You are on page 1of 24

JEE (Main), 2015

FULL TEST I

Time Allotted: 3 Hours

ALL INDIA TEST SERIES

FIITJEE Students From All Programs have bagged 34 in Top 100, 66 in Top 200 and 174 in Top 500 All India Ranks. FIITJEE Performance in JEE (Advanced), 2014:
2521 FIITJEE Students from Classroom / Integrated School Programs & 3579 FIITJEE Students from All Programs have qualified in JEE (Advanced), 2014.

FIITJEE

Maximum Marks: 432

Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u l l y. Yo u a r e a l l o t t ed 5 m i n ut es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a ll o wed t o l ea v e t h e E xa m i n at i o n Ha ll b ef o r e t h e en d o f
t h e t es t .

INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.

Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part has only one section: Section-A.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.


(i)

Section-A (01 to 03 and 10 to 12) contains 6 multiple choice questions which have only one
correct answer. Each question carries +8 marks for correct answer and 2 mark for wrong
answer.
Section-A (04 to 09 and 13 to 30) contains 24 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and 1 mark for wrong
answer.

Name of the Candidate


Enrolment No.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

2
AITS-FT-I-PCM-JEE(Main)/15

Useful Data

PHYSICS
Acceleration due to gravity

g = 10 m/s2

Planck constant

h = 6.6 1034 J-s

Charge of electron

e = 1.6 1019 C

Mass of electron

me = 9.1 1031 kg

Permittivity of free space

0 = 8.85 1012 C2/N-m2

Density of water

water = 10 kg/m

Atmospheric pressure

Pa = 105 N/m2

Gas constant

R = 8.314 J K1 mol1

CHEMISTRY
Gas Constant

Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV

=
=
=
=
=
=
=
=
=
=

8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J

Atomic No:

H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,


N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35,
Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

3
AITS-FT-I-PCM-JEE(Main)/15

Physics

PART I
SECTION A

Single Correct Choice Type


This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
1.

A projectile is fired with velocity v at angle of with horizontal. What would be the radius
of curvature of path at instant when rate of change of speed of projectile is minimum.
v 2 cos2
v2
(A)
(B)
g
gcos
(C)

v 2 cos
g

(D)
3

v2
gcos2

2.

Position of particle is given by x = t 4t + 5t + 9. What would be the distance travelled


by particle from instant
t = 0 to instant when particle changes its direction of
velocity for last time.
(A) 1.85 m
(B) 2.15 m
(C) 2m
(D) 2.85 m

3.

If a particle have velocity and acceleration given


1
2
3 i 4 j ms , 4 i 3 j ms respectively.

What would be the rate of change of speed at that instant?


(A) 4.8 ms2
(B) 5 ms2
2
(C) 3 ms
(D) 4 ms2

4.

A ball of mass 1 kg attached with string of length 10 m is free


to rotate in horizontal plane is subjected to constant force of

2 i j N. What should be the velocity of projection at

position shown in figure. Such that it complete full revolution.


(A) 10 ms1
(B) 2 5 ms1
(C) 4 5 ms1
(D) 6 ms1

X
10 m
45

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

4
AITS-FT-I-PCM-JEE(Main)/15

5.

Fluid of density 10 kg/m is kept in container. Container is


moving with acceleration of 10 ms2 find the magnitude of
pressure difference between A and B as shown in figure.
4
(A) 10
(B) 0
(C) 2 104
(D) 2 104

a = 10ms1
X
A(1,0)

6.

Coefficient of friction between all the surfaces is 0.5.


Which diagram would describe the friction between
ground and 2 kg block when f = t. N is applied on 1 kg
block. It is given that string is not taut initially

(A)

(B)

B(2,0)

f=t
1 kg
2 kg

5
5
0

15
5

20 25

10

-15

(C)

(D)

10

15

10

-5

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

5
AITS-FT-I-PCM-JEE(Main)/15

7.

If vA = 10 m/sec what would be the velocity of


C. 1 = 30 0, 2 = 60o. If B is very heavy and
remains on ground.
10
(A)
m/sec
3
(B) 10 3 ms1
(C) 10 ms1
(D) 5 3 ms1

8.

