salt will not change its solubility. the solubility of the salt will change. Therefore. not all of the ice can melt. D Ice melts at 0ºC. the addition of other substances and in the gas phase. only choice (A) does not affect solubility. If you heat the water. including temperature. Therefore. If you add another solute. less salt would dissolve. and the final energy is all potential: KEi ϭ PEf 1 ᎏ ᎏ(100)(v)2 ϭ (100)(10)(20) 2 v2 ϭ 400 → v ϭ 20 m/s. Since the chemist only heats the ice for a moment. The correct answer is choice (D). so choice (D) must be incorrect. 20 . the solvent. so choice (B) must be incorrect. However. so choice (C) must be incorrect. so (A) is the correct answer. it undergoes a phase transition. Think of a glass of water as the solvent and table salt as the substance being dissolved.75. 77. A Solubility is affected by a number of factors. once the solution is saturated with salt. D It might be easiest to handle this question by using conservation of energy. the temperature of a substance does not change. This means that as it is heated. the answer is (D). The initial energy is all kinetic. you can eliminate choices (A) and (B).

D 136. A 100. 83. C 103. C 107. 97. C 118. 98. 93. 95. B 119. 81. B 134. B 120. 80. C 132. D 121. A 115. A 129. B 108. A 131. D 111. 96. B 123. B 124. A 122. C 130. 86. C 114. 87. A 106. B B D B D B B C A A C A C B B B 94. D 117. 89. C 133. A 104. 84. 82. C 102. 99. 90. 92. D 109. 91. C 105.VERBAL REASONING ANSWER KEY 78. D 126. C A D C A A 110. 88. A 21 . C 113. A 112. 79. C 127. B 116. B 137. A 101. D 125. A 135. 85. D 128.

That’s wrong and does not address the question. The atmosphere’s absorption of heat decreases the temperature of the water and does not relate to its salinity. Notice that the author uses a superlative to describe the Atlantic’s salinity. any water coming from the North would be coming from the North Pole and be cold. Water in the North Atlantic doesn’t receive warm water from the North. It touches on the passage’s purpose. B This is a detail question. 23 . increases density. misusing a detail found near line 21. The scope of this paragraph concerns the factors involved in creating the ocean’s dense. This sentence appears in paragraph 2. In any case. Paragraph 2 states that atmospheric absorption of heat. Choice (A) is too extreme. (D) is the correct answer. while the passage doesn’t provide how disruption of the thermohaline circulation would change climate. (B) is a Distortion of a detail in the passage. While the passage mentions wind patterns and evaporation. (B) contradicts the information contained in the passage. 82. B Study the context of the section mentioned in the question. the author makes it clear that it would alter world climate. paragraph 5 teacher salaries. Density is a function of salinity and temperature. (C) is opposite. and the passage describes how salinity and temperature cause water to sink. It’s the saltiest of all high-latitude waters. The only answer that is not mentioned is (B). 5 and 6 list the author’s recommendations: paragraph 4 teacher education. Prevailing wind patterns (A) increase evaporation rates which increase density. Passage II (Questions 84–90) Topic and Scope: The need to implement national standards in teaching and the means to do so. which is a Distortion of a detail mentioned in paragraph 3. Paragraphs 2 and 3 discuss why schools can’t currently implement standards. D This inference question hits you with a lot of details so remember not to be intimidated by the answer choices. Choice (B) is correct since the author’s use of a superlative reinforces the importance of salinity. choice (C). Identify and reread the section of the passage concerning the density of North Atlantic waters and remember that you want the answer that the passage contradicts or does not support. Continental runoff (D) affects water density by lowering salinity. The author stresses the importance of the thermohaline circulation but discusses both the North Atlantic and the Southern Ocean. Paragraph 1 discusses the need for guidelines and the difference between setting them and implementing them.81. (D) states that the author mentions salinity in order to discuss the factors involved in wind patterns and evaporation rates. and paragraph 6 continuing education. (C) is never mentioned in the passage. The last sentences of paragraph 2 discuss the thermocline and how tidal action cause the mixing of oceanic waters. (A) is FUD. deep water. 83. Paragraphs 4. and this question asks you to evaluate why the author mentions the Atlantic’s salinity. The author would not endorse research focused on only one part of the ocean. which is to discuss deep-water formation and how its interruption could alter climate.

87. maintains the author. There is no evidence for (D) in the passage. (C) would be correct only if those with science backgrounds are choosing to enter other fields despite the fact that they have been enrolled in teacher graduate schools. choice (C) is correct. Hence. There is no evidence in the passage to suggest that graduate schools can force higher payscales for teachers (B) or that they can improve equipment (D). The author would certainly not support the immediate implementation of national standards (D). C The author’s assertion throughout the passage—in fact. the main idea in this passage—is that national science standards are useful only when teachers have the strong content knowledge and necessary supplies to use them effectively. A It would be a stretch to assume that older. 88. 90. even if the author would probably agree that some sort of teacher assessment would be important. and it is possible that the testing will drive the classroom instruction. 89. Yet new tests cannot improve teaching unless teachers are in place who can live up to the new expectations—thus. nor allowing teachers to omit teaching what they did not understand (C). All of the other choices involve issues that are specifically mentioned as impediments to the success of national standards— teachers avoiding topics out of ignorance. lack of proper equipment. C According to the passage. the fact that students did better on their tests strengthens neither of these assertions. so choice (A) is correct here. The author does not address anywhere in the passage whether teachers should be accorded the same respect as doctors or lawyers (C) or whether they should all be on the same pay scale (A).84. national standards can do more harm than good if they require teachers to teach things that either the teachers don’t know or for which there are not adequate classroom resources. teachers need training. it is probably not a reasonable assumption that just because teachers should be retrained like doctors and lawyers. 85. they should get paid like doctors and lawyers as well (B). Choice (C) is the only answer here that works. and not holding teachers responsible for their continuing education. choice (C) is correct. the purpose of the comparison to doctors and lawyers is not to show that it is important for teachers to remain current. it is in fact a Distortion of the recommendation made in the final paragraph. so choice (A) is correct. Nowhere in the passage is it suggested that teachers can determine their own curriculum regardless of national standards (D). B Although choice (D) may seem tempting. 24 . nor does the term “national standards” imply that the standards would not be implemented across the whole country (B). A In order for national standards to be implemented. A The author discusses how important continuing education is for teachers and how these teachers need to be held accountable for their knowledge base. While (A) and (B) are probably true. 86. Therefore. more experienced teachers would be an obstacle to instituting national standards. In addition. C The author would agree that what is tested has a lot to do with what is taught in the classroom. It does not stand to reason that the teachers should take the same tests as the students (D). (B) is the correct answer.

