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Title: Started: Submitted: Time spent: Chapter 16(1) September 27, 2009 5:56 PM September 27, 2009 6:31 PM 00:34:59 Total score adjusted by 0.0 Maximum possible score: 12

Total score: 12/12 = 100% 1. Average Rate 4

The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In one experiment, [AX2] was measured at various times, and these data recorded: Time (s) 0 2.0 6.0 8.0 10.0 20.0 [AX2] mol/L 0.0500 0.0448 0.0300 0.0249 0.0209 0.0088

What is the average rate from 2.0 to 6.0 seconds in mol / L s? Use 3 significant figures. [don't include units in your answer; if you want to use scientific notation, use the E format. e.g., 0.0011 is 1.1E-3

Student Response 1. 3.7E-3

Value 100%

Correct Answer Equals 0.0037 (0%) Equals 3.7E-3 (100%) Contains .0037 (100%) Equals 3.70E-3 (100%)

Score:

1/1

2.

Relative Rates of Substances 17 Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [H] is increasing at 0.47 mol/Ls, how quickly is [D] decreasing?

Student Response Answer .94 Score: 1/1

Value 100%

3.

Rate Law General 6 What is the overall reaction order for Cl2 in a reaction with the following rate law? Rate = k[Cl2][H+]2[CO]2

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Student Value Response 1. First 2. Second 3. Third 4. Fourth 5. Fifth Score: 1/1 100% 0% 0% 0% 0%

4.

Known Rate Law Change Conc 54 For the reaction, A(g) + B(g) => AB(g), the rate is 0.750 mol/L.s when the initial concentrations of both A and B are 2.00 mol/L. If the reaction is first order in A and first order in B, what is the rate when the initial concentration of A = 3.72 mol/L and that of B = 2.69 mol/L (give answers in E notation to 3 significant figures)

Student Response Answer 1.88 Score: 1/1

Value 100%

5.

Known Rate Law, Change Conc 26 Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2 By what factor does the rate change if the concentration of BrO3- is doubled and that of Br- is tripled? Just put in the number as a whole number or fraction.

Student Response 1. 6

Value 100%

Correct Answer Equals 6 (100%) Equals 6/1 (100%)

Score:

1/1

6.

Determine Rate Law 33 Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.----order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! : Experiment 1 2 Initial conc of A, mol/L 0.1 0.2 Initial conc of B, mol/L 0.2 0.2 Initial conc of C, mol/L 0.4 0.4 Initial rate, mol/L.s 2 x 10-3 8 x 10-3

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3 4

0.3 0.4

0.4 0.6

0.4 0.2

3.6 x 10-2 9.6 x 10-2

Student Response 1. second 2. first 3. zero 4. third Score: 1/1

Value 25% 25% 25% 25%

Correct Answer Equals second (25%) Equals first (25%) Equals zero (25%) Equals third (25%)

7.

Determine Rate Law 7 Consider the reaction of A(g) + B(g) + C(g) => D(g) for which the following data were obtained: Experiment 1 2 3 4 Initial [A], mol/L 0.0500 0.100 0.100 0.0500 Initial [B], mol/L 0.0500 0.0500 0.100 0.0500 Initial [C], mol/L 0.0100 0.0100 0.0100 0.0200 Initial rate, mol/L.s 6.25 x 10-3 2.50 x 10-2 1.00 x 10-1 1.25 x 10-2

What is the rate law for the reaction?

Student Response 1. rate = k[A][B][C]

Value 0%

Feedback

2. rate = 100% 2 2 k[A] [B] [C] 3. rate = 0% 2 k[A] [B][C] 4. rate = k[A]2[B]2 5. rate = k[A][B] Score: 1/1 0% 0%

8.

Calculate k from Rate Law 36 Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, Experiment Initial conc of A, mol/L Initial conc of B, mol/L Initial conc of C, mol/L Initial rate, mol/L.s

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1 2 3 4

0.1 0.2 0.3 0.4

0.2 0.2 0.4 0.6

0.4 0.4 0.4 0.2

2 x 10-3 4 x 10-3 2.4 x 10-2 3.6 x 10-2

Calculate the value of k to 3 significant figures and do not use scientific notation!

Student Response 1. 1.25 Score: 1/1

Value 100%

9.

Units of k 1 Which of the following would be a reasonable unit for the rate constant of a first order reaction?

Student Response 1. mol/L.sec
2 2

Value 0% 100% 0%

Feedback

2. mol /sec.L 0% 3. 1/sec 4. L/mol.sec

5. L2/mol2.sec 0% Score: 1/1

10. IRL 1 t 1 In a first order decomposition in which the rate constant is 0.0780 sec-1, how long will it take (in seconds) until 0.207 mol/L of the compound is left, if there was 0.821 mol/L at the start? (give answer to 3 sig figs using E notation)?

Student Response Answer 1.77E1 Score: 1/1

Value 100%

11. IRL 1 kt % 2 In a first order decomposition, the constant is 0.00354 sec-1. What percentage of the compound has decomposed after 43.3 seconds?

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Student Response Answer 14.2 Score: 1/1

Value 100%

12. IRL 1 k 1 When 0.990 mol/L of a compound X decomposes via a first order reaction, there are 0.360 mol/L left after 66.3 seconds. Calculate the rate constant, k, in sec-1.

Student Response Answer .0153 Score: 1/1

Value 100%