2
C

10 m/sec
A

A ball of mass m kept at top slide freely on frictionless


hemispherical surface. At what minimum angle net force acting
on ball would be equal to mg
(A) cos1 (2/3)
(B) cos1 (1/2)
o
(C) 0
(D) 30 o

9.

From the given velocity acceleration diagram identify in which case object is slowing and
turning to the left.
(A)
(B)
a
a

(C)

(D)
V

a
V

10.

A light ray is incident on a plane mirror M. The mirror is rotated


in direction as shown in figure by an arrows at frequency (9/)
revolution/sec. The light reflected by the mirror is received on the
wall W at a distance of 10 m from axis of rotation. speed of the
spot on wall when angle of incident = 37o is
(A) 10 m/sec
(B) 1000 m/sec
(C) 360 m/sec
(D) 500 m/sec

10 m

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

6
AITS-FT-I-PCM-JEE(Main)/15

11.


A ray of light moving along the vector i 2 j undergoes refraction at an interference of

5
. The unit vector along
2

two media which is x-z plane for y > 0 is 2 while Y < 0 it is


which the refracted ray moves is

3 i 5 j

(A)
34

3 i 4 j

(C)

12.

4i3 j

(D)
5

A dipole is placed at origin of co-ordinate system as shown in figure.


Electric field at point P (0, y) is given as

K
K

(A)
(B) 3 i 2 j
i j
y
3y3

(C)

13.

4 i 3 j
(B)
5

K
i 2 j
y3

(D)

Figure shows a large conducting sheet having


charge density on both sheet. The surface potential
of sheet is V0. A sphere of radius r is placed at a
distance ( >> r) from the sheet. When the key is
closed charge q appears on the surface. The values
on sheet is given by
q 40rV0
(A)

4 r

40rV0 q
(C)

2r

Y
(0, y)

45o

i2 j
3
2y

+
+
+
+
+
+

+
+
+
+
+
+

4 0rV0 q
(B)

2r

(D) Zero
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

7
AITS-FT-I-PCM-JEE(Main)/15

14.

The resistance between A and B of given circuit at t = 0


and t = will be (it the switch is closed at t = 0).
(A) at both t
(B) O at both t
(C) O and R respectively
(D) R at both t

15.

In series LCR circuit voltmeter and ammeter reading


are
(A) V = 250 V, I = 4A
(B) V = 150 V, I = 2A
(C) V = 1000V, I = 5A
(D) V = 100 V, I = 2A

200 V

200 V

50
A

100V, 50 Hz

16.

A radioactive substance X decays into another substance Y. Initially angle X was present.
x and y are distingration constant of x and y. Nx and Ny are the number of nuclei of x
and y at any time t. Number of nuclei Ny will be maximum when
Ny
y
Nx
x
(A)
(B)

Nx Ny x y
Nx Ny x y
(C) y Ny Nx x

17.

(D) x Nx xNy

A capillary tube is immersed vertically in water and the height of the water column is x.
When this arrangement is taken into a mine of depth d, the height of the water column is
x
y. If R is the radius of the earth, the ratio is
y
d

(A) 1
R
R d
(C)

R d

(B) 1
R
R d
(D)

R d

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

8
AITS-FT-I-PCM-JEE(Main)/15

18.

The ends of a rod of length and mass m are


attached to two identical springs as shown in
figure. The rod is free to rotate about its centre
O. The rod is depressed slightly at end A and
released. The time period of the resulting
oscillation is

(C)
19.

O
k

/2

2m
k

(B) 2

2m
3k

3m
2k

(D)

The period of oscillation of a simple pendulum of length L suspended from the roof of a
vehicle which moves without friction down an inclined plane of inclination , is given by
L
L
(A) 2
(B) 2
gcos
gsin
(C) 2

20.

m
2k

(A) 2

/2

L
g

(D) 2

In the circuit shown in figure, A


and B are two cells of the same
emf E and of internal resistances
rA and rB respectively. L is an ideal
inductor and C is an ideal
capacitor. The key K is closed.
When the current in the circuit
becomes steady, what should be
the value of R so that the potential
difference across the terminals of
cell A is zero
(A) R rA rB if rA rB

L
gtan

R
E

E
A

rA

2R

B X

rB
R

(B) R rA rB
1
rA rB
2
(D) For no value of R will the potential difference between the terminals of cell A be equal
to zero

(C) R

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

9
AITS-FT-I-PCM-JEE(Main)/15

21.

