Professional Documents
Culture Documents
REPORT ON
INDUSTRIAL TRAINING
AT
NARMADA CLEAN TECH LTD (NCTL)
ANKLESHWAR
Submitted by:
Sagar Divetiya
Enroll no. 110990135013
Academic year 2014- 2015
Guided by (Industry):
Mr. Dharmesh D. Shah
Senior manager
NCTL, Ankleshwar
Guided by (College):
Mrs. Pratibha Gautam
Assistant professor (DEST)
SRICT, Vataria.
Submitted to:
Mr. Manoj Kumar
Head of Department
Department of Environmental Science & Technology (DEST)
Shroff S. R. Rotary Institute of Chemical Technology
Vataria, Ankleshwar, Gujarat
A c k n o w l e d g e me n t P a g e | 2
Acknowledgement
Success of any training depends on the dedication and sincere hard work. It also requires
some essential like motivation, guidelines, encouragement, positive attitude, good
observation and time.
We would like to express our gratitude to Mr. K. R. Desai (C.E.O., NCTL) and Mr.
Paresh T. Sarvan (D.G.M.,NCTL) for giving us the opportunity to pursue the engineering
training at Narmada clean technology limited as a partial fulfilment of the requirement for the
degree of Bachelor of Engineering (Environmental Science and Technology).
We would like to thank Mr. Dharmesh D. Shah, (Sr. manager NCTL) without whom
the project would not have literally seen light of the day. He has given us a taste of real flavor
of engineering and industrial environment. Besides our lacking basic knowledge and skills,
he made it possible for us to polish our some of the weaknesses and directed us to minimize
the gap between theory and practical knowledge and skills. He has shared his knowledge and
experiences to enhance our understanding about actual scenarios and practices carried out in
industries to sustain in this competitive and ever-changing world. He has given us tasks in
form of question to put our brain on work that has created a huge impact on our
brainstorming capabilities. He has answered our reasonable question very precisely.
Mr. Pratik Patel (executive, monitoring & process audit, NCTL) being our mentor and
instructor helped and guided us in various ways to carry out our industrial training. He
provided us sufficient information about NCTL.
We would also like to mention that Mr. Shaktisinh Maharaul (QCD Executive,
NCTL) was the one who has helped and guided us in understanding facts, data and quality of
wastewater. He has induced us to perform analysis of effluent samples at NCTL laboratory.
We would like to thank Mrs. Megha Patel as well as all the chemist and analyst at
NCTL Mr. Girish J. Chavda, Mr. Manish h. Gandhi, Mr. Rajesh V. Patel, Mr. Prakash P.
Patel, Mr. Ajay P. Patel and Mr. Gaurang A. Patel for their extraordinary support and for
guiding us for analysis of wastewater samples.
Mr. N. J. Nathani explained us the plant and gave us troubleshooting problems to
understand the operation control of the plant. Mr. Sachin Bhatt explained us the operation of
newly established filter press for sludge dewatering.
We are thankful to each executives, technicians, operators of the facility for their help,
extraordinary support and kindness.
We are also thanking full to our Dr. Snehal Lokhandwala (Training and Placement In
charge, HOD of MSH dept.), Mr. Manoj Kumar (HOD of EST Dept.) and Mrs. Pratibha
Gautam (EST Dept.) from Shroff S.R. Rotary institute of chemical technology by whom we
were inspired to complete the industrial training for one month.
Finally we apologize all other unnamed who helped us in various ways to have a good
training.
A b s t r a c t P a g e | 3
Abstract
Common Effluent Treatment Plants (CETP) has become necessary for managing and treating
industrial wastewater in environmentally sound manner. Narmada clean tech ltd (NCTL) is a
type of CETP called Final Effluent Treatment Plant (FETP) since the industrial wastewater of
Ankleshwar, Panoli and Jaghadia is treated just before discharging into the ocean at the
FETP.
It is a great experience to get trained under such big unit. FETP, NCTL is the place to have a
taste of conventional treatment methods.
The prime purpose of this training was to identify and understand the real life
practical scenarios. Purpose was fulfilled up to great extent. Ultimately our knowledge and
skills are improved. Each day some task are given to practically understand the plant. It is an
extraordinary opportunity to experience practical industrial environment, work discipline,
team work, time management, quality controlling and to obtain a clear understanding of the
theoretical knowledge which was gathered at the university.
Industrial training report is prepared to present the knowledge gained throughout the
training. The report precisely represents the major tasks given and their reasonable
conclusions. The report elucidates the real practical experience and deviation from ideal
theories. Reader may find it comprehensive by first view but the report consists of concise
conclusions of all the witnessed conditions.
In one month training, approach taken by guide was very distinctive. So the module
followed was extremely helpful for understanding the technical as well as administrative
aspects of industry. The knowledge gain will be invaluable in near future.
The conventional technologies like Activated sludge process has been understood
thoroughly. But the care had taken to deliver the sufficient knowledge of fields other than
environment. As an environmental technologist FETP is the heaven. Basic design
calculations and troubleshooting has given very firm background for further education and
even for career.
I n d e x P a g e | 4
Index
Sections
1. Introduction to CETPs
2. NCTL overview
3. Process description
4. Environmental management at NCTL
5. Safety at NCTL
6. Equipment used
7. Analytical laboratory at NCTL
7.1 Overview
7.2 List of analytical instruments
7.3 Analysis of parameters
8. Tasks performed
8.1 On field task
8.2 Off field literary task
8.3 Lab task
9. Learning outcomes
10. Enhancements at NCTL
11. References
12. Conclusion
Page
6
8
9
13
14
15
18
23
34
36
38
39
I n d e x P a g e | 5
Table Index
Tables
Table-1: Inlet measured parameters at NCTL
Table-2: Places at NCTL where lighting arrestors are installed
Table-3: Comparison between pre-primary, primary, secondary clarifiers
Table-4: Levels of wastewater treatment
Page
10
14
24
25
Figure Index
Figures
Figure-1: NCTL Process Flow Diagram
Figure-2: Pre-Primary Clarifier
Figure-3: Surface Aspirators
Figure-4: Surface Aspirators working
Figure-5: Decanter
Figure-6: Decanter working
Figure-7: Filter press
Figure-8: Sludge dewatered cake
Figure-9: Filter press working
Figure-10: Ammonical Nitrogen analysis
Figure-11: Three phases of microbial growth
Page
9
11
15
15
15
15
16
16
16
20
32
1 | I n t r o d u c t i o n t o C E T P s P a g e | 6
1. Introduction to Common Effluent Treatment Pants (CETPs)
1.1 Concept of CETP
Common Effluent Treatment Plant is the concept of treating effluents by means of a
collective effort mainly for a cluster of small scale industrial units. This concept is similar to
the concept of Municipal Corporation treating sewage of all the individual houses.
