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B.Sc.

(H) Chemistry
THREE-YEAR FULL-TIME PROGRAMME
(Six-Semester Course)

COURSE CONTENTS
(Effective from the Academic Year 2010-2011)

UNIVERSITY OF DELHI
DELHI – 110 007

Course Structure
YEAR-1
PART I: Semester – 1
Paper 1

CHHT 101

Inorganic Chemistry- I

Paper 2

CHHT 102

Organic Chemistry –I

Paper 3

ENAT 101

Technical writing and Communication in English

Paper 4

MACT 101

Mathematics-I

PART I: Semester – 2
Paper 5

CHHT 203

Physical Chemistry – I

Paper 6

CHHT 204

Analytical Methods in Chemical Analysis

Paper 7

LSPT 202

Biology-II

Paper 8

PHCT 201

Physics-I

In addition, there shall be one qualifying paper in self-learning mode called Environmental
Studies offered in Semester-2

YEAR-2
PART II: Semester – 3
Paper 9

CHHT 305

Inorganic Chemistry – II

Paper 10

CHHT 306

Organic Chemistry – II

Paper 11

CHHT 307

Physical Chemistry – II

Paper 12

MACT 302

Mathematics-II

PART II: Semester – 4
Paper 13

CHHT 408

Inorganic Chemistry – III

Paper 14

CHHT 409

Organic Chemistry – III

Paper 15

CHHT 410

Physical Chemistry – III

Paper 16

PHCT 402

Physics-II

YEAR-3
PART III: Semester – 5
Paper 17

CHHT 511

Inorganic Chemistry – IV

Paper 18

CHHT 512

Organic Chemistry – IV

Paper 19
a/b
Paper 20

CHHT 513

Physical Chemistry – IV

CHHT 514

Biochemistry and Environmental Chemistry

PART III: Semester – 6
Paper 21

CHHT 615

Inorganic Chemistry – V

Paper 22

CHHT 616

Organic Chemistry – V

Paper 23

CHHT 617

Physical Chemistry – V

Paper 24

CHHT 618

Applications of Computers in Chemistry

Paper 1-CHHT 101: Inorganic Chemistry - I
THEORY

Marks: 100

Unit I: Atomic Structure:
Bohr’s theory, its limitations and atomic spectrum of hydrogen atom. Wave mechanics:
de Broglie equation, Heisenberg’s uncertainty principle and its significance,
Schrödinger’s wave equation, significance of ψ and ψ2. Quantum numbers and their
significance. Normal and orthogonal wave functions. Sign of wave functions. Radial
and angular wave functions. Radial and angular distribution curves. Shapes of s, p, d
and f orbitals. Contour boundary and probability diagrams.
Pauli’s exclusion principle, Hund’s rule of maximum multiplicity, Aufbau’s principle
and its limitations, Variation of orbital energy with atomic number.

Unit II: Periodicity of Elements:
s, p, d, f block elements, the long form of periodic table. Detailed discussion of the
following properties of the elements, with reference to s & p- block.
(a) Effective nuclear charge, shielding or screening effect, Slater rules, variation of
effective nuclear charge in periodic table.
(b) Atomic radii (van der Waals)
(c) Ionic and crystal radii.
(d) Covalent radii (octahedral and tetrahedral )
(e) Ionization enthalpy, Successive ionization enthalpies and factors affecting
ionization energy. Applications of ionization enthalpy.
(f) Electron gain enthalpy, trends of electron gain enthalpy.
(g) Electronegativity, Pauling’s/ Mulliken’s/ Allred Rachow’s/ and Mulliken-Jaffe’s
electronegativity scales. Variation of electronegativity with bond order, partial
charge, hybridization, group electronegativity. Sanderson’s electron density ratio.
Recommended Texts:
1. Lee, J.D. Concise Inorganic Chemistry, ELBS, 1991.
2. Douglas, B.E. and Mc Daniel, D.H., Concepts & Models of Inorganic Chemistry,
Oxford, 1970
3. Atkins, P.W. & Paula, J. Physical Chemistry, Oxford Press, 2006.
4. Day, M.C. and Selbin, J. Theoretical Inorganic Chemistry, ACS Publications 1962.

Paper 2-CHHT 102: Organic Chemistry - I
THEORY

Marks: 100

Unit-I: Basics of Organic Chemistry
Organic Compounds: Classification, and Nomenclature, Hybridization, Shapes of molecules,
Influence of hybridization on bond properties.
Electronic Displacements: Inductive, electromeric, resonance and mesomeric effects,
hyperconjugation and their applications; Dipole moment; Organic acids and bases; their relative
strength.
Homolytic and Heterolytic fission with suitable examples. Curly arrow rules, formal charges;
Electrophiles and Nucleophiles; Nucleophlicity and basicity; Types, shape and their relative
stability of Carbocations, Carbanions, Free radicals and Carbenes
Introduction to types of organic reactions and their mechanism: Addition, Elimination and
Substitution reactions.
Unit II: Stereochemistry
Fischer Projection, Newmann and Sawhorse Projection formulae and their interconversions;
Geometrical isomerism: cis–trans and, syn-anti isomerism E/Z notations with C.I.P rules.
Optical Isomerism: Optical Activity, Specific Rotation, Chirality/Asymmetry, Enantiomers,
Molecules with two or more chiral-centres, Distereoisomers, meso structures, Racemic mixture
and resolution. Relative and absolute configuration: D/L and R/S designations.
Unit III: Chemistry of Aliphatic Hydrocarbons
A.

Carbon-Carbon sigma bonds

Chemistry of alkanes: Formation of alkanes, Wurtz Reaction, Wurtz- Fittig Reactions, Free
radical substitutions: Halogenation - relative reactivity and selectivity.
B.

Carbon-Carbon pi bonds

Formation of alkenes and alkynes by elimination reactions, Mechanism of E1, E2, E1cb
reactions. Saytzeff and Hofmann eliminations.
Reactions of alkenes: Electrophilic additions their mechanisms (Markownikoff/ Anti
Markownikoff addition), mechanism of oxymercuration-demercuration, hydroboration-

R. aromatic character of arenes.addition reactions in conjugated dienes and. nitration. Recommended Texts: 1. Reactions of alkynes: Acidity. L. 2. R. Finar. Dorling Kindersley (India) Pvt. 1. Baeyer strain theory. Directing effects of the groups. & Wilen. ozonolysis. H. toluene. N. C. Stereochemistry of Organic Compounds. reduction (catalytic and chemical). Relative stability with energy diagrams. Dorling Kindersley (India) Pvt. Electrophilic and Nucleophilic additions. Unit IV: Aromatic Hydrocarbons Aromaticity: Hückel’s rule. Hydration to form carbonyl compounds. 1994. Morrison. propene. ethyl benzene. Cycloalkanes and Conformational Analysis Types of cycloalkanes and their relative stability. Finar. L. & Boyd. 4. (Pearson Education). e.oxidation. Diels-Alder reaction. cyclic carbocations/carbanions and heterocyclic compounds with suitable examples. 4. Ltd. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural Products). Ltd. Allylic and benzylic bromination and mechanism. Conformation analysis of alkanes: Relative stability: Energy diagrams of cyclohexane: Chair. 1-butene. Wiley: London. . 3. L. I. (Pearson Education). Electrophilic aromatic substitution: halogenation. (Pearson Education). S.and 1. sulphonation and Friedel-Craft’s alkylation/acylation with their mechanism. Alkylation of terminal alkynes. Ltd. E. Eliel. Organic Chemistry. syn and anti hydroxylation (oxidation). I. N. Dorling Kindersley (India) Pvt. Organic Chemistry (Volume 1).g. 2. Boat and Twist boat forms.

introductory. Greenbaum. . 8th Edition (2004). narrative. SUGGESTED READINGS 1. A course in written English. letters. distinct features of speech. developing the thesis. minutes. L. distinct features of writing. Leech and J. G. Quirk. Riordan & Steven A. notices. common errors to be avoided. 2. Panley: “Technical Report Writing Today” . formal writings/reports. 6. agenda. Frank.Paper 3-ENAT 101: TECHNICAL WRITING AND COMMUNICATION IN ENGLISH Marks: 100 Unit 1 Communication: Language and communication. Riordan. Prentice Hall Reagents. Hamp-Lyons and B. Longman. Scot Ober. Daniel G. R. memorandum. Press. 4. Cambridge Univ. handbooks. Writing as thinking: A guided process approach. Steven E. Heasely: Study Writing. Biztantra. developmental. differences between speech and writing. 3. linguistic unity. Daniel G. Additional Reference Books 5. expository and argumentative writing. manuals. Svartik: A comprehensive grammar of the English language. Unit 2 Writing Skills. thesis statement. Englewood Cliffs. 5th Edition (2004). For academic and professional purposes. formal and informal writings.Biztaantra. S. Contemporary Business Communication. descriptive. London. coherence and cohesion. Biztantra: Technical Report Writing Today. transitional and concluding paragraphs. Pauley. M. Unit 3 Technical Writing: Scientific and technical subjects. Selection of topic.

relative error. integrated rate law for second order reaction). identities. Unit II: Integral calculus: The process of integration. combining quantities. numerical differentiation (e. Data reduction and the propagation of errors. Uncertainty in experimental techniques: Displaying uncertainties. Trigonometric functions. manipulation of van der Waals equation in different forms). units of a measurement. odd and even functions.g. differentials. interconversion of units. Algebric operations on real scalar variables (e.g. inflexion points. standard deviation.I THEORY Marks: 100 Unit I: Recapitulation: Fundamentals. Uncertainty in measurement: types of uncertainties. maximumminimum problems. measurements in chemistry.g.Paper 4-MACT 101: Mathematics . polynomial expressions. equation of a straight line. methods of integration (e.g. Mean. the exponential function.g. Numerical curve fitting: the method of least squares (regression). Roots of quadratic equations analytically and iteratively (e. higher order derivatives. decimal places. e. Statistical treatment. Taylor series. change in pressure for small change in volume of a van der Waals gas. plotting graphs. significant figures. potentiometric titrations). convergence (e. colligative properties). combining limits. e. Mathematical series: Power series. pH of a weak acid not ignoring the ionization of water. equilibrium constant expressions). Maclaurin. pressure virial equation of state. logarithms. discontinuities. constants and variables. pH of a weak acid). Mathematical functions. volume of a van der Waals gas. Graphical and numerical data reduction. Pythagoras theorem in three dimensions. binary –bisection. numerical integration (Trapezoidal and Simpson’s rule. stationary points. entropy/enthalpy change from heat capacity data).g. standard integrals. limiting values of functions: L’Hôpital’s rule.. . indefinite integrals. Differential calculus: The tangent line and the derivative of a function. Numerical methods of finding roots (Newton-Raphson. combining uncertainties.g.

