You are on page 1of 22

IIT-JEE - 2001

Prelims
Mathematics
1. The maximum value of
(cos 1).(cos 2)...(cos n),
under the restrictions 0 1, 2, ...., n /2 and (cot 1).... (cot n) = 1 is
1) 1/2n/2
2) 1/2n

m
o

3) 1/2n
4) 1

c
.
rs

2. A man from the top of a 100 metres high tower sees a car moving towards the tower at an
angle of depression of 30. After some time, the angle of depression becomes 60. The
distance (in metres) travelled by the car during this time is

e
e
in

1) 1003
2) (200(3))/3
3) (100(3))/3

g
n

4) 2003

E
O

3. If + = (/2) and + = , then tan equals


1) 2 (tan + tan)

o
D

2) tan + tan

3) tan + 2tan

a
a

4) 2tan + tan

4. If sin-1 (x - (x2/2) + (x3/4) - ....) + cos-1(x2 - (x4/2) + (x6/4) - ....) = (/2) for 0 < |x| < 2, then
x equals
1) 1/2
5.

2) 1

3) -(1/2)

4) -1

2) a

3) /2

4) 2

The value of
1)

6. Let
depends on
1) only x
2) only y

1/21

eng.edooni.com

3) NEITHER x NOR y
4) both x and y
7. The number of solution of
log4(x -1) = log2(x - 3) is
1) 3

2) 1

3) 2

4) 0

8. Which of the following function is differentiable at x = 0 ?


1) cos (|x|) + |x|
2) cos (|x|) - |x|
3) sin (|x|) + |x|
4) sin (|x|) - |x|
9. If

m
o

are unit vectors, then

c
.
rs

does NOT exceed


1) 4

2) 9

3) 8

e
e
in

4) 6

10. Let f(x) = (x/(x + 1)), x -1. Then, for what value of is f (f(x)) = x ?
1) 2

2) -2

3) 1

4) -1

g
n

11. In the binomial expansion of (a - b)n, n 5, the sum of the 5th and the 6th terms is zero.
Then (a/b) equals

E
O

1) (n - 5)/6
2) (n - 4)/5

o
D

3) 5/(n - 4)
4) 6/(n - 5)

a
a

12. Let be the roots of x 2 - x + p = 0 and , be the roots of x 2 - 4x + q = 0. If, , ,


are in G.P., then the integral values of p and q respectively, are

1) -2, -32
2) -2, 3
3) -6, 3
4) -6, -32

13. Let f(x) = (1 + b2)x2 + 2b x + 1 and let m(b) be the minimum value of f(x). As b varies, the
range of m(b) is
1) [0, 1]
2) (0, 1/2]
3) [1/2, 1]
4) (0, 1]

2/21

eng.edooni.com

14. The number of distinct real roots of


| sin x cos x cos x |
| cos x sin x cos x | = 0
| cos x cos x sin x |
in the interval (/4) x (/4) is
1) 0

2) 2

3) 1

4) 3

15. If f(x) = x ex(1 - x), then f(x) is


1) increasing on [-(1/2), 1]
2) decreasing on R
3) increasing on R
4) decreasing on [-(1/2), 1]

m
o

16. Let f : R R be a function defined by f(x) = max (x, x3). The set of all points where f(x) is
NOT differentiable is

c
.
rs

1) {-1, 1}
2) {-1, 0}

e
e
in

3) {0, 1}
4) {-1, 0, 1}
17.

g
n

Let f : (0 ) R and F(x) =

E
O

1) 5/4

2) 7

18.
1) -

o
D

a
a

If F(x2) = x2(1 + x), then f(4) equals

2)

3) 4

4) 2

3) /2

4) 1

19. The left-hand derivative of f(x) = [x] sin(x) at x = k, k an integer, is

1) (-1)k (k - 1)
2) (-1)k - 1 (k - 1)
3) (-1)k k
4) (-1)k - 1 k

20. The equation of directrix of the parabola y2 + 4y + 4x + 2 = 0, is


1) x = -1
2) x = 1
3) x = -(3/2)
4) x = (3/2)