affirms it gained perceived value sooner than naive art. (A) is a Distortion. Paragraph 5 introduces the notion that a characteristic normally identifying folk art can also be a characteristic of fine art—different styles exist. rather than as intrinsic to each of two essentially distinct forms of art. the passage indicates that cave paintings cannot be considered both primitive and naive. and indicates how that characteristic is treated differently by those who are oriented toward the fine arts than by those who are oriented toward folk arts. The passage does not provide a basis to infer that several works of folk art would be likely to be of less aesthetic value than several works of fine art. and choice (B). 92. at least at first. springing from their customary way of life. for its historical significance). to consider more traditional art as inferior to their own creations. I and II only.Passage III (Questions 91–98) Topic and Scope: Folk art and fine art. (D) is an incorrect inference. Paragraph 6 questions the importance of a distinction proposed by some: that folk art may be distinguished from fine art in that it has a practical purpose. specifically. Choice (B) is correct because it is a paraphrase of this definition. B The first cave paintings can be defined as primitive art (statement II) based on the definition in the first sentence of paragraph 3. Paragraph 2 asserts that fine artists had a tendency. in terms of their appeal to the viewer. Although the passage indicates that that folk art was disparaged by early fine artists. (C) is opposite to what would be correct. Paragraph 7 explains how fine art and folk art differ. Thus. This sentence also indicates that primitive art is a type of folk art (statement I) and that it contrasts with naive art. (A) is also inconsistent with the statement in the last paragraph that folk art tends to have direct appeal and simple charm.” and suggests that the distinction be recognized as a convention of language. B Paragraph 4 defines folk art as the art of a people. Paragraph 1 introduces the notions “fine art” and “folk art. and expresses the author’s hypothesis regarding why this was so (primitive art was more easily valued. 91. it does not indicate that folk art is likely to be misunderstood by viewers today. 25 . Paragraph 4 defines “folk art” and introduces the notion that one of the key principles for appreciation of folk art—that appropriate standards are not the same as those appropriate for evaluation of fine art—is also applied to the appreciation of modern art. is correct. Paragraph 3 defines primitive art. what is similar and what is different in practice and appreciation of these two types of art. and thus provides a basis to infer that works of folk art would be more likely than works of fine art to meet this criteria.

The intention of the artist (statement II) is not relevant to distinguishing folk art from fine art. the change in Twain’s assessment of his father was not actually due to what his father had learned in seven years. Thus. but due to Twain’s maturation. (B) is a Distortion of the passage. which is not supported by anything in the passage. for example. it also likens the early stages of fine art to adolescence.” and the Mark Twain quote is an ironic statement. Although the sentence in question refers to “folk painting. Thus. (C) is not supported by the passage. A By contrasting the close relationship of folk art with the traditional culture of an area to the close association of the fine arts with sophisticated urban centers. Choice (A) cannot be correct because naive art and modern art are defined in a mutually exclusive way in lines 32–35 of paragraph 4. it would be more likely that the exhibit would not have been shown at all. Choices (A) and (B) are possible reasons why those who attended the exhibit were not impressed. country of origin is not focused on as a way of distinguishing fine art from folk art. Clearly. While the country of origin of the masks that served as a model for Picasso’s Les Demoiselles d’Avignon is mentioned in the paragraph. 26 . the author can be inferred to agree that folk art and fine art share a common origin. This leaves (C). the reason can be inferred from the context of the statement. it is not inconsistent with the passage to conclude that the rules of modern art could evolve. Those who attended the exhibit are analogous to the young Mark Twain. the passage focuses on the social context (statement I) in which the artist’s skill was developed. D Since the author mentions that the a distinction between “fine art” and “folk art” postdated the first cave paintings and that primitive art is part of the history of art. 96. but provides no support for an overall judgment that they are more different than they are similar (A). (D) cannot be correct because of how folk art is defined in the first sentence of paragraph 4. The earlier part of the paragraph refers to “maturation. (C) is inconsistent with the passage’s focus on specific criteria which distinguish folk art and fine art. (B) cannot be correct because of how primitive art is defined in the first sentence of paragraph 3. on furniture. it is their assessment that the passage refers to. then it is necessary to infer that the public would have had the capacity to appreciate the artistic work of particularly valuable folk art (had it been displayed). The passage mentions both similarities and differences between folk art and fine art. and a piece of modern art that violates today’s rules could be accepted as fine art in fifty years.” it does not indicate that the paintings were on canvas rather than. (D) is a Distortion of the passage. While the second paragraph of the passage makes reference to the maturation of fine art. This implies that the rules of fine art are not static. the best inference is choice (B). C This question is best answered by an elimination strategy. If fine artists had exercised undue influence on the gallery. 95. the intention of the artist is related to distinguishing modern art from folk art and modern art from the rest of fine art.93. Rather. choice (D). However. B The passage does not explicitly state why the exhibition at the National Gallery was greeted with disapproval. and cynicism. 94. Which is more likely in this context? Is it the curators of the exhibit or the attendees who are most likely to have lacked a “mature” sense of the artistic value of folk art? If it was primarily the curators. questioning. The passage indicates that the fine arts have “conventions” and that modern artists choose to violate “contemporary rules” of the fine arts.

and that Taft voters would not have switched to Wilson and Roosevelt voters would not have switched to Wilson. Paragraph 5 expresses both the author’s hope that an alternative system might be adopted and also the author’s belief that this would be beneficial. 99. Absent evidence that actual Taft or Roosevelt voters would have voted (in a two candidate race) for the other of the two. choice (C) is correct. 98. particularly since the passage does not identify Roosevelt’s affiliation at the time of the 1912 election. if Taft and Roosevelt “split a majority of the popular vote. an alternative to the plurality system of voting. Passage IV (Questions 99–104) Topic and Scope: The passage proposes that there is a problem with the plurality system of voting in multi-candidate contests and describes two alternative systems.. “similarity” between candidates can be assessed on many different parameters.” the implication is that economic constraints are a consideration more external to the artist than his other artistic decisions. the passage does not state that both were Republicans at the time they ran for election in 1912. Why would this be so? Choice (A) is most directly related to this point. Paragraph 2 describes the plurality system of voting. (B) is inconsistent with the statement in the passage that folk art springs naturally from customary way of life and beliefs. While the tendency of younger artists to learn from skilled adults (A) is certainly characteristic of folk art. Paragraph 4 describes approval voting. Paragraph 3 describes the Borda count. However. It focuses directly on how economics may force the artist to choose objects that also have practical value. the passage indicates that styles of fine art are likely to diffuse to other areas. who must have received a minority of the popular vote. Furthermore. Statement I is not an assumption because it is not clear from the passage what role party affiliation played in the election. a sentence in which the fact that folk art is often executed as a decoration to objects of practical value is presumed to represent a fundamental distinguishing characteristic of folk art. A The argument assumes that voters considered Taft and Roosevelt (former and incumbent Republican presidents) similar. A The referenced statement follows. since “sophisticated techniques” are not associated with folk art. Statement II contradicts the author’s explicit statement. 27 . C Since the passage indicates that folk art “springs naturally from the customary way of life and beliefs of the people of a region. Paragraph 1 suggests that the type of system used for casting and tabulating votes can affect the outcome of an election and influence what candidates will run for office. another alternative to the plurality system.97.” artists living in the same area would be likely to be stylistically similar. rather than for Wilson (statement III). Since the referenced statement challenges this presumption on the basis of “economic constraints. The correct answer is choice (A).e. and questions. must be considered an assumption. The remaining choices relate in some way to the economics of artistic life. (D) is only partly true. i. but are not as directly related to the artist’s choice of working surface.” by definition they collectively received more votes than Wilson. the passage provides no basis for this being less true in the fine arts. In contrast. Thus.