I PRACTICAL Marks: 50 (A) Titrimetric Analysis (i) Calibration and use of apparatus (i) Preparation of solutions of different Molarity/Normality of titrants (B) Acid. Mathematics for Physical Chemistry University Science Books (2008). Steiner. 2 Ed.probability distributions (gas kinetic theory) and mean values. A. Calculus of the trigonometric functions. P. CRC Press (2007). exact and inexact differentials (thermodynamics). Chemical Calculations. 2. Reference text: 1. D. Elsevier (2005). Euler’s theorem. (ii) Estimation of free alkali present in different soaps/detergents (C) Oxidation. McQuarrie. . ELBS. anthranilic acid) and external indicator. line integrals.Reduction Titrimetry (i) Estimation of Fe(II) and oxalic acid using standardized KMnO4 solution. Paper 1-CHHP 101: Inorganic Chemistry . Calculus with several independent variables: Functions of several independent variables. (ii) Estimation of carbonate and bicarbonate present together in a mixture. Mortimer. (iii) Estimation of Fe (II) with K2Cr2O7 using internal (diphenylamine. Yates.g. A Textbook of Quantitative Inorganic Analysis. (ii) Estimation of oxalic acid and sodium oxalate in a given mixture.Base Titrations (i) Estimation of carbonate and hydroxide present together in mixture. total differentials. E. change in pressure for small changes in volume and temperature). chain rules for partial differentiation. nd 4. Recommended Texts: 1. Vogel. A. R. change of variables. The Chemical Maths Book Oxford University Press (1996). 3. relations between partial derivatives (e. 3rd Ed.I. Mathematics for Physical Chemistry.

Water b. Alcohol c. (boiling point lower than and more than 100° C by distillation and capillary method) 6. collision frequency.and p-aminophenol by thin layer chromatography (TLC SEMESTER II Paper 5-CHHT 203: Physical Chemistry. Determination of boiling point of liquid compounds. including their temperature and pressure dependence. Chromatography a. Separation of a mixture of two sugars by ascending paper chromatography c. mean free path and viscosity of gases. relation between mean free path and coefficient of viscosity.and p-nitrophenol or o. Alcohol-Water 3. Effect of impurities on the melting point – mixed melting point of two unknown organic compounds 5. Determination of the melting points of above compounds and unknown organic compounds (Kjeldahl method and electrically heated melting point apparatus) 4. .I PRACTICAL Marks: 50 1. variation of viscosity with temperature and pressure.I THEORY Marks: 100 Unit I: Gaseous state: Kinetic molecular model of a gas: postulates and derivation of the kinetic gas equation. Checking the calibration of the thermometer 2. calculation of σ from η.Paper 2-CHHP 102: Organic Chemistry . Separation of a mixture of o. Purification of organic compounds by crystallization using the following solvents: a. Separation of a mixture of two amino acids by ascending and horizontal paper chromatography b. collision diameter.

Unit II: Liquid state: Qualitative treatment of the structure of the liquid state. Causes of deviation from ideal behaviour. and its variation with pressure for different gases. relation between critical constants and van der Waals constants. mention of other equations of state (Berthelot. CsCl and KCl. factors affecting degree of ionization. dissociation constants of mono-. Glasses and liquid crystals. continuity of states. Defects in crystals. symmetry elements and symmetry operations. van der Waals equation of state.Maxwell distribution and its use in evaluating molecular velocities (average. Analysis of powder diffraction patterns of NaCl. root mean square and most probable) and average kinetic energy. Ionization of weak acids and bases. common ion effect. virial equation of state. X-ray diffraction. Bragg’s law. Radial distribution function. pH scale. compressibility factor. surface tension and coefficient of viscosity. . degrees of freedom and molecular basis of heat capacities. elementary ideas of symmetry. physical properties of liquids. law of equipartition of energy. Qualitative discussion of structure of water. law of constancy of interfacial angles. qualitative idea of point and space groups. Z.and triprotic acids (exact treatment). Unit IV: Ionic equilibria: Strong. and their determination. Effect of addition of various solutes on surface tension and viscosity. Unit III: Solid state: Nature of the solid state. Explanation of cleansing action of detergents. Miller indices. critical state. Dietrici). ionization constant and ionic product of water. di. a simple account of rotating crystal method and powder pattern method. van der Waals equation expressed in virial form and calculation of Boyle temperature. Isotherms of real gases and their comparison with van der Waals isotherms. vapour pressure. Temperature variation of viscosity of liquids and comparison with that of gases. degree of ionization. Behaviour of real gases: Deviations from ideal gas behaviour. moderate and weak electrolytes. seven crystal systems and fourteen Bravais lattices. law of rational indices. its derivation and application in explaining real gas behaviour. law of corresponding states.

Multistage equilibria in polyelectrolyte systems. W. buffer action and applications of buffers in analytical chemistry and biochemical processes in the human body. J. and T test. interaction of radiation with matter. 3. Buffer solutions. normal law of distribution if indeterminate errors. India (2007). R. W. methods of their expression. Q. Solubility and solubility product of sparingly soluble salts – applications of solubility product principle. Mortimer. buffer capacity. buffer range. Atkins. Elsevier: NOIDA. de Atkin’s Physical Chemistry 8th Ed. and confidence intervals. errors. P. rejection of data. F. Ball. . Paper 6-CHHT 204: Analytical Methods in Chemical Analysis THEORY Marks: 100 Unit I : Qualitative and Quantitative aspects of analysis: Sampling. G. 4.. 2. Physical Chemistry 4th Ed. Physical Chemistry 3rd Ed.Salt hydrolysis-calculation of hydrolysis constant. statistical test of data. Physical Chemistry Thomson Press. UP (2009). hydrolysis and hydrolysis constants. degree of hydrolysis and pH for different salts. Qualitative treatment of acid – base titration curves (calculation of pH at various stages). G. W. Narosa (2004). D. Oxford University Press (2006). & Paula. selection of indicators and their limitations. Castellan. Recommended Texts: 1. validity of Beer-Lambert’s law. evaluation of analytical data. derivation of Henderson equation and its applications. Unit II: Optical methods of analysis: Origin of spectra. accuracy and precision. Theory of acid – base indicators. fundamental laws of spectroscopy and selection rules.

monochromator. sources of chemical interferences and their method of removal. Techniques for the quantitative estimation of trace level of metal ions from water samples. Techniques used for the determination of equivalence point. Unit IV: Electro analytical methods: Classification of electroanalytical methods. Unit III: Thermal method of analysis: Theory of thermogravimetry (TG). basic principle of instrumentation. Mechanism of extraction: extraction by solvation and chelation. Techniques of atomization and sample introduction. Techniques for quantitative estimation of Ca and Mg from their mixture. Effect and importance of isotope substitution. monochromator & detector) for single and double beam instrument. geometrical isomers. continuous and counter current extractions. basic principle of pH metric. keto-enol tautomers.UV-Visible Spectrometry: Basic principles of instrumentation (choice of source. Technique of extraction: batch. Determination of composition of metal complexes using Job’s method of continuous variation and mole ratio method. Unit V: Separation Techniques: Solvent extraction: Classification and principle and efficiency of the technique. Infrared Spectrometry: Basic principles of instrumentation (choice of source. potentiometric and conductometric titrations. detector. Choice of flame and Burner designs. monochromator and detector) for single and double beam instrument. Method of background correction. Techniques used for the determination of pKa values. . Flame Atomic Absorption and Emission Spectrometry: Basic principles of instrumentation (choice of source. sampling techniques. Basic principle of quantitative analysis: estimation of metal ions from aqueous solution. Structural illustration through interpretation of data.

New York. USA. S. GPC. Basic Concepts of Analytical Chemistry New Age. Christian. Khopkar. Holler F.A. Freeman. Ltd. Hobert H. Development of chromatograms: frontal. 8. 2009. Willard. W. New York. Ditts. The English Language Book Society of Longman 2.M. Role of computers in instrumental methods of analysis. Belmont. calculation of Enantiomeric excess (ee)/ diastereomeric excess (de) ratios and determination of Enantiomeric composition using NMR. 4. 7. Laboratory Hand Book of Chromatographic & Allied Methods. et. 1988. Daniel C: Exploring Chemical Analysis. Arthur I: A Test book of Quantitative Inorganic Analysis (Rev. R. Gary D. 3. 7th Ed. International Publisher. and Nieman. Chromatography: Classification and principle and efficiency of the technique. by GH Jeffery and others) 5th Ed.A.H. Analytical Chemistry – Methods of separation.V. London. D. Qualitative and quantitative aspects of chromatographic methods of analysis: IC.J.Qualitative and quantitative aspects of solvent extraction: extraction of metal ions from aqueous solution. Elles Harwood Ltd. Mechanism of separation: adsorption. Chiral solvents and chiral shift reagents Chiral chromatographic techniques using chiral columns (GC and HPLC). TLC and HPLC. California. 6th Ed. 6. GLC. Recommended texts: 1. Stereo isomeric separation and analysis: Measurement of optical rotation. partition & ion exchange. . Principles of Instrumental Analysis. al: Instrumental Methods of Analysis. Mikes. SKoog.John Willy. extraction of organic species from the aqueous and non aqueous media. T. 5. & Chalmes. Analytical Chemistry. elution and displacement methods. 2nd Ed. Wardsworth Publishing Company. Singapore. 2004. Thomson Asia Pvt. O. 2001.A. Harris. R. Vogel.

functions in animals and plants and biogenesis • Nucleus: Nuclear Envelope. molecular organization. semiautonomous nature. Cell as a unit of Life (Ch 6 Campbell) (10 Periods) The Cell Theory. Cell secretion. Semiautonomous organelle. Eukaryotic Cell components Unit 3. Techniques in Biology (Ch 1 Sheeler) (12 Periods) Principles of microscopy. nucleolus and ribosome structure (brief). • Peroxisomes and Glyoxisomes: Structures. X-ray diffraction analysis Unit 2. Proteins synthesized within mitochondria. chloroplast DNA • ER. Sample Preparation for electron microscopy. Prokaryotic and eukaryotic cells. Phase contrast microscopy. Cell Membrane and Cell Wall (Ch 7 Campbell / Ch 15 Sheeler / Ch 3 Raven) . Cell Organelles (Ch 15. DNA packaging in eukaryotes. Confocal microscopy. 17. Electron microscopy (EM). Signal peptide hypothesis. Fluorescence microscopy. marker enzymes. marker enzymes. composition. N-linked glycosylation. Golgi body & Lysosomes Structures and roles.Paper 7-LSPT 202-BIOLOGY-II THEORY Marks: 100 Cell and Cellular Processes Unit 1. Symbiont hypothesis. Lysosome formation. Sample Preparation for light microscopy. composition. Cell size and shape. Unit 4.19.20 Sheeler) (22 Periods) • Mitochondria: Structure.18.structure of nuclear pore complex. chromatin. mitochondrial biogenesis. composition.Scanning EM and Scanning Transmission EM (STEM). euchromatin and heterochromatin. mitochondrial DNA • Chloroplast Structure. Role of golgi in Olinked glycosylation. Light Microscope. 16.

