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)

IMPORTANT INSTRUCTIONS

1.

Immediately fill in the particulars on this page of the Test Booklet with Blue/Black Ball Point Pen. Use of

Pencil is strictly prohibited.

2.

The Answer Sheet is kept inside the Test Booklet. When you are directed to open the Test Booklet, take

out the Answer Sheet and fill in the particulars carefully.

3.

The test is of 3 hours duration.

4.

The Test Booklet consists of 90 questions. The maximum marks are 360.

5.

**There are three parts in the question paper A, B, C consisting of Physics, Mathematics, Chemistry having
**

30 questions in each part of equal weight age. Each question is allotted 4(four) marks for each correct

response.

Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each

question ¼ (one fourth) marks will be deducted for indicating incorrect response of each question. No

deduction from the total score will be made if no response is indicated for an item in the answer sheet.

6.

7.

There is only one correct response for each question. Filling up more than one response in each question

will be treated as wrong response and marks for wrong response will be deducted accordingly as per

instruction 6 above.

8.

Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and Side-2 of the

Answer Sheet. Use of pencil is strictly prohibited.

9.

**No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
**

phone, any electronic device, etc., except the Admit Card inside the examination hall/room.

10.

Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is

given at the bottom of each page and in 3 pages (Pages 21 – 23) at the end of the booklet.

11.

On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty in the

Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.

12.

The CODE for this Booklet is Q. Make sure that the CODE printed on Side-2 of the Answer Sheet is the

same as that on this booklet. In case of discrepancy, the candidate should immediately report the matter to

the Invigilator for replacement of both the Test Booklet and the Answer Sheet.

13.

Do not fold or make any stray marks on the Answer Sheet.

FIITJEE (Hyderabad Classes) Limited. 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 040-66777000 – 03 Fax: 040-66777004

AIEEE−2011−2

PART A : PHYSICS

1.

The transverse displacement y ( x,t ) of a wave on a string is given by y ( x,t ) = e

(

− ax2 + bt 2 + 2 ab xt

).

This represents a

(1) wave moving in – x direction with speed

(3) standing wave of frequency

1

b

b

(2) standing wave of frequency

a

b

(4) wave moving in + x direction with

a

b

2.

**A screw gauge gives the following reading when used to measure the diameter of a wire.
**

Main scale reading : 0 mm

Circular scale reading : 52 divisions

Given that 1 mm on main scale corresponds to 100 divisions of the circular scale.

The diameter of wire from the above date is :

(1) 0.052 cm

(2) 0.026 cm

(3) 0.005 cm

(4) 0.52 cm

3.

**A mass m hangs with the help of a string wrapped around a pulley on a frictionless bearing. The pulley
**

has mass m and radius R. Assuming pulley to be a perfect uniform circular disc, the acceleration of the

mass m, if the string does not slip on the pulley, is

2

g

3

(1) g

(2)

(3)

(4) g

g

2

3

3

4.

**Work done in increasing the size of a soap bubble from a radius of 3 cm to 5 cm is nearly (Surface
**

tension of soap solution = 0.03 Nm−1):

(1) 0.2π mJ

(2) 2π mJ

(3) 0.4 π mJ

(4) 4π mJ

5.

**A thin horizontal circular disc is rotating about a vertical axis passing through its centre. An insect is at
**

rest at a point near the rim of the disc. The insect now moves along a diameter of the disc to reach its

other end. During the journey of the insect, the angular speed of the disc:

(1) continuously decreases

(2) continuously increases

(3) first increases and then decreases

(4) remains unchanged

6.

Two particles are executing simple harmonic motion of the same amplitude A and frequency ω along the

x-axis. Their mean position is separated by distance X0 ( X0 > A ) . If the maximum separation between

them is ( X0 + A ) , the phase difference between their motion is :

(1)

π

3

(2)

π

4

(3)

π

6

(4)

π

2

7.

**Two bodies of masses m and 4 m are placed at a distance r. The gravitational potential at a point on the
**

line joining them where the gravitational field is zero is:

4Gm

6Gm

9Gm

(2) −

(3) −

(4) zero

(1) −

r

r

r

8.

**Two identical charged spheres suspended from a common point by two massless strings of length l are
**

initially a distance d ( d << 1) apart because of their mutual repulsion. The charge begins to leak from

both the spheres at a constant rate. As a result the charges approach each other with a velocity v. Then

as a function of distance x between them,

(2) v ∝ x1/ 2

(3) v ∝ x

(4) v ∝ x −1/ 2

(1) v ∝ x −1

FIITJEE (Hyderabad Classes) Limited. 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 040-66777000 – 03 Fax: 040-66777004

AIEEE−2011−3

9.

A boat is moving due east in a region where the earth’s magnetic field is 5.0 × 10−5 NA −1m−1 due north and

horizontal. The boat carries a vertical aerial 2m long. If the speed of the boat is 1.50 ms−1, the

magnitude of the induced emf in the wire of aerial is :

(1) 0.75 mV

(2) 0.50 mV

(3) 0.15 mV

(4) 1 mV

10.

**An object, moving with a speed of 6.25 m/s, is decelerated at a rate given by :
**

dv

= −2.5 v

dt

where v is the instantaneous speed. The time taken by the object, to come to rest, would be :

(1) 2 s

(2) 4 s

(3) 8 s

(4) 1 s

11.

**A fully charged capacitor C with initial charge q0 is connected to a coil of self inductance L at t = 0. The
**

time at which the energy is stored equally between the electric and the magnetic field is :

π

LC

(2) 2π LC

(3) LC

(4) π LC

(1)

4

12.

**Let the x – z plane be the boundary between two transparent media. Medium 1 in z ≥ 0 has a refractive
**

index of 2 and medium 2 with z < 0 has a refractive index of 3 . A ray of light in medium 1 given by

→

∧

∧

∧

**the vector A = 6 3 i + 8 3 j − 10k is incident on the plane of separation. The angle of refraction in
**

medium 2 is

(2) 600

(3) 750

(4) 300

(1) 450

13.

**A current I flows in an infinitely long wire with cross section in the form of a semicircular ring of radius R.
**

The magnitude of the magnetic induction along its axis is

µ0I

µ0I

µ0I

µI

(1)

(3)

(4) 20

(2)

2πR

πR

2π2R

4 π 2R

14.

**A thermally insulated vessel contains an ideal gas of molecular mass M and ratio of specific heats γ. It is
**

moving with speed υ and is suddenly brought to rest. Assuming no heat is lost to the surroundings, its

temperature increases by :

( γ − 1)

( γ − 1) 2

( γ − 1) 2

γMυ2

Mυ2 K

Mυ K

(3)

(4)

K

(1)

(2)

Mυ K

2 ( γ + 1) R

2R

2R

2γR

15.

**A mass M, attached to a horizontal spring, executes S.H.M. with amplitude A1. When the mass M passes
**

through its mean position then a smaller mass m is placed over it and both of them move together with

A

amplitude A2. The ratio of 1 is :

A2

(1)

16.

