Professional Documents
Culture Documents
VADE-MECUM
Rev. 2002
Table of Contents
1.
2.
3.
4.
5.
6.
7.
8.
Index - i
Rev. 2002
1. Fuel Theory
a) Low Heating Value
LHV is calculated from the Higher Heating Value (obtained by bomb calorimeter)
Considering that :
- Water created by the combustion doesnt condense
- The reaction takes place under constant pressure
LHV = HHV - 567W (at std. Temp = 25oC) in metric units
LHV = HHV 1020W (std. Temp = 60oF) in english units
-
The difference between the HHV and the LHV will vary with fuel type. The greater the proportion of
hydrogen in a fuel, the lower the resulting LHV:
Fuel
Coal
Coke
Waste Fuel
Fuel oil
Nat. gas
%H
5
4
10
10
25
HHV
(Btu/lb)
12,000
14,000
9,000
19,000
23,000
LHV
(Btu/lb)
11,540
13,630
8,070
18,070
20,680
LHV
(kcal/kg)
6410
7570
4480
10040
11490
LHV as a
% of HHV
96
97
90
95
90
Rule of thumb:
One cubic foot of air (+stochiometric amount of NG or oil) releases 100 Btu of heat (for fuel), 1m3 air
releases about 900 kcal.
b) Volatile Matter
Volatile matter is the loss in weight, corrected for moisture, of a sample heated to 950oC in the absence of
air.
Ignition
Temperature C
300
% VM
5.1
Rev. 2002
c) Ash
Ash is the inorganic residue remaining after burning coal heated to 750oC in an oxidizing atmosphere until
there is not weight change. It is composed chiefly (95-99%) of oxides of Si, Al, Fe, and Ca; Mg, Ti, S, Na,
K, and trace elements can also be present.
d) Fixed Carbon
Fixed carbon is the residue left after the volatile matter is driven off and is calculated as:
F.C. = 100 (% ash + % moisture + % volatile matter)
e) Flammability
H2
CO
CH4
12.5
5
74
15
610
580
C2H6
12.5
490
C3H8
2.2
9.5
480
C4H10
1.7
8.5
420
Gas
0.001
2. Solid Fuel
2.1 Coal
a) Main Coal Characteristics
Approximate Analysis and bulk density for Various Coals
Group
Anthracite
Meta anthracite
Anthracite
Semi anthracite
Bituminous
Low-vol
Med volatile
High vol A
High vol B
High vol C
Subbituminous
A
B
C
Lignitic
A
B
than
> than
98
92
86
98
92
2
2
8
86
78
69
14
22
31
< than
Kg/m3
800-930
8
14
670-910
78
69
22
31
13,000
11,500
10,500
9,500
8,300
640-860
6,300
5.2
Rev. 2002
Proximate Analysis
Volatile
Free carbon
Moisture
Ash
HHV
22.19
64.29
6.5
12.5
7.259
% dry
% dry
%
% dry
kcal/kg coal dry
(kcal/kg) @ 25 C,
or
(Btu/lb)
Carbon
Hydrogen
Sulfur
Nitrogen
Chlorine
Oxygen
Ash
% weight
74.87
3.78
2.24
1.93
0.08
3.53
13.57
C:
H2:
S:
N2:
Cl:
O2:
nb moles/kg
62.33
18.75
0.70
0.69
1.10
1
H 2 + O2 H 2 O + 2 ,8641 kcal / kg H
2
- the oxydation of coal is very quick: 0.1 to 0.3 seconds
(C ) + (S ) + (H ) (O )
22.4
*
21
12.01 32.06 4 *1.01 2 *15.99
Input in mass % V=
Rule of thumb
7.6 Nm3/kg of dry coal
Neutral Combustion Products
Nm3/kg
Combustion
CO2
1.306
H2O
0.393
SO2
0.015
N2
5.721
H2O
0.081
Moisture
Total
7.515
Kg/kg
2.564
0.316
0.042
7.152
0.065
10.138
%vol
17.4
5.2
0.2
76.1
1.1
%weight
25.3
3.1
0.4
70.5
0.7
5.3
Rev. 2002
2.2 Coke
LHV
MJ/t
%C
%H
C/H Ratio
%S
ASH content (%)
