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eA A
600 = [5004 – 3004] + [5004 – 3004] ....(2)
2 2
dividing (2) by (1)
e 1
2=
2 2
e 1 1
2e = e= Ans. ]
e 2 2 3
Q.3
[Sol.
k3
a = M 4 x4 x
3k 3k
2 = ,=
F = 4kx cos2 30°
M M
2 2 2 T1
T =
= T= M t1 = = M
3k / M 3k 2 3k
T2 M
t2 = =
2 k
M M
time period = t1 + t2 =
3k k
1
1 3 Ans.
M
time period = t1 + t2 =
]
k
Q.5
[Sol. In first case
i = k11, i = k22
k11 = k22 ...(1)
In second case
v1 = v2
k11' r1 = k 2 '2 r2 ...(2)
from (1) & (2), we get
2 '1
r2 = r1 ]
1'2
Code-B Page # 1
PHYSICS
Q.7
[Sol. Initially m1g = kx
When support is removed, spring force does not change.
New FBD
Q.10
[Sol. According to given condition,
u= 5gL & v= gL
mu 2
TL = mg + = 6mg
L
mv 2
TH = mg – =0
L
(TL – TH) = 6 mg i.e. independent of temperature ]
Q.14
[Sol.
Code-B Page # 2
PHYSICS
7g 4 mg
T = 2mg – 2m . = mg < ]
9 9 2
Q.15
[Sol. 1 + 2 > 0
µ1 > µ2
>0
1 – 2 > 0 ]
Q.16
u 2y
[Sol. H= uy = 5m/s
2g
24 sin 2uy
T= = = 1 sec
g g
1
=4×t– a × t2 (as a in × direction)
2
5 1
= 4x × 1 – × (0.5) × 12 ux = 3/2 m/sec
4 2
5
Along 2 axis = u2 × 1 v2 = 5/4 m/sec ]
2
PART-B
Q.1
[Sol.(A)For convex lens
| f | Converging power reduces, virtual image is formed closer to lens hence closer to screen
I moves away
if u0
m
thus distance between images increases
(D)
PART-C
Q.1
[Sol: Let is resistance per unit length of wire AB. When k is opened
I (x1) = E1 .........(1)
k is closed
Ix2 = E1 – ir ..........(2)
E1
Rr
i= ..............(3)
x1 0.75
r = x 1 R = 1 24
2 0.60
r=6
Q.2
[Sol. Distance of I1 from mirror = 40 cm
1 1 1 1 1 1 1 1 1
–
10 140
= + = + =
f v u v v 40 10
1 1 4
= v = – 40 / 3 cm
v 40
using magnification formula
I v I 40 / 3
=– 20 tan 1 = –
40
m=
0 u
20 tan 1 20 20
I= = tan ~ × = .
3 3 180 3 180 27
Code-B Page # 4
PHYSICS
20
Co-ordinate of image = ,
3 27
]
Q.4
2kQq
[Sol.
L
2 9 109 3 10 3 5 10 6 3
= 27 ]
R 5
Q.5
[Sol. Wgas + Wspring + Wafter = 0
1
Wgas – × 25 × 103 × (0.2)2 – 105 × 0.05 × 0.4 = 0
2
Wgas = 2500 T = 2.5 kJ ]
Q.6
u = 20 m/s
VA = 20 m/s
aA = 8 m/s2 Bolt (b)
a=g
h = 16m
[Sol.
