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# EKC316 - SEPARATION PROCESS

HUMIDIFICATION
DR. AZAM T MOHD DIN
SCHOOL OF CHEMICAL ENGINEERING
UNIVERSITI SAINS MALAYSIA
Semester II, 2014/2015

TEXT BOOKS

OUTLINES
Principles and theory of humidification process
Introduction to industrial
dehumidification equipment
Design of cooling tower

humidification

&

## From left to right: a reinforced concrete tower, a wood

tower, and a hyperbolic tower built with a steel framework

www.spxcooling.com/

HUMIDITY

Psychrometry

Moist air

## How does relative

humidity affects people?
0% humidity

100% humidity

London, 2006-2012

Penang, 2006-2012

## Temperature : dry-bulb, wet-bulb

Humidity : Relative, Absolute, Percent

Enthalpy

Dry-bulb Temperature
It is true temperature of air measured (or, any
non-condensable and condensable mixture) by a
thermometer whose bulb is dry.

Wet-bulb Temperature
It is the steady-state temperature attained by a
small amount of evaporating water in a manner
such that the sensible heat transferred from the
air to the liquid is equal to the latent heat
required for evaporation.

Dew point
A temperature at which a vapor-gas mixture must be cooled (at
constant humidity) to become saturated.
The dew point of a saturated gas equals the gas temperature.

## If a vapor-gas mixture is gradually cooled at a constant pressure,

the temperature at which it just becomes saturated is also called
its dew point.

Relative humidity
It is the ratio of partial pressure of water vapor
(pA) in air at a given temperature to the vapor
pressure of water (pvA) at the same temperature.
Re lative humidity

pA
v
pA

x100%

## Relative humidity does not explicitly give the

moisture content of a gas, but gives the degree
of saturation of the gas at a given temperature.

## It is the direct measurement of moisture content in

a gas. The mass of water vapor per unit mass of
dry gas is called absolute humidity, Y.
Eq. 1

## Percent humidity or percent saturation

It is the relation between absolute humidity to that of saturation humidity at the same temperature
and pressure.

Eq. 2
where, Y is absolute humidity of sample of air and Ys is humidity at same temperature and pressure
if saturated with water vapor.

Eq. 3

## and vapor pressure of water can be calculated

by Antoine Equation:
Eq. 4

## where, pressure is in bar and temperature is in K.

Humid volume
The humid volume, vH, is defined as the volume of
unit mass of dry air with accompanying water
vapor at a given temperature and pressure.
Eq. 5

## Assuming ideal gas behaviour.

TG is gas temperature in C.

Humid Heat
The humid heat, cH, is the heat energy required to raise the
temperature of unit mass of dry air with the accompanying
water vapor by one (1) degree.

## At ordinary T & P, the heat capacity of dry air = 1.005

kJ/kg.K and that of water vapor as 1.88 kJ/kg.K

## cH 1.005 1.88Y kJ/(kg dry air)(K) Eq. 6

'

Enthalpy
The enthalpy of a vapor-gas mixture, H is the sum of
the relative enthalpies of gas and vapor content.

## Enthalpy = Latent heat + Sensible heat

Eq. 7

At 0 C, 0 = 2500 kj/kg

## H ' 2500Y '(1.005 1.88Y ' )(TG T0 ) kJ/kg dry air

Sensible heat
When an object is heated, its temperature rises as heat is added. The increase in heat is called sensible heat. Similarly,
when heat is removed from an object and its temperature falls, the heat removed is also called sensible heat. Heat that
causes a change in temperature in an object is called sensible heat.
Latent heat
All pure substances in nature are able to change their state. Solids can become liquids (ice to water) and liquids can
become gases (water to vapor) but changes such as these require the addition or removal of heat. The heat that causes
these changes is called latent heat.
Latent heat however, does not affect the temperature of a substance - for example, water remains at 100C while boiling.
The heat added to keep the water boiling is latent heat. Heat that causes a change of state with no change in temperature
is called latent heat.