CETP was promoted by MoEF (Ministry of Environment and Forest) in 1984 to treat
waste water from small and medium scale industries sector (SMIs). First CETP was
constructed in 1985 in Jeedimelta near Hyderabad. CETP was followed by other states in TN,
MP, Gujarat, and Maharastra. A bulk environmental pollution is caused by SMIs small scale
industries policy has no thought for environmental planning. For the effluent from SSIs the
concept of CETP was introduced. The MOEF has instructed the SPCB (State Pollution
Control Board) to established CETP in different industrial estates in respective states. It said
that the central will provide up to 25% of the total cost of CETP and the remaining should be
contributed by state Govt. and industries.
1.2 Need of CETP
To minimize environmental pollution due to the small and medium scale industries.
Cleaner production technologies
Waste minimization methods and centers.
Collective treatment at a centralized facility, called as the CETP is a viable treatment
solution.
1.3 Advantages of CETP
Facilitates economy of scale in waste treatment
Addresses the lack of space issue
Homogenization of wastewater
Better hydraulic stability
Professional control
Facilitates small scale units
Eliminates multiple discharges
Recycling and reuse
Organization of treated effluent and sludge disposal
1 | I n t r o d u c t i o n t o C E T P s P a g e | 7
1.4 Problems and constraints
Consistency in operation
lack of access to
o capital investments
o working capitals
o specialized technical skills
inconsistent effluent quality from member industries
improper management of treatment units
Varied nature and scale of the industries, along with the addition of industries in a
haphazard manner, without proper planning
No provision to tackle the fluctuations in the pollution load and quantities, at
individual member industries no separate treatment units to deal with hazardous
and toxic effluents, etc.
1.5 Influencing factors in Planning of CETPs
Categories of effluent generating member industries
Qualitative/quantitative fluctuations of effluent (equalization/ homogenization
/modules)
Pretreatment requirements
Segregation of effluent streams at individual member industry
Collection and monitoring mechanism
Treatability choice of technology and bio degradability, interferences
Mode of disposal
Charging system
1.6 General Process of Common Effluent Treatment:
Preliminary treatment - It involves a number of unit processes to eliminate
undesirable characteristics of wastewater. Processes include use of screen, grit
chambers for removal of sand and large particles, communitors for grinding of
coarse solids, pre-aeration for odour control and removal of oil and grease.
Primary treatment- It involves removal of settable solids prior to biological
treatment. The general treatment units include: flash mixer + Flocculator +
sedimentation.
Secondary treatment- It involves purification of wastewater primarily with
dissolved organic matter by microbial action. A number of processes are available
but the ones that are mainly used are anaerobic and /or aerobic treatment methods.
Tertiary treatment - This mainly includes physical and chemical treatment
processes that can be used after the biological treatment to meet the treatment
objectives.
2 | N C T L O v e r v i e w P a g e | 8
2. NCTL Overview
Narmada Clean Tech Ltd. (NCTL) formerly known as Bharuch Eco Aqua Infrastructure Ltd.
(BEAIL) is a company, subsidiary of Gujarat Industrial Development Corporation (GIDC)
and jointly promoted by Member Industries of Ankleshwar, Jhagadia and Panoli Industrial
Estates. The objective is to receive the industrial effluent from Ankleshwar, Jhagadia &
Panoli Industrial Estates and to polish it at Final Effluent Treatment Plant (FETP) up to
marine standards and then to convey deep into the sea. VC & MD - GIDC is the Chairman of
NCTL.
Ever since the issues of Environment Protection become a priority agenda across the
world, Indian government & Gujarat government has joined the international community in
its commitment towards Environment Protection Program. The priority accorded to control of
Environmental pollution is evident from the number of pollution control acts enacted along
with rules and regulations. Keeping the spirit and intent of these policies, implementation at
ground level is the major challenge.
Prior to commencement of this project, treated effluent from three industrial estates
were disposing off into a natural creek namely Amlakhadi leading to Narmada Estuary.
Objection was raised by local population and NGOs against disposal of effluent and
subsequently High court has intervened and directed to stop the disposal of effluent into
Amlakhadi. Afterwards in high level Committee Meeting chaired by ACS, it was decided to
treat effluent up to marine standard and to release into Gulf of Khambhat beyond Narmada
Estuarine Zone. NCTL was set up to honor the directives given by the High Court.
The Final Effluent Treatment Plant (FETP) is spread over more than 3, 00,000 sq.
meters of land, has treatment capacity of 75,000 m
3
per day. More than 38000 trees are
planted to cover bare land. Facility was commissioned in December, 2006 at the cost of 131
crores to treat 40000 m
3
per day of effluent using conventional biological treatment. Facility
was enhanced by 20000 m
3
per day at an additional cost of 32 crores taking total project cost
to 167 crores. The continual improvement projects includes addition of preprimary clarifies
to reduce carryover of suspended solids, installation of additional decanters for solid removal,
installation of culture tank for sustainable development of microbes, etc. Technical &
Economic viability of other technologies to reduce COD namely Electro coagulation,
ozonation, Ultrasonic sound, RO, etc. are in progress.
