Professional Documents
Culture Documents
33 (2001) 267287
www.elsevier.com/locate/resconrec
Abstract
This article aims to determine the environmental performance of China reed fibre used as
a substitute for glass fibre as reinforcement in plastics and to identify key environmental
parameters. A life cycle assessment (LCA) is performed on these two materials for an
application to plastic transport pallets. Transport pallets reinforced with China reed fibre
prove to be ecologically advantageous if they have a minimal lifetime of 3 years compared
with the 5-year lifetime of the conventional pallet. The energy consumption and other
environmental impacts are strongly reduced by the use of raw renewable fibres, due to three
important factors: (a) the substitution of glass fibre production by the natural fibre
production; (b) the indirect reduction in the use of polypropylene linked to the higher
proportion of China reed fibre used and (c) the reduced pallet weight, which reduces fuel
consumption during transport. Considering the whole life cycle, the polypropylene production process and the transport cause the strongest environmental impacts during the use
phase of the life cycle. Since thermoplastic composites are hardly biodegradable, incineration
has to be preferred to discharge on landfills at the end of its useful life cycle. The potential
advantages of the renewable fibres will be effective only if a purer fibre extraction is obtained
to ensure an optimal material stiffness, a topic for further research. China reed biofibres are
finally compared with other usages of biomass, biomaterials, in general, can enable a three
to ten times more efficient valorisation of biomass than mere heat production or biofuels for
transport. 2001 Elsevier Science B.V. All rights reserved.
268
Keywords: Renewable raw materials; Biofibres; Biomaterials; Environmental life cycle assessment; Fibre
reinforced; Composites; Low-density materials; Transport pallets
1. Introduction
A life cycle assessment (LCA) is performed on two different plastic composite for
an application to plastic transport pallets. After a short introduction, the goal
definition and scooping, the inventory and the impact assessment, the results are
discussed.
1.1. Background
Towards development of sustainable biomass usage, one must first better understand the fundamental loops and processes of the material life cycle. The extraction,
use and disposal of materials indeed have substantial environmental and economic
implications. In many cases far more material is extracted and translocated than
what is actually used in the end product itself. An optimal material technology has,
therefore, to consider resource consumption and the amount and the quality of
waste material during the entire life cycle. Moreover, the sustainability of a specific
technology is determined to a large extent by the pollutant emissions to the
environment during the manufacture of a product, its use and the waste treatment
at the end of its useful life.
Most of the objects of every-day life have a much shorter lifetime than their
constituents. Through increased material efficiency and loop closing, resource
consumption and environmental emissions can be reduced. For that, Lundquist et
al. (1999) define three main possibilities:
Use of renewable resources.
Reuse of products and recycling of materials, including their energy content.
Increase in the product durability.
The use of China reed (Miscanthus sinensis) as the reinforcing fibre in plastics
instead of the more common glass fibre conforms to the first possibility. Moreover,
this replacement reduces the environmental impact of the product transport pallet
without using end-of-pipe technologies. This corresponds to what sustainable
development wants to achieve. The large number of criteria impinging on the
implementation of various kinds of loop-closing structures implies, however, tradeoffs between technological, environmental and socio-economic requirements. For
example, the addition of renewable resources can seriously limit the number of
times a material can be recycled. Furthermore, cultivation, extraction and treatment
of renewable materials are clearly not environmentally neutral, as they may involve
the use of hazardous chemicals in the form of fertilisers as well as refinery and
processing chemicals.
In order to provide optimal environmental solutions, Gutzwiller et al. (1998)
carried out a first comparison of the use of China reed instead of glass fibre in
269
plastics, using estimated physical properties of China reed. Lundquist et al. (1999)
investigated further the technical feasibility of this replacement in plastic transport
pallet. The physical properties of China reed fibre being better known, a more
realistic analysis can be performed. Based on the results of these investigations, this
new study analyses if the use of China reed instead of glass fibre in plastics is
advantageous from an ecological point of view. It also identifies key environmental
parameters, production and use of each material. A plastic transport pallet is the
application used for the comparison of the two types of plastic composites, enabling
one to perform sensitivity analysis on the influence of the lifetime transport
distance.