A uniform metal rod is moving with a uniform velocity v parallel to a long straight wire
carrying a current I. The rod is perpendicular to the wire with its ends at distance r1 and r2
(with r2 > r1) from it. The emf induced in the rod is
r
Iv
(A) Zero
(B) 0 loge 2
2
r1
(C)

22.

23.

r
0Iv
loge 1
2
r2

(D)

0Iv
r1
1
4 r2

When a centimeter thick surface is illuminated with light of wavelength , the stopping
potential is V. When the same surface is illuminated by light of wavelength 2, the
stopping potential is V/3. The threshold wavelength for the surface is
4
(A)
(B) 4
3
8
(C) 6
(D)
3
Magnetic field
The radiations emitted from a radioactive
(into
the page)
material separate into three distinct groups A, B
A
and C when a magnetic field is directed into the
B

plane of the paper. The names of radiations A,


C

B and C, respectively, are (see figure)

(A) , and

(B) , and

(C) , and

Radioactive
(D) , and
sample

24.

The radioactivity of a sample is X at a time t1 and Y at a time t2. If the mean life of the
specimen is , the number of atoms that have disintegrated in the time interval (t2 t1) is
(A) X t1 Y t2
(B) X Y
(C) (X Y)/
(D) (X Y)

25.

A block of silver of mass 4 kg hanging from a string is immersed in a liquid of relative


density 0.72. If relative density of silver is 10, then tension in the string will be:
[Take g = 10 m/s2]
(A) 37.12 N
(B) 42 N
(C) 73 N
(D) 21 N
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

10
AITS-FT-I-PCM-JEE(Main)/15

26.

An electron is accelerated from rest through potential difference V. Then electron


experience force f in uniform magnetic field on increasing the p.d. to v force became 2f.
(V/V) is equal to
(A) 1/4
(B) 2
(C) 1/2
(D) 4

27.

Magnetic flux linked with a stationary loop of resistance R varies with time T as = at (T
t) amount of heat generated in loop during that time is:
aT
a 2T 2
(A)
(B)
3R
3R
2 2
a T
a 2T 3
(C)
(D)
R
3R

28.

A large tank filled with water to height h is to be emptied through a hole at bottom ratio of
n n

time taken to value of water level from n to & to 0 is


2 2

1
(A) 2
(B)
2
1
(C) 2 1
(D)
2 1

29.

A conductivity rod of length = 1.0 m is moving with uniform


speed v = 20m/sec in field of 4.0T. C = 10 t is connected as
shown in figure
(A) qA = +80 C, q B = 80 C
(B) qA = 80 C, q B = +80 C
(C) qA = 40 C, q B = + 40 C
(D) qA = +40 C, q B = 40 C

30.

What resistor should be connected in parallel with


20 resistor in ADC branch so that potential
difference between B & D may be zero.
(A) 20
(B) 10
(C) 5
(D) 15

A
B

20
A

20

10

5
D

14V

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

11
AITS-FT-I-PCM-JEE(Main)/15

Chemistry

PART II
SECTION A
Single Correct Choice Type

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
1.

The Vander Waals equation of corresponding states for 1 mole of gas is:
[Where Pc = critical pressure, Tc = critical temperature, Vc = critical volume]

P
V
T
and
,
Pc
Vc
Tc

3
(A) 3 1 8R

3
(B) 3 1 8R

(D) 3 1 8R
3

3
(C) 3 1 8R

2.

+2

+3

0
0
Given that EFe
0.77. If Fe , Fe
2 |Fe 0.44V; E
Fe 3 |Fe 2

and Fe solid are kept together

then
(A) Fe3 increase

(C) Fe2 / Fe 3 remain unchanged

(B) Fe3 decrease

(D) Fe decrease

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

12
AITS-FT-I-PCM-JEE(Main)/15

3
conc.