110. The author never contrasts history and hard sciences such as physics directly. let alone the uniqueness of Dante. The New Historicists also try to study works in the context of other works from the era. a desert ant. these new scholars study the same marginalized groups. the point expanded in the rest of the paragraph. as in (A). But that’s not necessarily the same flaw. since the passage notes that. especially since the paragraph never urges any of these scholars to try a more straightforward. Paragraph 6 describes experiments being done to learn more about animal mapping. admiring a book from this backlash seems pretty inconsistent. only that their approach often clouded the uniqueness of canonical texts—not quite the same thing. objective approach. 108. since the passage never claims that the New Historicists unfairly concealed anything. Paragraph 5 gives other examples of animals that store food to relocate it later. however. Paragraph 1 discusses the basic dichotomy between moving and unmoving objects. we can infer that the new scholars are probably studying them too. So statement I is correct. the flaw of the backlash scholars is that they aren’t really studying anything new. The author never says. we don’t know whether or not the backlash provided any new historical insights. (C) wouldn’t necessarily be inconsistent with the author’s admiration. anthropologists and historians can even use the same methods used in the hard sciences.107. so (A) and (C). either. like the New Historicists. so (D) is clearly out. including pornographers. so we can’t infer that. and we can toss out choice (C). Since the New Historicists studied marginalized groups. but the scholars who followed them) study the same groups as their predecessors. Paragraph 3 gives an example. where two contemporary works are compared. The flaw for the New Historicists was that they assumed all cultures had some sort of cohesion. it lacks a single disciplinary approach. A The passage tells us that the new scholars (not the New Historicists. seems to be against the need for this historical backlash against the New Historicists. they’re probably not too likely to study the ruling group of any area. Paragraph 2 discusses why animals can’t use their own body movements to “map”. Statement II is definitely tricky. so choice (A) is out. As far as statement III goes. Paragraph 4 Explains why that any isn’t really “mapping”. Passage VI (Questions 111–116) Topic and Scope: How animals “map” their environments. is also out. D The answer can’t be choice (B). 109. that the backlash against the New Historicism lacks all claim to originality. The same thing goes for (C). The author also never suggests that economists. 30 . Since the author. so she can’t be criticizing scholars for not using these methods. D Because history isn’t an actual science. only that it’s flawed. But because the New Historicists focus on marginalized groups. B The author tells us that the New Historicists study marginalized and understudied groups.

this goes against choices (A) and (B).” Paragraph 3 continues this discussion and addresses parent’s concerns about children’s fears and emotions. (D) is contradicted by other information in the passage. C This question requires you to consider what events are more likely or easier than others. and presents the thesis that such polemical tales actually are more effective for helping children to deal with basic issues of life and death than are modern stories. lending no support to (A). A If in every instance animals operate similarly. perform any computations. themselves. There is no reason to think that the muscles. Paragraph 2 develops this thesis by discussing the polarization of the existential dilemma as it is present in fairy tales. This would eliminate choice (A). Also. (C) is the correct answer. 31 . we would assume that this animal will find food the way other animals do. 115. There is no evidence to support (B) or (C).111. claiming that fairy tales provide children with an outlet for dealing with their anxieties and even gives them solutions to such struggles in ways that children can understand. 116. by a configuration of landmarks. common sense suggests that one object could more easily be moved than several objects could. There is no evidence for (A) and (D). There is no evidence for (B) and (D). By presenting good and evil so clearly. Passage VII (Questions 117–124) Topic and Scope: The benefits of fairy tales in comparison to modern “safe” children’s stories Paragraph 1 introduces the underlying psychoanalytic aspects present in the simplistic plots of fairy tales. it is reasonable to assume that something about animals requires them to act that way. you must alter variables one at a time to see what each one’s individual contribution is. There is no reason to suspect that it is easier to remember many objects than one object. (D). B Choice (B) is the best answer because it takes into account the fact that animals need to use these cues from a distance. 114. A The passage clearly states that navigational errors would multiply rapidly in an kinesthetic system because small movements would throw the system off. C In an experiment. this supports choice (A). (C) is directly contradicted by information in the passage. 112. If you did them all at once. D If we find that every example of something operates similarly. (D) is contradicted by information in the passage. so (B) is out. that would actually be a new experiment. then it is reasonable to assume that a newly found example will operate in the same way. (A) is the best choice. and common sense suggests that the reverse is likely true. This would eliminate choice (C). contradicting (D). So. this is choice (C). 113. fairy tales allow children to better comprehend the differences than if the issues were more ambiguous or “true to life.

suggesting that children are able to discriminate between fiction and reality in the meaning of the fairy tale (B). C The final sentences in paragraph 3 attest to the fact that the fairy tale “addresses itself directly to anxieties and fears.” and is a Distortion of the first sentence of Paragraph 3. the author suggests that parents may not be able to provide this type of instruction to their own children. 118. B The author professes that children gain comfort from the typical fairy tale endings. (A) is the opposite of the third sentence in paragraph 2. (C) is outside the scope. (C) is a Distortion of the differences between modern stories and fairy tales. (B) is the opposite of the last few sentences of paragraph 1. B The central thesis of the passage is that traditional fairy tales are more beneficial to children’s growth and development than modern stories that attempt to provide “safe” plots and characters. 32 . which claim that “safe” stories do not discuss death.” just like choice (C). D Moral lessons and values are never mentioned directly by the author as a benefit of the polarities in fairy tale plots. and (C) are all discussed in paragraph 2 as support of the main idea expressed in the first sentence of the paragraph that fairy tales “state an existential dilemma briefly and pointedly. A By stating that children need the symbolic suggestions of fairy tales in order to understand life and death issues and mature properly. Choices (A). Choices (A) and (D) are outside the scope. 122. (D) is too extreme. Choice (B) does not give any indication as to whether or not the fictional representations lead to a deeper understanding of good and bad. (C) is a Distortion of the middle part of the final paragraph. are discussed. and (D) is a Distortion of part of paragraph 3 where parents’ fears. with the word “always. aging. since children’s own instinctive responses are never mentioned. since the passage never discusses the intentions of the authors of children’s stories. which discusses parents’ discomfort with their children’s fears or negative emotions. implying that such modernization is in fact detrimental to children’s maturation. (D) is opposite and would undermine the author’s assertion.117. Choice (A) is a Distortion of the final sentence of the passage. as described in paragraphs 1 and 2. B Paragraph 1 lays out the argument that fairy tales present children with conflicts between good and evil. since the validity of psychoanalytic examination of literature is not at issue. limits of existence. and a FUD. since it would in fact disprove the central thesis of the passage. (D) contradicts the first sentence of the paragraph. 120.” 121. misusing the statement made in lines 7–8 that “struggling against what seem like overwhelming odds” can give meaning to life. and their relation to different types of stories. but that they can also discern that “living happily ever after” should not be taken literally. or the wish for eternal life. Choice (A) is outside the scope. which clearly implies that the “dark side” of humanity does exist and should be acknowledged. 119. (C) is the opposite of the author’s belief that the inclusion of evil characters in fairy tales is a useful and necessary element of fairy tales. (B). nor the utopic lives presented in many fairy tales and the effects of such perfection on child readers. and that Freud’s recommendation to struggle against odds to find meaning in life is encapsulated by these types of stories.