Volatile matter (%)
Granulometry (mm)
Moisture content (%)
Ignition Temperature
Hard Grove (HGI)
Delayed Coke
34,300
88 90
3.9 4.5
21
26
0.5 1.5
10 15
0 50
7 10
220 - 250
90 100
Fluid Coke
31,000
87 88
23
35
58
28
5 10
08
5 10
230 250
10 - 30
3. Fuel Oil
3.1 Main Characteristics
Comp
C
H
O
N
S
Ash
C/H ratio
Specific Gravity
Api Gravity =
N1
86.4
13.6
0.01
0.003
0.09
<0.01
6.35
N2
87.3
12.6
0.04
0.006
0.22
<0.01
6.93
0.849
N4
86.47
11.65
0.27
0.24
1.35
0.02
7.42
0.902
N6 FO
87.26
10.49
0.64
0.28
0.84
0.04
8.31
N6
84.67
11.02
0.38
0.18
3.97
0.02
7.62
0.965
141.5
131.5 ( for SG < 1)
Specific Gravity
3.2 Viscosity
Theory
The viscosity of a fluid is a measure of its internal resistance to flow. Viscosity is the opposite of fluidity.
- abs visc is absolute viscosity, measured in cp (centipoise);
- kin visc is kinematic viscosity, C measured in cs or cSt (centistokes)
- abs visc in cp = kin visc cs * specific gravity
1 poise = 100 cp = 1 dyne.s/cm2+ = 1 g/s*cm, 1 stoke = 100 cs = 0.000 1 m2/s
Required:
- Viscosity: 20-25cSt, filtration<125m (abrasion and clogging: 3-stage filtration at 35, 60 and 120#)
- Variation at the pump should not be higher than 5cSt
5.4
Type of oil
#6 max
#6 min
#5 max
#5 min
#4 max
#4 min
#2 max
2200
220
165
32.1
20.7
6.9
3.5
Other Viscosities
At C
Water
Air
Natural gas
1.124
0.0180
0.011
(cp)
1.130
14.69
14.92
(cs)
Approximate viscosity of water at 21C is 1 cp and 1 cs
4. Waste Fuel
a) Waste Fuel Specification
Heat Content
<
Ash content
<
Specific gravity
Suspended solids
Water
Total halogens
Sulphur
Nitrogen
Inorganic acids and bases
Barium
Chromium
Lead
Zinc
Vanadium
PCB and PBB
Benzene
Odor
<
<
<
<
<
<
<
<
<
<
<
<
<
5.5
% Ash /
Moisture
1.0/5
3/5
20/30
5/10
10/25
5/70
5/70
5/85
3/10
Density
Lb/ft3
Kg/m3
50-60
801-961
7
112
10-15
160-240
62-125
8-10
8-10
15-20
30-35
45-55
35-50
20
993-2000
128-160
128-160
240-320
481-561
721-881
561-801
320
Tires are usually high volatile content and high S and Fe/Zn content (if steel belts are not removed).
Biomass fuels contain usually high level of moisture and O2 and may have a higher char reactivity than coal.
5. Natural Gas
a) Gas Characteristics
Typical example
CH4
C2H6
C3H8
C4H10 (ISO+N)
C5H10 (ISO+N)
S
CO2
N2
H2
He
O2
Total
Content (%)
93.93
2.42
0.26
0.002
0
0
0.34
3.05
0
0
0
LHV (Kcal/Nm3)
8,556
15,223
21,795
28,336
32,123
Sp weight (kg/Nm3)
0.7143
1.3393
1.9643
2.589
3.2143
8462
1.9643
1.2500
0.0893
0.1339
1.4286
0.7533
b) Combustion
C 5 H 12 + 8 O2 5 CO2 + 6 H 2 O
1
H 2 + O2 H 2 O
2
S + O2 SO2
5.6
Rule of thumb
9.412 Nm3/Nm3gas (for the example)
Neutral Combustion Products for natural gas
Nm3/Nm3 gas
0.999
0.000
1.962
7.466
10.426
CO2
SO2
H2O
N2
Total:
kg/Nm3 gas
1.962
0.000
1.576
9.332
12.871
% volume
9.58%
0.00%
18.81%
71.60%
% weight
15.25%
0.00%
12.25%
72.51%
6. Flame Theory
6.1 Definition
The oxidation reaction is an exothermic reaction, which can be developed either slowly or quickly: The fast
reaction leads to the flame.