NCTL has two departments for Sampling and Analysis:
1. Monitoring Department
2. Analysis Department
The Monitoring Department Collects Samples from Member industries. Coding of
these Samples is done so that the Analysis Department, while Analysis, could not identify the
sample. After Analysis, Samples are decoded. According to the parameters of the industries,
they are charged. They also match the readings of inlet to the plant with the outlet of the
2 | N C T L O v e r v i e w P a g e | 9
industries (i.e. differences experienced within the path from industries to the plant) for
checking purpose.
3 | P r o c e s s D e s c r i p t i o n P a g e | 10
3. Process Description
NCTL has a Final Effluent Treatment Plant which consists of the neutralization system,
clarification system, aeration system for biological oxidation of organic matter, guard pond &
pumping system after the effluent is being treated to some other Effluent treatment Plant.
3.1 Process Flow Diagram of NCTL
Figure-1: NCTL Process Flow Diagram
3.2 Inlet chamber
3 | P r o c e s s D e s c r i p t i o n P a g e | 11
Effluent from three industrial estates Ankleshwar, Panoli and Jhagadia comes to NCTL for
their final discharge to sea. Here two parameters are kept under consideration, pH and
temperature of the Effluent. Three different Flow Meters have been installed at NCTL for
continuous Flow measurement into the plant.
Table-1: Inlet measured parameters at NCTL
Parameters Ankleshwar Panoli Jhagadia
Flow (MLD) 41.1 6.5 7.4
pH 6.59 7.32 6.94
Temperature (c) 28 33.6 25
(These are the parameters measured on date: 10/06/2014)
Acidic Effluent can cause harm to the plant in form of corrosiveness and other factors.
This, it is tried to keep the pH in almost Neutral condition (pH: 7-8). Provisions for
neutralization are Lime dosing and caustic treatment. Usually Lime dosing is done to the
Effluent, but in cases of lower pH or highly acidic Effluent, Caustic treatment is applied for
immediate pH control.
3.3 Screens
The pipelines coming from the three Estates Ankleshwar, Panoli and Jhagadia are open
pipelines. There are chances of larger particles to flow to the plant with the flow of the
effluent. To prevent these particles from entering the clarifiers, Screens are installed after the
Inlet Chamber.
3.4 Flash mixture
The Effluent after passing through the Screens is free of larger foreign particles which then
reach the Flash Mixture. Here the effluent received is divided and passed to the four Pre-
Primary Clarifiers.
3.5 Flocculator
There is one flocculation Tank for each pre-primary clarifier. The effluent passes from Flash
Mixture to the pre-primary clarifier via flocculator. Here addition of coagulant/ flocculent is
done. At NCTL, Poly Electrolyte is used to serve this purpose.
3.6 Pre-primary clarifier
The inlet of a pre-primary Clarifier is from the top as shown in the figure below. Pre-primary
circular clarifiers are designed to receive raw wastewater after it has been pre-screened to
remove large objects and grit. The sludge settled at the bottom of the pre-primary clarifier is
pumped out at regular intervals and sent to sludge thickener and then to the decanter or filter
press for de-watering purpose.
3 | P r o c e s s D e s c r i p t i o n P a g e | 12
Figure-2: Pre-Primary Clarifier
3.7 Equalization Tank
There are two Equalization tank at NCTL each of Flow rate 20MLD and Capacity 12512 KL.
It is required to make all the parameters uniform throughout the effluent and to maintain the
Sock load. In the previous Plant, before the Expansion up to 60 MLD from 40 MLD, the
Equalization tank served the purpose of removal of some parts of Suspended Solids by
overflow from one tank to another via rectangular weirs. The leachate generated as a result of
dewatering is sent to the Equalization tank for further treatment.
3.8 Primary Clarifier
From here, the effluent flows in three parallel series namely A-series, B-series and C-series.
Three Primary Clarifier are there at NCTL, before expansion of the plant, form 40 MLD to 60
MLD, these were the first Clarifiers to receive the effluent. The effluent used to come from
inlet via Equalization Tank. After expansion, most of the solids are settled down at the pre-
primary Clarifiers. At primary Clarifier, rests of the solids are made to settle down so as to
proceed towards the secondary treatment. The sludge obtained at the bottom of the Primary
Clarifier is pumped out at regular intervals and sent to sludge thickener and then to the
Decanter for De-watering purpose.
3.9 Culture Tank
NCTL is having Culture tank which is used for the growth of microbes. Culture tank helps
replacing some of the MLVSS in following activated sludge process when needed. In The
Culture tank Spent wash or Jaggery from sugar industries is added as food and oxygen is
dissolved in the tank. The microbes developed at a culture tank where they get acclimatized
by giving them some exposer to the effluent. At culture tank, the ratio BOD : N : P = 20 : 1 :
5 is maintained and also a fixed ratio of fresh water to that of the effluent and spent wash or
jaggery is maintained for microbes growth. Nutrient phosphorous is added in form of
3 | P r o c e s s D e s c r i p t i o n P a g e | 13
phosphoric acid since microbe need nutrient like phosphorous and nitrogen for new cell
synthesis. But nitrogen is sufficient in wastewater introduced so it is not added externally.
3.10 Aeration Tank
There are in total 11 Aeration Tanks Available at NCTL as can be seen in the Process Flow
Diagram. From the 4 tanks available each in A and B series, the first two are not used for
Aeration purpose, similarly, the first tank out of three of C series is also not used for Aeration
Purpose. Effluent is filled in those tanks because the required BOD is obtained after the
aeration in rest two tanks. Here microbes are introduced to influent which oxidizes the
organics and ultimately reduces the BOD of wastewater.
Initially Blowers were installed to serve the purpose. The high pressure air was blown
from blowers to the diffusers installed at the bottom of the Aeration Tanks.
The Blower system was changed to the Surface aspirators. These are floating aeration
devices which are better than diffusers at aeration and mixing to serve the purpose required at
NCTL.