aB = 2 m/s2
[A] [B] VB = 10 m/s
2 16
= 4s for Bolt (b) : 0 = 30 – 12(t1)
2
T=
30 10 (30) 2 900
t1 = = = 2.5s h1 = =
12 4 2(12) 24
75
h1 =
2
In the ref. frame of B : t = 4s
Vb/B = 30 m/s ab/B = 12m/s2 T = 4s
VA/B = 30 m/s aA/B = 10m/s2 h
for A : SA/B
h1
1
SA/B = 30(4) – (10) (4)2 = 120 – 80 = 40
2
distance = 2h1 + h – SA/B = 75 + 16 – 40 = 51 m t=0
Code-B Page # 5
CHEMISTRY
PART-A
Q.1
[Sol. C4H6 C4H8O
Br Br O
| | ||
CH 3 C — C – CH 3
Br2
CH – C C – CH HgSO
4 CH 3 CH 2 C CH 3
excess 3 3 dil.H 2SO 4
| |
Br Br
Br Br O
| | ||
CH 3 CH 2 — C CH
Br2
CH3 – CH2 – C CH dil.H SO
HgSO 4
CH 3 CH 2 C CH 3 ]
excess 2 4
| |
Br Br
Q.2
[Sol. 2M2Sx + xC 4M + xCS2Not thermodynamically feasible.
However, roasting followed by smelting is thermodynamically feasible.
3x O 2
M2Sx + M2Ox + xSO2 : Roasting In totality
2
the process
M2Ox + xC
2M + xCO : Smelting is feasible
Q.3
[Sol. NBS
alc
. KOH
Ph–CH=CH2
Ph–CH2–CH2–OH Ph CH CH 2 B
H 2 O 2 / NaOH ]
|
H 3
Q.4
[Sol. 2 Br Cl
2 Br2 CCl4 layer becomes red or reddish-Brown.
Water
I¯ ion is oxidised preferably compared to Br¯. Hence I¯ is absent. ]
Q.5
CH3 (+ H)
[Sol.
CD3 (+ H)
+ H of CH3 is more as compared to CD3. So atttack of E+ will take place at ortho position of CH3]
Code-B Page # 1
CHEMISTRY
Q.6
[ NH 4 ]
[Sol. 5 = pKb + log
0.25
[NH4+] = 0.5
[NH3] = 0.25
m moles of KOH added = 50
NH4+ + OH¯ NH3 + H2O
100 50 50
50 0 100
50
pOH = pKb + log
100
pOH = 4.7 – 0.3 4.4
pH = 9.6 Ans. ]
Q.7
KClO4 + NH4
+ + HClO 4 +
[Sol. (K , + NH4 ) ]
Mixture of two White
cations (A) (B) (C)
NaOH
HgO·Hg(NH2)I NH3
K2[HgI4]
KOH (D)
(Brown ppt.)
Q.8
OH OH OH
[Sol. H
/ KMnO 4
]
CH2OH COOH
OH O O
Q.9
Source
100 J
max 1 20%
400 1
[Sol. H.E. 20 J Max ]
500 5
80 J Min
Sink
Q.10
C 2O 24 2H dil
. H No vapours or gas is evolved
2SO 4
[Sol. A:
NO : No reaction with dil H SO
3 2 4
Q.15
[Sol. (A) Isotopic effect is observed in sulphonation.
(B) Salicylic acid gives 2,4,6-tri bromo phenol (i.e. decarboxy bromination takes place)
(C) Product is sec. alcohol.
