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T p of
Types
f NiNi-Cu
C sulphide
lphid deposits
d p it
Astrobleme- associated in mafic intrusion ((Ni:Cu~ 1))
-- Sudbury: world largest Ni producing camp
Rift- and continental flood basalt and intrusions
((various
a ous Ni:Cu
Cu ratios)
at os)
Norilsk and Jinchuan: 2nd an 3rd world producers
Komatiitic volcanic flows and intrusions (Ni:Cu >
10);
Alexo Mine, Ontario; Thompson Nickel belt,
Manitoba; Kambalda and Agnew, Australia)
Third most important type in the world
Gabbro-Anorthosite intrusions (Ni:Cu ~2-3)
XXXXX
Naldrett, 1997
Grade
vs.
Tonnage
Eckstrand and
Hulbert, 2005
FIG.2.CartoonsofthegeologicsettingsofNisulfidedeposits.a.Meteorimpact,Sudbury.b.
Feederstofloodbasalt,e.g.,Norilsk.c.Feeders along asuture,Voiseys Bay.d.Thick crust,
Grenville.
,
TexturasensulfurosdeNiCuPGEdeorigenmagmtico
Canadian Ni
Ni-Cu
Cu sulfide deposits
Ages
Eckstrand and Hubert, 2007
Voiseys Bay
(1.3-1.4 Ga)
*
Thompson
Belt (1.88 Ga)
Sudbury
(1.85 Ga)
Sudbury
Ni-Cu
sulphide
deposits
in
Canada
Eckstrand, 1996
ASTROBLEME-ASSOCIATED NICKEL-COPPER
SUDBURY Ni-Cu
Ni C DEPOSITS
Sudbury
y
SIC:1.8
S
C 8 5Ga
WG
Sublayer:
contains the Ni-Cu sulphide deposits
a) contact sublayer: (< 200 m thick)
b) Offset sublayer:
Sudbury
y
SIC:1.8
S
C 8 5Ga
WG
Sudbury
Lower and Upper Zones
Sudbury:
y shatter cones
Shatter
cones
Sudbury breccia
Dresser et al
al., 1992
Sudbury:
y Footwall Breccia
Dresser et al., 1992
Onaping Formation
1m
Sudbury
y Ore Deposits
p
Ni/Cu ~> 1
(in or adjacent to the sublayer and comprise
pyrrhotite as dominated sulphide)
1.
1
2.
3.
4.
Ni/Cu < 1
(in footwall rocks and consist of coppersulphides
p
highly
g y enriched in PGE))
1. Deep Copper at Strathcona
Sudbury
y
M
Murray
Mine:
Mi
cross section
i
F l
Falconbridge
b id Mi
Mine
E kt
Eckstrand
d and
dH
Hulbert,
lb t 2007
Compositions
p
of typical
yp
Sudbury
y ores
Eckstrand, 1996
Slide
Slide
Slide
Naldretts model
Komatiite-hosted Nideposits
T p of
Types
f NiNi-Cu
C sulphide
lphid deposits
d p it
Astrobleme- associated in mafic intrusion ((Ni:Cu~ 1))
-- Sudbury: world largest Ni producing camp
Rift- and continental flood basalt and intrusions
((various
a ous Ni:Cu
Cu ratios)
at os)
Norilsk and Jinchuan: 2nd an 3rd world producers
Komatiitic volcanic flows and intrusions (Ni:Cu >
10);
Alexo Mine, Ontario; Thompson Nickel belt,
Manitoba; Kambalda and Agnew, Australia)
Third most important type in the world
Gabbro-Anorthosite intrusions (Ni:Cu ~2-3)
Komatiite
An igneous suite distinguished by
the p
presence of ultramafic lavas,,
commonly exhibing spinifex texture
High Mg content Ni mineralization
KOMATIITE
fl top
flow
t with
ith spinifex
i if textured
t t d olivine
li i blades
bl d
From Helmtaedt- Geol488-2002-notes, with permission
E k t d 1996,
Eckstrand,
1996 p.597
597
Ni-Cu
N
u
sulphide
deposits
in Canada
Eckstrand, 1996
Net-textured Ni ore
spnifex texture
Ni deposits in the
Yilgarn Block
Most of the deposits
Western Australia
are confined to a
central rift (200Km
wide)) which is
characterized by
abundant komatiites
p
cherts
and sulphidic
(deep marine
environment)
Kambalda
camp
Important features:
f
Ultramafic rocks
Sedimentary
rocks
Structures
(
(magma
conduit)
d i)
Perceverance Mine
Generalized Geology (Evans, 1996)
pyrite,
sulphides
magnetite,
In Barnes et al.