3.11 Secondary Clarifier
There are Four Secondary Clarifiers at NCTL. One each for A and B series and two for C
series making approximately same capacity of that of A or B series. Separation of MLSS is
done in a secondary clarifier which operates in the same manner as the primary clarifier
described previously. Some of the solids collected in the secondary clarifier (return activated
sludge) are sent back to the aeration tank to treat more wastewater and the excess (waste
activated sludge) is pumped out to thickeners and sent for final disposal. The effluent water
that flows out the top of the clarifier is sent along for guard pond and then final discharge
sump.
3.12 Guard pond
Guard pond with 24 hrs detention time is provided to hold effluent in case of discharge
delays. The water from Secondary Clarifiers of each series comes to the Guard Pond. Initially
only one guard pond was there to satisfy with the needs according to the 40 MLD plant, later
on with further expansion of 20 MLD more, another pond was created besides the initial
guard pond.
3.13 Final sump and discharge
The final treated effluent is collected in sump from where it is discharged deep into the sea
with the help of 44 km long onshore & 10 km long offshore pipe line through scientifically
designed diffuser. At marine outfall point maximum 235 and minimum 175 times dilution is
available since dispersion rate is too high. Treated effluent is monitored with the help of
3 | P r o c e s s D e s c r i p t i o n P a g e | 14
online pH meter, TOC analyzer and flow meter before being finally discharged. Composite
sample analysis is made to ensure compliance to marine standard.
4 | E n v i r o n me n t a l Ma n a g e me n t a t N C T L P a g e | 15
4. Environmental Management at NCTL
1. Since NCTL is an End of the Pipe Treatment, prevention of waste is not waste
generation is not possible on its part.
2. No recycling, No segregation and No reduction of waste occur.
3. NCTL was planned according to inlet parameter of 1000 mg/l COD, but actual inlet
exceeded that. To comply with the situation, flow meters were installed at the outlet
of each member industry and all parameters are analyzed by NCTL, GPCB and Third
Party.
4. Surface aerators were installed to reduce the BOD of waste water which ultimately
reduced the COD from 1000 mg/l to 500mg/l.
5. The efficiency of Diffuser decreases with time. To meet the consequences, Surface
Aerators were installed.
6. Deep sea discharge of effluent via diffuser is done and Institutes like NIO (National
Institute of Oceanography) check and monitor the diffusion and dilution of effluent on
regular intervals. Minimum dilution of 175 times and maximum dilution of 235 times
is noted to occur.
7. Energy Management
a. Gravity
b. VFD
8. Re-use
a. SAC instead of PAC
b. Sugar fact waste used as biomass
9. The sludge generated at the end of clarification process is dewatered and sent to BEIL
(Bharuch Enviro Infrastructure Limited) for final disposal.
10. Continuous monitoring of noise is done.
5 | S a f e t y a t N C T L P a g e | 16
5. Safety at NCTL
1. Safety in lab: Hand gloves, Shoes, Goggles, Lab Coat
2. More Safety Required At Aeration Tank
3. Lighting arrestors at top of buildings
Table-2: Places at NCTL where lighting arrestors are installed
Sr.
No.
Place Range
1 Adm 5-10 m
2 Old blower house 5-10 m
3 FPH area 5-10 m
4 New Blower
House
5-10 m
Sr.
No.
Place Range
5 EPH 5-10 m
6 DG, Storage area 100 m
7 Tert. Decanter
house
100m
8 NCR 100m
4. Electric lines were previously underground for safety purpose now they are over head
5. Fire Alarm (Accident Alarm), Tuesday 11:00 am alarm is tested
6. Assembly points in case of emergency
7. Life jackets for tanks and aspirators Maintenance
8. Life Ring at all tanks
9. Crane for aspirator removal/ installation
10. Boat for Aerator Maintenance
11. MSDS for all chemicals at Lab (Material Safety Data Sheet)
12. Dyke area surrounding tanks
13. Earth pits checked each 12 months
14. Motor covers and coupling guards
15. Wind sock for wind direction in case of fire
16. Lime dosing safety PPE: Boots, Apron, Mask
17. Safety Showers
18. Fire Extinguisher and Sand Buckets for fire
19. First Aid Box
20. Monthly safety training for workers
21. Total body checkup per year
22. Every Friday doctor arrives for minor check ups
6 | E q u i p me n t u s e d P a g e | 17
6. Equipment used
6.1 Pumps
NCTL has installed centrifugal as well as piston pumps for various pumping purposes.
6.2 Aspirators
Aspirators are used as surface aerator in the aeration tank unit. It operates by creating a partial
vacuum under the water, drawing air through the shaft and dispersing the oxygen into the
water in a horizontal direction.
Figure-3: Surface Aspirators Figure-4: Surface Aspirators working
6.3 Decanters
Decanters are devices which is used for the separation of dry solids from the sludge
and each decanter separate 5 to 6 ton dry solids in one day. Poly dosing is done to bind the
sludge for better sludge dewatering.
Figure-5: Decanter Figure-6: Decanter working
6 | E q u i p me n t u s e d P a g e | 18
6.4 Filter Press
Figure-7: Filter press Figure-8: Sludge dewatered cake
A filter comprises a set of vertical, juxtaposed recessed plates, presses against each
other by hydraulic jacks at one end of the set. The pressure applied to the joint face of each
filtering plate must withstand the chamber internal pressure developed by the sludge pumping
system. This vertical plate layout forms watertight filtration chambers allowing easy
mechanization for the discharge of cakes. Filter clothes finely or tightly meshed are applied
to the two grooved surfaces in these plates.
Orifices feed the sludge to be filtered under pressure in the filtration chamber. They
are usually placed in the center of the plates allowing a proper distribution of flow, right
pressure and better drainage of sludge within the chamber. Solids sludge gradually
accumulates in the filtration chamber until the final compacted cake is formed. The filtrate is
collected at the back of the filtration support and carried away by internal ducts.