Raven. idea of line. P and Bianchi. Membrane proteins and their functions. centre of mass. 13 Campbell) (8 Periods) Role of Cell division. (2008) Biology 8th edition. Gauss and Stokes’ theorem. conservation of linear momentum. surface and volume integrals. B. triple and quadruple products. Unit II:Vector calculus: Scalar and vector fields. N. conservative forces. polar and axial vectors. divergence. Faces of the membranes. Molecular controls. . Sheeler. The fluidity of membranes. Selective permeability of the membranes. J. Cell wall Unit 5. Models of membrane structure.(8 Periods) The functions of membranes. Mitosis and Meiosis (Ch 12. John Wiley & sons NY Paper 8-PHCT 201: Physics-I THEORY Marks: 100 Unit I :Mathematical Physics: Scalar and vector products. Overview of Cell cycle. particle collision. Carbohydrates in the membrane. New Delhi 3. Cell Cycle: Interphase. San Francisco. D. (2006) Cell and Molecular Biology. Pearson Benjamin Cummings. P. curl and ∆ operations and their meaning. gradient.H et al (2006) Biology 7th edition Tata McGrawHill Publications.A. Campbell. work energy theorem.E. 3rd edition. Unit III: Classical Mechanics: Particle dynamics: Newton’s laws of motion. and Reece. Meiosis SUGGESTED BOOKS 1. 2. differentiation of a vector.

J. resolving and dispersive power of a plane diffraction grating.: Singapore (1974) 2. John Wiley & Sons (2004) 4. & Krane. travelling and standing waves. b) Study the variation of surface tension of detergent solutions with concentration (II) Viscosity measurement using Ostwald’s viscometer (use of organic solvents . division of amplitudes. kinetic energy of rotation. Q factor. Concepts of Modern Physics McGraw-Hill Education (2002). Polarization: Polarization by reflection and refraction. Production and analysis of circularly and elliptically polarized light. K. Lissajous figures. forces and pseudo forces. double refraction.I PRACTICAL Marks: 50 (I) Surface tension measurements (use of organic solvents excluded). 3. Oscillations: Linearity and superposition principle. D. rigid body rotation dynamics. Paper 5-CHHP 203: Physical Chemistry . a) Determine the surface tension by (i) drop number (ii) drop weight method. quarter and half-wave plates. Serway. simple pendulum. comparison of linear and angular momentum. diffraction at a double split. superposition of waves. forced vibrations and resonance.Rotational kinematics and dynamics: Rotational motion. & Jewett. interference in thin films and wedged shaped films. Physics Vol. Fresnel diffraction: Diffraction at a single slit and a circular aperture. free and damped vibrations. A. resolving power of a telescope and a microscope. Halliday. combination of two simple harmonic motions. W. I and II 5th Ed. R. R. moment of inertia. S. R. conservation of angular momentum. Physics for Scientists and Engineers 6th Ed.. motion of a top. torque and angular momentum. nicol prism. Brewster’s law. wave equation. free oscillation with one and two degrees of freedom. McGraw-Hill Book Co. Unit IV :Wave optics: Interference. Resnick. Recommended Texts: 1. Spiegel. M. Young’s double split. Vector Analysis Schaum’s Outline Series. plane transmission grating. A. Fresnel’s biprism. Beiser. phase and group velocity.

excluded). d) pH metric titrations of (i) strong acid and strong base (ii) weak acid and strong base Any other experiment carried out in the class. Report the Rf values. c) Preparation of buffer solutions (i) Sodium acetate-acetic acid (ii) Ammonium chloride-ammonium hydroxide Measurement of the pH of buffer solutions and comparison of the values with theoretical values. Chromatography: (a) Separation of mixtures (i) Paper chromatographic separation of Fe3+. Al3+. (III) pH measurements b) Measurement of pH of different solutions using pH-meter. (b) Separate a mixture of Sudan yellow and Sudan Red by TLC technique and identify them on the basis of their Rf values. (a) Study the effect of the addition of solutes such as (i) polymer (ii) ethanol (iii) sodium chloride on the viscosity of water at room temperature. (c) Chromatographic separation of the active ingredients of plants. Solvent Extractions: (i) To separate a mixture of Ni2+ & Fe3+ by complexing with DMG and extracting . flowers and juices by TLC 2. (b) Study the effect of variation of viscosity of an aqueous solution with the concentration of solute. and Cr3+ (ii) Separate and identify the monosaccharides present in the given mixture (glucose & fructose) by paper chromatography. Paper 6-CHHP 204: Analytical Methods in Chemical Analysis PRACTICAL Marks: 50 Separation Techniques 1.

shampoos and soaps. Determination of Biological oxygen demand (BOD). 7. and determine its concentration with spectrophotometry. (iii)Separation of amino acids from organic acids by ion exchange chromatography. Determination of pKa values of indicator using spectrophotometry. Structural characterization of compounds by Infra-Red spectroscopy. separation from a mixture of irons and gallium. 5. Determination of chemical oxygen demand (COD). (ii) Solvent extraction of zisconium with amberliti LA-1. Determine the pH of given aerated drinks fruit juices. Determination of dissolved oxygen in water. Li in cola drinks and fruit juices using fame photometric techniques. Determination of Na. Ion exchange: (i) Determination of exchange capacity of cation exchange resins and anion exchange resins. (ii) Total soluble salt (iii) Estimation of calcium. (ii) Separation of metal ions from their binary mixture. Analysis of soil: (i) Determination of pH of soil. 10. phosphate. 9. 11. 3. magnesium. nitrate 6. . 4. 8.the Ni2+ DMG complex in chloroform. Ca.

Group A experiments A-1. A-4. LCR study of resonance Q-factor. 12. Study of thermal couple calibration and inversion temperature.Q factor. Study the structure of nuclear pore complex by photograph (from Gerald Karp) Paper 8. 8. A-2. A-5. 11. Demonstration of dialysis of starch and simple sugar. A-6. To study prokaryotic cells (bacteria). Study of the photomicrographs of cell organelles 3. and (ii) dynamic methods. To study the structure of animal cells by temporary mounts-squamous epithelial cell and nerve cell.Bar pendulum. To prepare temporary stained preparation of mitochondria from striated muscle cells /cheek epithelial cells using vital stain Janus green. Determination of spring constant of a spring by (i) static. Study the effect of temperature. 7. A-3. 2. organic solvent on semi permeable membrane.PHCP 201-PHYSICS-I PRACTICALS Marks: 50 Each student is expected to do at least 3 experiments each from Group A and Group B.Paper 7. 4. Study of damped harmonic oscillator. To study the structure of plant cell through temporary mounts. 10. Determination of temperature coefficient of resistance using platinum resistance thermometer. 9. Kator’s pendulum.LSPP 202-BIOLOGY-II PRACTICALS Marks: 50 1. viruses. Preparation of temporary mounts of striated muscle fiber 6. To prepare temporary stained squash from root tips of Allium cepa and to study the various stages of mitosis. Study of plasmolysis and deplasmolysis on Rhoeo leaf. . 5. Measure the cell size (either length or breadth/diameter) by micrometry. eukaryotic cells with the help of light and electron micrographs.

(idea of s-p mixing and orbital interaction to be given). B-3. NO. Determination of wavelength of light by Fresnel’s biprism. Solvation energy. Born-Landé equation with derivation and importance of Kapustinskii expression for lattice energy. HCl. Molecular orbital theory. equivalent and non-equivalent hybrid orbitals. CO. Formal charge. B-2. . size effects. Madelung constant. Determination of dispersive power of a glass prism using Cauchy’s constant. Determination of wavelength of sodium light by Newton’s arrangement. shapes of simple molecules and ions containing lone pairs and bond pairs of electrons. Resonance and resonance energy. Determination of refractive index of tint glass using a spectrometer. types of ions. O2. (ii) Covalent bond: Lewis structure. Molecular orbital diagrams of diatomic and simple polyatomic molecules N2. and their ions. Also determine the resolving power of a prism.Group B experiments B-1. Determination of wavelength of sodium light using a plane transmission grating and resolving power of a diffraction grating. radius ratio rule and its limitations. B2. B-4. Determination of specific rotation of cane sugar solution using a polarimeter. Bent’s rule. BeF2. multiple bonding (σ and π bond approach). Packing of ions in crystals. B-6. B-5. and bond lengths. Energetics of hybridization. Valence shell electron pair repulsion theory (VSEPR). Valence Bond theory (Heitler-London approach). SEMESTER – III Paper 9-CHHT 305: Inorganic Chemistry -II THEORY Marks: 100 Unit I: Chemical Bonding: (i) lonic bond: General characteristics. CO2. Born-Haber cycle and its application. F2. C2.