and the Emergency Wetlands Resources Acts is mentioned as an example of a stop-gap acquisition measure that is constrained by the small amount of federal funds allocated for wetlands protection. Paragraph 1 relates the history of wetlands conversion in the mid-19th and mid-20th centuries. it’s simply a view that accords with the author’s. (D) is clear-cut. since the author’s contention is that federal funds are insufficient for wetlands preservation. and problems with their effectiveness. but Freud’s prescription is not an analogy. the author’s purpose is to counterpose Freud’s idea to the dominant cultural attitude. smacks the nail on the head. which contends that “…public health benefits have been lost to agricultural forestry and development enterprises 33 . 126. including both governmental and private efforts to prevent the continued erosion and loss of these environmentally important areas. (C) is outside the scope.” Paragraph 3 discusses the current obstacles to wetland protection laws and programs. and (B) is a FUD from the second sentence of paragraph 2. (B) is implied in the final sentence of paragraph 2. Paragraph 4 explains why the current approach. (D) describes a theme that. If you were hesitant about (C). is ineffective and offers an alternative strategy. current protection methods. By contrast. sounds murky—it just doesn’t fit. and choice (B). B “Safe” stories paint an overly rosy picture of life. D The third sentence of paragraph 2 declares that budget concerns cause limits on the acquisition of new wetlands for preservation. (A) is inconsistent with the passage. the author suggests. 124. a paraphrase of the author’s point. using stringent permit guidelines that do not distinguish by wetland types or values. Paragraph 2 provides a detailed list of wetlands functions and benefits which have been lost. Why does the author mention Freud and his “prescription”? The author is using the reference to state an idea (“major struggles are fundamental to living”) which is central to his own argument about fairy tales. (B). The other choices all sound positive. stronger regulation. D This is a common type of Evaluation question. The author implies that this second method would be more effective. that should have been a signal that something was not quite right. and greater public understanding of wetland values. and which could have been achieved with less wetland loss through “regional planning. is characteristic of fairy tales. “Safe” stories don’t deal with problems (A) and they fail to depict struggles between good and evil (C). Passage VIII (Questions 125–131) Topic and Scope: Threats to wetlands. C Choices (A) and (D) are directly mentioned in Paragraph 1. like (C).123. in the second and last sentences of the opening paragraph. (C) may have been tempting. No contradiction is being exposed. 125. based on regional management and prioritization of the most severely-threatened areas. Choice (B) is opposite. whereas the author says nothing good about modern stories.

C Just after mentioning “severe budget constraints” that limit government acquisition. the “present approach” and an “alternative strategy. (A) incorrectly focuses on the need for legislation to save American wetland areas. and FUD of the “stringent permit guidelines” mentioned in the first sentence of the paragraph. 129. the EWRA is an example illustrating the preceding generalization. (C) is a Distortion of the phrase “Cooperating federal. with the phrase “qualitatively important but quantitatively limited. For this reason.” which suggests that an increase in wetlands purchases by private groups and trusts would benefit wetlands protection.” indicating that increased recognition of these benefits might bring about a change in business decisions and behaviors. A Government and private acquisitions are mentioned in paragraph 3. 131. So. and to go straight to the key idea—like “reverse” in (D)—that makes each one wrong. state. and local interests” and also uses extreme language by claiming that such collaboration is “the only way” to reach the goal of wetlands preservation. The author says the first “will always be limited by severe budget constraints” and will save only “a small percentage” of remaining wetlands. which infers that these organizations would cooperate for the purpose of wetlands protection. (C) makes a recommendation—further study—that doesn’t appear in the passage. (D) is halfright and half-wrong. 127. Try not to get bogged down in minutiae. is also treated pessimistically—only “some” developers have tried to combine protection and profit. D The author describes only two strategies for protecting wetlands. the author states that the Emergency Wetlands Resources Act (EWRA) allocates “only \$40 million per year” in federal funding for wetland purchases. A The author suggests that federal. and the marketplace generally does not favor such an approach. 130. state.of all kinds. The second offers “quantitatively limited” protection. which declares that “the marketplace does not generally recognize the public benefits of wetlands. choice (A) is a Distortion of the information in these sentences. since the author never mentions that any areas of wetlands should be exempt from protective regulations. (B) is a Distortion of the author’s criticism of the present approach. which is rephrased in choice (C). Although the EWRA is undeniably a piece of 34 . 128. (D) sounds okay until the end— the author never suggests that any policy will actually reverse the trend. All these choices are straightforwardly wrong and your only problem should be with their wordiness. C Statement I is implied in the middle of paragraph 3.” in the first and third sentences of paragraph 4. Protection by private developers. and that although no “general federal authority” currently exists for the protection of wetlands systems. (B) makes a distinction among the three strategies that the passage does not support. Choices (B) and (C) both contain extreme language (“never” and “only”).” (C) is a Distortion of this same sentence since no mention is made of either an increase in rezoning of wetlands nor of the impact of industry on the conversion of wetlands. and local interests need to be considered. Statement III is a Distortion of the first sentence of paragraph 4. “several authorities” do exist which could develop this conservation plan (last three sentences of paragraph 4). Statement II is implied in the final sentence of the paragraph. The most straightforwardly pessimistic choice (A) is the one you want. in paragraph 4.

Choice (A) is outside the scope for this question.134.” 136. which has both mass and motion. since the usefulness of research methods is never discussed. (B) is outside the scope as well. which together “travel around a common center. (C) is stated in the second sentence of paragraph 3. whereas the original sentence in the passage is much less certain. 137. D Paragraph 3 ends with a concluding sentence indicating that “Symbiotic stars may therefore represent a transitory phase in the evolution of certain types of binary systems. which mentions “transfer of matter from the larger partner to the smaller. the answer choice here is formulated as a statement of fact. Choice (B) is stated at the end of paragraph 1.” (C) is a Distortion of the second sentence of paragraph 4. which tells us only that there are “several hundred million binary systems estimated…and thus theoretically detectable on sky-survey photographs…”. B The “recurrent outburst of a nova” are used as a comparison to the outbursts that occur with symbiotic stars as a way of explaining a certain process observed in the latter that is similar to a well-documented and understood process that occurs with a nova. for dangers of radiation are not mentioned in the passage. (C) is a Distortion of parts of paragraphs 3 and 4. which is described in the final sentence of paragraph 3. which claims only that symbiotic stars emit flares. Likewise. for this sentence actually is a hypothetical—“if all binaries of modest mass normally pass through a symbiotic phase in their evolution…”—and the answer choice does not contain this all-important word “if” but instead turns this hypothetical statement into a definitive fact. Choice (B) is a Distortion of the final sentence of paragraph 3. since the contrast made between symbiotic stars and other binary stars occurs earlier in paragraphs 1 and 2. since the mention of the nova does not prove the existence of matter transfer.” so that binary stars must begin inside this cloud. 135. 36 . (D) is a Distortion of the first sentence of the passage. A Paragraph 2 described the structure of symbiotic stars. Again. (C) is FUD.” not around each other. and uses extreme language with the terms “all” and “must. (D) is a Distortion of the previous sentence in paragraph 3. and (D) is stated at the first sentence of paragraph 4. A Paragraph 4 tells us that the course of a binary system is “predetermined by the initial mass and angular momentum of the gas cloud within which binary stars are born.” Choice (A) is outside the scope. not that all binary systems do so.

