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Natural Gas (Sweet

)
SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET

Date of Preparation: September 11, 2014

Section 1: IDENTIFICATION
Product Name:

Natural Gas (Sweet)

Synonyms:

Marsh Gas; Methane (CH4); Fuel Gas.

Product Use:

Fuel Gas.

Restrictions on Use:

Not available.

Manufacturer/Supplier:

TransCanada PipeLines Limited
450 – First Street S.W.
P.O. Box 1000, Station M
Calgary, Alberta, CANADA, T2P 4K6

Emergency Phone:

1-888-982-7222 (24 Hour)

Date of Preparation of SDS:

September 11, 2014
Section 2: HAZARD(S) IDENTIFICATION

GHS INFORMATION
Classification:

Flammable Gases, Category 1
Gases Under Pressure - Compressed Gas
Simple Asphyxiant

LABEL ELEMENTS
Hazard
Pictogram(s):

Signal Word:

Danger

Hazard
Statements:

Extremely flammable gas.
Contains gas under pressure; may explode if heated.
May displace oxygen and cause rapid suffocation.

Precautionary Statements
Prevention: Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.
Response:

Storage:

Disposal:

Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Eliminate all ignition sources if safe to do so.
Store in a well-ventilated place.
Protect from sunlight.
Not applicable.

Hazards Not Otherwise Classified:

Not applicable.

Ingredients with Unknown Toxicity:

None.

This material is considered hazardous by the OSHA Hazard Communication Standard, (29 CFR
1910.1200).

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Deerfoot Consulting Inc.

Signs/symptoms may include cough. The pain after contact with liquid can quickly subside. Signs/symptoms may include localized redness. drowsiness.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. General Advice: In case of accident or if you feel unwell. Ingestion: Not a normal route of exposure. Not available. and blurred or hazy vision. Symptoms of frostbite include change in skin color to white or grayish-yellow. seek medical advice immediately (show the label or SDS where possible). Signs/symptoms may include redness. Acute and delayed symptoms and effects: Contact with rapidly expanding or liquefied gas may cause irritation and/or frostbite. disorientation. Not available. May cause skin irritation. swelling. and nose and throat pain. Not available. 100 90 . Acute and delayed symptoms and effects: May displace oxygen and cause rapid suffocation. sneezing. tearing. Natural gas Methane Ethane Nitrogen Propane Butane Pentane Not available. . hoarseness. Page 2 of 11 Deerfoot Consulting Inc. lightheadedness. Not available. Remove contact lenses. swelling. headache. and itching. 2014 Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredient(s) Common name / Synonyms CAS No. if present and easy to do. Do not remove adherent material or clothing. May cause respiratory irritation. Immediately call a poison center or doctor. 8006-14-2 74-82-8 74-84-0 7727-37-9 74-98-6 106-97-8 109-66-0 % vol. The pain after contact with liquid can quickly subside. nasal discharge. Continue rinsing. vomiting and seizures. Eye Contact: If in eyes: Rinse cautiously with water for at least 15 minutes. Symptoms may include headache. pain. Not available. Note to Physicians: Symptoms may not appear immediately. Remove non-adhering contaminated clothing. Skin Contact: Contact with rapidly expanding or liquefied gas may cause irritation and/or frostbite. May cause eye irritation. Central nervous system depression can occur if product is present in concentrations that will reduce the oxygen content of air below 18 % (vol). Acute and delayed symptoms and effects: Not a normal route of exposure. Not available. Permanent eye damage or blindness could result.99 0-6 0-3 0-3 0-3 0-3 Section 4: FIRST-AID MEASURES Inhalation: If inhaled: Call a poison center or doctor if you feel unwell. Do not rub affected area./vol. Acute and delayed symptoms and effects: Contact with rapidly expanding or liquefied gas may cause irritation and/or frostbite. Get immediate medical advice/attention. Unconsciousness and death may occur with severe oxygen deprivation. If on skin: Wash with plenty of water.

