}onailan Hemingway

Embiy-Riddle Aeionauiical Univeisiiy
Meniois: }oseiie Maiieio and Di. Don Blale
Why sample LA Alr?
• Aii qualiiy among woisi ciiies in ile US
(Ameiican Lung Assn.)
• Exceeds NAAQS foi ozone i:: days]yi
Ploio Ciedii: Fiancine Oii, Los Angeles Times
MounL Wllson Sampllng SlLe
! Elevaiion: -¸,yoo feei
! Miles away fiom majoi emission souices
! Allows mixing io occui
! Reduced inßuence fiom poini souice emissions
! Mucl cleapei io sample on ile giound
! Fliglis aie expensive
! Fuel, mainienance, aiiciew
! Simplei io sample fiom giound
CALnLx 2010
!"#"$%&'( !#"$%*'+
,-+./0102
3+/+
456.720
!89:0;/ %
Samples
41 40
Min
22.3 22.3
Max
1125.9 220.9
Average
59.4 32.7
StDev
173.6 31.7
,-+./0102
3+/+
456.720
!89:0;/ *
Samples
41 38
Min
91.0 91.0
Max
4066.0 1324.2
Average
407.4 228.4
StDev
742.6 260.8
Samples ialen ai vaiious LA Basin locaiions
Area of lnLeresL
MounL Wllson
Siolzenbacl ei al., :ooi
lly-8y Cans
¸ miles
Compounds
! Hydiocaibons
! Meilane
! Eilane
! i-Buiane
! n-Buiane
! Halocaibons
! HFC-i¸(a
! HCFC-::a
! HCFC-i(:b
! Clloiofoim
MounL Wllson Lo lllghL Sample 8auos
!"#$%&
()*+",
-&%)., /01+)., #234&)., .234&)., 5!62789) 56!62:: 56!6279:; 656"8
Fly-By
Aveiage
0.79 0.73 0.84 0.93 1.03 1.03 0.94 1.00
LA Basin
Moining
1.13 1.17 0.81 0.83 1.30 1.37 1.00 1.00
LA Basin
Afieinoon
1.40 1.23 0.86 0.83 1.38 1.32 1.01 1.19
LA Basin
Aveiage
1.23 1.19 0.83 0.83 1.33 1.43 1.00 1.08
Raiio = Mi. Wilson Sample ] Fligli Samples
Comparlson of concenLrauons
LA Basin beiween q:¸o am io io am PDT
Mouni Wilson sample ai (:oo pm PDT
o
¸oo
iooo
i¸oo
:ooo
:¸oo
Eilane Piopane i-Buiane n-Buiane
"
<
-
6
0
-
/
1
+
/
8
<
-

=
>
>
/
?

!@21<6+1(<-;
LA Basin Moining
Mouni Wilson
o
¸o
ioo
i¸o
:oo
:¸o
¸oo
¸¸o
(oo
(¸o
HFC-i¸(a HCFC-:: HCFC-i(:b CHCl¸
!+.<6+1(<-;
LA Basin Moining
Mouni Wilson
Comparlson of concenLrauons
LA Basin beiween q:¸o am io io am PDT and ¸:oo pm io ¸:i¸ pm PDT
Mouni Wilson sample ai (:oo pm PDT
o
¸oo
iooo
i¸oo
:ooo
:¸oo
Eilane Piopane i-Buiane n-Buiane
"
<
-
6
0
-
/
1
+
/
8
<
-

=
>
>
/
?

!@21<6+1(<-;
LA Basin Aveiage
Mouni Wilson
o
¸o
ioo
i¸o
:oo
:¸o
¸oo
¸¸o
(oo
(¸o
HFC-i¸(a HCFC-:: HCFC-i(:b CHCl¸
!+.<6+1(<-;
LA Basin Aveiage
Mouni Wilson
LlevaLed PlC-134a and PClC-22
! Refiigeianis in cai A]C sysiems
! Cool aggiegaies foi iefiigeiaiion iianspoii
liip:]]quiclmap.doi.ca.gov]
LlevaLed PlC-134a and PClC-22
! Refiigeianis in cai A]C sysiems
! Cool aggiegaies foi iefiigeiaiion iianspoii
liip:]]quiclmap.doi.ca.gov]
Comparlson of concenLrauons
LA Basin beiween q:¸o am io io am PDT and ¸:oo pm io ¸:i¸ pm PDT
Mouni Wilson sample ai (:oo pm PDT
o
¸oo
iooo
i¸oo
:ooo
:¸oo
Eilane Piopane i-Buiane n-Buiane
"
<
-
6
0
-
/
1
+
/
8
<
-

=
>
>
/
?

!@21<6+1(<-;
LA Basin Aveiage
Mouni Wilson
o
¸o
ioo
i¸o
:oo
:¸o
¸oo
¸¸o
(oo
(¸o
HFC-i¸(a HCFC-:: HCFC-i(:b CHCl¸
!+.<6+1(<-;
LA Basin Aveiage
Mouni Wilson
LlevaLed LLhane and Þropane
liip:]]maps.conseivaiion.ca.gov]doggi]index.liml=close
LlevaLed LLhane and Þropane
liip:]]maps.conseivaiion.ca.gov]doggi]index.liml=close
ulscusslon of 8esulLs
! Was noi expeciing iaiios neai i
! Expeciing iaiios neai : io ¸ ai besi
! Consideiaiions
! Only a poiiion of LA Basin was sampled
! Inconsisieni sampling aliiiudes
Concluslon
! Ii woiled!... Kind of
! Moie sampling needed
! Moie in-depil siudy necessaiy
! Eniiie LA Basin
! Consisieni Sampling Aliiiude
! Higlei Resoluiion Mouni Wilson Samples
AcknowledgmenLs
! Di. Donald Blale
! }oseiie Maiieio
! Di. Emily Sclallei
! Ricl Sleiiei
! NASA
! NSERC
! UND
! WAS Gioup
Cuesuons?

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