M+m

M

1/ 2

M

(2)

M+m

1/ 2

M+m

(3)

M

(4)

M

M+m

**Water is flowing continuously from a tap having an internal diameter 8 × 10−3 m . The water velocity as it
**

leaves the tap is 0.4 ms−1. The diameter of the water stream at a distance 2 × 10 −1m below the lap is

close to :

(2) 9.6 × 10 −3 m

(3) 3.6 × 10 −3 m

(4) 5.0 × 10 −3 m

(1) 7.5 × 10 −3 m

FIITJEE (Hyderabad Classes) Limited. 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Phone: 040-66777000 – 03 Fax: 040-66777004

Of the given four alternatives after the statements. respectively : 3 (2) 330 K and 268 K (3) 310 K and 248 K 1 . (Opp.2% (3) decrease by 0. 18. Statement-2 is true. Statement-2 is true. (2) 2. FIITJEE (Hyderabad Classes) Limited.05% (4) increases by 0.3 × 107 Ω (4) 1. Statement-2 is false. 5-9-14/B. Statement-2 is true.7 × 106 Ω (3) 3.AIEEE−2011−4 17. m2 and m3 and the number of molecules are n1. Statement-2 : The centre of the interference pattern is dark. Assuming no loss of energy.7 × 105 Ω 21. (3) Statement-1 is false. (3) Statement-1 is false. Statement-2 : The state of ionosphere varies from hour to hour. These signals are in general.2% (2) decrease by 0.3 × 10 4 Ω A Carnot engine operating between temperatures T1 and T2 has efficiency 1 . T2 and T3 are mixed. the reflected wave suffers a phase change of π. (1) Statement-1 is true. If a wire is stretched to make it 0.4 ) (1) 1. (4) Statement-1 is true. A pulley of radius 2 m is rotated about its axis by a force F = 20t − 5t 2 Newton (where t is measured in ( ) seconds) applied tangentially. When T2 is lowered by 62 6 K. Statement-1 : Sky wave signals are used for long distance radio communication. its efficiency increases to (1) 372 K and 330 K (4) 372 K and 310 K 22. choose the one that best describes the two statements. The masses of molecules are m1. this film gives an interference pattern due to light reflected from the top (convex) surface and the bottom (glass plate) surface of the film. Statement-1 : When light reflects from the air-glass plate interface. Three perfect gases at absolute temperatures T1. is : (1) more than 3 but less than 6 (2) more than 6 but less than 9 (3) more than 9 (4) less than 3 20. less stable than ground wave signals. day to day and season to season. Phone: 040-66777000 – 03 Fax: 040-66777004 . Across the capacitor is a neon bulb that lights up at 120 V. Statement-2 is the correct explanation of Statement-1. ( log10 2. (2) Statement-1 is true. Statement-2 is not the correct explanation of Statement-1. Statement-2 is true. 500 063.1% longer. Then T1 and T2 are. Statement-2 is true. Statement-2 is the correct explanation of Statement-1. A thin air film is formed by putting the convex surface of a plane – convex lens over a plane glass plate. With monochromatic light. Statement – 1 and statement – 2. A resistor ‘R’ and 2µF capacitor in series is connected through a switch to 200 V direct supply. Statement-2 is true. (1) Statement-1 is true. choose the one that describes the statements. (4) Statement-1 is true. Statement-2 is false. Of the four choices given after the statements.05% 23. Statement-2 is not the correct explanation of Statement-1. Secretariat) Hyderabad. Calculate the value of R to make the bulb light up 5 s after the switch has been closed. Saifabad. its resistance will : (1) increase by 0. Direction: The question has a paragraph followed by two statements.5 = 0. If the moment of inertia of the pulley about its axis of rotation made by the pulley before its direction of motion if reversed. (2) Statement-1 is true. n2 and n3 respectively. This question has Statement – 1 and Statement – 2. the final temperature of the mixture is : ( T1 + T2 + T3 ) n T + n2 T22 + n3 T32 n2 T 2 + n22 T22 + n32 T32 n T + n2 T2 + n3 T3 (2) 1 1 (3) 1 1 (4) (1) 1 1 3 n1T1 + n2 T2 + n3 T3 n1T1 + n2 T2 + n3 T3 n1 + n2 + n3 19.

choose the one that best describes the two statements. 500 063. 5-9-14/B. Statement-2 is false. (1) Statement-1 is true. The electrostatic potential inside a charged spherical ball is given by φ = α ρ2 + b where r is the distance from the centre. Ignoring the slight expansion of the water. The speed of the image of the second car as seen in the mirror of the first one is : 1 1 m/s m/s (2) 10m / s (3) 15m / s (4) (1) 15 10 25.8 m behind the first car is overtaking the first car at relative speed of 15 m/s. A second car 2. Saifabad. If the speed of water coming out of the fountain is v. A water fountain on the ground sprinkles water all around it. a. 2 1 of it has decayed and time t1 and of it had decayed is : 3 3 (2) 20 min (3) 28 min (4) 7 min This question has Statement – 1 and Statement – 2. Statement-2 is true. both the Kmax and V0 are also doubled. The approximate time interval ( t 2 − t1 ) between the time t2 when (1) 14 min 30. Statement-2 is true. (Opp. the total area around the fountain that gets wet is : v4 π v4 v2 v4 (1) π 2 (2) (3) π 2 (4) π 2 2g g g g 28. (3) Statement-1 is false. 100g of water is heated from 300C to 500C. the change in its internal energy is (specific heat of water is 4148 J/kg/K): (1) 8. The half life of a radioactive substance is 20 minutes. Then the charge density inside ball is (2) −24π aε0r (3) −6aε0 (4) −24 π aε0r (1) −6aε0r 27. Statement-2 is not the correct explanation of Statement-1.3 eV (2) 108.AIEEE−2011−5 24.1 kJ (4) 4. Secretariat) Hyderabad.4 kJ (2) 84 kJ (3) 2. Statement-2 is true.2 kJ 29. Phone: 040-66777000 – 03 Fax: 040-66777004 . (4) Statement-1 is true. Statement-2 is the correct explanation of Statement-1. Statement-2 : The maximum kinetic energy and the stopping potential of photoelectrons emitted from a surface are linearly dependent on the frequency of incident light. Of the four choices given after the statements.8 eV (3) 122. b are constants.1 eV 26. The maximum kinetic energy and the stopping potential are Kmax and V0 respectively.4 eV (4) 12. (2) Statement-1 is true. FIITJEE (Hyderabad Classes) Limited. Energy required for the electron excitation in Li++ from the first to the third Bohr orbit is : (1) 36. If the frequency incident on the surface doubled. A car is fitted with a convex side-view mirror of focal length 20cm. Statement-1 : A metallic surface is irradiated by a monochromatic light of frequency v > v0 (the threshold frequency).

(1) Statement – 1 is true.AIEEE−2011−6 PART B: MATHEMATICS 31. Saifabad. Statement– 2 is true. If A = sin2 x + cos4 x . bisector of an angle divides the triangle into two similar triangles. (3) (2) -144 { ) 6 (4) 3 ≤ A ≤1 4 is (3)132 (4) 144 } 1 − cos 2 ( x − 2 ) lim x →2 x−2 (1) equals (2) equals − 2 2 (3) equals 1 2 (4) does not exist Statement – 1 : The number of ways of distributing 10 identical balls in 4 distinct boxes such that no box is empty is 9 C3 Statement – 2 : The number of ways of choosing any 3 places from 9 different places is 9 C3 . (Opp. Statement – 2 is not a correct explanation for Statement –1 (2) Statement – 1 is true. 5-9-14/B. Statement – 2 is a correct explanation for Statement – 1 36. (1) Statement – 1 is true. (3) Statement – 1 is false. Statement – 2 is true. Statement – 1 : The ratio PR : RQ equals 2 2 : 5 . The bisector of the acute angle between L1 and L 2 intersect L3 at R . (3) Statement – 1 is false. 3 13 ≤A≤ 4 16 ( The coefficient of x 7 in the expansion of 1 − x − x 2 + x 3 (1) -132 34. Phone: 040-66777000 – 03 Fax: 040-66777004 . d2 x dy 2 equals −1 d2 y dy −3 (1) − 2 dx dx d2 y dy −2 (2) 2 dx dx d2 y dy −3 (3) − 2 dx dx d2 y (4) 2 dx −1 FIITJEE (Hyderabad Classes) Limited. (4) Statement – 1 is true. Statement – 2 is true. Statement – 2 is true. Secretariat) Hyderabad. (4) Statement – 1 is true. 500 063. then for all real x 13 ≤ A ≤1 (2) 1 ≤ A ≤ 2 (1) 16 35. Statement – 2 is not a correct explanation for Statement –1 (2) Statement – 1 is true. The lines L1 : y − x = 0 and L 2 : 2x + y = 0 intersect the line L3 : y + 2 = 0 at P and Q respectively. Statement– 2 is false. Statement – 2 is true. Statement– 2 is false. Statement – 2 : In any triangle. 33. Statement – 2 is a correct explanation for Statement – 1 32. Statement– 2 is true.

