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You are on page 1of 2

2 Heat capacity 15

How much heat needs to be supplied to an object to raise its

temperature by a small amount dT?

The answer to this question is the heat dQ = C dT, where we deﬁne

the heat capacity C of an object using

C =

dQ

dT

. (2.2)

As long as we remember that heat capacity tells us simply how much

heat is needed to warm an object (and is nothing about the capacity of

an object for heat) we shall be on safe ground. As can be inferred from

eqn 2.2, the heat capacity C has units J K

−1

.

As shown in the following example, although objects have a heat ca-

pacity, one can also express the heat capacity of a particular substance

per unit mass, or per unit volume.

3

3

We will use the symbol C to represent

a heat capacity, whether of an object,

or per unit volume, or per mole. We

will always state which is being used.

The heat capacity per unit mass is dis-

tinguished by the use of the lower-case

symbol c. We will usually reserve the

use of subscripts on the heat capacity

to denote the constraint being applied

(see later).

Example 2.2

The heat capacity of 0.125 kg of water is measured to be 523 J K

−1

at

room temperature. Hence calculate the heat capacity of water (a) per

unit mass and (b) per unit volume.

Solution:

(a) The heat capacity per unit mass c is given by dividing the heat

capacity by the mass, and hence

c =

523 J K

−1

0.125 kg

= 4.184 ×10

3

J K

−1

kg

−1

. (2.3)

(b) The heat capacity per unit volume C is obtained by multiplying

the previous answer by the density of water, namely 1000 kg m

−3

, so

that

C = 4.184 ×10

3

J K

−1

kg

−1

×1000 kg m

−3

= 4.184 ×10

6

J K

−1

m

−3

.

(2.4)

The heat capacity per unit mass c occurs quite frequently, and it is

given a special name: the speciﬁc heat capacity.

Example 2.3

Calculate the speciﬁc heat capacity of water.

Solution:

This is given in answer (a) from the previous example: the speciﬁc heat

capacity of water is 4.184 ×10

3

J K

−1

kg

−1

.

16 Heat

Also useful is the molar heat capacity, which is the heat capacity

of one mole of the substance.

Example 2.4

Calculate the molar heat capacity of water. (The molar mass of water

is 18 g.)

Solution:

The molar heat capacity is obtained by multiplying the speciﬁc heat

capacity by the molar mass, and hence

C = 4.184 ×10

3

J K

−1

kg

−1

×0.018 kg = 75.2 J K

−1

mol

−1

. (2.5)

When we think about the heat capacity of a gas, there is a further

complication.

4

We are trying to ask the question: how much heat should

4

This complication is there for liquids

and solids, but doesn’t make such a big

diﬀerence.

you add to raise the temperature of our gas by one degree Kelvin? But

we can imagine doing the experiment in two ways (see also Fig. 2.1):

Fig. 2.1 Two methods of heating a gas:

(a) constant volume, (b) constant pres-

sure.

(1) Place our gas in a sealed box and add heat (Fig. 2.1(a)). As the

temperature rises, the gas will not be allowed to expand because

its volume is ﬁxed, so its pressure will increase. This method is

known as heating at constant volume.

(2) Place our gas in a chamber connected to a piston and heat it

(Fig. 2.1(b)). The piston is well lubricated, and so will slide in

and out to maintain the pressure in the chamber to be identical

to that in the lab. As the temperature rises, the piston is forced

out (doing work against the atmosphere) and the gas is allowed to

expand, keeping its pressure constant. This method is known as

heating at constant pressure.

In both cases, we are applying a constraint to the system, either con-

straining the volume of the gas to be ﬁxed, or constraining the pressure

of the gas to be ﬁxed. We need to modify our deﬁnition of heat capacity

given in eqn 2.2, and hence we deﬁne two new quantities: C

V

is the heat

capacity at constant volume and C

p

is the heat capacity at constant

pressure. We can write them using partial diﬀerentials as follows:

C

V

=

∂Q

∂T

V

, (2.6)

C

p

=

∂Q

∂T

p

. (2.7)

We expect that C

p

will be bigger than C

V

for the simple reason that

more heat will need to be added when heating at constant pressure than

when heating at constant volume. This is because in the latter case

additional energy will be expended on doing work on the atmosphere

as the gas expands. It turns out that indeed C

p

is bigger than C

V

in

practice.

5

5

We will calculate the relative sizes of

C

V

and C

p

in Section 11.3.

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