(1999)
Leshers Model
Lesher, 1989
Leshers
Model
(cont)
Lesher, 1989
S-isotopes
(0)= [(Rsample/Rstandard)-1]103
R= moles of heavy isotope/ moles of light isotope
RS= moles
l 34S/moles
S/ l 32S
34S= [(RS sample
l /RSDCT)) 1]103
34S and 32S
Standard: Canon Diablo Troilite (CDT)
Voiseys
Voisey s Bay
T p of
Types
f NiNi-Cu
C sulphide
lphid deposits
d p it
Astrobleme- associated in mafic intrusion ((Ni:Cu~ 1))
-- Sudbury: world largest Ni producing camp
Rift- and continental flood basalt and intrusions
((various
a ous Ni:Cu
Cu ratios)
at os)
Norilsk and Jinchuan: 2nd an 3rd world producers
Komatiitic volcanic flows and intrusions (Ni:Cu >
10);
Alexo Mine, Ontario; Thompson Nickel belt,
Manitoba; Kambalda and Agnew, Australia)
Third most important type in the world
Gabbro-Anorthosite intrusions (Ni:Cu ~2-3)
Voiseys Bay
(1.3-1.4 Ga)
*
Thompson
Belt (1.88 Ga)
Sudbury
(1.85 Ga)
VOISEYS BAY
Tectonic setting:
Anorogenic plutonic suite emplaced in the
collisional boundary between Archean Nain and
Paleoproterozoic Churchill Province.
Host rock:
1,334 Ga Voiseys Bay Troctolite complex
Trocolitc gabbroic and gabbronorite intrusions of
the Nesoproterozoic Nain Plutonic Suite (NPS)
(1 35-1 29Ga)
(1.35-1.29Ga)
Regional
Geology
gy
In the boundary
between Churchill
and Nain
Provinces
In
I gabbrobb
anorthosite that
cuts Nain gneiss
Eckstrand
c st a d a
and
d
Hulbert, 2005,
(after Naldrett, 1997)
Voiseys
y Bay
y NW-SE
vertical section
Mineralized Zones
Eckstrand and
Hulbert 2005,
Hulbert,
2005
(after Li and Naldrett, 1999)
Mineralized Zones
Eckstrand and
Hulbert, 2005
(after Li et al., 2001)
Ore Types
Massive sulphide ore
(45 cm wide)
Leopard-textured
sulphide ore
(45 cm wide)
Disseminated
sulphide ore
(45 cm wide)
Geological Evolution
1860Ma
1794-1740 Ma
1350-1290 Ma
Voiseys
y Bay:
y conceptual
p
model
(trocolitic gabbro
gabbro, gabbro norite)
T p of
Types
f NiNi-Cu
C sulphide
lphid deposits
d p it
Astrobleme- associated in mafic intrusion ((Ni:Cu~ 1))
-- Sudbury: world largest Ni producing camp
Rift- and continental flood basalt and intrusions
((various
a ous Ni:Cu
Cu ratios)
at os)
Norilsk and Jinchuan: 2nd an 3rd world producers
Komatiitic volcanic flows and intrusions (Ni:Cu >
10);
Alexo Mine, Ontario; Thompson Nickel belt,
Manitoba; Kambalda and Agnew, Australia)
Third most important type in the world
Gabbro-Anorthosite intrusions (Ni:Cu ~2-3)
Tectonic setting:
Continental rift
Permo-Triassic Siberian Flood Basalt
Province
Ore is hosted in hypabyssal intrusions
(248 Ma)
Norilsk
Noril
sk
and
Talnakh
Important Features:
Fault
F
lt
Flood basalts
Sediments
Eckstrand, 1996
Eckstrand and
Hulbert 2007
Hulbert,
Massive Ore
Sh
Sheet-like
lik bodies,
b di may also
l intrude
i
d the
h underlying
d l i
metassedimentary rock footwall.
Form bodies as large as 1.5 km long , several hundred
kilometres wide, and several tens of meters thick
Succession of sulphides:
pyrhhotite
hh tit (FeS
(F S1-x),
) petlandite
tl dit [(FeNi)
[(F Ni)9S8] andd chalcopyrite
h l
it
(CuFeS2) chalcopyrite--cubanite (CuFe2S3),
mooihoekite (Cu9Fe9S16), and talnakhite [Cu9(Fe,Ni)8S16]
Copper Ore
(a)
( ) disseminated veinlets that form a halo around
the periphery of massive ore and
(b) breccia ores with copper sulfide matrix in the
roofs of some intrusions. PGE contents are higher
in the copper ores.
Engineering Issues
Mining Ni-Cu sulfide
Processing of Ni
Ni-Cu
Cu sulfide
Environmental remediation
Cu/Pdvs.CuforNorilsk.Circles=silicaterockswithintheintrusions,crosses=lavasabovetheintrusions,
triangles = disseminated and matrix ores. The solid lines represent tie lines between thesilicate liquid
composition(representedbythelavas)andsulfidesformedinequilibriumwiththelavasatRfactorsof100,
1,000, and 10,000. The solid dots represent the composition of a rock that contains a mixture of 1, 10, or
100 percent sulfides. Most of the Norilsk sulfides plot in the vicinity of R factors of 1,000 to 10,000. The
, lines represent models of the silicate liquid composition as sulfide liquid is removed in cotectic
dashed
proportions.Manyofthesilicaterocksoverlyingthesulfideoresplotinthisdepletedfield.