Appreciating this difference is fundamental to understanding why refrigerant is used in cooling systems. It also explains
why the terms 'total capacity' (sensible & latent heat) and 'sensible capacity' are used to define a unit's cooling capacity.
During the cooling cycling, condensation forms within the unit due to the removal of latent heat from the air. Sensible
capacity is the capacity required to lower the temperature and latent capacity is the capacity to remove the moisture from
the air.

Ref: https://www.spaceair.co.uk/faqs/what-is-the-difference-between-sensible-and-latent-heat

The adiabatic saturation temperature is a thermodynamic property of
moist air that is defined as the temperature that the air stream would
achieve if it were allowed to become saturated adiabatically. The
adiabatic saturation temperature is computed by equating the
enthalpy of moist air at a given temperature and relative humidity to
the enthalpy of a saturated air-water mixture at the adiabatic
saturation temperature (ASHRAE, 1996).

## The process of adiabatic saturation of air

an adiabatic saturator is a device in which air flows through an infinitely long duct
containing water.
As the air comes in contact with water in the duct, there will be heat and mass transfer
between water and air.
If the duct is infinitely long, then at the exit, there would exist perfect equilibrium
between air and water at steady state. Air at the exit would be fully saturated and its
temperature is equal to that of water temperature.
The device is adiabatic as the walls of the chamber are thermally insulated. In order to
continue the process, makeup water has to be provided to compensate for the amount of
water evaporated into the air. The temperature of the make-up water is controlled so
that it is the same as that in the duct.

Psychrometric Charts
The psychrometric chart characterizes the interdependences of seven properties of water-vapour
mixture:
dry-bulb temperature
wet-bulb temperature,
relative humidity,
absolute humidity,
dew point,
enthalpy and
specific volume

## If any two of these quantities are known, the

other five quantities can be readily obtained
from the Psychrometric chart.

## If TG is the dry-bulb temperature of air and Y is its humidity, its state is

denoted by point a. It falls on the constant humidity line, A%.
The adiabatic saturation line through a is ab.
c point indicates its humidity, Y.

## The adiabatic saturation temperature, Ts is obtained by drawing the

vertical line through b. For air-water system, wet-bulb temperature Tw
is practically same as Ts.

## The humidity of the adiabatically saturated air is given by the point e.

The dew point Td is given by the point d that can be reached by moving
horizontally from the point a to 100% humidity line and then moving
vertically down to the temperature axis.
The humid volume of saturated air at TG corresponds to the point f and that
of dry air at TG is given by point g.

The point m gives the humid volume if the humidity is Y and it is reached by
interpolation between g and f.
Enthalpy of a sample of air can also be obtained from humidity chart.

IN-CLASS EXERCISE 1
Determine the following psychrometric properties of a moist air sample having a dry bulb
temperature 27C and a humidity of 0.015 kg/kg dry air using the pyschrometric chart and/or
the vapour pressure equation for water:
a) Relative humidity

b) Dew point

## d) Wet bulb temperature

e) Enthalpy

f) Humid volume

g) Humid heat

DEFINITIONS
Humidification involves the transfer of water from the
liquid phase into a gaseous mixture of air and water
vapor (Geankoplis, 2003).
The process of increasing the moisture content of air
is called humidification (Dutta, 2007)

What is dehumidification?

## AIR-WATER CONTACTING APPS

Water cooling air-water contacting is done mostly for the
purpose of cooling the warm water before it can be reused.
Humidification of gas for drying of solids under controlled
condition.
Dehumidification and cooling of gas in air conditioning.
Gas cooling

## Cooling Tower Construction & Operation

A cooling tower is a special type of heat exchanger in which the warm water and
the air are brought in direct contact for evaporative cooling.
It provides a very good contact of air and water in terms of the contact area and
mass transfer co-efficient of water vapor while keeping air pressure drop low.
Enthalpy of air is lower than enthalpy of water. Sensible heat and latent heat
transfer take place from water drop to surrounding air.
Thus, cooling is accomplished by sensible heat transfer from water to air and
evaporation of a small portion of water.