Inorganic Chemistry. Paper 10-CHHT 306: Organic Chemistry -II THEORY Marks: 100 Unit I: Chemistry of Halogenated hydrocarbons: Alkyl halides: Methods of preparation. Oxford Press 1994. Oxford 1970 3. Second Edition. (iii) (iv) (v) Metallic Bond: Qualitative idea of valence bond and band theories. nucleophilic substitution reactions – SN1. solubility energetics of dissolution process. Repulsive forces. Weak Chemical forces: van der Waals forces. Recommended Texts: 1.W. Concise Inorganic Chemistry. 2005. solvated proton. Inorganic Chemistry. nucleophilic substitution vs elimination . Douglas.Covalent character in ionic compounds. ion-dipole forces. induced dipole interactions. melting and boiling points. Hydrogen bonding (theories of hydrogen bonding. Porterfield. Classification of Lewis acids.Lowry concept of acid-base reaction. Inorganic Chemistry. polarizing power and polarizability. and Mc Daniel. 5. Concepts & Models of Inorganic Chemistry. Third Edition. ELBS (1991) 4. Huheey.E. J. Hard and Soft Acids and Bases (HSAB) Application of HSAB principle. Shriver & Atkins. Acids and Bases: Brönsted. defects in solids.D... D. relative strength of acids. Ionic character in covalent compounds: Bond moment and dipole moment. dipole-dipole interactions. Instantaneous dipole-induced dipole interactions. types of acid-base reactions. levelling solvents. J. valence bond treatment) Effects of chemical force. Lewis acid-base concept.H. H. Percentage ionic character from dipole moment and electronegativity difference. Academic Press. Lee. Prentice Hall 1993 2. Fajan’s rules and consequences of polarization. B.E. SN2 and SNi mechanisms with stereochemical aspects and effect of solvent etc. Semiconductors and insulators.

MPV. Nucleophilic additions. Cannizzaro and Wittig reaction. allyl/benzyl. SNAr. oxidations and reductions (Clemmensen. vinyl and aryl halides towards nucleophilic substitution reactions. Knoevenagel condensation. Nucleophilic addition-elimination reactions with ammonia derivatives with mechanism. Addition reactions of unsaturated carbonyl compounds: Michael addition. 20. Perkin. α-substitution reactions. LiAlH4. Preparation and synthetic applications of diethyl malonate and ethyl acetoacetate: Unit IV:Carboxylic Acids and their Derivatives: Preparation. Phenols: Preparation and properties.Aryl halides: Preparation. PDC and PGC). Wolff-Kishner. Preparation and properties of glycols: Oxidation by periodic acid and lead tetraacetate. Reactions of epoxides with alcohols. Unit II: Alchols. Mechanisms of Aldol and Benzoin condensation. Reimer – Tiemann and Kolbe’s – Schmidt Reactions. Active methylene compounds: Keto-enol tautomerism. Pinacol. Benzyne mechanism Relative reactivity of Alkyl. Phenols. Acidity and factors effecting it. Beckmann and Benzil-Benzilic acid rearrangements. including preparation from diazonium salts. ammonia derivatives and LiAlH4 Unit III: Carbonyl Compounds: Structure. Claisan-Schmidt. Fries and Claisen rearrangements with mechanism. Bouvaelt-Blanc Reduction. physical properties and reactions of monocarboxylic acids: . 30 alcohols. reactivity and preparation. Organometallic compounds of Mg and Li – Use in synthesis of organic compounds. haloform reaction and Baeyer Villiger oxidation.Pinacolone rearrangement. NaBH4. nucleophilic aromatic substitution. Ethers and epoxide: Alcohols: preparation. Ring substitution reactions. properties and relative reactivity of 10. Ethers and Epoxides: Preparation and reactions with acids.

q. calculations of q.Typical reactions of dicarboxylic acids. Preparation and reactions of acid chlorides. w. (Pearson Education). Morrison. zeroth law of thermodynamics. U and H for reversible. calculation of bond energy. malic. irreversible and free expansion of gases (ideal and van der Waals) under isothermal and adiabatic conditions. T. closed and open systems. I. lactic. Finar. relation between heat capacities. & Boyd. hydroxy acids and unsaturated acids: succinic/phthalic. Claisen condensation. enthalpy of formation of molecules and ions and enthalpy of combustion and its applications. Comparative study of nucleophilic sustitution at acyl group . Paper 11-CHHT 307: Physical Chemistry -II THEORY Marks: 100 Unit I : Chemical thermodynamics: Intensive and extensive variables. esters and amides. Thermochemistry: Heats of reactions: standard states. Hofmann-bromamide degradation and Curtius rearrangement Unit V: Sulphur containing compounds: Preparation and reactions of thiols. citric. Dieckmann and Reformatsky reactions. state and path functions. work. internal energy U and statement of first law. N. R. First law: Concept of heat. thioethers and sulphonic acids. Recommended Texts: 1. (Pearson Education). Dorling Kindersley (India) Pvt. Ltd. bond . Organic Chemistry. tartaric. anhydrides. Dorling Kindersley (India) Pvt. Organic Chemistry (Volume 1).Mechanism of acidic and alkaline hydrolysis of esters. maleic and fumaric acids. w. 2. R. Ltd. H. enthalpy. L. isolated.

Thermodynamic derivation of relation between Gibbs free energy of reaction and reaction quotient. pressure and concentration. Equilibrium constants and their quantitative dependence on temperature. effect of temperature (Kirchoff’s equations) and pressure on enthalpy of reactions.dissociation energy and resonance energy from thermochemical data. GibbsDuhem equation. Kc and Kx. Second Law: Concept of entropy. P. G. dependence of thermodynamic parameters on composition. statement of the second law of thermodynamics. explosion temperature. Gibbs-Helmholtz equation. Adiabatic flame temperature. Le Chatelier principle (quantitative treatment). concept of fugacity. equilibrium between ideal gases and a pure condensed phase. chemical equilibria in ideal gases. degree of advancement of reaction. Calculation of entropy change for reversible and irreversible processes. concept of residual entropy. thermodynamic equation of state. chemical potential of ideal mixtures. Free energy of mixing and spontaneity. thermodynamic derivation of relations between the various equilibrium constants Kp. Free energy change and spontaneity. Coupling of exoergic and endoergic reactions. Maxwell relations. Unit IV: Solutions and colligative properties: Dilute solutions. calculation of absolute entropy of molecules. Excess thermodynamic functions. A with T. V. Unit II : Systems of variable composition: Partial molar quantities. Third Law: Statement of third law. Unit III: Chemical equilibrium: Criteria of thermodynamic equilibrium. Raoult’s and Henry’s Laws and their applications. Relation between Joule-Thomson coefficient and other thermodynamic parameters. molecular and statistical interpretation of entropy. thermodynamic scale of temperature. . change in thermodynamic functions in mixing of ideal gases. lowering of vapour pressure. inversion temperature. variation of S. Free Energy Functions: Gibbs and Helmholtz energy.

numerical solutions of differential equations. Molecular Thermodynamics Viva Books Pvt. Hermitian operators. Recommended Texts: 1. eigenfunctions and eigenvalues. & Paula. The linear harmonic oscillator: Linear differential equations with constant coefficients. Oxford University Press (2006). Atkins. W. Partial differential equations: separation of variables. Physical Chemistry 4th Ed. (ii) elevation of boiling point. Multiple integrals. Paper 12-MACT 302: Mathematics .Thermodynamic derivation using chemical potential to derive relations between the four colligative properties [(i) relative lowering of vapour pressure. Ltd. linear operators. commutators of operators. Schrödinger’s equation. Euler’s formula and polar form of complex numbers. modulus of a complex number. imaginary and complex numbers. de Atkin’s Physical Chemistry 8th Ed.. & Reid. Castellan. (iii) Depression of freezing point. A. complex conjugates. & Simon. Vector derivative operators. 3. dissociated and associated solutes in solution. J. J. McQuarrie. Stationary points. Newton’ laws of motion. Inc: New Delhi (2007). Applications in calculating molar masses of normal. Multiple integrals involving other coordinate systems (spherical polar). 4. Maximum and minimum values of functions of several variables. . complex plane. T. Changing variables.: New Delhi (2004). 2. series solution. & Kinetics Pearson Education. P. Statistical Thermodynamics. (iv) osmotic pressure] and amount of solute. D. G. D. Operators: operator algebra. W.II THEORY Marks: 100 Differential equations: differential equations with separable variables. P. Narosa (2004). The wave equation. Engel. Thermodynamics.

D. Elsevier (2005). Cu2Cl2 (ii) Preparation of Manganese (III) phosphate. Cramer’s rule. MnPO4. spectrophotometry). . diagonalization of a matrix. Mortimer.12H2O (Potash alum) or Chrome alum. Paper 9-CHHP 305: Inorganic Chemistry -II PRACTICAL Marks: 50 (a) Iodo / Iodimetric Titrations (i) Estimation of Cu (II) and K2Cr2 O7 Using sodium thiosulphate solution (Iodimetrically). Chemical calculations. 2nd Ed. A. Matrix algebra. Simultaneous equations: method of substitution and elimination. Recommended Texts: 1. matrix eigenvalues and eigenvectors.Vectors and coordinate systems: Unit vectors (application in solid state). (ii) (iii) Estimation of (i) arsenite and (ii) antimony in tartar-emetic iodimetrically Estimation of available chlorine in bleaching powder iodometrically. Homogeneous linear equations. addition and subtraction of vectors. CRC Press (2007). matrix inversion. Yates. multiplication of vectors. R. 3. spherical polar and their interconversion). Vectors and coordinate systems in three dimensions (Cartesian.g. orthogonal and unitary matrices.H2O (iii) Preparation of Aluminium Potassium sulphate KAl(SO4)2. Steiner. Determinants. McQuarrie. The Chemical Maths Book Oxford University Press (1996). (b) Inorganic preparations (i) Cuprous Chloride. 3rd Ed. 2. 4. P. E. consistency and independence. Simultaneous equations with more than two unknowns (e. Mathematics for Physical Chemistry. Mathematics for Physical Chemistry University Science Books (2008). Vector calculus.