3/21

eng.edooni.com

21. Area of the, parallelogram formed by the lines y = mx, y = mx + 1, y = nx and y = nx + 1


equals
1) |m + n|/(m - n)2
2) 2/|m + n|
3) 1/|m + n|
4) 1/|m - n|
22. The number of integer values of m, for which x-coordinate of the point of intersection of
the lines 3x + 4y = 9 and y = mx + 1 is also an integer, is
1) 2

2) 0

3) 4

4) 1

23. Let AB be a chord of the circle x2 + y2 = r2 subtending a right angle at the centre. Then the
locus of the centroid of the triangle PAB as P moves on the circle is

m
o

1) a parabola
2) a circle

c
.
rs

3) an ellipse
4) a pair of straight lines

e
e
in

24. Let PQ and RS be tangents at extremities of the diameter PR of a circle of radius r. If PS


and RQ intersect at a point X on the circumference of the circle, then 2r equals

g
n

E
O

o
D

a
a

1) (PQ . RS)

2) ((PQ + RS)/2)

3) (2PQ . RS)/(PQ + RS)


4) (PQ2 + RS2)/2

25. The equation of the common tangent touching the circle (x - 3)2 + y2 = 9 and the parabola
y2 = 4x above the x-axis is
1) (3) y = 3x + 1
2) (3) y = - (x + 3)
3) (3) y = x + 3
4) (3) y = - (3x + 1)
26. If f : [1, ) [2, ) is given by f (x) = x + (1/x) then f -1 (x) equals

4/21

eng.edooni.com

1) ((x + (x2 - 4))/2)


2) x/(1 + x2)
3) ((x - (x2 - 4))/2)
4) 1 + (x2 - 4)
27. The triangle formed by the tangent to the curve f(x) = x2 + bx - b at the point (1, 1) and the
coordinate axes, lies in the first quadrant. If its area is 2, then the value of b is
1) -1

2) 3

3) -3

4) 1

28. The domain of definition of f(x) = (log2(x + 3))/(x2 + 3x + 2) is


1) R\ {-1, -2}
2) (-2 , )

m
o

3) R\ {-1, -2, -3}


4) (-3, ) \ {-1, -2)
29.

Let g(x) = 1 + x - [x] and


1) x

c
.
rs

. Then for all x, f(g(x)) is equal to

2) 1

3) f(x)

n
i
g

ee

4) g(x)

30. The complex numbers z1, z2 and z3 satisfying ((z1 - z3)/(z2 - z3)) = ((1 - i(3))/2) are the
vertices of a triangle which is

n
E

O
o

D
a

1) of area zero

2) right-angled isosceles

a
F

3) equilateral

4) obtuse-angled isosceles

31. Let the positive numbers a, b, c, d be in A.P. Then abc, abd, acd, bcd are
1) NOT in A.P./G.P./H.P.
2) in A.P.
3) in G.P.
4) in H.P.
32. Let T n denote the number of triangles which can be formed using the vertices of a regular
polygon on n sides. If T n + 1 T n = 21, then n equals
1) 5

2) 7

3) 6

5/21

4) 4

eng.edooni.com

33. Let E ={1, 2, 3, 4} and F = {1, 2}, the number of onto functions from E to F is
1) 14

2) 16

3) 12

4) 8

34. If the sum of the first 2n terms of the A.P. 2, 5, 8, ..., is equal to the sum of the first n terms
of the A.P. 57, 59, 61, ... , then n equals
1) 10

2) 12

3) 11

4) 13

35. Let z1 and z2 be nth roots of unity which subtend a right angle at the origin. The n must be
of the form

m
o

c
.
rs

1) 4k + 1
2) 4k + 2
3) 4k + 3

e
e
in

4) 4k

Physics

g
n

36. P-V plots for two gases during adiabatic processes are shown in the figure. Plots 1 and 2
should correspond respectively to

E
O

o
D

1) He and O2

a
a

2) O2 and He

3) He and Ar

4) O2 and N2

37. Two pulses in a stretched string whose centers are initially 8 cm apart are moving towards
each other as shown in the figure. The speed of each pulse is 2 cm./s. After 2 seconds,
the total energy of the pulses will be

1) zero
2) purely kinetic
3) purely potential
4) partly kinetic and partly potential

