Scales

• Usually a precipitate from a brine that
becomes saturated with a material due to a
change in the flowing fluid conditions within a
well.
• Scale precipitation may be driven by mixing
incompatible waters, but can also be caused
by out-gassing, shear, turbulence, and
temperature and pressure loss – upsets in the
flowing equilibrium.
3/14/2009

George E. King Engineering
GEKEngineering.com

1

Scales

Saturation Indices for Scale Formation Potential for an
Example Formation Water
Calcite (CaCO3)

1.5

Gypsum (CaSO4)
1

Saturation Index

• calcium carbonate - upset
driven
• calcium sulfate - mixing
waters, upset, CO2
• barium sulfate - mixing
waters, upset
• iron scales - corrosion,
H2S, low pH, O2
• rarer scales - heavy brines

0.5
0
90

140

190

240

-0.5
-1
-1.5
Temperature, F

3/14/2009

George E. King Engineering
GEKEngineering.com

2

Some scales form in layers, often driven by an “upset” in the flow dynamics of the system.
These deposits can form almost anywhere, on any surface, but the deposits are usually just
downstream of the location of an upset in the flow system. The location of the scale is often an
indicator of what is causing the precipitation.

3/14/2009

George E. King Engineering
GEKEngineering.com

3

King Engineering GEKEngineering.Calcium sulfate scale from slow growth in a high water cut reservoir. 3/14/2009 George E.com 4 .

King Engineering GEKEngineering.com 5 .A rapidly formed deposit of calcium sulfate formed after an acid was mixed with a scale dissolver chemical that had removed a deposit of calcium sulfate scale at the perforations. 3/14/2009 George E.

Calcium Sulfate scale that completely blocked a section of downhole tubing – this piece was from a connection. King Engineering GEKEngineering.com 6 . 3/14/2009 George E.

A very unusual form of calcium carbonate scale – small pellets – 1/8” or 3 mm of carbonate scale formed around a grain of sand. Bailed from an East Texas well with natural flow (strong water drive) and significant rolling water in the bottom.com 7 . they sank. Oil Well Pearls? 3/14/2009 George E. King Engineering GEKEngineering. When the pellets got so heavy they could not be supported.

com 8 . 3/14/2009 George E.Calcium sulfate crystals removed from a flow line in West Texas. King Engineering GEKEngineering.

com 9 . There was almost no reaction in several days in a test with the best EDTA and DPTA Barium dissolvers. but was nearly pure BaSO4.Barium Sulfate deposition from topsides piping on a North Sea platform in the early 1990’s. King Engineering GEKEngineering. The scale was not radioactive. 3/14/2009 George E.

3/14/2009 George E. sludge and scale. • NOR’s present in water. present in almost all of the earth’s crust. King Engineering GEKEngineering. gas.com 10 .NORM Scales • NORM is Naturally Occurring Radioactive Material • Scales which form concentrates of various naturally occurring radionuclides (NOR’s).

3/14/2009 George E. 232Th • Potassium 40K • And their gamma-ray emitting products.What’s Radioactive? • Uranium series 238U and 226Ra • Thorium series.com 11 . King Engineering GEKEngineering.

hydrostatic sensitive shear points . gravel pack .Scale Location • • • • • at pressure drops .pumps. flood breakthru outgassing points .leaks.formation interface 3/14/2009 George E.com 12 . profiles water mixing points .perfs. perfs. chokes. King Engineering GEKEngineering.

or in the presence of Connate or Formation water 3/14/2009 George E.g. when Sea water breaks through in a production well already containing Formation water –e. When injecting Sea water into a Reservoir water Leg.g. King Engineering GEKEngineering.com 13 .g. Formation and Sea water) –e.Why Does Scale Form? • Sulphates: Ba2+ + SO42FW SW BaSO4 –Mixing of Incompatible waters (e.

com 14 ..each scale needs to be evaluated under prevailing conditions • Increasing salinity tends to increase solubility of both 3/14/2009 George E..Temperature and Pressure • Carbonate is Less Soluble with increasing temperature and Reducing Pressure • Sulphates tend to be more soluble with increasing temperature and pressure (less of an effect) • These are general rules. but there are exceptions. King Engineering GEKEngineering.

etc. – added shear .this is where the “upset” factor comes in. choke changes. – acidizing – venting pressure 3/14/2009 George E.Scale Prediction • Chemical models .com 15 . King Engineering GEKEngineering.require water analysis and well conditions • Predictions are usually a “worst case” .increased drawdown.

Water Composition Concentration (ppm) Ion Na K Mg Ca Sr Ba CI SO4 HCO3 3/14/2009 Sea Water Forties Miller 10890 460 1368 428 8 0 19700 2960 124 29370 372 504 2808 574 252 52360 0 496 Gyda Prudhoe Bay 28780 65340 1830 5640 2325 115 1060 30185 1085 110 485 1050 47680 167400 0 0 76 2090 George E.com 8000 83 84 180 24 4 11500 10 2222 16 . King Engineering GEKEngineering.

pptn predicted 150 100 50 0 0 10 20 30 40 50 60 70 80 90 100 % Seawater 3/14/2009 George E.com 17 . King Engineering GEKEngineering.Example of North Sea Scaling Indices for Formation / Sea Water Mixture 450 Calcite Anhydrite Barite Celestite 400 350 300 250 200 • SI = 1 equilibrium • SI > 1 over saturated.