(b) Determination of heat capacity of the calorimeter and enthalpy of neutralization of . o-. Vogel..I. resorcinol. diethyl ketone.m-. chlorobenzene. Hydrolysis of amides and esters to obtain benzoic acid 4.toluidines and o-. bromobenzene 6. The solid samples must be collected and may used for recrystallization.anisidine) and phenols (β-naphthol.4-DNP of one the following compounds. ELBS. Paper 11-CHHP 307: Physical Chemistry -II PRACTICAL Marks: 50 (I) Thermochemistry (a) Determination of heat capacity of a calorimeter for different volumes using change of enthalpy data of a known system (method of back calculation of heat capacity of calorimeter from known enthalpy of solution or enthalpy of neutralization).p.acetone. ethyl methyl ketone. benzyl alcohol acetophenone to benzoic acid (by iodoform reaction) The above derivatives should be prepared using 0. cyclohexanone 5.di-ethyl ketone. cyclohexanone  oxime of one the following compounds. vanillin. Benzolyation of one of the following compounds: amines (aniline.m.m-. Nitration of one the following compounds: nitrobenzene. o-. di-ethyl ketone. A text book of quantitative Inorganic Analysis. Acetylation of one of the following compounds: amines ( aniline.toluidines and o-. cyclohexanone  semicarbazone of one the following compounds. salicylic acid) 2.5-1g of the organic compound.p. melting point etc.Recommended Texts: 1. Oxidation of the following compounds: benzaldehyde.acetone. A. p-cresol) by SchottenBaumann reaction 3. 1978.anisidine ) and phenols (β-naphthol.p.m-. ethyl methyl ketone.p. Paper 10-CHHP 306: Organic Chemistry -II PRACTICAL Marks: 50 Organic preparations 1. Derivatives of the carbonyl compounds:  2.

diagonal relationship and anomalous behaviour of first member of each group. Study of the solubility of benzoic acid in water and determination of ∆H. Peroxo acids of sulphur. pseudohalogens and basic properties of halogens. . (II) Indexing of given powder diffraction pattern of a cubic crystalline system. Complex formation tendency of s and p block elements. Determination of enthalpy of hydration of copper sulphate. polyhalide ions. Oxides and oxoacids of nitrogen. boron nitrides. Phosphorus and chlorine. bonding. Theoretical principles involved in volumetric analysis. Calculation of the enthalpy of ionization of ethanoic acid. done in the lab. Allotropy and catenation. Basic beryllium acetate and nitrate. preparation. Study of the following compounds with emphasis on structure. Determination of basicity/proticity of a polyprotic acid by the thermochemical method in terms of the changes of temperatures observed in the graph of temperature versus time for different additions of a base. SEMESTER IV Paper 13-CHHT 408: Inorganic Chemistry -III THEORY Marks: 100 Unit I : Chemistry of s and p block elements: Inert pair effect. properties and uses. Also calculate the enthalpy of neutralization of the first step. Determination of heat capacity of the calorimeter and integral enthalpy (endothermic and exothermic) solution of salts. interhalogen compounds. Relative stability of different oxidation states. borohydrides (diborane) carboranes and graphitic compounds. Hydrides and their classification ionic. silanes. covalent and interstitial. Boric acid and borates. Any other experiment carried out in the class.(c) (d) (e) (f) (g) hydrochloric acid with sodium hydroxide.

2. 1997. Hofmann-elimination reaction. nitriles and isonitriles Amines: Effect of substituent and solvent on basicity. ButterworthHeinemann. F.R.. Freeman & Co. Lee. Cotton. ELBS (1991). and polysulphates. Recommended Texts: 1. 3. preparation and properties of XeF2 and XeF4. Molecular shapes of noble gas compounds (VSEPR theory). VCH. synthesis.N. comparison with organic polymers. Chemistry of the Elements. Distinction between 10. and Earnshaw. Paper 14-CHHT 409: Organic Chemistry -III THEORY Marks: 100 Unit I: Nitrogen Containing Functional Groups Preparation and important reactions of nitro and compounds. Concise Inorganic Chemistry. and Wilkinson.A. Hoffmann’s exhaustive methylation. Diazonium Salts: Preparation and their synthetic applications. Wiley. Canham. and Overton. Unit III : Inorganic Polymers: Types of inorganic polymers.D. J. T. Greenwood. . rationalization of inertness of noble gases. Nature of bonding in noble gas compounds (Valence bond treatment and MO treatment for XeF2). 1999. Advanced Inorganic Chemistry. silicates and phosphazenes. XeF6. Carbylamine reaction. 20 and 30 amines with Hinsberg reagent and nitrous acid. structural aspects and applications of silicones and siloxanes. G.2006 4. Borazines. Clathrates. G.Unit II : Noble gases : Occurrence & uses. N. Preparation and properties: Gabriel phthalimide synthesis. Mannich reaction. Descriptive Inorganic Chemistry.

Medicinal importance of Nicotine. Morphine. Bischler-Napieralski reaction. Recommended Texts: 1. Organic Chemistry. T. Isolation and their physiological action Hoffmann’s exhaustive methylation. Ltd. Quinine. Ltd. & Boyd. Cocaine. Unit IV: Alkaloids Natural occurrence. I. N. R. I. Polynuclear hydrocarbons. Fischer indole synthesis and Madelung synthesis). Doebner-Miller synthesis. Unit III: Heterocyclic Compounds Classification and nomenclature. L. Pyrimidine. 2. Friedlander’s synthesis. Dorling Kindersley (India) Pvt. Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural Products). (Pearson Education). aromaticity in 5-numbered and 6-membered rings containing one heteroatom. Finar. R. 3. Knorr pyrrole synthesis. Hantzsch synthesis). Pyridine (Hantzsch synthesis). Skraup synthesis. Structure. reactions and mechanism of substitution reactions of: Furan. Morrison. . Structure elucidation of indole. Thiophene. Pomeranz-Fritsch reaction Derivatives of furan: Furfural and furoic acid. Structure elucidation of quinoline and isoquinoline. Structure elucidation and synthesis of Hygrine and Nicotine. Synthesis. Hygrine. Dorling Kindersley (India) Pvt. General structural features. and Reserpine. Preparation and structure elucidation and important derivatives of naphthalene and anthracene. Emde’s modification. Organic Chemistry (Volume 1). Pyrrole (Paal-Knorr synthesis. Pictet-Spengler reaction. L. Dorling Kindersley (India) Pvt.Unit II: Polynuclear Hydrocarbons Reactions of naphthalene phenanthrene and anthracene Structure. Ltd. Knorr quinoline synthesis. Finar. (Pearson Education). (Pearson Education).

water-chloroform-acetic acid system. precipitation). (ii) equilibrium constants. rules of oxidation/reduction of ions based on half-cell potentials. azeotropes. Phase diagrams for systems of solid-liquid equilibria involving eutectic. solid solutions. Unit II: Electrochemistry Quantitative aspects of Faraday’s laws of electrolysis. partial miscibility of liquids. Concentration cells with and without transference. CST. with applications. determination of activity coefficients and transference numbers. quinone-hydroquinone. . Chemical cells. liquid junction potential. Qualitative discussion of potentiometric titrations (acid-base. Electromotive force of a cell and its measurement. phase diagram for one component systems. triangular plots.Paper 15-CHHT 410: Physical Chemistry -III THEORY Marks: 100 Unit I: Phase equilibria Concept of phases. derivation of Gibbs Phase Rule for nonreactive and reactive systems. using hydrogen. and (iii) pH values. applications of electrolysis in metallurgy and industry. components and degrees of freedom. liquid-vapour and solid-vapour equilibria. Nernst distribution law: its derivation and applications. lever rule. reversible and irreversible cells with examples. congruent and incongruent melting points. Clausius-Clapeyron equation and its applications to solid-liquid. enthalpy and entropy of a cell reaction. Binary solutions: Gibbs-Duhem-Margules equation. its derivation and applications to fractional distillation of binary miscible liquids (ideal and nonideal). glass and SbO/Sb2O3 electrodes. steam distillation. Three component systems. Application of EMF measurements in determining (i) free energy. redox. Nernst equation. miscible pairs. Standard electrode (reduction) potential and its application to different kinds of half-cells.

4. G. India (2007). de Atkin’s Physical Chemistry 8th Ed. UP (2009). Narosa (2004). Gauss’s law.Recommended Texts: 1. R.dia. wave equation and its plane wave solution. electric field in a dielectric. Oxford University Press (2006). rectification efficiency. electrical potential energy. full-wave and bridge rectifiers.. Physical Chemistry 3rd Ed. Physical Chemistry 4th Ed.Atkins.Castellan. Physical Chemistry Thomson Press. W. LC and π sections). ripple factor. 3. voltage regulations. Elsevier: NOIDA.Ball. potential due to a charge distribution and due to a dipole. Unit IV : Electronics: Half-wave. Unit III: Fundamental laws of electromagnetism: Modification of Ampere’s law. Characteristic curves of bipolar . W. magnetic properties of matter. polarization. 2. G. energy stored in an electric field. shunt capacitator. nature of electromagnetic waves. J. P. Maxwell’s equations. filters (series in inductor. propagation of electromagnetic plane waves in dielectric media. Paper 16-PHCT 402: Physics-II THEORY Marks: 100 Unit I: Electrostatics: Electric field. electromagnetic induction.Mortimer. Zener diode as voltage regulator. D. Lenz’s law. & Paula. magnetic force on a current. equation of continuity and displacement current. tranversality and polarization. load regulation. Biot Savart law. Lorentz force. Unit II : Magnetism: Magnetic field due to a current-carrying conductor. spinning of a magnetic dipole in an external magnetic field. W. flux. para.and ferromagnetism.

OR. Barkhausen’s criterion for self-sustaining oscillations. Devices and Applications (8th Ed. negative and positive feedback. the black box idea of CE. Electronic Fundamentals and Applications: Integrated and Discrete Systems. static and dynamic load line.transistors. small signal active output. Paper 13-CHHP 408: Inorganic Chemistry -III PRACTICAL Marks: 50 (a) Complexometric Titrations: (i) Complexometric estimation of (i) Mg2+ (ii) Zn2+ using EDTA (ii) Estimation of total hardnesss of water samples (iii) Estimation of Ca2+ in solution by (substitution method) using Erio-chrome black-T as indicator. biasing (fixed and self) of transistor circuit. Malvino. Boolean algebra (Boolean laws and simple expressions). Tata McGrawHill (2008). binary adders. D. D. BCD. NOR. . LC and phase shift oscillators. 1’s and 2’s complements. 3. M. 4. half adder. 5th Ed. D.) Prentice-Hall (2009). hybrid model of a CE transistor circuit. (ii) Estimation of Ca/Mg in drugs and Biological samples. octal and hexadecimal). Inc. Logic gates. CB and CC transistor circuits as two-port network. J.P. J. (2007). Prentice-Hall (1999). D. thermal instability of bias. Digital Principles and Applications. Recommended Texts: Griffiths. L. NAND. 2. analysis of a small signal amplifier: its voltage and current gains. T. half subtractor. & Buchla. 1. & Leach. AND. P. full adder and full subtractor. Introduction to Electromagnetism 3rd Ed. Electronics Fundamentals: Circuits. A. XOR and NXOR. Ryder. Prentice-Hall. Unit V: Digital electronics: Number systems (binary. Floyd.

benzoic acid. m-dinitrobenzene to m-nitroaniline 3. Photochemical reduction of benzophenone to benzopinacol 5. Cu(II) and Cd (II)C Paper 14-CHHP 409: Organic Chemistry -III PRACTICAL Marks: 50 Organic Preparations 1. Reduction: nitrobenzene to azobenzene (TLC of the mixture).(b) Argentometry Estimation of Cl‾ (i) By Mohr’s method. Diels-Alder reaction between anthracene and maleic anhydride 2. S-benzylisothiuranum salts of any one water soluble and one water insoluble acid: acetic acid. Glycine by formylation method 3. Condensation of p-toluidine with benzaldehyde/salicylaldehyde/2-hydroxy-3methoxy benzadehyde to get Schiff’s base (solventless condensation) Estimation of: 1. Benzoin condensation of benzaldehyde (using thiamine hydrochloride) 6. phthalic acid 4. Phenol and aniline by bromination with potassium bromate-potassium bromide method 2. (iii) By Fajan’s method. phenyl acetic acid. (c) Paper Chromatographic separation of Ni (II) and Co(II). Saponification value of an oil/fat Paper 15-CHHP 410: Physical Chemistry -III PRACTICAL (I) Marks: 50 Study the equilibrium of at least one of the following reactions by the distribution method: . (ii) By Vohlard’s method. oxalic acid.