Structural firefighters' protective clothing will only provide limited protection. Vapors may cause dizziness or asphyxiation without warning. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers. Products of Combustion: Oxides of carbon.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. Eliminate all ignition sources if safe to do so. basements). Section 6: ACCIDENTAL RELEASE MEASURES Emergency Procedures: As an immediate precautionary measure. Will be easily ignited by heat. Small Fire: Dry chemical or CO2. All equipment used when handling the product must be grounded. isolate spill or leak area for at least 100 meters (330 feet) in all directions. Protection of Firefighters: Leaking gas fire: Do not extinguish. Wear positive pressure self-contained breathing apparatus (SCBA). sparks or flames in immediate area). Environmental Precautions: Not normally required. Personal Precautions: Do not touch or walk through spilled material. ELIMINATE all ignition sources (no smoking. This material is sensitive to static discharge. Fire may produce irritating and/or toxic gases. 2014 Section 5: FIRE-FIGHTING MEASURES FLAMMABILITY AND EXPLOSION INFORMATION Extremely flammable gas. Sensitivity to Mechanical Impact: Sensitivity to Static Discharge: MEANS OF EXTINCTION Suitable Extinguishing Media: This material is not sensitive to mechanical impact. Use personal protection recommended in Section 8. Vapors may travel to source of ignition and flash back. Unsuitable Extinguishing Media: Not available. sparks or flames. Always wear thermal protective clothing when handling refrigerated/cryogenic liquids. . Keep out of low areas. CAUTION: Methane is lighter than air and will rise. Large Fire: Water spray or fog. Vapors from liquefied gas are initially heavier than air and spread along ground. unless leak can be stopped safely. Contact with gas or liquefied gas may cause burns. Some may be irritating if inhaled at high concentrations. flares. Stay upwind. Avoid allowing water runoff to contact spilled material. Page 3 of 11 Deerfoot Consulting Inc. Use water spray to reduce vapors or divert vapor cloud drift. Will form explosive mixtures with air. Keep unauthorized personnel away. severe injury and/or frostbite. Methods for Containment: Stop leak if you can do it without risk. DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED. Do not direct water at spill or source of leak.

Nitrogen [CAS No. Store away from incompatible materials. CAUTION: When in contact with refrigerated/cryogenic liquids. 2014 Methods for Clean-Up: Prevent spreading of vapors through sewers. No smoking. (2012) OSHA: 800 ppm (TWA) [Vacated]. Methane [CAS No. (2013) OSHA: 1000 ppm (TWA). Propane [CAS No. 74-82-8] ACGIH: Asphyxia OSHA: No PEL established. 8006-14-2] ACGIH: Asphyxia OSHA: No PEL established. 109-66-0] ACGIH: 1000 ppm (TWA). sparks. 750 ppm (STEL) [Vacated]. Section 7: HANDLING AND STORAGE Handling: Keep away from heat. many materials become brittle and are likely to break without warning. Isolate area until gas has dispersed. Ethane [CAS No.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. 600 ppm (TWA). ventilation systems and confined areas. See Section 10 for information on Incompatible Materials. Pentane [CAS No. open flames. and hot surfaces. 74-98-6] ACGIH: Asphyxia OSHA: 1000 ppm (TWA). Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Component Natural gas [CAS No. Keep out of the reach of children. 106-97-8] ACGIH: 1000 ppm (TWA). 7727-37-9] ACGIH: Simple asphyxiant OSHA: No PEL established. 74-84-0] ACGIH: Asphyxia OSHA: No PEL established. 1800 mg/m³ (TWA). Other Information: See Section 13 for disposal considerations. See Section 8 for information on Personal Protective Equipment. . Butane [CAS No. Storage: Store in a well-ventilated place. Protect from sunlight. Page 4 of 11 Deerfoot Consulting Inc. 2950 mg/m³ (TWA).

PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection: Wear safety glasses. Colour: Colourless. Supplied air breathing apparatus must be used when oxygen concentrations are low or if airborne concentrations exceed the limits of the air-purifying respirators. 2014 PEL: Permissible Exposure Limit TWA: Time-Weighted Average STEL: Short-Term Exposure Limit Engineering Controls: Use ventilation adequate to keep exposures (airborne levels of dust. Physical State: Gas. gas. Hand Protection: Wear protective gloves. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colourless gas.133 for Personal Protective Equipment. or self-contained breathing apparatus must be used.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. Respiratory Protection: If engineering controls and ventilation are not sufficient to control exposure to below the allowable limits then an appropriate NIOSH/MSHA approved air-purifying respirator that meets the requirements of CSA Standard CAN/CSAZ94. . fume. General Hygiene Considerations: Handle according to established industrial hygiene and safety practices. vapour. Skin and Body Protection: Wear protective clothing. Odour: Slight hydrocarbon odour not detectable by all people. Use equipment for eye protection that meets the standards referenced by CSA Standard CAN/CSA-Z94. Odour Threshold: Not available. Consult a competent industrial hygienist to determine hazard potential and/or the PPE manufacturers to ensure adequate protection. pH: Not available. Melting Point / Freezing Point: -187 to -182 °C (-304.6 °F) (estimated) Initial Boiling Point: Not available.) below recommended exposure limits. Consult manufacturer specifications for further information. Page 5 of 11 Deerfoot Consulting Inc. etc.6 to -295. Wear cold insulating gloves.4-11.3-92 and OSHA regulations in 29 CFR 1910.