The filter press is an intermittent dewatering process. Each press operation includes
the following steps:
1. Closing of the press: as the filter is completely empty, the moving head activated by
the jacks clamps the plates. Closing pressure is self-regulated through filtration.
2. Filling: During this short phase chamber are filled with sludge for filtration. Filling
time depends on the flow of the feed pump. For sludge having good filterability it is
Figure-9: Filter press working
6 | E q u i p me n t u s e d P a g e | 19
best to fill the filter very quickly so as to avoid the formation of a cake in the first
chamber before the last ones have been filled.
3. Filtration: Once the chamber have been filled continuous arrival of sludge to be
dewatered provokes a rise in pressure due to the formation of an increasingly thick
layer of filter sludge on the cloths. This filtration phase can be stopped manually, by a
timer or more conveniently by a filtrate flow indicator which issues a stop alarm when
the end of filtration rate has been reached. When the filtration pump has stopped, the
filtrate circuits and central duct, which is still filled with liquid sludge, are purged by
compressed air.
4. Filter opening: The moving head is drawn back to disengage the first filtration
chamber. The cake falls has a result of his own weight. A mechanized system pulls
out the plates one by one. The speed of plate separation can be adjusted to account to
the cake texture.
5. Washing: Washing of clothes should be carried out every 15-30 processing
operations. For mid or large units this take place on press using water sprayers at very
high pressure (80-100 bar). Washing is synchronized with separation of plates.
The production capacity of a filter press is somewhere between 1.5 and 10 kg of solid
per m
2
of filtering surface. For every the filter press model the chamber volume and the
filtering surface depend on the number of plates in the filter.
In practical terms pressing times are less than four hours filtration time depends on:
cake thickness
sludge concentration
specific resistance
compressibility coefficient.
One of the advantages of the filer press is that it can accept sludge with average
filterability. It is always advantageous to optimally thicken sludge before filter press
operations. Although sludge presenting a high filterability enables better production
capacities, a filter press still accepts sludge with low conditioning precision. This tolerance
means that the device offers greater overall operational safety.
The filter press is suitable for almost all types of sludge:
Hydrophilic organic sludge: inorganic conditioning is often recommended to enable
satisfactory cake release due to minimal adherence to filter cloth.
Hydrophilic inorganic sludge: the filer press generally requires the addition of lime
only.
Hydrophobic inorganic sludge: it is very dense and ideal for the filter press. It is
dewatered without any preliminary conditioning.
Oily sludge: the filter press can be used to treat sludge containing light oils, the
presence of grease can sometimes impair the smooth running of the filter; clothes
have to be degreased at frequent intervals.
6 | E q u i p me n t u s e d P a g e | 20
NCTL is also having filter press which is used for the same purpose as the Decanter.
But it is more efficient compare to decanter because of it gives best result and less time
require for the separation. It removes 4 to5 ton dry solids in an operation and time is required
8 hours.
7. Analytical laboratory at NCTL
7.1 Overview
NCTL has equipped analytical laboratory that analyzes around 80 samples a day of
plant itself and of member industries. A very skilled chemist staff is analyses around 20
parameters and they follow the GPCB standard manuals for analysis of wastewater. Data
management of the laboratory is appreciable. We have done some of the analysis by
ourselves then we came to know some of the practices adopted by chemists for accurate
readings.
7.2 List of Analytical instruments
7.2.1 Atomic Absorption Spectrometer
7.2.2 Ultraviolet spectrometer
7.2.3 Total Organic Carbon(TOC) analyzer
7.2.4 Flow meters
7.2.5 pH meters
7.2.6 TDS meters
7.2.7 DO meter
7.2.8 Noise level indicator
7.2.9 Oxidation Reduction Potential meter
7.3 Analysis of parameters
Following are the parameters which are analyzed at the NCTL lab. We have focused on some
of the most important parameters. Detailing all the parameters is beyond the scope of this
report but still we have mentioned some of the key points that we have got during analysis
mentioned.
Some of the important focused parameters
7.3.1 Chemical Oxygen Demand (COD)
COD analysis is the most important analysis of wastewater. We have done the analysis of
whole set from top to bottom.
Principle
7 | A n a l y t i c a l l a b o r a t o r y a t N C T L P a g e | 21
In this experiment we calculate the oxygen consumed by the chemicals in terms of
oxidation agent used.
Generally we use potassium permagnent as oxidization agent but in COD test we
use potassium dichromate as oxidization agent because it have excellent quality of
oxidizing the organic matter.
In this test organic matter and oxidisable inorganic substances present in water get
oxidised completely by standard potassium dichromate in presence of sulphuric acid to
produce CO
2
+H
2
O given in equation (1).
The excess K
2
Cr
2
O
7
remaining after the reaction is titrated with ferrous
ammonium sulphate. The dichromate consumed gives the O
2
required for oxidation of
organic matter given in equation (2). The contents are refluxed for 2 hours.
C
n
H
a
O
b
N
c
+ d Cr
2
O
7
2-
+ (8d+c)H
+
nCO
2-
+ (a+8d-3c/2) H2O + cNH
+4
+ 2d Cr
+3
.
Where d= 2n/3+a/6+b/3-c/2.
6Fe
+2
+Cr
2
O
7
2-
+14H
+
6Fe
+3
+2Cr
+3
+7H
2
O
The low molecular fatty acid are not easily oxidized by dichromate so AgSO4
with sulphuric acid is used as catalyst for oxidizing of fatty acid because Ag+2 have
excellent catalytic property.
Inorganic interferences
Generally chloride ion in water sample generates interference in COD result. Cl
-
ion react with K
2
Cr
2
O
7
and gives higher inorganic COD in result. To prevent such
interference we use HgSO
4
(mercuric sulphate) to precipitate the excess of Cl
2
as HgCl
2
.
Hg
+2
+ 2Cl
-
= HgCl
2
Note:
The COD of any sample should be higher than its BOD.
The aromatic hydrocarbon and pyridines are not oxidizing under any
circumstance.
