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Section 2

1.

Chemistry

What volume of Hydrogen gas, at 273 K and 1 atm pressure will be consumed in obtaining 21.6 g
of elemental boron (atomic mass = 10.8) from the reduction of boron trichloride by Hydrogen
(a) 22.4 L
(c) 67.2 L

(b) 89.6 L
(d) 44.8 L
px

2.

The number of nodal planes in a


(a)
One
(c) Three

3.

(b)

Two

(d) Zero

The correct order of increasing


CO 32

CO 2 CO

CO

CO 32

(a)

CO 2

CO

CO 32

CO, CO 32 , CO 2

bond length of

is

CO

(b)
CO CO 2 CO 32

CO 2

(c)
4.

is

(d)

An aqueous solution of a weak monobasic acid containing 0.1 g in 21.7g of water freezes at
Kf
272.813 K. If the value of
for water is 1.86 K/m, what is the molecular mass of the
monobasic acid
(a) 50 g/mole
(b) 46 g/mole
(c) 55 g/mole
(d) 60 g/mole

5.

In which compound 8 : 8 coordination is found


(a)

MgO

CsCl

(b)

Al 2O3

(c)

(d) All of these


CH 4

6.

At what temperature will the average speed of

molecules have the same

O2

7.

value as
has at 300 K
(a) 1200 K
(b) 150 K
(c) 600 K
(d) 300 K
Half-life of radium is 1580 yrs. Its average life will be
2.5 103 yrs

(a)

1.832 103 yrs

(b)
3

8.825 102 yrs

2.275 10 yrs

(c)

(d)
CH 3OH , CO

8.

The partial pressures of


reaction
CO 2H 2

CH 3OH

H2

and

in the equilibrium mixture for the

KP

at 427C are 2.0, 1.0 and 0.1 atm respectively. The value of
CH 3OH

decomposition of

H2

to CO and

is
2 102 atm1

1 10

(a)
50 atm2

(c)

(d)

for the

atm

(b)

5 103 atm2
1.0 105 ,

9.

The dissociation constant of a weak acid is


the reaction with strong base is
(a)

1.0 105

(b)

(c)

1.0 10

(d)

the equilibrium constant for

1.0 109
1.0 1014

H 9.08kJ mol1

S 35.7 JK

mol1

For a reaction
and
Which of the following statements is correct for the reaction
(a)
Reversible and Isothermal
(b) Reversible and Exothermic
(c) Spontaneous and Endothermic
(d) Spontaneous and Exothermic
11. Which of the following is the fastest reaction
10.

1
O2 250 C CO
2

(a)

1
O 2 500 C CO
2

(b)
C

1
O 2 750 C CO
2

(c)

1
O2 1000
C CO
2

(d)
Al 3

12.

4.5g of aluminum (at mass 27amu) is deposited at cathode from


solution
by a certain quantity of electric charge. The volume of hydrogen produced at
STP from
(a)22.4 L
(c)5.6 L

13.

ions in solution by the same quantity of electric charge will be


(b) 44.8 L
(d) 11.2 L

In which of the following compounds, is the oxidation number of iodine is


fractional
IF3

(a)

IF2

(b)
I 3

(c)
14.

IF7

(d)

Example of intrinsic colloid is


(a) Glue
(b) Sulphur

(c)
15.

As2S3

Fe

(d)

Which of the following configurations represents atoms of the elements having


the highest second ionization energy
1s2 2s2 2p4

1s2 2s2 2p6

(a)

(b)
2

1s2 2s2 2p6 3s2

1s 2s 2p 3s

(c)
16.

(d)

Zone refining is a technique used primarily for which one of the following
process
(a) Alloying
(b) Tempering
(c) Sintering

17.

(d) Purification

Which of the following pair will not produce dihydrogen gas


Fe H 2SO4

Cu HCl(dil.)

(a)

(b)
Mg steam

18.

Na alcohol

(c)
(d)
The composition of the common glass is
Na2O.CaO.6SiO3

(a)

Na2O.Al2O3.SiO2

(b)
CaO.Al2O3.SiO2

Na2O.CaO.6SiO2

(c)
(d)
19. Out of all the known elements, the percentage of transitional elements is
approximately
(a) 30%
(b) 50%
(c) 60%
20.

(d) 75%

Which one of the following has largest number of isomers ?


[Ir(PP3)2 H (CO)]2

(a)

[Co(NH3)5 Cl ]2

(b)
[Ru(NH3)4 Cl 2]

[Co(en)2 Cl 2]

(c)
(d)
(R = alkyl group; en = ethylenediamine)
FeSO4 , Al 2 SO4 3

21.

An aqueous solution of

and chrome alum is heated with excess of

Na2O2

and filtered. The materials obtained are


(a) A colourless filtrate and a green residue
(b) A yellow filtrate and a green residue
(c) A yellow filtrate and a brown residue
(d) A green filtrate and a brown residue
22. What is the correct IUPAC name of

CHO
NO2
OCH 3

(a) 4-methoxy-2-nitrobenzaldehyde
(b) 4-formyl-3-nitro anisole
(c) 4-methoxy-6-nitrobenzaldehyde
(d) 2-formyl-5-methoxy nitrobenzene
C 4 H 10

23.

Number of isomers of
is
(a) 2
(b) 3
(c) 4
(d) Isomerism not exist
CH 3
|

CH 3 C CH CH 3
24.

The compound
gives

NaIO4

on reaction with

KMnO4

in the presence of

CH 3CHO CO 2

(a)
CH 3COCH

CH 3COCH

CH 3COOH

CH 3COCH

CH 3CHO

(b)
(c)
(d)
25.

Wurtz reaction of methyl iodide yields an organic compound X. Which one of


the following reactions also yields X
C 2H 5Cl Mg

dryethe
r

(a)
C 2 H 5Cl LiAlH 4

(b)
C 2H 5Cl C 2H 5ONa

(c)
CHCl 3 Ag powder

(d)