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CHEMICAL EQUILIBRIUM- CPP

1. The yield to product in the reaction A2(g) + 2B(g) C(g) + QkJ would be high at
(A) high teperature and high pre!!ure (B) high teperature and low pre!!ure
(C) low teperature and high pre!!ure (") low teperature and low pre!!ure
2. #$ the e%uilibriu con!tant o$ the two reaction!& 2'() '2+)(2 and
2
1
'2 +
2
)
(2
'() are *1 + *2 re!pecti,ely at 2-C. then the relation between *1 and *2 i!
(A) *1 / *2 (B) *2 /
2
1
*
1
(C) *1 /
2
2
*
1
(") *1 /
2
*
1
). 0ure aonia i! placed in a ,e!!el at a teperature where it! di!!ociation con!tant () i!
appreciable. At e%uilibriu
(A) *0 doe! not change !igni$icantly with pre!!ure
(B) doe! not change with pre!!ure
(C) Concentration o$ '() doe! not change with pre!!ure
(") concentration o$ (2 i! le!! than that o$ '2
1. A reaction at e%uilibriu in,ol,ing 2 ol each o$ 0Cl-. 0Cl) and Cl2 i! aintained at 2-23C and at a
total pre!!ure o$ ) at. The ,alue o$ *p i!
(A) 2 (B) )
(C) 1 (") 1
-. The ,alue o$ *p $or the e%uilibriu o$ the reaction '241(g) 2'42(g) i! 2. Calculate the
percentage di!!ociation o$ '241 at a pre!!ure o$ 2.- at
(A) 51 (B) -2
(C) 2- (") 66
7. 8or the reaction
0Cl-(g)

0Cl)(g) +Cl2(g). the $orward reaction at con!tant teperature i! $a,oured by
1 introducing an inert ga! at con!tant ,olue
2 introducing chlorine ga! at con!tant ,olue
) introducing an inert ga! at con!tant pre!!ure
1 introducing 0Cl- at con!tant ,olue
(A) 1.2 (B) 1.-
(C) ).1 (") ).1.-
5. 9hen two reactant! A and B are i:ed to gi,e product! C and ". the reaction %uotient. Q at the initial
!tage! o$ the reaction
(A) i! ;ero (B) decrea!e! with tie
(C) in independent o$ tie (") increa!e! with tie
6 8or which reaction high pre!!ure and high teperature i! help$ul in obtaining a high e%uilibriu yield&
(A) 2'8) '2(g) + )82(g) < -1.12 kcal
(B) '2(g) + )(2 2'()(g) + 22.26 kcal
(C) Cl2(g) + 242(g) 2Cl42(g) < 1=.12 kcal
(") 2Cl245(g) 2Cl2(g) + 542(g) + 127.6 kcal
=. Aount o$ 0Cl-(in ole!) need to be added to 1 litre ,e!!el at 2-2C in order to obtain a
concentration o$ 2.1 ole o$ Cl2 at e%uilibriu $or the gi,en change i!
0Cl-

0Cl)+Cl2& *c / 2.2111 ole!> lit
(A) 2.)11- (B) 2.2)11
(C) ).11- (") 2.)11-
12 8or the reaction
C4(g) + (24(g) C42(g) + (2(g)
at a gi,en teperature. the e%uilibriu aount o$ C42(g) can be increa!ed by
(A) adding a !uitable cataly!t (B) adding an inert ga!
(C) decrea!ing the ,olue o$ the container (") #ncrea!ing the aount o$ C4(g)
11. #n an e%uilibriu reaction $or which ? / 2 the e%uilibriu con!tant * !hould be e%ual to
(A) @ero (B) 12
(C) 1 (") 2
12. 9hich graph will !how e%uilibriu conditionA
2
(A)
Tie
B
a
t
e
(B)
Tie
B
a
t
e
:
y
(C)
Tie
B
a
t
e
(") 'one o$ the!e
1). At con!tant teperature the e%uilibriu con!tant *p $or the decopo!ition reaction
'241 2'42
i! e:pre!!ed *p /
( )
2
2
: 1
0 : 1