CL and π filters). NOT. 7. Calibration of DC and AC voltages. 6. current sensitivity. CC configurations). (V) Phase equilibria: Construction of the phase diagram of (i) simple eutectic and (ii) congruently melting systems. using cooling curves and ignition tube methods. To verify experimentally OR. Study of Colpitts oscillator. NAND gates. Paper 16-PHCP 402: Physics-II PRACTICAL Marks: 50 1. 4. Study of a Ballistic Galvanometer: resistance. 12. 8. Any other experiment carried out in the class. .(aq) (ii) Cu2+(aq) + nNH3 → Cu(NH3)n2+ (II) Perform the following potentiometric titrations (at least two): (i) Strong acid with strong base (ii) weak acid with strong base and (iii) dibasic acid with strong base (III) Potentiometric titration of Mohr's salt with potassium dichromate. Determination of high resistance by leakage method. Self-inductance measurement by Owen’s bridge.(i) I2(aq) + I. frequency and phase measurements of a signal. 11. Determination of mutual inductance by Ballistic Galvanometer. 2. NOR. Study of power supply (rectification factor. NAD. CE. charge sensitivity. 10. 3. Study of basic RC coupled amplifier (frequency response and band width). 9. (IV) Determination of critical solution temperature and composition of the phenol-water system and to study the effect of impurities on it.→ I3. voltage and load regulation for C. Study of Half-Adder/ Subtractor. Operations and measurements by Cathode Ray Oscilloscope (CRO). 5. L. Study of transistor characeteristics (CB. Measurement of magnetic field by search coil. and critical damping resistance of the galvanometer.

f. and Kotz. Unit II: Transition elements: General group trends with special reference to electronic configuration. Saunders Co. 3. colour. magnetic and catalytic properties. spectral and magnetic properties. Chemistry of Ti. Chemistry of the Elements. Chelate effect. Labile and inert complexes. polynuclear complexes. IUPAC nomenclature of coordination compounds. Octahedral vs. J. oxidation states. Fe and Co in various oxidation states (excluding their metallurgy) Unit III: Lanthanoids and actinoids: electronic configuration. Crystal field theory. tetrahedral coordination. Recommended Texts: 1. and Pearson. electroneutrality principle and back bonding.. Greenwood. Difference between the first. Stability of various oxidation states and e. 1977. Inorganic Chemistry W. Mechanisms of Inorganic Chemistry. John Wiley & Sons..m. Stereochemistry of complexes with 4 and 6 coordination numbers. NY. V.. 1967. (Latimer & Bsworth diagrams).N.C.C. .1997.F. pairing energies. square planar geometry. Cr Mn. ∆t). & Earnshaw A. ButterworthHeinemann. Qualitative aspect of Ligand field and MO Theory. isomerism in coordination compounds. colour. CFSE in weak and strong fields. valence bond theory (inner and outer orbital complexes). tetragonal distortions from octahedral geometry Jahn-Teller theorem. variable valency. 2. Purecell. lanthanide contraction. factors effecting the magnitude of 10 Dq (∆o.SEMESTER V Paper 17-CHHT 511: Inorganic Chemistry -IV THEORY Marks: 100 Unit I : Coordination Chemistry Werner’s theory. N. ability to form complexes. measurement of 10 Dq (∆o). separation of lanthanides (ion-exchange method only). second and third transition series. Basolo.B. K. R. F.

Cytosine. ionic properties and reactions. α-Amino Acids . pKa values. lactose and sucrose Polysaccharides – Elementary treatment of starch. Haworth projections and conformational structures. C-protecting and C-activating groups . Peptides and Proteins Amino acids. epimers and anomers. isoelectric point and electrophoresis. Unit II: Nucleic Acids Components of nucleic acids. methods of peptide synthesis. mutarotation. classification and their biological importance Monosaccharides: Constitution and absolute configuration of glucose and fructose.Paper 18-CHHT 512: Organic Chemistry -IV THEORY Marks: 100 Unit I: Carbohydrates Occurrence. Structure of polynucleotides. Peptides and their classification. Unit III: Amino acids. Nucleosides and nucleotides. determination of ring size of glucose and fructose. Structure.Solid-phase synthesis Unit IV: Lipids . Guanine. Interconversions of aldoses and ketoses. Zwitterions. Killiani-Fischer synthesis and Ruff degradation. synthesis and reactions of: Adenine. Uracil nd Thymine. Synthesis of peptides using N-protecting. cellulose and glycogen.Synthesis. Disaccharides – Structure elucidation of maltose. Study of peptides: determination of their primary structures-end group analysis.

Finar. Ltd. Morrison. common fatty acids present in oils and fats. structure and therapeutic uses of antipyretics: Paracetamol (with synthesis). . Organic Chemistry (Volume 1). 5. (Pearson Education). Tymoczko. I. L. Finar. N. D. (Pearson Education). Lehninger’s Principles of Biochemistry. Freeman. Ltd. 3. Hydrogenntion of fats and oils. Berg. iodine number. Analgesics: Ibuprofen (with synthesis). J. Nelson. M. L. Neral and α. Biochemistry. H. Organic Chemistry. Freeman. & Stryer. Dorling Kindersley (India) Pvt. Elucidation of stucture and synthesis of Citral.. Recommended Texts: 1.Introduction to oils and fats. R. H. vitamin C and antacid (ranitidine) Unit VI: Terpenes Occurrence. T. Reversion and rancidity. Unit V: Pharmaceutical Compounds: Structure and Importance Classification. 2. Ltd. Antimalarials: Chloroquine (with synthesis). An elementary treatment of Antibiotics and detailed study of chloramphenicol. classification. azadirachtin (neem). W. W. Dorling Kindersley (India) Pvt. J. Fourth Edition. Dorling Kindersley (India) Pvt. Saponification value. Sixth Edition. acid value. M. L. & Boyd. L. I. 4. R. & Cox.terpineol. Medicinal values of curcumin (haldi). Organic Chemistry (Volume 2: Stereochemistry and the Chemistry of Natural Products). isoprene rule. M. (Pearson Education). L.

Molar conductivity at infinite dilution. effect of particle size and efficiency of nanoparticles as catalysts. specificity and selectivity. and (v) hydrolysis constants of salts. experimental methods of the determination of rate laws. (ii) ionic product of water (iii) solubility and solubility product of sparingly soluble salts. kinetics of complex reactions (integrated rate expressions up to first order only): (i) Opposing reactions (ii) parallel reactions and (iii) consecutive reactions and their differential rate equations (steady-state approximation in reaction mechanisms) (iv) chain reactions. chemisorption. equivalent and molar conductivity and their variation with dilution for weak and strong electrolytes. Catalysis: Types of catalyst. rate laws in terms of the advancement of a reaction. activation energy. Wien effect. Lindemann mechanism. Temperature dependence of reaction rates. Surface chemistry: Physical adsorption. Ionic velocities. mobilities and their determinations. Conductivity. Walden’s rules. Enzyme catalysis. nature of adsorbed state. (iv) conductometric titrations. acid-base catalysis. Collision theory of reaction rates. Debye-Falkenhagen effect. mechanisms of catalyzed reactions at solid surfaces. determination of transference numbers using Hittorf and Moving Boundary methods. qualitative treatment of the theory of absolute reaction rates. adsorption isotherms. Arrhenius equation. Unit II: Chemical Kinetics Order and molecularity of a reaction. differential and integrated form of rate expressions up to second order reactions.Paper 19-CHHT 513: Physical Chemistry -IV THEORY Marks: 100 Unit I : Conductance Arrhenius theory of electrolytic dissociation. transference numbers and their relation to ionic mobilities. Unit III: Photochemistry . Kohlrausch law of independent migration of ions. Debye-Hückel-Onsager equation. Michaelis-Menten mechanism. Applications of conductance measurement: (i) degree of dissociation of weak electrolytes.