6/21

eng.edooni.com

38. A hemisphrical portion of radius R is removed from the bottom of a cylinder of radius R.
The volume of the remaining cylinder is V and its mass is M. It is suspended by a string in
a liquid of density where it stays vertical. The upper surface of the cylinder is at a depth
h below the liquid surface. The force on the bottom of the cylinder by the liquid is

m
o

1) Mg

c
.
rs

2) Mg - Vg
3) Mg + R2hg
4) g(V + R2h)

e
e
in

39. The ends of a stretched wire of length L are fixed at x = 0, and x = L. In one experiment,
the displacement of the wire is
y1 = A sin(x/L) sin t and energy is E1 and in another experiment its displacement is
y2 = A sin (2x/L)sin 2t and energy is E2. Then

g
n

E
O

1) E2 = E1
2) E2 = 2E1

o
D

3) E2 = 4E1

4) E2 = 16E1

a
a

40. When a block of iron floats in mercury at 0C, a fraction k1 of its volume is submerged,
while a the temperature 60C a fraction k2 is seen to be submerged. If the coefficient of

volume expansion of iron is Fe and that of mercury is Hg, the n the ratio k1/k2 can be
expressed as
1) (1 + 60Fe)/(1 + 60Hg)
2) (1 - 60Fe)/(1 + 60Hg)
3) (1 + 60Fe)/(1 - 60Hg)
4) (1 + 60Hg)/(1 + 60Fe)

41. Three rods made of the same material and having the same cross-section have been
joined as shown in the figure. Each rod is of the same length. The left and right ends are
kept at 0oC and 90C respectively. The temperature of the junction of the the three rods
will be

7/21

eng.edooni.com

1) 45C
2) 60C
3) 30C
4) 20C
42. In a given process of an ideal gas, d W = 0 and d Q < 0. Then for the gas
1) the temperature will decrease
2) the volume will increase
3) the pressure will remain constant

m
o

4) the temperature will increase

c
.
rs

43. Three positive charges of equal value q are placed at the vertices of an equilateral
triangle. The resulting lines of force should be sketched as in
1)

e
e
in

g
n

2)

E
O

o
D

a
a

3)

8/21

eng.edooni.com

4)

44. In the given circuit, with steady current, the potential drop across the capacitor must be

1) V

2) V/2

3) V/3

c
.
rs

45. The electron emitted in beta radiation originates from


1) inner orbit of atoms
2) free electrons existing in nuclei

m
o

4) 2V/3

e
e
in

3) decay of a neutron in a nucleus


4) photon escaping from the nucleus

g
n

46. The intensity of X-rays from a Coolidge tube is plotted against wavelength
as shown in
figure. The minimum wavelength found is c and the wavelength of the K line is k. As the

E
O

accelerating voltage is increased

o
D

a
a

1) k - c increases
2) k - c decreases
3) k increases
4) k decreases

47. The transition from the state n = 4 to n = 3 in a hydrogen like atom results in ultraviolet
radiation. Infrared radiation will be obtained in the transition
1) 2 1
2) 3 2
3) 4 2

9/21

eng.edooni.com

4) 5 4
48. Two particles A and B of masses m A and m B respectively and having the same charge are
moving in a plane. A uniform magnetic field exists perpendicular to this plane. The speeds
of the particles are VA and VB respectively and their trajectories are as shown in the figure.
Then

1) m AvA < m BvB


2) m AvA > m BvB

m
o

3) m A < m B and vA < vB

c
.
rs

4) m A = m B and vA = vB

49. A wire of length L and 3 identical cells of negligible internal resistances are connected in
series. Due to the current, the temperature of the wire is raised
Tbyin a time t. A
number N of similar cells is now connected in series with a wire of the same material and
cross section but of length 2L. The temperature of the wire is raised by the same amount
T in the same time t. The value of N is
1) 4

e
e
in

g
n

2) 6

3) 8

E
O

4) 9

50. Two beams of light having intensities I and 4I interfere to produce a fringe pattern on a
screen. The phase difference between the beams is/2 at point A and at point B. Then
the difference between the resultant intensities at A and B is

o
D

1) 2I

2) 4I

3) 5I

4) 7I

a
a

51. A given ray of light suffers minimum deviation in an equilateral prism P. Additional prisms
Q and R of identical shape and of the same material as P are now added as shown in the
figure. The ray will now suffer