200 in each of the first three months of his service. Statement – 2 is not a correct explanation for Statement –1 (2) Statement – 1 is true. 1) 41. 1 (4) . (Opp. Statement – 2 : { } B = {( x. (3) .y ) ∈ R × R : x = αy for some rational number α} is an equivalence relation on R. 4 12 2 2 4 12 42. ∞ ) 44. A man saves Rs. 500 063. His total saving from the start of service will be Rs. 0 ) (3) β ∈ (1. Statement– 2 is false. 0 ) If the angle between the line x = equals 3 (1) 2 (2) 2 5 1 x −x is (3) ( −∞. (4) Statement – 1 is true. 40 more than the saving of immediately previous month. Phone: 040-66777000 – 03 Fax: 040-66777004 . 5-9-14/B. β be real and z be a complex number. If z2 + αz + β = 0 has two distinct roots on the line Re z = 1 . 11040 after (1) 19 months (2) 20 months (3) 21 months (4) 18 months 43. The value of ∫ 0 (1) 40. then it is necessary that (1) β ∈ ( −1. The domain of the function f ( x ) = (1) ( 0. (2) 0. then p lies in the interval 32 3 11 1 11 1 3 (1) . (3) Statement – 1 is false. (1) Statement – 1 is true. Consider 5 independent Bernoulli’s trials each with probability of success p. ∞ ) (2) β = 1 (4) β ∈ ( 0. then y ( ln2 ) is equal to dx (1) 5 (2) 13 (3) -2 If (4) 7 Let R be the set of real numbers Statement – 1 : A = ( x. Secretariat) Hyderabad. dy = y + 3 > 0 and y ( 0 ) = 2 . If the probability of at least 31 one failure is greater than or equal to .AIEEE−2011−7 37. Statement – 2 is true.y ) ∈ R × R : y − x is an int eger is an equivalence relation on R . (2) ( −∞. ∞ ) 5 y −1 z − 3 = and the plane x + 2y + 3z = 4 is cos−1 . π log2 8 8log (1 + x ) 1 + x2 dx is (2) π log2 2 (3) log2 (4) π log2 Let α. 38. Statement– 2 is true. Statement – 2 is true. then λ 14 λ 2 (3) 5 3 (4) 2 3 FIITJEE (Hyderabad Classes) Limited. Saifabad. ∞ ) − {0} (4) ( −∞. In each of the subsequent months his saving increases by Rs. Statement – 2 is a correct explanation for Statement – 1 1 39.

then the value of 2a − b . 2x + 2y + z = 0 possess a non-zero solution is (1) 2 (2) 1 (3) zero (4) 3 Consider the following statements P : Suman is brilliant Q : Suman is rich R : Suman is honest The negation of the statement “Suman is brilliant and dishonest if and only if Suman is rich” can be expressed as (2) ~ Q ↔~ P ∧ R (3) ~ (P∧ ~ R ) ↔ Q (4) ~ P ∧ ( Q ↔~ R ) (1) ~ Q ↔ (P∧ ~ R ) ( 53. Phone: 040-66777000 – 03 Fax: 040-66777004 . ) r 1 r r r r r r and b = 2i$ + 3j$ − 6k$ . (4) 2 a = c If C and D are two events such that C ⊂ D and P (D ) ≠ 0 . then the correct statement among the (1) P ( C | D ) ≥ P ( C ) 52.b (1) a = c 50.c r r b. 500 063. kx + 4y + z = 0 . 5-9-14/B. Then the vector d is equal to rr rr rr rr r a. I k The two circles x 2 + y 2 = ax and x 2 + y 2 = c 2 ( c > 0 ) touch each other if following is 51.c r r b.b a.c r r a. k (T − t) ) The shortest distance between line y − x = 1 and curve x = y 2 is (1) 3 2 8 (2) 8 3 2 (3) 4 3 (4) 3 4 FIITJEE (Hyderabad Classes) Limited.b a. Saifabad.c r (2) b + r r c (3) c − r r b (4) b − r r c (1) c + r r b a. where k > 0 is a dt constant and T is the total life in years of the equipment. Then the scrap value V ( T ) of the equipment is The value V ( t ) depreciates at a rate given by differential equation (1) I − 48.d = 0 . (2) 5 ( ) ( (3) 3 ) ( ) (4) -5 Equation of the ellipse whose axes are the axes of coordinates and which passes through the point 2 is ( −3.AIEEE−2011−8 45.b a. kT 2 2 (2) I − 2 2 (3) e −kT (2) a = 2c (3) a = 2c (2) P ( C | D ) < P ( C ) (3) P ( C | D ) = P (D ) P (C) (4) P ( C | D ) = P ( C ) The number of values of k for which the linear equations 4x + ky + 2z = 0 . Secretariat) Hyderabad. 49. (3i$ + k$ ) 10 r If a = 1 ( (1) -3 46. dV ( t ) = −k ( T − t ) . 1) and has eccentricity 5 (1) 5x 2 + 3y 2 − 48 = 0 47. a × b × a + 2b is 7 (2) 3x 2 + 5y 2 − 15 = 0 (3) 5x 2 + 3y 2 − 32 = 0 (4) 3x 2 + 5y 2 − 32 = 0 Let I be the purchase value of an equipment and V ( t ) be the value after it has been used for t years. (4) T 2 − r r r r r r r r The vector a and b are not perpendicular and c and d are two vectors satisfying: b × c = b × d and rr r a. (Opp.