## General cooling Tower

The hot water which is coming from heat exchanger is sprayed at the top of the cooling
tower.
Air enters through the louvers at the two opposite walls of the cooling tower.
During cooling process of water, around 2% water is evaporated. Make water is used to
compensate the water loss due to evaporation.
Blowdown is there to drain a part of water containing solid deposit.

The exit cold water from the cooling tower is used in the heat exchanger or other unit
operation.

## FACTORS GOVERN THE OPERATION OF COOLING

TOWER
The dry-bulb and wet bulb temperatures of air

## Temperature of warm water

The efficiency of contact between air and water in terms of volume transfer coefficient
Contact time between air and water

## The uniformity of the distribution of the phases within the tower

Air pressure drop
Desired temperature of cooled water

## Atmospheric Cooling Tower

It is a big rectangular chamber with two opposite louvered walls.

## Tower is packed with a suitable tower fill.

Atmospheric air enters the tower through louvers driven by its own velocity.
Direction and velocity of wind greatly influence its performance.

## Natural draft cooling tower has a large reinforced

concrete shell of hyperbolic shape (also called
hyperbolic tower).
Natural flow of air occurs through the tower; hence it is
called natural draft

## Factors responsible for creating natural draft

(a) A rise in temperature and humidity of air in the column reduces its density
(b) Wind velocity at the tower bottom

Fan is used to enhance the air flow rate in fan assisted natural draft tower.
The typical diameter of tower is 100 m, heigh of 150 m and capacity is
5,00,000 gallon/minute.

## Why hyperbolic shape?

(i) More packing materials can be placed at the bottom
(ii) The entering air gets smoothly directed towards the centre
(iii) Greater structural strength and stability

## Mechanical Draft Towers

Forced draft

Induced draft

Fans are used to move air through the tower in mechanical draft
cooling towers.

FORDED DRAFT: It has one or more fans located at the tower bottom to push air into tower.

(a) A part of the velocity head of air thrown by the blower is converted to pressure head on entering
into the tower. It makes energy efficient than induced draft.
(b) Less susceptible to vibrations as fans are installed near the ground.

(a) Air flow through the packing may not be uniform
(b) Some of the warm and humid air may be recirculated back. Recirculation rate becomes low if the
wind velocity is high. It is not popular except for small capacities.

## Forced draft cooling tower

Induced draft towers: One or more fans are installed at the top of the tower. Depending on the air inlet
and flow pattern, induced draft towers are of two types, cross-flow and counter flow towers.
Major advantages of countercurrent induced draft cooling tower
(a) Relatively dry air contacts the coldest water at the bottom of the cooling tower

(b) Humid air is in contact with the warm water and hence maximum average driving force prevails for
both heat and mass transfer.
Disadvantage of induced draft towers compared to forced draft towers

## (a)It consumes more horse power.

(b) Cross-flow induced draft cooling tower requires less motor horse power than countercurrent induced
draft cooling towers.

## Cross-flow induced draft cooling tower supplies horizontal

air flow along the packed height and requires less motor
horse power than the counter-flow type.

Counterflow

Cross flow

## Structural Components & MOC

The shell, the framework and casing walls wooden, concrete, steel , glass fibre reinforced casing
walls.
The tower fills/packings splash type, film type (counterflow), plastic, wood
Louvers air passage, glass fibre, wood
Drift eliminators - plastic
Fans propeller, centrifugal
Water distribution gravity distribution, spray

Drift Eliminator
In every cooling tower there is a loss of water to the environment due to the evaporative cooling
process.
This evaporation is usually in the form of pure water vapor and presents no harm to the
environment.