where 0 / pre!!ure. : / e:tent o$ decopo!ition. 9hich one o$ the $ollowing !tateent i! true
(A) *p increa!e! with increa!e! o$ 0 (B) *p increa!e! with increa!e o$ :
(C) *p increa!e with decrea!e o$ : (") *p reain! con!tant with change in 0 + :
11. 8or the reaction '2 + )(2 2'() in a ,e!!el. a$ter the addition o$ e%ual nuber! o$ ole o$
'2 and (2 e%uilibriu !tate i! achie,ed. 9hich o$ the $ollowing i! correctA
(A) C(2D / C'2D (B) C(2D E C'2D
(C) C(2D F '2D (") C(2D F C'()D
1-. 9hat are the o!t $a,orable condition! $or the reactionA
G42(g) +
2
1
42(g) G4)(g) ( / H ,e
(A) low teperature. high pre!!ure (B) low teperature. low pre!!ure
(C) high teperature. low pre!!ure (") high teperature. high pre!!ure
17. Aount o$ 0Cl-(in ole!) need to be added to 1 litre ,e!!el at 2-2C in order to obtain a
concentration o$ 2.1 ole o$ Cl2 at e%uilibriu $or the gi,en change i!
0Cl-

0Cl)+Cl2& *C / 2.2111 ole!> lit
(A) 2.)11- (B) 2.2)11
(C) ).11- (") 2.)11-
15. The e%uilibriu con!tant o$ the reaction )C2(2

C7(7 i! 1.2 at T*. #$ the e%uilibriu concentration
o$ C2(2 i! 2.- ole!> litre. the concentration o$ C7(7 i!
(A) 2.- I (B) 1.- I
(C) -12
H2
I (") 2.2- I
16. 8or the reaction '241(g) 2'42(g) the relation connecting degree o$ di!!ociation () o$ '241
with the e%uilibriu con!tant *0 i!
(A) /
0 * 1
0 *
0
p
+
(B) /
0
0
* 1
*
+
(C) /
2 > 1
0
0
0 * 1
0
*

+
(") /
2
1
0
0
* 1
*

+
1=. The reaction A+B C+" i! !tudied in a one litre ,e!!el at 2-2C. The initial concentration o$ A
wa! )n and that o$ B wa! n. 9hen e%uilibriu wa! attained. e%uilibriu concentration o$ C wa! $ound
to be e%ual to the e%uilibriu concentration o$ B. 9hat i! the concentration o$ " and e%uilibriuA
(A) n>2 (B) ()n <1>2)
(C) (n<n>2) (") n
22. 0Cl- i! 12J di!!ociated when pre!!ure i! 2 at. #t will be 62J di!!ociated when pre!!ure i!
appro:iately.
3
(A) 2.2 at (B) 2.- at
(C) 2.) at (") 2.7 at
21. 8or the reaction A + 2B C. - ole o$ A and 6 ole o$ B will produce C
(A) - ole! (B) 1 ole!
(C) 6 ole! (") 1) ole!
22. (aeoglobin ((b) binded with o:ygen and gi,e o:yH (aeoglobin ((b42). Thi! proce!! i! partially
regulated by the concentration o$ ()4
+
and di!!ol,ed C42 in blood a!
(b42 + ()4
+
+ C42 (
+
H (b H C42 + 42 + (24
#$ there i! production o$ Kactic acid and C42 in an u!cle e:erci!e then
(A) ore 42 i! relea!e (B) ore (b42 i! $ored
(C) both (a) + (b) (") C42 will be $ored
2). 8or the e%uilibriu in a clo!ed ,e!!el
0Cl-(g) 0Cl)(g) + Cl2(g)
*p o$ $ound to be double o$ *c. Thi! i! attained whenL
(A) T / 2* (B) T / 12.16 *
(C) T / 21.)7 * (") T / 252) *
21. 2G42 + 42

2G4). Gtarting with 2 ol G42 and 1 ol 42 in 1 K $la!k. i:ture re%uired 2.1 ol
In41
<
in acidic ediu. (ence *C i!
(A) 2 (B) 2.1
(C) 1.7 (") 2.7
2-. 8or 2A + B