Statement – 2 is not a correct explanation for Statement –1 (2) Statement – 1 is true. Then f has 0 (1) local minimum at π and 2π (2) local minimum at π and local maximum at 2π (3) local maximum at π and local minimum at 2π (4) local maximum at π and 2π FIITJEE (Hyderabad Classes) Limited. Then ( A. Statement – 2 is a correct explanation for Statement – 1 57. Statement – 2 : (1) Statement – 1 is true. is 5 1 3 1 1 3 1 3 (1) p = . Saifabad. 7 ) is the mirror image of the point B (1. 5-9-14/B. Statement – 1 : AB is symmetric matrix if matrix multiplication of A and B is commutative. Statement – 2 is true. 2a. (4) Statement – 1 is true. 3 ) . 500 063. x<0 x The value of p and q for which the function f ( x ) = q . …. q = (3) p = . 1) sin ( p + 1) x + sin x . 1) 58. Secretariat) Hyderabad. 2 x ∫ t sin t dt . (2) (1. 1 2 3 x y −1 z − 2 bisects the line segment joining A (1. 50a is 50. Statement – 2 is a correct explanation for Statement – 1 56. x>0 x3 / 2 is continuous for all x in R. If the mean deviation about the median of the numbers a. define f ( x ) = For x ∈ 0. (4) Statement – 1 is true. q = − 2 2 2 2 2 2 2 2 1 and the positive x-axis is The area of the region enclosed by the curves y = x. Statement– 2 is true. q = (4) p = . If ω ( ≠ 1) is a cube root of unity. (3) Statement – 1 is false. 0) (3) (-1. Statement – 2 is true. x = e. x=0 x + x2 − x . Statement – 2 is true. 59. 1) (4) (0. then a equals (1) 3 55. 0. Statement – 2 : The line: = = 1 2 3 (1) Statement – 1 is true. A (BA ) and ( AB ) A are symmetric matrices. (3) Statement – 1 is false. 6. B ) equals 7 (1) (1. 60. Let A and B be two symmetric matrices of order 3. Statement– 2 is false. y = x 3 5 1 square units (3) square units (4) square units (1) 1 square units (2) 2 2 2 5π . q = (2) p = − . Statement–2 is not a correct explanation for Statement – 1 (2) Statement – 1 is true. Statement– 2 is false. and (1 + ω) = A + Bω . Statement– 2 is true. 7 ) and B (1. Phone: 040-66777000 – 03 Fax: 040-66777004 . 0. 6. Statement – 1 : (2) 4 (3) 5 (4) 2 The point A (1. Statement–2 is true. (Opp. 3 ) in the line x y −1 z − 2 = = .AIEEE−2011−9 54.

Some of the CO2 is converted into CO on the addition of graphite.0 M (3) p (H2 ) = 2 atm and H+ = 2. Saifabad. The mixture of the products contains sodium trichloroacetate and another compound. 2. Sodium ethoxide has reacted with ethanoyl chloride. Phone: 040-66777000 – 03 Fax: 040-66777004 . Boron cannot form which one of the following anions ? (1) BH−4 71. 5-9-14/B. The strongest acid amongst the following compounds is : (1) HCOOH (2) CH3CH2CH ( Cl ) CO2H (4) CH3COOH (3) ClCH2CH2CH2COOH 67.8 atm. A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. 2-Trichloroethanol 64. Secretariat) Hyderabad. Chlorine is more easily liquefied than ethane because (1) a and b for Cl2 < a and b for C2H6 (2) a for Cl2 < a for C2H6 but b for Cl2 > b for C2H6 (3) a for Cl2 > a for C2H6 but b for Cl2 < b for C2H6 (4) a and b for Cl2 > a and b for C2H6 69.0 M (4) p (H2 ) =1 atm and H+ = 2. The reduction potential of hydrogen half cell will be negative if : (1) p (H2 ) = 1 atm and H+ =1. 2. Trichloroacetaldehyde was subjected to Cannizzaro’s reaction by using NaOH. 2-Trichloropropanol (3) Chloroform (4) 2. `a’ and `b’ are van der Waals’ constants for gases.0 M 66.0 M (2) p (H2 ) =2 atm and H+ =1. A xB y is related to van’t Hoff factor (i) by the expression : i −1 (1) α = x + y +1 (2) α = x + y −1 i −1 (3) α = x + y +1 i −1 (4) α = i −1 ( x + y − 1) 68. The degree of dissociation ( α ) of a weak electrolyte. the value of K is (1) 3 atm (2) 0.8 atm 70. (2) B ( OH)4 − (3) BO2− (4) BF63− Which of the following facts about the complex Cr (NH3 )6 Cl3 s wrong ? (1) The complex is paramagnetic (2) The complex is an outer orbital complex (3) The complex gives white precipitate with silver nitrate solution (4) The complex involves d2 sp3 hybridization and is octahedral in shape.18 atm (4) 1. FIITJEE (Hyderabad Classes) Limited. If the total pressure at equilibrium is 0. The presence or absence of hydroxyl group on which carbon atom of sugar differentiates RNA and DNA ? (2) 3rd (3) 4th (4) 1st (1) 2nd 63. The compound that is produced in the above reaction is : (1) 2-Butanone (2) Ethyl chloride (3) Ethyl ethanoate (4) Diethyl ether 65.AIEEE−2011−10 PART C: CHEMISTRY 61. 500 063. The other compound is : (1) Trichloromethanol (2) 2. Among the following the maximum covalent character is shown by the compound : (1) SnCl2 (2) AlCl3 (3) MgCl2 (4) FeCl2 62.3 atm (3) 0. (Opp.

78.N bond is weaker than the single P – P bond. sp. which of the following statements is not correct ? (1) All the members exhibit +3 oxidation state (2) Because of similar properties the separation of lanthanoids is not easy. 5-9-14/B. 82. A 5. In context of the lanthanoids.83 BM is (3) 1. The rate of a chemical reaction doubles for every 10o C rise of temperature. is supplied.100 79.086 (3) 0. (3) N2O4 has two resonance structures (4) The stability of hydrides increases from NH3 to BiH3 in group 15 of the periodic table 80. (4) 4f 3 4d5 6s2 Which of the following statements regarding sulphur is incorrect ? (1) The vapour at 200o C consists mostly of S8 rings (2) At 600o C the gas mainly consists of S2 molecules (3) The oxidation state of sulphur is never less than +4 in its compounds (4) S2 molecule is paramagnetic. The outer electron configuration of Gd (Atomic No : 64 is : (1) 4f 8 5d0 6s2 (2) 4f 4 5d4 6s2 (3) 4f 7 5d1 6s2 81. sp3 77. sp3 . (3) Availability of 4f electrons results in the formation of compounds in +4 state for all the members of the series. sp3 (2) sp.050 (4) 0. (2) 2. sp3 .NO2+ and NH+4 are respectively : (1) sp2 . The magnetic moment (spin only) of [NiCl4 ] 2− (1) 5. the rate of the reaction increases by about : (1) 24 times (2) 32 times (3) 64 times (4) 10 times 75.30g (2) 400. 500 063.190 (2) 0. What is the mole fraction of methyl alcohol in the solution ? (1) 0. (2) Single N.AIEEE−2011−11 72. Saifabad.86 K kg mol −1 .pπ bond. Phone: 040-66777000 – 03 Fax: 040-66777004 . Mass of ethylene glycol which should be added to 4 kg of water to prevent it from freezing at −6o C will be : [ K f for water = 1.46 BM 76. Which of the following statement is wrong ? (1) Nitrogen cannot form dπ . CH3OH . (Opp. Which one of the following order represents the correct sequence of the increasing basic nature of the given oxides ? (1) MgO < K 2O < Al2O3 < Na2O (2) Na2O < K 2O < MgO < Al2O3 (4) Al2O3 < MgO < Na2O < K 2O (3) K 2O < Na2O < Al2O3 < MgO 74.41 BM (4) 1. Secretariat) Hyderabad. Ethylene glycol is used as an antifreeze in a cold climate. sp (4) sp. sp2 (3) sp2 . and molar mass of ethylene glycol = 62g mol −1 ) (1) 204.82 BM The hybridization of orbitals of N atom in NO3− . If the temperature is raised by 50o C . sp2 .32g 73. (4) There is a gradual decrease in the radii of the members with increasing atomic number in the series.60 g (4) 804.00 g (3) 304.2 molal aqueous solution of methyl alcohol. The structure of IF7 is : (1) trigonal bipyramid (2) octahedral (3) pentagonal bipyramid (4) square pyramid FIITJEE (Hyderabad Classes) Limited.