H SO
2

SO3H
Mark out the incorrect statement:
(A) Hexa deutarated benzene gets sulphonated slower than simple benzene
(B) Electrophile in the reaction is SO3
(C) Dilution of acid during reaction promotes reversal (desulphonating)
(D) Polysulphonation is hard to proceed

4.

To maintain the pH of 7.4 for blood at normal condition which is 2M in H2CO3 (at
equilibrium). What volume of 5M NaHCO3 solution is required to mix with 10ml of blood?
K(H2CO3) = 7.8 107
(A) 78.36 ml
(B) 102 ml
(C) 52.71 ml
(D) 89.01 ml

5.

For fairly concentrated solution of a weak electrolyte AxBy, having concentration C the
degree of dissociation is given by:
(A) k eq xy / c
(B) K eqc / xy
(D) K eq / c x y 1.x x .y y

(C) K eq / c x y
6.

x y

XeF6 dissolves in anhydrous HF to give a good conductivity solution which contains:


(A) H and XeF7 ion
(B) HF2 and XeF5
(C) HXeF6 and F ion

(D) None
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

13
AITS-FT-I-PCM-JEE(Main)/15

7.

When the concentration of A is 0.1 M, it decomposes to give x by a first order process


2
1
with a rate constant of 6.93 10 min . The reactant A in the presence of catalyst gives
Y by a second order mechanism with a rate constant of 0.2 min1M1. In order that half
life of both the process is 10 min. One should start the initial concentration of A as:
(A) 0.01M
(B) 5.0 M
(C) 10.0 M
(D) 0.5 M

8.

According to Arrhenius equation, the rate constant (K) and energy of activation (E) of a
reaction are related by:
(A) A KeE / RT
(B) K AeE / RT
E / RT
(C) K Ae
(D) K AeE / RT

9.

HOOC

COOH
C

BD THF

H O , DO , D O

3
2 2
2


Pr oduct

(A)

(B)

COOH

COOD

OD

OD

COOH
(C)

COOD
(D)

COOH
H

OH

COOH
H

DO

COOH

10.

COOH

In alkaline medium, H2O2 acts as an oxidising agent in its reaction with:


(A) Cr2(SO4)3
(B) Ag2O
(C) K3[Fe(CN)6]
(D) K2Cr2O7
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

14
AITS-FT-I-PCM-JEE(Main)/15

11.

(a)

KNO2

(p)

1
pka pka2
2

(b)
(q)
1
pH = pkw pka pkb
PhNH2Cl
2
(c)
NaHCO3
(r)
1
pH = pkw pkb logc
2
(d)
NH4CN
(s)
1
pH = pkw pka logc
2
For abcd correct order of matching is
(A) pqrs
(B) qprs
(C) rspq
(D) srpq

12.

In which of the following case, increase in concentration of ion cause increase in Ecell?
(A) Pt H2 | H aq
(B) Ag, AgCl | Cl aq

pH =

(C) Pt | quinhydron | H
13.

Mark out the correct order of nucleophilicity in DMF:


(A) CH3
(C)

14.

(D) Ag | Ag aq

OH NH2 F I

I F OH NH2 CH3

(B) CH3

OH NH2 I

(D) CH3

NH2 OH

F I

Mark out the right combination of cell and conditious for spontenety
(A) Pt H2 | HCl | Pt H2 ; P1 P2
1M

P1

P2

C1 || Zn2 C1 | Zn; C1 C2
Pt Cl2 , 1 atm | Cl C1 || Cl C2 | Pt Cl2 , 1 atm ;
Pt H2 , 1 atm | HCl C1 || HCl C2 | Pt H2 , 1 atm;

(B) Zn | Zn
(C)
(D)
15.

C2 C1

C1 C2

The dissolution of Al(OH)3 by a solution of NaOH results in the formation of


(A) [Al(H2O)4(OH)4]+
(B) [Al(H2O)3(OH)3]

(C) [Al(H2O)2(OH)4]
(D) [Al(H2O)6(OH)3]
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

15
AITS-FT-I-PCM-JEE(Main)/15

16.

Which of the following is polar and aromatic?


(A)
(B)

(C)

17.