270
tal life cycle assessment for agriculture, Audsley et al. (1997) developed a systematic approach to LCA of agriculture production. Jolliet et al. (1997) and Wolfenberger et al. (1997) studied M. sinensis used for heat production compared with
other renewable materials. Landtechnik Weihenstephan (1995) and Dinkel et al.
(1996) developed LCA for different renewable materials.
For the plastic components of the transport pallet, Ko ppen et al. (1994)
performed an LCA of glass fibre for insulation purposes. Detailed LCA data for
plastics have recently been updated and published in the BUWAL database
(Haberstatter et al., 1998). Based on these earlier works, this paper develops the
specific case of M. sinensis biofibres and presents results according to the four
phases of LCA, finally comparing the obtained performances to earlier studies.
2.1. Goals
The present study concentrates on the comparison of China reed biofibres used
instead of glass fibre as reinforcement in plastics, with transport pallets as the end
product. It specifically aims:
To determine if the use of China reed instead of glass fibre as reinforcement in
plastics is advantageous from an ecological point of view.
To identify key environmental parameters and phases in the whole life cycle of
transport pallets.
To study various disposal scenarios of the transport pallets (incineration, discharge and recycling) in order to optimise environmentally this part of the life
cycle.
To investigate the sensitivity of the LCA results to different factors, such as
product lifetime, resin fibre content and total transport distance.
271
The system boundaries are chosen in order to include all the processes necessary
for the realisation of the system function. All the processes related to manufacture,
use and disposal of each type of pallet are taken into account. The process tree is
depicted in Fig. 2. For the China reed reinforced pallet, the production of China
reed fibre is considered instead of the production of glass fibre. China reed is
cultivated and then transported to a depot, where it is ground. The unusable part
is put in a bioactive discharge; the fibre is used for the pallet production. During the
manufacture, it is necessary to use a compatibiliser to improve the interface
between polypropylene and natural fibres. The production of this compatibiliser
272
(maleic anhydride) is also taken into account in the system. For the glass fibrereinforced pallet, the following processes are included in the system, production
of glass fibre, polypropylene production, pallet production, use (transporting)
and disposal of the pallets.
Detailed assumptions made in the environmental assessment are presented in
Appendix A.
2.3. Scenarios
The first type of transport pallet studied is composed of polypropylene and
glass fibre (GF pallet). Their lifetime is assumed to be 5 years. The second type
of pallet is composed of polypropylene and China reed fibre (CR pallet). For
this material, only the mechanical properties of its constituents (i.e. fibre and
matrix) are currently available.
A comparison of the two types of pallets requires that they meet the same
service requirements. Thus, they must have the same mechanical properties (in
this case stiffness characterised by the E-modulus). A GF pallet weighting 15 kg,
containing 42% by weight of glass fibre, which is representative for this application, was chosen as a basis for comparison (Lundquist et al., 1999). The fibre
weight fraction of a CR reinforced composite with equivalent stiffness was calculated using a simple law of mixtures, assuming an optimal contact between
matrix and fibre in order to determine the potential of these biofibres. This
pallet weighs 11.8 kg and contains 53% by weight of CR fibre. In practice,
remaining parenchyma residues lead to a poor contact between matrix and biofibres and thus to a strong decrease in the material stiffness. Further research is
presently carried out to enable a purer extraction of the renewable fibre to take
full advantage of their potential. Both pallets are assumed to be disposed by
incineration. This is the reference scenario.
Two alternatives to incineration are considered. On the one hand, a 20%
recycling of the GF pallet, on the other hand bioactive discharge. In addition,
three sensitivity studies have been performed, analysing variations in lifetime,
resin fibre content and use (transport distance), all three compared with the
reference scenario.