500 063. The entropy change involved in the isothermal reversible expansion of 2 moles of an ideal gas from a volume of 10 dm3 to a volume of 100 dm3 at 27o C is : (1) 35.8J mol −1K −1 (2) 32.AIEEE−2011−12 83. Secretariat) Hyderabad. the other is at : (1) 325 nm (2) 743 nm (3) 518 nm (4) 1035 nm 85.Tribromophenol (4) 2-Bromophenol 88. atom A occupies the corner positions and atom B occupies the face centre positions. 5-9-14/B. A gas absorbs a photon of 355 nm and emits at two wavelengths.Butene FIITJEE (Hyderabad Classes) Limited. In a face centred cubic lattice. the formula of the compound is : (1) AB2 (2) A 2B3 (3) A 2B5 (4) A 2B 89. The major product obtained in the above reaction is (1) 3-Bromophenol (2) 4-Bromophenol (3) 2. 4. Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence of : (1) a vinyl group (2) an isopropyl group (3) an acetylenic triple bond (4) two ethylenic double bonds 84. (Opp. If one of the emissions is at 680 nm. Silver Mirror test is given by which one of the following compounds ? (1) Acetone (2) Formaldehyde (3) Benzophenone (4) Acetaldehyde 86. Phone: 040-66777000 – 03 Fax: 040-66777004 . If one atom of B is missing from one of the face centred points. (1) Lactic acid (2) 2-Pentanone (3) Phenol (4) 2. Phenol is heated with a solution of mixture of KBr and KBrO3. 6. Identify the compound that exhibits tautomerism. Which of the following reagents may be used to distinguish between phenol and benzoic acid ? (1) Tollen’s reagent (2) Molisch reagent (3) Neutral Fe Cl3 (4) Aqueous NaOH 87.3J mol−1K −1 (4) 38. Saifabad.3J mol−1K −1 (3) 42.3J mol−1K −1 90.

10. 500 063. 14. Out of the four options given for each question. 3. the candidates must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However. (Opp. pager etc. will be made if no response is indicated for an item in the Answer Sheet. marked ‘Space for Rough Work’. The candidates are not allowed to do any rough work or writing work on the Answer Sheet. No deduction from the total score. Cases where a candidate has not signed the Attendance Sheet a second time will be deemed not to have handed over the Answer Sheet and dealt with as an unfair means case. however. 4. Each candidate must show on demand his/her Admit Card to the Invigilator. On completion of the test. will another set be provided. 8. only one option is the correct answer. 7. as under no circumstances (except for discrepancy in Test Booklet Code and Answer Sheet Code). No part of the Test Booklet and Answer Sheet shall be detached under any circumstances. Handle the Test Booklet and Answer Sheet with care. 2. 11. one-fourth (1/4) of the total marks allotted to the question would be deducted from the total score. 5-9-14/B. The candidates are also required to put their left hand THUMB impression in the space provided in the Attendance Sheet. is prohibited. 13. Phone: 040-66777000 – 03 Fax: 040-66777004 . No candidate. Secretariat) Hyderabad. the candidates are allowed to take away this Test Booklet with them. electronic device or any other material except the Admit Card inside the examination hall/room. without special permission of the Superintendent or Invigilator. Use of Electronic/Manual Calculator and any Electronic Item like mobile phone. printed or written. All cases of unfair means will be dealt with as per Rules and Regulations of the Board. mobile phone. The candidates are governed by all Rules and Regulations of the Board with regard to their conduct in the Examination Hall. For writing/marking particulars on Side-2 of the Answer Sheet. 12. Candidates are not allowed to carry any textual material. This space is given at the bottom of each page and in 4 pages (Pages 20 – 23) at the end of the booklet. pager. 9. FIITJEE (Hyderabad Classes) Limited. For each incorrect response. All calculations/writing work are to be done in the space provided for this purpose in the Test Booklet itself. bits of papers. should leave his/her seat. The candidates should not leave the Examination Hall without handing over their Answer Sheet to the Invigilator on duty and sign the Attendance Sheet again. Saifabad.AIEEE−2011−13 READ THE FOLLOWING INSTRUCTIONS CAREFULLY 1. use Blue/Black Ball Point Pen only. The candidates should fill in the required particulars on the Test Booklet and Answer Sheet (Side–1) with Blue/Black Ball Point Pen. 6. The candidates should not write their Roll Numbers anywhere else (except in the specified space) on the Test Booklet/Answer Sheet. 15. 5.

52mm = 0. Phone: 040-66777000 – 03 Fax: 040-66777004 . 6. 3 Sol. 3 τ=0 Angular momentum is conserve Iω I1ω1 = I2 ω2 ⇒ ω2 = 1 1 I2 I2 first decreases and then increases ∴ω first increases and then decreases. Sol. Sol. Secretariat) Hyderabad. (Opp. (1) R 1 MR 2 α 2 T ( a = αR ) From (1) and (2) a = …. 3 W = T × ∆A = T × 8π r22 − r12 = 0.t ) = e − ax+ bt 2. Sol. Saifabad. 1 ( ) b a Wave moving in − ve x –direction. 500 063.052cm 100 α …. 5-9-14/B.. 2 Mg –T = Ma T × R = Iα = 1 T = Ma 2 2 V= 1 × 52 = 0.. 1 Sol. 4 φ1 = 0 ( φ2 = ) X0+A π 2 X0 7. Diameter of wire = 3. Sol. Position of the null point from mass m. y ( x.4π mJ 5. (2) 2g 3 a Mg 4.AIEEE−2011−14 SOLUTIONS PART A PHYSICS 1. Sol. x = r 4m 1+ m = A r 3 Gm 3 12 V = −Gm + = −9 r r 2r FIITJEE (Hyderabad Classes) Limited.

15mV 10. at v = 0 ⇒ t = 5 = 2s 2. 500 063.5t + C at t = 0. 5-9-14/B. Normal to the plane is z –axis A 10 1 cos θ1 = z = = .25 ⇒ C = 5 Sol.5 11. θ1 = 60 A 20 2 µ1 sin θ1 = µ 2 sin θ2 ⇒ 2 × 13. Phone: 040-66777000 – 03 Fax: 040-66777004 . Sol. 3 E = BH lV = 0. Sol. 1 Sol. Charge oscillates simple harmonic motion q = q0 sin ωt.5 v dt Integrating the above equation. (Opp.AIEEE−2011−15 8.v = 6. Sol. Secretariat) Hyderabad. U = q= q0 ⇒ ωt = 1 q2 2C π 4 2 T 2π π LC = LC ⇒t= = 8 8 4 12. Sol. 1 dv = −2. 4 At any instant of separation between charges is x. Saifabad. 3 = 3 sin θ2 ⇒ θ2 = 450 2 4 ∧ ∧ µ0 di cos i sin j − θ − θ 2πR T di = Rdθ πR I = dθ π y → dB = → dB = dθ θ θ x ∧ ∧ µ0I cos i sin j − θ − θ 2 2π R FIITJEE (Hyderabad Classes) Limited. ⇒ 2 v = −2. Q2 x equilibrium condition = K 2 = ω 2l x ⇒ Q2 = Cx 3 dQ dx ⇒ 2Q = C3x 2 dt dt 3/2 dx x ⇒ ∝ 2 ∝ x −1/ 2 dt x 9.