(D)

The species that undergo disproportion in alkaline medium:


(A) Cl2
(B) MnO4
(D) ClO 4

(C) HNO3
18.

None

The compound, whose stereo chemical formula is written below, exhibits are geometrical
isomers & y optical isomers
H
C
H

OH

C
CH2

CH2 C

CH3

The value of x & Y are:


(A) 4 & 4
(C) 2 & 4
19.

(B) 2 & 2
(D) 4 & 2

HBr
Z CH CH2
Z CH2 CH2 Br

Which of the following is Z?


(A) Cl
(C) OCH3
20.

(B) SO3H
(D) CH3

Rank the following in the order of increasing value of the equilibrium constant for
hydration:
O
O

O
(I)
(A) I < II < III
(C) II < I < III

(H3C)3C

(II)

C(CH3) 3

(III)
(B) III < I < II
(D) II < III < I
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

16
AITS-FT-I-PCM-JEE(Main)/15

21.

To a one liter solution of 0.1 N HCl, 0.025 mol of NH4Cl are added. Assuming 80%
dissociation of the solutes, the freezing point of the solution is (Kf = 1.85 deg/molal)
(A) 0.33C
(B) 0.85C
(C) 0.23C
(D) 0.416C

22.

The suggested mechanism for reaction:


CHCl3 Cl2 CCl4 HCl
1

2Cl
Cl2

K2

3
CHCl3 Cl
HCl CCl3 slow

K4
CCl3 Cl
CCl4

The experimental mechanism for reaction:


(A) R = K3[CHCl3][Cl2]
(C) R = K3K1[CHCl3][Cl]
23.

1/2

(B) R = K3K2[CHCl3][Cl2]
(D) R = K3(Keq)1/2[CHCl3][Cl2]1/2

A catalyst increases the rate of reaction at 27C by 10 times. By what amount it is


decreasing Ea at the same temperature.
(A) 2 kJ/mol
(B) 1.3 kJ/mol
(C) 5.7 kJ /mol
(D) 21 kJ/mol

24.

CH3
Li / NH

3
3


Pr oduct
Zn, CH , COOH
3

(A)
H3C

(C)

(B)

OHC

C (CH2) 4CHO
CH

CHO

H3C

(D)

CH3

C (CH2) 3

CH3

O
H3C

CH2

CHO

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

17
AITS-FT-I-PCM-JEE(Main)/15

25.

CH3
1. BH THF

3
Pr oduct major
CH3

2. HO O H, OH
18 18

CH3
(A)

18
HO

H
H3C

CH3

(D)

CH3

HO

CH3
CH3
H

CH3

HO

CH3

26.

18
HO

CH3

(C)

(B)

CH3

H
H3C

CH3

CH3
H

Which of the following is the best synthesis of 2-chloro-4-nitro benzoic acid?


Cl
O2N

COOH

(A) (i) Heat benzoic acid with HNO3 + H2SO4


(i) Cl2, FeCl3,
(B) (i) Toluene + (HNO3 + H2SO4)
(ii) K2Cr2O7, H2O, H2SO4,
(iii) Cl2, FeCl3
(C) (i) Heat chlorobenzene with (HNCO3 + H2SO4)
(ii) CH3Cl, AlCl3
(ii) K2Cr2O7, H2O, H2SO4, Heat
(D) (i) Toluene + (HNO3 + H2SO4)
(ii) Cl2, FeCl3, Heat
(iii) K2Cr2O7, H2O, H2SO4, heat
Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

18
AITS-FT-I-PCM-JEE(Main)/15

27.

When a certain volume, V1 ml of a gaseous hydrocarbon is exploded with excess of


oxygen and the product coded to room temperature, the observed concentration in
volume was 1.5 V1 ml. A further contraction of 2V1 ml was observed on exposure of
product to alkali. Formulae of hydrocarbon is
(A) C2H4
(B) C2H2
(C) C2H6
(D) C3H4

28.

The de-broglie wavelength of an electron that has been accelerated through a potential
difference of 100V is:
(A) 0.12264nm
(B) 1.226m
(C) 1.226nm
(D) 0.012264nm

29.