(D) Products are diastereomers ]
Q.17
[Sol. CaCO3 (S) CaO (S) + CO2 ]
(A) (B)
H2O Ca(OH)2
C
Ca(OH)2 CaCO3
(C) (D)
CO2
BaCO3
Boil Ca(HCO )
BaCl2 Soluble3 2
(White)
Q.18
[Sol. (A) Methane can not prepared by catalytic hydrogenation of alkene
(B) CH3 – CH2 – CH2– CH2 – CH = CH2 CH3 – CH2 – CH2– CH2 – CH2 – CH3
H2
Ni
CH 3 CH CH 2 CH CH 2 CH 3 CH CH 2 CH 2 CH 3
H2
Ni
| |
CH 3 CH 3
CH 3 CH 2 CH CH CH 2 CH 3 CH 2 CH CH 2 CH 3
H2
Ni
| |
CH 3 CH 3
CH 3 C C CH 3
H2
CH 3 CH CH CH 3
Ni
| | | |
CH 3 CH 3 CH 3 CH 3
Code-B Page # 3
CHEMISTRY
CH 3 CH 3
| |
CH 3 C CH CH 2 CH 3 C CH 2 CH 3
H2
Ni
| |
CH 3 CH 3
CH3 CH3
D H D D H
(D)
H2
+ Racemic mixture ]
Ni D H H D (optically inactive)
D
CH3 CH3
PART-B
Q.1
[Sol. A : [Fe(NH3)6]2+, P > 0, Hyb : Sp3d2, eff = 4.9 B.M., number of unpaired electrons = 4
B : [MnO4]–, Hyb : d3s, eff = 0, number of unpaired electrons = 0
C : [Mn(NH3)6]2+, P > 0, hyb. sp3d2, number of unpaired electrons = 5, eff= 5.9 B.M. ]
PART-C
Q.2
(b) + Cl 2
ZnCl 2 H-atoms
O O Me
|| || C Me
(c) + Me 3C C O C CMe3 AlCl
3 Me 9 H-atoms
O
Me O Me
| || C–CH
(d) + Me C C Cl AlCl
3 Me 1 H-atoms ]
|
H
Code-B Page # 4
CHEMISTRY
Q.4
[Sol. Ag2SO3
AgCl
White ppt
Ag2C2O4 Ag3PO4 : yellow
AgNO2 Ag2CrO4 : Red. ]
CH3COOAg
Q.5
[Sol. A 2B + C
1–x 2x x
at 12 hrs
24
10
10 1 2 x
20 =
11 + 2x = 12
1
x=
2
3
At 24 hrs amount reacted = moles
4
24
10
10 1 3 / 2
PH 2O =
= 19.2 Ans. ]
Q.6
0.06 [ Zn 2 ]
[Sol. 0.8 = 1.1 – log
2 Cu 2
[ Zn 2 ]
2
1010
[Cu ]
To get above ratio almost all the Cu+2 will have to be consumed
[Zn+2] = [Zn+2] original + [Zn+2]formed
= 0.1 + 1 = 1.1
Cu = 1.1 × 10–10
+2 ]
Code-B Page # 5
MATHEMATICS
PART-A
Q.1
nx
1 n
[Sol. We have 1 =e ....(1)
n
Taking log on both sides of equation (1), we get
1
(n + xn) ln 1 = 1 –n
1 1
n
n + xn = xn = ....(1)
1 1
l n 1 l n 1
n n
n 1 1
u 1
Let =u nu = n + 1 n=
n
0
Lim x n = Lim 1 1 = Lim ( u 1) ln u form
n u 1
ln u u 1 u 1 ( u 1) ln u 0
1
1 1
u u2 1
u 1
= Lim = Lim = Ans. ]
u 1 u 1
ln u
1 1 2
u u2 u
Q.2
a 13
[Sol. On solving, we get = 13 + 7 = 20 Ans.]
b 7
Q.3
[Sol. We have y Lim f (cos 3 x cos 2 x ) = x Lim f (sin 2 x sin 3 x )
x 0 x 0
cos3x – cos2x 0 from L.H.S. y
Lim f (cos3x – cos2x) = 4 (0, 5)
x 0
(0, 4)
sin2x – sin3x 0 from R.H.S.
Lim f (sin2x – sin3x) = 3
x 0
(0, 3)
x
O
Equation of the line is
4y = 3x ....(1)
3
Equation of line perpendicular to y = x and passing (0, 1), is
y = –x
4 y 3
4 4
y–1= x ....(2) (0, 1)
3 12 9
,
On solving (1) and (2), we get 25 25
x
24 7
,
25 25
Code-B Page # 1
MATHEMATICS
12 9
x= , y=
25 25
24 7
Hence image point is , ]
25 25
Q.4
[Sol. We have f (x) = x3 + x2 f '(1) + x f "(2) + f '"(3)
f '(x) = 3x2 + 2x f '(1) + f "(2) f '(1) = 3 + 2 f '(1) + f "(2) f '(1) + f "(2) + 3 = 0 ....(1)
f "(x) = 6x + 2 f '(1) f "(2) = 12 + 2f '(1)
f '"(x) = 6 f '"(3) = 6
f '(1) = – 5
f "(2) = 2
Hence f (x) = x3 – 5x2 + 2x + 6 ....(2)
Now f (–1) = – 1 – 5 – 2 + 6 = – 2
f (0) = 6 one root (–1, 0)
f (2) = 8 – 20 + 4 + 6 = – 2 One root (0, 2)
Two roots are real All three roots are real.
