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1. The yield to product in the reaction A2(g) + 2B(g) C(g) + QkJ would be high at
(A) high teperature and high pre!!ure (B) high teperature and low pre!!ure
(C) low teperature and high pre!!ure (") low teperature and low pre!!ure
2. #$ the e%uilibriu con!tant o$ the two reaction!& 2'() '2+)(2 and
2
1
'2 +
2
)
(2
'() are *1 + *2 re!pecti,ely at 2-C. then the relation between *1 and *2 i!
(A) *1 / *2 (B) *2 /
2
1
*
1
(C) *1 /
2
2
*
1
(") *1 /
2
*
1
). 0ure aonia i! placed in a ,e!!el at a teperature where it! di!!ociation con!tant () i!
appreciable. At e%uilibriu
(A) *0 doe! not change !igni$icantly with pre!!ure
(B) doe! not change with pre!!ure
(C) Concentration o$ '() doe! not change with pre!!ure
(") concentration o$ (2 i! le!! than that o$ '2
1. A reaction at e%uilibriu in,ol,ing 2 ol each o$ 0Cl-. 0Cl) and Cl2 i! aintained at 2-23C and at a
total pre!!ure o$ ) at. The ,alue o$ *p i!
(A) 2 (B) )
(C) 1 (") 1
-. The ,alue o$ *p $or the e%uilibriu o$ the reaction '241(g) 2'42(g) i! 2. Calculate the
percentage di!!ociation o$ '241 at a pre!!ure o$ 2.- at
(A) 51 (B) -2
(C) 2- (") 66
7. 8or the reaction
0Cl-(g)
0Cl)(g) +Cl2(g). the $orward reaction at con!tant teperature i! $a,oured by
1 introducing an inert ga! at con!tant ,olue
2 introducing chlorine ga! at con!tant ,olue
) introducing an inert ga! at con!tant pre!!ure
1 introducing 0Cl- at con!tant ,olue
(A) 1.2 (B) 1.-
(C) ).1 (") ).1.-
5. 9hen two reactant! A and B are i:ed to gi,e product! C and ". the reaction %uotient. Q at the initial
!tage! o$ the reaction
(A) i! ;ero (B) decrea!e! with tie
(C) in independent o$ tie (") increa!e! with tie
6 8or which reaction high pre!!ure and high teperature i! help$ul in obtaining a high e%uilibriu yield&
(A) 2'8) '2(g) + )82(g) < -1.12 kcal
(B) '2(g) + )(2 2'()(g) + 22.26 kcal
(C) Cl2(g) + 242(g) 2Cl42(g) < 1=.12 kcal
(") 2Cl245(g) 2Cl2(g) + 542(g) + 127.6 kcal
=. Aount o$ 0Cl-(in ole!) need to be added to 1 litre ,e!!el at 2-2C in order to obtain a
concentration o$ 2.1 ole o$ Cl2 at e%uilibriu $or the gi,en change i!
0Cl-
0Cl)+Cl2& *c / 2.2111 ole!> lit
(A) 2.)11- (B) 2.2)11
(C) ).11- (") 2.)11-
12 8or the reaction
C4(g) + (24(g) C42(g) + (2(g)
at a gi,en teperature. the e%uilibriu aount o$ C42(g) can be increa!ed by
(A) adding a !uitable cataly!t (B) adding an inert ga!
(C) decrea!ing the ,olue o$ the container (") #ncrea!ing the aount o$ C4(g)
11. #n an e%uilibriu reaction $or which ? / 2 the e%uilibriu con!tant * !hould be e%ual to
(A) @ero (B) 12
(C) 1 (") 2
12. 9hich graph will !how e%uilibriu conditionA
2
(A)
Tie
B
a
t
e
(B)
Tie
B
a
t
e
:
y
(C)
Tie
B
a
t
e
(") 'one o$ the!e
1). At con!tant teperature the e%uilibriu con!tant *p $or the decopo!ition reaction
'241 2'42
i! e:pre!!ed *p /
( )
2
2
: 1
0 : 1
where 0 / pre!!ure. : / e:tent o$ decopo!ition. 9hich one o$ the $ollowing !tateent i! true
(A) *p increa!e! with increa!e! o$ 0 (B) *p increa!e! with increa!e o$ :
(C) *p increa!e with decrea!e o$ : (") *p reain! con!tant with change in 0 + :
11. 8or the reaction '2 + )(2 2'() in a ,e!!el. a$ter the addition o$ e%ual nuber! o$ ole o$
'2 and (2 e%uilibriu !tate i! achie,ed. 9hich o$ the $ollowing i! correctA
(A) C(2D / C'2D (B) C(2D E C'2D
(C) C(2D F '2D (") C(2D F C'()D
1-. 9hat are the o!t $a,orable condition! $or the reactionA
G42(g) +
2
1
42(g) G4)(g) ( / H ,e
(A) low teperature. high pre!!ure (B) low teperature. low pre!!ure
(C) high teperature. low pre!!ure (") high teperature. high pre!!ure
17. Aount o$ 0Cl-(in ole!) need to be added to 1 litre ,e!!el at 2-2C in order to obtain a
concentration o$ 2.1 ole o$ Cl2 at e%uilibriu $or the gi,en change i!