In stable burner flames, the flame front appears to be stationary because the flame is moving toward the
burner at the same speed that the fuel air mixture is coming out of the burner.
Thus risk of blow off if mixture speed>flame speed.
Natural gas flame speed in air: 0.3m/s and in Oxygen: 4 to 5m/s.
R = T4
= Boltsman constant
T = Flame temperature
: flame intensity:
1 solid fuel
0.8 0.95 heavy oil
0.25 0.70 gas
5.7
Temperature Impact
% 02preheat temperature, F
Fuel Requirements
To provide 1 000 000 Btu of available
heat (fuel is CH4 and excess air=2%)
then for instance with air (21% O2) it
requires 4.6/2.3=2 times as much fuel
when preheat temp=500F as when
preheat is 1500F when flue gas
temperature is 3000F
7. Burner Pipes
For solid fuels, the number of air circuits determines the degree of control on the flame shape.
5.8
Semi-direct system
Primary air quantity varies (usually 18 to 25 %), depending upon the incoming fuel moisture.
To keep a constant flow (10 to 15 % of total combustion air), it is possible to send the "overflow" to the kiln
hood (for the direct or semi-direct system).
Primary air impact on heat consumption
Indirect
Semi-direct
Primary air
12%
20-25%
kcal/kg
4-5
20-25
Direct
30-35%
50
Tip velocity:
axial air
80 to 250 m/s
transport air
20 to 40 m/s
swirl air
50 to 250 m/s
gas
200 m/s
200 - 2000
2000 - 3500
Is = Characterizes approximately the primary/secondary air ratio irrespective of the kiln. Usually two thirds
or more of the primary air (non included transport air).
Momentum impulse:
where:
M *V
Is =
Q
- Q = ki ln ( heat power )inGJ .h 1
-
Rules of thumb
Specific impulse
Fuel Oil
Coal
Coke
Long Kilns
1,2 N.h.GJ-1
1,5 N.h.GJ-1
1,8 N.h.GJ-1
Short Kilns
1,2 N.h.GJ-1
1,5 N.h.GJ-1
1,8 N.h.GJ-1
5.9
7.5 Swirl
Swirl is the ratio of the tangential component produced by the rotational air to the sum of the axial
components Ix produced by the various primary air and gas circuits.
It improves the stability by forming toroidal recirculation zones that recirculate heat and species (when
Sw>0.3).
where:
Rotational moment / axial moment ratio
- I r = I xr t g
Vry
Rot. circ. velocity: Vr
Vrx
I r r g
SW =
I x . De
rg
where:
I r = Qmr . Vry
Ix =
I
i xi
De =
I : tangential impulsion
Rules of thumb
swirl
Fuel, coal, coke
Gas
Long Kilns
0,02 to 0.08
0,05
Short Kilns
0,12 to 0.15
0,05
Pillard Standard
Axial
Transport
Swirl
Gas
rotational circuit
2 expansion seals
Lafarge Burner
Axial
Transpor
t
Swirl
Gas
coal conveying
circuit
central air
(flame catcher)
5.10
Sep-99
218 m/s
Version 2.2
PLANT :
Date : 24/02/2000
Name
Apr-95
Diameters :
(mm)
320.7
291.7
36 m/s
196.7
172.8
71.6%
23 m/s
247.7
223.1
212 m/s
31 m/s
mm
56.2%
26 m/s
2500
1437
mm
Swirler
angle (o)
35
-
Number
of vanes
20
Number of holes :
slots
width(mm)
12.0
groove width
(mm)
9.800
355.6
9.525
273.1
12.7
219.1
8.179
141.3
6.553
radial gap
vanes(mm)
0.5
radius
raccord.