1) greater deviation
2) no deviation
3) same deviation as before
4) total internal reflection
52. A metallic square loop ABCD is moving in its own plane with velocity v in a uniform
magnetic field perpendicular to its plane as shown in the figure. An electric field is induced

10/21

eng.edooni.com

1) in AD, but not in BC


2) in BC, but not in AD
3) neither in AD nor in BC
4) in both AD and AC
53. In the given circuit, it is observed that the current I is independent of the value of the
resistance R6. Then the resistance values must satisfy

m
o

c
.
rs

1) R1R2R5 = R3R4R6
2) (1/R5) + (1/R6) = (1/(R1 + R2)) + ((1/(R3 + R4))

e
e
in

3) R1R4 = R2R3
4) R1R3 = R2R4 = R5R6

g
n

54. A radioactive sample consists of two distinct species having equal number of atoms
initially. The mean life time of one species is and that of the other is.5 The decay
products in both cases are stable. A plot is made of the total number of radioactive nuclei
as a function of time. Which of the given figures [(A), (B), (C), (D)] best represents the
form of this plot?

E
O

o
D

1)

a
a

2)

3)

4)

55. Two circular coils can be arranged in any of the three situations shown in the figure. Their
mutual inductance will be

11/21

eng.edooni.com

1) maximum in situation (a)


2) maximum in situation (b)
3) maximum in situation (c)
4) the same in all situations
56. A ray of light passes through four transparent media with refractive indices 1, 2, 3 and
4 as shown in the figure. The surfaces of all media are parallel. If the emergent ray CD is
parallel to the incident ray AB, we must have

m
o

1) 1 = 2

c
.
rs

2) 2 = 3
3) 3 = 4

e
e
in

4) 4 = 1

57. An insect crawls up a hemispherical surface very slowly (see the figure). The coefficient of
friction between the insect and the surface is 1/3. If the line joining the center of the
hemispherical surface to the insect makes an angle
with the vertical, the maximum
possible value of is given by

g
n

E
O

o
D

1) cot = 3

2) tan = 3

a
a

3) sec = 3

4) cosec = 3

58. A string of negligible mass going over a clamped pulley of mass m supports a block of
mass M as shown in the figure. The force on the pulley by the clamp is given by

1) 2 Mg
2) 2 mg
3) ((M + m)2 + m 2) g
4) ((M + m)2 + M 2) g

12/21

eng.edooni.com

59. The pulleys and strings shown in the figure are smooth and of negligible mass. For the
system to remain in equilibrium, the angle should be

1) 0

2) 30

3) 45

4) 60

60. A quantity X is given by o L(V/t) where o is the permittivity of free space. L is a length,
V is a potential difference and t is a time interval. The dimensional formula for X is the
same as that of
1) resistance
2) charge

m
o

3) voltage
4) current

c
.
rs

61. One quarter sector is cut from a uniform circular disc of radius R. The sector has mass M.
It is made to rotate about a line perpendicular to its plane and passing through the center
of the original disc. Its moment of inertia about the axis of rotation is

e
e
in

1) (1/2) MR2

g
n

E
O

o
D

2) (1/4) MR2
3) (1/8) MR2

a
a

4) 2 MR2

62. A simple pendulum has a time period T 1 when on the earth's surface, and T 2 when taken
to a height R above the earth's surface, where R is the radius of the earth. The value of
T 2/T 1 is
1) 1

2) 2

3) 4

4) 2

63. Two particles of masses m 1 and m 2 in projectile motion have velocities 1 and 2
respectively at time t = 0. They collide at time to. Their velocities become 1' and 2' at
time 2to while still moving in air. The value of
|(m 1 1' + m 2 2') - (m 1 1 + m 2 2)| is
1) zero
2) (m 1 + m 2)gt0
3) 2(m 1 + m 2)gt0

13/21

eng.edooni.com

4) 1/2 (m 1 + m 2)gt0
64. A small block is shot into each of the four tracks as shown below. Each of the tracks rises
to the same height. The speed with which the block enters the track is the same in all
cases. At the highest point of the track, the normal reaction is maximum in
1)

2)