Drift, however, is the undesirable loss of liquid water to the environment via small droplets that
become entrained in the leaving air stream.
There, water droplets carry with them chemicals and minerals, thus impacting the surrounding
environment.

## Drift eliminators are designed to capture large

water droplets caught in the cooling tower air
stream.
The eliminators prevent the water droplets and
mist from escaping the cooling tower.
Eliminators do this by causing the droplets to
change direction and lose velocity at impact
on the blade walls and fall back into the
tower.

## Efficient drift eliminators will keep drift losses

to less than .001% of the re-circulating water
flow rate.

http://www.towercomponentsinc.com/operation-drift-eliminator.php

Tower Problems
Scale inorganic minerals CA2CO3 etc.
Fouling waterborne contaminants
Microbial growth bacteria, algae, fungi, legiollosis
Corrosion

Consequences
Energy losses

## Reduced heat transfer efficiency

Increased corrosion and pitting

## Loss of tower efficiency

Wood decay and loss of structural integrity of the cooling
tower

## Cooling Range & Approach

Cooling range is the difference in the temperature of the inlet hot
water and the outlet cooled water.
If hot water is cooled from 40C to 30C, the range is 10C.

## Approach is the temperature difference between what is

being produced and the power source that creates the
product.
In the case of cooling tower, the product is cold water
leaving the tower and ambient wet bulb is the driving force
that creates the cold water.
If a cooling tower produces 85F cold water when the
ambient wet bulb is 78F, then the cooling tower approach is
7F.

## If a small approach is targeted, the height of packing

increases rapidly.

## Theoretically, the approach is zero if a tower has an infinite

packed height.

What happened if the designed wet bulb temperature is higher than the actual wet bulb
temperature?

## Design of Cooling Tower

We need to determine:
The tower cross-section required to take the given load of
warm water.

## The height of packing required to achieved the desired

cooling of water.

## Basic assumptions for the design of cooling tower are as

follows:
(i) the rate of vaporization of water is much less than the rate
of water input to the tower (about 1% loss of feed water)

tower

## Enthalpy balance diagram of cooling tower

Let, L is the constant water flow rate (kg/m2s) and Gs is the air
rate (kg dry air/m2s). Across a differential thickness dz of the
bed, temperature of water is decreased by dTL and the
enthalpy of air is increased by dH.
Hence, change in enthalpy of water = L.cWL.dTL and,

Eq. 8

Eq. 9

## Enthalpy balance over envelope I:

LcWL(TL - TL1) = Gs(H - H1) This is the operating line for
air-water contact. Eq. 11
Enthalpy balance over envelope II:
LcWL(TL2 - TL1) = Gs(H2 - H1)

Eq. 12

## The equilibrium curve for air-water system on TL-H plane is

the plot of enthalpy of saturated air versus liquid temperature
at equilibrium.

## Rate of transfer of water vapor to air in the differential

volume is
Eq. 13
The decrease in temperature of air for sensible heat transfer
to water is

Eq. 14

Eq. 15

by
Eq. 16

Eq. 17

## Height of gas-enthalpy transfer units

Eq. 18
Height of gas-enthalpy transfer unit
Eq. 19
Hence, height of cooling tower (packing section), z
Eq. 20

In Class Example
A cooling tower is to be designed to cool water from 45C to 30C by
countercurrent contact with air of dry bulb temperature 30C and wet bulb
temperature of 25C. The water rate is 5500 kg/m2.h and the air rate is 1.25
times the minimum. Determine the tower height if the individual gas-phase
mass transfer coefficient (kY/) is 5743.5 kg/m3h. The volumetric water side heat
transfer coefficient is given by hL=0.059L0.51Gs, in Kcal/m3hK, where L and Gs are
mass flow rates of water and air (dry basis).
Antoine Equation: ln PVA(bar)=11.96481-3984.923/(T-39.724)

Solutions
TG1 = 30, TW = TS = 25, used a psychrometric chart to read Y.
From chart, Y1 = 0.019
Now, used equation 6 & 7 to calculate H1
TL1 = 30, TL2 = 45

## Plot the equilibrium line

Locate point Q(TL1,H1 ) (Lower terminal of operating line) at Q(30, 78.7) on TL-H plane.
Draw a tangent to the equilibrium line through Q. Slope of the tangent is 8.44.

