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Section 2

Chemistry
Na2S2O3

1.

In standardization of
MW / 2

The frequency of a wave of light is


light is
(a)

5 107 m

(b)

K 2Cr2O7

by iodometry, the equivalent weight of


MW / 6
MW / 1
(c)
(d)

(b)

(a)

2.

K 2Cr2O7

using
MW / 3

4 108 cm1

12 1014 s1.

(c)

3.

In the compound
sp3 sp3

(b)

(d)

of 1,4-dioxane is 4.9
for 1000 g. The depression in freezing point for a 0.001 m solution in
dioxane is
(a) 0.0049
(b) 4.9 + 0.001
(c)
4.9
(d)0.49

If the coordination of
in
(a) 3
(b) 4

CaF2

is 8, then the coordination number of


(c) 6
(d) 8

O2

6.

sp2 sp3

(c)

Ca 2

5.

bond is of the type

sp sp3

mol 1

Kf
4.

(d)

4 104 cm1

C2 C3

the

sp sp2

(a)

The wave number associated with this

2 107 m1

CH 2 CH CH 2 CH 2 C CH ,

is

A sample of

gas is collected over water at

23o C

ion would be

at a barometric pressure of 751


O2

23 C

mm Hg (vapour pressure of water at


gas in the sample collected is
(a) 21 mm Hg
(b) 751 mm Hg
(c)

is 21 mm Hg). The partial pressure of


0.96 atm

(d) 1.02 atm

0.5 g

7.

8.

8 gms of a radioactive substance is reduced to


radioactive substance is
(a) 15 min
(b) 30 min
c) 45 min

t1 / 2

after 1 hour. The

of the

(d) 10 min

One mole of a compound AB reacts with one mole of a compound CD according to the
equation
AB + CD AD + CB.
3
4

When equilibrium had been established it was found that mole each of reactant AB
and CD had been converted to AD and CB. There is no change in volume. The
equilibrium constant for the reaction is
9
16

1
9

(a)

(b)

The

(c)

of

solution of the following salts increases in the order

NaCl NH 4 Cl NaCN HCl

(a)

(d) 9

0.1 M

pH
9.

16
9

HCl NH 4Cl NaCl NaCN

(b)

NaCN NH 4Cl NaCl HCl

HCl NaCl NaCN NH 4Cl

(d)

(c)
10.

For a reaction to occur spontaneously


(H TS)

(a)
(c)

must be negative

(H TS)

(b)

must be negative

(d)

N 2O5 (g)

11.

must be negative
must be negative
2NO2(g)

1
02(g)
2

The rate constant k, for the reaction

2.3 102 s1

is
[N2O5]

equation given below describes the change of

. Which

[N 2O5 ]0

with time?

[N 2O5 ]t

and

N 2O5

correspond to concentration of

initially and at time, t


[N2O5 ]0 [N 2O5 ]t ekt

[N 2O5]t [N 2O5]0 kt

(a)

(b)
In

log10[N 2O5 ]t log10[N 2O5 ]0 kt

[N2O5]0
kt
[N2O5 ]t

(c)
(d)
12. What amount of Cl2 gas liberated at anode, if 1 amp. current is passed for 30 min.
from NaCl solution.
(a) 0.66 moles
(b) 0.33 moles
(c) 0.66 g
(d) 0.33
YBa2Cu3O7

13.

The compound

which shows superconductivity has copper in oxidation


3

state ........ Assume that the rare earth element Yttrium is in its usual
state
(a) 3/7
(b) 7/3
(c) 3
(d)
7

oxidation

14.

Colloidal solution of arsenious sulphide can be prepared by


(a) Electrodispersion method
(b) Peptization
(c) Double decomposition
(d) Hydrolysis]

15.

The first ionization potentials in electron volts of nitrogen and oxygen atoms are
respectively given by
(a) 14.6, 13.6
(b) 13.6, 14.6
(c) 13.6, 13.6
(d) 14.6, 14.6

16.

Method used for obtaining highly pure silicon used as a semiconductor material is
(a) Oxidation
(b) Electrochemical(c) Crystallization (d)
Zone refining
H 2O2

17.

18.

The amount of
(a) 2.5 g

present in 1 L of 1.5 N
solution is
(b) 25.5 g
(c) 3.0 g

(d) 8.0 g

The metal which does not form ammonium nitrate by reaction with dilute nitric acid is
(a) Al

19.

H 2O2

(b) Fe

(c)

Pb

(d) Mg

Atomic number of Cr and Fe are 24 and 26 respectively. Which of the following is


paramagnetic with the spin of electron
[Cr(NH 3 )6 ]3

(a)

[Fe(CN )6 ]4

[Fe(CO)5 ]

(b)

(c)

[Cr(CO)6 ]

(d)

Co(NH3)4 Br2Cl

20.

Which kind of isomerism is exhibited by octahedral


?
(a) Geometrical and Ionization
(b) Geometrical and Optical
(c) Optical and Ionization
(d)
Geometrical only

H 3 PO4
21.

Phosphoric acid

is tribasic acid and one of its salts is sodium dihydrogen

NaH2 PO 4

NaOH

phosphate
. What volume of 1 M
solution should be added to 12 g of
sodium dihydrogen phosphate (mol. wt. 120) to exactly convert it into trisodium
Na3 PO 4

phosphate
(a) 80 ml
22.

HO

(b) 100 ml

c)

200 ml

(d) 300 ml

The IUPAC name of the compound is


(a) 3, 3- dimethyl-1-cyclohexanol
(b) 1, 1-dimethyl-3-hydroxy cyclohexane
(c) 3, 3-dimethyl-1-hydroxy cyclohexane(d) 1, 1-dimethyl-3-cyclohexanol
C 2 H 3 Cl 2 Br

23.

24.

The number of possible isomers for compound


(a) 2
(b) 3
(c) 4

is
(d) 5

In the reaction :
HC CH 2AgNO3 NH 4OH
X 2NH 4 NO3 2H 2O

,
Ag2C

(b)

(a)
25.

Ag2C 2

X is
AgC

(c)

AgOH

(d)

Ethyl orthoformate is formed by heating with sodium ethoxide


CHCl 3

(a)
(c)

C 2 H 5OH

(b)
HCOOH

CH 3CHO

(d)