3)

m
o

4)

c
.
rs

e
e
in

65. In the Young's double slit experiment, 12 fringes are observed to be formed in a certain
segment of the screen when light of wavelength 600 nm is used. If the wavelength of light
is changed to 400 nm, number of fringes observed in the same segment of the screen is
given by
1) 12

g
n

2) 18

3) 24

4) 30

E
O

66. A non-planar loop of conducting wire carrying a current I is placed as shown in the figure.
Each of the straight sections of the loop is of length 2a. The magnetic field due to this loop
at the point P(a, 0, a) points in the direction

o
D

a
a

1) 1/(2)
2) 1/(3)
3) 1/(3)
4) 1/(2)

67. A particle executes simple harmonic motion between x = -A and x = +A. The time taken for
it to go from 0 to A/2 is T 1 and to go from A/2 to A is T 2. Then
1) T 1 < T 2
2) T 1 > T 2

14/21

eng.edooni.com

3) T 1 = T 2
4) T 1 = 2T 2
68. A coil having N turns is wound tightly in the form of a spiral with inner and outer radii a and
b respectively. When a current I passes through the coil, the magnetic field at the center is
1) m 0NI/b
2) 20NI/a
3) (0NI/(2(b - a))) ln (b/a)
4) (0 IN/(2(b - a))) ln (b/a)
69. Consider the situation shown in the figure. The capacitor A has a charge q on it whereas B
is uncharged. The charge appearing on the capacitor B a long time after the switch is
closed is
1) zero

2) q/2

3) q

m
o

4) 2q

c
.
rs

70. A uniform electric field pointing in positive x direction exists in a region. Let A be the
origin, B be the point on the x-axis at x = +1 cm and C be the point on the y-axis at y = +1
cm. Then the potentials at the points A, B and C satisfy :

e
e
in

1) VA < VB
2) VA > VB
3) VA < VC

g
n

4) VA > VC

E
O

Chemistry

Use the values of the constants as given below :

o
D

Plank's constant, h = 6.626 x 10-34 Js


Atomic Numbers : Cr = 24, Mn = 25, Fe = 26, Co = 27, Pt = 78

a
a

71. The number of SS bonds in sulphur trioxide trimer (S3O9) is

1) three

2) two

3) one

4) zero

72. A aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 ml. The volume of 0.1
N NaOH required to completely neutralize 10 ml of this solution is
1) 40 ml
2) 20 ml
3) 10 ml
4) 4 ml
73. The chemical composition of 'slag' formed during the smelting process in the extraction of
copper is
1) Cu2O + FeS
2) FeSiO3

15/21

eng.edooni.com

3) CuFeS2
4) Cu2S + FeO
74. The Common features among the species CN-, CO and NO+ are
1) bond order three and isoelectronic
2) bond order three and weak field ligands
3) bond order two and -acceptors
4) isoelectronic and weak field ligands
75. In a solid 'AB' having the NaCl structure, 'A' atoms occupy the corners of the cubic unit
cell. If all the face-centered atoms along one of the axes are removed, then the resultant
stoichiometry of the solid is

m
o

c
.
rs

e
e
in

1) AB2

g
n

2) A2B
3) A4B3

E
O

4) A3B4

o
D

76. The root mean square velocity of an ideal gas at constant pressure varies with density (d)
as
1) d2

a
a
2) d

3) d

4) 1/d

77. The reaction,

, is an example of

1) oxidation reaction
2) reduction reaction
3) disproportionation reaction
4) decomposition reaction
78. In thermodynamics, a process is called reversible when
1) surroundings and system change into each other
2) there is no boundary between system and surroundings
3) the surrounding are always in equilibrium with the system
16/21

eng.edooni.com

3) the surrounding are always in equilibrium with the system


4) the system changes into the surroundings spontaneously
79. The set with correct order of acidity is
1) HClO < HClO2 < HClO3 < HClO4
2) HClO4 < HClO3 < HClO2 < HClO
3) HClO < HClO4 < HClO3 < HClO2
4) HClO4 < HClO2 < HClO3 < HClO
80. The wavelength associated with a golf ball weighing 200 g and moving at a speed of 5 m/h
is of the order
1) 10-10 m
2) 10-20 m

m
o

3) 10-30 m
4) 10-40 m

c
.
rs

81. An SN2 reaction at an asymmetric carbon of a compound always gives

e
e
in

1) an enantiomer of the substrate


2) a product with opposite optical rotation
3) a mixture of diastereomers
4) a single stereoisomer