C 212. D 201. B 163. A 193. A 182. D 164. C 159. A 180. A 173. B 206. A 153. D 154. D 199.BIOLOGICAL SCIENCES ANSWER KEY 138. A 210. D 184. B 191. D 178. C 172. B 150. B 147. B 183. C 211. A 209. C 202. D 174. B 156. C 186. C 192. D 196. B 195. C 208. B 158. D 189. C 204. C 205. B 155. B 185. D 207. B 198. A 197. C 166. D 145. A 143. D 213. D 168. B 37 . A 188. D 144. D 142. B 141. B 167. B 140. C 169. C 157. D 149. B 203. C 175. A 176. A 170. A 171. A 152. C 160. C 181. D 179. D 161. B 214. B 200. B 151. B 187. D 194. C 139. A 165. A 146. A 148. C 177. C 190. D 162.

though it is indispensable in the absorption of lipids and other nutrients. choice (A). is correct. without which the enzymatic dissociation of the cobalamin-R-binder complex would not be possible. temperature) under which it operates. recall that myelin is composed of one type of cell in the peripheral nervous system—the Schwann cell. C Theoretically. The same holds for choices (C) and (D). and a different cell type in the central nervous system— the oligodendrocyte. second is the jejunum. 139. which is composed of all parts of the nervous system outside the brain and spinal cord proper. this unmyelinated space is obviously not a site of demyelination. B Recall that myelin is a major factor in the speed of neuronal transmission. one would still require both an absorptive surface (ileum) with the specific receptor and transcobalamin to transport the absorbed vitamin to the liver and red blood cells. Lastly. choice (D) which controls only voluntary muscle action. So choice (B) would also affect the absorption of cobalamin since the pancreas is a major source of the bicarbonate that allows for an alkaline environment in the duodenum. and the ileum is where the cobalamin-IF complex is actually absorbed. as opposed to the somatic division.) Also. the dendrites are the receivers of inter-neuronal transmission. Pernicious anemia is briefly mentioned at the end of the passage and is characterized by absent or deficient IF. choice (A) is incorrect. medication that inhibits the production of gastric acid.Passage I (Questions 138–143) 138. and choice (D) is incorrect. The nervous system can also be divided into those cells that relate sensory information from the internal or external environment (afferent neurons) and those that bring reflexive or processed information to the effectors (such as muscle) in response to the sen38 . Thus. B A person given this supplement would only depend on the latter steps discussed in the first paragraph of this passage. which then connects to the first part of the colon. thus choice (C) is incorrect. affect the other major factor—synaptic transmission of a message from neuron-to-neuron. Both the autonomic and somatic divisions are subsets of the peripheral nervous system. however. choice (A). Myelin acts to insulate the axon and allow increased speed of propagation of an action potential down a given axon. is not a necessary component of this process. there is no mention of a defect of synaptic transmission in cobalamin deficiency. thus. D Control of involuntary muscle groups falls within the autonomic division of the peripheral nervous system. which would both affect earlier steps and which could both be bypassed by this supplement. 141. The passage states that cobalamin deficiency causes demyelination. (It does not. Bile. a person with a transcobalamin deficiency would still suffer from a lack of cobalamin despite such a supplementation. and choice (B) is correct. choice (B). The question describes an experiment being done at a site of the peripheral nervous system. The nodes of Ranvier are the areas of the axon between the myelinated segments which are devoid of myelin. not choice (A). Choice (D) would result in a person without an ileum. So a supplement such as the proposed one would treat cobalamin deficiency due to this disorder. and third is the ileum. so you can assume that slower transmission in this case is due to a defect of the myelinating cells of the peripheral nervous system. however. choice (B). Recall that the small intestine is composed of three segments— first the duodenum. 140. would not allow for the proper environment for both the release of cobalamin from its complex with food components and the binding of cobalamin with R-protein. Remember that every enzyme has optimal conditions (pH.

uracil (U) is only found in RNA. G. The boiling point of isoamyl acetate is ~140°C according to the passage. Thus. and a peak at 2800 cm–1 indicates a C-H stretch. 145. but much fewer than the segment given as choice A. Isopentyl alcohol is completely used in the reaction because it is the limiting reagent (remember acetic acid is used in excess!). The passage states that the student forgot to dry the compound with anyhdrous sodium sulfate. thus.sory information gathered (efferent neurons). D Lipid digestion begins once food reaches the small intestine. Isoamyl acetate cannot be distilled from the solution because isopentyl alcohol and acetic acid would distill with it. the product removed must be water. These emulsified units are then acted on by lipases from the pancreas. or the DNA segment with the most T’s and C’s. The wide boiling point range and the presence of an OH stretch (broad band at 3200 cm–1) indicate the presence of some impurity. Think of the alphabet: “a before e” to help remember this sequence. replace “water” with “isopentyl alcohol and acetic acid) 146. in fact. Communication to the sphincter muscles described in the question stem is via efferent neurons by definition. Fatty acids can then be absorbed by the cells lining the small intestine. A Le Châtelier’s Principle states that if reactant is added. C. choice (B). acetic acid would not be present in the final solution because the student extracted the reaction mixture with sodium bicarbonate. In this case. the reaction will be driven to product. Isoamyl acetate is hydrophobic and will not dissolve in aqueous solution. For this reason. Choice C is incorrect because DNA is made of the four bases A. the stomach has no role in this process. is secreted into the first part of the small intestine (the duodenum) where it begins to emulsify and break down lipids into smaller. Passage II (Questions 144–149) 144. D A sharp peak at 1735 cm–1 is indicative of a carbonyl. if product is removed. The boiling point of water is 100°C. 142.” The transcription process that will be most affected will be the one that must produce mRNA from the most A’s and G’s. B Sodium bicarbonate is a base and will consequently deprotonate an acid. respectively.e. However. (i. Bile produced by the liver. the compound giving rise to the carbonyl and C-H stretches is most likely isoamyl acetate. Choices B and D also have some T’s and C’s. drive the reaction toward formation of products. the reaction will be driven to product. 39 . Addition of water would. such as by adding a dehydrating material. acetic acid will be deprotonated because it is the only acid in solution. will also work. A Recall that the purines are adenine (A) and guanine (G)—“PURe As Gold. The resulting salt (acetate) is water-soluble and so will be separated from the hydrophobic product. Removing water by another method. 143. choice A is correct. efferent neurons could be involved in this effect of cobalamin deficiency. choice (A). Therefore. Similarly. more soluble units. if one product is to be removed by distillation. T. which break down the lipids further into free fatty acids. This suggests that water is present which agrees with the O-H stretch. choice (C). These peaks would be present both in isoamyl acetate and in acetic acid.