If the sample have high COD (above 800mg/L) so dilute it before
experiment.it can be known by instant colour change of sample orange to
green if it have high COD during addition of potassium dichromate solution in
given sample.
7.3.2 Ammoniacal Nitrogen
It is the parameter which is important from the point of view of nutrient for biological
reactors. Ammoniacal nitrogen in discharge may cause damage to aquatic life of ocean.
7 | A n a l y t i c a l l a b o r a t o r y a t N C T L P a g e | 22
Principle
The distillation method is used to separate the ammonia from interfering
substance and the measurement of ammoniacal nitrogen is done. Distillation avails the
nitrogen in the form of NH
3
at pH 4.5 this ammonia condensed is collected in absorbent
boric acid and then collected distillate is titrated against dilute acid.
Figure-10: Ammonical Nitrogen analysis
Note:
Use filtrate as sample for aeration so that aeration biomass does not interfere
If Boric acid and mixed indicator solution remains blue up to 150ml there is
not ammoniacal nitrogen present
If it turns green, ammoniacal nitrogen present then titrate it against 0.02N
Sulfuric acid.
Only when acidic sample comes, buffer is used otherwise not.
Wait up to 150ml after color is green.
Keep nozzle dipped into the solution so ammonia does not get to surrounding
if we are using beaker instead round bottom flask for absorbing solution.
7.3.3 Biochemical Oxygen Demand (BOD)
3day BOD method is employed for the measurement of BOD. Only plant samples are
analyzed for BOD. There are two incubators but only one is used having three trays,
every day one tray of samples is removed and one tray of samples is put into the
incubator. BOD data are used to determine the strength of wastewater through plant in
terms of oxygen required for stabilization of waste and for checking wastewater strength
from inlet to discharge.
The principle involved here is to fill the specific sized an airtight bottle with
diluted sample and incubate it at the specified temperature for three days or five days. DO
is measured initially and after incubation. The BOD is calculated from the difference
between initial and final.
7.3.4 pH, TDS, Turbidity, Colour and Odour
At first, these tests are carried out for any sample since they are primary tests. pH and
TDS both are determined by pH meter and TDS meter respectively. Both the meters are
calibrated daily. pH meter is calibrated with buffers of pH 4 and 9 replaced every day.
7 | A n a l y t i c a l l a b o r a t o r y a t N C T L P a g e | 23
And TDS meter is calibrated with standard KCL solutions replaced after 3 days. Turbidity
and colour are analyzed visually by observing in 100ml glass measuring cylinder. Odour
is also analyzed by smelling the sample.
7.3.5 TSS, MLSS, MLVSS
Suspended solids are analyzed by filtration and drying. For samples from member
industries vacuum filtration apparatus is used but for plant samples funnel filtration is
used. Whatman filter 41 is used for TSS analysis and Whatman filter 42 is used for MLSS
analysis. MLSS filtration takes 24 h and TSS filtration takes 8 h to filter. Samples from
activated sludge process is not directly used for other analysis but filtrate is used for
further analysis so the biomass does not interfere COD, BOD, Nitrogen etc. analysis.
Note:
Take initial and final weight of filter paper directly from desiccator otherwise
it will absorb so much moisture.
Whatman filter no.42 is denser than no.41 since it has less pores than no.41.
7.3.6 Oil and grease
Oil and grease analysis is done by to operation in sequence,
1. Solvent extraction
Solvent extraction is carried out in separating funnel using hexane as the
solvent. Oil and grease is extracted from the sample by the 50ml hexane in
two stages. Each by 25ml hexane. Grit is removed from the top and extract is
collected in conical flask.
2. Evaporation
Extract is pass through a filter having 10g anhydrous sodium sulphate to
absorb any water remained in extract and filtrate taken in initially dry
weighed beaker. Now evaporate all the solvent from the extract by heating on
hot plate. Difference between initial (dried) and final weight of beaker gives
oil and grease content of sample.
Some other parameters
7.3.7 Heavy metals
Atomic absorption spectroscope is used to determine the heavy metals present in sample.
7.3.8 Phosphate
Ultraviolet spectroscope is used to measure phosphate content of sample.
7.3.9 Sulphide
7.3.10 Phenolic content
Ultraviolet spectroscope is used to measure phosphate content of sample.
7 | A n a l y t i c a l l a b o r a t o r y a t N C T L P a g e | 24
7.3.11 Moisture content for sludge
Moisture content of sludge from decanter was 68 to 72% and from Filter press is 60 to
62%.
7.3.12 Sludge Volume Index (SVI)
Determine the suspended solids concentration of a well-mixed sample of the suspension.
Determine the 30 min settled sludge volume in a liter of graduated cylinder for a liter of
sample.
SVI (mL/g) =
(
7.3.13 SAC Quality & other chemicals used in plant action
Chemicals used in plant processes are also analyzed to determine the quality. One of them
is Spent Aluminum Chloride (SAC) which is the waste product from the other industry so
quality must be determined in order to evaluate the dosing in coagulation.
7.3.14 Toxicity test (fish tank)
Toxicity test is done by using fish tank having fishes sensitive to the toxic substances in
order to identify after dilution of discharge of plant in ocean it will have toxic effect on
the aquatic life or not.
8 | T a s k p e r f o r me d P a g e | 25
8. Task performed
8.1 On-Field Tasks
8.1.1 Observing the VFD for varying output voltage without power loss
A variable-frequency drive (VFD) (also termed adjustable-frequency drive, variable-
speed drive, AC drive, micro drive or inverter drive) is a type of adjustable-speed drive
used in electro-mechanical drive systems to control AC motor speed and torque by
varying motor input frequency and voltage. We have seen all the VFDs installed at
NCTL.