g
n

82. A mixture of benzaldehyde and formaldehyde on heating with aqueous NaOH solution
gives

E
O

1) benzyl alcohol and sodium formate

o
D

2) sodium benzoate and methyl alcohol


3) sodium benzoate and sodium formate

a
a

4) benzyl alcohol and methyl alcohol

83. The complex ion which has no d electrons in the central metal atoms is
1) [MnO4]2) [Co(NH3)6]33) [Fe(CN)6]3
4) [Cr(H2O)6]3
84. The set representing the correct order of first ionization potential is
1) K > Na > Li
2) Be > Mg > Ca
3) B > C > N
4) Ge > Si > C

17/21

eng.edooni.com

85. The correct order of hybridization of the central atom in the following species
NH3, [PtCl4]2-, PCl5 and BCl3 is
1) dsp2, dsp3, sp2 and sp3
2) sp3, dsp2, dsp3, sp2
3) dsp2, sp2, sp3, dsp3
4) dsp2, sp3, sp2, dsp3
86. In the standardization of Na2S2O3 using K2Cr2O7 by iodometry, the equivalent weight of
K2Cr2O7 is
1) (molecular weight)/2
2) (molecular weight)/6
3) (molecular weight)/3

m
o

4) same as m.w.

c
.
rs

Directions for question 87 to 91 :


The given questions consists of an 'Assertion' and 'Reason'. Use the following key
to choose the appropriate answer

e
e
in

(A) If both assertion and reason are CORRECT, and reason is the CORRECT explanation
of the assertion.
(B) If both assertion and reason are CORRECT, but reason is NOT the CORRECT explana
tion of the assertion
(C) If assertion is CORRECT, but reason is INCORRECT
(D) If assertion is INCORRECT, but reason is CORRECT.

g
n

E
O

87. ASSERTION :- In any ionic solid [MX] with Schottky defects, the number of positive and
negative ions are same
REASON :- Equal number of cation and anion vacancies are present

o
D

1) (A)

a
a

2) (B)

3) (C)

4) (D)

88. ASSERTION :- Addition of bromine to trans-2- butene yields meso-2, 3-dibromobtitane


REASON :- Bromine addition to an alkene is an electrophilic addition

1) (A)

2) (B)

3) (C)

4) (D)

89. ASSERTION :- Between SiCl4 and CCl4, only SiCl4 reacts with water
REASON :- SiCl4 is ionic and CCl4 is covalent.
1) (A)

2) (B)

3) (C)

4) (D)

90. ASSERTION :- Dimethylsulphide is commonly used for the reduction of an ozonide of an


alkene to get the carbonyl compounds
REASON :- It reduces the ozonide giving water soluble dimethyl sulphoxide and excess of
it evaporates
1) (A)

2) (B)

3) (C)

4) (D)

91. ASSERTION :- In strongly acidic solution, aniline becomes more reactive towards

18/21

eng.edooni.com

electrophilic reagents
REASON :- The amino group being completely protonated in strongly acidic solution the
lone pair of electrons on the nitrogen is no longer available for resonance.
1) (A)

2) (B)

3) (C)

4) (D)

92. Hydrogenation of the given compound in the presence of poisoned palladium catalyst
gives

1) an optically active compound


2) an optically inactive compound
3) a racemic mixture

m
o

4) a diastereomeric mixture

c
.
rs

93. The reaction of propene with HOCl proceeds via the addition of
1) H+ in the first step
2) Cl+ in the first step

e
e
in

3) OH- in the first step


4) Cl- and OH- in a single step

g
n

94. 1-propanol and 2-Propanol can he best distinguished by

1) oxidation with alkaline KMnO4 followed by reaction with Fehling solution

E
O

2) oxidation with acidic dichromate followed by reaction with Fehling solution


3) oxidation by heating with copper followed by reaction with Fehling solution

o
D

4) oxidation with concentrated H2SO4 followed by reaction with Fehling solution

a
a

95. The number of isomers for the compound with molecular formula C2BrClFI is

1) 3

2) 4

3) 5

4) 6

96. The compound that will react most readily with NaOH to form methanol is
1) (CH3)4N+ I2) CH3OCH3
3) (CH3)3S+ I4) (CH3)3CCl
97. The correct order of basicities of the following compounds is
1.
2. CH3 - CH2 - NH2