Table 1
Pallet composition, reference scenario
PP weight (kg)
Fibre weight (kg)
Total weight (kg)
GF pallet
CR pallet
8.73
6.27
15
5.55
6.22
11.77
273
3. Inventory
3.1. Method
The inventory is the quantitative description of all emissions and all resources
used during the life cycle of each pallet type. Inventory calculations were performed
based on Haberstatter et al. (1998) and Frischknecht et al. (1996). A detailed
description is given by Gfeller Laban et al. (1999). The emissions to air, water and
soil, as well as the renewable and non-renewable raw materials needed during the
entire life cycle, are taken into account. The primary non-renewable energy
consumption for each pallet is then calculated on the basis of the inventory, using
the energy contents proposed by Gaillard et al. (1997).
3.2. Allocation
Other valuable products than pallet use during the 5 years are generated in the
considered system. During incineration usable energy in the form of heat and
electricity can be recovered. It is possible to take account of these valuable products
by allocating them an environmental load. In this study, the allocation is avoided
by system extension: this means that the heat and the produced electricity replace
a quantity of heat and electricity which does not have to be manufactured in the
economic background system according to ISO Standards (ISO, 1998). In a
practical way, they will reduce energy consumption and environmental impacts.
Detailed assumptions are given in Appendix A.
Fig. 3. Energy consumption for the glass fibres (GF) and the China reed pallets (CR). The processes that
are not mentioned, GF incineration, PP incineration, pallet transport, pallet use (transport van),
compatibiliser manufacture, fibre grinding, fibre in bioactive discharge-are negligible.
274
4. Results
http://www.miscanthus.de/anbau.htm
275
Table 2
Emissions of pollutants into air, soil and water for the glass fibre (GF) and the China reed (CR) pallets
Substance
Unit
GF pallet
CR pallet
Air emissions
Maleic anhydride
Benzo[a]pyrene
Cd
CO
CO2
Cr
Cu
Dimethenamide
Glyphosate
H2S
HCl
HF
Hg
Methane
Mn
N2O
NH3
Ni
NMHC
NOx
P
Particles
Pb
Pendimethaline
SOx
V
Zn
(mg)
(mg)
(mg)
(g)
(kg)
(mg)
(mg)
(mg)
(mg)
(mg)
(g)
(mg)
(mg)
(g)
(mg)
(g)
(g)
(mg)
(g)
(g)
(mg)
(g)
(mg)
(mg)
(g)
(g)
(mg)
x
84.1
32.7
74.3
73.1
8.53
45
x
x
80.6
4.48
506
1.48
150
36.6
1.96
0.123
142
497
513
5.19
57.5
195
x
289
1.16
512
5.88
57.8
26.8
54.6
42
4.92
28.6
36.9
38.7
28.3
3.65
201
0.68
79.4
24.3
2.2
11.3
88.6
318
349
2.27
35.1
56.2
34.6
163
0.731
375
Soil emissions
As
Cd
Co
Cr
Cu
Fe
Hg
Mn
Ni
Pb
Zn
(mg)
(mg)
(mg)
(mg)
(mg)
(g)
(mg)
(mg)
(mg)
(mg)
(mg)
447
33.9
6.94
5.61
0.128
2.24
3.54
44.8
0.192
46.9
18.1
264
324
268
5.97
22.5
1.32
274
26.4
3.04
34.2
110
Raw material
Energy
(kWh)
388
199
Water emissions
Ag
Al
(mg)
(g)
607
8.81
382
3.56
276
Table 2 (Continued)
Substance
Unit
GF pallet
CR pallet
As
Ba
BOD
Cd
Chloride
Cl
Co
COD
Cr+3
Cr+6
Cu
Cyanide
F
Fe
Hg
Hydrocarbons
Mn
NH3
NH4+
Ni
Nitrate
Oil
Pb
Phenol
Phosphate
Se
Sulfide
TBT
Zn
(mg)
(g)
(mg)
(mg)
(g)
(mg)
(mg)
(g)
(mg)
(mg)
(mg)
(mg)
(mg)
(g)
(mg)
(mg)
(mg)
(g)
(kg)
(mg)
(g)
(g)
(mg)
(mg)
(g)
(mg)
(mg)
(mg)
(g)
18.1
3.09
414
123
702
119
17
10.7
670
16.3
133
6.55
326