1
Diameter :
24
AS
14.50
2630.00
PRODUCTION (T CK /d ) :
70.26
2.03
3.09
3486.00
Dext :
thk :
mmWG
Nm/h
Dext :
thk :
Dext :
thk :
mmWG
Nm/h
Dext :
thk :
%O
NCA
Nm/kg fuel
Throughput
kg/h
4760
L.H.V.
KJ/kg
28087
5.43
B
65.00
6.96
Total (GJ/h ) :
GAS FLOW MEASUREMENTS
Static pressure in the tip (mm WG)
Temperature in the pipe ( deg C)
Theoretical flow rate ( Nm/h)
Bias coefficient :
Accepted flowrate ( Nm/h)
Axial
2667
100
2360
1.00
2360
Swirl
2500
100
1437
1.00
1437
62%
4.14
3486
kJ/kg CK
38%
860
RESULTS
FLOW VELOCITIES
Axial
Swirl
Swirl
36
Is
N.h/GJ
2.14
Fuel-Oil
Coal
Coke
1.2
1.5
1.8
0.15
0.15
0.15
Transport
subsonic
Nature of flow
Release tip velocity (m/s)
Primary air rate, axial
:
swirl :
transport :
Axial + Transport:
Primary air rate
subsonic
velocity
218
212
Targets:
6.78%
4.13%
2.47%
9.26%
13.39%
0.18
3.16
5.11
The Hardgrove Grindability Index (HGI) indicates the ease of grinding solid fuel.
A standard coal in the cement industry has a HGI of 65 or 76.
HGImix = x * HGI coal + y * HGI coke.
100
80
60
90% Raymond
85% Raymond
80% Raymond
75% Raymond
20
0.6
0.8
1.0
1.2
1.4
10
Combustion Temp.
= 900C
1
Combustion Temp.
= 1500C
.1
.01
.1
Diameter of coal particle (mm)
5.12
8.3 Dosing
Dosing should insure a regular and steady feeding of the burner. The targeted precision should be in the
range of 1% (see Les Cahiers Techniques Combustion). Coal concentration up to 7kg/m3 of air.
Recommendations
(to be adjusted plant by plant)
Sensor
Storage temperature, external, unpacted
Raw silo (lower base)
Raw silo (top) CO
Grinding mill outlet temp (coke)
Grinding mill outlet temp (Coal)
Mill inlet temp: (High VM : 40%)
Mill inlet temp: (Low VM : 20%)
Filter outlet O2 (coke)
Filter outlet (coal)
(sources: PyroI, modified 2000, RdeB)
Threshold
50C
50C
1500 ppm
120C
65C
200C
360C
15%
13%
Sensor
Filter outlet temp (coke)
Temp difference (outlet-inlet)
Temp difference variation
Filter outlet CO
Filter hopper temp (coke)
Pulverized hopper CO
Pulverized hopper temp
Fired fuel into the kiln (%H2O)
Transport air (non inert/inert) temp (Coal)
Threshold
105C
10C
10C
2000ppm
85C
1000ppm
85C
0.5-1.5%
65/85C
Feed size: 0-50mm, moisture content: 10-15%, exhaust gases dust load: 500-600g/m3.
Hot gases temperature 250-400C, dew point: 20-70C, exhaust gases temperature: 80-100C.
Moisture content in the blasted fuel below 1%.
Type of grinder
Hammer mill
Tube mill
Roller mill
Ring ball mill (Babcock)
kWh/t
20-30
25-30
10-13
Lifetime wear part
500-1000h
Liners: 25-40000h 3-5000 h
9-12000h
Drying capacity
0-15% H2O
0-15% H2O
0-20% H2O
Tube mill
Balls
Liners
Diaphragms
Life (h)
25-40000
10-20000
Rollermill
Roller liners
Table liners
Casting liners
Life (h)
4-9000
4-12000
2-12000
Rules of thumb:
Mill sweep : 1.7 to 2.2 Nm3/kg fuel
Drying efficiency : average 1200kcal/kgH2O for a residual moisture of 0.5 to 1.5%
5.13