Also f (5) = 125 – 125 + 10 + 6 = 16 One root (2, 5)
Roots lies in (–1, 0), (0, 2), (2, 5)
Hence all roots are real and distinct. ]
Q.5
[Sol. We have g (t) = – 2 cot–1(3–t)
2
1
g (– t) = – 2 cot–1(3t) = – 2 tan–1(3–t) (As cot–1x = tan–1 , x > 0)
2 2 x
1 t
– 2 cot (3 ) = + 2 cot–1(3–t) (As cot–1x + tan–1x = , x R)
2
=
2 2 2
= – g (t)
Hence g (– t) = – g (t) g is an odd function.
2.3 t ·ln 3
1 (3 t ) 2
Also g' (t) =
Q.6
[Sol. Clearly I3 < I2 < I1 in 0, (D) is correct. ]
4
Q.7
[Sol. Area of rectangle = A = xy ....(i)
36 12
3y = (36 – x)
12 y
Also = .....(ii)
x
Code-B Page # 2
MATHEMATICS
x 1 A
A = (36 – x) = (36x – x2)
3 3
Now A'(x) = 0 36 – 2x = 0 x = 18 (12 – y)
S R 12
1
A'' (x) = (–2) < 0 y
3
36 x 36 18 B
P Q C
Also y= = =6 x
3 3 36
Amax = 18 × 6 = 108 sq. feet ]
Q.8
(3e3x 2e 2 x e x ) (e3x e 2 x e x 1)
ln 2
dx = ln e3x e 2 x e x 1 x ln 2
e e e 1
[Sol. We have T = 3x 2x x
0
0
= ln (8 4 2 1) ln 2 ln 2 0 = ln
11
11 11
– ln 2 = ln e =e 4 =
11 T
ln
Ans. ]
2 4 4
Q.9
x2
t f (t ) dt x x5
4
[Sol. We have F(x2) = ....(1)
0
5
f (r 2 ) = 2 2 r = 24 + 2
12 12
5 (12)(13)
= 24 + (15)(13) = 24 + 195 = 216
r 1 r 1 2
f (r 2 ) = 219
12
Hence Ans.]
r 1
Q.10
[Sol. We have ax3 + bx2 + cx + d = 0
ax 4 bx 3 cx 2
Let f(x) = + + + dx + e
4 3 2
f(0) = e
8b (12a 8b 6c 6d ) 2
f(2) = 4a + + 2c + 2d + e = + e = (6a + 4b + 3c + 3d) + e = 0 + e
3 3 3
f (2) = e
By Rolle’s theorem, there exist atleast one value of x (0, 2) such that f ' (x) = 0
The equation ax3 + bx2 + cx + d = 0 has atleast one real root in [0, 2] ]
Code-B Page # 3
MATHEMATICS
Paragraph for question nos. 11 to 13
[Sol.
(i) We have h''(x) = 6x – 4 h'(x) = 3x2 – 4x + C
As h'(1) = 0 C=1
So, h' (x) = 3x – 4x + 1
2 h(x) = x3 – 2x2 + x + k
Also h(1) = 5 k=5
h(x) = x – 2x + x + 5
3 2
Now h'(2) = 5
The equation of tangent at M(2, 7) to y = h(x), is
(y –7) = 5(x – 2) 5x – y = 3
Also gf ( x ) = 0 x R
Y
(ii)
x4 2 3 x2
2
Required Area =
2
h ( x ) dx x 5 x
0
=
4 3 2 X
x
x=0 1 x=1 x=2
0
3
16 16 32
=4– + 2 + 10 = 16 –
Graph of y = h(x)
= Ans.