Of the answer choices given. Water usually does not appear in nmr spectra. Compounds that exhibit the most hydrogen bonding have the highest boiling points. A The carbonyl carbon is electrophilic (eliminate choice (B)).2 ppm is likely due to a carboxylic acid such as acetic acid. B This question is essentially asking which compound has the lowest boiling point and which the highest. Lipid-soluble hormones. D An extreme shift such as 11. 152. Choice (B) is incorrect because a hypotonic medium outside the cell will increase the rate of ATP entry. then we apply the reaction to the compound. The rate at which this 40 . The electron-withdrawing effects of the chloride ion make the carbonyl more electrophilic than acetic acid making it more susceptible to nucleophilic attack by the alcohol. aldosterone. 149. A The net effect of the Na+/K+ pump is to transport one ion out of the cell. thereby lowering intracellular osmolarity. 151. Noctyl alcohol has the highest boiling point and will distill last. Note that this process has nothing to do with “need”. those with the least hydrogen bonding have the lowest boiling points. esters do not). Esterification is an addition-elimination reaction so no carbocation is formed (eliminate choice (C)) and an SN1 reaction does not take place (eliminate choice (D)). and therefore glucagon will not cross the lipid bilayer. 148. We recognize that the reaction is similar to the one depicted in Equation 4. Acetyl chloride would not be found in the reaction mixture because it was not used in this reaction. Also suspect acetic acid because it is used in excess in the reaction. since a hypertonic solution around the cell would decrease the concentration gradient such that there would be a significantly lower draw on ions to leave the cell. causing it to consume more ATP. thereby maintaining cellular osmolarity. Octane clearly has the least hydrogen bonding and so has the lowest boiling point. isopentyl alcohol is unlikely. B Glucagon is the only hormone that is not lipid-soluble like steroid hormones. Placement of an animal cell into a hypertonic environment creates a tendency for water to leak out of the cell because of high extracellular osmolarity. A The passage states that the small bleached region regains its fluorescence after the fluorescently labeled molecules exchange places with bleached molecules. First. Alcohols have more hydrogen bonding than esters (alcohols have an O-H group. To prevent water loss from the cell. Again. the Na+/K+ pump will slow down the rate of ion exchange. Choices (C) and (D) are incorrect because both channels dissipate the function of the pump. on the other hand. It occurs automatically.147. we need to determine the correct structure. Water-soluble hormones require membrane receptors in order to conduct the signal. because it is the limiting reagent in the reaction and because the hydroxyl hydrogen in most alcohols is usually found around 5-6 ppm. and estrogen are all lipid-soluble steroid hormones. can cross the lipid bilayer and bind to cytoplasmic or nuclear receptors. testosterone. except with a different alkene. which are derived from cholesterol. and if it does it is a very broad peak due to extensive hydrogen bonding. Passage III (Questions 150–154) 150. It will therefore distill first.

159. is the molecule that precedes oxaloacetate in the citric acid cycle. protons augment nociceptor activation by thermal. choice (D) is correct. Choice (C). D Oxaloacetate is the molecule regenerated at the end of the citric acid cycle. opiates activate sodium channels. Choice (B) is incorrect because the bromine is missing from the intermediate. produced during pyruvate decarboxylation to form citrate. Since oxaloacetate is the molecule regenerated at the end of the citric acid cycle. The intermediate formed has the structure shown in choice (D). 160. Choice (D) is correct. Thus if the G protein-coupled receptors are blocked the sensation of pain will be increased rather than diminished. 2N. Malate. 162. Although the cell contains twice as much genetic materials as it did prior to the S phase. Choice (A) is incorrect because the passage states that protons can directly activate nociceptive neurons only at pH values lower than 6. Choices (A) and (B). Among the listed answer choices all but choice (C) present a scenario that will actually lead to activation of the postsynaptic neurons. Choice (C) is correct. thereby stimulating postsynaptic neurons. B During the S phase. Inhibition of cation channels in postsynaptic neurons can prevent activation of those neurons in response to excitatory stimuli. which inevitably leads to depolarization of the postsynaptic neurons. the thermal stimulus generated by an actively respiring muscle can be augmented by acidity and become sufficiently strong to activate nociceptive neurons. because the chromatids have not yet separated. Choice (A) is incorrect because the free radical is on the same carbon as the bromine. on the other hand. Choice (C) is correct. C The passage states that below pH 7. describes a mechanism that can explain the inhibitory effect of opiates. D The passage states that G protein-coupled receptors are involved in dampening of the nociceptive signaling in response to endogenous pain stimuli. for example. the cells are still 2N. Discrete Questions (Questions 161–164) 161. is correct. C The action of opiates must account for the inhibition of postsynaptic neurons in the spinal cord.158. each chromosome is replicated to produce two identical sister chromatids joined by a centromere. Oxaloacetate combines with acetyl CoA. The reaction is a free-radical chain process in which a bromine atom adds to the double bond in the first propagation step. Choices (B) and (D) are unsupported by the passage. choice (C). even at the end of the S phase. In choice (D). This indicates that the threshold for activating nociceptors in response to various stimuli is reduced under acidic conditions. will lead to an increase in the number of excitatory neurotransmitters in the synaptic cleft. choice (A). Thus choice (B). Choice (C) is incorrect because the more substituted (Markovnikov) addition product would be formed. Thus. 163. This mechanism is also described in the passage for the dampening of nociceptive signaling in response to pain producing stimuli. choice (B). 42 . D Hydrogen bromide adds to alkenes in the presence of peroxides with a regioselectivity opposite to that predicted by Markovnikov’s rule. chemical or mechanical stimuli. anti-Markovnikov addition is observed and the less-substituted alkyl bromide is the major product.

Passage V (Questions 165–170) 165. Transcription is the process whereby information coded in the base sequence of DNA is transcribed into a strand of mRNA. (An example of an overriding factor would be the C-H/C-LG periplanar requirement for the E2 reaction. Attack at any position leads to a carbocation with at least three resonance structures.) The X group disfavors attack at the ortho position because it is more crowded than the meta or para positions. Resonance generally dominates. is an electron-donating group.) Since the electrophilic attack affords a carbocation. RNA contains the nucleotide uracil (U) rather than thymine (T). Two major factors influence this. so the process of transcription requires the presence of uracil. In the specific example of this question. the attack leading to the most stable carbocation is favored. further improving their stability over the meta carbocation. A Uracil is a nucleotide found only in RNA. Choice (A) is the correct answer. Electron-donating groups are therefore termed ortho/para directors. through which genetic material is exchanged. Translation is the process whereby mRNA codons are translated into a sequence of amino acids.164. Thus the order of attack when X = CH3 or any other electron-donating group is: para (most) > ortho > meta (least). so the carbocation stability issue is more important than the steric effect. while the best carbocation in the meta case is secondary. (If the X group can share lone pairs through resonance then the ortho and para carbocations can have a fourth resonance structure. we predict attack at the ortho and para positions to be favored over meta attack. Conjugation is the temporary joining of two organisms via a tube called a pilus. The best carbocation in the ortho and para cases is tertiary. Based on carbocation stability. Ortho attack: X E+ X H E + + X H E X + H E Meta attack: X E+ H X + E H + E + H E X X Para attack: X X X + + E+ E H E H E H + X 43 . X = CH3. a mechanism step proceeds to give the most stable product if there are no other overriding factors. C The isomer of the product that is formed is controlled by the position of attack of the electrophile on the benzene ring. As in all other mechanisms. Mitosis is the process of cellular division that results in the formation of two daughter cells that are genetically identical to each other and to the parent cell.