Saifabad. Sol. Sol.t1 + n2kT2 + n3kT3 = ( n1 + n2 + n3 ) kT ∴T = 19. K 3 Energy of simple harmonic oscillator is constant. 1 Data ⇒ n.6 × 10 −3 m 17. 18.k. 1 1 ⇒ Mω2 A12 = ( m + M) ω2 A 22 2 2 A12 M + m = M A 22 ∴ 16. Secretariat) Hyderabad.8 × 0. Sol. Sol.4 = πd2 × 4 d ≈ 3. Sol. Phone: 040-66777000 – 03 Fax: 040-66777004 . 1 Since ionospheric properties change with time. Sol. (Opp.AIEEE−2011−16 µ0I ∧ j π 2R → B=− 14.2 v 2 − u2 = 2gh is used 2 vb = 2m/s (nearly) π 8 × 10 −3 × 0.4 ) = 2 × 9. 500 063. n1T1 + n2 T2 + n3 T3 n1 + n2 + n3 1 r×F=I×α 2 20t − 5t 2 = 10α ⇒ α = 4t − t 2 ( ) dω = 4t − t 2 dt ( ) dω = 4t 2 − t 2 dt 3 t (on integration) 3 ω = 0 ⇒ t = 6s ω = 2t 2 − FIITJEE (Hyderabad Classes) Limited. 5-9-14/B. 2R A1 M+m = A2 M 3 Equation of continuity ⇒ ( a × v ) top = ( a × v ) bottom v b2 − ( 0. 3 W = ∆U 1 mv 2 = nCv dT 2 m R dT = M γ −1 M ( γ − 1) v 2 dT = 15. these signals are in general less stable than ground wave signals.

2 Vc = E 1 − e − t / Rc ( ) 120 3 = 200 5 5 ⇒R= = 2. Sol.7 × 106 Ω −6 1. 4 Sol.2% FIITJEE (Hyderabad Classes) Limited. Saifabad.1% resistance increases by 0. 1 R ∝ l 2 (for a given volume) ∆R 2 ∆l ⇒ %= % l R Thus when wire is stretched by 0. 5-9-14/B. η1 = η2 = ⇒ T1 − T2 1 = T1 6 T1 − ( T2 − 62 ) T1 = 1 3 T1 − T2 62 1 + = T1 T1 3 1 62 1 + = 6 T1 3 62 1 = T1 6 ∴ T1 = 62 × 6 = 372K T1 − T2 1 = T1 6 1− T2 1 = T1 6 T2 5 = 372 6 ⇒ T2 = 310K 22.84 × 10 1 − e − t / Rc = 21.AIEEE−2011−17 ω= dθ t3 = 2t 2 − dt 3 t3 dθ = 2t 2 − dt 3 2t 3 t 4 − (on integration) 3 12 θ ( in 6s ) = 36rad ⇒θ= ⇒ 2πn = 36 36 n= =< 6 2π 20. 500 063. Phone: 040-66777000 – 03 Fax: 040-66777004 . Sol. (Opp. Secretariat) Hyderabad.

Secretariat) Hyderabad.4 ) ELi + + = −13. Saifabad. 500 063.6 − ( −122. range = u2 v2 i.. So charge density is constant φnet = ( −2ar ) 4πr 2 = −8πar 3 −8πar = 3 σ× 4 3 πr 3 ε0 ∴ σ = −6aε0 27. Max. dv v 2 du =− 2 dt u dt f = 20 cm 1 1 1 + = u −280 20 280 cm ⇒v= 15 2 280 vI = − × 15 15 × 280 1 m/s = 15 25. Sol.4eV 1 9 ELi ++ + = −13. 24. 1 1 1 1 + = v u f 1 dv 1 du − 2 − =0 v dt u2 dt Sol. En = −13. (radius of circle) g g 2 v2 πv 4 Area occupied = π = 2 g g FIITJEE (Hyderabad Classes) Limited. (Opp. Phone: 040-66777000 – 03 Fax: 040-66777004 .6 × = 108. 1 As light enters from air to glass it suffers a phase change on π and therefore at centre there will be destructive interference. 5-9-14/B. 3 Potential inside (φ) = ar2 + b δv ∴ Er = − = −2ar δr Electric field inside uniformly charged solid volume varies with ‘r’. 2 Sol.6 Z2 n2 9 = −122.6eV 9 ∆E = −13. 1 Sol.e.AIEEE−2011−18 23.6 × = −13.8 eV 26. Sol.

Secretariat) Hyderabad. 3 KEmax = hυ − hυ0 hυ − hυ0 = e × ∆v hυ hυ0 − e e ‘υ’ is doubled KEmax = 2hυ − hυ0 2hυ hυ0 V0′ = ( ∆V )′ = − e e KEmax may not be equal to 2 KEmax V0 = ⇒ V0′ may not equal to 2 V0 KE max = hυ .368kJ 29.693 = ln = λ 2 λ = 20 min 30. Sol. (Opp. 1 ∆Q = ∆U + ∆W (ignoring expansion) ∆U = ms∆T = 0. 500 063.hυ0 hυ hυ0 V= − e e FIITJEE (Hyderabad Classes) Limited.1× 4. 5-9-14/B. Sol.AIEEE−2011−19 28.184 × 20 = 8. Sol. Phone: 040-66777000 – 03 Fax: 040-66777004 . Saifabad. 2 t 1 = 20 minutes 2 N = N0 e − λt2 λt1 = ln3 2 1 N0 = N0 e − λt2 t1 = ln3 3 λ 2 N0 = N0 e − λt2 3 1 3 t 2 = ln λ 2 1 3 t 2 − t1 = ln − ln3 λ 2 1 1 0.

Q = (1.AIEEE−2011−20 PART B: MATHEMATICS 31. 4 Sol: A = sin2 x + cos4 x = 33. 2 Sol: 1 − x − x 2 (1 − x ) = (1 − x )6 1 − x 2 7 + cos 4x 3 ⇒ ≤ A ≤1 8 4 6 ( ) 6 = 6 C0 − 6 C1x + 6 C2 x 2 − 6 C3 x 3 + 6 C4 x 4 − 6 C5 x 5 + 6 C6 x 6 × 6 C0 − 6 C1x 2 + 6 C2 x 4 − 6 C3 x 6 + . L. 4 Sol: lim x →2 lim 2sin2 ( x − 2 ) x−2 2 sin ( x − 2 ) x−2 R. = 2 .H.. Secretariat) Hyderabad. Saifabad. − 2 ) . 2 Sol: Q R L2 = 0 • y+2=0 P O L1 = 0 L3 = 0 P ( −2.. It is correct explanation. FIITJEE (Hyderabad Classes) Limited. = − 2 Limit does not exist. x →2 35. Phone: 040-66777000 – 03 Fax: 040-66777004 . 5-9-14/B. (Opp..L. − 2 ) Equation of angular bisector OR is ( ) ( 5 +2 2 x = ) 5− 2 y ∴ PR : RQ = 2 2 : 5 32. 7 6 6 6 6 6 6 Coefficient of x = C1 C3 − C3 C2 + C5 C1 = 120 − 300 + 36 = −144 34. 500 063.H. Sol: 4 (n −1) C(r −1) = (10 −1) C(4 −1) = 9 C3 Statement 1 is correct Statement 2 is also correct From 9 we can select 3 in 9 C3 ways.L.