8.1.2 Few measures taken to lower the noise of fluid passing through pipes
Lower the bends and tangential flow when necessary
Fix the pipe with sufficient support and clamps to avoid vibrations
Decrease the pipe diameter where necessary to maintain same pressure
through out
8.1.3 Observe the actual RPM of clarifier rotating arm cycle
We have observe the actual RPM of clarifier rotating arm of primary and preprimary
clarifier and it is found to be primary clarifier arm is slightly faster than preprimary
because preprimary has full diameter are where else primary has half diameter arm.
8.1.4 Observing the foam appearance and its cause
We have observed the foam color of B-series tank was white one which was not normal
and it is found to be it is because of slightly low MLVSS. After three day when we went
back foam color was light tan which is the normal condition. Operator must have taken
corrective actions.
8.1.5 Observed the flow rate of monsoon and comment
When we have observed the flow rate when heavy rain has just appeared, the flow rate of
inlet gone too much higher than its desired value. It has one positive impact that influent
get diluted and all the parameter concentration get reduced but one negative impact is
system has to handle more than its design capacity. Fortunately NCTL plant has the
capacity to accumulate influent.
8.1.6 Comparison between preprimary primary and secondary clarifier
8 | T a s k p e r f o r me d P a g e | 26
Table-3: Comparison between pre-primary, primary, secondary clarifiers
Sr.
No.
Parameter of
Comparison
Pre-Primary
Clarifier
Primary Clarifier Secondary Clarifier
Design calculation comparisons
1. Inlet Flow rate 15 MLD 20 MLD 20 MLD
2. Quantity 4 Nos 3 Nos 3 Nos
3.
Surface Area
4.
Volume
5.
Surface Overflow Rate
SOR=
6.
Detention Time
=
(
= 7.6 hrs
=2.5 hrs
=11.4 hrs
7. Revolutions per hour 2.5 - 3 3 - 3.5 3 3.5
Other Comparisons
8. Oil Scrapper Yes, it is present No, it is not
required
No, it is not required
9. Effluent Inlet From the Top From
Bottom(centre)
From Bottom(centre)
10. Drive Central Driven
Motor
Periphery driven
Motor
Periphery driven
Motor
11. Clarifier Position Almost
underground
Partially
underground
Partially
underground
12. Removal of Total Suspended
Solids
Solids Left over
after pre-primary
Clarification
MLSS after Aeration
13. Effluent Comes From Inlet Equalization Tank Aeration Tank
14. Oil and grease
peripheral baffle
Yes present Not present Not present
15. Scrapper arm Sludge
rake
(for the same RPM
pre-primary scrapper
removes sludge twice)
8 | T a s k p e r f o r me d P a g e | 27
8.2 Off-field Tasks
8.2.1 Difference between Coagulant and Flocculent
The process of coagulation neutralizes charges on the suspended particles by addition of a
coagulant so that other forces such as repulsion are nullified on the particles. When the
charges are neutralized they can come closer to each other and join together to form
bigger particle called flocs. Process of floc formation is known as flocculation. Due to
their own weight enough for gravitational force to make it settle, they come out of
suspension and starts settling down. A Coagulant is the chemical that is added to
neutralize the particles (i.e. Aluminum chloride). Flocculent is a chemical, typically
organic, added to enhance flocculation process (i.e. poly electrolyte).
8.2.2 Difference between Primary, Secondary and tertiary treatment (Levels of
wastewater treatment) adopted from Metcalf and Eddy, wastewater
engineering,2011, pg. 11
Table-4: Levels of wastewater treatment
Preliminary
Removal of wastewater constituents such as rags, sticks, floatables,
grit, and grease that may cause maintenance or operational problems
with the treatment operations, processes, and ancillary systems
Primary Removal of a portion of the suspended solids and organic matter from
the wastewater
Advanced
primary
Enhanced removal of suspended solids and organic matter from the
wastewater typically accomplished by chemical addition or filtration
Secondary
Removal of biodegradable organic matter (in solution or suspension)
and suspended solids. Disinfection is also typically included in the
definition of conventional secondary treatment
Secondary
with nutrient
removal
Removal of biodegradable organics, suspended solids and nutrients
(nitrogen, phosphorus or both nitrogen and phosphorus)
Tertiary
Removal of residual suspended solids (after secondary treatment),
usually by granular medium Filtration or micro screens. Disinfection is
also typically a part of tertiary treatment. Nutrient removal is often
included in this definition
Advanced
Removal of dissolved and suspended materials remaining after normal
biological treatment when required for various water reuse applications
8.2.3 Feasible vs. viable
Feasible is technically sustainable. Viable is commercially possible.
8.2.4 Few energy saving strategies at design stage
Using natural forces ( like gravity) to carry out operations and processes
8 | T a s k p e r f o r me d P a g e | 28
Install adjustable speed drives (i.e. Variable frequency drives) on pumps
and blowers for variable operations
Install DO monitoring and control in aeration tanks
Install electric load monitoring devices
8.2.5 Few energy saving strategies adopted by NCTL at design stage
Operations by gravity instead of pumps
NCTL has used gravity to carry out as much as operation possible.
1. Convey effluent from member industries through gravity pipeline
2. Clarifiers are used instead filtration devices that uses gravity to
settle suspended solids.
Aspirators are installed since have lower power consumption than diffuser
system.
Variable frequency drives are installed that does not cause power loss due
to varying speed.
NCTL is experimenting on filter press for sludge dewatering that has
lower power consumption than decanter.
8.2.6 Variable frequency drive
A Variable Frequency Drive (VFD) is a type of motor controller that drives an electric
motor by varying the frequency and voltage supplied to the electric motor which does not
cause power loss just as conventional resistor regulators. At NCTL, VFDs are installed at
four places,
1. Equalization Pump House
2. Secondary Recirculation
3. Recirculation Pump House
4. Final Discharge
8.2.7 Design and process control parameters, their significance and typical values
Clarifiers: Important design considerations
8.2.7.1 Surface overflow rate (SOR) or Surface loading rate
Sedimentation tanks (clarifiers) are normally designed on the basis of a surface
overflow rate expressed as cubic meters per square meter of surface area per
day, m
3
/ m
2
day. The selection of suitable loading rate depends on the type of
suspension to be separated.