3 3 3
(iii) Also range of f g ( x ) = 1, 0, 1
f g ( x ) {0, 1}
Hence range of sin–1 fog(x ) = 0, ]
2
Y
Q.14
1
C
B curve
[Sol. The equation of normal at P(x, y) is (Y – y) = (X x )
dy
dx
1 P(x,y)
:2
dy
A x y , 0 and B 0, y
x
dx dy
X
dx
O (0,0) A
Tangent
Normal
dy
1 x y 2(0)
Now
dx
x x y 3x
dy Y
1 2 dx
2x
dy
y ....(1)
dx (0, 4)
y dy = 2x dx
y2
x2 C
X X
2 (0, –4)
3( h ) 0 [1 (1 h )] 0
3; Lim 1 ]
h
f ' (1+) = Lim f ' (1–) = Lim
h 0 h h 0 h h 0 h
Q.17
1 1 tan 1 x , x 0
= tan–1 x + cot–1 x = xR
x0
[Sol. We have cot 1 and
x tan x , 2
(cot
2
1
cot 1 x )dx
1
Now, let J =
–1
x
3
(cot cot 1 x )dx (cot 1 cot 1 x )dx =
0 2
1
=
1 1 5
=
x x 2 2
–1 0
7 7
Q.18
0
[Sol. We have Lim a f ( x ) x f (a ) =2
ax ax 0
5=c+2 c=3
Hence f (x) = 3x + 2 A 2 0(0,0)
X
,0
1 2 2 3
Clearly area (OAB) = (2) = (square units)
2 3 3
Code-B Page # 5
MATHEMATICS
3x 2
2 2
Also ( 3 x 2 ) dx = 2 x = 6 + 4 = 10 ]
0 2 0
PART-B
Q.1
[Sol.
1 2 1
sin (1 h ) sin (1 h ) cos 1 (1 h 2 ) sin 1 (1 h )
2 Lim
2 h (1 (h ))2
(A) R.H.L. = Lim = h 0
h 0 2 (h h 3 )
k=
2
3 4 h 3 4h
1 1
3 4 h 3 4 h 3 4 h 3 4h
1 1 1 1
Lim
expx 2ln 4 4 16 1
4 16
Now
= ]
x 2
x 2
Code-B Page # 6
MATHEMATICS
PART-C
Q.1
x3
[Sol. We have F(x) = + (a – 3) x2 + x – 13
3
For F(x) to have negative point of local minimum, the equation F '(x) = 0 must have two distinct
negative roots.
Now, F '(x) = x2 + 2(a – 3) x + 1
Following condition(s) must be satisfied simultaneously.
(i) Discriminant > 0; (ii) Sum of roots < 0 ; (iii) Product of roots > 0
Now, D > 0
4(a – 3)2 > 4 (a – 3)2 – 1 > 0 (a – 2) (a – 4) > 0
a (– , 2) (4, ) ........... (i)
Also –2(a – 3) < 0 a–3>0 a > 3 .......... (ii)
And product of root(s) = 1 > 0 a R
(i) (ii) (iii) a (4, ) ....(iii)
Hence sum of value(s) of a = 5 + 6 + 7 + ......... + 100 = 5040 Ans. ]
Q.2
[Sol. We have
(3 x ) 3 (3 x ) 5 (2x )3 (2x )5 x3 x5
3 x ...... A 2 x ..... B x ......
f (0) = Lim 3! 5! 3! 5! 3! 5! ....(1)
x 0 x5
Now f (x) is continuous at x = 0, so we must have
2A + 3 + B = 0 ....(2)
=0
27 8A B
and 8A + B = – 27 ....(3)
6 6 6
On solving (2) and (3), we get
A = – 4, B = 5
Hence f (0) = 1 Ans.