The correct order of increasing C O bond length of CO, CO32 , CO2 is:
(A) CO23 CO2 CO
(B) CO2 CO32 CO
2
(C) CO CO3 CO2
(D) CO CO2 CO32
Ph

30.
CH2

CH2

CH

CH

Product A is:
(A)

CH2

H+

Ph

(B)

Ph

CH2

CH3

(C)

(D)
CH2

CH3

Ph

Ph

Space for Rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

19
AITS-FT-I-PCM-JEE(Main)/15

Mathematics

PART III
SECTION A
Single Correct Choice Type

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONLY ONE is correct.
1.

For the system of equations

y
z

log
log

log10 x 3 x 2 log5 y 2
log10

log10

y2

z2

z2

x2

Which of following is/are true?


(A) there are infinite number of solution
(B) there is unique solution with x, y, z Q
(C) there are exactly two solution with x, y, z Q
(D) there is no solution
2.

Three points A, B and C are considered on a parabola. The tangents to the parabola at
these points form triangle MNP (NP being tangent at A, PM at B and MN at C). If the line
through B and parallel to axis of parabola intersect AC at L then quadrilateral LMNP
(A) is always a parallelogram
(B) can never be parallelogram
(C) is parallelogram only when ordinates of A, B, C are in AP
(D) has exactly two sides parallel to each other, always

3.

Let f x

e tan x e x ln sec x tan x x


tan x x

be a continuous function at x = 0. The value of

f(0) equals
1
(A)
2
3
(C)
2

(B)

2
3

(D) 2
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

20
AITS-FT-I-PCM-JEE(Main)/15
3

4.

Let , , are the roots of the equation , 8x + 1001x + 2008 = 0. The value of
3
3
3
( + ) + ( + ) + ( + ) is
(A) 251
(B) 751
(C) 735
(D) 753

5.

Number of four digit numbers of the form N = abcd which satisfy following three condition
(i) 4000 < N < 6000 (ii) N is a multiple of 5 (iii) 3 b < c 6 is equal to
(A) 12
(B) 18
(C) 24
(D) 48

6.

A coin that comes up head with probability p > 0 and tails with probability 1 p > 0
independently on each flip, is flipped eight times. Suppose the probability of three heads
1
and five tails is equal to
of the probability of five heads and three tails. The value of p
25
is
5
2
(A)
(B)
6
3
1
3
(C)
(D)
6
4
10

7.

The power of x which has the greatest coefficient in the expansion of 1


2

(A) 2
(B) 3
(C) 4
(D) 5

is

8.

The first two terms of a G.P. add up to 12. The sum of the 3rd and 4th term is 48. If the
term of the G.P. are alternatively positive and negative, then the first term is
(A) 4
(B) 12
(C) 12
(D) 14

9.

If a curve is represented parametrically by the equations x = 4t + 3 and y = 4 + 3t and


d2 x
2
dy is a constant then the value of n, is

dx

dy
(A) 3
(C) 5

(B) 4
(D) 6
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

21
AITS-FT-I-PCM-JEE(Main)/15

10.

The minimum value of the function f x x 3/2 x 3/2 4 x for all permissible real x,
x

is
(A) 10
(B) 6
(C) 7
(D) 8

11.

The complete set of value of a for which there exists at least one line that is tangent to
the graph of the curve y = x 3 ax at one point and normal to the graph at another point is
given by
4

4
(A) a ,
(B) a ,
3

3
4
4

(C) a ,
(D) a ,
3
3

12.

In ABC, if

13.

14.

sin A sinB sinC


c
b
a
, then the value of A is (All symbols have

c sinB
c
b
ab ac bc
there usual meaning)
(A) 120
(B) 90
(C) 60
(D) 30

0 2b c
If A a b c is orthogonal matrix, then |abc| is equal to
a b c
1
1
(A)
(B)
2
3
1
(C)
(D) 1
6

If A aij , where aij i100


nn
1
50
2
(C)
101

(A)

aii
j100 , then lim i1101 equals
n n

1
(B)
101
3
(D)
101

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

22
AITS-FT-I-PCM-JEE(Main)/15

15.

If a + b + c + ab + bc + ca 0 a, b, c R, then value of the determinant

a b 2 2

b c 2

1
2

c a

a2 b 2

1
2

b c2

c a 2

is equal to
2
2

(A) 65
2
2
2
(C) 4(a + b + c )
16.

