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Polymath

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Polymath Capabilities

Nonlinear Equations Solver

Differential Equations Solver

Regression

Linear & Polynomial

Data Table

Multiple Linear or Multiple Nonlinear Regression

Additional Capabilities

Export to Excel

Calculator and unit conversion tools

Polymath Export to Matlab (see help Menu for more

information)

Todays Class

Provide information on Polymath

How to open and use the software

differential equations

Provide step-by-step instructions so you can practice

and compare results

software program?

Starting Polymath

1. Open Polymath Fogler from the start menu.

1 2 3 4

5 6 7 8

9 10 11 12 13 14 15 16 17 18 19

1. New program

13. Solve system of ODEs

2. Open file

14. Regress and analyze data

3. Open recent file

15. Calculator

4. Save file

16. Unit converter

5. Cut

17. Scientific constants

6. Copy

18. Setup preferences

7. Paste

19. Help

8. Delete

9. Find

10. Find and replace

11. Solve system of linear equations

12. Solve system of nonlinear equations

Help Menu

Consider the following set of equations:

kCA12 = v(CA0-CA1)/V

kCA22 = v(CA1-CA2)/V

where k = 0.075, v = 30,

CA0 = 1.6, and CA2 = 0.2 CA0.

Therefore, we have two remaining variables: variables

CA1 and V.

We will use initial estimates: CA1=1 and V=300.

Rearrange:

0 = kCA12 v(CA0 - CA1)/V

0 = kCA22 v(CA1-CA2)/V

In Polymath, the appropriate forms for these equations

are:

f(V) = kCA22 v(CA1-CA2)/V = 0

Can f(CA1) and f(V) be switched?

corner.

2. Open Nonlinear Equations

3. In the upper left corner, click the f(x)+ button. This will allow

you to enter one of the two equations.

4. A new window will open.

5. Type in the first equation as shown before.

3. In the upper left corner, click the f(x)+ button. This will allow

you to enter one of the two equations.

4. A new window will open.

5. Type in the first equation as shown before.

6. Press Done.

the comments.

8. Enter the second equation by repeating the same steps.

9. You will see the two equations and two initial value guesses in the

worksheet.

10. The red X displays the undefined variables.

11. Enter the undefined variables by either 1) clicking on the x(=)+

button in the menu or 2) entering directly into the worksheet.

9. You will see the two equations and two initial value guesses in the

worksheet.

10. The red X displays the undefined variables.

11. Enter the undefined variables by either 1) clicking on the x(=)+

button in the menu or 2) entering directly into the worksheet.

12. Now you should see a blue check mark indicating this system of

equations can be solved.

13. To solve, click the purple arrow.

Results:

CA1 initial guess: 1

V initial guess: 300

CA1 = 0.602

V= 1102

Ordinary Differential Equations (ODEs)

This system may contain two types of equations: 1) first order

ordinary differential equations and 2) explicit algebraic

equations.

The differential equations must be entered in the following form:

d(x)/d(t)= .

Here t is the independent variable and x is a dependent variable.

Auxiliary algebraic equations must be entered in the form:

x = .

variables. A final value is needed for the independent variable.

2. Select Differential Equations

Series Reaction:

k1

k2

ABC

of A, the formation (and disappearance) of B,

and the formation of C.

Species Balances:

d ( A)

k1* A

d (t )

d ( B)

k1* A k 2 * B

d (t )

d (C )

k2* B

d (t )

parameters: A(0)=1, B(0)=0, C(0)=0

6. We still have two undefined variables: k2 and k1

7. Enter k1 as 1 and k2 as 2.

parameters: A(0)=1, B(0)=0, C(0)=0

6. We still have two undefined variables: k2 and k1

7. Enter k1 as 1 and k2 as 2.

We have an error. We need to enter the initial and final values for

our independent variable (t).

Define Initial and Final values

9. Then enter the initial and final values for t: 0 and 3.

Initial and Final values

9. Then enter the initial and final values for t: 0 and 3.

10. Select Problem and Arrange Equations to sort the list.

Initial and Final values

9. Then enter the initial and final values for t: 0 and 3.

10. Select Problem and Arrange Equations to sort the list.

11. Select Edit and Enter Problem Title

Graph

Run Program

Final values:

A = 0.050

B = 0.047

C = 0.903

Concentration Profiles

Graph generated to show disappearance of reactant A.

Concentration Profiles

Graph generated to show disappearance of reactant A.

Click

Graph

to

modify

Concentration Profiles

Click

brush to

edit

k1

k2

ABC

If k1>>k2, what happens?

Change k2 to 0.5 and k1 to 2

Bmax = 0.25

Bmax = 0.63

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