19/21

eng.edooni.com

3. (CH3)2NH
4.
1) 2 > 1 > 3 > 4
2) 1 > 3 > 2 > 4
3) 3 > 1 > 2 > 4
4) 1 > 2 > 3 > 4
98. In the presence of peroxide, hydrogen chloride and hydrogen iodide do not give anti-Mark
ovnikov addition to alkenes because
1) both are highly ionic
2) one is oxidising and the other is reducing
3) one of the steps is endothermic in both the cases

m
o

4) all the steps are exothermic in both the cases

c
.
rs

99. The quantum numbers of +1/2 and -1/2 for the electron spin represent

1) rotation of the electron in clockwise and anti-clockwise direction respectively


2) rotation of the electron in anticlockwise and clockwise direction respectively

e
e
in

3) magnetic moment of the electron pointing up and down respectively

4) two quantum mechanical spin states which have no classical analogue

g
n

100. Which of the following statements is false?


1) Work is a state function

E
O

2) Temperature is a state function

3) Change in the state is completely defined when the initial and final states are specified
4) Work appears at the boundary of the system

o
D

101. For the sparingly soluble salt ApBq, the relationship of its solubility product (LS) with its
solubility (S) is

a
a

1) Ls = Sp + q . pp . qq
2) Ls = Sp + q . pq . qp
3) Ls = Spq . pp . qq
4) Ls = Spq . (pq)p + q

102. Saturated solution of KNO3 is used to make salt-bridge because


1) velocity of K+ is greater than that of NO-3
2) velocity of NO-3 is greater than that of K+
3) velocity of both K+ and NO-3 are nearly the same
4) KNO3 is highly soluble in water

20/21

eng.edooni.com

103. At constant temperature, the equilibrium constant (Kp) for the decomposition reaction
N2O4
2NO2 is expressed by Kp = (4x2P)/(1 - x2), where P = pressure, x = extent of
decomposition.
Which one of the following statements is true ?
1) Kp increases with increase of P
2) Kp increases with increase of x
3) Kp increases with decrease of x
4) Kp remains constant with change of P and x
104. If 'I' is the intensity of absorbed light and 'C' is the concentration of AB for the
photochemical process AB + hv AB*, the rate of formation of AB* is directly proportional
to
1) C

m
o

2) I
3) I2

c
.
rs

4) C.I

e
e
in

105. The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and KCl is
1) LiCl > NaCl > KCl
2) KCl > NaCl > LiCl
3) NaCl > KCl > LiCl

g
n

4) LiCl > KCl > NaCl

E
O

o
D

a
a

21/21

eng.edooni.com

Answer Key
1) 1

2) 2

3) 3

4) 2

5) 3

6) 3

7) 2

8) 4

9) 2

10) 4

11) 2

12) 1

13) 4

14) 3

15) 1

16) 4

17) 3

18) 2

19) 1

20) 4

21) 4

22) 1

23) 2

24) 1

25) 3

26) 1

27) 3

28) 4

29) 2

30) 3

31) 4

32) 2

33) 1

34) 3

35) 4

36) 2

37) 2

38) 4

39) 3

40) 1

41) 2

42) 1

43) 3

44) 3

45) 3

46) 1

47) 4

48) 2

49) 2

50) 2

51) 3

52) 4

53) 3

54) 4

55) 1

56) 4

57) 1

58) 4

59) 3

60) 4

61) 1

62) 4

63) 3

64) 4

65) 2

66) 4

67) 1

68) 3

69) 1

70) 2

71) 4

72) 1

73) 2

74) 1

75) 4

76) 4

77) 3

78) 3

79) 1

80) 3

81) 4

82) 1

83) 1

84) 2

85) 2

86) 2

87) 1

88) 2

89) 3

90) 1

91) 4

92) 2

93) 2

94) 3

95) 4

96) 1

97) 2

98) 3

99) 4

101) 1

102) 3

103) 4

104) 2

105) 2

m
o

100) 1

c
.
rs

e
e
in

g
n

E
O

o
D

a
a

1/1

eng.edooni.com