Rather. D Reaction rate is controlled by the rate-determining step (rds) of the mechanism. This is the first step of the mechanism shown. Electron-withdrawing groups are termed meta directors. (In cases where an arenium ion with a full octet resonance structure is produced. the bromine may be sufficiently electrophilic by itself. NO2 is an e-withdrawing group and thus nitrobenzene (III) is a weaker nucleophile than benzene (IV). CH3 CH3 CH3 + Br 3Al Br Br Br H Br AlBr 3 Br HBr + AlBr3 CH3 CH3 Br H Br H 167. C Side-chain halogenation takes place under conditions that favor the formation of radicals (e. thus increasing the amount of positive charge on the bromine by decreasing its electron density. this step is attack of the electrophile on the aromatic ring. Since the rds involves electrophilic attack.g. B Electrophilic attack on the benzene ring disrupts aromaticity and forms a carbocation. factors which make the benzene ring a better nucleophile will increase the rate of reaction (e-donating groups also produce more stable cations). thus. In this case the order of attack is meta > para > ortho.) Choice (D) is incorrect because AlBr3 is regenerated in the reaction. This is the rds because aromaticity is sacrificed. HBr is the byproduct. CH3 is a weaker e-donating group than OCH3. This occurs in the carbocations resulting from ortho and para attack. it destabilizes an adjacent carbocation by increasing the net positive charge on that carbon. The AlBr3 serves to increase the electrophilicity of the bromine by strongly polarizing the Al-Br bond. The OCH3 group is a strong e-donating group which increases the e-density of the benzene ring making it a better nucleophile. but not from meta attack. choice (A) is incorrect. The halogen dissociates to produce halogen atoms and then the halogen atoms initiate chains by abstracting hydrogens of the methyl group: 44 . A more powerful electrophile is needed. UV light). and thus requires a powerful electrophile.166. Molecular bromine is not sufficiently electrophilic to overcome aromaticity. When X is a electron-withdrawing group. 168. For EAS.

Step 2 involves deprotonation and restoration of aromaticity which produces a product much more stable than the carbocation intermediate. Steps 2 and 3 repeat. exposure to UV light over short periods of time wouldn’t lead to significant decomposition. H2OBr+ is a stronger electrophile (better able to accept electrons) because the bromine bears a positive charge (it is electron deficient). H2OBr+ is an ion and is therefore highly soluble in H2O compared with Br2 (Answer D incorrect). the rate-determining step is electrophilic attack on the benzene ring (not deprotonation of the aromatic ring) because it results in loss of aromaticity. the carbocation intermediate must capture a nucleophilic bromide ion instead of losing a proton. Capture of a proton does not restore aromaticity whereas deprotonation does. Thus. whereas many aryl halides are UV-sensitive. 170. 169. and more stable than the starting materials since the reaction proceeds spontaneously. The rate determining step is the first step which involves electrophic attack and carbocation formation. Choices (A) and (D) are incorrect because. If Choice (C) were correct. H2O is an excellent leaving group. Answer B is correct. A The mechanism of an EAS reaction involves two steps. The benzyl radical then reacts with a halogen molecule to produce a benzyl halide and a halogen atom. This automatically eliminates choices (B) and (C) which are potential energy diagrams for one-step reactions. This provides a significant driving force for deprotonation over capture of chloride ion. The purpose of AlBr3 is to increase the electrophilic nature of Br2 by polarizing the Br-Br bond. A In an EAS reaction. Also. Thus choice (A) is correct. 45 .Step 1: Br2 UV light 2 Br Step 2: Chain Propagation CH3 + Br Benzyl radical Step 3: CH2 + Benzyl radical Br2 Benzyl halide CH2Br + Br CH2 + HBr Abstraction of a halogen from the methyl group of toluene produces a benzyl radical.

8 to 3 mmol/L in 8 hours.L-glyceraldehyde will thus have no influence on insulin secretion by the pancreas. This corresponds with answer choice (A). you can see that glucose concentration changes from approximately 4. In contrast. it allows intracellular components to mix with plasma.L-glyceraldehyde will have 50% or 15 mmol/L of the L isomer. Since 30 mmol/L of racemic D. it diffuses into plasma. C To answer this question correctly you must know the relative intracellular and plasma concentration of various components in the blood. The net change of glucose concentration was thus 4. 15 mmol/L of pure isomer will be required to have the same effect. Passage VII (Questions 176–180) 176. vecuronium competes but does not cause a depolarization and is classified as a competitive inhibitor. 174. Since fluoride causes hemolysis. (B) and (D) are incorrect because for urea.L-glyceraldehyde is an antiglycolytic agent and one can infer that it will inhibit a glycolytic enzyme. D.L-glyceraldehyde will thus interfere with measurements of creatinine. 175. thereby raising plasma concentration of intracellular components. 172.L-glyceraldehyde increased the rate of glucose synthesis then an analysis would provide an overestimate of plasma glucose concentration thus rendering D. 173.Lglyceraldehyde unsuitable as preserving agent. The correct answer is choice (C).L-glyceraldehyde on blood after it was collected from patients.8 – 3 = 1. Choice (A) is correct. Choices (A). Potassium is found in high concentration inside cells and in low concentration outside cells due to the action of Na+/K+ ATPase. A From Figure 1. D. The average rate of disappearance is simply the slope of the line and is equal to (1. Choice (C) is not only unsupported by the passage. but also incorrect because if D. D The beginning of the third paragraph states that D. Choice (D) is incorrect because after bicarbonate ion is made inside red blood cells.8 mmol. A The last sentence of the passage states that the L stereoisomer was responsible for all or most of the antiglycolytic activity of the racemic mixture. C Succinylcholine competes with acetylcholine for the receptor (paragraph 2) and causes a depolarization (activator). Choice (A) is incorrect because Na+ is present mostly in the plasma.L-glyceraldehyde is an antiglycolytic agent the last thing it will do is increase the rate of glycolysis. Choice (A) is incorrect because the passage is discussing the effects of D.Passage VI (Questions 171–175) 171. Thus during hemolysis. 46 . Choice (B) is incorrect because albumin is a plasma protein. C Table 1 shows that creatinine concentration values for blood treated with D.8 mmol/L)/8 hr which is approximately 1/4. the plasma concentration of K+ will be raised significantly.L-glyceraldehyde are significantly different from those obtained from blood with no additives. calcium and potassium there is almost no difference in concentration values obtained with and without D.L-glyceraldehyde. Choice (B) is incorrect because if D.