SOR =
8 | T a s k p e r f o r me d P a g e | 29
SOR for plain sedimentation is 18-24m
3
/m
2
day and sedimentation
following coagulation and flocculation is 28-36 m
3
/ m
2
day. Higher the SOR,
lower the Detention time, lower the SS removal.
For example, in section of comparison between preprimary primary and
primary clarifiers, we obtained the SOR for three clarifiers, we conclude that
major part of SS get removed in preprimary so its SOR is lower than primary
but secondary clarifier has to handle biomass having poor settling
characteristics. So secondary clarifier has lowest SOR hence detention time also
changes accordingly.
SOR is directly proportionate to detention time required. If SOR is too
small the detention time required is more and dimension of the unit will be too
big and ultimately cost will be more so we should select such SOR at which
efficiency is optimum and detention time is minimum.
8.2.7.2 Weir overflow rate (WOR) or Weir loading rate
Weir loading rates are used commonly in the design of clarifiers although they
are less critical in clarifier design than hydraulic overflow rates.
WOR =
The value of WOR should be between 200 to 300 m
3
/ m
2
day. It
determines the velocity at which the water will flow towards the outlet. Higher
the WOR higher the flow velocity.
V-notchs are provided to control the WOR having small flow
fluctuations and make uniform flow.
8.2.7.3 Detention time
The time for which the water or effluent remains in the tank and fill and
withdrawal is possible in the small amount is called as detention time.
Detention time =
(
Depending upon the type of solid its value may be decided. By analysis
or experience its value can be decided. For plain sedimentation 3 to 8 h. For
sedimentation following coagulation and flocculation 2 to 4 h, typically 3.
8.2.7.4 Velocity and turbulence
Based on type of solids, horizontal velocity of particles and turbulence has huge
impact on settling of particles. Flow must be close to laminar region for
optimum settling and horizontal velocity (also termed as scour velocity) must be
in optimum range.
8 | T a s k p e r f o r me d P a g e | 30
Activated sludge process: Process control parameters
8.2.7.5 Constant MLSS concentration
The mixture of activated sludge and effluent in the aeration tank is called
Mixed liquor. Suspended solid in the mixed liquor are called Mixed liquor
suspended solid (MLSS).
At 55050C the organic fraction of MLSS will be oxidized and driven
off as gas. This fraction of MLSS is referred to as Mixed liquor volatile
suspended solids (MLVSS). MLVSS represents the amount of microbes
present in wastewater.
MLSS = MLVSS + MLFSS is of no use
Depending upon the type of industry, nature of coagulants used and the
sludge age, the MLVSS constitute from 60% to 90% of MLSS. MLVSS/MLSS
ratio must be as high as possible because MLFSS content just increase the load
and does not help in any manner.
MLSS concentration should be in the range of 3000 to 5000ppm. If
MLSS is higher than 5000ppm clarifier will not be able to handle it and
overflow discharge of clarifier will higher COD because of unsettled MLSS
8.2.7.6 Dissolve oxygen (adopted from Metcalf and Eddy, Wastewater
engineering,2011, pg.690)
Theoretically, the amount of oxygen that must be transferred in the aeration
tanks equals the amount of oxygen required by the microorganisms in the
activated-sludge system to oxidize the organic material. In practice, the transfer
efficiency of oxygen for gas to liquid is relatively low so that only a small
amount of oxygen supplied is used by the microorganisms. When oxygen limits
the growth of microorganisms, filamentous organisms may predominate and the
settleability and quality of the activated sludge may be poor. In general, the
dissolved oxygen concentration in the aeration tank should be maintained at
about 1.5 to 2 mg/L in all areas of the aeration tank. Higher DO concentrations
(>2.0 mg/L) may improve nitrification rates in reactors with high BOD loads,
Values above 4mg/L do not improve operations significantly, but increase the
aeration costs considerably. The aeration capacity of the aerators should be
sufficiently flexible, to reasonably match the DO requirement of the variable
effluent flows and loadings.
8.2.7.7 F/M
The F/M ratio (the relationship in the mixed liquor of the amount of incoming
food to the amount of microorganisms) describes how well the process will
perform.
8 | T a s k p e r f o r me d P a g e | 31
F/M =
(
Where, Q = Flow rate, V = Aeration tank volume, m
3
The ideal F/M for a well stabilized Activated Sludge Process ranges
from 0.2 to 0.4.
If F/M ratio is higher than 0.4 than it indicates that food available (i.e.
BOD) per microorganism is high. The growth rate of microbes is high. But
ultimately we will not get the desirable results.
If F/M is lower than 0.2 than it indicates that food available per
microorganism is less. The growth rate of microorganism is low. Under such a
circumstances the microorganism will go under endogenous phase. And will not
be able to get the desired results.
8.2.7.8 Sludge volume index (SVI)
Sludge volume index is a test to evaluate sludge settling or thickening
characteristics, and techniques have been developed to apply these fundamental
characteristics to clarifier design. SVI is the volume of 1g of sludge after 30 min
of settling.
SVI (mL/g) =
(
SVI values below 100 mL/g are desired and is considered as good
settling sludge. And above 150 mL/g are typically associated with filamentous
growth.
8.2.7.9 Sludge recycle and wasting
The purpose of the recycle of activated sludge is to maintain a sufficient
concentration of activated sludge in the aeration tank so that the required degree
of treatment can be obtained in the time interval desired. The return of activated
sludge from the final clarifier to the inlet of the aeration tank is the essential
feature of the process.
Common control strategies for determining the return sludge flow rate
are based on maintaining either a target MLSS level in the aeration tanks or a
given sludge blanket depth in the final clarifiers.
To maintain a given SRT, the excess activated sludge produced each day
must be wasted.
To determine the Sludge Recycle Rate (SRR) material balance can be
made.
8 | T a s k p e r f o r me d P a g e | 32
Where,