13
166
2.96
257
1.53
x
46.1
1.72
18
135
132
0.587
44.6
31.3
1.01
1.86
7.54
1.78
266
80
443
120
6.87
6.81
406
6.48
77.9
4.29
203
5.08
101
1.11
111
0.947
0.00122
18.7
153
11.1
42.8
83
1.67
18.1
19.7
0.608
1.18
277
the classification, the pollutant emissions are attributed to each impact category or
problem type (greenhouse effect, human toxicity, ecotoxicity, etc.). In the characterisation, the impact of the emissions are weighted and quantified within each
category. In the weightings, the relative damage to safeguard subjects generated by
each impact category is assessed. The main assessment method used in this work
was the Critical Surface-Time method (CST95) developed by Jolliet and Crettaz
(1997) because it enables to take into account the heavy metals in the soil. The
methods CML 92 (Heijungs et al., 1992), Ecopoints (Braunschweig and Mu llerWenk, 1993), and Eco-indicator 95 (Goedkoop, 1995) were also applied to check
the reliability of the results obtained with CST 95.
Fig. 4. Characterisation of incinerated and discharged pallets (GF, glass fibre; CR, China reed),
according to CST95.
278
Fig. 5. Results of the damage characterisation of glass fibre (GF) and China reed (CR) pallets, according
to CST95 for the incineration scenarios.
The polypropylene plays an important role in the life cycle of both pallet types
for primary non-renewable energy consumption and emissions, especially during
material production and incineration. A lower polypropylene content of the pallet
would thus be favourable from these points of view. The use (transporting) of
pallets plays an important role and increases directly with the transport distance.
Furthermore, the glass fibre production generates a significant part of the impacts
of the GF pallets.
For CR pallets, the cultivation has a dominant role for the categories human
toxicity, terrestrial ecotoxicity, and eutrophication. This is due to heavy metal
emissions to soil and to phosphate emissions to water originating from manure and
fertiliser use during China reed cultivation. In this application, applied herbicides
(dimetenamide, glyphosate and pendimethaline) have very little influence. A crucial
point is the crop rotation. It was assumed here that edible crops followed China
reed, which means that a significant fraction of the heavy metals will enter human
diet. This fraction is null if other long-term non-edible crops followed China reed.
Table 3
Results with CML
Unit
Human toxicity
Terrestrial ecotoxicity
Aquatic ecotoxicity
Greenhouse effect
Ozone formation
Acidification
Eutrophication
Energy
kg 1,4
dichleq./pal.
kg 1,4
dichleq./pal.
kg 1,4
dichleq./pal.
kg CO2eq./pal.
kg
ethyleneeq./pal.
kg SO2eq./pal.
kg PO4eq./pal.
MJ/pal.
GF pallet
CR pallet
21.2
9.04
5250
4480
CR pallet (% GF pallet)
43
85
1.09
0.665
61
75.3
0.208
40.4
0.133
54
64
0.653
0.0682
1400
0.432
0.0628
717
66
92
51
279
Table 4
Results with Ecoindicateurs 95
Carcinogenic
substances
Heavy metals
Winter smog
Greenhouse effect
Ozone formation
Acidification
Eutrophication
Energy
Unit
GF pallet
CR pallet
CR pallet (% GF pallet)
kg PAHeq./pal.
7.11107
4.48107
63
kg Pbeq./pal.
kg SO2eq./pal.
kg CO2eq./pal.
kg ethyleneeq./pal.
kg SO2eq./pal.
kg PO4eq./pal.
MJ/pal.