MagmaticNiCusulfidedepositsformwhenimmisciblesulfideliquidseparatesfromamafic
or ultramafic magma. The trigger is commonly assimilation of wall rocks, which adds sulfur
and/ordecreasessulfidesolubility.Whenthesegregatedsulfide interactswithlargevolumes
of magma, it scavenges chalcophile elements (Ni, Cu and PGE) to produce hightenor ores.
Such processes should operate in most or all magmatic systems, but ore deposits are found
only in restricted parts of certain magmatic provinces. The restricted distribution might be
explained by the cratonmargin model, according to which deposits form when a mantle
plumeascendsattheslopingcontactofcratoniclithosphere.Thehypothesisthatoremetals
are derived from metasomatically enriched portions of the subcontinental lithospheric
mantle (SCLM) receives little support when the compositions of orebearing magmas and
samples from the SCLM are examined. A better understanding of the controls on ore
formation will come from modelling of flowage of mixtures of silicate and sulfide liquid and
solidphases(crystalsandrockfragments)inthe complex magmatic conduits that constitute
containtheoredeposits.
,
Fig1.Temperaturedistributionsin
plumes rising at the boundary of
an Archean craton, as at the
margin of the Archean craton
where
the
NorilskTalnakh
deposits are localized. The top
four diagrams show that the
plume flows laterally towards to
the thinner lithosphere, then
upwards: as it ascends it partial
melts and magma formation is
thereby focussed near the craton
margin. The lower diagram shows
a plume ascending beneath
thinner lithosphere beneath the
West Siberian Basin where the
plume produces highdegree
melts dispersed over a wide area.
Diagrams from S. Sobolev
(unpublished) using techniques
describedbySobolevetal.(2012)
Barnes, S-J and Maier, W.D (1999). The Fractionation of Ni, Cu and the Noble Metals in Silicate and Sulphide
Liquids. In Keas, R.R., Lesher, M.C., Lightfoot, P.C., Farrow, C.E.G. (1999). Dynamic Processes in
Magmatic Ore Deposits and Their Applications to Mineral Exploration. GAC- Short Course Notes, v. 13, p.
69 106
69-106
Barnes, S-J, Hill, RET , Perring C.S. and Dowling, S.E. Komatiite Flow Fields and Associated Ni-Suphide
Mineralization with Examples form the Yilgarn, Block, Western Australia. In Keas, R.R., Lesher, M.C.,
Lightfoot, P.C., Farrow, C.E.G. (1999). Dynamic Processes in Magmatic Ore Deposits and Their
Applications to Mineral Exploration. GAC- Short Course Notes, v. 13, 159-194
Eckstrand, O. R. (1996). Nickel-copper
Nickel copper sulphide. . In Geology of Canadian Mineral Deposit Types. (ed. OR
Eckstrand, WD Sinclair, RI Thorpe) Geological Survey of Canada. Geology of Canada, 8, p. 584-605
Eckstrand and Hubert (2007). Magmatic Ni-Cu-Pt deposits. In Mineral Deposits of Canada, Geological
Association of Canada, special publication n.5.
Evans, A., M. (1996) Ore geology and Industrial minerals: An introduction. Backwell Sciences Ltd., 3e edition.
Great Britain
Britain, 389 p
p. (ISBN 0-632-02953-6)
0 632 02953 6)
Guilbert, J.M. et Park, C.F, Jr. (1986) The Geology of Ore Deposits. W. H. Freeman and Company, USA, 985 p.
(ISBN 0-7167-1456-6)
Keas, R.R., Lesher, M.C., Lightfoot, P.C., Farrow, C.E.G. (1999). Dynamic Processes in Magmatic Ore Deposits
and Their Applications to Mineral Exploration. GAC- Short Course Notes, v. 13, 477p.
Lesher C.
Lesher,
C M (1989).
(1989) Komatiite
Komatiite-associated
associated Nickel sulfide deposits
deposits. In Reviews in Economic Geology
Geology, vv. 4
4, p
p.4545
101
Naldrett, A.J. (1981). Nickel sulfide deposits: Classification, composition and genesis. Economic Geology,
Seventy-fifth anniversary volume. P. 628-685.
Naldrett, A.J. (1989). Ore Associated with flood basalts. Dans Ore deposition associated with magmas. Reviews
in Economic Geology vv.4,
4 Society of Economic Geologists
Geologists., USA
USA, 250p
250p. (ISBN 0
0-9613074-3-9)
9613074 3 9)
th
Naldrett, A.J. (1997). Magmatic Sufides:17 Ore Deposit Workshop, University of Toronto, Department of
Geology.
References- complementary
See also
S
l th
the references
f
in
i the
th first
fi t partt off the
th Ni-Cu
Ni C sulphide
l hid deposits
d
it file.
fil
Ryan, B., Wardle, R., Gower, C., and Nunn, G. (1985). Nickel-Copper-Sulphide
Mineralization in Labrador: The Voisey Bay Discovery and its Exploration Implication:
Geological Survey of Newfoundland and Labrador, Current Research , report 95-1