H2 = 180 kJ/kg
locate point P (TL2, H2) (Upper terminal of the operating line) at P (45, 180) on TL-H2 plane.

## Randomly choose one upper point within graph (x2, y2).

Choose another one point at lower part of the graph (x1, y1) with x1 is left unknown.
Use the following formula to guess x1.

Solved for x1 and draw the 1st tie line. Subsequently, replicate the line by maintaining the same
slope to get a set of tie lines.

250

Equilibrium Line

230

Q point
210

Tangent

P Point

## H' (kJ/kg dry air)

190
170

Operating Line

150
130

110
90

Tie line

70
50
22

27

32

37

Temperature (Celcius)

42

47

A set of tie lines of this slope is drawn from several points on the operating line. These tie lines
meet the equilibrium line at (TLi,Hi ). Hence, the points (H, Hi ) are obtained.

TL

30

32.5

35

37.5

40

42.5

45

H'

78.7

96.4

112.8

130.3

148.8

165.3

184

TLi

28.7

31.4

33.9

36.6

39

41.4

43.7

H'i

93.0

107.5

123.2

139.9

158.4

177

198.8

1/(H'-H'i)

0.070

0.090

0.096

0.104

0.104

0.085

0.068

0.120
0.100

1(H'-H'i)

0.080
0.060
0.040
0.020
0.000
78.0

98.0

118.0

138.0

H'

158.0

178.0

## NtG =Area under the curve= (184-78.7)0.088=9.27

HtG = Gs/kYa = 3410/5743.5 = 0.59 m

## z = HtGNtG = 0.59 x 9.27 = 5.47 m

Blowdown
During the cooling process of hot water in cooling tower, around 2% water
evaporates.

In the long run, it increases the solid content in the circulating water. Some dust
particles also come from the environment and mix with circulating water.
The solid content of the cooled water must be kept under a certain limit to avoid
scaling or fouling on the heat exchange equipment.
A part of the circulating water is drained from the bottom of the cooling tower to
discard the deposited solids from the cooling tower blowdown.
The losses due to blowdown, evaporation, drift and leakage are compensated by

## Water balance in cooling tower M = B + D + E

Solid balance MC1 = (B + D)C2 + (E)(0)

The water vaporized (E) does not have any solids in it, and the TDS in the
blowdown and in the drift is the same as that in the circulating water.
(B + D + E)C1 = (B + D) C2
Where r = C2/C1

M Makeup rate
B Blowdown rate
D Rate of looses due to drift
and leakages
C1 = dissolved content in the
makeup water
C2 = dissolved content in the
circulating water

## Once the blowdown rate B is known, the makeup rate MEmay

be flow
calculated.
= (water
rate)(range, F)(0.0008)

IN CLASS EXAMPLE
An induced draft crossflow tower is rated to cool 15000 gpm of
water from 40C to 29C. The total solid concentration must not
exceed 900 ppm. The TDS of the makeup water is 300 ppm. About
0.1% of the water is lost by drift from the tower and leakages in the
circulation system. Calculate the blowdown and makeup rate.

Solutions
The range = 40 29 = 11C = 19.8 F
E = (15000)(19.8)(0.0008) = 237.6 gpm
D = 0.1% x 15000 = 15 gpm

r = C2/C1 = 900/300 = 3
B = [(237.6 15(3-1)]/(3-1) = 104 gpm
M = B + D + E = 104 + 15 + 237.6 = 356.6 gpm