leaving only elements related to signal transmission (statements I and II). Choices (A) and (C) are signs of increases in sympathetic activity. The two alkenes have the same molecular formulas but the atoms are bonded in different arrangements. Choice (A) is incorrect because configurational isomers are stereoisomers (enantiomers or diastereomers). Because the muscle is able to contract with an external electrical depolarization. It is the channels remaining open that causes the subsequent paralysis. Choice (D) is incorrect because relative product distribution can be predicted according to the alkene substitution pattern. Differentiation between statements I and II is impossible without further experimentation. would not allow the impulse to be transmitted to the skeletal muscle cells. Alkene A has three substituents while alkene B has only two. However. This rules out any elements of this apparatus (statement III). choice (A). Preventing calcium ion release. C This experiment suggests that curare interferes with transmission of the signal to contract rather than contraction itself. The correct answer is choice (D). the very binding of succinylcholine causes a depolarization.177. choice (C). D Loss of the acetylcholine receptors. Choice (D) is incorrect since conformers have different arrangements of atoms in a molecule according to rotation around single bonds. Choice (D) is false because succinylcholine cannot cross the blood-brain barrier (paragraph 1) and would not suppress brain activity. Choice (C) is incorrect because although succinylcholine does bind and prevent ACh from binding. Downregulating the acetylcholinesterase gene would result in hyperexcitation rather than paralysis. Choices (B) and (C) are incorrect since. in each case. Succinylcholine depolarizes muscle cells individually as the succinylcholine reaches them. would also prevent impulse transmission. Choice (B) describes allosteric binding (induced fit type). The correct answer is choice (A). molecules cannot be transformed into one another by rotation around single bonds. D Decreased heart rate and increased salivation are signs of parasympathetic activity. or choice (C). Choice (D) is incorrect because diastereomers are configurational isomers or stereoisomers. The atoms are bonded in the same manner but have different arrangements in space. 180. A Succinylcholine binds to the receptor and causes a depolarization (paragraph 2). one alkene has fewer substituents than the other. The stability of an alkene is directly related to the number of substituents. The correct answer is I and II only. 182. within the muscle cells would prevent calcium binding to troponin. Choice (B) is incorrect because atropine (a parasympathetic blocker) would not be expected to interfere with edrophonium’s neuromuscular effects. this will cause the actin-binding site to remain covered. 47 . the muscle cell contraction apparatus must be intact. As in spinal cord injury. choice (B). 179. 178. Passage VIII (Questions 181–186) 181. B 2-Methyl-2-butene and 2-methyl-1-butene are constitutional isomers. severing motor neural axons. A The alkene in choice (A) is favored over that of choice (B) since it has more substituents on the double bond. edrophonium increases parasympathetic activity (paragraph 4). Choice (C) is incorrect because the alkenes have different substituents and consequently are formed in different amounts.

The substitution product (the ether) is formed via an SN2 mechanism (substitution.183. never a combination of the two. they are the rounded. (B) and (D) are incorrect because water. the outer electrons are further from the positively-charged nucleus and so are less tightly held. choice (A) is correct. 1-Bromooctadecyl bromide is a primary halide that reacts with a good nucleophile (ethoxide ion) through a transition state involving a pentacoordinted carbon atom. unimolecular) and E1 (elimination. nucleophilic. and the elimination product (the alkene) is formed via an E2 mechanism (elimination. The more electronegative species has a tighter hold on its electrons and does not share them as easily. methanol. which forms a firm but elastic matrix to form cartilage. consequently. B An anion is a better nucleophile than the corresponding neutral compound since the electrons on the anion are not as tightly held. unimolecular) mechanisms indicate. Choice (C) is incorrect since larger atoms are better nucleophiles. the electrons of the anion are more easily shared than those of the neutral compound. B The tert-Butoxide ion is very bulky when compared to the methoxide ion. cylindrical shaft in between the epiphyses. When the electrons are more loosely held the atom is more polarizable and its electrons are more easily shared. Rather. Choice (A) is incorrect since the reaction does not proceed through a carbocation intermediate as SN1 substitution (substitution. 184. Epiphyses aren’t actually cells. and formamide have hydrogens that participate in hydrogen bonding and solvate the nucleophile. nucleophilic. Discrete Questions (Questions 187–191) 187. Osteoblasts are the cells that help build bone and function antagonistically to osteoclasts. bimolecular). the nucleophile (cyanide ion) is not solvated and is therefore a much more powerful nucleophile. the more nucleophilic it is. Choices (B) and (C) are incorrect because substitution and elimination reactions are either both unimolecular or both bimolecular. 48 . Therefore. 186. D The reaction is a second-order reaction that proceeds in one step. Choice (A) is incorrect since tert-butoxide ion is actually much more basic than methoxide ion. which are the cells that help break down bone. The nucleophilic power of the cyanide ion would be reduced thus slowing the reaction. Steric considerations reveal that removal of a proton to form the elimination product is achieved more easily than attack of the electrophilic carbon center to give the substitution product. Choice (A) is incorrect because a more electronegative species is less nucleophilic. The diaphysis is the long. A Chondrocytes are the specialized cells that secrete chondrin. dilated ends of the bone. Choices (A). C The best solvent choice is dimethylformamide since it is a polar. Choice (C) is incorrect because the time and temperature differences are minimal when compared to the steric and basicity differences of the nucleophiles. The electrons are more easily shared and so the atom is a better nucleophile. The solvent has no protons to participate in hydrogen bonding and. bimolecular). Polarizability is directly related to the magnitude of the force with which the electrons are attracted to the nucleus. In larger atoms. Choice (D) is incorrect since the more polarizable a species is. This higher (not lower) basicity also significantly contributes to the product outcome. Thus. 185. aprotic solvent.

Thus. T cells are not. This corresponds with answer choice (C). 1/2 are carriers of the gene for hemophilia. and the X chromosome with the gene for hemophilia is denoted by Xh. and thus the acidity of a carboxylic acid is increased by the presence of an electron-withdrawing group such as chlorine. 189. 1 X+Y. D Helper T cells activate B cells and other T cells through the secretion of lymphokines. Choice (D) is a carbinolamine. Choice (D) is correct. Acid III. Thus. it may be determined that the genotypes of their offspring are 1 X+Xh. C If the normal X chromosome is denoted by X+. is stronger than acid II where there is no chlorine present. 1 XhXh. Choice (C) is an enamine. 190. and I is the strongest acid. but their job is to proliferate and produce a large number of cytotoxic T cells upon secondary exposure. not an imine. Thus the conjugate base of acid I is stabilized to the greatest extent. 49 . of the female children. C CH3CH2CH NCH3 + H2O Electron withdrawal stabilizes the conjugate base of a carboxylic acid. Carbinolamines are intermediates in the formation of imines. a female who is a carrier for hemophilia has a genotype of X+Xh. responsible for recognizing antigen upon secondary exposure to it. and 1/2 are hemophiliacs. OH CH3CH2CHNHCH3 191. Rather. There is a class of memory T cells. Suppressor T cells downregulate B and T cell activity against antigens. O CH3CH2CH + CH3NH2 CH3CH2CH NCH3 Choice (A) is incorrect because it is an amine. the carbinolamine in choice D would spontaneously lose water to form the imine in the correct answer (B). Utilizing a Punnett square. having a chlorine on the carbon. formed by the reaction of an aldehyde or ketone with a secondary amine. the carboxylate ion. however. while a male who is a hemophiliac has a genotype of XhY. B Imines are formed from the reaction of an aldehyde or ketone and a primary amine. 50% of the female children of a hemophilia carrier female and a hemophiliac male will be hemophiliacs. 1 XhY. that is the job of memory B cells. The imine in the correct answer choice (B) is formed by the reaction of propanal and methylamine. The proximity of the electron-withdrawing group to the carboxyl group determines the degree of stabilization of the carboxylate ion. Cytotoxic T cells destroy foreign antigens.188.