Classification. of photochemistry.pleated sheets. Cellular currency of energy (ATP). Chemical Kinetics Pearson Education: New Delhi (2004).Characteristics of electromagnetic radiation. P. Stereospecificity of enzymes. 3. Alcoholic and Lactic acid fermentations. Castellan.Active site. Paper 20-CHHT 514: Biochemistry and Environmental Chemistry THEORY Marks: 100 Unit I: Carbohydrates: Biological importance of carbohydrates. Physical Chemistry Thomson Press. Narosa (2004). Liposomes and their biological functions and underlying applications. Enzyme inhibitors. Recommended Texts: 1. D. Role of photochemical reactions in biochemical processes. J. photosensitised reactions. Atkins. Laws. actinometry. . Lipid membrane. Oxford University Press (2006). de Atkin’s Physical Chemistry 8th Ed. Primary. secondary and tertiary structures of proteins: α-helix and β. Structure of DNA (Watson-Crick model) and RNA. & Paula.Coenzymes and cofactors. Laidler. India (2007). Physical Chemistry 4th Ed. Ball. examples of low and high quantum yields. 4. Genetic Code. Transcription and Translation. Introduction to Biocatalysis:Importance in “Green Chemistry” and Chemical Industry Unit II: Lipids: Biological importance of triglycerides and phosphoglycerides and cholesterol. 2. quenching. Denaturation of proteins Enzymes: Nomenclature. chemiluminescence. G. W.. J. biological importance. Introduction to Gene therapy. W. Biological roles of DNA and RNA: Replication. photostationary states. K. Glycolysis.Krebs cycle Proteins: classification. photochemical equilibrium and the differential rate of photochemical reactions. Metabolism. W. Lambert-Beer’s law and its limitations. Mechanism of enzyme action. Characteristics (mention of Ribozymes). quantum yield. physical significance of absorption coefficients.

aquatic ecosystems. and Rodwell. . (2005) Environmental Studies. New Paper 17-CHHP 511: Inorganic Chemistry -IV PRACTICAL (a) Marks: 50 Quantitative Analysis: The following quantitative estimations are to be carried out. Selective and Scientific Books. Techniques for measuring water pollution. nitrogen and sulfur Air Pollution: Major regions of atmosphere. Solar energy. D.L. Biogeochemical cycles of carbon.A. Hydrogen. Tymoczko. Air pollutants: types.M.. 2. (i) Estimation of nickel (II) using Dimethylglyoxime as the precipitant. A. 3. Controls of air pollution. Techniques of measuring air pollutants. Photochemical Smog: its constituents and photochemistry.M. and Stryer. Climate change. sources. G. R.E. (2009) Harper’s Illustrated Biochemistry. Nuclear Fusion / Fisson. (2006) Environmental Science 11th edition. Sources and nature of water pollutants. V. XXVIII edition. J. Granner. Green house effect. Murray. Manahan S. (2006) Biochemistry.. L. (2009) principles of Biochemistry. Impacts of water pollution on hydrological and ecosystems. Freeman and Co. Lange medical Books/ McGraw-Hill 4. petrol and Natural gas. Mayes.L. Tidal and Hydel etc. and Lehninger.H. Nuclear Pollution: Disposal of nuclear waste. CRC Press 5. particle size and chemical nature. Miller. Chemical and photochemical reactions in atmosphere. VI the Edition.Unit III: Environment and it’s segments. Freeman and Co. Ecosystems.T.IV Edition. Berg. nuclear disaster and it’s Management Recommended Texts: 1. W. Major sources of Air pollution Effects of air pollution on living organisms and vegetation. Water Pollution: Hydrological cycle..W. Brooks/Cole 6. Water purification methods Unit IV: Energy and Enviornment: Sources of energy: Coal. Mishra. geothermal. P. Nelson. D..K. A.K. water resources. (2005) Environmental Chemistry. global warming. Cox. M. Environmental effects of Ozone. W.H. J.L.

A text book of Quantitative Analysis.(ii) Estimation of copper as CuSCN (iii) Estimation of iron as Fe2O3 by precipitating iron as Fe(OH)3 through (i) Heterogeneous and (ii) Homogeneous media. [Cu(NH3)4]SO4 H2O (ii) Potassium trisoxalatochromate (III).10 phenanthroline Recommended Texts: 1.I. Vogel. Tests for following functional groups and unsaturation 3. A. Qualitative analysis of the following types of unknown organic compounds       Carboxylic acids Phenols Alcohols Aldehydes Ketones Esters . (iv) (b) Inorganic Preparations (i) Tetraammine copper (II) sulphate. K3[Cr(C2O4)3] (iii) Cis and trans K[Cr(C2O4)2 (H2O2] Potassium dioxalatodiaquachromate (III) Pentaammine carbonato Cobalt (III) ion (iv) (c) Spectrophotometric estimation of Ferrous ions by using 1. Paper 18-CHHP 512: Organic Chemistry -IV PRACTICAL Marks: 50 1. Systematic analysis of extra elements in the given unknown compounds 2. Estimation of Al (III) by precipitating with oxine and weighing as Al(oxine)3 (aluminium oxinate). ELBS 1986.

To perform quantitative estimation of protein using Lowry’s method. organic solvents. To study the effect of temperature. Paper 20-CHHP 514: Biochemistry and Environmental Chemistry PRACTICAL 1. Qualitative analysis of the soil from different locations for pH and different water soluble cations and anions Marks: 50 .Paper 19-CHHP 513: Physical Chemistry -IV PRACTICAL (I) (II) Marks: 50 To study changes in conductance in the following systems (i) strong acid-strong base (ii) weak acid-strong base and (iii) mixture of strong acid and weak acid-strong base Study the kinetics of the following reactions. Study of the activity of Trypsin using fresh tissue extracts. Initial rate method: Iodide-persulphate reaction 2. Integrated rate method: (a) Acid hydrolysis of methyl acetate with hydrochloric acid. 8. Study of the action of salivary amylase at optimum conditions 3. (b) Iodide-persulphate reaction (c) Saponification of ethyl acetate. Determine the concentration of the unknown sample using the standard curve plotted. Effect of pH on the action of salivary amylase 4. Isolation of Genomic DNA from E Coli 9. on semi-permeable membrane. Effect of temperature on the action of salivary amylase 5. volumetrically or conductometrically. 2. 7. 1. Effect of inhibitor on the action of salivary amylase 6. Any other experiment carried out in the class.

synergic effect (MO diagram of CO) Carbonylate anions. . Quantitative estimation of oxidisable organic matter in soil. Sodium / K-pump. Excess and deficiency of some trace metals. EAN rule. Unit III: Metal carbonyls: Preparation. classification of elements according to their action in biological system. Use of chelating agents in medicine. SEMESTER VI Paper 21-CHHT 615: Inorganic Chemistry -V THEORY Marks: 100 Unit I: Theoretical principles: Theoretical principles and chemistry involved in qualitative analysis of mixture of cations and anions including interfering and insolubles. π-acceptor behaviour of carbon monoxide. ferrocene and its reactions. Cd and As).10. structure and bonding of mononuclear carbonyls. Hardness of water by EDTA titration 12. carbonate and bicarbonates by volumetry and calcium and magnesium by EDTA titration. properties. Study of pH and conductivity of tap water and polluted water. Unit II: Organometallic Compounds: Definition and classification of organometallic compounds. Pb. Geochemical effect on the distribution of metals. reasons for toxicity. Toxicity of metal ions (Hg. 11. Unit IV: Bioinorganic Chemistry: Metal ions present in biological systems. carbonic anhydrase and carboxypeptidase.

Wiley-VCH. N and S containing functional groups. conjugation. Intensity of absorption. & Wilkinson. 1999. carboxylic acids and esters. Lippard. Application of Woodward Rules for calculation of λmax for the following systems: α. UV Spectroscopy: Types of electronic transitions. Cotton. homoannular and heteroannular. 2.B. Conjugated dienes: alicyclic. K. 1993. F. Principles of Bioinorganic Chemistry Panima Publishing Company 1994. IR Spectroscopy: Fundamental and non-fundamental molecular vibrations. Inorganic Chemistry W. Anisotropic effects in alkene. 3. aldehydes and aromatics. chemical shift and factors influencing it. resonance and ring size on IR absorptions. Storage and transfer of iron. Paper 22-CHHT 616: Organic Chemistry -V THEORY Marks: 100 Unit I: Organic spectroscopy General principles Introduction to absorption and emission spectroscopy. Purcell. NMR Spectroscopy: Basic principles of Proton Magnetic Resonance. ketones and dienes). alkyne.bonding. distinction between cis and trans isomers. ketones. J. application in functional group analysis. G. Hemoglobin. Interpetation of NMR spectra of simple compounds Applications of IR.M..J.A. UV and NMR for identification of simple organic molecules. 1977. J. IR absorption positions of O. Prentice Hall. S.C. Saunders Co. λmax. Huheey. Inorganic Chemistry. Recommended Texts: 1.Iron and its application in bio-systems. Effect of H. Extended conjugated systems (aldehydes. J.β unsaturated aldehydes. 4. Fingerprint region and its significance. Chromophores and Auxochromes. .E. & Berg. Advanced Inorganic Chemistry. Bathochromic and Hypsochromic shifts. Spin – Spin coupling and coupling constant.F & Kotz.

Mordant and Vat Dyes. anionic and free radical addition polymerization. 3. Phthalein Dyes – Phenolphthalein and Fluorescein. Degree of polymerization. Polydispersity Index. Organic Chemistry. Dorling Kindersley (India) Pvt. (Pearson Education). R.). Edible Dyes with examples. Morrison. Billmeyer. T. Polyurethanes) and thermosoftening (PVC. Rubbers – natural and synthetic: Buna-S. tri-block and amphiphilic polymers. Vulcanization. Biodegradable and conducting polymers with examples. Metallocene-based Ziegler-Natta polymerisation of alkenes.Addition and condensation . Polymer additives. Ltd. & Boyd. F.Unit II: Dyes Classification. Chemistry of dyeing. Rosaniline and Crystal Violet. Chloroprene and Neoprene. S. Textbook of Organic Chemistry (1st Ed. Weight average molecular weight. polyamido. R. polythene). W. Organic Spectroscopy. Recommended Texts: 1.Mechanism of cationic.Malachite Green. polyester). Preparation and applications of plastics – thermosetting (phenol-formaldehyde. New Age International (P) Ltd. Fabrics – natural and synthetic (acrylic. . Colour and constitution. Synthesis and applications of: Azo dyes – Methyl Orange and Congo Red (mechanism of Diazo Coupling). Number average molecular weight. Unit III: Polymers Introduction and classification including di-block. P. Kemp. Textbook of Polymer Science. 2. Introduction to liquid crystal polymers. Triphenyl Methane Dyes . N. John Wiley & Sons. Pub. Palgrave. Polymerisation reactions . Kalsi. W. Inc. Natural dyes –structure elucidation and synthesis of Alizarin and Indigotin. 4.