Calcium sulfate growth rates for various stimulation methods (upsets).com 18 . King Engineering GEKEngineering. 3/14/2009 George E.

com 19 . ETAP) • Remedial Action – Chemical Dissolution – Mechanical Removal 3/14/2009 George E. King Engineering GEKEngineering.How do we Control Scale? • Inhibition – Downhole – Subsea – Topsides • Stop mixing of incompatible waters – PWRI Vs SWI (Harding) – Use De-Sulphated sea water (Marathon) – Train segregation (Bruce.

yet prevent them from becoming large enough to precipitate from solution – The initial nucleation reduces the supersaturation of the solution quickly – The large molecules attach to active crystal growth planes and block growth in one particular direction 3/14/2009 George E. which act as nucleation sites.com 20 . King Engineering GEKEngineering. – Promote the formation of small crystals.How Do They Work? • Crystal Modifiers – These chemicals are believed to work predominantly by retarding crystal growth.

King Engineering GEKEngineering.How Do They Work • Threshold Inhibitors – These chemicals inhibit predominantly by preventing crystal nucleation – They stop the ions from aggregating together and in effect delay scale formation 3/14/2009 George E.com 21 .

King Engineering GEKEngineering.com 22 .Inhibitor Deployment Above the Packer • Continuous Injection via Chemical Injection Control Line (Macaroni string) – Well integrity (leak path) – Increases well completion running times (rig costs?) – Blockage issue • Continuous Injection via Gas Lift – Atomisation and Gunking issue – Orifice to Packer Volume 3/14/2009 George E.

Inhibitor Deployment Below the Packer • Matrix squeezes with scale inhibitor – Adsorption and Absorption – Precipitation squeezes • Impregnated proppant (short lived) • Continuous Inhibition from capillary • Inhibitor placement in the rat hole 3/14/2009 George E. King Engineering GEKEngineering.com 23 .

inhibitor is slowly George E. 50bbls – maximize contact with rock and minimizes near well bore damage • Main treatment – typical vol. • Overflush – typical vol. S tag e 1: Preflush Stage 2: Pump Scale Inhibitor Stage 3: Pump Overflush mixed in compatible fluid. 50 – 500 bbls of actual chemical required for inhibition. 50 to over 1000bbls Stage 4: Shut in – ensures deeper placement of Stage 5: Return the well to production . King Engineering chemicals 3/14/2009 GEKEngineering.com released into the well.Scale Inhibitor Squeeze Treatments • Bull heading – Chemicals pumped directly down well (rate 3-30 bpm) • Pre-flush flush – typical vol. 24 .

com 200 AEA 25 .Inhibitors can be squeezed into the formation. 0. scale can form. 0 3/14/2009 50 100 Elapsed Tim e / days 150 George E. There is a “threshold” level of inhibitor needed to prevent scale in a specific well system. Optimizing inhibitor squeeze design can change the useful inhibitor life from a few weeks to 12 to 18 months. 20. When the inhibitor level falls below the threshold. Inhibitor return data Active Inhibitor Content / ppm 60. Milne Point L-40 well. 10. 50. returning slowly. King Engineering GEKEngineering. 40. 30.

King Engineering GEKEngineering.com 26 .PDTA and EDTA Pure Barium Sulfate .Scale Removal • • • • • Calcium Carbonate . EDTA Calcium Sulfate .mechanical Thick deposits of any sulfate scale mechanical removal 3/14/2009 George E.EDTA and converters Barium Sulfate mixtures .HCl.

• Mechanical Removal – Milling with carefully selected mills – also watch the hydraulics. Acetic Acid) and EDTA and DPTA • Calcium Sulfate – Chelants (e. • Multiple trips in tapered diameter completion string • Problems with nipple profiles – Jetting with Solid Beads (e.g. – Shock (e. – Under-reaming under restrictions (under-reamers are slower than mills).Scale Removal • Chemical Dissolution – Scale Dissolvers • Carbonates – Mineral Acids (e. 3/14/2009 George E. HCl. abrasives) – tubing damage potential is moderate to high. King Engineering GEKEngineering. EDTA and DPTA based) and Converters (strong bases) • Barium Sulfate – treat only scale mixtures.g.g. too slow on pure BaSO4 under pressure. String Shot) – 1 to a maximum of 4 strands of 90 grain RDX.com 27 .g.

King Engineering GEKEngineering.corrosion. 3/14/2009 George E.upset driven calcium sulfate .mixing waters. upset iron scales .com 28 . H2S. low pH.Scales • • • • • calcium carbonate . CO2 barium sulfate . upset.heavy brines create zinc and other metal sulfides.mixing waters. O2 rarer scales .

Problems with over-running the dissolver or converter with acid – the resulting reaction can re-precipitate everything! Calcium sulfate scale precipitated from a scale dissolver solution of EDTA when treated with 15% HCl.com 29 .. King Engineering GEKEngineering. Most dissolvers and converters cannot hold the by-products in solution as pH drops. 3/14/2009 George E.

Understand why.g.com 30 . heating. etc. cost. King Engineering GEKEngineering. 3/14/2009 George E.Sale – Know Why. e. acidizing and other factors. impact. access. cooling. corrosion. • Scales precipitate due to fluid mixing.. • Is it easier to prevent the scale or remove it once it has formed? It depends on the individual well conditions. upsets in flowing conditions.