2.43103
0.289
75.3
1.05103
0.653
0.0682
1400
1.72103
0.163
40.4
5.56104
0.411
0.0632
717
71
56
54
53
63
93
51
Substituted
product
Source
2500
Present study
1200
300750
Glass fibre
pallet
Glass fibre
pallet
(LDPE)
polyethylene
foils
Polystyrene
chips
Oil for heat
production
600700
200240
Rapes biofuel
Diesel fuel
Rapes biofuel+heat
production for straw
Diesel fuel+oil
4060
110120
280
Fig. 6. Energy consumption as a function of the recycling rate for the glass fibre (GF) and the China
reed (CR) pallets.
281
6. Interpretation
Fig. 7. Relation between the CR pallet lifetime and primary non-renewable energy consumption.
282
Fig. 8. Relation between primary non-renewable energy consumption and Youngs moduli for the glass
fibre and the China reed pallets.
283
For a GF pallet with a long use distance (over 38 000 km in 5 years), an increase
of the glass fibre content is environmentally unfavourable. The glass fibre has a
three times higher density than the PP. They are heavier and a larger amount of
primary non-renewable energy is needed to transport them.
284
reed is more efficient than starch based biomaterials, as China reeds are a low
energy requiring and efficient C4 plants. More generally, Table 3 confirms that
biomaterials have a much higher substitution potential than the use of biomass
for direct heat production or the production of biofuels for transport. Moreover,
the manufacturing of biomaterials can also be combined with heat production at
the materials end-of-life.
8. Conclusions
The use of China reed fibre as reinforcement in plastics proves to be advantageous from an ecological point of view, provided that the CR pallet has a
minimum lifetime of 3 years. Generally, and this applies to both pallet types, an
optimisation of the polypropylene production process would bring great advantages from both a primary non-renewable energy and an emissions point of view.
A reduction of these emissions to the atmosphere, for example due to better
exhaust gas treatment, would have a very positive influence on the environmental
impacts of both pallet types. Another possible solution would be to replace the
matrix material with a natural and biodegradable material.
It is also important to pay attention to the process of pallet disposal. The
environmental assessment of the discharge shows that the soluble and toxic
heavy metal emission (cadmium) in seepage is the major problem of this disposal
method. An improvement of the incineration plants exhaust gas treatment efficiency, especially the reduction of the heavy metal emissions, would be very
advantageous for this type of disposal.
As far as the basic recycling scenario is concerned, it was observed that
recycling has a positive effect, but that a recycling level of 20% was not sufficient for the GF pallets to match the lower environmental impact of the CR
pallets. To obtain comparable results, it would be necessary to go to extremely
high recycling rates, which may be difficult from a technological and logistic
point of view.
The results of this study could be used as a starting point for the environmental study of other plastics made up of polypropylene and China reed fibre or
polypropylene and glass fibre in order to develop other technical applications.
Furthermore, the comparison with other uses of biomass shows that biomaterials
have a much higher substitution potential than the use of biomass for direct
heat production or the production of biofuels for transport. Higher priority in
research about the use of biomass should, therefore, be given to biomaterials.
Acknowledgements
The authors would like to thank Genossenshaft Biomasse Technologie,
Switzerland for supplying the China Reed used in this study. Pharmacia and
Upjohn, Sweden, financially supported this work.
285
Appendix A. Assumptions
Name of process
Cultivation of China
reed
Assumptions
Source
Gutzwiller et al. (1998)
286
Consumption of energy of
the UIOM: Heat: 0.24
MJtherm/kg. Electricity:
0.36 MJelect/kg
ESU (1996)
Bonus of incineration PP Energy recovery:
(PCIPP = 30.5 MJ/kg).
Heat: 26%. Electricity:
10%
Bonus of incineration
Energy recovery:
reed
(PCICR = 14 MJ/kg).
Heat: 26%. Electricity:
10%
ESU (1996)
Wolfenberger et al.
(1997)
Transports which are not explicitly mentioned in this table (for example: transport of glass fibres from production to pallet manufacture) are not taken into
account in this study as they are negligible from an environmental point of view
compared to the transport studied above.
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