Angular momentum: Commutation rules. separation of variables. Rigid rotator model of rotation of diatomic molecule. harmonic oscillator. 2p. Schrödinger equation. transformation to spherical polar coordinates. 3s. Paper 23-CHHT 617: Physical Chemistry -V THEORY Marks: 100 Unit I: Quantum Chemistry Postulates of quantum mechanics. quantum mechanical operators. detailed solution not required) and their limitations. Refinements of the two approaches (Configuration Interaction for . 2s. R. quantization of energy (only final energy expression). degeneracy. radial part. Schrödinger equation and its application to free particle and “particle-in-a-box” (rigorous treatment). Viswanathan. Spherical harmonics. Qualitative treatment of simple harmonic oscillator model of vibrational motion: Setting up of Schrödinger equation and discussion of solution and wavefunctions.. Need for approximation methods. Extension to two and three dimensional boxes. radial distribution functions of 1s. Qualitative extension to H2. hydrogen atom). zero-point energy and Heisenberg Uncertainty principle. Gowariker. J. quantization of energy levels. Bonding and antibonding orbitals. New Age International (P) Ltd. Average and most probable distances of electron from nucleus. LCAOMO treatment of H2+. 3p and 3d orbitals. Pub. & Sreedhar. wavefunctions. N. V. Vibrational energy of diatomic molecules and zero-point energy. V. Discussion of solution. Separation of variables. probability distribution functions. Polymer Science. Chemical bonding: Covalent bonding. nodal properties. Setting up of Schrödinger equation for many-electron atoms (He. Li). Statement of variation theorem and application to simple systems (particle-in-a-box. valence bond and molecular orbital approaches. Qualitative treatment of hydrogen atom and hydrogen-like ions: setting up of Schrödinger equation in spherical polar coordinates.5. quantization of square of total angular momentum and z-component. Comparison of LCAO-MO and VB treatments of H2 (only wavefunctions.

BornOppenheimer approximation. Tata McGraw-Hill: New Delhi (2006). Larmor precession. & McCash. House. J. hot bands. their intensity difference. anharmonicity. Stokes and anti-Stokes lines. electronic transitions. spin-spin coupling and high resolution spectra. modes of vibration. Vibration-rotation spectroscopy: diatomic vibrating rotator. computation of force constant. interpretation of PMR spectra of organic molecules. Chandra. chemical shift and low resolution spectra. amplitude of diatomic molecular vibrations. Electronic spectroscopy: Franck-Condon principle. Introductory Quantum Chemistry Tata McGraw-Hill (2001). Effect of nuclear spin. E. Banwell.MO. Simple Hückel Molecular Orbital (HMO) theory and its application to simple polyenes (ethene. concept of group frequencies. Qualitative description of LCAO-MO treatment of homonuclear and heteronuclear diatomic molecules (HF. Q. K. N. fundamental frequencies. hyperfine structure. Localised and non-localised molecular orbitals treatment of triatomic (BeH2. R branches. Recommended Texts: 1. M. A. Electron Spin Resonance (ESR) spectroscopy: Its principle. fluorescence and phosphorescence. Unit II: Molecular Spectroscopy: Interaction of electromagnetic radiation with molecules and various types of spectra. 2. rule of mutual exclusion. dissociation energies. Elsevier: USA (2004). butadiene). isotopic substitution. C. Fundamentals of Molecular Spectroscopy 4th Ed. calculation of electronic transitions of polyenes using free electron model. Rotation spectroscopy: Selection rules. ESR of simple radicals. E. different scales. determination of bond lengths of diatomic and linear triatomic molecules. Nuclear Magnetic Resonance (NMR) spectroscopy: Principles of NMR spectroscopy. Qualitative MO theory and its application to AH2 type molecules. overtones. Fundamentals of Quantum Chemistry 2nd Ed. H2O) molecules. singlet and triplet states. LiH). . ionic terms in VB). 3. Vibrational Raman spectra. degrees of freedom for polyatomic molecules. Vibrational spectroscopy: Classical equation of vibration. Raman spectroscopy: Qualitative treatment of Rotational Raman effect. dissociation and predissociation. intensities of spectral lines. P. Morse potential.

Lowe. BASIC keywords and commands.M. Simple programs using these concepts. Elements of the BASIC language. inbuilt functions. information technology. iterative. T. Programming in Basic: Problem solving with structure and style. data storage and backup. P. Conceptual background of molecular modelling: Potential energy surfaces. networks. . Statistical analysis. P. Unit II: Computer programming: Constants. arithmetic expressions. Quantum Chemistry Academic Press (2005). (1985). Noggle. & Peterson. hierarchy of operations. Basic operations using windows. Venit. Debugging. Jaico Publishing House: Delhi (1996). H. Logical and relative operators. Matrix addition and multiplication. Newton-Raphson method). S. numerical solution of differential equations. Recommended Texts: 1. Physical Chemistry 2nd Ed. K. & Reid. J. Simpson’s rule). Physical chemistry on a Microcomputer. Pearson (2010). Paper 24-CHHT 618: Applications of Computers in Chemistry THEORY Marks: 100 Unit I :Recapitulation of computer basics: PC hardware. BASIC programs for numerical differentiation and integration (Trapezoidal rule. 3. Engel. bits. J. Chapter on Computational Chemistry.4. Elementary ideas of molecular mechanics and practical MO methods. bytes. finding roots (quadratic formula. binary and ASCII formats. Strings and graphics. variables. Little Brown & Co. 2. Compiled versus interpreted languages. operating systems.

S2-. 2. BO33-. Bi3+ Cu2+. Fe2+ OR Fe3+. As3+. Al3+. Sn2+ or Sn4+. CO23. Cd2+. insoluble should be avoided. C2O2-4 Paper 22-CHHP 616: Organic Chemistry -V PRACTICAL Marks: 50 1. Qualitative analysis of following types of unknown organic compounds 1. K+ Anion : CO32-. Cl-. F-. NO-2.Paper 21-CHHP 615: Inorganic Chemistry -V PRACTICAL Marks: 50 Qualitative analysis: Using H2S /PTC/ Thioacetamide or any other reagent. I-. NH4+.Co2+. SO42-. Identification of cations and simple anions in a mixture of salts containing not more than six ions (Three cations and three anions) interfering anions using semimicro scheme of analysis. Cr3+. Mg2+. If combination of cations or anions is given in the mixture. PO43-. Carbohydrates Primary. 3. Mn2+. CH3 COO-. Spot tests should be carried out for final identifications wherever feasible. Ba2+. Tests for following functional groups 2. Ca2+. NO-3. 5. SO2-3. 6. Sr2+. Ni2+. Br-. SO32-. 4. secondary and tertiary amines Nitro compounds Amides Aryl halides Hydrocarbons . Zn2+. Cation : Pb2+. Sb3+.

V. multimedia animations. sp3.e. i. kJ/mol. cm-1. online publication (www/html). • Study the kinetics of interaction of crystal violet with sodium hydroxide colourimetrically. • Analysis of the given vibration-rotation spectrum of HCl(g) • Record the UV spectrum of p-nitrophenol (in 1:4 ethanol:water mixture). if any. C-C and C-N triple bonds. spectrum of a given compound (acetone) in cyclohexane (a) Plot transmittance versus wavelength. (b) Plot absorbance versus wavelength. Paper 24-CHHP 618: Application of Computers in Chemistry PRACTICAL Marks: 50 Word processing: Incorporating chemical structures into word processing documents. Any other experiment carried out in the class. Repeat after adding a small crystal of NaOH. Comment on the difference. . (c) Calculate the energy involved in the electronic transition in different units. • Record the U. sp2 and sp hybridized C-H bonds by IR spectroscopy (IR spectra to be provided) Paper 23-CHHP 617: Physical Chemistry -V PRACTICAL Marks: 50 • Colourimetry • Verification of Lambert-Beer's Law • Determination of pK (indicator) for phenolphthalein or methyl red • Study the formation of a complex between ferric and thiocyanate (or salicylate) ions. kcal/mol & eV.Identification of the functional groups. presentation graphics. etc.

g. ArgusLab (www. volume of a van der Waals gas. pH of a weak acid ignoring/ not ignoring the ionization of water. molar exinction coefficients from absorbance data). These are representative projects. spectral data.planaria-software. gas kinetic theory. Numerical solution of differential equations (e.openoffice.g. ChemOffice (Free alternatives: OpenOffice (www.. numerical curve fitting. graphical solution of equations. References: Internet. integration (e. kinetics). documentation of software.Handling numeric data: spreadsheet software (Excel). registration required). Numeric modelling.Software: Microsoft Office.g. simulation of Diels-Alder reaction. rotation of 1. Structures and properties. statistical analysis. SN2 reactions).g. Internal assessment may be based on the project. Chemical information on the web. data from phase equilibria studies).g. solving equations numerically (e. The students must be encouraged to explore other projects and prepare a presentation/poster based on their project.3-butadiene.com. calculation of molecular structures and properties (e. distribution of isomers. numerical differentiation (e. equilibrium constant expressions). ISIS Draw (http://www. entropy/enthalpy change from heat capacity data). linear regression (rate constants from concentrationtime data. pressure-volume curves of van der Waals gas. handling data from potentiometric titrations). . plotting graphs using a spreadsheet (radial distribution curves for hydrogenic orbitals. simple calculations. Note: 1. 2.mdli. conformational energies of butane. Molecular modelling: Visualization of 3D structures. energies of orbitals and total energy as a function of bond angle for H2O.com).org). Chemical abstracts.

410 PHCT .512 CHHT .102 Technical Writing and Communication in English ENAT – 101 Paper 4 Mathematics–I MACT .101 Semester III Paper 9 Inorganic Chemistry – II CHHT .617 Paper 24 Applications of Computers in Chemistry CHHT .302 Semester V Paper 17 Paper 5 Physical Chemistry – I CHHT .616 Paper 23 Physical Chemistry – V CHHT .Semester System at the undergraduate level Course of Study : B.514 Paper 21 Inorganic Chemistry – V CHHT .203 Paper 6 Analytical Methods in Chemical Analysis Paper 7 Paper 8 Biology-II Physics – I LSPT .306 CHHT .511 CHHT .101 Total number of papers: 24 Semester II Paper 3 Paper 2 Organic Chemistry –I CHHT .202 PHCT .408 CHHT .Sc (Hons.402 Semester VI Paper 18 Paper 19 Inorganic Chemistry – IV Organic Chemistry – IV Physical Chemistry – IV CHHT .409 CHHT .I CHHT .513 Paper 20 Biochemistry and Environmental Chemistry CHHT.615 Paper 22 Organic Chemistry – V CHHT .) Chemistry Semester I Paper 1 Inorganic Chemistry.307 Paper 12 Mathematics– II MACT .204 Paper 16 Paper 13 Inorganic Chemistry – III Paper 14 Organic Chemistry – III Paper 15 Physical Chemistry – III Physics – II CHHT .305 Semester IV Paper 10 Organic Chemistry – II Paper 11 Physical Chemistry – II CHHT .618 .201 CHHT .