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This document is a collection of formulae in Thermodynamics as required by CBSE - 11 students. The formulae are more extensive than given in the NCERT textbook.

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1.

Q = U + W

where,

Q is the heat supplied to the system by the surroundings

W is the work done by the system on its surroundings

U is the change in internal energy of the system

2.

Thermodynamics reduce to?

Q = W

i.e., the heat supplied to the system is used up entirely by the system in

doing work on the environment.

3.

Give expression for the work done at constant pressure. How does

the First Law of Thermodynamics translate for a process

performed at constant pressure?

W = PV

Therefore, we have:

Q = U + PV

4.

the atoms are vibrating about their mean positions.

U = 3RT

5.

Give expression for the molar specific heat of a solid. (This is the

Dulong and Petits Law)

C = 3R

6.

constant pressure and at constant volume.

Cp Cv = R

7.

quantities on both the sides are extensive. The product of an

intensive variable like P and an extensive quantity V is extensive.

Q = U + PV

8.

process.

W = nRT ln (V2/V1)

OR

W = nRT ln (P1/P2)

9.

W = nR (T2 T1)

10.

= W/Q1

where, Q1 is the heat input or the heat absorbed by the system in one

complete cycle.

11.

system to the surroundings. In such circumstances, what is the

efficiency of the heat engine?

= 1 Q2/Q1

12.

refrigerator.

= Q2/W

where,

Q2 is the heat extracted from the cold reservoir

W is the work done on the system, i.e. the refrigerant

13.

in terms of the heat extracted from the cold reservoir and the heat

pumped to the surroundings.

14.

= Q1/W

15.

= 1 T2/T1

16.

17.

same thermal capacity as body.

water equivalent = mass of body x specific heat of the material of body

18.

change.

Q=mL

where L is the latent heat

m is the mass of the body

19.

20.

(dP/dV)isothermal = (P/V)

21.

ideal gas.

22.

curves.

Slopeadiabatic = Slopeisothermal

23.

W = nR (T1 T2) ln (V2/V1)

24.

S = mL/T

where L is the latent heat

25.

of Cv.

S = n[Cv ln (Tf/Ti) + R ln (Vf/Vi)

26.

of Cp.

S = n[Cp ln (Tf/Ti) R ln (Pf/Pi)

27.

of Cp and Cv.

S = n[Cv ln (Pf/Pi) + Cp ln (Vf/Vi)

28.

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