Auto-ignition Temperature: 537 °C (998. Partition Coefficient: nOctanol/Water: Not available. Viscosity: Not available. 2014 Boiling Range: -162 °C (-259.6 °F) Decomposition Temperature: Not available. Conditions to Avoid: Contact with incompatible materials. . Chemical Stability: Stable under normal storage conditions. Percent Volatile. Exposure to heat. wt. Hazardous Decomposition Products: Oxides of carbon. Solubilities: Negligible solubility in water. Incompatible Materials: Strong oxidizers. wt.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. Density: Not available. %: Not available.6 (Air = 1) at 20 °C (68 °F) (Methane) Relative Density: Not available. %: 100 VOC content. Exposure to heat. Sources of ignition.6 °F) (estimated) Flash Point: Not available. Section 10: STABILITY AND REACTIVITY Reactivity: Contact with incompatible materials. Coefficient of Water/Oil Distribution: Not available. gas): Extremely flammable gas. Sources of ignition. Evaporation Rate: > 1 (n-BuAc = 1) at 20 °C (68 °F) Flammability (solid. Page 6 of 11 Deerfoot Consulting Inc. Lower Flammability Limit: 5. Possibility of Hazardous Reactions: None known.3 % Upper Flammability Limit: 14 % Vapor Pressure: > 1000 mmHg at 20 °C (68 °F) Vapor Density: 0.

Ingestion: Not a normal route of exposure. Eye: Contact with rapidly expanding or liquefied gas may cause irritation and/or frostbite. Not available. Central nervous system. 4H 8006-14-2 74-82-8 74-84-0 7727-37-9 74-98-6 106-97-8 109-66-0 Likely Routes of Exposure: Eye contact. Medical Conditions Aggravated By Exposure: Not available. and itching. Not available. lightheadedness. The pain after contact with liquid can quickly subside. Eyes. Not available. Signs/symptoms may include redness. Not available. Respiratory system. Page 7 of 11 Deerfoot Consulting Inc. . May cause eye irritation. Not available. swelling. Skin Sensitization: Not available. Signs/symptoms may include localized redness. Symptoms (including delayed and immediate effects) Inhalation: May displace oxygen and cause rapid suffocation. vomiting and seizures. Inhalation: Not available. and blurred or hazy vision. Component Toxicity Component CAS No. hoarseness. 658000 mg/m³ (rat). Target Organs: Skin. Not available. headache. pain. Not available. Not available. Symptoms may include headache. Unconsciousness and death may occur with severe oxygen deprivation. nasal discharge. Respiratory Sensitization: Not available. and nose and throat pain. 400 mg/kg (rat) Not available. Permanent eye damage or blindness could result. Inhalation. 2014 Section 11: TOXICOLOGICAL INFORMATION EFFECTS OF ACUTE EXPOSURE Product Toxicity Oral: Not available. Not available. sneezing. Not available. 4H 364000 mg/m³ (rat). Signs/symptoms may include cough. Skin: Contact with rapidly expanding or liquefied gas may cause irritation and/or frostbite. Not available. Symptoms of frostbite include change in skin color to white or grayish-yellow. Not available. Skin contact. LD50 oral LD50 dermal LC50 Natural gas Methane Ethane Nitrogen Propane Butane Pentane Not available. disorientation. Not available.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. drowsiness. May cause skin irritation. swelling. Not available. Dermal: Not available. Not available. May cause respiratory irritation. Not available. The pain after contact with liquid can quickly subside. tearing. Central nervous system depression can occur if product is present in concentrations that will reduce the oxygen content of air below 18 % (vol).