3 sin x 4 sin 3 x 2A sin x cos x B sin x 0
Alternatively: We have f (0) = Lim form
0
....(1)
x 0 x 5
[Nr = 3 + 2A + B = 0]
3 sin x 4 sin 3 x 2A sin x cos x (3 2A) sin x 0
= Lim form
x 0 x5 0
Code-B Page # 7
MATHEMATICS
x x
A 4 cos 2
sin 2
= Lim 2
2
x 0
4 2
x x
4
A+4=0 A= –4 B=5
Also f (0) = 1 Ans.]
Q.3 y
[Sol. Equation of normal is
1 (x,y)
Y – y = – (X – x)
y
m
X + mY – (x + my) = 0 ...... (1) y O (1, 0)
x
Perpendicular distance from (0, 0) to equation (1) is x
x my
=|y|
1 m2
y2 x 2 dy
(x + my)2 = y2 (1 + m2) x2 + 2mxy = y2 m = 2xy = y2 – x2 ....(2)
2 xy dx
dy dt
Put y2 = t = 2y
dx dx
Equation (2) becomes
dt dt 1
x = t – x2 – t = –x
dx dx x
dx
1
e ln x
1
I.F. = e x
x
Now general solution is given by
1 1
t = – x + C y2 = – x + C
x x
As (1, 1) satisfy it, so C = 2
y2 = –x2 + 2x x2 + y2 – 2x = 0
k
Hence required area =
2
k = 1 Ans. ]
Q.4
1
We have F(x) + F x = 3
2
[Sol. ...... (1)
1
in (1), we get F x + F(x + 1) = 3
1
2
Replace x by x + ...... (2)
2
From (1) and (2), we get F(x) = F(x + 1) ...... (3) F(x) is periodic function.
1 Using property
2 of periodic
Now consider I = F( x ) dx = 1500 F( x ) dx = 1500 F( x ) dx F( x ) dx
1500 1 1
0 function
0 0 1
2
Code-B Page # 8
MATHEMATICS
1
Put x = y + in 2nd integral, we get
2
1 1 1 1
2 1 1
I = 1500 F( x ) dx F y dy = 1500 F( x) F x 2 dx = 1500 3 dx [Using (i)]
2 2 2
0
0 2
0 0
1
Hence I = 1500(3) = 750 × 3 = 2250 Ans.
2
Note that for objective purpose take F(x) = 3/2 ]
Q.5
[Sol. Let given limit = L, then
1 1 1 1
........ – Lim ........
1 1 1 1
L = nLim
2n 1 2n 2 2n 3
4n n 2 n 2 2 n 4 2n 6 4n
1 2n n n 1 2n 1
Lim
1 n n
1 1
= nLim
r 1 2n r n r 1 2n 2r n n r 1 2 r r
n =
2 2
n r 1
n n
= 2 2 x dx = ln (2 x ) 0 – ln (1 x ) 0
2 1
1 1
dx –
1 2 1
0
2x 0
2
3
ln 2 = 2 ln 2 = ln 2 =
1 1 A
= ln 4 – ln 2 – ln C
2 2 2 B
Hence least value of A + B + C = 1 + 2 + 2 = 5 Ans. ]
Q.6
2 x log 1 (k 2 6k 8), 2 x 1
[Sol. We have F(x) =
x 3 3x 2 4 x 1 ,
2
1 x 3
Also F(x) is increasing on [–1, 3] because F '(x) > 0 x [–1, 3].
And F '(x) = –2 x [–2, –1), so F(x) is decreasing on [–2,–1).
If F(x) has smallest value at x = –1, then we must have
Lim F( 1 h ) F(1)
h 0
2 + log1/2 (k2 – 6k + 8) –1 log1/2(k2 – 6k + 8) –3 k2 – 6k + 8 8
k2 – 6k 0 k [0, 6] ....(1)
But in order to define log1/2(k – 6k + 8),
2