Hence statement – 1 is true. x Also = 1 is a rational number ⇒ B is reflexive x x y = α is rational ⇒ need not be rational y x 1 0 is rational ⇒ is not rational 0 1 Hence B is not symmetric ⇒ B is not an equivalence relation. 5-9-14/B.e. Saifabad. Sol: −2 d2 y dy −3 1 d dy = − 2 dy dx dx dx dx dx 4 dy dy = y+3⇒ = dx dx y+3 ln ( y + 3 ) = x + c x=0⇒y=2 ⇒ ln5 = 0 + c c = ln5 ln ( y + 3 ) = x + ln5 y + 3 = e x +ln 5 ⇒ y + 3 = eln 2 +ln 5 y + 3 = 10 ⇒ y = 7 38. ⇒ ( x − y ) + ( y − z ) = x − z is an integer ⇒ A is transitive.. (Opp. Phone: 040-66777000 – 03 Fax: 040-66777004 . Secretariat) Hyderabad. Sol: 2 x − y is an integer x − x = 0 is an integer ⇒ A is Reflexive x − y is an integer ⇒ y − x is an integer ⇒ A is symmetric x − y. FIITJEE (Hyderabad Classes) Limited. i. 3 Sol: d dx d 1 1 d dy =− = 2 dy dy dy dy dy dy dx dx dx dy = − dx 37. 500 063. y − z are integers As sum of two integers is an integer.AIEEE−2011−21 36.

∞ ) p ≠ 0 since roots are distinct. 5-9-14/B. 1 − pi Product of roots = β = 1 + p2 ∈ (1. 41. Phone: 040-66777000 – 03 Fax: 040-66777004 . (Opp. 4 Sol: I=8 1 ∫ 0 π 4 =8 ∫ 0 π 4 log (1 + x ) 1 + x2 dx log (1 + tan θ ) 1 + tan2 θ sec 2 θ dθ ( let x = tan θ ) π 4 π 4 π 4 1 − tan θ π = 8 log 1 + tan − θ dθ = 8 log 1 + dθ = 8 log2 dθ − 8 log (1 + tan θ ) dθ 4 1 + tan θ 0 0 0 0 ∫ ∫ ∫ ∫ π −I 4 2I = 2π log2 I = π log2 = 8log2 40. Sol: 2 n=5 Success = p Failure = q P (at least one failure) ≥ 1 – P (no failure) ≥ 31 32 31 32 31 32 31 1 − 5 C5p5 ≥ 32 1 −p5 ≥ − 32 1 p5 ≤ 32 1 p≤ 2 1 p ∈ 0. Sol: 3 Suppose roots are 1 + pi.AIEEE−2011−22 39. 500 063. 1 + qi Sum of roots 1 + pi + 1 + qi = −α which is real ⇒ roots of 1 + pi. Saifabad. Secretariat) Hyderabad. 2 1− P ( x = 5) ≥ FIITJEE (Hyderabad Classes) Limited.

Saifabad.b ) = −5 2 2 2 46. Phone: 040-66777000 – 03 Fax: 040-66777004 . 4 Sol: cos θ = 5 14 3 sin θ = 14 1 + 4 + 3λ sin θ = 1 + 4 + λ2 1 + 4 + 9 3 5 + 3λ 2 = ⇒λ= 2 3 14 5 + λ 14 45. Sol: 4 ( 2a − b).(a + 2b) b − b. 500 063. ……. Sol: 3 1 2 3 4 200 200 200 240 Sum = 11040 120 + 80 + 160 + 40 + 200 + 240 + … = 11040 n 2a + ( n − 1) d + 80 + 40 = 11040 2 n 240 + ( n − 1) 40 = 10920 2 n 6 + n − 1 = 546 5 6 …… 280 ……. 0 ) 44. 2 1 Sol: ⇒ x − x > 0 ⇒ x > x ⇒ x is negative x −x x ∈ ( −∞.AIEEE−2011−23 42.{a. (Opp.{(a × b) × (a + 2b )} = ( 2a − b ).. 4 Sol: 2 3 3a2 b2 = a 2 1 − e 2 = a 2 1 − = a 2 = 5 5 5 ( x2 a 2 + y2 2 b 32 a2 = 3 32 b2 = 5 ) =1⇒ 9 a 2 + 5 3a2 =1 ∴ Required equation of ellipse 3x 2 + 5y 2 − 32 = 0 FIITJEE (Hyderabad Classes) Limited.(a + 2b ) a} = −5 ( a ) ( b ) + 5 ( a. Secretariat) Hyderabad. n ( n + 5 ) = 546 n = 21 43. 5-9-14/B.

c ∴d = c − b a.b ) c = − ( a. Sol: 1 dV = −k ( T − t ) ⇒ dV = −k ( T − t ) dt dt Integrate V= −k ( T − t ) 2 ( −2 ) +c ⇒ V = k (T − t) 2 2 +c at t = 0 ⇒ V = I I= kT 2 kT 2 kT 2 + c ⇒ c = I− ⇒ c = V (T) = I − 2 2 2 48. 500 063.c ) b − ( a. 5-9-14/B. r2 = c 2 a a c1c 2 = r1 − r2 ⇒ = c − ⇒ c = a 2 2 1 C P (C ∩ D) C ∩ D = C ⇒ P (C ∩ D) = P (C) ⇒ P = ≥ P (C) P (D ) D 1 4 k 2 k 4 1 = 0 ⇒ k 2 − 6k + 8 = 0 ⇒ k = 4. Sol: 1 a c1 = . 0 . Phone: 040-66777000 – 03 Fax: 040-66777004 . 0 ) 2 a r1 = .AIEEE−2011−24 47.b ) c = ( a. 2 2 2 1 1 ~ ( P∧ ~ R ) ↔ Q =~ Q ↔ (P∧ ~ R ) { } { } FIITJEE (Hyderabad Classes) Limited. 3 Sol: b×c = b×d ( ) ( ) ⇒ ( a. Sol: 52.b ) d ⇒ ( a. Sol: 51. (Opp.b ) d ⇒ a× b×c = a× b×d a.c ) b − ( a. c 2 = ( 0.b 49. Saifabad. Sol: 50. Secretariat) Hyderabad.d) b − ( a.

Phone: 040-66777000 – 03 Fax: 040-66777004 . Saifabad..6. (Opp.5a} = 50 50 ⇒ 625a = 2500 ⇒ a = 4 A = Median = { 55. Secretariat) Hyderabad.. 5-9-14/B. ( 0.5a + 23.5a ) 50 50 2 (Given) = {312.3) 1. Sol: } { } 1 B (1.5a 2 1 2 a − 25. 1 Sol: P = y2 . 2.5a ) + . BT = B ( A (BA ) ) = (BA )T A T = ( A TBT ) A = ( AB ) A = A (BA ) T ( ( AB ) A ) = A T ( AB )T = A (BT A T ) = A (BA ) = ( AB ) A T ∴ Statement – 1 is correct Statement – 2 ( AB )T = BT A T = BA = AB (Q AB is commutative) Statement – 2 is also correct but it is not correct explanation of Statement – 1 FIITJEE (Hyderabad Classes) Limited.5a + 2a − 25. 3 •A (1.5a = Mean deviation = ( 24.0.7) Statement – 1 : AB is perpendicular to given line and mid point of AB lies on line Statement – 2 is true but it is not correct explanation as it is bisector only. 56. Sol: 2 1 n 1 4ac − b2 4a 2 3 = 4 2 ∑ x −A i 25a + 26a = 25. If it is perpendicular bisector then only statement – 2 is correct explanation. 500 063.AIEEE−2011−25 53. Sol: 1 A T = A. y ( ) Perpendicular distance from P to x − y + 1 = 0 is y2 − y + 1 2 y 2 − y + 1 > 0 ∀y ∈ R ∴ Coefficient y 2 > 0 ∴ Min value = 54.