(B) a + b + c + 31
(D) 0

If z is a complex number satisfying the equation |z (1 + i)|2 = 2 and w


locus traced by w in the complex plane is
(A) x y 1 = 0
(C) x y + 1 = 0

2
, then the
z

(B) x + y 1 = 0
(D) x + y + 1 = 0
2

17.

The angle between pair of tangents drawn to the curve 7x 12y = 84 from M(1, 2) is
1
1
(A) 2 tan1
(B) 2 tan 2
2
1
1

1
(C) 2 tan1 tan1
(D) 2 tan 3
3
2

18.

Tangents PA and PB are drawn to the circle x2 + y2 = 8 from any arbitrary point p on the
line
x + y = 4. The locus of the midpoint of chord of contact AB is
(A) x 2 + y2 + 2x + 2y = 0
(B) x 2 + y2 2x 2y = 0
2
2
(C) x + y 2x + 2y = 0
(D) x 2 + y2 + 2x 2y = 0

19.

Let A(5, 12), B(13 cos , 13 sin ) and C(13 sin , 13 cos ) are vertices of ABC
where R. The locus of the orthocentre of ABC is
(A) x y + 7 = 0
(B) x y 7 = 0
(C) x + y 7 = 0
(D) x + y + 7 = 0

20.

The range of the f x cos1

log4 x

1 x2

sin1
is equal to
2
4x

(A) 0,

2
2


(C) ,
6 2

(B) ,

2
2 2

(D)
6

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

23
AITS-FT-I-PCM-JEE(Main)/15

21.

If lim

n 3n

n x 2 n 3

n 1

1
where n N, then the number of integer(s) in the range
3

x is
(A) 3
(C) 5
22.

(B) 4
(D) infinite

For any natural number m,

7m

x 2m x m 2x 6m 7xm 14

1/m

dx (where x > 0),

equals

7x
(A)

7m

2x 2m 14xm

m 1
m

14 m 1

2x
(C)

7m

7x 2m 14xm
14 m 1

2x
(B)

7x
(D)

m 1
m

7m

14x 2m 7xm

m 1
m

14 m 1
7m

2x 2m xm
14 m 1

m 1
m

23.

Let f: (0, ) R be a continuous function such that F x t f t dt . If F(x2) = x4 + x 5,


0

12

then

f r 2

is equal to

r 1

(A) 216
(C) 222
24.

(B) 219
(D) 225
x 1
and the line L : y = 1, is
x2 1

(B) ln 2 1
4

(D) ln 2 1
2

The area of the region bounded by the curve C : y


1

(A) 1 ln2
2
4
1

(C) ln 2 1
2
4

25.

dy
ey x
dx
1
(A) ln 1 x 2
2

If

(C) ln x 1 x 2

where y(0) = 0, then y is expressed explicitly as


(B) ln(1 + x 2)

(D) ln x 1 x 2

Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com

24
AITS-FT-I-PCM-JEE(Main)/15

26.


If a, b, c are non-zero vectors then value of the scalar
2
(A) a b a b
2 2
(C) b a b

The distance between the line x = 2 + t, y = 1 + t, z



r i 2j 6k 10 , is

2
(B) a 2 a b
2
(D) a b a b

27.

a b a b a b equals

1 t
and the plane

2 2

1
6
1
(C)
7

(A)

(B)
(D)

1
41
9
41

28.

Let a relation R in the set N of natural numbers be defined as (x, y) R if and only if
2
2
x 4xy + 3y = 0 x, y N. The relation R is
(A) reflexive
(B) symmetric
(C) transitive
(D) an equivalence relation

29.

The top of a hill observed from the top and bottom of a building of height h is at angles of
and respectively. The height of the hill is
hcot
hcot
(A)
(B)
cot cot
cot cot
h tan
(C)
(D) none of these
tan tan

30.

Mean deviation about mean from the following data


xi : 3
9 17 23 27
f i : 8 10 12
9
5 is
(A) 7.15
(B) 7.09
(C) 8.05
(D) none of these
Space for rough work

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com