0Cl-
0Cl)+Cl2& *C / 2.2111 ole!> lit
(A) 2.)11- (B) 2.2)11
(C) ).11- (") 2.)11-
15. The e%uilibriu con!tant o$ the reaction )C2(2
C7(7 i! 1.2 at T*. #$ the e%uilibriu concentration
o$ C2(2 i! 2.- ole!> litre. the concentration o$ C7(7 i!
(A) 2.- I (B) 1.- I
(C) -12
H2
I (") 2.2- I
16. 8or the reaction '241(g) 2'42(g) the relation connecting degree o$ di!!ociation () o$ '241
with the e%uilibriu con!tant *0 i!
(A) /
0 * 1
0 *
0
p
+
(B) /
0
0
* 1
*
+
(C) /
2 > 1
0
0
0 * 1
0
*
+
(") /
2
1
0
0
* 1
*
+
1=. The reaction A+B C+" i! !tudied in a one litre ,e!!el at 2-2C. The initial concentration o$ A
wa! )n and that o$ B wa! n. 9hen e%uilibriu wa! attained. e%uilibriu concentration o$ C wa! $ound
to be e%ual to the e%uilibriu concentration o$ B. 9hat i! the concentration o$ " and e%uilibriuA
(A) n>2 (B) ()n <1>2)
(C) (n<n>2) (") n
22. 0Cl- i! 12J di!!ociated when pre!!ure i! 2 at. #t will be 62J di!!ociated when pre!!ure i!
appro:iately.
3
(A) 2.2 at (B) 2.- at
(C) 2.) at (") 2.7 at
21. 8or the reaction A + 2B C. - ole o$ A and 6 ole o$ B will produce C
(A) - ole! (B) 1 ole!
(C) 6 ole! (") 1) ole!
22. (aeoglobin ((b) binded with o:ygen and gi,e o:yH (aeoglobin ((b42). Thi! proce!! i! partially
regulated by the concentration o$ ()4
+
and di!!ol,ed C42 in blood a!
(b42 + ()4
+
+ C42 (
+
H (b H C42 + 42 + (24
#$ there i! production o$ Kactic acid and C42 in an u!cle e:erci!e then
(A) ore 42 i! relea!e (B) ore (b42 i! $ored
(C) both (a) + (b) (") C42 will be $ored
2). 8or the e%uilibriu in a clo!ed ,e!!el
0Cl-(g) 0Cl)(g) + Cl2(g)
*p o$ $ound to be double o$ *c. Thi! i! attained whenL
(A) T / 2* (B) T / 12.16 *
(C) T / 21.)7 * (") T / 252) *
21. 2G42 + 42
2G4). Gtarting with 2 ol G42 and 1 ol 42 in 1 K $la!k. i:ture re%uired 2.1 ol
In41
<
in acidic ediu. (ence *C i!
(A) 2 (B) 2.1
(C) 1.7 (") 2.7
2-. 8or 2A + B
C + M cal. The $a,ourable condition! to obtain a:iu yield o$ B will be
(A) Kow 0re!!ure and low Teperature (B) Kow 0re!!ure and high Teperature
(C) (igh 0re!!ure and (igh Teperature (") (igh 0re!!ure and (igh Teperature
27. #n the reaction. '2 + )(2 2'() + M kcal. one ole o$ '2 react! with three ole! o$ (2. At
e%uilibriu. the ,alue o$ (degree o$ di!!ociation) i! appro:iately
(0/ pre!!ure at e%uilibriu)
(A)
6
* 25 0
0
(B)
25 *
0 6
0
(C)
0
* 6
25 0
(") 'one o$ the!e
25. #n the reaction M nN. the initial ,apour den!ity o$ M i! " and ,apour den!ity at e%uilibriu i! d. #$
degree o$ di!!ociation o$ M i! then. i! e%ual to
(A)
( ) 1 n d
d "
(B)
( )" 1 n
d "
(C)
( ) 1 d n
d "
(")
( )
d "
1 n d