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Ans\ver the foll0 .

-ELECT!)\O CHE1\HSTl{Y
.
.

\ l
,
.
wing questions in
n the redox rca ti 2 3+ a \\ ord or fill rn the blank ----- .. -- .
21
2
c ion Fe + - 2F )+ +Ii. What is ox id1.
W hat is
d
oxi
f
---..
zc .' Jethe . no. o S .
.
t n S 0 2: . '> .r-i.
3 .The
s l
.no. of
on
.
Pho
. 4 6 t . vc:
oxi
4 I \ 11. .
P torus may vary from ---------------------------.
a)
. ~ w uc of the following is hydrogen acting as oxidizing agent
r

'wvt ~ 12
1

to

give Hl b) with 02

tthStogivcH1s.

5.

rr'm'

is

to

.- ...

give H7 0 C) with Li to give LiH d)

the unit of------------

6. \V~1ich one of the following w~uld displace all others from their salt
solutions -rvtg, Al , Fe ,Zn .
Cl2 + 2e-+ 2cr. E0 = l .40 V, Au +3 + Je =- Au E0 .; J .50 V.
7 For
What is E0 cell for 2Au ~3 + 6Cr = 2Au + 3CJ2.
8. On passing a given quahtityof charge through molten salt of
aluminium 18 g of aluminium is produced. What mass of copper is
produced by same charge?

9. 12 and Br.:! arc added to a soln. containing rand B( ions. What

would occur if cone. of each species is IM.


( E0 Iii r = 0.54
V , E0 Br7 I f3r- = l.08V )
l 0. The reduction potential ----------- with decrease in cone. of ions in the

reduction

.soln .
I I. During electrolysis

of 11q. MgS04 the products at anode and cathode

arc-------------------------------------------------.

12. The cells vvliic h convert energy obtained by combustion of Cl I~ . CO


, 112 de. art: called--------------.
I 1. The no. of es involved in the reaction when 1 F electricity i. pas~cd

t hrougl: an clcctrnlytt:
i.-.; -------------------14. 11 tci! storage battery at cathode---------------;-

.-

15. lftlic conductance and sp. conductance


cc I/ constant is --------------- .
--------- J\ -1 B 2
/ 6. For
tlH.: CJct:/ I rc.icuor:O
.
.
(.iq)
100. 1 he E eel I ~t 2,5; is ---------------- .

l 7. Ef~ctrolytic conductance --------------with


metallic conductance
---------------

is reduced .
of the soln are same then its
C + D12
increase

\aq)

cq.constt.

in temp.

while

is

lead storage battery is charged------a) Ph02 dissolves b )


H2S04 1s regenerated c) the lead electrode is coated with PbS0.1 d) the
amount of l-fiS04 decreases.
19. The unit for cell constant is ------------20. A redox_ rc~ction occurs only when the species having higher
------ potential rs reduced .
18. /\s

~1

\ JJ\,),

-' ll rc1u v .
i\
c
,
,
... is
111tllH.\1
e ,vnen
cone.
r
\\/\\at happens to Kand I\ q
- Cl-,~
-1
~ll
cuon . NaOl l , )CJ Ba\ance the fo . tea
. - 'bl 'l
given below feasi e
4
the reaction
.
+ Cb .
,
_, ,IJaCl(aq) + Br2 ~ Na81{a~) u.: ;_ N01 -has

~t\~~

slaw

ta~:d~;~t

9/N:1me a_ secondary cell. H

between

d 1

NaCl+

NaClOJ

f!'

Ln crease

an exarnpl_e:

+H

the

value of

Al IAl+3(0.03M)

[ I x 6 :::: 6 ]

What is cathodic

i1Gand

/I Fe +2(0.02M)

Ecc11

pt ocess .

l
at 298K ror t ie
c.

.
c. 1I 0J

I Fe .

ce

II

Given that E0 At+J/At= ~l.66 and EF/21Fe= -0.44V .What IS the


Afect on e.m.f if [Al+3J = 0.01 M.~

Determine the value of K of the reaction at 298K :

EFe+3,.F/+1rt=
2Fe+3 + Sn+2 -) 2Fe+2 + Sn.,. 4 _Given
77V'
~ o Sn t-4 +2 .
= O i 50V From the obtained value ot Kc '
E
/Sn
, Pt

+ ~
+2
- ot
S
2

h h s
d u cc Fe -- to Fe or n
+

-I
rr: - =
n lOll can r~
and
pre
er d ict W et
12.The A m" NH4Cl is I49.7Scn1-rnol
, the >-..,n OH . 198
A,1111.c1- = 76.J resp. Calculate Arn;NI-LiOH.
_ :-.
13.An N/2 soln. ofa salt occ-upying a vol_t'!T!e bet,_,r:en2~ Pt electrodes
I. 72 cm apart and of area of cross secrron of 4.5 cm nas a

n':

?-

n:.:.-;1::-;Uu1ce

or ]5 ohm

~o

ac-t while di~chargmg and

can _.
K
d E0
_

hip
}.- Justify that rusting is an electrochen11cal
protection?
_/ Describe Fuel cell or Mercury cell.

_ 7/ Derive relations

7.~alculate
, fY"r

i.

)/ Jtate Kohlrausch
recharging

:.

. Ca lculnt: A co .
i.s
14.F.ind the weight of chlorine gas produced when l amp. current
passed for l 51nin through molten NaCl .
. 5.Calculate Kc and maximum work that can be obtained from a cell
with n = 2 . E0 cc11 = 0.46V .
l 6.Discuss the dependence of A m of strong and weak electrolyte on
the
cone. of soln of electrolyte .

o-

l 7 .Conductivity of 0.00241 M acetic acid is 7.896 x l 5Scn1-1


Caku\ate its!\ m, if its A" rn = 390.5 Scn}moi-1 What is its
Dissociation constant ?
18. The+3 foll. reaction is taking
place in a Galvanic cell
2
Cr (aq) + Mg -7 Mg+ (aq) + Cr . Balance it. The electronic flow
\S

from
? How does salt bridge m t
I t which metal to which metal
?
am
1
1-tty in
e c
the two ha ves . Which metal has hi h am
Eo red ?
roneutra
g er
,
[2x 12 = 24]

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