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Product : R3XHT (Part A),

Date : 5 January 2013

MSDS No. : 21112012

MATERIAL SAFETY DATA SHEET


1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product Name: R3XHT (Part A),
Date : 5 January 2013
MSDS No. : 21112012
Company:
Supplier:
3X ENGINEERING
9 Av. Albert II
98000 Monaco
Tel. : +377 92 05 79 81
Fax : +377 92 05 72 71
(mon. fri. 8 a.m. 5 p.m.)
E-mail (questions) : 3x@3xeng.com
For Chemical Emergency:
ORFILA : 01.45.42.59.59
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical characterization:
Modified epoxide resin on basis Bisphenol-A-Epichlorhydrinresin especially formulated on
non-corroding steel-alloy powder and+ AI2O3+ SiC
Dangerous components:
Bisphenol A-epichlorohydrin resin
CAS-Number:
25068-38-6
NLP:
500-033-5
Symbol(s):
Xi, N
R-phrase(s):
36/38, 43, 51/53
Concentration:
> =95 %
3. HAZARDS IDENTIFICATION
R 36/38
R 43
R 51/53
4. FIRST AID MEASURES
General advice:
Eeye contact:
Skin contact:
Inhalation :
Ingestion:

Irritating to eyes and skin.


May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Move out of dangerous area. Take off all contaminated clothing immediately.
Rinse immediately 15 minutes with plenty of water, also under the eyelids. Consult a doctor.
If you have skin contact, you must wash off with much water and soap. If irritation persists,
consult a doctor.
Move to fresh air. Consult a physician after significant exposure.
Prevent vomiting if possible. Clean mouth with water and drink afterwardsplenty of water. Call
a physician immediately.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing agents:
Special hazards during fire fighting:
Protective equipment:

Water spray, foam, CO2, extinguishing powder


In case of fire toxic gases may be built
In the event of fire, wear self-contained breathing apparatus. Wear personal
protective equipment.
Additional information
Water mist may be used to cool closed containers, risk of bursting. Extinguishing
water is to be disposed of in accordance with local authority regulations
6. ACCIDENTAL RELEASE MEASURES
Person precautions:
Keep unprotected people away. Use personal protective equipment. Avoid
contact with skin, eyes and clothing.

Product : R3XHT (Part A),


Date : 5 January 2013
Environmental precaution:
Methods for cleaning up:
Additional advice:
7. HANDLING AND STORAGE
Handling
Safe handling advice:

MSDS No. : 21112012


Do not allow reach sewage system or water bodies. Do not allow to enter the
ground/soil.
Soak up with inert absorbent material e.g. sand, silica gel, acid binder, uni-versal binder, sawdust
Inform fire brigade or police if the product has penetrated into water or into
the sewerage or if soil or plants have been contaminated.

Ensure adequate ventilation, especially in confined areas. Avoid contact with skin and eyes.
Handle in accordance with good industrial hygiene and safety practice.

Advice on protection against


fire and explosion:
No special precautions necessary if used correctly
Requirements for storage
areas and containers:
Keep container tightly closed. Keep in a well-ventilated place.
Advice on common storage:
No materials to be specially mentioned
8. EXPOSURE CONTROLS PROTECTION
Additional information on the
lay-out of technical plant:
No special precautions necessary if used correctly
Components with workplace control parameters
Components:
CAS-Number:
Value:
Release notes:
Basis:
Personal protection equipment
Respiratory protection:
Breathing apparatus only if aerosol or dust is formed. No personal respiratory
protective equipment normally required.
Hand protection:
Polyvinyl alcohol or nitrile-butil rubber gloves
Eye protection: safety glasses
Skin and body protection:
Long sleeved clothing, rubber or plastic apron
Hygiene measures:
Avoid contact with skin and eyes. Wash hands before breaks and the end of
workday. Keep away from food and drink.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Appearance:
pasty or brushable
Form:
Colour:
Odour:
Other data
Boiling point/range:
Flash point:
Ignition temperature:
Upper explosion limit:
Lower explosion limit:
Vapour pressure:
Density:
Solubility/qualitative:
Water solubility:
pH-value:
Viscosity, dynamic:
10. STABILITY AND REACTIVITY
Thermal decomposition / conditions
to be avoided:
Hazardous reactions:
Hazardous decomposition products:

grey
almost odourless
< 200C
> 200C (DIN 53213)
approx. 460C

at 20C > 0.1 hPa


at 20C > 2,5 g/cm3
at 20C >0.1g/l
400000 mPa

No decomposition if stored and applied as directed.


Exothermic reaction with amines and strong acids.
NO decomposition if stored and applied as directed.

11. TOXICOLOGICAL INFORMATION


Acute oral toxicity:
LD50 rat 10000 mg/kg (for main component)

Product : R3XHT (Part A),


Date : 5 January 2013

MSDS No. : 21112012

Acute inhalation toxicity:


Acute dermal toxicity: LD50 rat > 2000 mg/kg
Skin irritation
May cause skin irritation in susceptible persons.
Eye irritation:
Contact with eyes may cause irritation.
Sensitization:
May cause sensitization of susceptible persons by skin contact.
Further information:
This product was not tested itself. The above mentioned values are results
of a product with comparable formulation.
Human Experience:
Repeated or prolonged skin contact may cause allergic reactions with susceptible
persons.
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Biodegradability:
The product has not been tested. Not readily biodegradable.
Physicochemical removability:
Most parts can be separated mechanically in a sewage plant.
AOX:
Additional information:
Do not allow to reach sewage system or water bodies. Do not allow to enter
the ground/soil.
13. DISPOSAL CONSIDERATIONS
Product:
Remove according to local authority recommendations, e.g. convey to a suitable incinerator.
Package not cleaned:
Empty containers should be transported/delivered using a registered waste
carrier for local recycling or waste disposal.
14. TRANSPORT INFORMATION
Land transport:
UN-No. 3082
Proper shipping name 3082 Environmentally hazardous substance, liquid n.o.s. epoxy resin
Class 9
Item 11c ADR
HI Number 90
Sea transport:
UN-No. 3082
Proper shipping name Environmentally hazardous substance, liquid n.o.s.(epoxide resin)
Class 9
Packing group 3
EmS MFAG
Marine pollutant P
Air transport:
UN-No. 3082
Proper shipping name Environmentally hazardous substance, liquid n.o.s. (Epoxy resin)
Class 9
Packing group III
15. REGULATORY INFORMATION
Labelling according to EEC Directive
Hazard-determining
components of labelling:
Bisphenol-A-Epichlorhydrinresin
Symbol(s):
Xi Irritant
N Environment
R-phrases: R 36/38 Irritation to eyes
R 43 May cause sensitisation by skin contact
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrases:
S 28 In case of contact with skin, rinse immediately with plenty of water and soap, seek medical
advice
S 37/39 Wear suitable gloves and eye/face protection
S 61 Avoid release to the environment. Refer to special instructions/Safety Data Sheets. Contains
epoxy constituents. See information supplied by the manufacturer.
16. OTHER INFORMATION
These information are based on the present state of our knowledge and do therefore not guarantee certain properties. However, it shall not
constitute a guarantee for any specific product feature and shall not establish a legally valid contractual relationship.