Sol: x →0 2 1 ∫ Area = x dx + 0 60.AIEEE−2011−26 57. 500 063. Sol: e 1 O e 1 1 3 ∫ x dx = 2 + 1 = 2 1 3 f ' ( x ) = x sin x 5π Given x ∈ 0. Sol: 1 1+ ω = −ω2 (1 + ω)7 = ( −ω2 ) 58. local min at 2π FIITJEE (Hyderabad Classes) Limited. q = 2 2 2 x x →0 59. 2 f ' ( x ) changes sign from +ve to –ve at π f ' ( x ) changes sign from -ve to +ve at 2π f has local max at π . (Opp. B ) = (1. 1) 2 lim sin ( p + 1) + sin x = q = lim x + x2 − x x3 / 2 1 lim ( p + 1) cos ( p + 1) x + cos x = q = x →0 2 1 3 1 ⇒ p + 1+ 1 = ⇒ p = − . Secretariat) Hyderabad. Saifabad. 7 = −ω14 = −ω2 = 1 + ω = A + Bω ⇒ ( A. Phone: 040-66777000 – 03 Fax: 040-66777004 . 5-9-14/B.

(Opp.0591 −. other one is reduced to Alcohol. Saifabad. 2. The +I effect of C3H7 is less than .0591 2 = log10 = × .α + nα = 1 + α ( n − 1) i −1 =α n −1 A xB y → xA + y + yB− x n = x+y So α = i −1 x + y −1 FIITJEE (Hyderabad Classes) Limited. 5-9-14/B. Sol : 65. Sol : (1) In RNA.059 log H+ 2 (here E is –ve when P > H+ 2 ) H2 −0. Phone: 040-66777000 – 03 Fax: 040-66777004 .AIEEE−2011−27 PART C: CHEMISTRY 61. Sol : (4) i = 1.Trichloro ethanol (3) ( −) ⊕ C2H5 O N a + CH3 − C − Cl || O → CH3 − C − O − C2H5 Ethyl ethanoate || O (2) 2H+ + 2e− → H2 (g) P H2 E = Eo − 0. Sol : (2) Greater charge and small size of cation cause more polarization and more covalent is that compound 62.3010 = negative value 2 2 1 66.I effect of Cl Ka of HCOOH is 17. where as in DNA the Sugar is β -D-2-deoxy Ribose 63. 500 063. the sugar is β − D − Ribose. 2. (4) Sol : 64.9 × 10−5 K a of CH3 CH2 CH− COOH is 139 × 10 −5 | Cl 67. Sol : OH( − ) 2CCl3 CHO → CCl3 COONa + CCl3 CH2OH Cannizaro reaction is a disproportionation reaction One aldehyde molecule is oxidized to salt of the carboxylic Acid. Sol : (2) Electron releasing groups (Alkyl groups) de stabilizes conjugate base. So the compound is CCl3 CH2OH IUPAC Name is 2. Secretariat) Hyderabad. .

5-9-14/B. 0. 2py & 2pz) it can show a maximum valency of four only.8 p + x Kp = 70.of moles = p + x.49. k1 50 210 = 25 = 32 = k2 k1 Therefore 32 k1 = k 2 FIITJEE (Hyderabad Classes) Limited.86 × Therefore w 2 = 800g w 2 × 1000 4000 × 62 73. Secretariat) Hyderabad. 72. 500 063.2 (4) As Boron has only four orbitals in the valence shell ( i.0562 ease of liquefaction ∝ (4) CO2 (g) + C Sol : 2CO(g) Initial moles p O Equilibriumm moles p-x 2x Total pressure at equilibrium = 0.6 × 0.6 = = 1. (Opp. 2s. Total no. (3) a b for ethane a = 5.5 p Therefore p ∝ n . Sol : 69. 2px. (4) Sol : ∆Tf = K f × m = K f × w 2 × 1000 w 1 × m2 w1 & w 2 = wt of solvent & solute respecting m2 = mw of solute ( ) ∆Tf = 0o − −60 = 6 = 1. Sol : (2) Cr (NH3 )6 Cl3 involves d2 sp3 hybridization and it is an inner orbital complex. Sol : (2) Temperature coefficient µ =2.49.8 atm PCO2 0.3 0.AIEEE−2011−28 68. Sol : 2 PCO 0.0638 for Cl2 a = 6.8 atm . Therefore [BF6 ] 3− is not possible 71. Saifabad. Phone: 040-66777000 – 03 Fax: 040-66777004 .e. b=0. b = 0. = ⇒ x = 0. ∆T µ 10 = k2 . Sol : (4) Across a period metallic strength decreases & down the group it increases 74.

H2 S ) 82.s. (Opp. FIITJEE (Hyderabad Classes) Limited.2 + 18 on ozonolosys give formaldehyde 84. Sol : (2) 1 λ absorbed ⇒ = 1 1 + λ1 λ 2 1 1 1 = + 355 680 λ 2 ⇒ λ 2 = 742.8 ≅ 743 nm 85.AIEEE−2011−29 75. Sol : (1) Vinyl group CH2 = CH − m 1000 m+ 18 5.82BM = 76. Secretariat) Hyderabad. (3) 81. 500 063. 5-9-14/B. Sol : (4) Stability of hydrides decreases down the group from NH3 to BiH3 as M-H bond energy decreases.s of lanthanides is +3. Sol : (2) In [NiCl4 ] . only few elements exhibit +4 o. 80. Saifabad. (2) Sol : Molefraction of solute ( X2 ) in aqueous solution = 79. 78. n = 2 2− n ( n + 2 ) BM µ = 2 ( 2 + 2 ) = 2.09 = 1000 5. Sol : (1) 77. Sol : (2 . Sol : (3) The general o. I undergoes sp3 d3 hybridisation 83. 4) Formaldehyde and Acetaldehyde can be oxidized by tollen’s reagent to give silver mirror. Phone: 040-66777000 – 03 Fax: 040-66777004 . Sol : (3) In IF7 . Sol : (3) `S’ can exhibit a minimum oxidation state of -2 (Ex.2 = 0.

500 063. benzoic acid gives pale dull yellow ppt. Sol : (4) For an ideal gas.303 nR log 2 v1 100 = 2. Secretariat) Hyderabad. for isothermal reversible process. v ∆S = 2. 5-9-14/B. 6trinitrophenol 88. (2.of A atoms = 2 89.AIEEE−2011−30 86. Saifabad. with neutral FeCl3 87. (3) Sol : 1 ×8 =1 8 1 5 Effective no. Phone: 040-66777000 – 03 Fax: 040-66777004 .k −1 90. KBr + KBrO3 in turn produces Br2 . Sol : (3) In acidic medium.314 × log 10 = 38.of B atoms = × 5 ( One is missing) = 2 2 Therefore formula is A1B 5 = A 2B5 Effective no. (Opp. 3) both 2-pentanone. 4. Phenol reacts with Br2 (aq) to give 2. Sol : 2. phenol can exhibit tautomerism FIITJEE (Hyderabad Classes) Limited. Sol : (3) Phenol gives violet coloured comlex compound with neutral FeCl3 .3 J mol−1.303 ×2 × 8.

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