bluish colouration to the skin.1 UN Number: UN1971 Packing Group: Not applicable. COMPRESSED. Central nervous system. 2014 EFFECTS OF CHRONIC EXPOSURE (from short and long-term exposure) Target Organs: Skin. NATURAL GAS. Developmental Effects Teratogenicity: Not available. Eyes. Toxicologically Synergistic Materials: Not available. or NTP. Reproductive Effects: Not available. Department of Transportation (DOT) Proper Shipping Name: UN1971. heart sensitization. . OSHA. IARC. Chronic Effects: Prolonged exposure to Natural gas can lead to hypoxia. damage to the nervous system. Local regulations may be more stringent than regional or national requirements. Carcinogenicity: This product does not contain any carcinogens or potential carcinogens as listed by ACGIH. Respiratory system. Label Code: Page 8 of 11 Deerfoot Consulting Inc. Section 14: TRANSPORT INFORMATION U. Section 13: DISPOSAL CONSIDERATIONS Disposal Instructions: Disposal should be in accordance with applicable regional. 2. Persistence / Degradability: Not available. Bioaccumulation / Accumulation: Not available. Component Carcinogenicity Mutagenicity: Not available. national and local laws and regulations. Other Adverse Effects: Not available. Section 12: ECOLOGICAL INFORMATION Ecotoxicity: Not available. Mobility in Environment: Not available.S. reduced consciousness and death. Embryotoxicity: Not available.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11.1 Class: 2. numbness.

Not listed. Not listed. 2014 Canada Transportation of Dangerous Goods (TDG) Proper Shipping Name: UN1971. Not listed. Not listed. Not listed. Hazard Symbols: United States This SDS has been prepared to meet the U. SARA Title III Component Methane Ethane Propane Butane Pentane Section 302 (EHS) TPQ (lbs. Not listed. 2. Not listed.1 Class: 2. 29 CFR 1910. Not listed.Compressed Gas.Flammable Gases.1200. Class B1 . Not listed.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. Not listed. 1999.) 10000 10000 10000 10000 10000 Deerfoot Consulting Inc. Not listed. OSHA Hazard Communication Standard. NATURAL GAS. Federal Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Not listed. Not listed. Not listed. Not listed.) CERCLA RQ (lbs. Not listed. Not listed. Not listed. Not listed. WHMIS Classification: Class A . Not listed. Label Code: Section 15: REGULATORY INFORMATION Chemical Inventories US (TSCA) The components of this product are in compliance with the chemical notification requirements of TSCA. Not listed. Canada (DSL) The components of this product are in compliance with the chemical notification requirements of the NSN Regulations under CEPA.S. . Not listed.1 UN Number: UN1971 Packing Group: Not applicable. Not listed.) Section 313 RCRA CODE Not listed. Not listed. COMPRESSED.) Section 304 EHS RQ (lbs. Page 9 of 11 CAA 112( r ) TQ (lbs.

RTK List Methane Ethane Nitrogen Propane Butane Pentane 74-82-8 74-84-0 7727-37-9 74-98-6 106-97-8 109-66-0 SHHS SHHS Listed. . Listed.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11. Listed. Listed. 2014 State Regulations Massachusetts US Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section 670. Listed. California California Prop 65: This product does not contain chemicals known to the State of California to cause cancer. Listed. Listed. 301-323) Component CAS No. Listed. RTK List Natural gas Methane Ethane Nitrogen Propane Butane Pentane 8006-14-2 74-82-8 74-84-0 7727-37-9 74-98-6 106-97-8 109-66-0 Listed. SHHS SHHS SHHS Note: SHHS = Special Health Hazard Substance Pennsylvania US Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Listed.000) Component CAS No. RTK List Natural gas Methane Ethane Nitrogen Propane Butane Pentane 8006-14-2 74-82-8 74-84-0 7727-37-9 74-98-6 106-97-8 109-66-0 Listed. birth defects or other reproductive harm. Listed. Listed. Listed. Listed. Page 10 of 11 Deerfoot Consulting Inc. New Jersey US New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) Component CAS No. Code Chap.

It may not be valid for this material if it is used in combination with any other materials. 2014 Section 16: OTHER INFORMATION Disclaimer: The information contained in this document applies to this specific material as supplied. Date of Preparation of SDS: September 11. 2014 SDS Expiry Date (Canada): September 10. Phone: (403) 720-3700 Page 11 of 11 Deerfoot Consulting Inc. 2017 Version: 1.Natural Gas (Sweet) SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 11.0 GHS SDS Prepared by: Deerfoot Consulting Inc. . It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for his own particular use.