C + M cal. The $a,ourable condition! to obtain a:iu yield o$ B will be
(A) Kow 0re!!ure and low Teperature (B) Kow 0re!!ure and high Teperature
(C) (igh 0re!!ure and (igh Teperature (") (igh 0re!!ure and (igh Teperature
27. #n the reaction. '2 + )(2 2'() + M kcal. one ole o$ '2 react! with three ole! o$ (2. At
e%uilibriu. the ,alue o$ (degree o$ di!!ociation) i! appro:iately
(0/ pre!!ure at e%uilibriu)
(A)
6
* 25 0
0
(B)
25 *
0 6
0
(C)
0
* 6
25 0
(") 'one o$ the!e
25. #n the reaction M nN. the initial ,apour den!ity o$ M i! " and ,apour den!ity at e%uilibriu i! d. #$
degree o$ di!!ociation o$ M i! then. i! e%ual to
(A)
( ) 1 n d
d "

(B)
( )" 1 n
d "

(C)
( ) 1 d n
d "

(")
( )
d "
1 n d

26. (ow will the rate o$ the reaction


2G42(g) + 42(g)

2G4)(g) change i$ the ,olue o$ the reaction ,e!!el i! doubled
(A) #t will be 1>1
th
o$ the initial ,alue (B) #t will be 1>7
th
o$ the original ,alue
(C) #t will be 6 tie! o$ it! initial ,alue (") #t will be 1 tie! o$ it! initial ,alue
2=. At a certain teperature the e%uilibriu con!tant $or the reaction
C4 (g) + (24(g)

C42()g) + (2(g) i! 1. A i:ture initially containing one ole o$ each o$ carbon
ono:ide and !tea i! allowed to reach e%uilibriu. (ow any ole! o$ carbon ono:ide are now
pre!entA
(A) 1>1 (B) 1>)
(C) 1>2 (") 2>)
)2. The e%uilibriu con!tant $or the reaction 0Cl-(g)

0Cl)(g) + Cl2)g) i! 2.27 at -5) *. #n the pre!ence o$
a cataly!t the e%uilibriu con!tant i! attained 12 tie! $a!ter. The new e%uilibriu con!tant i!
(A) 2.7 (B) 2.27
(C) 27 (") -.2
4
)1. 8or )A + 2B

2C + ". initial ole o$ A i! double o$ B. At e%uilibriu ol o$ A and " are e%ual.
(ence percentage di!!ociation o$ A i!
(A) -2J (B) 2-J
(C) 5-J (") none o$ the!e
)2. 8or which o$ the $ollowing e%uilibria *C i! ore than *p
(A) A2(g) + B2(g)

2AB(g) (B) 0(g)

2C(g) + B(g)
(C) 2A(g) + B(g)

C(g) (") 'one
)). The e%uilibriu con!tant o$ reaction i! 22.2. At e%uilibriu. the rate con!tant o$ $orward reaction i!
12.2. The rate con!tant $or backward reaction i!
(A) 2.- (B) 2.2
(C) 12.2 (") 222.2
)1. )g ole! o$ 0Cl- are heated in a clo!ed ) litre ,e!!el. At e%uilibriu 0Cl - i! 12J di!!ociated into 0Cl)
and Cl2. Calculate the e%uilibriu con!tant
(A) 2.275 (B) 2.725
(C) 2.527 (") 2.7-2
)-. 6 ole! o$ a ga! AB) are introduced into a 1.2 d
)
,e!!el. #t di!!ociate! a!
2 AB)(g)

A2(g) + )B(g)
At e%uilibriu. 2 ole o$ A2 are $ound to be pre!ent. The ,alue o$ *c $or the reaction i!
(A) = ol
2
K
H2
(B) 16 ol
2
K
H2
(C) 25 ol
2
K
H2
(") )7 ol
2
K
H2
)7. The reaction )A+B

2C+" wa! initiated by taking 1 ole o$ A and 2 ole! o$ B. At e%uilibriu
ole! o$ A and C are e%ual. (ence. the di!!ociation percentage o$ B i!
(A) -J (B) 12J
(C) 1-J (C) 22J
)5. 8or a reaction o$ the type A(!) + 2B(g)

C(g) an e%uilibriu i:ture con!i!t o$ ).2 ole o$ A. 2.62
ole o$ B. and 2.12 ole o$ C. in a 2.22 K $la!k. 9hat i! the ,alue o$ *C $or thi! reactionA
(A) -.2 12
<1
(B) 6.) 12
<1
(C) 1.2- (") 1.5 12
<1
)6. A i:ture o$ heliu and argon contain! ) ole o$ (e $or e,ery 2 ole o$ Ar. The partial pre!!ure o$
argon i!
(A) 2>) the total pre!!ure (B) 1>) the total pre!!ure
(C) 2>- the total pre!!ure (") 1>- the total pre!!ure
)=. (eliu ato i! two tie! hea,ier than a hydrogen olecule. At 2-3C the a,erage *.O. o$ heliu ato
i!
(A) Twice that o$ hydrogen (B) Gae a! that o$ hydrogen
(C) 8our tie! that o$ hydrogen (") (al$ that o$ hydrogen
12. 8or the reaction '2+)(2

2'(). the e%uilibriu partial pre!!ure o$ '2 and (2 are 2.6 and 2.1 at
re!pecti,ely. "eterine the ,alue o$ *p.
(A) -2 at (B) 2- at
H2

(C) -2 at
H2
(") 2- at
11. *p ,alue! $or C2(1+(2

C2(7 i! -12
16
at
H1
and *p $or C2(2+(2

C2(1 i! -12
27
at
H1
at
-2C. "eterine *p $or the reaction.
2(2+C2(2

C2(7
(A) 12
6
(B) 2.-12
1-
(C) -12
16
(") 12
H6
12. The ,apour den!ity o$ '241 at a certain teperature i! )2. The percentage di!!ociation o$ '241 at thi!
teperature i!
(A) -).) (B) 27.5
(C) 2.-)) (") 2.75
5
1). The decopo!ition o$ aoniu carbonate at )2C i! repre!ented a!
'(2C44'(1(!)

2'()(g) + C42(g)
The e%uilibriu con!tant *p i! )212
H7
at
)
. 9hat i! the total pre!!ure o$ ga!e! in e%uilibriu with
'(2C44'(1(!) at )2CA
(A) 612
H7
at (B) 212
H2
at
(C) 712
H2
at (") =12
H1
at
11. #n the reaction A+2B

2C+". the initial concentration o$ B wa! 1.- tie! that o$ A. but e%uilibriu
concentration o$ A and B are $ound to be e%ual. The e%uilibriu con!tant $or the reaction i!
(A) 1 (B) 17
(C) 2 (") )2
1-. 8or which reaction high pre!!ure and high teperature i! help$ul in obtaining a high e%uilibriu yield&
(A) 2'8) '2(g) + )82(g) < -1.12 kcal
(B) '2(g) + )(2 2'()(g) + 22.26 kcal
(C) Cl2(g) + 242(g) 2Cl42(g) < 1=.12 kcal
(") 2Cl245(g) 2Cl2(g) + 542(g) + 127.6 kcal
17. Aoniu carbaate di!!ociation a!
(2'C44'(1(!) 2'()(g) + C42(g)
#n a clo!ed ,e!!el containing aoniu carbonate in e%uilibriu. aonia i! added !uch that partial
pre!!ure o$ aonia now e%ual to the original total pre!!ure what i! the ratio o$ the total pre!!ure
now to the original pre!!ure.
(A)
25
)1
(B)
)1
25
(C)
)1
=
(")
=
)1
15. The e%uilibriu G42Cl2(g) G42(g) + Cl2(g) i! attained at 2-C in a clo!ed ,e!!el and (e i!
introduced which o$ the $ollowing !tateent i! correct
(A) Concentration! o$ G42. Cl2 and G42Cl2 change
(B) Iore Cl2 i! $ored
(C) Concentration o$ G42 i! reduced
(") 'one
16. 4ne ole each o$ A and B and ) ole each o$ C and " are placed in 1 litre $la!k. i$ e%uilibriu
con!tant i! 2.2- $or A + B C + ". e%uilibriu con!tant o$ A and C will be in the ratio
(A) 2 L ) (B) ) L 2
(C) 1 L 2 (") 2 L 1
1=. The e%uilibriu. 2 G42(g) + 42(g)

2G4)(g) !hi$t! $orward i$
(A) a cataly!t i! u!ed
(B) !all aount! o$ reactant! are u!ed
(C) an ad!orbent i! u!ed to reo,ed G4) a! !oon a! it i! $ored
(") 'one
-2. Con!ider the $ollowing e%uilibriu in a clo!ed ,e!!el '241(g) 2'42(g)
At $i:ed teperature. the ,olue o$ the container i! hal$ than which o$ the $ollowing !tateent! hold
true regarding the e%uilibriu con!tant (*p) and degree o$ di!!ociation ()A
(A) neither *p nor change (B) both *p and change
(C) *p change but doe! not (") *p doe! not change but change

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